EP4452901A1 - Support de cuisson de poudre alcaline avec revêtement de porosité contrôlée - Google Patents
Support de cuisson de poudre alcaline avec revêtement de porosité contrôléeInfo
- Publication number
- EP4452901A1 EP4452901A1 EP22854157.9A EP22854157A EP4452901A1 EP 4452901 A1 EP4452901 A1 EP 4452901A1 EP 22854157 A EP22854157 A EP 22854157A EP 4452901 A1 EP4452901 A1 EP 4452901A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- micrometers
- support according
- less
- ceramic body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 53
- 238000000576 coating method Methods 0.000 title claims abstract description 53
- 239000000843 powder Substances 0.000 title claims abstract description 33
- 229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 8
- 150000001340 alkali metals Chemical class 0.000 title claims abstract description 8
- 238000010304 firing Methods 0.000 title abstract description 4
- 239000000919 ceramic Substances 0.000 claims abstract description 60
- 239000011148 porous material Substances 0.000 claims abstract description 51
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 42
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 36
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000005524 ceramic coating Methods 0.000 claims abstract description 28
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 239000010703 silicon Substances 0.000 claims abstract description 6
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims abstract description 6
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 5
- 239000011029 spinel Substances 0.000 claims abstract description 5
- 241000588731 Hafnia Species 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 16
- 229910052744 lithium Inorganic materials 0.000 claims description 13
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 12
- 238000010411 cooking Methods 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000007751 thermal spraying Methods 0.000 claims description 11
- 229910052593 corundum Inorganic materials 0.000 claims description 7
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910052863 mullite Inorganic materials 0.000 claims description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052878 cordierite Inorganic materials 0.000 claims description 6
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052753 mercury Inorganic materials 0.000 claims description 6
- 229910004009 SiCy Inorganic materials 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- -1 Li2<3 Inorganic materials 0.000 claims description 4
- 239000011153 ceramic matrix composite Substances 0.000 claims description 4
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 4
- 238000002459 porosimetry Methods 0.000 claims description 4
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 claims description 3
- 229910021343 molybdenum disilicide Inorganic materials 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 229910052582 BN Inorganic materials 0.000 claims description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims description 2
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052580 B4C Inorganic materials 0.000 claims 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- 150000004767 nitrides Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 238000000151 deposition Methods 0.000 description 10
- 238000009826 distribution Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 238000010191 image analysis Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000007750 plasma spraying Methods 0.000 description 6
- 230000035939 shock Effects 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 229910003564 SiAlON Inorganic materials 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 230000001186 cumulative effect Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910000174 eucryptite Inorganic materials 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000013519 translation Methods 0.000 description 2
- 230000014616 translation Effects 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910020968 MoSi2 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- SOXUFMZTHZXOGC-UHFFFAOYSA-N [Li].[Mn].[Co].[Ni] Chemical compound [Li].[Mn].[Co].[Ni] SOXUFMZTHZXOGC-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010288 cold spraying Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910052670 petalite Inorganic materials 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62222—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic coatings
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
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- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0051—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore size, pore shape or kind of porosity
- C04B38/0058—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof characterised by the pore size, pore shape or kind of porosity open porosity
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4523—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied from the molten state ; Thermal spraying, e.g. plasma spraying
- C04B41/4527—Plasma spraying
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F27B14/08—Details specially adapted for crucible or pot furnaces
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- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D5/00—Supports, screens or the like for the charge within the furnace
- F27D5/0006—Composite supporting structures
- F27D5/0012—Modules of the sagger or setter type; Supports built up from them
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- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D5/00—Supports, screens or the like for the charge within the furnace
- F27D5/0068—Containers
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- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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Definitions
- the invention relates to the field of firing supports, in particular containers, crucibles or gazettes, for the heat treatment of alkaline powders intended for the manufacture of batteries.
- These powders in particular the lithium-based powders used for the manufacture of cathodes making up the latest generation batteries.
