EP4221670A1 - Composition hydratante sans rinçage pour le démaquillage - Google Patents
Composition hydratante sans rinçage pour le démaquillageInfo
- Publication number
- EP4221670A1 EP4221670A1 EP21791203.9A EP21791203A EP4221670A1 EP 4221670 A1 EP4221670 A1 EP 4221670A1 EP 21791203 A EP21791203 A EP 21791203A EP 4221670 A1 EP4221670 A1 EP 4221670A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- peg
- dimethicone
- composition
- weight
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 159
- 230000000887 hydrating effect Effects 0.000 title claims abstract description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 41
- 239000003974 emollient agent Substances 0.000 claims abstract description 38
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 38
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 37
- 150000002148 esters Chemical class 0.000 claims abstract description 36
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 229940008099 dimethicone Drugs 0.000 claims description 61
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 61
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 61
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 61
- 229920006037 cross link polymer Polymers 0.000 claims description 29
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 19
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 16
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 claims description 14
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 11
- OQILCOQZDHPEAZ-UHFFFAOYSA-N Palmitinsaeure-octylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 claims description 11
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 claims description 11
- 229940099549 polyglycerin-3 Drugs 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 9
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 claims description 8
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 8
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 claims description 7
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 7
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 claims description 7
- 229940091554 lauryl peg-9 polydimethylsiloxyethyl dimethicone Drugs 0.000 claims description 7
- 229940088608 peg-9 polydimethylsiloxyethyl dimethicone Drugs 0.000 claims description 7
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 claims description 6
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 claims 4
- -1 actives Substances 0.000 abstract description 11
- 239000000654 additive Substances 0.000 abstract description 11
- 239000003205 fragrance Substances 0.000 abstract description 5
- 239000003755 preservative agent Substances 0.000 abstract description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 15
- 239000000463 material Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229940051250 hexylene glycol Drugs 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- 229940048081 trisodium ethylenediamine disuccinate Drugs 0.000 description 2
- QEHXDDFROMGLSP-VDBFCSKJSA-K trisodium;(2s)-2-[2-[[(1s)-1-carboxy-2-carboxylatoethyl]amino]ethylamino]butanedioate Chemical compound [Na+].[Na+].[Na+].OC(=O)C[C@@H](C([O-])=O)NCCN[C@H](C([O-])=O)CC([O-])=O QEHXDDFROMGLSP-VDBFCSKJSA-K 0.000 description 2
- 239000007762 w/o emulsion Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- JSOVGYMVTPPEND-UHFFFAOYSA-N 16-methylheptadecyl 2,2-dimethylpropanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C(C)(C)C JSOVGYMVTPPEND-UHFFFAOYSA-N 0.000 description 1
- NOFQKTWPZFUCOO-UHFFFAOYSA-N 2,2,4,4,6-pentamethylheptane Chemical compound CC(C)CC(C)(C)CC(C)(C)C NOFQKTWPZFUCOO-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- FOKDITTZHHDEHD-PFONDFGASA-N 2-ethylhexyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CC)CCCC FOKDITTZHHDEHD-PFONDFGASA-N 0.000 description 1
- LCVHZNSIAYNAGX-UHFFFAOYSA-N 2-ethylhexyl 3,5,5-trimethylhexanoate Chemical compound CCCCC(CC)COC(=O)CC(C)CC(C)(C)C LCVHZNSIAYNAGX-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- XEYIWOWYMLEPSD-UHFFFAOYSA-N 2-ethylhexyl decanoate Chemical compound CCCCCCCCCC(=O)OCC(CC)CCCC XEYIWOWYMLEPSD-UHFFFAOYSA-N 0.000 description 1
- LWLRMRFJCCMNML-UHFFFAOYSA-N 2-ethylhexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)CCCC LWLRMRFJCCMNML-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 description 1
