EP4561262A1 - Heat generating device - Google Patents

Heat generating device Download PDF

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Publication number
EP4561262A1
EP4561262A1 EP23894270.0A EP23894270A EP4561262A1 EP 4561262 A1 EP4561262 A1 EP 4561262A1 EP 23894270 A EP23894270 A EP 23894270A EP 4561262 A1 EP4561262 A1 EP 4561262A1
Authority
EP
European Patent Office
Prior art keywords
slit
electrode
honeycomb structure
heat generating
generating device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23894270.0A
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German (de)
English (en)
French (fr)
Inventor
Masato Yamashita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
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NGK Insulators Ltd
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Filing date
Publication date
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Publication of EP4561262A1 publication Critical patent/EP4561262A1/en
Pending legal-status Critical Current

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    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/141—Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/20—Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater
    • H05B3/22—Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater non-flexible
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/40—Heating elements having the shape of rods or tubes
    • H05B3/42—Heating elements having the shape of rods or tubes non-flexible
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F01N3/027—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using electric or magnetic heating means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/002—Heaters using a particular layout for the resistive material or resistive elements
    • H05B2203/003—Heaters using a particular layout for the resistive material or resistive elements using serpentine layout

Definitions

  • the present invention relates to a heat generating device.
  • a honeycomb structure having a plurality of cells allows a fluid to flow through an interior of the cells.
  • filters for use in various industrial products for example, filters for exhaust gas purification and filters for acid gas adsorption
  • it may be required to heat the honeycomb structure for example, in order to activate a catalyst or to desorb acid gases.
  • a ceramic heat generating element including: a honeycomb structure made of silicon nitride, a conductive substance, oxide, or oxynitride; and electrodes respectively provided on both end surfaces of the honeycomb structure in an extending direction of cells (see Patent Literature 1).
  • the electrodes provided on the end surfaces of the honeycomb structure may become an obstacle that restricts application to various industrial products.
  • the present invention has a main object to provide a heat generating device in which a first electrode and a second electrode can be provided on a profile surface of a honeycomb structure and in which a honeycomb structure can be configured as a heat generating element.
  • the first electrode and the second electrode can be provided on the profile surface of the honeycomb structure and in which the honeycomb structure can be configured as a heat generating element.
  • FIG. 1 is a schematic plan view of a heat generating device according to one embodiment of the present invention.
  • FIG. 2 is a sectional view of the heat generating device taken along the line II-II' of FIG. 1 .
  • a heat generating device 100 in the illustrated example includes a honeycomb structure 1, a first electrode 2, and a second electrode 3.
  • the honeycomb structure 1 includes an outer wall 10 and partition walls 12.
  • the partition walls 12 are arranged inside the outer wall 10, and define a plurality of cells 13.
  • Each of the plurality of cells 13 extends from a first end surface E1 to a second end surface E2 of the honeycomb structure 1 (see FIG. 2 ).
  • the cells 13 allow a fluid according to the use of the heat generating device to flow therethrough.
  • a profile surface 11 of the honeycomb structure 1 is located between the first end surface E1 and the second end surface E2 , and extends in parallel to an extending direction of the cells 13.
  • the profile surface 11 of the honeycomb structure 1 is an external surface of the outer wall 10.
  • the profile surface 11 of the honeycomb structure 1 means an entire surface that is located between the first end surface E1 and the second end surface E2 and extends in parallel to the cells 13.
  • the first electrode 2 is provided on the profile surface 11 of the honeycomb structure 1.
  • the second electrode 3 is provided on the profile surface 11 of the honeycomb structure 1, and is located away from the first electrode 2.
  • the profile surface 11 of the honeycomb structure 1 includes: a first portion P1 located between the first electrode 2 and the second electrode 3 ; and a second portion P2 located on a side opposite to the first portion P1 with respect to a center of a cross section of the honeycomb structure 1 taken along a direction orthogonal to the extending direction of the cells 13.
  • the first portion P1 and the second portion P2 are in a 180-degree rotationally symmetric relationship with respect to a center axis of the honeycomb structure 1.
  • the honeycomb structure 1 has a first slit 17.
  • the first slit 17 extends from the first portion P1 toward the second portion P2 of the profile surface 11.
  • the first slit 17 functions as an electrical insulating portion.
  • the first slit extends from the first portion located between the first electrode and the second electrode on the profile surface of the honeycomb structure, and hence even when the first electrode and the second electrode are provided on the profile surface of the honeycomb structure, a short circuit between the first electrode and the second electrode can be prevented.
