EP4303506A1 - Conteneur destiné au transport de marchandises sensibles à la température - Google Patents
Conteneur destiné au transport de marchandises sensibles à la température Download PDFInfo
- Publication number
- EP4303506A1 EP4303506A1 EP22020321.0A EP22020321A EP4303506A1 EP 4303506 A1 EP4303506 A1 EP 4303506A1 EP 22020321 A EP22020321 A EP 22020321A EP 4303506 A1 EP4303506 A1 EP 4303506A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- loading space
- container
- wall
- container according
- barrier element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000011068 loading method Methods 0.000 claims abstract description 76
- 239000002826 coolant Substances 0.000 claims abstract description 52
- 230000004888 barrier function Effects 0.000 claims abstract description 46
- 239000003570 air Substances 0.000 claims description 42
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 27
- 235000011089 carbon dioxide Nutrition 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 13
- 239000012080 ambient air Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 description 90
- 229910052782 aluminium Inorganic materials 0.000 description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 22
- 239000007789 gas Substances 0.000 description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 239000011888 foil Substances 0.000 description 11
- 229910002804 graphite Inorganic materials 0.000 description 10
- 239000010439 graphite Substances 0.000 description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 125000006850 spacer group Chemical group 0.000 description 6
- 239000011162 core material Substances 0.000 description 4
- 229920002799 BoPET Polymers 0.000 description 3
- 239000004696 Poly ether ether ketone Substances 0.000 description 3
- 239000004964 aerogel Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012782 phase change material Substances 0.000 description 3
- 229920002530 polyetherether ketone Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- 230000008646 thermal stress Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920000582 polyisocyanurate Polymers 0.000 description 2
- 239000011495 polyisocyanurate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229960005486 vaccine Drugs 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D3/00—Devices using other cold materials; Devices using cold-storage bodies
- F25D3/02—Devices using other cold materials; Devices using cold-storage bodies using ice, e.g. ice-boxes
- F25D3/06—Movable containers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D11/00—Self-contained movable devices, e.g. domestic refrigerators
- F25D11/003—Transport containers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/02—Doors; Covers
- F25D23/025—Secondary closures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D3/00—Devices using other cold materials; Devices using cold-storage bodies
- F25D3/12—Devices using other cold materials; Devices using cold-storage bodies using solidified gases, e.g. carbon-dioxide snow
- F25D3/125—Movable containers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D11/00—Self-contained movable devices, e.g. domestic refrigerators
- F25D11/006—Self-contained movable devices, e.g. domestic refrigerators with cold storage accumulators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2201/00—Insulation
- F25D2201/10—Insulation with respect to heat
- F25D2201/12—Insulation with respect to heat using an insulating packing material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
- F25D23/065—Details
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/08—Parts formed wholly or mainly of plastics materials
- F25D23/082—Strips
- F25D23/087—Sealing strips
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2303/00—Details of devices using other cold materials; Details of devices using cold-storage bodies
- F25D2303/08—Devices using cold storage material, i.e. ice or other freezable liquid
- F25D2303/082—Devices using cold storage material, i.e. ice or other freezable liquid disposed in a cold storage element not forming part of a container for products to be cooled, e.g. ice pack or gel accumulator
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2303/00—Details of devices using other cold materials; Details of devices using cold-storage bodies
- F25D2303/08—Devices using cold storage material, i.e. ice or other freezable liquid
- F25D2303/084—Position of the cold storage material in relationship to a product to be cooled
- F25D2303/0844—Position of the cold storage material in relationship to a product to be cooled above the product
Definitions
- the invention refers to a container for transporting temperature-sensitive goods, comprising a wall structure which surrounds a loading space for receiving the goods and comprising an opening for loading and unloading the loading space, further comprising a door device for selectively opening and closing the opening, wherein at least one coolant reservoir for holding a coolant is arranged and/or fastened in the loading space on at least one wall of said wall structure, in particular an upper wall, wherein the at least one coolant reservoir or a coolant contained therein is exchangeable via a coolant access portion of the opening.
- IATA International Air Transport Association
- passive containers Active containers are maintained at a target temperature by means of a heat pump, requiring an electricity source to function.
- Passive containers do not require an energy input and rely on their insulation and on passive coolants to maintain their temperature, such as a phase-changing material (PCM), including ice or dry ice for example.
