EP4489967A1 - Verfahren zur herstellung eines mindestens zweischichtigen sandwichbauelements - Google Patents
Verfahren zur herstellung eines mindestens zweischichtigen sandwichbauelementsInfo
- Publication number
- EP4489967A1 EP4489967A1 EP23710825.3A EP23710825A EP4489967A1 EP 4489967 A1 EP4489967 A1 EP 4489967A1 EP 23710825 A EP23710825 A EP 23710825A EP 4489967 A1 EP4489967 A1 EP 4489967A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- glass
- insulation layer
- layer
- sandwich component
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/08—Other methods of shaping glass by foaming
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B29/00—Reheating glass products for softening or fusing their surfaces; Fire-polishing; Fusing of margins
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/007—Foam glass, e.g. obtained by incorporating a blowing agent and heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/14—Arrangements for the insulation of pipes or pipe systems
- F16L59/147—Arrangements for the insulation of pipes or pipe systems the insulation being located inwardly of the outer surface of the pipe
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M3/00—Investigating fluid-tightness of structures
- G01M3/002—Investigating fluid-tightness of structures by using thermal means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/103—Metal fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/105—Ceramic fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/04—Inorganic
- B32B2266/057—Silicon-containing material, e.g. glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
Definitions
- the invention relates to a method for producing an at least two-layer sandwich component in the form of a tube or in the form of a plate, the sandwich component being exposed to a cold side and a hot side.
- the sandwich component according to the invention can be used as a hot gas line, as an exhaust line, as a silencer or as a fire protection wall in an aircraft, for example in an airplane, a land vehicle, a water vehicle or a space vehicle.
- DE 10 2016 000 915 A1 relates to a foundation structure of a building.
- the structure includes load-bearing insulation, with the insulation being provided as foam glass gravel as a base for a strip foundation.
- the strip foundation is completely surrounded by a foam glass gravel layer, except where there are load-bearing walls or supports. This avoids thermal bridges in the parts of the floor slab facing the outer wall, which prevents mold and moisture in the outer corners of a building.
- Foam glass can contain natural glass, whereby the foam glass contains more than 5% aluminum oxide, based on the weight of the foam glass, and has a coefficient of thermal expansion Range between 4Dx 10' 6 ppm/°C and 6 x 10' 6 ppm/°C.
- a composition for producing the foam glass may include natural glass containing at least 5% aluminum oxide by weight of the composition, sodium carbonate containing less than 10% by weight of the composition, and boric acid containing at least 5% based on the weight of the composition.
- a method of making foam glass may include mixing natural glass with boron to form a mixture, grinding and melting the mixture at a temperature of at least 900 °C, and allowing the molten mixture to cool so that the foam glass contains at least 5% alumina , based on the weight of the foam glass, and at least 5% boron oxide, based on the weight of the foam glass.
- AT 521 214 B1 refers to the shaping of glass foam into semi-finished products with fiber composites.
- a fiber composite semi-finished product is proposed, having a lower and an upper cover layer with fibers, the lower cover layer being arranged parallel to the upper cover layer.
- ellipsoidal glass foam elements are arranged in at least two parallel planes, with the glass foam elements being arranged in a Cartesian grid in each plane and the grid points of two adjacent parallel planes being offset from one another in the direction of the planes in such a way that the Cartesian grid points in the one of the two adjacent levels, are arranged between the Cartesian grid points in the other of the two adjacent levels, with fibers and binding material being arranged between the ellipsoidal glass foam elements.
- the ellipsoid-shaped elements are manufactured separately as finished glass foam elements and glued to cover layers using a different material.
- the glass foam elements have ribs on their surfaces, the ribs of the glass foam elements interlocking with ribs of glass foam elements arranged in adjacent levels.
- DE 103 41 158 A1 relates to a component containing glass foam for sound dampening and sound insulation.
- the component containing glass foam for sound dampening and/or sound insulation is connected to a protective material at least on parts of the component.
- the glass foam component preferably has a first side, a second side and an edge connecting the first and second sides.
- the protective material preferably closes at least on parts of the edge and on an area near the edge of the first and second sides of the Glass foam component.
- stand walls, silencer backdrops and gas-carrying channels are disclosed, which are equipped with glass foam components for sound insulation and/or sound insulation.
- Previous concepts for insulated hot gas pipes are generally constructed in such a way that there is a gas-tight metal pipe on the hot inside, which is usually surrounded by insulating material, whereby the insulating material is generally not airtight and usually not dimensionally stable, such as insulating wool.
- insulating material is generally not airtight and usually not dimensionally stable, such as insulating wool.
- pipe half-shells made of foam glass which are applied to the outside of an airtight metal pipe as external insulation, whereby the joint between the two half-shells is glued, does not need to be airtight and does not absorb any internal pressure, as this only comes from the Inner tube is worn.
- such inner tubes for hot gas are currently often made of titanium in order to meet the weight, temperature and corrosion requirements and are therefore relatively expensive.
- such tubes are made of steel alloys, which, however, entails significant weight disadvantages in aircraft construction.
- the invention is based on the object, particularly in aviation applications, of providing a line or plate arrangement which is very economical in terms of weight and creates an airtight insulating layer, while at the same time ensuring resistance to high temperatures.