  • application of voltage to the honeycomb structure through the first electrode and the second electrode can cause the honeycomb structure to generate heat stably. That is, the first electrode and the second electrode can be provided on the profile surface of the honeycomb structure, and the honeycomb structure can be configured as a heat generating element.
  • the heat generating device according to one embodiment of the present invention may be also applied to industrial products to which it is difficult to apply a heat generating device in which the electrodes are provided on the end surfaces of the honeycomb structure. Accordingly, applicability to various industrial products can be improved.
  • the honeycomb structure 1 in the cross section taken along the direction orthogonal to the extending direction of the cells 13 any suitable shape may be adopted.
  • the sectional shape of the honeycomb structure may be triangular, quadrangular, pentagonal, hexagonal or a polygonal shape having more than six sides, circular, or oval.
  • a size of the honeycomb structure may be set appropriately in accordance with the purpose.
  • the honeycomb structure 1 is substantially quadrangular in the cross section taken along the direction orthogonal to the extending direction of the cells 13.
  • the honeycomb structure 1 has a rectangular column shape having a quadrangular bottom surface.
  • the honeycomb structure 1 includes: a first profile surface 11a and a second profile surface 11b that are arranged apart from each other in a first direction orthogonal to the extending direction of the cells 13; and a third profile surface 11c and a fourth profile surface 11d that are arranged apart from each other in a second direction orthogonal to the extending direction of the cells 13 and to the first direction.
  • the profile surface 11 of the honeycomb structure 1 includes the first profile surface 11a, the second profile surface 11b, the third profile surface 11c , and the fourth profile surface 11d.
  • the first electrode 2 and the second electrode 3 are provided on the first profile surface 11a of the honeycomb structure 1.
  • the first profile surface 11a includes the first portion P1 located between the first electrode 2 and the second electrode 3 in the second direction.
  • the second profile surface 11b on a side opposite to the first profile surface 11a includes the second portion P2.
  • the first slit 17 extends from the first portion P1 of the first profile surface 11a toward the second portion P2 of the second profile surface 11b.
  • the first slit 17 extends in the first direction.
  • a proximal end of the first slit 17 is located in the first portion P1 on the first profile surface 11a of the honeycomb structure 1, and a distal end of the first slit 17 is located between the first portion P1 and the second portion P2 without reaching the second portion P2. That is, the distal end of the first slit 17 is located away from the second portion P2 on the second profile surface 11b.
  • any suitable value may be adopted in accordance with the size of the honeycomb structure.
  • the length of the first slit 17 is, for example, 1 times or more, preferably 5 times or more, and for example, 25 times or less, preferably 15 times or less, a distance between the distal end of the first slit and the second portion.
  • a length of a conductor 19, which electrically connects the first electrode and the second electrode to each other can be sufficiently secured.
  • the number of the first slit 17 is not particularly limited.
  • the number of the first slit 17 is, for example, 1 or more, preferably 2 or more, more preferably 3 or more, for example, 20 or less.
  • an interval between slits becomes too narrow, with the result that strength is impaired in some cases.
  • a plurality of first slits 17 are formed. Typically, the plurality of first slits 17 are arranged apart from each other in a direction orthogonal to an extending direction of the first slits. In the illustrated example, three first slits 17 are arranged apart from each other in the second direction.
  • the honeycomb structure 1 further has a second slit 18. Similarly to the first slit 17, the second slit 18 functions as an electrical insulating portion. The second slit 18 is located between first slits 17 arranged adjacent to each other among the plurality of first slits 17. The second slit 18 extends from the second portion P2 toward the first portion P1 on the profile surface 11 of the honeycomb structure 1.
  • the honeycomb structure 1 is configured by the first slit 17 and the second slit 18 as the conductor 19 that electrically connects the first electrode 2 and the second electrode 3 to each other.
  • the conductor 19 is formed into a zigzag shape when viewed from an axial direction of the honeycomb structure 1. Accordingly, voltage can be applied uniformly to the entire honeycomb structure through the first electrode and the second electrode, thereby being capable of causing the entire honeycomb structure to generate heat uniformly.
  • one second slit 18 is arranged between each pair of the first slits 17 arranged adjacent to each other.
  • the second slit 18 extends from the second portion P2 of the second profile surface 11b toward the first portion P1 of the first profile surface 11a in the first direction.
  • a proximal end of the second slit 18 is located in the second portion P2 on the second profile surface 11b of the honeycomb structure 1, and a distal end of the second slit 18 is located between the second portion P2 and the first portion P1 without reaching the first portion P1. That is, the distal end of the second slit 18 is located away from the first portion P1 on the first profile surface 11a.
  • any suitable value may be adopted in accordance with the size of the honeycomb structure.