- PCM phase-changing material
- Opening the container creates challenging conditions for the transported goods.
- the cold air in the loading space leaves the container within seconds, due to the difference of density between the gases present within the loading space and outside of it. This difference of density is due to the temperature difference between the two environments and can be estimated using the ideal gas law.
- the instant invention aims at protecting such sensitive goods from potential temperature excursions during shipment, in particular when containers need to be opened to refill them with coolant, and thus prolonging the runtime of the transporting containers, thereby providing additional security in the transport of life-saving medicine.
- the instant invention provides a container of the type mentioned at the outset, which comprises at least one coolant reservoir that is arranged and/or fastened in the loading space on at least one wall of said wall structure, in particular an upper wall, wherein the at least one coolant reservoir or a coolant contained therein is exchangeable via a coolant access portion of the opening, and which is characterized by a barrier element being arranged to separate the loading space from the outside in a remaining portion of the opening when the door device is in an open position.
- the invention is based on the idea to limit the airflow between the internal loading space and the external environment, hence preventing or reducing the mass transfer of cold air from inside the container to the outside and preventing hot air from entering into the loading space when opening the container door(s).
- limiting the air exchange when opening the container door(s) is achieved by means of the barrier element.
- the barrier element shields the loading space from external heat. In other use cases, the barrier element may be useful to prevent or reduce mass transfer of warm air from inside the container to the outside and preventing cold air from entering into the loading space when opening the container door(s).
- the barrier element is arranged so as not to impair the access to the coolant reservoir for exchanging or refilling the same. Therefore, the invention provides that the barrier element is arranged to keep clear the coolant access portion of the container opening and is thus arranged in the remaining portion of the opening.
- the barrier element In order to minimize the loss of energy during opening of the door(s), the barrier element shall be configured to cover as much as possible of the remaining portion of the opening, i.e. of the air flow sectional area between the loading space and the environment of the container. Therefore, a preferred embodiment of the invention provides that the barrier element covers at least 50 %, preferably at least 80%, more preferably at least 90 %, of an air exchange flow sectional area between the loading space and the outside.
- the air exchange flow sectional area is preferably defined as a rectangular area enclosed by three walls of the wall structure and the coolant reservoir arranged on a fourth wall, preferably the upper wall.
- a preferred embodiment provides that a distance between the barrier element and a bottom wall of the wall structure is less than 50mm, preferably less than 30mm.
- the barrier element is preferably arranged to cover at least 70 %, preferably et least 90 %, more preferably at least 98 % of a width of the opening.
- the barrier element comprises elastic sealing elements on at least one lateral rim thereof.
- the barrier element is substantially impermeable to ambient air.
- the barrier element may be made of a sheet of material, such as metal, wood, fabric, plastic or a combination thereof.
- the barrier element is made of metal, which is advantageous due to its sturdiness and rigidity.
- the mass transfer of cold air can be calculated as follows.
- ⁇ represents the density of the gas
- g represents the gravity of Earth
- h represent the height along which the pressure difference is evaluated.
- the density for each volume shall be approximated as being constant given the small height of the container.
- P represents the pressure in a given volume
- V the volume
- n the amount of substance of the gas occupying the volume
- R the ideal gas constant
- T the temperature of the gas in the considered volume.
- M ⁇ C f S ⁇ P across ⁇ .
- C f the friction coefficient
- S the surface area through which the gas can flow
- ⁇ P across the pressure difference across the exchange area
- ⁇ the density of the gas flowing out through the constricted area.
- ⁇ P across is expressed as P in - P out .
- the inner and outer pressures are expressed according to the expression of ⁇ P vertical and vary depending on the height at which the opening is positioned.
- the container of the invention is preferably configured for transporting temperature-sensitive goods, such as pharmaceuticals, over a period of several days, wherein specified temperature ranges must be maintained during storage and transport in order to ensure the usability and safety of the goods being transported.
- the container of the invention is configured to maintain the loading space at a temperature of -60°C to -80°C over at least 3-5 days, which corresponds to specified storage and transport conditions for various drugs and vaccines.
