EP4243762A1 - Émulsion contenant de la gomme de ceratonia siliqua et des chlorhydrates d'aluminium - Google Patents
Émulsion contenant de la gomme de ceratonia siliqua et des chlorhydrates d'aluminiumInfo
- Publication number
- EP4243762A1 EP4243762A1 EP21798388.1A EP21798388A EP4243762A1 EP 4243762 A1 EP4243762 A1 EP 4243762A1 EP 21798388 A EP21798388 A EP 21798388A EP 4243762 A1 EP4243762 A1 EP 4243762A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- preparation
- polyglyceryl
- preparation according
- proportion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 title claims description 13
- 235000013912 Ceratonia siliqua Nutrition 0.000 title claims description 10
- 240000008886 Ceratonia siliqua Species 0.000 title claims description 10
- 235000017367 Guainella Nutrition 0.000 title claims description 10
- -1 aluminum chlorohydrates Chemical class 0.000 title description 4
- 238000002360 preparation method Methods 0.000 claims abstract description 89
- 239000002537 cosmetic Substances 0.000 claims abstract description 12
- 230000001166 anti-perspirative effect Effects 0.000 claims description 22
- 239000003213 antiperspirant Substances 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 239000004480 active ingredient Substances 0.000 claims description 15
- 239000003995 emulsifying agent Substances 0.000 claims description 14
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 claims description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- 229940045898 sodium stearoyl glutamate Drugs 0.000 claims description 9
- KDHFCTLPQJQDQI-BDQAORGHSA-M sodium;(4s)-4-amino-5-octadecanoyloxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC([O-])=O KDHFCTLPQJQDQI-BDQAORGHSA-M 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- NKEQOUMMGPBKMM-UHFFFAOYSA-N 2-hydroxy-2-[2-(2-hydroxy-3-octadecanoyloxypropoxy)-2-oxoethyl]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CC(O)(C(O)=O)CC(O)=O NKEQOUMMGPBKMM-UHFFFAOYSA-N 0.000 claims description 7
- 229920000223 polyglycerol Polymers 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 6
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- 150000003626 triacylglycerols Chemical class 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000012874 anionic emulsifier Substances 0.000 claims description 2
- 239000007764 o/w emulsion Substances 0.000 claims description 2
- 239000008406 cosmetic ingredient Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 23
- 235000019198 oils Nutrition 0.000 description 23
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 16
- 235000015112 vegetable and seed oil Nutrition 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- YCLAMANSVUJYPT-UHFFFAOYSA-L aluminum chloride hydroxide hydrate Chemical compound O.[OH-].[Al+3].[Cl-] YCLAMANSVUJYPT-UHFFFAOYSA-L 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000004471 Glycine Substances 0.000 description 6
- 125000005534 decanoate group Chemical class 0.000 description 6
- 239000002781 deodorant agent Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 210000004243 sweat Anatomy 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- 241000402754 Erythranthe moschata Species 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 229940105132 myristate Drugs 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 4
- 229940049964 oleate Drugs 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 4
- 239000000230 xanthan gum Substances 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- 235000010493 xanthan gum Nutrition 0.000 description 4
- 229940082509 xanthan gum Drugs 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 229940116224 behenate Drugs 0.000 description 3
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- 240000003133 Elaeis guineensis Species 0.000 description 2
- 235000001950 Elaeis guineensis Nutrition 0.000 description 2
- 239000001534 FEMA 4201 Substances 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229940053431 aluminum sesquichlorohydrate Drugs 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- 229920001222 biopolymer Polymers 0.000 description 2
- HQKQRXZEXPXXIG-VJOHVRBBSA-N chembl2333940 Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1[C@@](OC(C)=O)(C)CC2 HQKQRXZEXPXXIG-VJOHVRBBSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 235000008524 evening primrose extract Nutrition 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical compound C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000007931 macrolactones Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229940097941 polyglyceryl-10 laurate Drugs 0.000 description 2
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 2
- 229940066675 ricinoleate Drugs 0.000 description 2
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- 150000003890 succinate salts Chemical class 0.000 description 2
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 2