  • the length of the second slit 18 is, for example, 1 times or more, preferably 5 times or more and, for example, 25 times or less, preferably 15 times or less, a distance between the distal end of the second slit and the first portion.
  • the conductor that electrically connects the first electrode and the second electrode to each other can be stably formed into a zigzag shape.
  • the number of the second slit 18 is, for example, 1 or more, preferably the number obtained by subtracting 1 from the number of the first slits.
  • the sum of the number of the first slits 17 located between the first electrode 2 and the second electrode 3 and the number of the second slits 18 located between the first electrode 2 and the second electrode 3 is preferably an odd number. In the illustrated example, the sum of the number of the first slits 17 located between the first electrode 2 and the second electrode 3 and the number of the second slits 18 located between the first electrode 2 and the second electrode 3 is 5.
  • the conductor that electrically connects the first electrode and the second electrode to each other can be stably formed into a zigzag shape.
  • each of the first slit 17 and the second slit 18 may be adopted as long as each of the first slit 17 and the second slit 18 functions as an electrical insulating portion.
  • Each of the first slit 17 and the second slit 18 has any suitable shape in the cross section taken along the direction orthogonal to the axial direction of the honeycomb structure 1.
  • the sectional shape of each of the first slit 17 and the second slit 18 may be a substantially rectangular shape (see FIG. 1 ) or a substantially wedge shape (see FIG. 3 ).
  • a width of the slit is substantially constant throughout the slit.
  • the dimension in a width direction of the slit (first slit or second slit) having a substantially rectangular shape any suitable value may be adopted in accordance with the voltage to be applied to the first electrode and the second electrode.
  • the width of the slit (first slit or second slit) having a substantially rectangular shape is, for example, 0.05 cm or more, preferably 0.1 cm or more.
  • the width of the slit having a substantially rectangular shape is equal to or larger than the above-mentioned lower limit, it is possible to stably prevent a short circuit of the conductor that electrically connects the first electrode and the second electrode to each other.
  • the width of the slit having a substantially rectangular shape is 1.0 cm or less.
  • the slit width exceeds the above-mentioned upper limit, a region to be filled with a filler increases, and a pressure loss increases in some cases. Further, when the slit width is below the above-mentioned lower limit, a sufficient insulation distance is not obtained in some cases.
  • the first slit 17 becomes narrower as the first slit 17 extends away from the first portion P1 .
  • a range of a width of the proximal end of the first slit 17 is the same as a range of the width of the above-mentioned slit having a rectangular shape.
  • the width of the proximal end of the first slit is equal to or larger than the above-mentioned lower limit, and hence it is possible to stably prevent a short circuit between portions with a relatively large potential difference. Further, the width of the first slit located between portions in which the potential difference is relatively small in the conductor can be set to be smaller than that of the proximal end of the first slit.
  • an area occupied by the first slit in the cross section of the honeycomb structure can be reduced as compared to the case in which the sectional shape of the first slit is a substantially rectangular shape, and in turn, the area occupied by the plurality of cells can be increased.
  • a taper angle of the distal end of the first slit 17 having a substantially wedge shape is, for example, 0.5° or more, preferably 1.0° or more, and for example, 12.0° or less, preferably 3.0° or less.
  • the slit width becomes too small, which results in an insufficient insulation distance in some cases.
  • the taper angle exceeds the above-mentioned upper limit, the slit width at a base of the slit becomes larger, which results in a larger pressure loss and a smaller surface area in some cases.
  • the second slit 18 becomes narrower as the second slit 18 extends away from the second portion P2.
  • a range of a width of the proximal end of the second slit 18 is the same as the range of the width of the above-mentioned slit having a rectangular shape.
  • the width of the second slit may be appropriately adjusted in accordance with a magnitude of a potential difference in the conductor. In the conductor that electrically connects the first electrode and the second electrode to each other, a potential difference between turning portions located between the distal end of the first slit and the second portion is liable to be relatively large.
  • the width of the proximal end of the second slit is equal to or larger than the above-mentioned lower limit, and hence it is possible to stably prevent a short circuit between portions with a relatively large potential difference.
  • the width of the second slit located between portions in which the potential difference is relatively small in the conductor can be set to be smaller than that of the proximal end of the second slit. Accordingly, an area occupied by the second slit in the cross section of the honeycomb structure can be reduced as compared to the case in which the sectional shape of the second slit is a substantially rectangular shape, and in turn, the area occupied by the plurality of cells can be increased.
  • a range of a taper angle of the distal end of the second slit 18 having a substantially wedge shape is the same as the range of the taper angle of the distal end of the first slit 17 described above.