- a method for producing an at least two-layer sandwich component is proposed, which is manufactured in the form of a tube or in the form of a plate, the sandwich component having a cold side and is exposed to a hot side, and at least the following process steps are carried out: a) production of an insulation layer facing the hot side, which contains a gas-tight, high-temperature-resistant glass foam material and b) production of an outer layer of the sandwich component facing the cold side, which comprises a fiber composite material.
- the method proposed according to the invention makes it possible to produce sandwich components that can withstand high and extremely high temperatures, while at the same time, by using a fiber composite material, inexpensive materials can be used that also have an extremely low weight, which is very advantageous for aviation applications.
- the insulation layer facing the hot side can be provided with a layer which contains a fiber composite material with a ceramic, glass ceramic or glass matrix material.
- This optional additional layer on the insulation layer facing the hot side makes it possible to achieve a further increase in temperature resistance as well as an improved mechanical resistance of the surface on the hot gas side.
- the insulation layer facing the hot side according to method step a), which consists of a gas-tight, high-temperature-resistant glass foam material, is manufactured from a block material or with the aid of a preform which comprises at least one glass granulate and a foaming agent.
- the insulation layer facing the hot side is smoothed by locally generating high temperatures.
- This allows, for example, broken glass pores to be smoothed at locally high temperatures, resulting in an extremely smooth, fluidically favorable inside of the insulation layer.
- the resulting closure of the glass foam surface also prevents water from penetrating into pores and thus preventing damage in the event of frost.
- the sandwich component is held in a closed mold during the implementation of method steps a) and b), in which the glass granules are melted and then foamed under the action of the foaming agent.
- the fiber material from which the cover layer or the cover layers are formed is impregnated with the melt of the glass granules as a preform in the form of a fiber molding or a porous fiber-ceramic material in the closed mold.
- the gas-tight, high-temperature-resistant glass foam material is mixed with fiber material, in particular carbon, metal, basalt or ceramic fiber material or particularly high-temperature-resistant glass fiber material during its production, the fiber material being present both as a short fiber and as a long fiber can.
- the fiber material - present as a short or long fiber or as a continuous fiber - is introduced into or around the glass granulate before it is melted or foamed or as a wound preform for later cover layers or as a semi-finished textile product, in particular as a braided fabric cover layer on a or several surfaces, or introduced as a spacer fabric, which are soaked by the glass granules during the melting and foaming process.
- a glass material that achieves a particularly low viscosity at the process temperature for example a glass solder, is used to impregnate the fiber gaps with the glass matrix.
- this glass material with a particularly low viscosity is only used in the areas of the particularly densely packed fiber cover layers (hot and / or cold side) and in the area of the glass foam another glass material, which may also have a higher melting temperature.
- the fibers (e.g. rovings) used for depositing the cover layers are already in production of the preform, for example wound, is pre-impregnated with a glass material or a glass solder, for example in the form of a prepreg tape, which was impregnated in a previous process.
- air channels are introduced on an outside of the insulation layer, which contains the gas-tight, high-temperature-resistant glass foam material, which remain air-permeable after the outer layer has been laminated on and, in the event of a leak in the insulation layer, guide air escaping through this to discrete air outlet openings assigned to the temperature sensors.
- Preparatory measures for a leak detection system can be taken during the production of the sandwich component.
- fiber-optic temperature sensors are laminated into the outer layer made of fiber material covering the insulation layer. This also means that, in an alternative approach, precautions can be taken for a later leak detection device.
- the heat treatment is also carried out on the end faces of the sandwich component, in the event that this is manufactured as a tube, in order to obtain smooth surfaces for sealing a joint of two sandwich components proposed according to the invention to be connected to one another, designed as tubes.
- the fiber composite material with a ceramic matrix is laminated onto the insulation layer facing the hot side, and then a temperature treatment of the laminate and the insulation layer is carried out for joint curing or pyrolysis of the ceramic matrix.
- a temperature treatment of the laminate and the insulation layer is carried out for joint curing or pyrolysis of the ceramic matrix.
- a prefabricated layer of the fiber material with a ceramic, glass-ceramic or glass-like inorganic matrix can be applied to the hot side facing the hot side by means of a soldering process, for example using a glass solder (i.e. a glass with a lower melting temperature than that of the foam glass).
- a glass solder i.e. a glass with a lower melting temperature than that of the foam glass
- gas-tight, high-temperature-resistant insulation layer can be soldered on.
- this soldering process can also be carried out on both sides, i.e. H. be applied on the hot side and on the cold side, for example if both can take place at the same time in a temperature treatment process.
- a prefabricated layer of the fiber composite material with a ceramic matrix can be glued to the gas-tight, high-temperature-resistant insulation layer facing the hot side by means of an adhesive process using a high-temperature-resistant adhesive. With this procedure, the high-temperature treatment between the fiber composite material with a ceramic matrix on the one hand and the insulation layer can be saved.
- the fiber composite material is applied to the cold side as an outer layer using thermoset prepreg-based processes, resin infusion processes, RTM processes or thermoplastic prepreg-based processes, in particular TP-AFP processes.
