EP4355292A1 - Produit cosmétique constitué d'un matériau d'emballage et d'une préparation contenant des diesters de propylène-glycol - Google Patents
Produit cosmétique constitué d'un matériau d'emballage et d'une préparation contenant des diesters de propylène-glycolInfo
- Publication number
- EP4355292A1 EP4355292A1 EP22734245.8A EP22734245A EP4355292A1 EP 4355292 A1 EP4355292 A1 EP 4355292A1 EP 22734245 A EP22734245 A EP 22734245A EP 4355292 A1 EP4355292 A1 EP 4355292A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- inci
- propylene glycol
- preparation
- cosmetic according
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 49
- 239000002537 cosmetic Substances 0.000 title claims abstract description 47
- -1 propylene glycol diester Chemical class 0.000 title claims abstract description 32
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 24
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 17
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 17
- 239000004743 Polypropylene Substances 0.000 claims abstract description 10
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 10
- 229920001155 polypropylene Polymers 0.000 claims abstract description 10
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 9
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 9
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 claims description 40
- 239000003921 oil Substances 0.000 claims description 26
- 235000019198 oils Nutrition 0.000 claims description 26
- UTEGPGXBIXWSQE-UHFFFAOYSA-N 2-heptanoyloxypropyl heptanoate Chemical compound CCCCCCC(=O)OCC(C)OC(=O)CCCCCC UTEGPGXBIXWSQE-UHFFFAOYSA-N 0.000 claims description 9
- NFIHXTUNNGIYRF-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)OC(=O)CCCCCCCCC NFIHXTUNNGIYRF-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229940008099 dimethicone Drugs 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 5
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 5
- OVYMWJFNQQOJBU-UHFFFAOYSA-N 1-octanoyloxypropan-2-yl octanoate Chemical compound CCCCCCCC(=O)OCC(C)OC(=O)CCCCCCC OVYMWJFNQQOJBU-UHFFFAOYSA-N 0.000 claims description 4
- DDGZCTKMHAYRKN-UHFFFAOYSA-N 2-ethylhexyl 12-acetyloxyoctadecanoate Chemical compound CCCCCCC(OC(C)=O)CCCCCCCCCCC(=O)OCC(CC)CCCC DDGZCTKMHAYRKN-UHFFFAOYSA-N 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims description 4
- UMVMVEZHMZTUHD-UHFFFAOYSA-N DL-Propylene glycol dibenzoate Chemical compound C=1C=CC=CC=1C(=O)OC(C)COC(=O)C1=CC=CC=C1 UMVMVEZHMZTUHD-UHFFFAOYSA-N 0.000 claims description 4
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229940116422 propylene glycol dicaprate Drugs 0.000 claims description 4
- 239000011241 protective layer Substances 0.000 claims description 4
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- GKAVWWCJCPVMNR-UHFFFAOYSA-N tridecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC GKAVWWCJCPVMNR-UHFFFAOYSA-N 0.000 claims description 4
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 claims description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 2
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 235000019489 Almond oil Nutrition 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 244000020551 Helianthus annuus Species 0.000 claims description 2
- 235000003222 Helianthus annuus Nutrition 0.000 claims description 2
- 235000017011 Mandorlo dulce Nutrition 0.000 claims description 2
- 244000076313 Mandorlo dulce Species 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 claims description 2
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
- 239000008168 almond oil Substances 0.000 claims description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 2
- 229940067596 butylparaben Drugs 0.000 claims description 2
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 2
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 2
- 229960002216 methylparaben Drugs 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N n-alpha-hexadecene Natural products CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 claims description 2
- 239000007764 o/w emulsion Substances 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 2
- 229960001679 octinoxate Drugs 0.000 claims description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 2
- 229960000601 octocrylene Drugs 0.000 claims description 2
- 229960001173 oxybenzone Drugs 0.000 claims description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N p-hydroxybenzoic acid methyl ester Natural products COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N p-hydroxybenzoic acid propyl ester Natural products CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 235000019809 paraffin wax Nutrition 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229960003415 propylparaben Drugs 0.000 claims description 2
- 239000012176 shellac wax Substances 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- 229960001295 tocopherol Drugs 0.000 claims description 2
- 229930003799 tocopherol Natural products 0.000 claims description 2
- 235000010384 tocopherol Nutrition 0.000 claims description 2
- 239000011732 tocopherol Substances 0.000 claims description 2
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 2
- 229940117972 triolein Drugs 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 claims description 2
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims 1
- 239000005022 packaging material Substances 0.000 description 11
- 229920003023 plastic Polymers 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- 239000002994 raw material Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 206010063493 Premature ageing Diseases 0.000 description 1
- 208000032038 Premature aging Diseases 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008827 biological function Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Definitions
- the present invention relates to a cosmetic made from a cosmetic preparation containing propylene glycol diester and a packaging material made from HDPE, LDPE, PP or PET.