- dry ice solid CO 2
- an amount of energy of 571.1 kJ/kg is required for the phase transition from solid to gas (sublimation), which enables a very large cooling effect with low weight compared to commercially available phase change material in a similar temperature range ( ⁇ 200 kJ/kg).
- Another advantage of dry ice is its residue-free dissolution. It is only necessary to ensure safe drainage of the gaseous carbon dioxide, which at normal pressure and a temperature of 0°C occupies about 760 times the volume of the dry ice. For air transport, there are usually maximum sublimation rates or dry ice quantities per flight, which must not be exceeded. Minimizing the amount of dry ice used per kg of cargo therefore directly affects the total amount of cargo allowed per flight.
- An efficient use of the coolant such as dry ice, may preferably be achieved, if the wall structure and/or the door device is designed as a layered structure comprising, from the outside to the inside, a first insulating layer, optionally a second insulating layer, and an energy distribution layer bounding the loading space and made of a material with a thermal conductivity of > 100 W/(m.K).
- the at least one coolant reservoir or its support structure is directly connected to the energy distribution layer in a thermally conductive manner, the thermally conductive connection preferably having a thermal conductivity of > 100 W/(m.K).
- the energy distribution layer bounding the loading space is preferably in direct contact with the loading space, so that direct heat transfer between the loading space and the energy distribution layer is ensured.
- the loading space can be used entirely for the payload. No air gaps are required to maintain air circulation.
- the highly efficient use of dry ice by internal heat distribution in combination with a two-layer insulation of the container wall results in a running time of more than 100-140h at an average outside temperature of 30°C with a dry ice quantity of 80-120 kg and a payload volume of 1 to 1.5 m 3 with an outside volume of 2-4 m 3 .
- This is a significant improvement by a factor of 2 to 20 compared to conventional solutions, allowing a payload volume of 1 to 1.5 m 3 per RKN aircraft position, or 4 transport containers to be arranged on a PMC pallet with a total payload volume of 4 ⁇ 1.5m 3 or 6m 3 .
- the first insulation layer, the second insulation layer, if present, and the energy distribution layer lie directly on top of each other.
- the first insulating layer, the second insulating layer, if present, and the energy distribution layer surround the loading space on all sides and without interruption, with the exception of the opening.
- the energy distribution layer completely surrounds the loading space with the exception of the opening, i.e. each wall of the container wall comprises the energy distribution layer as the innermost layer, the energy distribution layers of all walls being connected to one another in the adjacent edges and corners in a thermally conductive manner, i.e. by means of a joint which has a thermal conductivity of > 100 W/(m.K).
- the door device also comprises the layered structure used for the container wall structure.
- the door device consists of a layered structure comprising, from the outside to the inside: a first insulation layer, optionally a second insulation layer, and an energy distribution layer bounding the loading space and made of a material with a thermal conductivity of > 100 W/(m.K).
- a thermal conductivity of the energy distribution layer of at least 100 W/(m.K) is specified.
- the thermal conductivity of the energy distribution layer of the wall structure and/or the door device is at least 140 W/(m.K), more preferably at least 180 W/(m.K).
- the energy distribution layer of the container wall and/or the door device may, for example, be made of aluminum, of graphite or of a graphite composite material, in particular graphite sheets coated on both sides with carbon fiber-reinforced plastic. Such materials also result in mechanical reinforcement of the container wall at low weight.
- 0.5-5 mm thick aluminum plates can be used, which have a thermal conductivity of about 150 W/(m.K), distributing local heat inputs across the inner shell and resulting in a uniform temperature distribution in the loading space.
- the joints of the individual aluminum panels on the sides and corners can be reinforced with rivets so that they can withstand the forces generated by thermal stresses.
- CFRP carbon fiber reinforced plastic
- the at least one coolant reservoir is designed as a drawer that is guided in a guidance element such that it can be pulled out of and pushed into the loading space.
- a guidance element such that it can be pulled out of and pushed into the loading space.
- the drawer(s) has/have dimensions such that the entire dimension of a wall of the container wall structure is covered by the drawer(s).
- the at least one coolant reservoir in particular the drawer(s) as well as the drawer guide, which is attached to at least one wall, also consists of a highly heat-conductive material, so that the heat introduced is distributed evenly over the coolant.