- VKTQADPEPIVMHK-UHFFFAOYSA-N (2-phenylphenyl)methanol Chemical compound OCC1=CC=CC=C1C1=CC=CC=C1 VKTQADPEPIVMHK-UHFFFAOYSA-N 0.000 description 1
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 description 1
- VSRVCSJJKWDZSH-UHFFFAOYSA-N (3-pentyloxan-4-yl) acetate Chemical compound CCCCCC1COCCC1OC(C)=O VSRVCSJJKWDZSH-UHFFFAOYSA-N 0.000 description 1
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- MTDAKBBUYMYKAR-SNVBAGLBSA-N (3r)-3,7-dimethyloct-6-enenitrile Chemical compound N#CC[C@H](C)CCC=C(C)C MTDAKBBUYMYKAR-SNVBAGLBSA-N 0.000 description 1
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- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000019498 Walnut oil Nutrition 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- JKRWZLOCPLZZEI-UHFFFAOYSA-N alpha-Trichloromethylbenzyl acetate Chemical compound CC(=O)OC(C(Cl)(Cl)Cl)C1=CC=CC=C1 JKRWZLOCPLZZEI-UHFFFAOYSA-N 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 description 1
- 229940062909 amyl salicylate Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000010478 argan oil Substances 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FZJUFJKVIYFBSY-UHFFFAOYSA-N bourgeonal Chemical compound CC(C)(C)C1=CC=C(CCC=O)C=C1 FZJUFJKVIYFBSY-UHFFFAOYSA-N 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000000828 canola oil Substances 0.000 description 1
- 235000019519 canola oil Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- BLBJUGKATXCWET-UHFFFAOYSA-N cyclaprop Chemical compound C12CC=CC2C2CC(OC(=O)CC)C1C2 BLBJUGKATXCWET-UHFFFAOYSA-N 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 229940045761 evening primrose extract Drugs 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000002532 grape seed extract Nutrition 0.000 description 1
- 239000008169 grapeseed oil Substances 0.000 description 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229930002839 ionone Natural products 0.000 description 1
- 150000002499 ionone derivatives Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- HEBMCVBCEDMUOF-UHFFFAOYSA-N isochromane Chemical compound C1=CC=C2COCCC2=C1 HEBMCVBCEDMUOF-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 229940061570 polyglyceryl-10 stearate Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000008171 pumpkin seed oil Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229940098760 steareth-2 Drugs 0.000 description 1
- 229940100458 steareth-21 Drugs 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 229940117960 vanillin Drugs 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
Definitions
- the invention belongs to the cosmetic field and relates to an antiperspirant cosmetic preparation which is present as an emulsion.
- cosmetic products not only serve to look beautiful and attractive, but with their effect they make a decisive contribution to increased self-esteem and the well-being of people. Accordingly, a wide variety of cosmetic products are used for the daily cleansing and care of the skin.
- deodorants and antiperspirants which are used under the armpits to prevent bad smells.
- the cause of bad odors is the decomposition of per se odorless sweat by bacteria. Fatty acid residues occur as a product of the decomposition, which characterize the typically known smell of sweat. Regardless of the fact that deodorants and antiperspirants are used on the same area of skin and have the same objective, they differ in their technical effect.
- Antiperspirants contain antiperspirant active ingredients that serve to impede and reduce the flow of sweat. Aluminum-containing antiperspirant active ingredients clog the sweat glands.
- Deodorants are characterized in that they do not prevent the flow of sweat. Instead, deodorants are products that contain special antimicrobial agents that reduce the growth of bacteria such as Corynebacterium jeikeium or Staphylococcus epidermidis. Consequently, the decomposition of the odorless sweat is reduced, so that less malodor occurs.
- antiperspirants and deodorants are applied to the skin either by means of an application roller or as a spray.
- Both propellant-operated aerosol sprays and those operated by means of a hand pump come as sprays Pump sprays used.
- the composition of the cosmetic preparations varies significantly.
- a known form of antiperspirant preparations for application using a roll-on applicator are (macro) emulsions.
- these usually contain emulsifiers which have at least one polyethylene glycol (PEG) subunit.
- PEG polyethylene glycol
- a popular emulsifier combination is Steareth-21 and Steareth-2.
- the emulsifiers serve to prevent phase separation of the oil and water phases of the emulsion.
- an aqueous phase and an oil phase a preparation is obtained which has a milky appearance. This appearance is particularly popular with consumers, since a white, creamy preparation is always associated with an increased care effect for the skin.