- AMEMLELAMQEAIA-UHFFFAOYSA-N 6-(tert-butyl)thieno[3,2-d]pyrimidin-4(3H)-one Chemical compound N1C=NC(=O)C2=C1C=C(C(C)(C)C)S2 AMEMLELAMQEAIA-UHFFFAOYSA-N 0.000 description 1
- 244000144927 Aloe barbadensis Species 0.000 description 1
- 235000002961 Aloe barbadensis Nutrition 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 235000005940 Centaurea cyanus Nutrition 0.000 description 1
- 240000004385 Centaurea cyanus Species 0.000 description 1
- 235000007866 Chamaemelum nobile Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 244000042664 Matricaria chamomilla Species 0.000 description 1
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 1
- PVCJKHHOXFKFRP-UHFFFAOYSA-N N-acetylethanolamine Chemical compound CC(=O)NCCO PVCJKHHOXFKFRP-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229940093528 cetearyl ethylhexanoate Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940031578 diisopropyl adipate Drugs 0.000 description 1
- 229940031569 diisopropyl sebacate Drugs 0.000 description 1
- XFKBBSZEQRFVSL-UHFFFAOYSA-N dipropan-2-yl decanedioate Chemical compound CC(C)OC(=O)CCCCCCCCC(=O)OC(C)C XFKBBSZEQRFVSL-UHFFFAOYSA-N 0.000 description 1
- XJFGDLJQUJQUEI-UHFFFAOYSA-N dodecyl decanoate dodecyl octanoate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC.CCCCCCCCCCCCOC(=O)CCCCCCCCC XJFGDLJQUJQUEI-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229940100549 ethylhexyl isononanoate Drugs 0.000 description 1
- 229940095139 ethylhexyl laurate Drugs 0.000 description 1
- 229940096388 ethylhexyl oleate Drugs 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229960001031 glucose Drugs 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- 229940033357 isopropyl laurate Drugs 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- HRPZGPXWSVHWPB-UHFFFAOYSA-N octyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCCCCCC HRPZGPXWSVHWPB-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 239000008132 rose water Substances 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
Definitions
- This invention relates to a hydrating no-rinse makeup removal composition.
- a makeup removal composition comprising: i. at least one silicone-based emulsifier; ii. at least one branched, liquid alkane with carbon chain length of C12 to C20; iii. at least one emollient ester, ether, or carbonate with carbon chain length of C12 to C24; iv. at least one hydrating agent; and v. water.
- the composition may include more than one of each of the components.
- the composition may further include one or more additives including preservatives, actives, and fragrances.
- the at least one silicone-based emulsifier is present from about 0.5% to about 20%, by weight of the composition; ii. the at least one branched, liquid alkane is present from about 1 % to about 15% by weight of the composition; iii. the at least one emollient ester, ether, or carbonate is present from about 0.5% to about 10% by weight of the composition; iv. the at least one hydrating agent is present from about 10% to about 20% by weight of the composition; and v. water is present from about 60% to about 85% by weight of the composition.
- the at least one silicone-based emulsifier is chosen from dimethicone/PEG-10/15 crosspolymer, dimethicone/polyglycerin-3 crosspolymer, cetyl PEG/PPG-10/1 dimethicone, PEG-18/PPG-18 dimethicone, PEG-10 dimethicone, PEG/PPG-18/18 methicone, lauryl PEG/PPG-18/18 methicone, PEG-9 polydimethylsiloxyethyl dimethicone, and lauryl PEG-9 polydimethylsiloxyethyl dimethicone, and combinations thereof; ii.
- the at least one branched, liquid alkane has a carbon chain length of C12 to C20; iii. the at least one emollient ester, ether, or carbonate has a carbon chain length of C12 to C24 and comprises a dialkylated ether or dialkylated carbonate; and iv. the at least one hydrating agent comprises a polyol.
- the at least one silicone-based emulsifier comprises dimethicone/PEG-10/15 crosspolymer, dimethicone/polyglycerin-3 crosspolymer, cetyl PEG/PPG-10/1 dimethicone, or PEG-18/PPG-
- the at least one branched, liquid alkane has a carbon chain length of C12 to C20 and comprises isohexadecane, isododecane, CI S-
- the at least one emollient ester, ether, or carbonate has a carbon chain length of C12 to C24 and comprises isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, dicaprylyl ether, dicaprylyl carbonate, or a combination thereof;
- the at least one hydrating agent comprises glycerin.