- lithium-ion batteries comprise a part, generally the cathode, of an oxide comprising lithium, in particular an oxide of a metal or of several lithiated transition metals, in particular LiFePCy (or LPF), LUVipCy (or LMO ), or a lithium-nickel-cobalt-manganese (or NMC) oxide.
- an oxide comprising lithium in particular an oxide of a metal or of several lithiated transition metals, in particular LiFePCy (or LPF), LUVipCy (or LMO ), or a lithium-nickel-cobalt-manganese (or NMC) oxide.
- the cathode is generally manufactured by shaping a powder of said oxide of a metal or of several alkaline transition metals, in particular lithiated.
- the mixture is placed in a cooking medium, in particular a gazette or "sagger" in English.
- a cooking medium in particular a gazette or "sagger" in English.
- the synthesis conditions of said powders , as well as said mixture , in particular the elements containing lithium, are particularly stressful for the firing medium containing lithiated powders.
- the known solutions of monolithic crucibles, for example as described in application US2021269365A1, can still be improved in terms of service life.
- CN112537967A consisting for example of depositing a layer by cold spraying of a suspension, the formulation of which comprises alumina, quartz, oxide of titanium, tungsten carbide, sintering agent and shaping agents.
- CN111233482A also offers a gazette with a coating sintered from a deposit mineral formulation including silicon carbide, magnesia, talc and graphite. The corrosion resistance of this coating is however insufficient.
- KR20020050390A suggests an alumina gazette coated with a 30 to 500 ⁇ m thick deposit of zirconia followed by sintering between 400 and 1500 ° C in order to improve the chemical resistance of the coating against barium titanate powders or ferrites.
- KR20010045759A offers an alumina gazette provided with a rough zirconia layer of 30 to 1000 ⁇ m deposited by thermal spraying at a specified angle in order to reduce the cost of deposition and improve the mechanical properties of the coating.
- the object of the invention is to propose cooking supports which make it possible to meet , at least partially , this need , in particular containers in the form of crucibles or gazettes that can be easily reused , highly resistant to corrosion by alkali metals and in particular by lithium, and highly resistant to thermal shock and cycling.
- the object of the invention is a support for cooking a powder comprising an alkali, in particular Li, capable of being used for the heat treatment of a load comprising an alkaline powder intended for the manufacture of batteries.
- a porous ceramic body forming a cavity or a container for said powder , in which said ceramic body is coated on at least part of its internal surface with a ceramic coating , in which : a) said porous body has, as measured by mercury porosimetry and by volume, an open porosity of between 10 and 40%, and an equivalent or median pore diameter of between 0.1 and 25 micrometers, preferably between 0 .5 and 25 microns; preferably the open porosity of said porous body is between 10 and 30%, more preferably is between 10% and 20%; b) said coating has the following characteristics:
- Said compound is preferably chosen from alumina, a lithium aluminate optionally further comprising silicon, in particular LiAlSiOs, LiAlSi20s, LisAlSiOs, LiAlSi4010, LiAlSiO4, an alumina/magnesia spinel. its average thickness is between 50 and 500 micrometers; preferably between 100 and 300 micrometers;
- the median pore diameter dso of said ceramic coating is between 0.1 micrometers and 1.5 micrometers.
- the median pore diameter dso of said ceramic coating is greater than 0.5 micrometers and/or less than 1 micrometer;
- the pore diameter dgo of said ceramic coating is less than 2.5 micrometers.
- the median grain size of said ceramic coating is between 5 and 100 micrometers.
- said size is greater than 10 micrometers and/or less than 70 micrometers, preferably less than 50 micrometers, preferably less than 30 micrometers;
- the mass content of said ceramic coating in alkaline oxides apart from Li2 ⁇ 3 is less than 0.5%.
- the mass content of said ceramic coating in Na2 ⁇ 3 and/or K2O is preferably less than 0.5%, preferably is less than 0.2%, preferably is less than 0.1%;
- the mass content of said SiCy ceramic coating is less than 0.5%, preferably is less than 0.2%; more preferably is less than 0.1%;
- the chemical composition of said ceramic coating in metal oxides Cr2 ⁇ 3, Fe2 ⁇ 3, ZnO or CuO capable of reacting with alkaline powders is such that the mass content of said coating in the sum of the oxides Cr2 ⁇ 3+ZnO+Fe2O3+CuO is less than 0 .5%.
