EP4347080A1 - Procédé et dispositif de pressage d'un extrait liquide hors d'un matériau à presser - Google Patents

Procédé et dispositif de pressage d'un extrait liquide hors d'un matériau à presser

Info

Publication number
EP4347080A1
EP4347080A1 EP22730893.9A EP22730893A EP4347080A1 EP 4347080 A1 EP4347080 A1 EP 4347080A1 EP 22730893 A EP22730893 A EP 22730893A EP 4347080 A1 EP4347080 A1 EP 4347080A1
Authority
EP
European Patent Office
Prior art keywords
screw press
carbon dioxide
pressed
dry ice
extract
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22730893.9A
Other languages
German (de)
English (en)
Inventor
Denis Beil
Frank Gockel
Maximilian ROSENBERGER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Messer SE and Co KGaA
Original Assignee
Messer SE and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Messer SE and Co KGaA filed Critical Messer SE and Co KGaA
Publication of EP4347080A1 publication Critical patent/EP4347080A1/fr
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B9/00Presses specially adapted for particular purposes
    • B30B9/02Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material
    • B30B9/12Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using pressing worms or screws co-operating with a permeable casing
    • B30B9/14Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using pressing worms or screws co-operating with a permeable casing operating with only one screw or worm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B9/00Presses specially adapted for particular purposes
    • B30B9/02Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material
    • B30B9/12Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using pressing worms or screws co-operating with a permeable casing
    • B30B9/122Means preventing the material from turning with the screw or returning towards the feed hopper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B9/00Presses specially adapted for particular purposes
    • B30B9/02Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material
    • B30B9/12Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using pressing worms or screws co-operating with a permeable casing
    • B30B9/125Control arrangements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B9/00Presses specially adapted for particular purposes
    • B30B9/02Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material
    • B30B9/12Presses specially adapted for particular purposes for squeezing-out liquid from liquid-containing material, e.g. juice from fruits, oil from oil-containing material using pressing worms or screws co-operating with a permeable casing
    • B30B9/127Feed means
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/06Production of fats or fatty oils from raw materials by pressing
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/10Production of fats or fatty oils from raw materials by extracting
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/10Production of fats or fatty oils from raw materials by extracting
    • C11B1/104Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/0203Solvent extraction of solids with a supercritical fluid