- the at least one silicone-based emulsifier comprises dimethicone/PEG-10/15 crosspolymer; ii. the at least one branched, liquid alkane with carbon chain length of C12 to C20 comprises isododecane or C15-19 alkane; iii.
- the at least one emollient ester, ether, or carbonate with carbon chain length of C12 to C24 comprises isopropyl palmitate, ethylhexyl palmitate, dicaprylyl ether, dicaprylyl carbonate, a combination of isopropyl palmitate and dicaprylyl ether, or a combination of isopropyl palmitate and dicaprylyl carbonate; and iv. the at least one hydrating agent comprises glycerin.
- the at least one silicone-based emulsifier comprises dimethicone/PEG-10/15 crosspolymer and PEG-10 dimethicone; ii. the at least one branched, liquid alkane with carbon chain length of C12 to C20 comprises isohexadecane; iii. the at least one emollient ester, ether, or carbonate with carbon chain length of C12 to C24 comprises one of isopropyl palmitate, and ethylhexyl palmitate; and iv. the at least one hydrating agent comprises glycerin.
- the composition comprises at least two silicone-based emulsifiers, each present in the composition from about 0.1 % to about 20%, by weight of the composition.
- the at least two silicone-based emulsifiers are chosen from dimethicone/PEG-10/15 crosspolymer, dimethicone/polyglycerin-3 crosspolymer, cetyl PEG/PPG-10/1 dimethicone, PEG-18/PPG-18 dimethicone, PEG-10 dimethicone, PEG/PPG-18/18 methicone, lauryl PEG/PPG-18/18 methicone, PEG-9 polydimethylsiloxyethyl dimethicone, and lauryl PEG-9 polydimethylsiloxyethyl dimethicone, and combinations thereof.
- the composition comprises at least one additive. In some embodiments, the at least one additive is present up to about 0.5% by weight of the composition.
- FIG 1 is a data plot in the form of a 2D graph that shows the makeup removal efficacy of inventive compositions according to the disclosure and comparative compositions.
- Cosmetically acceptable means a carrier that is compatible with any keratinous substrate.
- Keratinous substrate and “keratinous tissue” each includes but is not limited to skin, hair, and nails.
- the composition according to the disclosure includes at least one of each of a silicone-based emulsifier, a branched, liquid alkane with carbon chain length of C12 to C20, an emollient ester, ether, or carbonate with carbon chain length of C12 to C24, a hydrating agent, and water.
- the composition may further include one or more additives including preservatives, actives, and fragrances.
- the composition according to the disclosure is a water-in-oil (as exemplified herein, a silicone oil) emulsion.
- a water-in-oil emulsion is sometimes referred to as a reverse emulsion in comparison with the more common type of oil-in-water emulsion skin cleanser formulations.
- the composition has a cream-gel texture that demonstrates medium to long playtime, providing a pleasant feel when applied and does not immediately absorb into the skin or evaporate. Upon massaging onto the face, the composition demonstrates effective dissolving of eye, face and lip makeup. Using a tissue or a cotton round allows the user to gently wipe away the dissolved makeup products. The composition does not require rinsing after application and leaves the skin with a silky and hydrated feel that is not greasy or sticky.
- the inventive composition overcomes the shortcomings of the prior art and provide unexpected benefits that include ease with overall makeup removal and easy foundation removal and easy mascara removal (regular and waterproof) with no rubbing, with overall improved efficacy as compared with commercial comparative compositions, leaves skin feeling clean and fresh, soft and smooth, is non-greasy and does not leave a residue, has a pleasant fragrance.
- exemplified embodiments of the composition according to the disclosure demonstrated significantly better performance in removing both mascara (including waterproof mascara) and long- wear foundation as compared with currently marketed MURs.
