EP4633768A2 - Vorrichtung zur wärmeabfuhr oder wärmeverteilung für einen gasgenerator und verfahren zur herstellung eines solchen gasgenerators - Google Patents

Vorrichtung zur wärmeabfuhr oder wärmeverteilung für einen gasgenerator und verfahren zur herstellung eines solchen gasgenerators

Info

Publication number
EP4633768A2
EP4633768A2 EP23821744.2A EP23821744A EP4633768A2 EP 4633768 A2 EP4633768 A2 EP 4633768A2 EP 23821744 A EP23821744 A EP 23821744A EP 4633768 A2 EP4633768 A2 EP 4633768A2
Authority
EP
European Patent Office
Prior art keywords
heat
vessel
discharging
gas generator
distributing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23821744.2A
Other languages
English (en)
French (fr)
Inventor
Tom COREMANS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlas Copco Airpower NV
Original Assignee
Atlas Copco Airpower NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlas Copco Airpower NV filed Critical Atlas Copco Airpower NV
Publication of EP4633768A2 publication Critical patent/EP4633768A2/de
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407Constructional details of adsorbing systems
    • B01D53/0438Cooling or heating systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • B01D53/053Pressure swing adsorption with storage or buffer vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00Apparatus for generating gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/12Oxygen

Definitions

  • the present invention relates to an apparatus for discharging or distributing heat for a gas generator.
  • adsorption apparatuses are based on the principle of adsorption, with a gas mixture, for example air, being purified by contacting it with an adsorption agent, for example zeolite.
  • a gas mixture for example air
  • an adsorption agent for example zeolite
  • temperature swing adsorption based on the periodical variation of the temperature of the adsorption agent and the pressure swing adsorption based on the periodical variation of the pressure of the gas mixture to be treated when it contacts the adsorption agent, are already known.
  • the invention is specially intended for an apparatus based on the principle of pressure exchange adsorption.
  • Such apparatuses are typically provided with pressure vessels in which an adsorption agent is provided.
  • an adsorption agent is provided.
  • the gas mixture is led through the pressure vessel and the adsorption agent under pressure, one of the components of the gas mixture will be adsorbed by the adsorption agent and purified gas will leave the apparatus.
  • the pressure in the pressure vessel is reduced, so that the adsorbed component of the gas mixture is released and may be discharged from the adsorption agent.
  • This process is what is called desorption in the following.
  • such known apparatuses contain multiple pressure vessels, for example two, which adsorb and desorb alternately.
  • This invention aims at solving at least one of the aforementioned and other disadvantages.
  • the present invention has as its object an apparatus for discharging or distributing heat for a gas generator, the apparatus for discharging or distributing heat comprising:
  • the adsorption agent of the gas generator is provided, for example zeolite.
  • the heat transporting medium is intended to mean, for example water, air, ammonia, cooling agent or the like, but also for example metal or a phase changing material.
  • the means for heat conduction comprise, for example, tubes, pipes, conduits, cooling fins and the like or a heat pipe.
  • the heat transporting medium will contain a phase changing material.
  • An advantage is that the apparatus will make it possible to discharge or redistribute the heat reprocessed during the adsorption phase of the vessel by having the heat transporting medium flow through or along the means for heat conduction.
  • the apparatus may be used for both steel vessels and for (extruded) aluminum vessels.
  • the said at least one vessel comprises one or more external tubes provided on the said outer surface.
  • the said at least one vessel comprises one or more hollow structures integrated on or in the outer surface of the said vessel.
  • the means for heat conduction may be provided or they may be the means for heat conduction themselves.
  • a heat pipe will be provided in the external tubes or hollow structures, while, in the latter case, the heat transporting medium will flow through the external tubes or hollow structures.
  • the said one or more means for heat conduction are mounted on the said inner surface of the said vessel.