  • the first slit 17 and the second slit 18 have substantially wedge shapes that are opposed to and congruent with each other in the cross section taken along the direction orthogonal to the axial direction of the honeycomb structure 1.
  • the end surface of the first slit and the end surface of the second slit that are located adjacent to each other can be arranged substantially in parallel to each other, and hence the width of the conductor formed between the slits can be made constant. Accordingly, when voltage is applied to the honeycomb structure through the first electrode and the second electrode, the honeycomb structure can be caused to generate heat more uniformly.
  • the slit (first slit or second slit) having a substantially wedge shape may be formed by linearly cutting out the partition walls 12 so that the slit becomes narrower toward the distal end (see FIG. 4 ), or may be formed by removing the partition walls 12 in a stepped manner (see FIG. 5 ).
  • the sectional shape of any one of the first slit 17 and the second slit 18 can be a substantially rectangular shape, and the sectional shape of the other of the first slit 17 and the second slit 18 can be a substantially wedge shape.
  • the first slit 17 is formed throughout the honeycomb structure 1 in the extending direction of the cells 13 (that is, from the first end surface E1 to the second end surface E2 ). Further, although not shown, typically, the second slit 18 is also formed throughout the honeycomb structure 1 in the extending direction of the cells 13.
  • an interior of each of the first slit 17 and the second slit 18 is hollow.
  • the air is present inside each of the first slit and the second slit. Accordingly, the first slit and the second slit can function stably as electrical insulating portions.
  • an interior of each of the first slit 17 and the second slit 18 may be filled with the filler 5.
  • the strength of the honeycomb structure can be improved.
  • the fluid can be prevented from flowing into the slits when the fluid according to the use of the heat generating device is caused to flow through the cells. Accordingly, the fluid can be caused to stably flow through the cells.
  • the interior of the first slit may be hollow, and the interior of the second slit may be filled with the filler.
  • the interior of the second slit may be hollow, and the interior of the first slit may be filled with the filler.
  • the filler 5 may be filled throughout the first slit 17 and/or the second slit, or may be filled only in a part of the first slit 17 and/or the second slit.
  • the filler when the filler is filled in an end portion of the first end surface side (inflow end surface side) in the slit (first slit or second slit), the fluid can be prevented from flowing into the slit.
  • the strength of the honeycomb structure can be sufficiently improved, and the inflow of the fluid into the slit can be more stably prevented.
  • a volume resistance value of the filler at 25°C is, for example, more than 1.0 ⁇ 10 11 ⁇ cm, preferably 1.0 ⁇ 10 13 ⁇ cm or more.
  • a typical example of the filler is an insulating ceramic material. Examples of the insulating ceramic material include aluminum nitride, aluminum oxide, silicon nitride, zirconia silicon carbide, cordierite, and mullite. The fillers may be used alone or in combination thereof.
  • the honeycomb structure 1 illustrated in FIG. 1 to FIG. 6 has a plurality of second slits 18. As described above, the number of the second slits 18 is not limited thereto. As illustrated in FIG. 7 , there may be only one second slit 18. Further, as illustrated in FIG. 8 , the honeycomb structure 1 may have only the first slit 17 without the second slit 18.
  • the heat generating device illustrated in FIG. 1 to FIG. 8 includes one first electrode and one second electrode.
  • the number of electrodes is not limited thereto.
  • the heat generating device 100 may include a plurality of first electrodes and/or second electrodes.
  • the profile surface 11 of the honeycomb structure 1 includes a plurality of first portions P1 and a plurality of second portions P2.
  • one first electrode 2 and two second electrodes 3 are provided on the first profile surface 11a of the honeycomb structure 1, and the first electrode 2 is arranged between the two second electrodes 3.
  • the sum of the number of the first slits 17 located between the first electrode 2 and each second electrode 3 and the number of the second slit 18 located between the first electrode 2 and each second electrode 3 is an odd number, specifically 3.
  • the first electrode and the second electrode are arranged on the same profile surface among the four profile surfaces of the honeycomb structure having a rectangular column shape.
  • the arrangement of the first electrode and the second electrode is not limited thereto.
  • the first electrode 2 and the second electrode 3 may be respectively arranged on different profile surfaces among the four profile surfaces of the honeycomb structure having a rectangular column shape.
  • the first electrode 2 is arranged on the first profile surface 11a of the honeycomb structure 1
  • the second electrode 3 is arranged on the third profile surface 11c of the honeycomb structure 1.
  • the honeycomb structure 1 has a substantially quadrangular shape in the cross section taken along the direction orthogonal to the extending direction of the cells 13.
  • the sectional shape of the honeycomb structure is not limited thereto.
  • the honeycomb structure 1 has a substantially circular shape in the cross section taken along the direction orthogonal to the extending direction of the cells 13.
  • the honeycomb structure has a circular column shape having a circular bottom surface.
  • the first electrode 2 and the second electrode 3 are arranged on an outer peripheral surface 11e as the profile surface of the honeycomb structure 1.