- the invention relates to a sandwich component in the form of a tube or a plate, which is exposed to a cold side and a hot side, the sandwich component being designed in at least two layers and comprising an insulation layer facing the hot side, which comprises a gas-tight, high-temperature-resistant glass foam material and a outer layer facing the cold side, which contains a fiber composite material.
- the sandwich component proposed according to the invention has, on the one hand, a very low weight, which is extremely advantageous for aviation applications, and, on the other hand, is characterized by the fact that there is an airtight insulation layer, namely the insulation layer made of the glass foam material, which at the same time can withstand high temperatures.
- the sandwich component can be designed both in the form of a tube and in the form of a plate, for example as a panel.
- a further advantageous embodiment variant of the sandwich component proposed according to the invention provides that the insulation layer facing the hot side, which comprises a gas-tight, high-temperature-resistant glass foam material, is provided with a layer which contains a fiber composite material with a ceramic, glass ceramic or glass matrix material. This makes it possible to provide a three-layer sandwich component that goes beyond a two-layer sandwich component and is further improved in terms of its temperature resistance and mechanical strength and its tightness requirements.
- the invention relates to the use of the sandwich component in an aircraft, in particular in an airplane, as a hot gas line, bleed air or exhaust line or as an engine or APU silencer.
- Another use of the sandwich component proposed according to the invention is its use as an enclosure for units that either become hot during operation and/or can potentially become hot in the event of an error/failure or in the event of fire, in particular a solid oxide fuel cell or batteries or low-temperature energy converters or other waste heat.
- the sandwich component can be used as a fire protection barrier or the like in a land vehicle, water vehicle or even in a space vehicle.
- a sandwich component in particular manufactured according to the method proposed according to the invention, this comprises a jacket made of high-strength fiber composite material and a Insulating layer made of a gas-tight, high-temperature-resistant glass foam material.
- the invention provides functionality for a sandwich component in that, on the one hand, it comprises an airtight insulation layer, which, on the other hand, withstands high temperatures.
- the solution proposed according to the invention enables the use of foams also for high temperatures, but now with glass instead of polymer materials as the foam material.
- the solution proposed according to the invention can be used to achieve constructions with a high thermal insulation effect, which, in contrast to often used soft mineral or glass wool mats, have increased dimensional stability and can therefore be structurally connected to structural components in an easier way.
- the solution proposed according to the invention can further improve the roughness of mechanically processed surfaces of the glass foam material, since the number of open glass foam material pores on the surface, in particular on the inside of the insulation layer, is significantly reduced and thus the durability of this surface is improved. Furthermore, by smoothing the inside of the insulation layer, the flow resistance for media is reduced and at the same time the probability of detachment of surface particles of the insulation layer is reduced.
- the solution proposed according to the invention makes it possible to provide a sandwich component, which in particular represents a hot gas line, for example a bleed air or exhaust line or an engine or APU silencer in an aircraft, in particular in an airplane, the proposed sandwich component comprising an outer jacket a fiber composite material and comprises an internal insulation layer made of a gas-tight, high-temperature-resistant glass foam material, such as foam glass.
- the inside of the insulation layer can be coated with another high-temperature-resistant material, in particular a fiber composite material with ceramic, glass-ceramic or glass-like, inorganic Matrix must be covered.
- the sandwich component proposed according to the invention can be in the form of a tube or, when opened, as a flat panel, which serves, for example, as a heat or fire protection wall.
- a previously necessary additional outer shell for leak detection in bleed air lines can either be reduced to a thin film shell without further insulation or can be eliminated entirely by introducing air channels on the outer layer of the insulation layer, which lead to discrete, defined air outlet points of the pipe-shaped manufactured sandwich component, which in turn has temperature sensors on it.
- these temperature sensors can also be laminated into the sandwich component in the form of films, fibers or wires.
- the outer layer made of fiber composite material can absorb the tensile load that can arise, for example, from internal pressure in the tube and not the inner tube as in previous applications.
- the gas-tight, high-temperature-resistant foam glass material takes on, in addition to the insulation function, the task of ensuring the tightness of the tubular sandwich component, so that the outer layer made of fiber composite material does not have to take on this task.
- This can advantageously be achieved for the outer shell, i.e. H. the outer layer can be used materials that have a lower temperature resistance than would be the case for an inner shell in contact with the hot gas.
- the foam glass material used as an insulation layer has the advantage that it hardly emits gases and therefore the hot medium is not contaminated with vapors.
- fiber material in the form of carbon, metal (for example steel or nickel-based superalloy), basalt, ceramic fibers or particularly high-temperature-resistant glass fibers can be introduced during the production of the glass granules and / or the glass foam material in order to increase the strength and Damage tolerance of this material increase.
- the fiber material available as short, long or so-called continuous fibers, serves as a stiffener and crack stopper in the glass foam material.
- the fiber material can be mixed into the glass granulate before it is melted or foamed or can be inserted as a wound preform (for later cover layers) or semi-finished textile product, in particular as a braid or fabric cover layer or spacer fabric.
- a glass material can optionally be used that achieves a particularly low viscosity at the process temperature, for example a glass solder. Furthermore, this glass material with a particularly low viscosity can only be used in the areas of the fiber cover layers (hot and / or cold side) and in the area of the glass foam another glass material, which may also have a higher melting temperature.