Definitions

  • the invention relates to a method for pressing a liquid extract from a material to be pressed, in which the material to be pressed is fed to a screw press, transported in the screw press along a pressing path and subjected to a pressing pressure, and in which the screw press is fed with an extractant which, together with the Extract is derived from the pressed material, with carbon dioxide being used as the extraction agent.
  • the invention also relates to a corresponding device.
  • the invention relates to a method and a device for pressing seeds.
  • Seeds such as rapeseed or sunflower seeds are today primarily mechanically pressed to obtain the oil contained in the seeds, and in some cases also obtained by extraction with a solvent such as hexane or supercritical CO2. Oilseeds with a high oil content are usually mechanically pressed because the process is more economical than pure extraction.
  • Screw presses in particular are used for pressing. They enable the seeds to be pressed continuously. The seeds are fed via a feed hopper to the screw press on the input side and transported through the pressing chamber by the rotating screw.
  • the pressing chamber is formed by parallel rods (strainer rods), which are provided with small gaps and are arranged around the screw (strainer basket).
  • the rotation of the auger presses the seed against the inner wall of the auger press and the oil can flow out through the gaps.
  • the compression volume narrows towards the outlet end of the screw, so that when the screw is running, a continuous pressure acts on the mass and oil is pressed out.
  • a largely de-oiled press cake leaves the screw.
  • this largely de-oiled press cake still has an oil content of 10%-15%, and it is also rich in proteins.
  • the press cake is usually processed and used as animal feed, the oil is sold as cooking or industrial oil.
  • there have been various efforts to reduce the residual oil content of the press cake One possibility is to preheat the seeds and press them at temperatures above 100°C (hot pressing). Here the viscosity of the oil is reduced by the increased temperature, more oil can be extracted.
  • the pressing temperatures should be limited to a maximum of 60°C.
  • the density of the carbon dioxide is comparatively low under the conditions of 300-400 bar and 70-90° C. that typically prevail in the screw press; If the temperature in the screw press is reduced, the density of the carbon dioxide used could be significantly increased and thus significantly more CO2 could be dissolved in the oil.
  • WO 2008/116457 A1 discloses a method and a device for pressing, in which the material to be pressed is conveyed by a screw press along a pressing path is transported and subjected to a pressing pressure.
  • the material to be pressed is treated with supercritical carbon dioxide as an extraction agent, which is discharged from the material to be pressed together with the extract.
  • the material to be pressed is transported at a maximum temperature of 60°C along the entire pressing path.
  • the invention is therefore based on the object of specifying a simple possibility for pressing seeds, in particular, which works with a high level of efficiency and requires comparatively little hardware.
  • carbon dioxide is supplied to the screw press in the form of dry ice, which is at least partially transported with the material to be pressed through the screw press along the pressing path, whereby it is sublimated and at least partially compressed to form liquid or supercritical carbon dioxide, and in which the liquid and/or supercritical and/or gaseous carbon dioxide is used as the extraction agent.
  • the effect of carbon dioxide as an extraction agent is therefore based on at least one of several effects.
  • liquid or supercritical carbon dioxide dissolves in the oil, reduces its viscosity and guides it through the openings provided in the screw press, for example through gaps or openings in a strainer basket or strainer rods (here also “extract discharge " called), off.
  • the viscosity of the oil is also reduced by sublimated carbon dioxide gas that dissolves in the oil.
  • the sublimation of the carbon dioxide leads to an increase in volume, which leads to a strong movement of the resulting carbon dioxide gas in the direction of the extract outlet of the screw press, entraining oil with it in a mechanical entrainment effect.
  • the dry ice is thus fed into a feeding unit together with the material to be pressed, fed to the screw press and transported through the screw press along the pressing path.
  • the dry ice sublimes and changes to the liquid or supercritical state in the high-pressure areas of the screw.
  • the liquid or supercritical CO2 dissolves in the extract and moves together with it - driven outwards by the pressure drop - through the extract discharge (e.g. strainer rods) out of the press.
  • CO2 gas also dissolves in the extract, reduces its viscosity and in this way acts as a volume-increasing propellant, which also pushes the extract through the extract outlet to the outside.
  • Any liquid supercritical or gaseous carbon dioxide that is not dissolved in the material to be pressed also exits via the extract discharge line and is discharged.
  • the sublimating dry ice which goes into the liquid or supercritical state, continuously absorbs heat from the pressed material during the pressing process and in this way ensures cooling of the pressed material, which lasts as long as dry ice particles are still present in the pressing path. On the one hand, this happens over at least a large part of the longitudinal extent of the screw press, since the dry ice particles only sublimate gradually. On the other hand, the dry ice particles are also distributed evenly over the cross section by being fed together with the material to be pressed, so that the carbon dioxide is well distributed and can act both as a refrigerant and as an extraction agent.
  • the dry ice is preferably fed to the screw press in the form of carbon dioxide pellets (nuggets) or carbon dioxide snow, which can be easily mixed into the material to be pressed.
  • the carbon dioxide pellets or the carbon dioxide snow are preferably produced from liquid carbon dioxide in a pelleting device or a snow generator on site and fed to a feeding unit of the screw press together with the material to be pressed immediately after their production.
  • the liquid CO2 used to produce the carbon dioxide particles is stored in a tank, for example at a temperature of -20°C and a pressure of 20 bar.
  • the gaseous carbon dioxide produced in the screw press before or during pressing can be removed and put to further use.
  • the gaseous carbon dioxide is used to render the extract inert.
  • carbon dioxide gas that is released during pressing can be fed together with the extract to a collection container, in which it forms an atmosphere that keeps atmospheric oxygen away.
  • a further improvement in quality is achieved in this way, particularly in the case of slightly oxidizing extracts such as edible oils.
  • the temperature in the screw press is measured continuously and the amount of dry ice supplied is regulated so that a predetermined target temperature in the screw press is not exceeded.
  • Material to be pressed and dry ice are preferably fed into the screw press in such a ratio that the temperature in the screw press is kept below a value of 60°C.
  • the amount of pressing material and/or dry ice, which is fed to the screw press is variably adjustable and is controlled as a function of a temperature measured in the screw press, or a proportionate metering of seed and dry ice is installed.
  • the comparatively low temperature of no more than 60°C ensures a particularly low viscosity of the extract and at the same time gentle treatment, especially of pressed goods with temperature-sensitive ingredients such as oilseeds.
  • a device for pressing a liquid extract from a material to be pressed with a screw press which is equipped with a feed unit for feeding in material to be pressed, an extract discharge line for discharging extract separated from the material to be pressed in the screw press, and an outlet line for discharging the material to be pressed that has been at least partially freed from the extract is equipped from the screw press, is characterized according to the invention in that a feed for dry ice, which is operatively connected to a device for producing dry ice, opens into the feed unit.
  • Both the material to be pressed and carbon dioxide in the form of dry ice, in particular dry ice pellets or carbon dioxide snow, are fed into the feeding unit of the screw press. It preferably includes a dosing device, by means of which the quantity flows of product and/or dry ice can be varied.
  • the dry ice particles are expediently produced on site in a commercially available pelleting device, from which the dry ice pellets produced are fed to the dosing device of the feed unit immediately or after intermediate storage in a buffer container.
  • a snow horn can also be used as a device for producing the dry ice, in which liquid carbon dioxide is expanded to form carbon dioxide gas and carbon dioxide snow and the carbon dioxide snow produced is then fed to the dosing device of the feed unit.
  • the task unit Upon contact with the material to be pressed, which may be at ambient temperature, for example, some of the dry ice sublimes into carbon dioxide gas, thereby cooling the material to be pressed.
  • the task unit therefore suitably includes an im essentially gas-tight feed hopper, which is equipped with an exhaust pipe for discharging the resulting carbon dioxide gas.