- Known formulations according to the above description result, inter alia, from EP 2023888 A1.
- polymers such as hydroxyethyl cellulose do not belong in the biopolymer category, as this is a chemically modified polymer.
- a well known biologically occurring polymer is xanthan gum.
- xanthan gum is unsuitable for PEG-free emulsions containing an aluminum-containing antiperspirant active ingredient, since precipitation occurs when used in combination in the preparations.
- the present invention was able to address the disadvantages of the prior art.
- the subject matter of the present invention is a cosmetic preparation in the form of an emulsion containing a) at least one aluminum-containing antiperspirant active ingredient, and b) Ceratonia Siliqua Gum, characterized in that the preparation is free from substances which have a polyethylene glycol subunit.
- Another object of the invention is the use of Ceratonia Siliqua Gum in a cosmetic preparation in the form of an emulsion containing an aluminum-containing antiperspirant active ingredient to stabilize the emulsion, the preparation being free of substances which have a polyethylene glycol subunit.
- stabilization is understood as preventing and/or reducing the formation of precipitates in the emulsion.
- normal conditions / normal conditions refers to 20 ° C, 1013 hPa and a relative humidity of 50%.
- skin refers exclusively to human skin. If viscosity values are given in this disclosure, then all values relate to a measurement at 25° C. in a 150 ml wide-mouth bottle (VWR No.: 807-001) using Rheomat R 123 from the company proRheo.
- the Rheomat R 123 from proRheo GmbH is a rotational viscometer, ie a measuring body rotates in the substance to be measured. The force required to rotate the measuring body in the sample at a specified speed is measured. The viscosity is calculated from this torque, the speed of the measuring body and the geometric dimensions of the measuring system used. Measuring body No. 1 (item no. 200 0191), suitable for a viscosity range of up to 10,000 [mPa s], speed range 62.5 rpm, is used as the measuring body.
- the preparation according to the invention was surprisingly able to eliminate or reduce the disadvantages of the prior art.
- no precipitation occurred with the mixture of Ceratonia Siliqua Gum with aluminum-containing antiperspirant active ingredient and a stable product could be provided in which a biopolymer is used as the polymer.
- the preparation of the present invention is advantageously characterized in that it is in the form of an oil-in-water emulsion.
- the preparation contains at least one aluminum-containing antiperspirant active ingredient.
- Examples of aluminum salts according to the invention are:
- Aluminum salts such as aluminum chloride AlC, aluminum sulphate Ah(SO4)3
- At least one aluminum zirconium salt is present as the antiperspirant active ingredient.
- These are advantageously selected from the group of aluminium/zirconium trichlorohydrex glycine ([Al4Zr(OH)i3Cls] x H2O x Gly), aluminium/zirconium tetrachlorohydrex glycine ([Al4Zr(OH)i2Cl4] x H2O x Gly), aluminium/zirconium pentachlorohydrex glycine ([Al8Zr(OH)2sCl5] x H2O x Gly), aluminum/zirconium octachlorohydrex glycine ([Al8Zr(OH)2oCls] x H2O x Gly) and the glycine-free aluminum/zirconium salts.
- Aluminum/zirconium tetrachlorohydrex glycine is particularly preferred.
- the proportion of the aluminum-containing antiperspirant active ingredient is advantageously from 2.5% by weight to 20% by weight, preferably from 5% by weight to 17.5% by weight and particularly preferably from 7.5% by weight to 15% by weight % by weight, based on the total weight of the preparation.
- the proportion of aluminum chlorohydrate is from 2.5% by weight to 20% by weight, preferably from 5% by weight to 17.5% by weight and particularly preferably from 7.5% by weight. is up to 15% by weight, based on the total weight of the preparation.
- the preparation according to the invention comprises Ceratonia Siliqua Gum. It is advantageous if the proportion of Ceratonia Siliqua Gum is from 0.1 to 1.0% by weight, preferably from 0.15 to 0.7% by weight and in particular 0.2 to 0.55% by weight. % is based on the total weight of the preparation.
- the preparation according to the invention preferably contains at least one emulsifier which has no polyethylene glycol subunit.
- a polyethylene glycol subunit consists of at least 2 consecutive ethylene glycol units.