  • the outer peripheral surface 11e of the honeycomb structure 1 includes: the first portion P1 that is located between the first electrode 2 and the second electrode 3 in a circumferential direction of the honeycomb structure 1; and the second portion P2 that is located on a side opposite to the first portion P1 with respect to a center axis of the honeycomb structure 1.
  • honeycomb structure the first electrode, and the second electrode are described below.
  • the honeycomb structure 1 is a flow-through honeycomb structure including the plurality of cells 13.
  • the cells 13 each have any suitable shape in the cross section taken along the direction orthogonal to the axial direction of the honeycomb structure 1.
  • the sectional shape of the cell may be triangular, quadrangular, pentagonal, hexagonal or a polygonal shape having more than six sides, circular, or oval.
  • the sectional shapes and sizes of the cells may all be identical or at least partially different. Among such sectional shapes of the cells, a quadrangular shape is preferred, and a square or rectangle is more preferred.
  • an interior space of the cell 13 is configured as a flow passage through which the fluid according to the use of the heat generating device 100 flows.
  • a cell density (that is, the number of the cells 13 per unit area) in the cross section taken along the direction orthogonal to a length direction of the honeycomb structure may be set appropriately in accordance with the purpose.
  • the cell density may be, for example, from 4 cells/cm 2 to 320 cells/cm 2 . When the cell density falls within such a range, the strength and an effective geometric surface area (GSA) of the honeycomb structure can be sufficiently ensured.
  • the honeycomb structure 1 is made of a conductive ceramic material. With this configuration, the honeycomb structure can be stably configured as a heat generating element.
  • a volume resistance value of the conductive ceramic material at 25°C is 10 ⁇ cm or less, preferably 1 ⁇ cm or less.
  • the conductive ceramic material include a conductive zirconia-based material, an alumina-titanium carbide-based composite material, a Si-SiC-based composite material, and a Si metal impregnated Si-SiC-based composite material. Of those, a Si-SiC-based composite material is preferred.
  • the conductive ceramic materials may be used alone or in combination thereof.
  • the honeycomb structure 1 includes the outer wall 10 and the partition walls 12.
  • the outer wall 10 and the partition walls 12 are formed integrally.
  • the conductive ceramic material for forming the outer wall 10 and the conductive ceramic material for forming the partition walls 12 are the same.
  • the outer wall 10 and the partition walls 12 may be formed separately.
  • the conductive ceramic material for forming the outer wall 10 and the conductive ceramic material for forming the partition walls 12 may be the same or different.
  • the outer wall 10 has a tubular shape in accordance with the shape of the honeycomb structure 1.
  • the outer wall 10 has a rectangular tube shape.
  • the thickness of the outer wall 10 may be, for example, from 0.5 mm to 10 mm, and may also be, for example, from 1 mm to 8 mm.
  • the partition walls 12 define the plurality of cells 13. More specifically, the partition walls 12 include first partition walls 12a and second partition walls 12b that are orthogonal to each other, and the first partition walls 12a and the second partition walls 12b define the plurality of cells 13.
  • the configuration of the partition walls is not limited to the partition walls 12 described above.
  • the partition walls may include first partition walls extending in a radial direction and second partition walls extending in a circumferential direction, and the first partition walls and the second partition walls may define the plurality of cells.
  • a functional layer may be formed on a surface of the partition wall 12.
  • a portion typically, center portion in a cross section of the cell 13 in which the functional layer is not formed is configured as a flow passage.
  • the functional layer may be formed on an entire inner surface of the partition wall 12 or on a part of the surface of the partition wall 12.
  • the thickness of the partition wall 12 may be set appropriately in accordance with the use of the honeycomb structure. Typically, the thickness of the partition wall 12 is smaller than the thickness of the outer wall 10.
  • the thickness of the partition wall 12 may be, for example, from 0.05 mm to 1.0 mm, and may also be, for example, from 0.08 mm to 0.6 mm.
  • the thickness of the partition wall is measured, for example, by cross-section observation with a scanning electron microscope (SEM). When the thickness of the partition wall falls within such ranges, the mechanical strength of the honeycomb structure can be improved, and an opening area (total area of the cells in the cross section) can be increased.
  • the partition wall 12 is basically a dense body, and a porosity in the partition wall 12 is, for example, 10% or less, preferably 5% or less.
  • the porosity may be measured, for example, by mercury porosimetry.
  • a density of the partition wall 12 is, for example, 0.4 g/cm 3 or more, preferably 0.5 g/cm 3 or more, and for example, 6 g/cm 3 or less, preferably 5 g/cm 3 or less.
  • the density may be measured, for example, by the mercury porosimetry.
  • each of the first electrode 2 and the second electrode 3 is provided directly on the profile surface 11 of the honeycomb structure 1. Any suitable metal may be adopted as a material for the electrode (first electrode or second electrode). Although not shown, each of the first electrode 2 and the second electrode 3 can be electrically connected to a power source.
  • the heat generating device according to the embodiment of the present invention can be used in various industrial products, and may be suitably used particularly as filters.