- the at least one coolant container is made of a material with a thermal conductivity of > 100 W/(m.K), preferably > 140 W/(m.K), in particular > 180 W/(m.K), for example of aluminum, of graphite or of a graphite composite material, in particular of graphite sheets coated on both sides with carbon fiber-reinforced plastic.
- the barrier element is removably fixed to the wall structure and/or the guidance element of the drawer.
- the barrier element may be pivotably mounted to a wall of the wall structure and/or to the guidance element of the drawer.
- the thermal insulation of the container is preferably achieved by a first and, if necessary, a second insulation layer.
- the structure of the container wall with at least two insulation layers allows each insulation layer to be optimized with regard to its respective insulation function.
- one of the insulation layers, in particular the first, outer insulation layer is designed to minimize heat transfer to the loading space via thermal radiation.
- the other insulation layer, in particular the second, inner insulation layer may be formed to minimize heat transfer to the loading space occurring via heat conduction.
- the first insulation layer may have a thermal conductivity of 4 to 300 mW/(m.K) and the second insulation layer may have a thermal conductivity of 1 to 30 mW/(m.K), with the first insulation layer preferably having a higher thermal conductivity than the second insulation layer.
- the first insulation layer may comprise a heat-reflective coated substrate, such as a substrate provided with a metal coating.
- the heat-reflective coating is formed by a metallic, in particular gas-tight coating, preferably a coating with an emissivity of ⁇ 0.5, preferably ⁇ 0.2, particularly preferably ⁇ 0.04, such as a coating of aluminum.
- said insulation layer comprises a multilayer structure of honeycomb-shaped thermoformed plastic films, which is provided on both sides with a heat-reflecting coating, in particular of aluminum.
- said insulation layer has a plurality of, in particular, honeycomb-shaped hollow chambers, a honeycomb structural element according to WO 2011/032299 A1 being particularly advantageous.
- said insulation layer may be made of a conventional porous insulation material, such as polyurethane, polyisocyanurate or expanded polystyrene.
- said insulation layer has a thickness of 60-80 mm.
- said insulation layer may preferably be designed as vacuum insulation and preferably comprise or consist of vacuum insulation panels.
- the second insulation layer has a thickness of 30-50 mm.
- the vacuum insulation panels have a porous core material as a support body for the vacuum present in the interior and a gas-tight envelope surrounding the core material, the core material preferably consisting of an aerogel, open-pore polyurethane or open-pore polyisocyanurate.
- the core material preferably consisting of an aerogel, open-pore polyurethane or open-pore polyisocyanurate.
- the advantage of these core materials over conventional fumed silica is their lower density, which can result in weight savings over conventional vacuum panels.
- the density of aerogel for example, is in the range 80-140 kg/m 3
- fumed silica typically has a density of 160-240 kg/m 3 , both materials having similar thermal conductivity properties in the range 2-6 mW/(m.K).
- the second insulation layer may have an outer wall, an inner wall spaced therefrom, and a vacuum chamber formed between the outer and inner walls, the vacuum chamber being a continuous vacuum chamber surrounding the loading space on all sides except for the opening.
- This insulation layer of the container wall is thus designed as a double-walled vacuum container which surrounds the loading space on all sides with the exception of the container opening.
- the insulation therefore does not consist of individual vacuum elements that have to be assembled to form an envelope, but instead encompasses in one piece all sides of the container with the exception of the opening.
- vacuum chamber means that the space between the inner and outer walls of the insulation layer is evacuated, thereby achieving thermal insulation by reducing or preventing heat conduction of the gas molecules through the vacuum.
- air pressure in the vacuum chamber is 0.001-0.1 mbar.
- the outer and inner walls consist of a metal sheet, in particular stainless steel, aluminum or titanium, and preferably have a thickness of 0.01 to 1 mm. This ensures on the one hand the required stability and on the other hand the gas-tight design of the walls.
- the inner wall of the insulation layer when arranged as the second insulation layer, can simultaneously form the energy distribution layer.
- the outer wall and the inner wall are preferably connected by a plurality of spacers, which are preferably made of a synthetic material with a thermal conductivity of ⁇ 0.35 W/(m ⁇ K), such as polyetheretherketone or aramid.
- the spacers ensure the desired distance between the outer and inner walls so that the intervening cavity, i.e., the vacuum chamber, remains. Since the spacers form thermal bridges, it is advantageous to form them from a material with the lowest possible thermal conductivity.
