ES2052687T5 - Catalizador de deshidrogenacion. - Google Patents
Catalizador de deshidrogenacion.Info
- Publication number
- ES2052687T5 ES2052687T5 ES88201357T ES88201357T ES2052687T5 ES 2052687 T5 ES2052687 T5 ES 2052687T5 ES 88201357 T ES88201357 T ES 88201357T ES 88201357 T ES88201357 T ES 88201357T ES 2052687 T5 ES2052687 T5 ES 2052687T5
- Authority
- ES
- Spain
- Prior art keywords
- dehydrogenation catalyst
- larger
- quantities
- alkenylaromatics
- alkylaromatics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN CATALIZADOR DE DESHIDROGENACION MEJORADO, UTIL PARA TRANSFORMAR ALQUILAROMATICOS EN ALQUENILAROMATICOS, POR EJEMPLO, ETILBENCENO EN ESTIRENO, QUE CONTIENE CANTIDADES INFERIORES DE HIERRO Y CANTIDADES MAYORES DE CERIO Y POTASIO QUE LAS CONOCIDAS DE LA TECNICA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/069,464 US4758543A (en) | 1987-07-01 | 1987-07-01 | Dehydrogenation catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2052687T3 ES2052687T3 (es) | 1994-07-16 |
ES2052687T5 true ES2052687T5 (es) | 1998-04-16 |
Family
ID=22089136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES88201357T Expired - Lifetime ES2052687T5 (es) | 1987-07-01 | 1988-06-30 | Catalizador de deshidrogenacion. |
Country Status (8)
Country | Link |
---|---|
US (1) | US4758543A (es) |
EP (1) | EP0297685B2 (es) |
JP (1) | JP2604426B2 (es) |
AU (1) | AU606174B2 (es) |
BR (1) | BR8803250A (es) |
CA (1) | CA1329584C (es) |
DE (1) | DE3876155T3 (es) |
ES (1) | ES2052687T5 (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05504907A (ja) * | 1989-10-31 | 1993-07-29 | ザ・ダウ・ケミカル・カンパニー | 担持された触媒、その製造法及び炭化水素の脱水素におけるその使用 |
US5262198A (en) * | 1991-04-08 | 1993-11-16 | Aluminum Company Of America | Method of producing a carbon coated ceramic membrane and associated product |
US5376613A (en) * | 1993-05-04 | 1994-12-27 | The Dow Chemical Company | Dehydrogenation catalyst and process for preparing same |
DE4324905A1 (de) * | 1993-07-24 | 1995-01-26 | Basf Ag | Dehydrierungskatalysator und dessen Verwendung |
EP0797560B1 (en) * | 1994-12-14 | 1999-03-10 | Shell Internationale Researchmaatschappij B.V. | Large particle dehydrogenation catalyst and process |
DE19535416A1 (de) * | 1995-09-23 | 1997-03-27 | Basf Ag | Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen |
US6037305A (en) * | 1997-03-03 | 2000-03-14 | Rhodia Chimie | Use of Ce/Zr mixed oxide phase for the manufacture of styrene by dehydrogenation of ethylbenzene |
IT1293531B1 (it) | 1997-08-01 | 1999-03-01 | Sud Chemie Mt S R L Ex Monteca | Catalizzatori per la deidrogenazione dell'etilbenzene a stirene |
US6756339B1 (en) | 1998-04-01 | 2004-06-29 | Sud-Chemie Inc. | Dehydrogenation catalysts |
US6242379B1 (en) | 1998-04-01 | 2001-06-05 | United Catalysts Inc. | Dehydrogenation catalysts |
KR100584961B1 (ko) * | 1999-11-10 | 2006-05-29 | 에스케이 주식회사 | 배연탈질용 선택적 환원 촉매의 코팅방법 및 이의방법으로 제조된 지지체 |
BR0016762A (pt) * | 1999-12-17 | 2002-09-03 | Dow Global Technologies Inc | Processo para desidrogenação de um composto aromático de alquila e regeneração de catalisador em um reator de leito fluidizado e reator de leito fluidizado |
US20020183573A1 (en) * | 2002-05-17 | 2002-12-05 | Cocco Raymond A | Dehydrogenation of an alkyl aromatic compound and catalyst regeneration in a fluidized bed reactor |
US7244868B2 (en) | 2002-06-25 | 2007-07-17 | Shell Oil Company | Process for the dehydrogenation of an unsaturated hydrocarbon |
WO2004060839A1 (en) * | 2002-12-19 | 2004-07-22 | Dow Global Technologies Inc. | Dehydrogenation of alkyl aromatic compound over a rare earth catalyst |
US7282619B2 (en) | 2003-10-14 | 2007-10-16 | Shell Oil Company | Method of operating a dehydrogenation reactor system |
US7297402B2 (en) * | 2004-04-15 | 2007-11-20 | Shell Oil Company | Shaped particle having an asymmetrical cross sectional geometry |
US20060020152A1 (en) * | 2004-07-22 | 2006-01-26 | Theobald Eugene H | Method for the low temperature selective oxidation of hydrogen contained in a hydrocarbon stream |