- the cleansing of the skin serves to remove dirt, sweat and the remains of dead skin particles, which form an ideal breeding ground for pathogens and parasites of all kinds.
- Skin care products are mostly used to moisturize and moisturize the skin. Active ingredients are often added to them, which regenerate the skin and, for example, prevent and reduce its premature aging (e.g. the development of fine lines, wrinkles).
- Skin care products are usually stored in packaging in the form of bottles, tubes or jars. These consist mainly of glass (glass jars) or plastics such as high-density polyethylene (HDPE), low-density polyethylene (LDPE), polypropylene (PP) or polyethylene terephthalate (PET).
- HDPE high-density polyethylene
- LDPE low-density polyethylene
- PP polypropylene
- PET polyethylene terephthalate
- a disadvantage of such packaging which is actually very cheap and extremely hygienic, is the fact that this packaging is not particularly sustainable/environmentally friendly, since it is made from petroleum products and/or natural gas and, when it is thermally recycled (combustion in the waste incineration plant), ultimately carbon dioxide from fossil fuels sources is released.
- these packaging materials In order to conserve natural resources, attempts are therefore being made to make these packaging materials as thin as possible and to recycle them after the preparation has been used.
- these thin-walled packaging materials have the disadvantage that, if the cosmetic preparation filled in them contains one or more oil components, they are not particularly stable in storage, but rather swell on contact with the oil, since the oil is "sucked up” and absorbed by the plastic.
- the products can oil out.
- the oil in the plastic means that the inscriptions printed on the packaging can smudge and become detached.
- the oil absorbed by the packaging makes it more difficult to recycle the plastic because the oil has to be separated from the polymer in a laborious process before new packaging can be made from the polymer plastic.
- oil-free preparations e.g. toothpaste
- packaging has to be coated or sealed on the inside facing the cosmetic, which is a complex process.
- protective barriers made of ethylene vinyl alcohol are known from the prior art, which are relatively expensive and also less easy to recycle than pure polyolefin packaging materials.
- a cosmetic made from a) a packaging material made of high-density polyethylene (HDPE), low-density polyethylene (LDPE), polypropylene (PP) or polyethylene terephthalate (PET), and b) a cosmetic preparation containing propylene glycol diester.
- HDPE high-density polyethylene
- LDPE low-density polyethylene
- PP polypropylene
- PET polyethylene terephthalate
- the packaging means a is formed from high-density polyethylene (HDPE).
- HDPE high-density polyethylene
- the packaging a has a wall thickness (thickness) of 1 to 8 mm.
- the advantageous embodiments of the present invention according to the invention are characterized in that the packaging has no protective layer (e.g. made of ethylene vinyl alcohol) on the inside facing the preparation.
- the packaging has no protective layer (e.g. made of ethylene vinyl alcohol) on the inside facing the preparation.
- Embodiments of the present invention that are advantageous according to the invention are characterized in that the propylene glycol diester is one or more compounds from the group of propylene glycol diheptanoate (INCI: propylene glycol diheptanoate), propylene glycol dicaprate (INCI: propylene glycol dicaprate), propylene glycol dicaprylate/dicaprate (INCI: propylene glycol dicaprylate/dicaprate) and propylene glycol dibenzoate (INCI: Propylene Glycol Dibenzoate) can be used.
- the propylene glycol diester is one or more compounds from the group of propylene glycol diheptanoate (INCI: propylene glycol diheptanoate), propylene glycol dicaprate (INCI: propylene glycol dicaprate), propylene glycol dicaprylate/dicaprate (INCI: propylene glycol dicaprylate/dicaprate) and propylene glycol dibenzoate
- propylene glycol diheptanoate (INCI: Propylene Glycol Diheptanoate) is used as the propylene glycol diester.
- Embodiments of the present invention that are advantageous according to the invention are also obtained in that the preparation is free from dimethicone (INCI: Dimethicone).
- the preparation is free from silicone oil, mineral oil, paraffin wax, microcrystalline wax, shellac wax and polyethylene wax.
- the preparation is free from polyacrylates, crosslinked acrylate/C10-C30 alkyl acrylate polymers and vinylpyrrolidone/hexadecene copolymers and free from 3-(4-methylbenzylidene)camphor, 2-hydroxy-4-methoxybenzophenone (INCI: oxybenzone), 2-ethylhexyl 4-methoxycinnamate (INCI octyl methoxycinnamate), ethylhexyl 2-cyano-3,3-diphenyl acrylate (INCI: octocrylene), parabens (particularly methyl, propyl and butyl paraben), methylisothiazolinone, chloromethylisothiazolinone and DMDM hydantoin, polyethylene glycol ethers or polyethylene glycol esters
- the cosmetic preparation is in the form of an emulsion. It is preferred according to the invention if the cosmetic preparation is in the form of an oil-in-water emulsion (O/W emulsion). It is advantageous according to the invention if the cosmetic preparation contains propylene glycol diester in a concentration of 0.1 to 10% by weight, based on the total weight of the preparation. A use concentration of 0.1 from 5 to 5% by weight, based on the total weight of the preparation, is preferred according to the invention. These use concentrations relate to the total amount of propylene glycol diesters used. If only one propylene glycol diester (eg propylene glycol diheptanoate) is used, this is the advantageous or preferred use concentration for this one compound.
