MD466G2 - Procedeu de preparare a amesticurilor de izomeri ai cipermetrinei - Google Patents
Procedeu de preparare a amesticurilor de izomeri ai cipermetrineiInfo
- Publication number
- MD466G2 MD466G2 MD94-0336A MD940336A MD466G2 MD 466 G2 MD466 G2 MD 466G2 MD 940336 A MD940336 A MD 940336A MD 466 G2 MD466 G2 MD 466G2
- Authority
- MD
- Moldova
- Prior art keywords
- isomers
- cis
- trans
- preparation
- cypermetrine
- Prior art date
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Invenţia se referă la un procedeu de preparare a unor amestecuri de izomeri ai cipermetrinei cu formula Iîn care atomii de carbon, marcaţi prin 1, 3 şi α, se referă la atomii chiralici de carbon, iar linia ondulată indică configuraţia cis- sau trans relativ de inelul ciclopropanic, care conţin din cei 8 izomeri teoretic posibili ai cipermetrinei, cel puţin, 95% cuplu de izomeri 1RtransS şi 1StransR (Ib) sau numai amestecul de cupluri de izomeri 1RcisS şi 1ScisR (Ia) şi (Ib) în raport (Ia): (Ib) = 55:45-25:75, prin transformarea asimetrică de gradul 2, în prezenţa unei amine terţiare şi a unui solvent protonic de la 0°C până la +25°C din amestecul iniţial de izomeri ai cipermetrinei de puritate minimă 90 % masă, care conţine şi alţi izomeri cis şi trans, ce urmează după cuplul de izomeri (Ib), sau cuplul de izomeri Ia+Ib într-un raport nedorit. Procesul decurge continuu în câteva reactoare, amplasate consecutiv. La capătul liniei de reactoare se formează cristale, care opţional se separă din suspensia de cristale.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU678089A HU210098B (en) | 1989-12-27 | 1989-12-27 | Process for producing isomeric mixtures of cypermethrin and stabilised insecticidal compositions and concentrates containing the mixtures |
PCT/HU1990/000006 WO1990008132A1 (en) | 1989-01-17 | 1990-01-17 | Process for the preparation of cypermethrine isomers |
Publications (2)
Publication Number | Publication Date |
---|---|
MD466F1 MD466F1 (ro) | 1996-09-30 |
MD466G2 true MD466G2 (ro) | 1997-04-30 |
Family
ID=10972006
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MD94-0336A MD466G2 (ro) | 1989-12-27 | 1990-01-17 | Procedeu de preparare a amesticurilor de izomeri ai cipermetrinei |
Country Status (6)
Country | Link |
---|---|
AR (1) | AR247726A1 (ro) |
HU (1) | HU210098B (ro) |
LV (1) | LV10232B (ro) |
MD (1) | MD466G2 (ro) |
RU (1) | RU2045516C1 (ro) |
TR (1) | TR25674A (ro) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0205010A2 (en) * | 1985-06-14 | 1986-12-17 | International Business Machines Corporation | Multiple port communications adapter apparatus |
EP0208758A1 (en) * | 1985-01-16 | 1987-01-21 | Chinoin Gyogyszer Es Vegyeszet | PYRETHROIDAL COMPOSITION WITH MORE THAN ONE COMPONENT. |
-
1989
- 1989-12-27 HU HU678089A patent/HU210098B/hu not_active IP Right Cessation
-
1990
- 1990-01-17 RU SU905010694A patent/RU2045516C1/ru not_active IP Right Cessation
- 1990-01-17 MD MD94-0336A patent/MD466G2/ro active IP Right Grant
- 1990-02-07 AR AR90316104A patent/AR247726A1/es active
- 1990-02-28 TR TR20790A patent/TR25674A/xx unknown
-
1993
- 1993-06-15 LV LVP-93-586A patent/LV10232B/xx unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0208758A1 (en) * | 1985-01-16 | 1987-01-21 | Chinoin Gyogyszer Es Vegyeszet | PYRETHROIDAL COMPOSITION WITH MORE THAN ONE COMPONENT. |
EP0205010A2 (en) * | 1985-06-14 | 1986-12-17 | International Business Machines Corporation | Multiple port communications adapter apparatus |
Also Published As
Publication number | Publication date |
---|---|
HU210098B (en) | 1995-02-28 |
HUT55746A (en) | 1991-06-28 |
LV10232B (en) | 1995-04-20 |
AR247726A1 (es) | 1995-03-31 |
RU2045516C1 (ru) | 1995-10-10 |
TR25674A (tr) | 1993-07-01 |
MD466F1 (ro) | 1996-09-30 |
HU896780D0 (ro) | 1990-03-28 |
LV10232A (lv) | 1994-10-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG3A | Granted patent for invention | ||
IF99 | Valid patent on 19990615 |
Free format text: EXPIRES: 20140825 |