  • the carbon dioxide gas is discharged into the atmosphere via the exhaust pipe, fed to a further use, such as the pre-cooling of the material to be pressed, or returned to the device for producing dry ice.
  • the rest of the dry ice gets into the screw press with the material to be pressed, where it changes to a liquid or supercritical state during the pressing process and at least partially dissolves in the extract, which reduces the viscosity of the extract and increases the extract yield.
  • the carbon dioxide supplied in the form of dry ice thus becomes the extraction agent that favors the separation of the extract from the rest of the pressed material.
  • a colander screw press is preferably used as the screw press.
  • the screw press is equipped with closed walls in at least one section, for example the front section, through which no extract and no carbon dioxide can escape to the outside; it is also possible to provide several such sections with completely closed walls along the pressing path, which alternate with strainer basket sections through which the extract or carbon dioxide can escape.
  • the closed wall sections serve to ensure that the liquid or supercritical carbon dioxide can act on the material to be pressed and dissolve as well as possible in the extract.
  • the method according to the invention and the device according to the invention are particularly suitable for pressing oilseeds, such as linseed, poppy seeds, rapeseed, soybeans and/or sunflowers; however, the invention is not limited to this application, but can also be used, for example, in applications in environmental technology or the chemical industry.
  • FIG. 1 schematically shows the circuit diagram of a device according to the invention.
  • the device 1 shown in FIG. 1 comprises a screw press 2, for example a colander screw press.
  • the screw press 2 is equipped in a manner known per se with a screw shaft 4 which is driven by a motor 3 and is accommodated in a cylindrical press chamber so that it can rotate about its longitudinal axis.
  • the movement of the worm shaft 4 moves a material to be pressed in the direction of the arrow 5 (press path) and is thereby subjected to increasing pressure, which separates the material to be pressed into a liquid extract and a solid residue (press cake).
  • the walls 6 of the press chamber are, as is usual in a strainer rod screw press, formed at least in sections by rods (strainer rods) arranged parallel to one another. Small gaps 7 between or in the strainer rods allow the extract to pass through, which is then collected in an extract catcher 8 and discharged via an extract discharge line 9 .
  • the press cake, which has largely been freed from the extract, is drawn off via an outlet line 12 arranged on a press head 11 of the screw press 2 .
  • the device 1 comprises a feed unit 13 which opens into the screw press 2 and has a feed hopper 14 which opens into the screw press 2.
  • the feeder 17 is part of a device 15 for producing and transporting dry ice pellets.
  • the device 15 comprises a pelleting device 20, which can be a commercially available device for producing dry ice pellets, for example an ASCO dry ice pelletizer A120P.
  • the pelletizing device 20 is connected via a carbon dioxide supply line 21 to a tank 22 for storing liquid carbon dioxide.
  • a motor-driven conveying device 19, for example a screw conveyor, enables the dry ice pellets produced in the pelletizing device 20 to be conveyed to the feed unit 17.
  • the dry ice pellets can also first be conveyed into a buffer container (not shown here), which is equipped with a dosing screw for onward transport to the feed unit 13 connected is.
  • the material to be pressed for example oilseeds such as rapeseed
  • the feed hopper 14 is fed into the feed hopper 14 via the feed 16 .
  • 20 dry ice pellets are produced in the pelletizing device.
  • the dry ice pellets are produced from liquid carbon dioxide, which is stored in the tank 22 at low temperatures of, for example, -20° C. and a pressure of, for example, 20 bar.
  • the liquid carbon dioxide is fed via the feed line 21 to the pelletizing device 20 and is initially expanded there, with the formation of carbon dioxide gas and carbon dioxide snow.
  • the carbon dioxide snow is then pressed into cylindrical dry ice pellets which, for example, have a length of between 2 mm and 20 mm, a diameter of between 1 mm and 5 mm and a temperature of -78.9°C.
  • the carbon dioxide gas produced during the expansion of the liquid carbon dioxide in the pelletizing device 20 is discharged via an exhaust gas line 22 which opens into the exhaust gas line 18 .
  • the dry ice pellets are fed to the feed hopper 14 by means of the conveying device 19 via the feed 17 .
  • the material to be pressed mixes with the dry ice pellets and is thereby cooled.
  • the dry ice pellets partially sublimate and the resulting carbon dioxide gas is discharged via the exhaust pipe 18 .
  • the carbon dioxide gas from the exhaust lines 18, 22 can then be put to further use; for example, the still fairly cool gas can be used to pre-cool the material to be pressed, or it can be reliquefied and returned to the pelletizing device 20 and used there to produce dry ice pellets.
  • the material to be pressed which has been cooled and still heavily mixed with dry ice pellets, is then fed to screw press 2.
  • the rotation of the screw shaft 4 drives the material to be pressed forward in the direction of the arrow 5 and is compressed to pressures of 200 bar to 400 bar in the press chamber 24 between the screw shaft 2 and the walls 6 of the screw press, whereby extract (oil) from the press cake separates.
  • the extract is pressed out of the press chamber 24 via the column 7, collects in the extract catcher 8 and is discharged via the extract discharge line 9 and collected in a collecting container 10, for example.
  • the thermal energy introduced into the material to be pressed during pressing is partially absorbed by the dry ice pellets still present in the material to be pressed.
  • the amount of dry ice pellets fed in via the feeder 17 should be selected in such a way that the temperature inside the screw press 2 does not exceed a predetermined value, for example 60° C., at any point during the pressing process. These sublime or convert directly into liquid or supercritical carbon dioxide. A separate supply of liquid or supercritical carbon dioxide to the screw extruder 2 that goes beyond this is not required in the device 1 .
  • the liquid or supercritical carbon dioxide partially dissolves in the extract and reduces its viscosity, as a result of which the yield of extract in the screw press 2 is significantly increased compared to a mode of operation without the supply of dry ice pellets.
  • the remaining portion of the liquid or supercritical carbon dioxide that does not dissolve in the extract also escapes via column 7 and is discharged in a manner not shown here.
  • this carbon dioxide can be collected and fed into one of the exhaust gas lines 18, 22. It can also be drawn off together with the extract via the extract discharge line 9 and - like the carbon dioxide discharged via the exhaust gas lines 18, 22 - can be used in the further course of the process to protect the extract from oxidation with atmospheric oxygen, for example by the carbon dioxide in the collection container 10 forms an inerting atmosphere.
  • the press cake that accumulates at the press head 11 and has been largely freed of extract is discharged via the outlet line 12 and supplied for a further use, for example as animal feed.
  • the walls 6 in a front section 25 of the screw press 2 are closed, ie they have no gaps 7 .
  • Neither extract nor carbon dioxide can escape to the outside in this front section 25; Rather, it serves to ensure that the dry ice, which has been converted into liquid or supercritical carbon dioxide, can affect the extract and dissolve well in it.
  • a first section can be provided with sieve rods, which are used for pre-pressing or pre-oil removal, then comes a closed area (extraction area) in which the dry ice is transformed into supercritical carbon dioxide, followed by another strainer area for oil removal and CO2 expansion.
  • the temperature inside the screw press 2 is determined by the ratio of the press material supplied and the dry ice.
  • a control unit 26 is provided for this purpose, which regulates the supply of dry ice pellets via the conveyor device 19 as a function of a temperature measured in the screw press 2 by means of a sensor 27 .
  • a quantity of dry ice is fed in via the feed 17, which is sufficient to keep the temperature in the screw press 2 at a predetermined target value of, for example, below 60° C. over the entire pressing path.
  • the device 1 By feeding dry ice pellets into the screw press 2, the material to be pressed is cooled and at the same time the extract yield is increased. In this way, the device 1 enables the pressing material to be treated both gently and efficiently. In addition, in the case of the device 1 there is no need for a complex, high-pressure-resistant tubing for supplying liquid or supercritical carbon dioxide.
  • a snow horn can also be used, on which liquid carbon dioxide is expanded to form a mixture of carbon dioxide snow and carbon dioxide gas, and the resulting carbon dioxide snow is fed into the feed unit 13 via the conveyor device 19 and the feed 17 .
  • the procedure described above in relation to dry ice pellets applies in the same way to the particles of the carbon dioxide snow.
  • the method according to the invention and the device according to the invention are particularly suitable for obtaining oil from oilseeds such as linseed, poppy, rapeseed, soybeans and sunflowers.
  • oilseeds such as linseed, poppy, rapeseed, soybeans and sunflowers.
  • Feeder for pressed material
  • Feeder for dry ice pellets