  • the invention also relates to a method for manufacturing a gas generator according to the invention using an extrusion process, where the method either:
  • A. comprises the following steps:
  • Figure 1 schematically shows a gas generator
  • figures 2-5 schematically show an apparatus for discharging or distributing heat according to the invention for a gas generator.
  • the gas generator 1 schematically shown in figure 1 substantially comprises two vessels 2, each with a gas entry 3 and a gas exit 4, filled with an adsorption agent 5.
  • the said vessels 2 are provided with a removable element 7 at both ends 6.
  • These elements 7 may be considered a type of bottom and lid of the vessels 2, the said gas entry 3 being provided in one element 7 and the said gas exit 4 being provided in another element.
  • the adsorption agent is, for example, silica gel, but this might also be zeolite or the like.
  • zeolite is always used.
  • the gas generator 1 is provided with an inlet 8 for gas to be purified and an outlet 9 for purified gas.
  • each vessel 2 is, with its gas entry 3 or gas exit 4, respectively, connected to the said inlet 8 or the said outlet 9, respectively.
  • the valve system 10 will allow leading the gas to be purified to one of the two vessels 2 for adsorption, and also to split away a portion of the purified gas to lead it to the other vessel 2 for regeneration of saturated adsorption agent.
  • the specific embodiment of the gas generator 1 is not limiting for the invention, and that the number of vessels 2 with adsorption agent 5, the embodiment of the valve system 10, the adsorption agent 5 itself and the like may be designed in many different ways.
  • the gas generator 1 according to the invention is also provided with an apparatus 11 for discharging or distributing heat according to the invention.
  • Figures 2-4 show different embodiments of this apparatus 11 .
  • the apparatus 11 for discharging or distributing heat comprises at least one vessel 2 provided with an outer surface 12 and an inner surface 13.
  • the vessels 2 of the gas generator 1 constitute the vessels 2 of the apparatus 1. So, in this case, there are two vessels 2 of the apparatus 11.
  • the apparatus 11 is further provided with a number of means for heat conduction 14 configured to be provided to the said vessel 2.
  • the said at least one vessel 2 comprises one or more external tubes 15 provided on the said outer surface 12.
  • Figure 2 shows one of the two vessels 2 of the apparatus 11 , the second vessel 2 being designed identically.
  • These external tubes 15 serve as the said means for heat conduction 14. However, it is also possible that, in the external tubes 15, the means for heat conduction 14 are provided; this will be elucidated hereinbelow. In the example shown, these external tubes 15 extend according to a longitudinal direction X-X’ of the vessel 2.
  • the external tubes 15 are uniformly distributed along the circumference of the vessel 2.
  • the external tubes 15 are individually equidistantly placed along the circumference. Also, the number of external tubes 15 is not limiting for the invention.
  • the means for heat conduction 14 are configured to allow continuous heat discharge during the operating of the gas generator 1 to be able to extract heat from the said vessel 2. This is, among others, made possible by the fact that the means for heat conduction 14 are provided to the vessel 2.
  • the at least one vessel 2 of the apparatus, or more in particular the means for heat conduction 14, are adapted to contain a heat transporting medium, which heat transporting medium is configured to allow heat discharge during an adsorption phase.
  • the heat transporting medium is also intended to mean a medium such as water, air, ammonia, cooling agent or another phase changing material.
  • the heat transporting medium and the one or more means for heat conduction 14 cooperate to make discharging heat from the gas generator 1 or distributing heat in the gas generator 1 possible.
  • the means for heat conduction 14 may then comprise tubes, pipes, conduits, or the like, but also a heat pipe which is slid into the external tubes 15. This is particularly used in an embodiment as shown in Figure 3, as will be elucidated hereinbelow.
  • the heat exchanging medium is then located in these said tubes, pipes, or conduits or, as known, in the heat pipe.
  • the means for heat conduction 14, i.e. the external tubes 15, are provided on the outer surface 12 of the vessel 2.
  • Figure 3 shows a variant of the said at least one vessel 2 comprising one or more hollow structures 16 integrated on or in the outer surface 12 of the said vessel 2.
  • the hollow structures 16 and the vessel 2 are one integrated whole.