- the mass content of said ceramic coating in Fe2O3 is less than 0.5%, preferably is less than 0.2%;
- - the mass content of said ceramic coating in oxides other than Al2O3, MgO, Li2 ⁇ 3, Y2O3, ZrCy, HfCy is less than 1%, preferably is less than 0.5%; more preferably is less than 0.2%; - the mass content of said ceramic coating in Al2O3 is greater than 98%, preferably greater than 98.5%, preferably greater than 99.0%, more preferably greater than 99.5%;
- said porous ceramic body comprises alumina, zirconia, magnesia, mullite, cordierite, carbide and/or silicon nitride or oxynitride, boron nitride, boron or molybdenum disilicide.
- said porous ceramic body comprises alumina, zirconia, magnesia, mullite, cordierite, carbide and/or silicon nitride or oxynitride ;
- said porous ceramic body comprises and preferably consists of a ceramic matrix composite.
- the ceramic matrix comprises alumina, zirconia, magnesia, mullite, cordierite, carbide and/or silicon nitride or oxynitride, including SiAlON and Si2 ⁇ N2, boron nitride (BN), boron carbide (B4C), or molybdenum disilicide (MoSi2.
- said matrix comprises alumina, zirconia, magnesia, mullite, cordierite, carbide and/or silicon nitride or oxynitride
- the Ceramic Matrix Composite preferably comprises alumina and/or mullite and/or SiC and/or carbon fibers;
- the mass content of said porous ceramic body in the sum of the oxides ZrO2+A12O3+SiO2+MgO is greater than 95%, preferably greater than 98%, preferably greater than 99%;
- the wall thickness of said porous ceramic body is preferably between 3 and 30 mm, preferably is between 5 and 15 mm.
- a cooking support with a porous ceramic body provided with a coating of controlled porosity solves the above technical problem in that it has excellent resistance to corrosion and very low adhesion with alkali metals, in particular lithium, while remaining adherent to the support despite thermomechanical stresses, which gives it an improved lifespan.
- the maximum pore diameter (Dioo) of said ceramic coating is less than 7 micrometers.
- the median pore diameter Dso of said ceramic coating is between 0.1 and 5 micrometers, in particular between 0.5 and 5 micrometers, more preferably between 0.5 and 1.5 micrometers;
- the median grain size of said ceramic coating measured by image analysis taken on polished sections observed under a scanning electron microscope is between 10 and 100 micrometers, preferably greater than or equal to 20 micrometers and/or less than 70 micrometers, preferably also comprised 20 micrometers and 50 micrometers; the thickness of said ceramic coating is less than 500 micrometers, preferably less than 400 micrometers, preferably less than 300 micrometers and/or greater than 50 micrometers, preferably greater than 100 micrometers; the material constituting said ceramic coating is preferably essentially alumina;
- said coating is obtained by thermal spraying
- said coating consists of two layers, preferably of similar chemical composition, that is to say that the difference in chemical composition is less than 5% for its constituent elements;
- porous ceramic body of said cooking support which can be combined between, where appropriate: - said porous ceramic body in monolithic form is particularly well suited for use in an automated method of loading and unloading respectively before and after heat treatment of the alkaline powder;
- said porous ceramic body is preferably coated over at least 50% or 60%, in particular 80% or 90%, or even over all of its internal surface with the coating as defined previously;
- said ceramic body normally comprises a bottom and walls
- said ceramic body contains little or no free silica, that is to say silica (SiCg) not combined with another oxide, for example in the form of mullite or cordierite;
- the mass content of said porous ceramic body in alkaline oxides is less than 1%.
- mass content of said porous ceramic body in alkaline oxides is less than 1%.
- Na2O is less than 0.5%;
- the mass content of said porous ceramic body in alkaline-earth oxides is less than 1%.