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L'invention concerne un procédé de pressage d'un extrait liquide hors d'un matériau à presser. Le matériau à presser est fourni à une presse à vis et est transporté le long d'une trajectoire de pressage dans la presse à vis, et une pression de pressage est appliquée sur le matériau à presser. La presse à vis est alimentée par un agent d'extraction qui est évacué du matériau à presser conjointement avec l'extrait, le dioxyde de carbone étant utilisé en tant qu'agent d'extraction. L'invention est caractérisée en ce que le dioxyde de carbone est fourni à la presse à vis sous la forme de billes de glace sèche. La glace sèche est mélangée avec le matériau à presser et est transportée conjointement avec le matériau à presser à travers la presse à vis le long de la trajectoire de pressage. Dans le procédé, la glace sèche est convertie en dioxyde de carbone liquide ou supercritique, qui se dissout dans l'extrait et réduit sa viscosité et qui refroidit efficacement le matériau à presser dans la presse à vis.
EP22730893.9A 2021-06-01 2022-05-30 Procédé et dispositif de pressage d'un extrait liquide hors d'un matériau à presser Pending EP4347080A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102021002823.6A DE102021002823A1 (de) 2021-06-01 2021-06-01 Verfahren und Vorrichtung zum Pressen eines flüssigen Extrakts aus einem Pressgut
PCT/EP2022/064594 WO2022253749A1 (fr) 2021-06-01 2022-05-30 Procédé et dispositif de pressage d'un extrait liquide hors d'un matériau à presser