  • the said means for heat conduction 14 are placed inside the one or more hollow structures 16.
  • the means for heat conduction 14 may then comprise tubes, pipes, conduits, or the like, but also a heat pipe which may be slid into the hollow structures 16.
  • hollow structures 16 serve as the means for heat conduction 14 themselves.
  • the hollow structures 16 also extend according to a longitudinal direction X-X’ of the vessel 2. Moreover, the hollow structures 16 are uniformly distributed along the circumference of the vessel 2, just like in the embodiment of figure 2.
  • the apparatus 11 for discharging or distributing heat is therefore designed as one integrated structure.
  • the said vessel 2 and the one or more means for heat conduction 14, i.e. the hollow structures 16 are formed as one single structure by means of an extrusion process.
  • the means for heat conduction 14 are provided on the outer surface 12 of the vessel 2.
  • the said one or more means for heat conduction 14 in this case being located inside the vessel 2, amid the adsorption agent 5.
  • tubes 17, pipes or conduits are provided, extending according to the longitudinal direction X-X’ of the vessel 2. They are uniformly distributed over the circumference of the inner surface 13. Just like in the above-described embodiments, in these tubes 17, pipes or conduits, a heat transporting medium will flow.
  • Figure 5 shows yet another embodiment of an apparatus 11 for discharging or distributing heat.
  • the means for heat conduction 14 are designed as one or more cooling fins 16 provided on the outer surface 12 of the vessel 2.
  • the heat conducting medium will be air or another cooling gas.
  • the operation of the gas generator 1 and in particular of the apparatus 11 for discharging or distributing heat is very simple and is as follows.
  • the gas generator 1 will purify the gas to be purified in the known way by adsorption.
  • One of the vessels 2 will adsorb, while the other vessel 2 will desorb gas.
  • This heat is led away from the respective vessel 2 by the apparatus 11 for discharging or distributing heat.
  • the heat transporting medium will be sent through the means for heat conduction 14.
  • the heat transporting medium will discharge or distribute the heat generated by the adsorption process and discharge the heat produced at the top of the vessel 2 to the bottom of the vessel 2.
  • cooling air or cooling gas will be sent along the cooling fins 18.
  • the heat transporting medium By sending the heat transporting medium through or along the means for heat conduction 14 in a direction going from the high to the low temperature of the vessel 2, it will be possible to redistribute the heat in the vessel 2 without it being necessary to effectively discharge the heat. This is because, when going through multiple cycles, a temperature gradient will be created in the vessel 2, which adversely affects the performance. By redistributing the heat, the temperature gradient may be smoothed.
  • the adsorption agent 5 in the vessel 2 When the adsorption agent 5 in the vessel 2 is completely saturated, the other vessel 2 will adsorb, while the first vessel 2 will undergo a desorption.
  • the vessel 2 with adsorption agent 5 is first completely finished, before mounting the means for heat discharge 14.
  • the bottom lid and the top lid are the said elements 7.
  • the following method is used:
  • Filling the hollow structures 16 may be done with either the heat transporting medium itself or with, for example, a heat pipe with phase changing material.
  • the present invention is by no means limited to the embodiments described as examples and shown in the figures, but an apparatus for discharging or distributing heat for a gas generator and method for manufacturing such a gas generator according to the invention may be realized according to various variants without going beyond the scope of the invention.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Sorption Type Refrigeration Machines (AREA)
EP23821744.2A 2022-12-14 2023-12-06 Vorrichtung zur wärmeabfuhr oder wärmeverteilung für einen gasgenerator und verfahren zur herstellung eines solchen gasgenerators Pending EP4633768A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE20226014A BE1031133B1 (nl) 2022-12-14 2022-12-14 Inrichting voor het afvoeren of verdelen van warmte voor een gasgenerator en werkwijze voor het vervaardigen van dergelijke gasgenerator
PCT/IB2023/062299 WO2024127165A2 (en) 2022-12-14 2023-12-06 Apparatus for discharging or distributing heat for a gas generator and method for manufacturing such a gas generator