- a preferred further embodiment provides that a plurality of insulation foils lying at a distance above one another are arranged in the vacuum chamber, the foil plane of which runs essentially parallel to the plane of the outer and inner walls.
- the insulation foils are present in stacked form, with a foil stack preferably being arranged in each wall of the container wall and extending substantially over the entire wall.
- the insulation foils are arranged to surround the loading space on all sides except for the opening.
- the insulation foils are arranged in such a way that a space (protective space) remains between the inner surface of the outer wall or the inner wall facing the vacuum chamber and the foil stack in each case, so that the foil stack is not compressed by possible deformations of the walls.
- the space provides room for structural stabilization of the spacers and facilitates vacuuming.
- a further preferred embodiment provides that the insulation foils are held spaced apart from one another by planar spacer elements, the planar spacer elements preferably being formed by a textile sheet material, in particular being formed as a polyester nonwoven.
- the insulation foils can be designed as metal-coated or metal-vaporized plastic films. Such insulation foils are also referred to as superinsulation films.
- the metal coating is made of aluminum, for example.
- the door device can in this case consist of a layered structure corresponding to the layered structure of the container wall and comprising, from the outside to the inside, a first insulation layer, a second insulation layer and an energy distribution layer bounding the loading space and made of a material with a thermal conductivity of > 100 W/(m.K).
- the door device comprises at least one inner door leaf and at least one outer door leaf.
- the door leaves are hinged doors attached to the container by means of a hinge.
- the arrangement of at least one outer door leaf and at least one inner door leaf gives rise to a two-layer construction, in which the at least one outer door leaf preferably forms the first insulation layer of the door device and the at least one inner door leaf forms the second insulation layer of the door device, reference being made to the functions and properties described above in connection with the insulation layers of the container wall with respect to the properties and construction of the first and second insulation layers.
- the at least one outer door leaf and the at least one inner door leaf can preferably be opened and closed separately and independently of each other.
- the double-walled construction of the door device results in a temperature around 0°C (between -20°C and 8°C) on the outside of the at least one inner door leaf at an interior temperature of - 60°C to -80°C.
- This makes it possible to open the inner door leaf manually (i.e., without risk of cold burn) during operation.
- this effect is achieved by the at least one inner door leaf having a higher insulation performance (1 to 30 mW/(m.K)) than the at least one outer door leaf (4 to 300 mW/(m.K)).
- the door device comprises a single outer door leaf and two inner door leaves to form an inner double door.
- the at least one outer door leaf and the at least one inner door leaf are each sized to entirely cover the opening, including the coolant reservoir(s) and the barrier element.
- the loading space of the container remains at least partly closed by means of the barrier element, while the coolant reservoir, such as in the form of a drawer, can be pulled out of the loading space.
- containers When containers are carried by air, containers must allow pressure equalization between the loading space and the pressurized cabin of the aircraft, especially since the cabin pressure prevailing in the passenger cabin and the cargo hold is set lower than this corresponds to the ambient air pressure during takeoff and landing.
- containers are usually equipped with a valve or door seal that allows air to flow out of the loading space to the outside (during climb) or from the outside into the loading space (during descent) when a predetermined differential pressure between the environment and the loading space is exceeded. In the latter case, however, warm ambient air enters the loading space with the air flow, which has a significantly colder temperature compared to the surroundings, so that the temperature can fall below the dew point and water can condense from the air. The occurrence of condensate in the loading space is undesirable because it affects the transported goods.
- At least one inner circumferential seal is provided between the at least one inner door leaf and the opening of the container wall and at least one outer circumferential seal is provided between the at least one outer door leaf and the opening of the container wall, and that a buffer space is arranged between the at least one inner door leaf and the at least one outer door leaf.
- the double-walled door structure consisting of an inner and outer door leaf, together with the internal temperature of -60 to -80°C as described above, ensures that a temperature of around 0°C prevails on the outside of the inner door leaf, so that the buffer space formed in the intermediate space between the outer and inner door leaf is cooled. Due to the pre-cooling of the ambient air in the buffer space, drying also takes place, with any condensate occurring along the flow path of the air upstream of the loading space and in particular in the buffer space, but in any case not in the loading space itself.