- emulsifiers and/or emulsifier combinations enable effective stabilization of the preparations according to the invention. It was surprisingly found that the specific use of emulsifiers preferred according to the invention means that water does not separate out when stored at temperatures of 40° C. or occurs only later and/or the preparation does not become gritty when stored.
- anionic emulsifier it is advantageous if at least one anionic emulsifier is present as the emulsifier.
- anionic emulsifiers sodium stearoyl glutamate is particularly preferred. If sodium stearoyl glutamate is present, it is advantageous if the proportion of sodium stearoyl glutamate is from 0.1 to 4% by weight, preferably from 0.2 to 2.5% by weight and particularly preferably 0.3% by weight. % to 0.5% by weight, based on the total weight of the preparation.
- glyceryl stearate citrate is also included. If glyceryl stearate citrate is present, the proportion of glyceryl stearate citrate is advantageously from 0.5 to 6% by weight, preferably from 1.5 to 5% by weight and particularly preferably from 3.5 to 4.5% by weight. -% based on the total weight of the preparation.
- compositions according to the invention are advantageously characterized in that they contain no glyceryl stearate citrate.
- Another, even more advantageous combination of emulsifiers results from the combination of sodium stearoyl glutamate and methyl glucose sesquistearate.
- the proportion of methyl glucose sesquistearate is advantageously from 0.5 to 6% by weight, based on the total weight of the preparation.
- the proportion of methyl glucose sesquistearate is advantageously from 0.9 to 6% by weight, preferably from 2.8 to 5.5% by weight and particularly preferably from 3 .8 to 5.0% by weight, based on the total weight of the preparation.
- polyglyceryl esters are understood as meaning an ester which consists of
- Polyglycerol e.g. polyglycerol-10 and at least one fatty acid is formed.
- advantageous polyglycerol esters are polyglyceryl-10 caprate, polyglyceryl-10 laurate, polyglyceryl-10 trilaurate, polyglyceryl-10 myristate, polyglyceryl-10 dimyristate, polyglyceryl-10 oleate, polyglyceryl-10 diolate, polyglyceryl-10 stearate, polyglyceryl-10 distearate, polyglyceryl -10 Diisostearate, Polyglyceryl-6 Caprylate, Polyglyceryl-6 Dicaprylate, Polyglyceryl-6 Oleate, Polyglyceryl-6 Ricinoleate, Polyglyceryl-6 Stearate, Polyglyceryl-6 Behenate, Polyglyceryl-5 Laurate, Polyglyceryl-5 Myristate, Polyglyceryl-5 Oleate, Polyglyceryl -5 dioleates, polyglyceryl 5 stearates, polyglyceryl 4 caprates, polyglyceryl 3
- polyglyceryl ester or polyglyceryl esters are formed from a polyglycerol having 3 to 10 glycerol subunits and at least one fatty acid having 12 to 22 carbon atoms. It is particularly advantageous if the polyglyceryl ester or polyglyceryl esters are formed from a polyglycerol having 6 glycerol subunits and at least one fatty acid having 18 to 22 carbon atoms.
- Polyglyceryl-10 laurates, polyglyceryl-6 stearates and/or polyglyceryl-6 behenates are particularly preferred.
- the total proportion of polyglyceryl esters is advantageously from 0.5 to 8.0% by weight, preferably from 1.0 to 6.0% by weight and particularly preferably from 2.0 to 5.5% by weight, based on the total weight of the preparation.
- the total proportion of the polyglyceryl esters from a polyglycerol with 3 to 10 glycerol subunits and at least one fatty acid having 12 to 22 carbon atoms is advantageously from 0.5 to 8.0% by weight, preferably from 1.0 to 6.0% by weight particularly preferably from 2.0 to 5.5% by weight, based on the total weight of the preparation.
