ES2018381A6 - Preparacion de complejos x- mercaptoacetatos de mo (vi) de formula general m moo2 (co2csr2r2)2. - Google Patents

Preparacion de complejos x- mercaptoacetatos de mo (vi) de formula general m moo2 (co2csr2r2)2.

Info

Publication number
ES2018381A6
ES2018381A6 ES8902805A ES8902805A ES2018381A6 ES 2018381 A6 ES2018381 A6 ES 2018381A6 ES 8902805 A ES8902805 A ES 8902805A ES 8902805 A ES8902805 A ES 8902805A ES 2018381 A6 ES2018381 A6 ES 2018381A6
Authority
ES
Spain
Prior art keywords
co2csr1r2
complexes
moo2
general formula
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES8902805A
Other languages
English (en)
Inventor
Avalos Antonio Cervilla
Jover Elisa Llopis
Uribes M Teresa Picher
Persiva Vicent Sanz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universitat de Valencia
Original Assignee
Universitat de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universitat de Valencia filed Critical Universitat de Valencia
Priority to ES8902805A priority Critical patent/ES2018381A6/es
Priority to PCT/ES1990/000029 priority patent/WO1991001988A1/es
Publication of ES2018381A6 publication Critical patent/ES2018381A6/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE HAN AISLADO POR PRIMERA VEZ COMPLEJOS DE MOLIBDENO DERIVADOS DEL ACIDO 2-MERCAPTOACETICO DE FORMULA GENERAL M MOOSI2(COSI2CSRSI2RSI2)SI2 DONDE M ES UN CONTRACATION Y R1 Y R2 CADENAS ALQUILICAS RAMIFICADAS O NO, O AROMATICAS QUE PUEDEN EN AMBOS CASOS POSEER OTROS GRUPOS FUNCIONALES POR TRATAMIENTO DE UNA DISOLUCION DEL LIGANDO DE UN DISOLVENTE POLAR Y LA ADICION LENTA DE UNA DISOLUCION DE UN COMPUESTO DE MOVI, MANTENIENDO EL PH CONTROLADO ENTRE 3 Y 8. ESTOS COMPLEJOS POSEEN POTENCIALES REDOX ADECUADOS PARA EFECTUAR CICLOS CATALITICOS DE INTERES Y PRESENTAN ADEMAS LA PARTICULARIDAD DE SER SOLUBLES EN DISOLVENTES POLARES TALES COMO AGUA Y METANOL. ESTAS PROPIEDADES LOS HACEN PARTICULARMENTE UTILES EN LA INDUSTRIA QUIMICA (COSI2CSRSI2RSI2)S
ES8902805A 1989-08-07 1989-08-07 Preparacion de complejos x- mercaptoacetatos de mo (vi) de formula general m moo2 (co2csr2r2)2. Expired - Lifetime ES2018381A6 (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES8902805A ES2018381A6 (es) 1989-08-07 1989-08-07 Preparacion de complejos x- mercaptoacetatos de mo (vi) de formula general m moo2 (co2csr2r2)2.
PCT/ES1990/000029 WO1991001988A1 (es) 1989-08-07 1990-08-02 PREPARACION DE COMPLEJOS α-MERCAPTOACETATOS DE Mo(VI) DE FORMULA GENERAL M[MoO2(CO2CSR1R2)2]

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES8902805A ES2018381A6 (es) 1989-08-07 1989-08-07 Preparacion de complejos x- mercaptoacetatos de mo (vi) de formula general m moo2 (co2csr2r2)2.

Publications (1)

Publication Number Publication Date
ES2018381A6 true ES2018381A6 (es) 1991-04-01

Family

ID=8263501

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8902805A Expired - Lifetime ES2018381A6 (es) 1989-08-07 1989-08-07 Preparacion de complejos x- mercaptoacetatos de mo (vi) de formula general m moo2 (co2csr2r2)2.

Country Status (2)

Country Link
ES (1) ES2018381A6 (es)
WO (1) WO1991001988A1 (es)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE738264A (es) * 1968-09-05 1970-02-16

Also Published As

Publication number Publication date
WO1991001988A1 (es) 1991-02-21

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Effective date: 20141120