Publications (1)

Publication Number Publication Date
EP4347080A1 true EP4347080A1 (fr) 2024-04-10

Family

ID=82067495

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22730893.9A Pending EP4347080A1 (fr) 2021-06-01 2022-05-30 Procédé et dispositif de pressage d'un extrait liquide hors d'un matériau à presser

Country Status (6)

Country Link
EP (1) EP4347080A1 (fr)
CN (1) CN117545537A (fr)
BR (1) BR112023025130A2 (fr)
CA (1) CA3220864A1 (fr)
DE (1) DE102021002823A1 (fr)
WO (1) WO2022253749A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116571324B (zh) * 2023-07-12 2023-09-29 山东省食品药品检验研究院 一种含油作物粉碎设备以及含油作物粉碎方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL79838A0 (en) 1976-08-26 1986-11-30 Vitamins Inc Mass transfer extraction of liquids from solids
US5290959A (en) * 1985-09-10 1994-03-01 Vitamins, Inc. Mass separation of materials
DE4426757A1 (de) 1994-07-28 1996-02-01 Bayer Ag 2-Imidazolidinon-Derivate
ES2123345T3 (es) 1995-04-27 1999-01-01 Sucher & Holzer Bauplan Handel Prensa de tornillo.
GB2343898B (en) 1998-11-17 2002-09-18 Express Separations Ltd Pressing of oil from plant material with the assistance of gases under pressure
DE102007014775B4 (de) 2007-03-28 2022-05-25 Harburg-Freudenberger Maschinenbau Gmbh Verfahren und Vorrichtung zum Pressen
GB2485814A (en) 2010-11-25 2012-05-30 Desmet Ballestra Engineering S A Nv Dry ice assisted mechanical extraction process
DE102019007439A1 (de) * 2019-10-25 2021-04-29 Messer Group Gmbh Vorrichtung zum Erzeugen und Transportieren von Trockeneispellets

Also Published As

Publication number Publication date
CN117545537A (zh) 2024-02-09
WO2022253749A1 (fr) 2022-12-08
BR112023025130A2 (pt) 2024-02-27
DE102021002823A1 (de) 2022-12-01
CA3220864A1 (fr) 2022-12-08

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