- K2O or CaO is less than 0.5%;
- the chemical composition of said porous ceramic body in each metal oxide capable of reacting with the alkali powders is such that the mass content of each of the following oxides Cr2 ⁇ 3, Fe2 ⁇ 3, ZnO or CuO, is less than 1%.
- the content of the ceramic body of each of these oxides is preferably less than 0.5% by mass;
- the median pore diameter of said porous ceramic body measured by mercury porosimetry is between 0.1 and 10 ⁇ m;
- said porous ceramic body preferably has a volume of at least 1 dm 3 , in particular 2 or even more than 3 dm 3 .
- Another object of the invention is a method of manufacturing a cooking medium according to the invention, in which the coating is formed by thermal spraying by depositing a plurality of superposed layers of molten particles which are then solidified by cooling.
- the coating is formed by thermal spraying by depositing a plurality of superposed layers of molten particles which are then solidified by cooling.
- flame spraying and plasma spraying are preferred.
- the porous ceramic body is coated with said coating by thermal spraying, the ceramic particles used for the spraying having a mass content of the sum of the oxides A12O3 +MgO+Li2O+Y2O3+ZrO2+Hf O2 greater than 99.9%.
- the median diameter of the population of said particles is between 10 and 50 micrometers, preferably greater than 10 micrometers and/or less than or equal to 40 micrometers.
- the ratio (D90-D10)/D10 of particle diameter is less than 3, preferably less than 2.
- the porous ceramic body preferably a gazette or a crucible, is obtained by conventional techniques known to those skilled in the art.
- the porous ceramic body is made of Alundum® AN199B material marketed by Saint-Gobain Performance Ceramics & Refractories.
- the material of the porous ceramic body is SiC with SisN4 bond typically obtained by reactive sintering, for example in an N-durance® material marketed by Saint-Gobain Performance Ceramics & Refractories.
- the porous ceramic body can be obtained, for example, by reactive sintering of preforms made from mixtures or suspensions containing silicon and/or silicon nitride powder, techniques described in particular in applications WC2007/148986, WC2004/016835 or again WC2012/084832.
- the coating according to the invention can be obtained by thermal spraying consisting of at least partial melting of particles which are sprayed onto the porous ceramic body.
- the mixture of particles is preferably very low in impurities such that the contents of oxides SiO2, Na2O, K2O, Cr2O3, ZnO, CuO and Fe2O3 in particular are very low.
- a mass content of the sum of the oxides A12O3+MgO+L ⁇ 2O+Y2O3+ZrO2+Hf O2 is greater than 99.9% is particularly advantageous for better control of the solidification-recrystallization phase after projection of the molten particles on the porous ceramic body.
- a mass content of the population of particles to be projected the mass content of the sum of the SiO2+Na2O+Fe2O3 oxides of which is preferably less than 0.05%.
- the median diameter of the population of particles to be projected is between 20 and 40 micrometers. Such a range is particularly suitable for obtaining the grain size of the coating according to the invention exhibiting the best performance.
- the process for depositing the coating consists of thermal spraying by flame consisting in projecting particles from a bead passing in front of the flame of a gun in which a gaseous mixture of acetylene and 'Oxygen so as to at least partially melt the ceramic particles of the bead.
- a cord of the Alumina Supra Flexicord® type supplied by Saint-Gobain coating Solution is particularly suitable given the diameter of the alumina particles in the cord (median diameter of the population of particles of 10 to 15 micrometers) and the very high purity of the alumina grains (>99.9% Al2O3).
- a Master Jet® type flame gun is particularly suitable for this type of projection.
- the deposition of the coating consists of a plasma projection, for example using a Proplasma® torch similar to that shown in Figure 1 of EP2407012B1 supplied with a ceramic powder, for example an alumina powder of purity greater than 99% and of median diameter between 10 and 100 micrometers.
- the substrate formed by the porous ceramic body is preheated to a temperature of between 200 and 400° C., preferably in air and at atmospheric pressure.