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
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EP23894270.0A 2022-11-21 2023-10-05 Heat generating device Pending EP4561262A1 (en)

Applications Claiming Priority (2)

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JP2022185921 2022-11-21
PCT/JP2023/036366 WO2024111258A1 (ja) 2022-11-21 2023-10-05 発熱装置

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EP4561262A1 true EP4561262A1 (en) 2025-05-28

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US (1) US20250098034A1 (https=)
EP (1) EP4561262A1 (https=)
JP (1) JPWO2024111258A1 (https=)
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WO (1) WO2024111258A1 (https=)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6126564A (ja) * 1984-07-13 1986-02-05 日本特殊陶業株式会社 耐熱・耐摩耗性セラミツク材料の製造法
DE8816514U1 (de) * 1988-04-25 1989-10-26 Emitec Gesellschaft für Emissionstechnologie mbH, 5204 Lohmar Elektrisch beheizbarer Katalysator-Trägerkörper
JP2931362B2 (ja) * 1990-04-12 1999-08-09 日本碍子株式会社 抵抗調節型ヒーター及び触媒コンバーター
JP3040510B2 (ja) * 1991-03-06 2000-05-15 日本碍子株式会社 ハニカムヒーター
US5254840A (en) * 1991-12-12 1993-10-19 Corning Incorporated Mounting for metal honeycomb structures
DE4213261A1 (de) * 1992-04-22 1993-10-28 Emitec Emissionstechnologie Elektrisch leitfähiger Wabenkörper, insbesondere für elektrisch beheizbare katalytische Konverter von Kraftfahrzeugen
JPH0785952A (ja) * 1993-09-16 1995-03-31 Sharp Corp ハニカムヒータ
JPH08218857A (ja) * 1995-02-15 1996-08-27 Honda Motor Co Ltd 電気加熱式触媒
JP3345222B2 (ja) * 1995-07-21 2002-11-18 日本碍子株式会社 通電発熱用ハニカム体およびハニカムユニット
JP2014054934A (ja) * 2012-09-13 2014-03-27 Ngk Insulators Ltd ヒーター
FR3111944B1 (fr) * 2020-06-30 2023-03-24 Faurecia Systemes Dechappement Dispositif de chauffage, dispositif de purification, ligne d’échappement, procédé de fabrication du dispositif de chauffage
JP2022072369A (ja) * 2020-10-29 2022-05-17 日本碍子株式会社 接合体および接合体の製造方法

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US20250098034A1 (en) 2025-03-20
CN119896031A (zh) 2025-04-25

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