- the total proportion of the polyglyceryl esters selected from the group of polyglyceryl esters which are advantageous according to the invention is polyglyceryl-10 caprate, polyglyceryl-10 laurate, polyglyceryl-10 trilaurate, polyglyceryl-10 myristate, polyglyceryl-10 dimyristate, polyglyceryl-10 oleate, polyglyceryl-10 dioleate, polyglyceryl -10 stearates, polyglyceryl-10 distearates, polyglyceryl-10 diisostearate, polyglyceryl-6 caprylate, polyglyceryl-6 Dicaprylate, Polyglyceryl-6 Oleate, Polyglyceryl-6 Ricinoleate, Polyglyceryl-6 Stearate, Polyglyceryl-6 Behenate, Polyglyceryl-5 Laurate, Polyglyceryl-5 Myristate, Polyglyceryl-5 Oleate, Polyglyceryl-5 Dioleate, Polyglyceryl-5 Ste
- the total proportion of the polyglyceryl esters polyglyceryl-10 laurates, polyglyceryl-6 stearates and/or polyglyceryl-6 behenates is advantageously from 0.5 to 8.0% by weight, preferably from 1.0 to 6.0% by weight and in particular preferably from 3.0 to 5.5% by weight based on the total weight of the preparation.
- the weight ratio of polyglyceryl-6 stearate to polyglyceryl-6 behenate is from 99:1 to 70:30, particularly preferably from 98:1 to 80:20.
- the weight ratio of the one or more polyglycerol esters to methyl glucose sesquistearate is from 10:1 to 1:1 and in particular from 5:1 to 2:1.
- polyglyceryl-3 methylglucose distearate is present as an emulsifier. If polyglyceryl-3 methylglucose distearate is present, it is preferred if the proportion of polyglyceryl-3 methylglucose distearate is from 0.5 to 4% by weight, based on the total weight of the preparation.
- the proportion of sorbitan stearate is preferably from 0.2 to 3% by weight, more preferably from 0.7 to 1.5% by weight, based on the total weight of the preparation.
- the preparation according to the present invention comprises at least one oil component. It is preferred according to the invention if the preparation contains one or more oils in a total proportion of from 0.5 to 10% by weight, preferably from 1.0% by weight to 8% by weight and particularly preferably from 2.0 to 4% by weight, based on the total weight of the preparation. According to the invention, it is advantageous if at least one natural oil is contained as the oil component.
- the natural oils are advantageous selected from the group of sunflower oil (Helianthus Annuus Seed Oil), rapeseed oil (Canola Oil), soybean oil (Glycine Soya Oil), olive oil (Olea Europaea Fruit Oil), almond oil (Prunus amygdalus dulcis Oil), avocado oil (Persea gratissima oil), walnut oil (Junglans Regia Seed Oil), peach kernel oil (Prunus Persica Kernel Oil), apricot kernel oil (Prunus Armeniaca Kernel Oil), sesame oil (Sesamum Indicum Seed Oil), camellia oil (Camelia Oleifera/ Camelia Sasanqua), evening primrose oil (Oenothera biennis) , Macadamia Nut Oil (Macadamia Intergrifolia Seed Oil), Safflower Oil (Silybum Marianum Seed Oil), Wheat Germ Oil (Triticum Vulgare Germ Oil), Palm Kernel Oil (Elaeis guineensis Kerna), sunflower oil
- caprylic/capric triglycerides are present as the oil.
- caprylic/capric triglycerides have turned out to be surprisingly advantageous with regard to the prevention of water separation in the preparations according to the invention.
- the total proportion of caprylic/capric triglyceride in the preparation is preferably from 0.6 to 9.9% by weight, preferably from 1.1 to 7.9% by weight and particularly preferably from 2.1 to 5.9% by weight, based on the total weight of the preparation.
- dicaprylyl ether is contained as an oil. If dicaprylyl ether is present, it is advantageous if the proportion of dicaprylyl ether is from 0.6 to 9.9% by weight, preferably from 1.1 to 7.9% by weight and particularly preferably from 2.0 to 4.0% by weight, based on the total weight of the preparation.
- the preparation additionally contains at least one or more perfume substances which are liquid under normal conditions.
- perfumes are selected from essential oils, geraniol, geranyl acetate, linalool, linalyl acetate, tetrahydrolinalool, citronellol, citronellyl acetate, dihydromyrcenol, dihydromyrcenyl acetate, tetrahydromyrcenol, terpineol, terpinyl acetate, nopol, nopyl acetate, 2-phenyl benzyl alcohol, benzyl acetate, benzyl salicylate, benzyl benzoate, styrallyl acetate , amyl salicylate, dimethylbenzyl carbinol, trichloromethylphenylcarbinyl acetate, p-tert-butylcyclohexyl acetate, isononyl
- the proportion of perfume substances which are liquid under normal conditions is advantageously from 0.001 to 2.0% by weight, preferably from 0.005 to 1.5% by weight and particularly preferably from 0.01 to 1.0% by weight, based on the total weight the preparation.