- the exemplified embodiments of the inventive composition according to the disclosure not only performed better in makeup removal efficacy, including improved performance in the removal of both mascara and foundation, they also provided an experience that was more pleasing and resulted in comparatively better skin feel after use.
- embodiments of the composition include at least one silicone-based emulsifier.
- the composition comprises more than one silicone-based emulsifier.
- the composition includes two or more silicone-based emulsifiers, wherein the two silicone-based emulsifiers may differ from one another in that one emulsifier has a greater chemical molecular weight than the other emulsifier.
- suitable silicone-based emulsifiers may be chosen from silicone emulsifiers that include functional groups chosen from polyglyceryl, polyethylene glycol, or polypropylene glycol, wherein such silicone-based emulsifiers may be chosen from dimethicone/PEG-10/15 crosspolymer, dimethicone/polyglycerin-3 crosspolymer, polyether-modified crosslinked silicone polymers in dimethicone, including, for example, but not limited to PEG-15/lauryl polydimethylsiloxyethyl dimethicone crosspolymer.
- suitable silicone-based emulsifiers may be chosen from alkyldimethicone copolyol type and dimethicone copolyol type silicone emulsifiers.
- the at least one silicone-based emulsifier may be chosen from dimethicone/PEG-10/15 crosspolymer, dimethicone/polyglycerin-3 crosspolymer, cetyl PEG/PPG-10/1 dimethicone, PEG-18/PPG-18 dimethicone, PEG-10 dimethicone, PEG/PPG-18/18 methicone, lauryl PEG/PPG-18/18 methicone, PEG-9 polydimethylsiloxyethyl dimethicone, and lauryl PEG-9 polydimethylsiloxyethyl dimethicone, and combinations thereof.
- the composition comprises a silicone-based emulsifier comprising dimethicone/PEG-10/15 crosspolymer, alone or in combination with PEG-10 dimethicone.
- each of the at least one silicone-based emulsifier is present in the composition at a concentration, from about 0.1 % to about 20%, and in some embodiments, from about 0.2% to about 15%, and in some embodiments, from about 0.3% to about 10%, and in some embodiments, from about 1 % to about 5%, and in some embodiments, from about 2% to about 4%, or any suitable combination, subcombination, range, or sub-range thereof by weight, based on the weight of the composition.
- the composition comprises more than one silicone- based emulsifier, the combination thereof present in the composition at a concentration, from about 0.2% to about 20%, and each of the more than one present in the composition at a concentration from about 0.1 % to about 20%, or any suitable combination, subcombination, range, or sub-range thereof by weight, based on the weight of the composition.
- silicone- based emulsifier the combination thereof present in the composition at a concentration, from about 0.2% to about 20%
- each of the more than one present in the composition at a concentration from about 0.1 % to about 20%, or any suitable combination, subcombination, range, or sub-range thereof by weight, based on the weight of the composition.
- a silicone-based emulsifier comprising dimethicone/PEG-10/15 crosspolymer may be present in the composition in a range from about 1 % to about 4% or at about 3% together with PEG-10 dimethicone present in the composition in a range from about 0.1 % to about 0.5% or at about 0.2%.
- each of the at least one silicone-based emulsifier is present in a composition according to the disclosure from about 0.1 , 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1 , 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 , 12, 13, 14, 15, 16, 17, 18, 19 to about 20 percent by weight, including increments and ranges there between.
- embodiments of the composition include at least one branched, liquid alkane.
- the composition comprises more than one branched, liquid alkane.
- the branched, liquid alkane has a carbon chain length of C12 to C20.
- the branched, liquid alkane has a carbon chain length of C12 to C20.
- the branched, liquid alkane may be chosen from those with a carbon chain length of from C12 to C20, from C13-C15, from C15 to C19, and C12, C13, C14, C15, C16, C17, C18, C19 and C20.
- the branched, liquid alkane may be chosen from isoparaffins, for instance isododecane (also known as 2,2,4,4,6-pentamethylheptane), isodecane, C15-19 alkane, and isohexadecane.
