ES2057531T3 - Procedimiento para la preparacion de isomeros de cipermetrina. - Google Patents

Procedimiento para la preparacion de isomeros de cipermetrina.

Info

Publication number
ES2057531T3
ES2057531T3 ES90901870T ES90901870T ES2057531T3 ES 2057531 T3 ES2057531 T3 ES 2057531T3 ES 90901870 T ES90901870 T ES 90901870T ES 90901870 T ES90901870 T ES 90901870T ES 2057531 T3 ES2057531 T3 ES 2057531T3
Authority
ES
Spain
Prior art keywords
pct
isomer
cypermethrine
isomers
pair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90901870T
Other languages
English (en)
Inventor
Sandor Zoltan
Cyorgy Hidasi
Bela Bertok
Istvan Szekely
Janis Hajimichael
Sandor Botar
Lajos Nagy
Va Somfai
Istvan Lak
Andras Rapi
Antal Gajary
Agnes Hegedus
Maria Tary
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chinoin Private Co Ltd
Original Assignee
Chinoin Gyogyszer es Vegyeszeti Termekek Gyara Zrt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from HU16789A external-priority patent/HU199390B/hu
Priority claimed from HU678089A external-priority patent/HU210098B/hu
Application filed by Chinoin Gyogyszer es Vegyeszeti Termekek Gyara Zrt filed Critical Chinoin Gyogyszer es Vegyeszeti Termekek Gyara Zrt
Application granted granted Critical
Publication of ES2057531T3 publication Critical patent/ES2057531T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/11—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound oxygen atoms bound to the same saturated acyclic carbon skeleton
    • C07C255/14—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound oxygen atoms bound to the same saturated acyclic carbon skeleton containing cyano groups and esterified hydroxy groups bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

EL INVENTO SE REFIERE A UN PROCESO PARA LA PREPARACION DE MEZCLAS ISOMERAS DE CIPERMETRINA DE LA FORMULA I, EN LA QUE LOS ATOMOS DE CARBONO INDICADOS POR 1,3 Y ALFA REPRESENTAN UN ATOMO DE CARBONO QUIRAL Y LA LINEA ONDULADA INDICA UNA CONFIGURACION CIS O TRANS RELACIONADA CON EL ANILLO DE CICLOPROPANO QUE CONTIENE MAS ALLA DE LOS OCHO ISOMEROS TEORICAMENTE POSIBLES DE CIPERMETRINA EN ALMENOS EL 95% DEL PAR DE ISOMEROS 1RTRANSS Y 1STRANSR (IB) O SOLAMENTE UNA MEZCLA DE 1RCISS Y 1SCIOSR (IA) Y EL PAR DE ISOMEROS (IB) CON UNA RELACION (IA): (IB) QUE SE ENCUENTRA ENTRE 55:45 ICA DE UN SEGUNDO ORDEN OBTENIDO EN LA PRESENCIA DE UNA BASE DE AMINO Y UN SOLVENTE DE UNA MEZCLA INICIADORA DE ISOMERO DE CIPERMETRINA LA CUAL PRESENTA UNA COMPOSICON PROXIMA AL PAR DE ISOMEROS (IB) Y OTROS ISOMEROS TRANS O BIEN EL PAR DE ISOMEROS (IA) + (IB) EN UNA RELACION NO DESEADA.
ES90901870T 1989-01-17 1990-01-17 Procedimiento para la preparacion de isomeros de cipermetrina. Expired - Lifetime ES2057531T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HU16789A HU199390B (en) 1989-01-17 1989-01-17 Process for producing mixture of cipermetrin's enantiomeres
HU678089A HU210098B (en) 1989-12-27 1989-12-27 Process for producing isomeric mixtures of cypermethrin and stabilised insecticidal compositions and concentrates containing the mixtures

Publications (1)

Publication Number Publication Date
ES2057531T3 true ES2057531T3 (es) 1994-10-16

Family

ID=26317170

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90901870T Expired - Lifetime ES2057531T3 (es) 1989-01-17 1990-01-17 Procedimiento para la preparacion de isomeros de cipermetrina.

Country Status (12)

Country Link
US (1) US5153349A (es)
EP (1) EP0404922B1 (es)
KR (1) KR940003358B1 (es)
AT (1) ATE90338T1 (es)
BR (1) BR9004617A (es)
CA (1) CA2020356C (es)
DE (1) DE69001866T2 (es)
DK (1) DK0404922T3 (es)
ES (1) ES2057531T3 (es)
GE (2) GEP19981465B (es)
LV (1) LV10771B (es)
WO (1) WO1990008132A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0601237A1 (en) * 1992-12-09 1994-06-15 Duphar International Research B.V Method of preparing optically active cyanohydrin derivatives
LV12032B (en) 1995-04-24 1998-09-20 ARGO-CHEMIE Novenyvedoszer Gyarto Ertekesito es Forgalmazo Kft. METHODS OF PESTICIDE COMPOSITIONS AND THEIR ACQUISITION
CN103819363A (zh) * 2014-03-21 2014-05-28 中国农科院植保所廊坊农药中试厂 一种提高高效氯氰菊酯转位合成收率的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4308279A (en) * 1979-06-06 1981-12-29 Fmc Corporation Crystalline, insecticidal pyrethroid
CA1150301A (en) * 1979-11-27 1983-07-19 Michael J. Bull Cyclopropane carboxylic acid ester derivatives
DE3372480D1 (en) * 1982-10-18 1987-08-20 Ici Plc Insecticidal product and preparation thereof
CA1206483A (en) * 1982-11-11 1986-06-24 Johannes Van Berkel Process for preparing cyclopropane carboxylic acid ester derivatives
GB8422872D0 (en) * 1984-09-11 1984-10-17 Ici Plc Insecticidal product
CA1275108A (en) * 1985-01-16 1990-10-09 Laszlo Pap Insecticidal composition comprising more than one active ingredients
DE3522629A1 (de) * 1985-06-25 1987-01-08 Bayer Ag Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl -ester
US4997970A (en) * 1987-06-15 1991-03-05 Fmc Corporation Conversion of pyrethroid isomers to move active species
CA1314559C (en) * 1987-06-15 1993-03-16 John Winfrid Ager Conversion of pyrethroid isomers to more active species

Also Published As

Publication number Publication date
EP0404922B1 (en) 1993-06-09
BR9004617A (pt) 1991-07-30
DE69001866D1 (de) 1993-07-15
DE69001866T2 (de) 1993-09-23
KR940003358B1 (ko) 1994-04-21
US5153349A (en) 1992-10-06
DK0404922T3 (da) 1993-07-12
ATE90338T1 (de) 1993-06-15
CA2020356C (en) 2002-09-03
LV10771B (en) 1996-06-20
GEP19981465B (en) 1998-09-25
CA2020356A1 (en) 1990-07-18
EP0404922A1 (en) 1991-01-02
KR910700229A (ko) 1991-03-04
GEP19981466B (en) 1998-09-25
WO1990008132A1 (en) 1990-07-26
LV10771A (lv) 1995-08-20

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