NL7708307A - Fischer-Tropsch hydrocarbon synthesis - using catalyst contg. ruthenium and iron-group metal - Google Patents
Fischer-Tropsch hydrocarbon synthesis - using catalyst contg. ruthenium and iron-group metalInfo
- Publication number
- NL7708307A NL7708307A NL7708307A NL7708307A NL7708307A NL 7708307 A NL7708307 A NL 7708307A NL 7708307 A NL7708307 A NL 7708307A NL 7708307 A NL7708307 A NL 7708307A NL 7708307 A NL7708307 A NL 7708307A
- Authority
- NL
- Netherlands
- Prior art keywords
- esp
- catalysts
- group metal
- pref
- fischer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
- C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/045—Regeneration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
Prodn. of hydrocarbons is carried out by reaction of CO with H2 on a catalyst contg. Ru and one or more Fe-group metals (esp. Fe). The catalysts have higher activity than Fe-group metal catalysts and higher stability than Ru catalysts. Selectivity is high, esp. wrt suppression of O-contg. product formation. The catalysts are pref. by impregnating a porous support (esp. Al2O3) with aq. solns. of Ru and Fe-gp. metal salts, drying, calcining in an inert gas, and then reducing in H2 at 200-400 degrees C and 1-50 bar (GHSV = 500-5000). The atomic ratio of Fe-group metal to Ru is pref. 0.5-3:1 (esp. 1.5-2.5:1). The particle size is pref. 1-5 mm for a fixed bed, 0.5-2.5 mm for an expanded bed or 20-150 mu for a catalyst suspension.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7708307A NL7708307A (en) | 1977-07-27 | 1977-07-27 | Fischer-Tropsch hydrocarbon synthesis - using catalyst contg. ruthenium and iron-group metal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7708307A NL7708307A (en) | 1977-07-27 | 1977-07-27 | Fischer-Tropsch hydrocarbon synthesis - using catalyst contg. ruthenium and iron-group metal |
Publications (1)
Publication Number | Publication Date |
---|---|
NL7708307A true NL7708307A (en) | 1979-01-30 |
Family
ID=19828936
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NL7708307A NL7708307A (en) | 1977-07-27 | 1977-07-27 | Fischer-Tropsch hydrocarbon synthesis - using catalyst contg. ruthenium and iron-group metal |
Country Status (1)
Country | Link |
---|---|
NL (1) | NL7708307A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1985004598A1 (en) * | 1984-04-05 | 1985-10-24 | The British Petroleum Company P.L.C. | Catalyst, process for its preparation and use thereof in conversion of synthesis gas to hydrocarbons |
US4613624A (en) * | 1981-10-13 | 1986-09-23 | Chevron Research Company | Conversion of synthesis gas to diesel fuel and catalyst therefor |
US4717702A (en) * | 1985-04-26 | 1988-01-05 | Shell Internationale Research Maatschappij Bv | Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst |
EP0753562A1 (en) * | 1995-07-13 | 1997-01-15 | Institut Français du Pétrole | Liquid phase conversion of synthesis gas |
EP0773274A1 (en) | 1995-11-10 | 1997-05-14 | Institut Francais Du Petrole | Process for the conversion of synthesis gas into hydrocarbons |
EP0794239A1 (en) * | 1996-03-08 | 1997-09-10 | Institut Français du Pétrole | Conversion of synthesis gas into hydrocarbons in the presence of a liquid phase |
-
1977
- 1977-07-27 NL NL7708307A patent/NL7708307A/en not_active Application Discontinuation
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4613624A (en) * | 1981-10-13 | 1986-09-23 | Chevron Research Company | Conversion of synthesis gas to diesel fuel and catalyst therefor |
EP0162554A1 (en) * | 1984-04-05 | 1985-11-27 | The British Petroleum Company p.l.c. | Catalyst, process for its preparation and use thereof in conversion of synthesis gas to hydrocarbons |
WO1985004598A1 (en) * | 1984-04-05 | 1985-10-24 | The British Petroleum Company P.L.C. | Catalyst, process for its preparation and use thereof in conversion of synthesis gas to hydrocarbons |
US4717702A (en) * | 1985-04-26 | 1988-01-05 | Shell Internationale Research Maatschappij Bv | Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst |
US5786393A (en) * | 1995-07-13 | 1998-07-28 | Institut Francais Du Petrole | Liquid phase process for converting synthesis gas |
EP0753562A1 (en) * | 1995-07-13 | 1997-01-15 | Institut Français du Pétrole | Liquid phase conversion of synthesis gas |
FR2736650A1 (en) * | 1995-07-13 | 1997-01-17 | Inst Francais Du Petrole | PROCESS FOR CONVERTING SYNTHESIS GAS TO LIQUID PHASE |
EP0773274A1 (en) | 1995-11-10 | 1997-05-14 | Institut Francais Du Petrole | Process for the conversion of synthesis gas into hydrocarbons |
US5776988A (en) * | 1995-11-10 | 1998-07-07 | Institut Francais Du Petrole | Process for converting synthesis gas into hydrocarbons |
FR2741064A1 (en) * | 1995-11-10 | 1997-05-16 | Inst Francais Du Petrole | PROCESS FOR THE CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS |
EP0794239A1 (en) * | 1996-03-08 | 1997-09-10 | Institut Français du Pétrole | Conversion of synthesis gas into hydrocarbons in the presence of a liquid phase |
FR2745820A1 (en) * | 1996-03-08 | 1997-09-12 | Inst Francais Du Petrole | CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS IN THE PRESENCE OF A LIQUID PHASE |
US5869541A (en) * | 1996-03-08 | 1999-02-09 | Institut Francais Du Petrole | Conversion of synthesis gas to hydrocarbons in the presence of a liquid phase |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
BV | The patent application has lapsed |