- the preparation contains water, it being preferred if the proportion of water is from 60 to 88% by weight, particularly preferably 68 to 85% by weight, the figures relating to the total weight of the preparation relate.
- the preparation comprises glycerol, the proportion of glycerol advantageously being in the range from 0.5 to 12% by weight, preferably 2 to 11% by weight and particularly preferably in the range from 2.5 to 10.5% by weight, the figures relating to the total weight of the preparation.
- the preparations can contain further excipients. These can include dyes, deodorants or other ingredients.
- the preparation according to the invention is advantageously characterized in that it is free from xanthan gum.
- the preparation according to the invention is advantageously characterized in that it is free from polymers which are obtained from homopolymerization or copolymerization with acrylic acid.
- the preparation according to the invention is advantageously characterized in that it is free from hydroxyethyl celluse.
- the preparation according to the invention is advantageously characterized in that it is free from polyurea crosspolymer-2.
- the preparation can advantageously contain one or more fatty alcohols having 12 to 22 carbon atoms, it being further preferred if the proportion of fatty alcohols having 12 to 22 carbon atoms is from 0.5 to 3% by weight, based on the total weight of the preparation.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
L'invention concerne une préparation cosmétique contenant des ingrédients cosmétiques.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102020214353.6A DE102020214353A1 (de) | 2020-11-16 | 2020-11-16 | Emulsion enthaltend Ceratonia Siliqua Gum und Aluminium Chlorohydrate |
PCT/EP2021/079538 WO2022100994A1 (fr) | 2020-11-16 | 2021-10-25 | Émulsion contenant de la gomme de ceratonia siliqua et des chlorhydrates d'aluminium |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4243762A1 true EP4243762A1 (fr) | 2023-09-20 |
Family
ID=78372041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21798388.1A Pending EP4243762A1 (fr) | 2020-11-16 | 2021-10-25 | Émulsion contenant de la gomme de ceratonia siliqua et des chlorhydrates d'aluminium |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP4243762A1 (fr) |
DE (1) | DE102020214353A1 (fr) |
WO (1) | WO2022100994A1 (fr) |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU7789800A (en) * | 1999-10-22 | 2001-04-30 | Unilever Plc | Stable multiple emulsion composition |
DE102006020382A1 (de) | 2006-04-28 | 2007-10-31 | Henkel Kgaa | Schnell trocknende kosmetische Emulsionen zur Roll-on-Applikation |
DE102007030099A1 (de) | 2007-06-28 | 2009-01-02 | Henkel Ag & Co. Kgaa | Kosmetische Zusammensetzung enthaltend einen Champagner-Extrakt |
DE102008042149A1 (de) | 2008-09-17 | 2010-03-18 | Evonik Goldschmidt Gmbh | Kosmetische und dermatologische Formulierungen enthaltend Phenoxyalkylester |
DE102011089340A1 (de) | 2011-12-21 | 2013-06-27 | Henkel Ag & Co. Kgaa | PEG-freie Antitranspirant-Öl-in-Wasser-Emulsionen mit verbesserter Haptik |
DE102013220767A1 (de) | 2013-10-15 | 2015-04-16 | Henkel Ag & Co. Kgaa | Verwendung von Polysacchariden in schweißhemmenden kosmetischen Mitteln zur Textilschonung |
DE102015225958A1 (de) | 2015-12-18 | 2017-06-22 | Henkel Ag & Co. Kgaa | Kosmetische Mittel, enthaltend eine Kombination von mindestens zwei verschiedenen Wirkstoffen |
KR102060699B1 (ko) * | 2018-10-19 | 2019-12-30 | 주식회사 러브바드 | 신축성 마스크팩용 하이드로겔 조성물 및 이를 함유하는 신축성 마스크팩 |
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2020
- 2020-11-16 DE DE102020214353.6A patent/DE102020214353A1/de not_active Withdrawn
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2021
- 2021-10-25 WO PCT/EP2021/079538 patent/WO2022100994A1/fr unknown
- 2021-10-25 EP EP21798388.1A patent/EP4243762A1/fr active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2022100994A1 (fr) | 2022-05-19 |
DE102020214353A1 (de) | 2022-05-19 |
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