- propylene glycol diester eg propylene glycol diheptanoate
- the total amount of propylene glycol diesters in the oil phase of the preparation is at least 3% by weight, based on the total weight of the oil phase.
- Embodiments that are advantageous according to the invention are also characterized in that the preparation contains one or more oils selected from the group consisting of the compounds octyldodecanol, caprylic/capric acid triglycerides (INCI: caprylic/capric triglycerides), coconut glycerides (INCI: cocoglycerides), tridecyl stearate (INCI: tridecyl stearate) , tridecyl trimelliate (INCI: Tridecyl Trimelliate).
- the preparation contains one or more oils selected from the group consisting of the compounds octyldodecanol, caprylic/capric acid triglycerides (INCI: caprylic/capric triglycerides), coconut glycerides (INCI: cocoglycerides), tridecyl stearate (INCI: tridecyl stearate) , tridecyl trimelliate (INCI: Tride
- the preparation contains one or more oils selected from the group of compounds containing polycitronellol (INCI: polycitronellol), polycitronellol acetate (INCI: polycitronellol acetate), triolein, ethylhexyl acetoxystearate (INCI: ethylhexyl acetoxystearate), acetylethylhexyl polyhydroxystearate (INCI: acetyl ethylhexyl polyhydroxystearate).
- the preparation contains one or more oils selected from the group consisting of almond oil (INCI: Prunus Amygdalus Dulcis Oil) and/or sunflower oil (INCI: Helianthus Annuus Seed Oil), hydrogenated castor oil (INCI: Hydrogenated Castor Oil) contains.
- almond oil INCI: Prunus Amygdalus Dulcis Oil
- sunflower oil INCI: Helianthus Annuus Seed Oil
- hydrogenated castor oil INCI: Hydrogenated Castor Oil
- the preparation contains tocopherol.
- the preparation according to the invention can contain the ingredients customary for cosmetics and be composed accordingly. comparison tests
- the penetration of the following cosmetic oils into the packaging material HDPE was examined.
- the product “Hostalen ACP 5831 D” from Lyondellbasell was used as the HDPE.
- Raw materials or components of the cosmetic preparation have migrated into the packaging material if the weight of the die-cut m1 is greater than the weight of mO.
- Weight increase (%) (m1 - mO) / mO
- the formula (m1 - m0)/m0 is used to determine the increase in weight (%) of the raw material or cosmetic preparation that has migrated into the packaging material.
- the mean value [%] and standard deviation [%] of the triple determination are also calculated.
- Example 1 O/W lotion
- Example 2 W/O lotion
- Example 3 O/W cream
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Produit cosmétique constitué a) d'un matériau d'emballage en polyéthylène haute densité (HDPE), polyéthylène basse densité (LDPE), polypropylène (PP) ou polyéthylène téréphtalate (PET), et b) d'une préparation cosmétique contenant des diesters de propylène-glycol.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102021206043.9A DE102021206043A1 (de) | 2021-06-14 | 2021-06-14 | Kosmetikum aus einem Packmittel und einer Zubereitung enthaltend Propylenglycoldiester |
| PCT/EP2022/065646 WO2022263271A1 (fr) | 2021-06-14 | 2022-06-09 | Produit cosmétique constitué d'un matériau d'emballage et d'une préparation contenant des diesters de propylène-glycol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4355292A1 true EP4355292A1 (fr) | 2024-04-24 |
Family
ID=82258549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22734245.8A Pending EP4355292A1 (fr) | 2021-06-14 | 2022-06-09 | Produit cosmétique constitué d'un matériau d'emballage et d'une préparation contenant des diesters de propylène-glycol |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP4355292A1 (fr) |
| DE (1) | DE102021206043A1 (fr) |
| WO (1) | WO2022263271A1 (fr) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102762661B (zh) * | 2010-02-12 | 2014-06-18 | 花王株式会社 | 包装体成型用材料、包装体、制品以及防止吸附的方法 |
-
2021
- 2021-06-14 DE DE102021206043.9A patent/DE102021206043A1/de not_active Withdrawn
-
2022
- 2022-06-09 WO PCT/EP2022/065646 patent/WO2022263271A1/fr active Application Filing
- 2022-06-09 EP EP22734245.8A patent/EP4355292A1/fr active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2022263271A1 (fr) | 2022-12-22 |
| DE102021206043A1 (de) | 2022-12-15 |
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