- a leak detection device By introducing air channels on the outside of the insulation layer, preparatory work for a leak detection device can be carried out. If the further manufacturing steps ensure that the air channels remain permeable to air even after the outer layer made of fiber composite material has been laminated on, in the event of a leak in the inner layer, ie the insulation layer, they direct air escaping to discrete air outlet points located in the outer layer, in front of which temperature sensors are placed . This means that an additional, non-structural air ducting envelope can be saved.
- a leak detection device can be provided by laminating fiber optic sensors into the outer layer made of fiber composite material. If, in the event of a leak in the insulation layer and air flowing out as a result, this causes a local increase in temperature in the outer layer, the leak can be detected.
- a leak detection device Another possibility for a leak detection device is that the solid, load-bearing outer layer is covered with a simple air-conducting cover made of film material, which, in the event of a fault, directs air flowing out to certain openings with temperature sensors. Since this outer shell made of foil material does not perform any insulating function, it is significantly easier to manufacture and assemble.
- a film reserve in the form of folds or embossing can be used to ensure that in the event of air escaping, there is enough space between the outer cover and the film or is formed by the differential pressure so that this air can flow to discrete openings in the film with leak detection sensors.
- the inside of the insulation layer is designed as a smooth surface, which can be achieved by heat treatment, whereby webs of broken glass bubbles melt and the surface of the molten glass contracts to form a smooth surface.
- the volume of the glass foam material decreases locally, so that an optionally mechanically processed blank must be produced with a corresponding oversize on the sides to be treated.
- the surface heat treatment must be dosed in such a way that the target geometry results after treatment and melting.
- the desired layer thickness of the glass foam material which is no longer porous on the surface but is monolithic, can be influenced by this and by the size of the excess dimension provided.
- the heat treatment can be carried out, for example, using a laser or with a gas combustion or arc-based device, similar to welding or glassblowing work.
- the heat treatment can advantageously be carried out on the end faces of pipe ends in order to achieve a smooth surface for sealing the joint.
- a hot stamp tool or similar can also be used to carry out the heat treatment.
- Around In order to avoid harmful tensile stresses in the workpiece, it can also make sense to either heat the blank as a whole to a higher temperature level during its surface processing and/or to carry out a heat treatment following the surface processing, similar to glass tempering processes.
- the sandwich component proposed according to the invention can be used to enclose hot units, such as an APU (Auxiliary Power Unit) of an aircraft, for supply air or exhaust gases, or can be used to enclose associated silencers, which also become hot.
- hot units such as an APU (Auxiliary Power Unit) of an aircraft
- APU Advanced Power Unit
- silencers which also become hot.
- the airtightness here is rather negligible, so that the sandwich components proposed according to the invention can also be produced in parts.
- insulating wool these have a solid structure, and as a result there is a solid connection layer on both sides, which offers advantages for fastening elements inside or for connecting to the structure outside. For example, fewer structural elements have to be passed through the insulation layer, which reduces thermal bridges.
- a sandwich component proposed according to the invention with fiber ceramic on one side, an insulation layer made of glass foam material in the middle and fiber composite material as the outer layer can be used to house further hot units, such as a solid oxide fuel cell, or to increase the safety of potentially hot units, such as batteries, low-temperature fuel cells and other energy converters.
- the sandwich components proposed according to the invention can also be used as structural elements, for example serving as heat shields from the outside, for example in spacecraft for atmospheric re-entry or in supersonic aircraft.
- the fiber-ceramic cover layer is on the outside and the outer layer made of fiber composite material is on the inside of the missile.
- FIG. 1 shows a sandwich component according to the invention, designed as a tube with an insulating layer made of glass foam material and an outer layer made of fiber composite material,
- FIG. 2 shows an embodiment variant of the sandwich component according to the invention with an additional layer of a fiber composite material with a ceramic or glass-like, inorganic matrix on the inside of the insulation layer,
- Figure 3 shows a schematically indicated device for local temperature increase to smooth the inside of the insulation layer
- Figure 5 shows a cross section through a tubular sandwich component according to the invention with attachments or internals on the cold side and hot side,
- Figures 6a - 6d show a manufacturing process of a sandwich component designed in the form of a tube
- Figure 7 shows a sandwich component, designed as a tube
- Figure 8 shows a sandwich component, also designed as a tube, enclosed by an air-guiding sleeve and
- Figures 9 and 9.1 show a sandwich component, also designed as a tube, with fiber-optic sensors laminated into the outer layer.
- Figure 1 shows a sandwich component 50 designed as a tube 24 and proposed according to the invention.
- the illustration according to Figure 1 shows that the sandwich component 50 proposed according to the invention is designed in the form of a tube 24.
- the sandwich component 50 is exposed to a cold side 20 and a hot side 22.
- the cold side 20 can, for example, be the environment where ambient temperature prevails, while on the hot side 22 the flow cross section of the tube 24, for example, has hot air or another hot gas flowing through it. Higher temperatures therefore prevail in the flow cross section of the pipe 24 than on its outside, the cold side 20.