- the projection is done with the axis of the thermal projection tool normal to the surface by carrying out translations and slots with overlap.
- the coated porous ceramic body is then placed in an oven between 200 and 400° C., preferably in air, and subjected to a controlled drop in temperature of less than 200° C./h.
- the porous ceramic body after depositing a first layer is temperature stabilized in an oven between 200 and 400° C. before depositing a second layer.
- the invention also relates to the use of a baking support according to the invention as described above for the heat treatment of powders of an alkali metal, in particular comprising lithium, intended for the manufacture of batteries.
- FIGS. 1 to 3 The invention will be better understood on reading the non-limiting examples which follow, illustrated by FIGS. 1 to 3 .
- FIGS. 1 to 3 represent in section a porous ceramic body 1 with its coating 2 , respectively for examples 1 to 3 .
- the oxides are typically determined by X-ray fluorescence analysis or by TCP according to the measured contents. Unless otherwise stated, all oxide contents are mass percentages based on the oxides.
- a mass content of an oxide of a metallic element relates to the total content of this element expressed in the form of the most stable oxide, according to the usual industry convention.
- HfO 2 is not chemically dissociable from ZrO 2 when HfO 2 is not added voluntarily. This oxide being always naturally present in the sources of zirconia at mass contents generally lower than 5%, generally lower than 2%. Symmetrically during a voluntary addition of HfO2 there may be inevitable impurities of zirconium oxide. For the sake of clarity, the total content of zirconium oxide and of traces of hafnium oxide can be designated either by “ZrO2” or by “ZrO2 + HfO2” and vice versa for “HfO2”.
- SiAlON is an oxynitride compound of at least the elements Si, Al and N, in particular of a compound respecting one of the following formulas:
- Ceramic Matrix Composite we conventionally mean a product composed of fibers ceramics rigidly bound together by a ceramic matrix.
- ceramic we mean a product that is neither metallic nor organic. In the context of the present invention, an oxide glass and carbon are considered ceramic products.
- coating is meant one or more layers of material (x). At least one of said layers, in particular the layer comprising a compound chosen from alumina, lithium aluminate, an alumina/magnesia spinel, zirconia, preferably stabilized for example by yttrium, hafnia, yttrine .
- This layer may be the result of the reaction of the ceramic body and the deposition by thermal spraying of the particles on the surface of said ceramic body.
- pores refers to all the pores.
- the porosity and the size of the pores of the ceramic body can be determined using a mercury porosimeter in application of Washburn's law mentioned in standard ISO 15901-1.2005 part 1. From a sample of cubic shape of approximately 1 cm 3 , a mercury porosimeter makes it possible to establish a size distribution of the pores by volume, that is to say to determine, for each pore size, a volume occupied by the pores having this size. It is thus possible to determine an equivalent diameter (also called median pore diameter Dso) corresponding to the 50th percentile of the median size of the population of pores of the ceramic body.
- an equivalent diameter also called median pore diameter Dso
- This size divides, in volume, said population into two groups: a group representing 50% of the pore volume and whose pores have a size less than the median size and another group representing 50% of the pore volume and whose pores have a size greater than or equal to said median size.
- the size or diameter of the pores or grains of the coating or the size of the grains of the porous ceramic body are determined by image analysis of cross sections observed under a scanning electron microscope with a magnification at least equal to 1000 , preferably equal to . 2000 .
- the area and the diameter of each of the grains or pores are obtained from the negatives by conventional image analysis techniques, preferably after binarization or segmentation of the image aimed at increasing its contrast.
- a distribution of grain diameters in percentage (in number) or of pores in percentage (in volume) is thus deduced, from which the median diameter of grains or pores corresponding to the percentile Dso is extracted.
- the open porosity of the material measured according to the mercury porosimetry techniques previously described, is approximately 16% (by volume) and its median pore diameter is of the order of 5 micrometers.