- the at least one branched, liquid alkane comprises isohexadecane.
- the at least one branched, liquid alkane is present in the composition at a concentration, from about 1 % to about 15%, and in some embodiments, from about 2% to about 10% , and in some embodiments, from about 2% to about 5% or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the weight of the composition.
- the composition comprises more than one branched, liquid alkane, the combination thereof present in the composition at a concentration, from about 5% to about 10%, and each of the more than one present in the composition at a concentration from about 2% to about 5% or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the weight of the composition.
- each of the at least one branched, liquid alkane is present in a composition according to the disclosure from about 1 , 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 , 12, 13, 14 to about 15 percent, by weight, including increments and ranges therein and there between.
- embodiments of the composition include at least one emollient ester, ether, or carbonate.
- the composition comprises more than one emollient ester, ether, or carbonate.
- the emollient ester, ether, or carbonate has a carbon chain length of C12 to C24.
- the at least one emollient ester is an alkylated alcohol ester.
- suitable emollient ester, ether, or carbonates may be chosen from isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, methyl palmitate, 2-ethylhexyl palmitate, hexyl laurate, ethylhexyl laurate, isopropyl laurate, ethylhexyl oleate, ethylhexyl isononanoate, isononyl isononanoate, myristyl myristate, 2-ethylhexyl caprate/caprylate (or octyl caprate/caprylate), isostearyl neopentanoate, cetearyl ethylhexanoate, isopropyl isostearate, diisopropyl sebacate, coco caprylate/ caprate, diis
- the at least one emollient ester, ether or carbonate is selected from ethylhexyl palmitate, isopropyl palmitate, dicaprylyl ether, dicaprylyl carbonate, isopropyl myristate and combinations thereof.
- the emollient ester, ether, or carbonate is an emollient ester comprising esters of lactic acid and fatty alcohols and comprising 12 or 13 carbon atoms, and combinations thereof.
- the at least one emollient ester, ether, or carbonate branched is an alkylated alcohol ester.
- the composition comprises two or more branched, alkylated alcohol esters.
- the at least one branched, alkylated alcohol ester comprises isopropyl myristate and optionally one or more additional branched, alkylated alcohol ester.
- the composition comprises one or a combination of ethylhexyl palmitate, isopropyl palmitate, dicaprylyl ether, dicaprylyl carbonate and isopropyl myristate. In some particular embodiments, the composition comprises only one of ethylhexyl palmitate, isopropyl palmitate, dicaprylyl ether, or dicaprylyl carbonate, or a combination of isopropyl palmitate with one of dicaprylyl ether and dicaprylyl carbonate.
- the at least one emollient ester, ether, or carbonate is present from about 0.5% to about 10% by weight of the composition, and in some embodiments, from about 0.8% to about 8%, and in some embodiments, from about 1 % to about 7%, and in some embodiments, from about 2% to about 5%, and in some embodiments, about 5% or about 2%, or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the weight of the composition.
- the composition comprises more than one emollient ester, ether, or carbonate, the combination thereof present in the composition at a concentration, from about 1 % to about 20%, and each of the more than one present in the composition at a concentration from about 0.5% to about 10%, or any suitable combination, subcombination, range, or sub-range thereof by weight, based on the weight of the composition.
- emollient ester, ether, or carbonate the combination thereof present in the composition at a concentration, from about 1 % to about 20%, and each of the more than one present in the composition at a concentration from about 0.5% to about 10%, or any suitable combination, subcombination, range, or sub-range thereof by weight, based on the weight of the composition.
- each one or a combination of the at least one emollient ester, ether, or carbonate is present in a composition according to the disclosure from about 0.5, 0.6. 0.7, 0.8, 0.9, 1 , 2, 3, 4, 5, 6, 7, 8, 9,10, 11 , 12, 13, 14, 15, 16, 17, 18, 19, to about 20 percent, by weight, including increments and ranges therein and there between.
- compositions include at least one hydrating agent.
- the composition comprises more than one hydrating agent.
- the hydrating agent may be a polyol.