- the sandwich component 50 in the form of the tube 24 contains a surrounding insulation layer 54, which comprises a gas-tight, high-temperature-resistant glass foam material 10. Furthermore, the sandwich component 50 designed as a tube 24 according to FIG. 1 comprises an outer layer 52, which is designed as a fiber composite material. 1, a glass layer 14 is formed on the inside of the insulation layer 54 facing the hot side 22, which forms the surface of the gas-tight, high-temperature-resistant glass foam material 10, which determines the flow cross section of the tube 24, i.e. H. whose cavity is limited.
- FIG. 2 shows an alternative embodiment variant of the sandwich component 50 proposed according to the invention, which is also designed as a tube 24 according to Figure 2.
- the sandwich component 50 includes an outer layer 52 which comprises a fiber composite material 12.
- the outer layer 52 encloses said insulation layer 54, which comprises a gas-tight, high-temperature-resistant glass foam material 10.
- the sandwich component 50 designed as a tube 24 has a glass layer 14 as the surface of the insulation layer 54 on its inside, which limits the flow cross section and is exposed to the hot side 22,
- a sandwich component 50 is shown, which can be exposed to higher temperatures and/or mechanical loads.
- the hot side 22 of the sandwich component 50 can be fiber-reinforced.
- a layer of fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix is applied to the hot side 22 of the insulation layer 54, ie on the glass layer 14. This can be done, for example, by laminating directly onto the insulation layer 54, which comprises a gas-tight, high-temperature-resistant glass foam material 10.
- the laminated layer and the glass foam material 10 are then heat treated together for consolidation or curing or for pyrolysis of the fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix, if the temperature resistance of the foam glass material 10 is high enough for the process necessary for the curing.
- the glass layer 14 is omitted, and the layer of fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix is applied directly to the surface of the glass foam material 10 on the hot side 22 of the insulation layer 54.
- FIG. 3 shows a heat treatment of the glass layer 14 of the glass foam material 10 facing the hot side 22, which forms the insulation layer 54.
- a device 18 for locally generating high temperatures for surface melting of the glass foam material 10 is used.
- the device 18 can be, for example, a laser or a device based on gas combustion or arc, similar to welding and glassblowing work.
- 3 shows that the device 18 is moved in a feed direction 92 along the glass layer 14 of the glass foam material 10.
- the outer area of the glass foam material 10 which is exposed to the heat treatment, melts together, any remaining open glass pores close and, due to the surface tension, the insulation layer 54, ie the glass foam material 10, shrinks from an oversize 96 to a target size 98.
- the glass layer 14 becomes very smooth because the open glass pores are closed and, due to the surface tension, a very smooth inside of the glass foam material 10 forming the insulation layer 54 is formed , which assigns the hot side 22 of the insulation layer 54.
- the sandwich component 90 includes the insulation layer 54, which includes the gas-tight, high-temperature-resistant glass foam material 10.
- the insulation layer 54 of the sandwich component 90 is provided with the fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix, while on the cold side 20 the fiber composite material 12 is arranged as an outer layer 52, which is made of a very light and Fiber composite material 12 is thus manufactured with favorable weight properties for aircraft construction.
- the sandwich component 90 can also serve as a heat or fire protection wall.
- Figure 5 shows an embodiment variant of the sandwich component 50 proposed according to the invention, which is designed with a variable cross section.
- the sandwich component 50 shown in section in Figure 5 and also designed in the form of a tube 24 has a variable cross section.
- the hot side 22 is formed, for example, by the flow cross section of the tube 24, which is designed with a variable cross section and through which a hot air flow flows, for example.
- the sandwich component 50 in the form of the tube 24 includes the insulation layer 54, formed from the gas-tight, high-temperature-resistant glass foam material 10, furthermore the fiber composite material 12 forming the outer layer 52 and, facing the hot side 22, the fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix, ie that Sandwich component 50 is designed in three layers in this exemplary embodiment.
- FIG. 5 shows that the sandwich component 50 in this embodiment variant can be connected, for example, via attachments 30, for example made of fiber composite material, on the cold side 20 under normal environmental conditions, for example with structural elements of an aircraft, in particular an airplane. Furthermore, Figure 5 shows that on the hot side 22 of the sandwich component 50, i.e. H. Attachments 28 are also arranged in the flow cross section of the pipe 24, which consist, for example, of a fiber composite material 12 with a CMC matrix and can therefore withstand high temperatures, such as those that can occur on the hot side 22 of the sandwich component 50.
- the tube 24 of the sandwich component 50 lies one behind the other in the axial direction, has several attachment parts 28 made of a fiber composite material 16 with a ceramic matrix or glass-like, inorganic matrix protruding from the inside of the fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix into the flow cross section .
- the diameter of the sandwich component 50 designed as a tube 24 is indicated by dashed lines.
- the insulation layer 54 includes the glass foam material 10, which is made from glass granules 62 with the addition of a foaming agent.
- fiber material in short form 58 or in long form 60 is added to the glass granulate 62, the fiber material being carbon, metal (for example steel or nickel-based superalloys), basalt or Ceramic fibers or high temperature resistant glass fibers can act.
- Such a manufacturing process can be seen, for example, in the sequence of figures in FIGS. 6a to 6d.
- the inner molded part 34 can, for example, be divisible, have a demolding slope or the like, or enable demolding due to a difference in thermal expansion. In the latter case, this can be achieved, for example, by selecting a material for the material of the inner molded part 34 that has a higher thermal expansion than the material of the workpiece solidified after the shaping process, so that the inner molded part 34 contracts more strongly during the cooling process the workpiece.