- a first series of ten gazettes was preheated to a temperature of 300° C. in an oven before being coated on its inner surface (side and bottom) with an alumina coating by thermal spraying using a Master Jet® type flame gun powered by a bead of Flexicord Pure Alumina® alumina reference 982101147000 supplied by Saint-Gobain Coating solutions.
- the gazettes are placed in an oven at 300°C subjected to a controlled temperature drop at 100°C/h.
- Example 2 unlike the previous example, on a second series of ten gazettes the layer is deposited using a flame gun of the Master Jet® type powered by a Flexicord Alumina Supra ® alumina cord reference 98210 1347000 supplied by Saint-Gobain Coating solutions.
- the gazettes are placed in an oven at 300°C subjected to a controlled temperature drop at 100°C/h.
- a series of ten gazettes is coated on its inner surface (side and bottom) with an alumina coating by thermal spraying using a Proplasma® torch similar to that shown in Figure 1 of EP2407012B1 of WO2014/083544 supplied with an alumina powder.
- the substrate formed by the gazette was preheated to a temperature of 300°C.
- Plasma spraying is done with the axis of the thermal spraying tool normal to the surface by performing translations and slots with overlap. The cooling of the coated gazettes after plasma spraying of the coating is free.
- a fourth example on a series of ten gazettes is deposited an intermediate layer in a manner similar to example 1 then a second layer is deposited by plasma spraying in a manner similar to example 3.
- the cooling of the coated gazettes after plasma spraying of the coating is free.
- the average thickness of the entire coating was determined by scanning electron microscope observation.
- the size of the grains and pores constituting the coating comprises the succession of the following steps, standard in the field:
- a series of 5 SEM shots is taken from the support according to a cross section (that is to say in the entire thickness of a wall). For greater clarity, the shots are made on a polished section of the material. Image acquisition is performed over a cumulative length of coating at least equal to 1.5 cm, in order to obtain values representative of the entire sample.
- the shots are subjected to binarization techniques, well known in image processing techniques, to increase the contrast of the outline of the grains or pores.
- a pore or grain diameter is determined (e), corresponding to the diameter of a perfect disc of the same area as that measured for said grain or said pore (this operation possibly being carried out using dedicated software in particular Visilog® marketed by Noesis).
- a grain or pore size distribution is thus obtained according to a conventional distribution curve and a median size of the grains or pores constituting the coating is thus determined, this median size corresponding respectively to the diameter dividing said distribution into a first population not comprising only grains with a diameter greater than or equal to this median size and a second population comprising only grains or pores with a diameter less than this median size or this median diameter.
- the measurements were carried out by image analysis of the set of the two layers constituting the coating.
- the corrosion resistance of the coating by lithium was evaluated for each example by the following method: A powder of lithium hydroxide with a purity of >99.9% by mass of LiOH was placed in a gazette provided with the coating. The assembly is then placed in an electric oven under vacuum at a temperature of 900°C maintained for 8 hours (rise to 900°C at a rate equal to 500°C/h, natural descent to ambient temperature by thermal inertia of the oven After 5 cycles, the presence of lithium penetration is observed by image analysis using the same method as for the average coating thickness:
- the resistance is excellent if there is no trace of lithium penetration deeper than 20 micrometers in the thickness of the coating; the resistance is considered good for a penetration depth between 20 and less than 30 micrometers;
- the resistance is considered average for a penetration depth greater than 30 and less than 50 micrometers
- the resistance to thermal shock of the gazette was determined according to the following method: A sample of five gazettes previously dried at 110° C. is placed in an oven then heated to 900° C. according to a ramp of 250° C./h. The oven is then maintained at this temperature for one hour. Each gazette is then quickly removed from the oven to undergo quenching in ambient air (20° C.) for 20 minutes. The operation continues in this way until ten cycles have been completed. Each gazette is then analyzed for external and internal observation of the microstructure, in particular of the coating. Observation with the naked eye makes it easy to identify the appearance of external cracks. In particular, very good resistance to thermal shock corresponds to an absence of cracks in the coating or at the interface between the ceramic coating and body. Good resistance to thermal shock corresponds to a localized presence of one or more microcracks, which however do not threaten the integrity of the coating.