Publications (1)

Publication Number Publication Date
EP4633768A2 true EP4633768A2 (de) 2025-10-22

Family

ID=84785362

Family Applications (1)

Application Number Title Priority Date Filing Date
EP23821744.2A Pending EP4633768A2 (de) 2022-12-14 2023-12-06 Vorrichtung zur wärmeabfuhr oder wärmeverteilung für einen gasgenerator und verfahren zur herstellung eines solchen gasgenerators

Country Status (5)

Country Link
EP (1) EP4633768A2 (de)
CN (2) CN118179202A (de)
BE (1) BE1031133B1 (de)
TW (1) TWI891161B (de)
WO (1) WO2024127165A2 (de)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5520731B2 (de) * 1973-02-15 1980-06-04
GB0227222D0 (en) * 2002-11-21 2002-12-24 Air Prod & Chem Apparatus for use in regenerating adsorbent
TWM249431U (en) * 2003-09-23 2004-11-01 Jiung-Jung Wang Heat sink fin
CN110526212B (zh) * 2019-10-12 2021-05-11 安泰环境工程技术有限公司 一种带有鱼骨结构的氢气净化装置

Also Published As

Publication number Publication date
WO2024127165A2 (en) 2024-06-20
TW202440211A (zh) 2024-10-16
TWI891161B (zh) 2025-07-21
CN118179202A (zh) 2024-06-14
CN222034167U (zh) 2024-11-22
BE1031133B1 (nl) 2024-07-15
BE1031133A1 (nl) 2024-07-08
WO2024127165A3 (en) 2024-07-18

Similar Documents

Publication Publication Date Title
CN102893115B (zh) 用于压缩和干燥气体的设备
US5802870A (en) Sorption cooling process and system
JP5534865B2 (ja) 圧力スイング吸着法によるガス分離方法及びガス分離装置
JP2012531299A (ja) ガス除去のための方法および装置
US11305244B2 (en) Gas-liquid contact apparatus
JP2011152526A (ja) 熱媒体送給用の流路を備えた吸着塔と該吸着塔の利用方法
US20210339165A1 (en) Rotary solid/fluid counter-current contacting apparatus
EP3067114A1 (de) Gas-flüssigkeits-schütz und vorrichtung zur co2-gewinnung
CN1666077A (zh) 多用途热交换单元
EP4633768A2 (de) Vorrichtung zur wärmeabfuhr oder wärmeverteilung für einen gasgenerator und verfahren zur herstellung eines solchen gasgenerators
CN215742696U (zh) 用于味精生产的压缩空气除油除水系统
WO2013027821A1 (ja) 除湿装置、及び、除湿装置の製造方法
US4059421A (en) Cross-flow type stripping-absorption apparatus
JP3669003B2 (ja) 吸着器
US4578961A (en) Absorption apparatus for use with absorption heat pumps
CN117531329A (zh) 具有吸附剂冷却功能的烟气净化装置
CN109157980B (zh) 一种空气发生器
RU2200283C1 (ru) Адсорбер
JP2014226617A (ja) ガス精製装置とガス精製方法
SU1593690A1 (ru) Адсорбер
JPH10160287A (ja) コンデンサユニット
WO2025004726A1 (ja) ガス精製方法及びガス精製装置
KR100665895B1 (ko) 가이드 베인을 장착한 고효율 냉동식 드라이어의 a-a열교환기
JPS61110878A (ja) 熱交換器
JP2006329560A (ja) 吸着式冷凍機及びその製造方法

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20250708

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC ME MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
RAV Requested validation state of the european patent: fee paid

Extension state: MA

Effective date: 20250708