- Figure 6b shows how dry reinforcing fibers assigned to the outer tube surface are wound around a preform 36, which represents a hollow component, after or independently of the previously described process.
- the hollow preform 36 comprises a mixture of glass granules 62 with foaming agent and a binding material. Furthermore, the granules 62 can contain short fibers 58 or long fibers 60 if these are needed as crack stoppers in the glass foam material 10 to be foamed.
- the fibers applied according to Figure 6b are not the same as those in Figure 6a, but are new fibers which later form an outer cover layer.
- the hollow preform made of glass granules, foaming agent and binding material is needed as a support for winding in order to hold the fibers on the circumference of the outer diameter, since a cavity is still needed in the mold for space to foam the foam glass.
- the inner fiber layer remains wound on the inner mold after the foaming process until the finished component is removed from the mold.
- the preform 36 prepared according to Figure 6b is either produced around the preform 36 prepared according to Figure 6a or the preforms 36 produced according to Figures 6a and 6b are manufactured separately and then joined together, for example by pushing them into one another.
- the combination of both preforms 36 is, as described below, in transferred to a closed mold 100, whereby the inner molded part 34 described in FIG. 6a can represent a part of this closed mold.
- Figure 6c shows that the closed mold 100 is designed to be divisible and includes a first mold half 102 and a second mold half 104.
- the inner mold 34 prepared according to Figure 6a is enclosed by the closed mold 100 or its mold halves 102 and 104 and both preforms 36 are joined together into a closed mold 100.
- a heating process takes place to approximately 800 ° C, in which it becomes a melting and foaming of the glass granules 62 occurs, so that the fiber layers of the dry reinforcing fibers 32 are saturated.
- reference number 40 denotes an expansion during the foaming process.
- the space for foaming is limited by the annular area between the dry reinforcing fibers 32 on the circumference of the inner mold 34 and on the other hand by the inside of the glass foam material 10 to be foamed.
- a blank of a sandwich component 90 made of fiber ceramic or fiber-reinforced glass, foam glass and fiber composite material 12 is obtained.
- the sandwich component 90 shown in Figure 6d therefore comprises an outer layer 52 made of fiber composite material 12, which covers the insulation layer 54 made of foamed glass foam material 10, which in turn is covered on its side facing the hot side 22 with the fiber composite material 16 with a ceramic matrix or glass-like, inorganic Matrix is covered.
- the resulting blank shown in Figure 6d is cooled and removed from the mold and has a near-net-shape foam glass sandwich structure with fiber-reinforced outside and inside.
- the reinforcing fibers 32 can also have already been completely or partially impregnated with a glass-shaped matrix in advance, so that they are in the form of flat prepreg tapes and in this form in the processes described on the inner mold 34 or the preform 36 can be wrapped.
- the glass from the glass granules has not penetrated into the fiber cover layers during the foaming process, or has not penetrated so deeply, which may have advantages with high-viscosity glasses.
- the sandwich component 50, 90 described above with reference to Figures 1 to 6d or its manufacturing process enables the use of the glass foam material 10 as an insulation layer 54 on the hot side 22 and the use of a fiber composite material 12 as an outer layer 52 on the cold side 20.
- the outer layer 52 made of fiber composite material takes over 12 the tensile load that can arise, for example, due to internal pressure in the tube 24, and not the inner tube as usual.
- the gas-tight, high-temperature-resistant glass foam material 10 takes on the task of sealing the pipe 24 in addition to the insulating function, so that this function cannot be ensured by the fiber composite material 12.
- the described sandwich component 50 which is designed as a tube 24, has the advantage that materials can be used for the outer layer 52 that have a lower temperature resistance than would be the case for an inner shell in contact with a hot gas stream on the hot side 22. Since a significantly larger selection of fiber composite materials is available, materials with better mechanical properties and/or lower prices or lower processing costs can also be used.
- the glass foam material 10 in turn has the advantage that it hardly outgases and therefore the hot medium is not contaminated with vapors.
- the sandwich component 50 proposed according to the invention can be expanded in such a way that it can be provided with a leak detection device 66.
- air channels 76 can be introduced on the outside of the insulation layer 54, which contains a gas-tight, high-temperature-resistant glass foam material 10, which can be done, for example, by milling or molding. These remain air-permeable even after the outer layer 52 has been laminated in the form of the fiber composite material 12 and, in the event of a leak in the insulation layer 54, direct air escaping there to the discrete air outlet points 68 located in a fiber composite shell 78.
- Another possibility for integrating a leak detection device 66 is to laminate fiber-optic sensors 82 into the outer structural fiber composite shell 78. Since in the event of a leak in the insulation layer 54, the hot air that then flows out causes a local temperature increase in the outer layer 52, the leak can be detected in this way , provided that the distance between the fiber optic sensors 82 is small enough so that the temperature influence area of a critical leak is not smaller than the grid of the arrangement of the temperature sensors 72.
- the solid, load-bearing outer layer 52 is covered with a simple air-guiding cover made of film 84, which directs potentially escaping hot air to certain openings with temperature sensors 72. Since this outer shell no longer has an insulating function, it is significantly easier to manufacture and easier to install.