- the deposition conditions are specified in Table 1 below.
- the examples according to the invention whose coating has a pore volume fraction greater than or equal to 2 micrometers less than 2.5%, as measured by image analysis, show a satisfactory appearance after deposition, good or even very good resistance to thermal shock and good or even excellent resistance to corrosion, unlike Comparative Example 1.
- the examples according to the invention have little adhesion after baking so that the gazettes are easily cleaned by blowing or scraping without significant deterioration of the coating after 5 lithium corrosion tests.
- Example 4 shows that, in the case of superposition of deposits, the performance of the final coated support still depends on the distinctive criterion cited above.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Composite Materials (AREA)
- Coating By Spraying Or Casting (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Furnace Charging Or Discharging (AREA)
- Cookers (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2114403A FR3131295B1 (fr) | 2021-12-23 | 2021-12-23 | support de cuisson de poudre alcaline avec revêtement de porosité contrôlée |
| PCT/FR2022/052495 WO2023118767A1 (fr) | 2021-12-23 | 2022-12-23 | Support de cuisson de poudre alcaline avec revêtement de porosité contrôlée |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4452901A1 true EP4452901A1 (fr) | 2024-10-30 |
Family
ID=80786830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22854157.9A Pending EP4452901A1 (fr) | 2021-12-23 | 2022-12-23 | Support de cuisson de poudre alcaline avec revêtement de porosité contrôlée |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20250100940A1 (enExample) |
| EP (1) | EP4452901A1 (enExample) |
| JP (1) | JP2025501107A (enExample) |
| KR (1) | KR20240128842A (enExample) |
| CN (1) | CN118475547A (enExample) |
| CA (1) | CA3240132A1 (enExample) |
| FR (1) | FR3131295B1 (enExample) |
| WO (1) | WO2023118767A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3159808B1 (fr) * | 2024-02-29 | 2026-02-13 | Saint Gobain Ct Recherches | support poreux avec revêtement céramique de porosité contrôlée |
| FR3161213A1 (fr) * | 2024-04-10 | 2025-10-17 | Novadditive | Dispositif de support de cuisson |
| CN118374796B (zh) * | 2024-06-26 | 2024-08-30 | 河南驰耐特材科技有限公司 | 一种管道内壁耐腐蚀涂层 |
| CN121318511A (zh) | 2024-07-12 | 2026-01-13 | 欧洲技术研究圣戈班中心 | 具有氮化物基体的陶瓷焙烧载具 |
| FR3164460A1 (fr) | 2024-07-12 | 2026-01-16 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Support de cuisson de carbure de silicium fritté avec phase liante de corindon |
| FR3164459A1 (fr) | 2024-07-12 | 2026-01-16 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Support de cuisson céramique avec matrice de nitrure |
| CN121318510A (zh) | 2024-07-12 | 2026-01-13 | 欧洲技术研究圣戈班中心 | 具有刚玉粘结相的用于烧结碳化硅的焙烧载具 |
| FR3165693A3 (fr) | 2024-08-22 | 2026-02-27 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Support de cuisson comprenant un revêtement de grains de borocarbonitrure et une phase liante phosphatée |
| WO2026041719A1 (fr) | 2024-08-22 | 2026-02-26 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Support de cuisson comprenant un revêtement de grains de borocarbonitrure et une phase liante phosphatee |