- the inner and outer seals therefore preferably each comprise at least one sealing element which can be displaced by pressure difference and which opens a gas passage from the inside to the outside when a predetermined pressure difference is exceeded.
- the generation of CO 2 gas in the loading space can also compensate for a pressure equalization during descent, where otherwise an airflow from the outside into the loading space (during descent) would occur. This further reduces the risk of air ingress, including humidity, compared to using a non-sublimating coolant.
- the inner circumferential seal can be designed in such a way that it allows the CO 2 gas produced to escape, but at the same time largely prevents warm ambient air from flowing in. Together with the outer circumferential seal, this creates a labyrinth which, on the one hand, allows the CO 2 gas to escape and, on the other hand, ensures that the moisture of incoming air condenses on the outside of the at least one inner door leaf, which has a temperature of around 0°C (between -20°C and 8°C). This prevents the moisture in the air from penetrating into the loading space and the associated formation of ice.
- a preferred design of the thermal insulation provides that the at least one inner door leaf comprises an inner aluminum shell and an outer aluminum shell and that a vacuum thermal insulation, preferably vacuum insulation panels, is or are arranged between the inner and outer aluminum shells for their thermal decoupling.
- a vacuum thermal insulation preferably vacuum insulation panels
- 30-50 mm thick vacuum insulation panels can be used.
- the inner and outer aluminum shells can be held together with connecting elements made of low-heat-conducting, cold-resistant plastic (e.g. PEEK).
- the outer door leaf may be insulated with a 60-80 mm thick multi-layered structure of honeycomb thermoformed PET films coated on both sides with aluminum.
- the insulation of the outer door leaf can be further improved by inserting additional vacuum panels or partially replacing the existing insulation with vacuum panels. This reduces the heat input through the outer door leaf and therefore has a beneficial effect on the transit time of the container.
- the container or container wall can be of various geometric shapes, in which a plurality of walls adjacent to each other at an angle are provided.
- it is a cuboid container having six walls, of which the wall structure forms five walls and the door device forms the sixth wall.
- the container according to the invention is preferably designed as an air freight container and therefore preferably has external dimensions of at least 0.4x0.4x0.4 m, preferably 0.4x0.4x0.4 m 3 to 1.6 ⁇ 1.6 ⁇ 1.6 m 3 , preferably 1.0 ⁇ 1.0 ⁇ 1.0 m 3 to 1.6 ⁇ 1.6 ⁇ 1.6 m 3 .
- the first insulation layer of the container wall forms the outer surface of the container so that no other layers or elements are attached to the outer wall.
- another thermal insulation layer can be arranged on the outside of the first insulation layer, or a layer that protects the container from mechanical impact and damage.
- Dry ice is preferably used as a coolant.
- phase change materials are also possible. Common phase change materials based on kerosene or salt hydrate or other materials with high enthalpy are suitable as coolants.
- the target temperature that can be achieved in the loading space of the container depends on the selection of the coolant and is not limited to specific temperature ranges within the scope of the present invention. Therefore, the transport container can be operated not only in a range of -60 to -80°C, but also in a range of 25 to -15°C, for example.
- At least one temperature sensor is arranged in the loading space, and preferably at least one temperature sensor on each side of the container. Based on the measured values of the at least one temperature sensor, the performance of the insulation can be continuously monitored.
- a sensor can be arranged to measure the ambient temperature, whereby the insulation performance of the container wall can be continuously calculated from the temperature difference curve of the at least one temperature sensor arranged in the loading space and the external temperature sensor. This data can be continuously transmitted to a central database by wireless data transmission means, so that the functional efficiency of the container can be globally monitored and ensured.
- FIG. 1 shows a perspective view of a container according to the invention with the barrier element being unmounted
- Fig. 2 shows a cross section of the container of Fig. 1 with the doors being closed
- Fig. 3 shows a detailed view of region A of
- Fig. 2 shows the container of Fig. 1 with the barrier element being mounted und
- Fig. 5 shows a detailed view of the fixation of the barrier element to the container.
- Fig. 1 shows a cuboid container 1 whose container wall surrounds a loading space on all sides except for an opening.
- the container wall comprises two side walls, a rear wall, a bottom and a top wall.