- a film reserve 88 in the form of folds or an embossing can be used to ensure that in the event of air escaping, there is enough distance between the outer cover and the film or is formed by the differential pressure so that this air can flow to discrete openings in the film with leak detection sensors 66 .
- the surface of the insulation layer 54 which faces the hot side 22, is very rough.
- the surface of the glass foam layer 54 (insulation layer) consists of a number of webs of broken glass bubble cells. On the outside, where the outer layer 52 is laminated, this is advantageous in terms of the adhesion of the fiber composite material 12.
- a smooth surface on the inside of the insulation layer 54 is advantageous. It is also advantageous if there are no open glass pores 94 into which liquid could potentially penetrate. To achieve this, a heat treatment is carried out on the surface of the insulation layer 54 that faces the hot side 22.
- the surface treatment can be carried out, for example, using the device 18 in the form of a laser or with a device based on gas combustion or arc.
- the heat treatment described can also be carried out on the end faces of the tube ends of the sandwich components 50 manufactured as tubes 24 in order to achieve a smooth surface for sealing the connecting joints between two tubes 24 to be connected to one another.
- a hot stamp tool or similar can also be considered.
- the insulation layer 54 which comprises a gas-tight, high-temperature-resistant glass foam material 10
- fiber reinforcement can be carried out on the hot side 22 become.
- a fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix is used on the unprocessed surface of the insulation layer 54 on the side of the insulation layer 54 facing the hot side 22.
- Its construction can be done, for example, by direct laminating and subsequent temperature treatment of the laminated layer and the insulation layer 54 together for the consolidation and hardening or pyrolysis of the fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix, if the temperature resistance of the glass foam material 10 is high enough for that
- the above-mentioned fiber composite material 16 is a necessary process (e.g. glass soldering process).
- the sandwich component proposed according to the invention can be used in hot gas lines, for air or exhaust gas routing or as an enclosure for hot units, such as an APU (Auxiliary Power Unit) of an aircraft; it can also be used as an enclosure for associated silencers.
- hot units such as an APU (Auxiliary Power Unit) of an aircraft
- APU Advanced Power Unit
- the sandwich component 50 in contrast to insulating wool, has a solid structure and therefore there is a solid connecting layer on both sides, which is used for fastening add-on elements (see positions 28, 30) or for connecting to external ones structures are suitable.
- the sandwich component 50 proposed according to the invention can be made with a fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix of an insulation layer 54, which has a gas-tight, high-temperature-resistant glass foam material 10 and a fiber composite material 12 as an outer layer 52, for housing further hot aggregates, such as For example, a solid oxide fuel cell or for safety-enhancing housing of potentially hot units (e.g. in the event of a fault), such as batteries, low-temperature fuel cells or other energy converters.
- a fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix of an insulation layer 54 which has a gas-tight, high-temperature-resistant glass foam material 10 and a fiber composite material 12 as an outer layer 52, for housing further hot aggregates, such as For example, a solid oxide fuel cell or for safety-enhancing housing of potentially hot units (e.g. in the event of a fault), such as batteries, low-temperature fuel cells or other energy converters.
- Another application for the described sandwich component 50, 90 proposed according to the invention can be structural elements that serve as heat protection shields from the outside, for example in spacecraft, where they serve as heat protection during atmospheric re-entry or in supersonic aircraft.
- the side provided with the fiber composite material 16 with a ceramic matrix or glass-like, inorganic matrix is on the outside and the outer layer 52 made from the fiber composite material 12 is on arranged on the inside of the aircraft.
- an adaptation of the principle of laminating fiber-optic sensors 82 described above, in this case possibly also in the fiber-ceramic cover layer or in the inner fiber composite material layer in this case or in both, can serve to detect leaks or damage.
- AFP process Thermoplastic Automated Fiber Placement
- mechanical and thermal loads for example due to autoclave pressure, laying head contact pressure or due to temperature gradients, are not higher than the load limit of the glass foam material 10 used as the insulation layer 54.
- the sandwich component 50 designed as a tube 24, can be seen in FIGS. 7 and 7.1.
- the hot side is designated by reference number 22, while the cold side is designated by reference number 20.
- a leak point 48 extends through which hot medium flows from the hot side 22 in the direction of the cold side 20 through the glass foam material 10, which forms the insulation layer 54, via air channels 76 in the direction of an outlet 68 in the area of the outer layer 22.
- a temperature sensor 72 Opposite the outlet 68 on the outer layer 52 is a temperature sensor 72. This senses the temperature increase that occurs due to the emerging hot medium.
- Figure 7.1 shows air channels 76 which cross one another and are embedded in the outer layer 52 of the sandwich component 50, which is also designed as a tube 24.
- the tube 24 has end faces 86 on which the tube 24 can be integrated into a line at corresponding joints or connected to other tubes.
- Figure 8 shows that the sandwich component 50, which is also designed here as a tube 24, is enclosed by an air-guiding cover 84, for example made of a film material.
- the air-conducting sleeve 84 has film reserves 88 at, for example, opposite locations, so that if the medium escapes via a leak in the foam glass layer and the fiber composite layers, it is caught by the air-conducting sleeve 84 and, thanks to the existing reserve 88, there is a gap between outer fiber composite layer and the air guide cover 84 can form, so that the air flows through this gap to one of the outlets 68 and only there exits to the outside.