| CN119038966B (zh) * | 2024-10-30 | 2025-04-25 | 苏州锦艺新材料科技股份有限公司 | 一种用于锂离子电池的多孔氧化铝粉末、电池隔膜、电池、用电设备 |
| CN120829303B (zh) * | 2025-09-19 | 2025-12-12 | 湖南德景源科技有限公司 | 一种铝酸锂复合匣钵及其制备方法和应用 |
| CN121554310B (zh) * | 2026-01-22 | 2026-04-28 | 阳泉银宇新材料有限责任公司 | 一种锂电池匣钵涂层及其制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6057030A (en) * | 1997-07-21 | 2000-05-02 | Kanebo Ltd. | Porous ceramic body and kiln furniture made from a porous ceramic body |
| KR100314726B1 (ko) | 1999-11-08 | 2001-11-17 | 신현준 | 지르코니아가 코팅된 알루미나 내화갑의 제조방법 |
| KR100694265B1 (ko) | 2000-12-21 | 2007-03-14 | 재단법인 포항산업과학연구원 | 알루미나 내화갑에 지르코니아를 습식코팅하는 방법 |
| NO317080B1 (no) | 2002-08-15 | 2004-08-02 | Crusin As | Silisiumnitriddigler som er bestandige mot silisiumsmelter og fremgangsmate for fremstilling av slike digler |
| WO2007148986A1 (en) | 2006-06-23 | 2007-12-27 | Rec Scanwafer As | Reusable crucibles and method of manufacturing them |
| FR2943209B1 (fr) | 2009-03-12 | 2013-03-08 | Saint Gobain Ct Recherches | Torche a plasma avec injecteur lateral |
| SG191169A1 (en) | 2010-12-22 | 2013-07-31 | Steuler Solar Gmbh | Crucibles |
| FR2997419A1 (fr) * | 2012-10-31 | 2014-05-02 | Saint Gobain Ct Recherches | Creuset incorporant un revetement sialon. |
| FR2998561B1 (fr) | 2012-11-29 | 2014-11-21 | Saint Gobain Ct Recherches | Poudre haute purete destinee a la projection thermique |
| CN104987094B (zh) * | 2015-07-08 | 2017-11-17 | 武汉理工大学 | 一种抗碱性陶瓷涂层材料及其制备方法 |
| CN108302942A (zh) * | 2018-01-08 | 2018-07-20 | 朱性宇 | 锂电池电极材料制备用匣钵、该匣钵的保护层以及匣钵的制备方法 |
| DE102018115771A1 (de) | 2018-06-29 | 2020-01-02 | Saint-Gobain Industriekeramik Rödental GmbH | Kapselartige Aufnahme, insbesondere Kapsel zum Brennen von pulverförmigem Kathoden-Material für Lithium-Ionen-Akkus sowie Mischung hierfür |
| CN111233482A (zh) | 2020-01-19 | 2020-06-05 | 湖南太子新材料科技有限公司 | 一种耐高温匣钵及其制备方法 |
| DE102020000510B4 (de) | 2020-01-28 | 2026-01-15 | Saint-Gobain Industriekeramik Rödental GmbH | Transportwanne zum Transportieren und Erhitzen chemischer Substanzen |
| CN112537967A (zh) | 2020-12-07 | 2021-03-23 | 合肥融捷能源材料有限公司 | 一种锂离子电池正极材料生产用匣钵的修复材料及其修复方法 |
-
2021
- 2021-12-23 FR FR2114403A patent/FR3131295B1/fr active Active
-
2022
- 2022-12-23 WO PCT/FR2022/052495 patent/WO2023118767A1/fr not_active Ceased
- 2022-12-23 US US18/721,600 patent/US20250100940A1/en active Pending
- 2022-12-23 KR KR1020247020809A patent/KR20240128842A/ko active Pending
- 2022-12-23 JP JP2024537908A patent/JP2025501107A/ja active Pending
- 2022-12-23 EP EP22854157.9A patent/EP4452901A1/fr active Pending
- 2022-12-23 CN CN202280085335.0A patent/CN118475547A/zh active Pending
- 2022-12-23 CA CA3240132A patent/CA3240132A1/fr active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA3240132A1 (fr) | 2023-06-29 |
| JP2025501107A (ja) | 2025-01-17 |
| FR3131295B1 (fr) | 2023-12-29 |
| FR3131295A1 (fr) | 2023-06-30 |
| CN118475547A (zh) | 2024-08-09 |
| WO2023118767A1 (fr) | 2023-06-29 |
| US20250100940A1 (en) | 2025-03-27 |
| KR20240128842A (ko) | 2024-08-27 |
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