- the container wall consists of multilayer insulation 2 and 3, an inner double door 4, an outer door 5, an energy distribution layer 6 forming the inner shell, drawers 7 with dry ice and a drawer guide 8, which are attached to the energy distribution layer 6 of the top wall.
- the insulation consists of an outer, first insulation layer 2 and an inner, second insulation layer 3.
- the first insulation layer has a thickness of, for example, 60-80 mm and consists of a multilayer structure of honeycomb-shaped deep-drawn PET films coated on both sides with aluminum. This achieves an insulation performance of the first insulation layer of 4 to 300 mW/(m.K).
- the second insulation layer 3 has a thickness of 30-50 mm and consists of a high-performance insulation, such as vacuum insulation panels (VIP) or aerogel, thus achieving an insulation performance of 1 to 30 mW/(m.K).
- the inner double door 4 can be attributed to the inner, second insulation layer 3 and the outer door 5 to the outer, first insulation layer 2.
- the inner double door 4 consists of an inner 13 and an outer aluminum half-shell 14, respectively, with the inner and outer shells being thermally decoupled.
- the decoupling is achieved with an inner insulation 3 made of a 30-50 mm thick high-performance insulation, such as vacuum panels, and connecting elements made of low-heat conducting, cold-resistant plastic 12 (e.g., PEEK).
- the outer door 5 is insulated with a 60-80 mm thick, multilayer structure of honeycomb deep-drawn PET films coated on both sides with aluminum.
- the combination of high insulation performance of the inner double door 4 (1 to 30 mW/(m.K)) and medium insulation performance of the outer door 5 (4 to 300 mW/(m.K)) results in a temperature of around 0°C (between - 20°C and 8°C) on the outside of the inner double door 4 at an interior temperature of -60°C to -80°C. This makes it possible to open the inner double door 4 manually (without risk of cold burns) during operation.
- Seals 10 are also located on the outer door so that, together with the inner door seal 11, a labyrinth is created which, on the one hand, allows the CO 2 gas that is generated to escape and, on the other hand, ensures that the moisture of incoming air condenses on the outside of the inner double door 4, which has a temperature around 0°C (between -20°C and 8°C). This prevents the moisture in the air from penetrating into the interior and the associated formation of ice.
- the energy distribution layer 6 consists, for example, of 0.5-5 mm thick aluminum plates. These have a thermal conductivity of about 150 W/(m.K), which distributes local heat inputs across the inner shell and results in a uniform temperature distribution in the loading space.
- the joints between the individual aluminum panels at the sides and corners are reinforced with rivets so that they can withstand the forces generated by thermal stresses.
- the drawers 7 as well as the drawer guides 8, which are attached to the top of the inner shell 6, are also made of 0.5-5 mm thick aluminum plates with a thermal conductivity of 150 W/(m.K).
- the dry ice 9 is introduced directly into the drawers.
- Fig. 4 shows the container 1 with a plate-like barrier element 15 being installed, in order to minimize heat exchange between the loading space and the environment when the inner doors 4 and the outer door 5 are open.
- the barrier element 15 covers essentially the entire area of the opening through which air could be exchanged between the loading space and the environment, but leaves the drawers 7 unobstructed.
- Handles 16 are arranged in order to facilitate manipulation of the barrier element 15.
- the barrier element 15 may be fixed to the container by means of a hook 18 that engages with a bearing element 17 arranged on the drawer guide 8 or a wall of the container.
- a hook 18 is arranged on each of the two lateral sides of the barrier element 15.
