ES2021494A6 - Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2) - Google Patents

Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2)

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Publication number
ES2021494A6
ES2021494A6 ES9000543A ES9000543A ES2021494A6 ES 2021494 A6 ES2021494 A6 ES 2021494A6 ES 9000543 A ES9000543 A ES 9000543A ES 9000543 A ES9000543 A ES 9000543A ES 2021494 A6 ES2021494 A6 ES 2021494A6
Authority
ES
Spain
Prior art keywords
synthesis
vanadium
magnesium
development
unsaturated hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES9000543A
Other languages
Spanish (es)
Inventor
Ramos I Rodriguez
Ruiz A Guerrero
Fierro J L Garcia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES9000543A priority Critical patent/ES2021494A6/en
Publication of ES2021494A6 publication Critical patent/ES2021494A6/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2), in which the previously purified high surface area carbon is doped with the oxides by impregnation or adsorption with solutions of the respective salts in ethanol or water. The impregnates are dried and calcined at 420 degree C in a nitrogen flux. The cobalt is deposited on this precursor, either by impregnation with a solution of the nitrate or by adsorption of the carbonyl [CO2(CO)8] dissolved in pentane. The activation is then performed in a hydrogen flux at temperatures between 300 and 450 degree C. The catalysts are used in the Fischer-Tropsch reaction on mixtures of CO and H2 in the ratio of 1 to 2 by volume. The promoted catalysts show high activity per gram of metal, independent of the presence of the promoters.
ES9000543A 1990-02-23 1990-02-23 Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2) Expired - Fee Related ES2021494A6 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
ES9000543A ES2021494A6 (en) 1990-02-23 1990-02-23 Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9000543A ES2021494A6 (en) 1990-02-23 1990-02-23 Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2)

Publications (1)

Publication Number Publication Date
ES2021494A6 true ES2021494A6 (en) 1991-11-01

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Application Number Title Priority Date Filing Date
ES9000543A Expired - Fee Related ES2021494A6 (en) 1990-02-23 1990-02-23 Development of cobalt catalysts promoted by magnesium, vanadium or cerium oxides for the synthesis of unsaturated hydrocarbons from the synthesis gas (CO+H2)

Country Status (1)

Country Link
ES (1) ES2021494A6 (en)

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20000922