MX2007005878A (es) * | 2004-11-18 | 2007-06-19 | Shell Int Research | Proceso de deshidrogenacion. |
KR20080046697A (ko) * | 2005-09-16 | 2008-05-27 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 방향족 생성물의 제조방법 |
JP5096751B2 (ja) | 2007-01-26 | 2012-12-12 | クラリアント触媒株式会社 | 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 |
US20090246523A1 (en) * | 2008-03-28 | 2009-10-01 | Shizhong Jason Zhao | Small Diameter Calcium Aluminate Based Catalyst Supports by Extrusion and Pelletizing |
CN102046568A (zh) * | 2008-04-09 | 2011-05-04 | 国际壳牌研究有限公司 | 改进脱氢工艺的方法 |
US20110178350A1 (en) | 2008-09-22 | 2011-07-21 | Waseda University | Dehydrogenation Catalyst of Alkylaromatic Compounds Having High Redox Ability, Process for Producing Same, And Dehydrogenation Method Using Same |
US8809609B2 (en) | 2008-11-07 | 2014-08-19 | Sued-Chemie Catalysts Japan, Inc. | Dehydrogenation catalyst for alkyl aromatic compounds exhibiting high performance in the presence of high-concentration CO2 |
CN103539627B (zh) * | 2012-07-12 | 2015-09-09 | 中国石油化工股份有限公司 | 制造苯乙烯的方法 |
US10336667B2 (en) | 2014-05-09 | 2019-07-02 | Basf Se | Catalyst for dehydrogenating hydrocarbons |
WO2015169825A1 (de) | 2014-05-09 | 2015-11-12 | Basf Se | Katalysator für die dehydrierung von kohlenwasserstoffen |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2036410A (en) * | 1929-08-20 | 1936-04-07 | Du Pont | Process of making styrene |
US1985844A (en) * | 1930-08-16 | 1934-12-25 | Ig Farbenindustrie Ag | Process for the manufacture of aromatic hydrocarbons containing unsaturated side chains |
US2408140A (en) * | 1944-09-18 | 1946-09-24 | Shell Dev | Dehydrogenation catalyst |
US2414585A (en) * | 1945-06-26 | 1947-01-21 | Shell Dev | Catalytic dehydrogenation |
US2866790A (en) * | 1957-02-18 | 1958-12-30 | Phillips Petroleum Co | Catalyst and dehydrogenation process |
NL256686A (es) * | 1959-10-28 | |||
US3223743A (en) * | 1961-12-29 | 1965-12-14 | Monsanto Chemicals | Dehydrogenation of ethylbenzene |
US3364277A (en) * | 1965-05-21 | 1968-01-16 | Shell Oil Co | Dehydrogenating olefins to diolefins in the presence of a yellow iron oxide catalyst |
US3360579A (en) * | 1965-05-21 | 1967-12-26 | Shell Oil Co | Catalytic dehydrogenation of alkylaromatics |
US3904552A (en) * | 1973-03-08 | 1975-09-09 | Girdler Chemical | Dehyrogenation catalyst |
US4098723A (en) * | 1977-01-27 | 1978-07-04 | Shell Oil Company | Catalyst for dehydrogenation |
IN148558B (es) * | 1977-04-14 | 1981-04-04 | Shell Int Research | |
US4467046A (en) * | 1982-01-07 | 1984-08-21 | Smith James L | Dehydrogenation catalyst |
JPS58177148A (ja) * | 1982-04-13 | 1983-10-17 | Mitsubishi Petrochem Co Ltd | スチレン製造用触媒 |
JPS6190741A (ja) * | 1984-10-11 | 1986-05-08 | Nissan Gaadoraa Shokubai Kk | 脱水素用触媒 |
-
1987
- 1987-07-01 US US07/069,464 patent/US4758543A/en not_active Expired - Lifetime
-
1988
- 1988-06-27 CA CA000570520A patent/CA1329584C/en not_active Expired - Lifetime
- 1988-06-29 AU AU18525/88A patent/AU606174B2/en not_active Expired
- 1988-06-30 ES ES88201357T patent/ES2052687T5/es not_active Expired - Lifetime
- 1988-06-30 BR BR8803250A patent/BR8803250A/pt not_active IP Right Cessation
- 1988-06-30 JP JP63164089A patent/JP2604426B2/ja not_active Expired - Lifetime
- 1988-06-30 EP EP88201357A patent/EP0297685B2/en not_active Expired - Lifetime
- 1988-06-30 DE DE3876155T patent/DE3876155T3/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2604426B2 (ja) | 1997-04-30 |
EP0297685A1 (en) | 1989-01-04 |
AU1852588A (en) | 1989-01-05 |
AU606174B2 (en) | 1991-01-31 |
EP0297685B2 (en) | 1998-02-25 |
JPS6445320A (en) | 1989-02-17 |
BR8803250A (pt) | 1989-01-31 |
DE3876155T2 (de) | 1993-04-01 |
DE3876155T3 (de) | 1998-04-30 |
US4758543A (en) | 1988-07-19 |
ES2052687T3 (es) | 1994-07-16 |
DE3876155D1 (de) | 1993-01-07 |
EP0297685B1 (en) | 1992-11-25 |
CA1329584C (en) | 1994-05-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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