- suitable hydrating agents may be chosen one or more of polyols, including, for example, glycerin, glycerol, glycols, such as caprylyl glycol, butylene glycol, propylene glycol, isoprene glycol, dipropylene glycol, hexylene glycol and polyethylene glycols, monoethylene glycol, diethylene glycol, diethylene glycol, diethylene glycol, hexylene glycol; glycol ethers such as monopropylene, dipropylene and tripropylene glycol alkyl(C1 -C4)ethers; squalane; triacetin; sugars, such as glucose, xylitol, maltitol, sorbitol, sucrose pentaerythritol, inositol; pyrrolidone carboxylic acid (PCA); lactic acid; lithium chloride; acetamide MEA; sodium lac
- the hydrating agent comprises glycerin.
- the at least one hydrating agent is present from about 5% to about 30% by weight of the composition, and in some embodiments, from about 5% to about 25%, and in some embodiments, from about 10% to about 20%, and in some embodiments, about 15%, or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the weight of the composition.
- the composition comprises more than one hydrating agent, the combination thereof present in the composition at a concentration, from about 5% to about 30%, and each of the more than one present in the composition at a concentration from about 5% to about 25%, and in some embodiments, about 15% or any suitable combination, sub-combination, range, or sub-range thereof, by weight, based on the weight of the composition.
- hydrating agent the combination thereof present in the composition at a concentration, from about 5% to about 30%, and each of the more than one present in the composition at a concentration from about 5% to about 25%, and in some embodiments, about 15% or any suitable combination, sub-combination, range, or sub-range thereof, by weight, based on the weight of the composition.
- each of the at least one emollient ester, ether, or carbonate is present in a composition according to the disclosure from about 5, 6, 7, 8, 9, 10, 11 , 12,13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, to about 30 percent, by weight, including increments and ranges therein and there between.
- water is present in the compositions in a range from about 60% to about 85%, and in some embodiments, from about 65% to about 85%, and in some embodiments, from about 65% to about 75%, and in some embodiments, from about 66% to about 72%, and in some embodiments, about 68% or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the weight of the composition.
- a range from about 60% to about 85%, and in some embodiments, from about 65% to about 85%, and in some embodiments, from about 65% to about 75%, and in some embodiments, from about 66% to about 72%, and in some embodiments, about 68% or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the weight of the composition.
- water is present, by weight, based on the total weight of the composition, from about 60, 61 , 62, 63, 64, 65, 66, 67, 68, 69, 70, 71 , 72, 73, 74, 75, 76, 77, 78, 79, 80, 81 , 82, 83, 84, to about 85 percent, by weight, including increments and ranges therein and there between.
- ranges are within the scope of the invention.
- the water used may be sterile demineralized water and/or a floral water such as rose water, cornflower water, chamomile water or lime water, and/or a natural thermal or mineral water such as, for example: water from Vittel, water from the Vichy basin, water from llriage, water from La Roche Posay, water from La Bourboule, water from Enghien-les-Bains, water from Saint Gervais-les-Bains, water from Neris-les-Bains, water from Allevar-les-Bains, water from Digne, water from Maizieres, water from Neyrac-les-Bains, water from Lons-le-Saunier, water from Eaux Bonnes, water from Rochefort, water from Saint Christau, water from Les Fumades, water from Tercis-les- Bains or water from Avene.
- the water phase may also comprise reconstituted thermal water, that is to say a water comprising trace elements such as zinc, copper, magnesium, etc., reconstituting the characteristics of
- the pH of the composition may be adjusted prior to combining the oil phase with the water phase to avoid the practical difficulty with measuring pH in an internal water phase of the water-in-oil emulsion. Accordingly, the pH of the water phase prior to emulsification can be adjusted with pH adjusters to a pH in a range from about 2 to about 12, and in some embodiments, is from about 3 to about 11 , and from about 4 to about 9, and from about 5 to about 8, and in some embodiments about 5.5.