- the sandwich component 50 designed as a tube 24, is flowed through by a medium on the hot side 22. Analogous to the illustration according to FIG. 7, a temperature sensor 72 is also assigned to the outlet 68.
- the sandwich component 50 includes, in addition to the glass foam material 10, the fiber composite material 12 as an outer layer 52 on its inside, the fiber composite material 16 with a ceramic matrix or with a glass-like, inorganic matrix.
- the sandwich component 50 here also designed as a tube 24, can include fiber-optic sensors 82 laminated into its outer layer 52. These are on the outside of the tube 24, i.e. H. arranged on the outer layer 52, analogous to the course of air channels 76 (see illustration according to Figure 7.1).
- the sandwich component 50 shown in Figure 9 in the form of the tube 24 is one which is constructed analogously to the sandwich component 50 according to Figure 7, namely the glass foam material 10 as an insulating layer 54 and the fiber composite material 12 as the outer layer 52. In the outer layer The fiber optic sensors 82 are laminated into 52.
- the course of the arrangement of the fiber-optic sensors 82 can correspond to the course of the air channels 76, but this is not absolutely necessary. With the air ducts 76, for example, it makes sense if they cross each other regularly; In the case of fiber-optic sensors 82, a close-meshed, spiral-shaped winding in only one direction can also be considered without crossing over.
- the air channels 76 according to FIG. 7 are located in the foam glass layer, while the fiber-optic sensor genes 82 according to FIG. 9 can be assigned to the outer fiber composite layer.
- the invention is not limited to the exemplary embodiments described here and the aspects highlighted therein. Rather, within the range specified by the claims, a large number of modifications are possible, which are within the scope of professional action.
- Air guide cover made of foil
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Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102022105673.2A DE102022105673A1 (de) | 2022-03-10 | 2022-03-10 | Verfahren zur Herstellung eines mindestens zweischichtigen Sandwichbauelements |
| PCT/EP2023/055678 WO2023170029A1 (de) | 2022-03-10 | 2023-03-07 | Verfahren zur herstellung eines mindestens zweischichtigen sandwichbauelements |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4489967A1 true EP4489967A1 (de) | 2025-01-15 |
Family
ID=85601707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23710825.3A Withdrawn EP4489967A1 (de) | 2022-03-10 | 2023-03-07 | Verfahren zur herstellung eines mindestens zweischichtigen sandwichbauelements |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP4489967A1 (de) |
| DE (1) | DE102022105673A1 (de) |
| WO (1) | WO2023170029A1 (de) |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3157204A (en) * | 1960-10-19 | 1964-11-17 | Morris T Phillips | Insulating and protective covering devices |
| DE4338807C1 (de) | 1993-11-12 | 1995-01-26 | Heraeus Quarzglas | Formkörper mit hohem Gehalt an Siliziumdioxid und Verfahren zur Herstellung solcher Formkörper |
| FR2719065B3 (fr) * | 1994-04-11 | 1996-03-29 | Techni Clean | Panneau d'isolation thermique ininflammable constitué d'un élément en mousse isolante minérale et d'un élément en matière synthétique thermodurcissable renforcée. |
| US20080063875A1 (en) | 2000-09-20 | 2008-03-13 | Robinson John W | High heat distortion resistant inorganic laminate |
| WO2003016232A1 (en) | 2001-08-20 | 2003-02-27 | Advanced Minerals Corporation | Improved foam glass product |
| DE10341158A1 (de) | 2003-09-06 | 2005-05-12 | Fraunhofer Ges Forschung | Glasschaum enthaltendes Bauelement zur Schalldämpfung und Schalldämmung |
| DE102007042546B4 (de) * | 2007-09-07 | 2010-01-14 | Ulrich Glombitza | Verfahren zur ortsaufgelösten Temperaturmessung in einem Rohr- oder Kanalsystem |
| WO2012012259A1 (en) | 2010-07-19 | 2012-01-26 | World Minerals, Inc. | Foam glass having a low coefficient of thermal expansion and related methods |
| FR3021350B1 (fr) | 2014-05-20 | 2016-07-01 | Snecma | Procede de detection de fuite de fluide dans une turbomachine et systeme de distribution de fluide |
| DE102016000915A1 (de) | 2016-01-29 | 2017-08-03 | Hans-Peter Reinberger | Gründungsaufbau eines Bauwerkes |
| AT521214B1 (de) | 2018-04-18 | 2020-07-15 | Profeta Da Silva Alois | Formung von Glasschaum zu Halbzeugen, mit Faserverbund |
| ES3006583T3 (en) * | 2019-11-14 | 2025-03-18 | Airbus Operations Sl | Fireproof and thermal insulator product |
-
2022
- 2022-03-10 DE DE102022105673.2A patent/DE102022105673A1/de not_active Withdrawn
-
2023
- 2023-03-07 EP EP23710825.3A patent/EP4489967A1/de not_active Withdrawn
- 2023-03-07 WO PCT/EP2023/055678 patent/WO2023170029A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2023170029A1 (de) | 2023-09-14 |
| DE102022105673A1 (de) | 2023-09-14 |
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