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- Combustion & Propulsion (AREA)
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- Mechanical Engineering (AREA)
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- General Engineering & Computer Science (AREA)
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Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22020321.0A EP4303506A1 (fr) | 2022-07-07 | 2022-07-07 | Conteneur destiné au transport de marchandises sensibles à la température |
PCT/IB2023/055079 WO2024009151A1 (fr) | 2022-07-07 | 2023-05-17 | Contenant pour le transport de marchandises sensibles à la température |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22020321.0A EP4303506A1 (fr) | 2022-07-07 | 2022-07-07 | Conteneur destiné au transport de marchandises sensibles à la température |
Publications (1)
Publication Number | Publication Date |
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EP4303506A1 true EP4303506A1 (fr) | 2024-01-10 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP22020321.0A Pending EP4303506A1 (fr) | 2022-07-07 | 2022-07-07 | Conteneur destiné au transport de marchandises sensibles à la température |
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EP (1) | EP4303506A1 (fr) |
WO (1) | WO2024009151A1 (fr) |
Citations (11)
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CZ20001109A3 (cs) * | 1998-09-09 | 2001-04-11 | Messer Griesheim Gmbh | Zařízení pro teplotně citlivé zboží |
WO2003035505A1 (fr) * | 2001-10-22 | 2003-05-01 | Langeland Oskar E | Procede et dispositif de transport avec qualite garantie |
US20100072211A1 (en) * | 2004-03-18 | 2010-03-25 | Eggs Overnight, Inc. | Reusable shipping container and method for using the same |
WO2011032299A1 (fr) | 2009-09-15 | 2011-03-24 | Nico Ros | Élément à structure alvéolaire |
GB2530077A (en) * | 2014-09-12 | 2016-03-16 | Peli Biothermal Ltd | Thermally insulated containers |
EP3051239A1 (fr) * | 2015-01-29 | 2016-08-03 | Air Liquide Deutschland GmbH | Procédé et conteneur polyvalent permettant de transporter des articles nécessitant différentes températures pendant leur transport |
WO2017072508A1 (fr) * | 2015-10-30 | 2017-05-04 | Tower Cold Chain Solutions Limited | Chariot de service en vol et contenant à isolation thermique pour un chariot de service en vol |
WO2018222645A1 (fr) * | 2017-05-31 | 2018-12-06 | Carrier Corporation | Dispositif à refroidissement actif pour distribution à petite échelle |
FR3076285A1 (fr) * | 2018-01-03 | 2019-07-05 | Sofrigam | Dispositif et procede pour garantir un releve de temperature fiable dans une caisse thermo-isolante. |
EP3921583A1 (fr) * | 2019-02-07 | 2021-12-15 | Rep Ip Ag | Contenant de transport |
US11359852B2 (en) * | 2015-08-04 | 2022-06-14 | Rep Ip Ag | Transport container for transporting temperature-sensitive transport goods |
-
2022
- 2022-07-07 EP EP22020321.0A patent/EP4303506A1/fr active Pending
-
2023
- 2023-05-17 WO PCT/IB2023/055079 patent/WO2024009151A1/fr active Search and Examination
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ20001109A3 (cs) * | 1998-09-09 | 2001-04-11 | Messer Griesheim Gmbh | Zařízení pro teplotně citlivé zboží |
WO2003035505A1 (fr) * | 2001-10-22 | 2003-05-01 | Langeland Oskar E | Procede et dispositif de transport avec qualite garantie |
US20100072211A1 (en) * | 2004-03-18 | 2010-03-25 | Eggs Overnight, Inc. | Reusable shipping container and method for using the same |
WO2011032299A1 (fr) | 2009-09-15 | 2011-03-24 | Nico Ros | Élément à structure alvéolaire |
GB2530077A (en) * | 2014-09-12 | 2016-03-16 | Peli Biothermal Ltd | Thermally insulated containers |
EP3051239A1 (fr) * | 2015-01-29 | 2016-08-03 | Air Liquide Deutschland GmbH | Procédé et conteneur polyvalent permettant de transporter des articles nécessitant différentes températures pendant leur transport |
US11359852B2 (en) * | 2015-08-04 | 2022-06-14 | Rep Ip Ag | Transport container for transporting temperature-sensitive transport goods |
WO2017072508A1 (fr) * | 2015-10-30 | 2017-05-04 | Tower Cold Chain Solutions Limited | Chariot de service en vol et contenant à isolation thermique pour un chariot de service en vol |
WO2018222645A1 (fr) * | 2017-05-31 | 2018-12-06 | Carrier Corporation | Dispositif à refroidissement actif pour distribution à petite échelle |
FR3076285A1 (fr) * | 2018-01-03 | 2019-07-05 | Sofrigam | Dispositif et procede pour garantir un releve de temperature fiable dans une caisse thermo-isolante. |
EP3921583A1 (fr) * | 2019-02-07 | 2021-12-15 | Rep Ip Ag | Contenant de transport |
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WO2024009151A1 (fr) | 2024-01-11 |
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