- the pH of the water phase can be adjusted by addition of a base (organic or inorganic) to the composition, for example ammonia or a primary, secondary or tertiary (poly)amine, such as monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or 1 ,3- propanediamine, or alternatively by addition of an inorganic or organic acid, advantageously a carboxylic acid, such as, for example, citric acid.
- a base organic or inorganic
- a primary, secondary or tertiary (poly)amine such as monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or 1 ,3- propanediamine
- an inorganic or organic acid advantageously a carboxylic acid, such as, for example, citric acid.
- compositions may also comprise at least one additive used in the cosmetics field which does not affect the properties of the compositions according to the invention, such as fragrances, preservatives/anti-microbials (for example, potassium sorbate, and caprylyl glycol); actives (for example, hydroxyacetophenone, vitamins, panthenol, tocopherol); coloring materials; essential oils; citric acid, sodium citrate, sodium chloride; neutralizing, chelating or pH-adjusting agents (for example, triethylamine (TEA), trisodium ethylenediamine disuccinate, and sodium hydroxide), and combinations thereof.
- fragrances for example, preservatives/anti-microbials (for example, potassium sorbate, and caprylyl glycol); actives (for example, hydroxyacetophenone, vitamins, panthenol, tocopherol); coloring materials; essential oils; citric acid, sodium citrate, sodium chloride; neutralizing, chelating or pH-adjusting agents (for example, triethylamine (
- the composition may include optional additives selected chose from sodium citrate, sodium chloride, hydroxyacetophenone sodium benzoate, potassium sorbate, citric acid, caprylyl glycol, and trisodium ethylenediamine disuccinate, and combinations thereof.
- the amount of one or more actives and additives, alone or in combination, when present in the composition according to the disclosure can be present in a range from about 0.0001 % to about 20%, and in some embodiments, from about 0.005% to about 0.01 %, and in some embodiments, from about 0.01 % to about 0.1 %, and in some embodiments, from about 0.15% to about 5%, and in some embodiments, from about 0.40% to about 4%, and in some embodiments, from about 0.5% to about 2.5%, and in some embodiments, from about 0.1 % to about 0.5%and in some embodiments, from about 1 % to about 2%, or any suitable combination, sub-combination, range, or sub-range thereof by weight, based on the total weight of the composition.
- One of ordinary skill in the art will appreciate that other ranges are within the scope of the invention.
- any one or a combination of actives and additives may be present, each one or the combination present from about 0.0001 , 0.0005, 0.001 , 0.002, 0.003, 0.004, 0.005, 0.006, 0.007, 0.008, 0.009, 0.01 , 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.10, 0.20, 0.30, 0.40, 0.50, 0.60, 0.70, 0.80, 0.90, 1.0, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 , 12, 13, 14, 15, 16, 17, 18, 19 to about 20 percent, by weight, including increments and ranges therein and there between.
- Table 3 Comparative Composition 2 - Lancome Galateis Douceur (Gentle Cleanser for Face and Eyes), a commercially available emulsion (cream)-based makeup removing product
- the aesthetician removed the makeup with test products (inventive and comparative), using 3 cotton rounds each soaked with 2 ml of the test composition for mascara removal, and using 2 cotton rounds each soaked with 2 ml of the test composition for foundation removal.
- the degree of removal was assessed by the amount of residual makeup that was removed by using Lancome (TM) Bi-Facil (TM) Makeup Remover (a two-phase make-up removal product), 2 mL on a cotton pad for up to 4 cotton pads.
- TM Lancome
- TM Bi-Facil
- Makeup Remover a two-phase make-up removal product
- the makeup removal efficacy data was plotted using a 2D graph, shown as FIG. 1 ; the data as shown in FIG. 1 are represented in Table 7.
- the inventive compositions each fall within the “most effective MUR” category for removing stubborn makeup products. This is the same category of Lancome Bi-Facil, compared to which the inventive compositions lack a greasy after-feel typically found with use of Bi-Facil.
- the disclosure has been described with reference to described embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the disclosure. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the disclosure without departing from the essential scope thereof. Therefore, it is intended that the disclosure is not limited to the particular embodiment disclosed as the best mode contemplated for carrying out this disclosure, but that the disclosure will include all embodiments falling within the scope of the appended claims.
- At least one means one or more and thus includes individual components as well as mixtures/combinations.
- the terms “free” and “devoid” indicates that no reliably measurable excluded material is present in the composition, typically 0% by weight, based on the total weight of the composition.
- the term “essentially free” means that, while it prefers that no excluded material is present in the composition, it is possible to have very small amounts of the excluded material in the composition of the invention, provided that these amounts do not materially affect the advantageous properties of the composition.
- “essentially free” means that excluded material can be present in the composition at an amount of less than about 0.1 % by weight, based on the total weight of the composition.
- weight or amount as used herein with respect to the percent amount of an ingredient refers to the amount of the raw material comprising the ingredient, wherein the raw material may be described herein to comprise less than and up to 100% activity of the ingredient. Therefore, weight percent of an active in a composition is represented as the amount of raw material containing the active that is used, and may or may not reflect the final percentage of the active, wherein the final percentage of the active is dependent on the weight percent of active in the raw material.
- weight percent and “wt%” may be used interchangeably and mean percent by weight, based on the total weight of a composition, article or material, except as may be specified with respect to, for example, a phase, or a system that is a component of a composition, article or material. All ranges and amounts given herein are intended to include subranges and amounts using any disclosed point as an end point. Thus, a range of “1 % to 10%, such as 2% to 8%, such as 3% to 5%,” is intended to encompass ranges of “1 % to 8%,” “1 % to 5%,” “2% to 10%,” and so on.
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Abstract
Une composition de démaquillage comprend au moins l'un de chacun des éléments suivants : un émulsifiant à base de silicone, un alcane liquide ramifié, un ester émollient, un éther ou un carbonate, un agent hydratant et de l'eau. Dans certains modes de réalisation, la composition peut en outre comprendre un ou plusieurs additifs comprenant des conservateurs, des principes actifs et des parfums.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17/038,943 US20220096357A1 (en) | 2020-09-30 | 2020-09-30 | Hydrating no-rinse composition for makeup removal |
FR2013074A FR3117364B1 (fr) | 2020-12-11 | 2020-12-11 | Composition hydratante sans rinçage pour le démaquillage |
PCT/US2021/052764 WO2022072571A1 (fr) | 2020-09-30 | 2021-09-30 | Composition hydratante sans rinçage pour le démaquillage |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4221670A1 true EP4221670A1 (fr) | 2023-08-09 |
Family
ID=78135221
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21791203.9A Pending EP4221670A1 (fr) | 2020-09-30 | 2021-09-30 | Composition hydratante sans rinçage pour le démaquillage |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP4221670A1 (fr) |
JP (1) | JP2023543589A (fr) |
CN (1) | CN116322611A (fr) |
WO (1) | WO2022072571A1 (fr) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2789307B1 (fr) * | 1999-02-08 | 2001-03-09 | Oreal | Composition cosmetique de demaquillage et/ou de nettoyage sous forme d'emulsion eau-dans-huile |
FR2834916B1 (fr) * | 2002-01-24 | 2004-10-08 | Oreal | Stick demaquillant gelifie par un polymere semi-cristallin |
FR2881342B1 (fr) * | 2005-01-31 | 2007-03-02 | Oreal | Composition demaquillante |
-
2021
- 2021-09-30 EP EP21791203.9A patent/EP4221670A1/fr active Pending
- 2021-09-30 JP JP2023519396A patent/JP2023543589A/ja active Pending
- 2021-09-30 CN CN202180066853.3A patent/CN116322611A/zh active Pending
- 2021-09-30 WO PCT/US2021/052764 patent/WO2022072571A1/fr unknown
Also Published As
Publication number | Publication date |
---|---|
CN116322611A (zh) | 2023-06-23 |
WO2022072571A1 (fr) | 2022-04-07 |
JP2023543589A (ja) | 2023-10-17 |
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