EP4189050B1 - Zusammensetzung für kerze - Google Patents

Zusammensetzung für kerze Download PDF

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Publication number
EP4189050B1
EP4189050B1 EP21749866.6A EP21749866A EP4189050B1 EP 4189050 B1 EP4189050 B1 EP 4189050B1 EP 21749866 A EP21749866 A EP 21749866A EP 4189050 B1 EP4189050 B1 EP 4189050B1
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EP
European Patent Office
Prior art keywords
composition
wax
oil
group
set forth
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EP21749866.6A
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English (en)
French (fr)
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EP4189050A1 (de
Inventor
Thierry Bernoud
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Biosynthis SARL
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Biosynthis SARL
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C5/00Candles
    • C11C5/002Ingredients

Definitions

  • the present invention relates to a bio-sourced composition for the manufacture of candles.
  • soybean wax was made from mixtures of soybean oil and beeswax or a mixture of coconut, palm and soybean oil....
  • liquid oils made it possible to no longer be dependent on concrete oils such as coconut (copra) or palm and palm kernel oils and to obtain "solid” oils capable of being used in the composition of candles.
  • compositions comprising palm oil and fatty alcohols have been described to address known flow and surface problems of palm oil-based candles.
  • compositions of renewable (bio-based) waxes are disclosed.
  • the composition of these candles comprises a fatty alcohol and according to another embodiment may comprise a fatty alcohol and a "vegetable-based wax".
  • the compositions described are free of alkanes, they all comprise ingredients derived from palm oil.
  • the fatty alcohols are derived from palmitic fatty acids and the majority of the compositions comprise palm "waxes" which are not clearly defined.
  • the aspects of certain compositions described seem to constitute counter-examples such as for example the "greasy and semi-transparent" aspect which cannot be the expected aspect.
  • the present invention makes it possible to solve all of the problems mentioned above and in particular both the problems of appearance of fragility and combustion and makes it possible to obtain candles comprising only completely bio-sourced ingredients and free of palm oil having performances at least equal to those obtained with waxes of mineral or animal origin and making it possible to comply with the standards EN15426, RAL GZ-041 EU Reach and ASTM title 16.
  • composition according to the invention is characterized in that it is free of palm oil.
  • the composition according to the invention is characterized in that the at least one fatty alcohol has a carbon number greater than or equal to 16.
  • the composition according to the invention is characterized in that it is free of palm oil and in that the at least one fatty alcohol has a carbon number greater than or equal to 16.
  • the composition according to the invention is characterized in that it is free of fatty alcohol.
  • the composition according to the invention is characterized in that it is free of palm oil and fatty alcohol.
  • the composition according to the invention is characterized in that its melting point is between 45 and 55°C.
  • the composition according to the invention is characterized in that its melting point is between 46 and 52°C.
  • composition according to the invention is characterized in that it further comprises from 0 to 60% of at least one non-hydrogenated vegetable oil.
  • composition according to the invention is characterized in that it further comprises from 0 to 60% of at least one completely hydrogenated vegetable oil.
  • the composition according to the invention is characterized in that it comprises a mixture of vegetable oils of which at least one is at least partially hydrogenated and at least the other is not hydrogenated.
  • the composition according to the invention is characterized in that it comprises a mixture of vegetable oils of which at least one is completely hydrogenated and at least the other is not hydrogenated.
  • the composition according to the invention is characterized in that the at least one fatty alcohol, the at least one volatile alkane and the at least one vegetable oil are biosourced.
  • composition according to the invention is characterized in that the at least one volatile alkane and the at least one vegetable oil are biosourced.
  • a "fatty alcohol” is a long-chain alcohol with carbon atoms, most of which have an even number of carbon atoms, and contain from 8 to 36 carbon atoms.
  • an “alkane” is a saturated hydrocarbon consisting solely of carbon and hydrogen atoms linked together by simple covalent bonds, the general formula of which is C n H 2n+2 , it is called a “linear alkane” when each carbon atom is linked to a maximum of two carbon atoms and a “branched alkane” when certain carbon atoms are linked to three atoms, or even four carbon atoms.
  • liquid oil of plant origin means: a water-insoluble fraction, extracted from a plant part (seeds, fruits, etc.), which mainly contains fatty acid triglycerides.
  • Triglycerides also called triacylglycerols, triacylglycerides or fatty acid triglycerides, are glycerides in which the three hydroxyl groups of glycerol are esterified by fatty acids. They are the main constituents of vegetable oil.
  • vegetable wax means a composition comprising at least one partially or completely hydrogenated oil.
  • These vegetable waxes may comprise fatty acid esters. and fatty alcohol, and may further comprise fatty acids, free fatty alcohols, long chain linear alkanes and/or unsaponifiables.
  • an “unsaponifiable” or even an “unsaponifiable matter” designates any organic matter constituting oils or fats in general which cannot be saponified or extracted from vegetable oils along with triglycerides by molecular distillation.
  • unsaponifiable matters include natural constituents of fats such as sterols, phytosterols, hydrocarbons and higher alcohols: aliphatic and terpenic.
  • a “mass percentage” is the ratio of the mass of a first compound to the total mass of a mixture of compounds (including the first compound) or composition, reduced to a percentage.
  • a bio-based compound or organic composition is defined as one in which the organic carbon present in the compound or composition is of plant origin by radiocarbon analysis according to one of the following standards: ASTM D6866, EN 16640 or EN 16785-1.
  • the composition according to the invention is characterized in that the fatty alcohol is chosen from the group consisting of fatty alcohols comprising from 16 to 24 carbon atoms, alone or in mixtures.
  • the composition according to the invention is characterized in that the fatty alcohol is chosen from the group consisting of fatty alcohols comprising from 18 to 24 carbon atoms, alone or in mixtures.
  • the composition according to the invention is characterized in that the fatty alcohol is chosen from the group consisting of fatty alcohols comprising from 18 to 22 carbon atoms, alone or in mixtures.
  • the composition according to the invention is characterized in that the fatty alcohol is chosen from the group comprising octadecanol, eicosanol, docosanol and tetracosanol, alone or in mixtures.
  • the composition according to the invention is characterized in that the fatty alcohol is chosen from the group comprising octadecanol and docosanol, alone or in mixtures.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is less than 180°C is chosen from the group comprising linear and/or branched bioalkanes of 10 to 24 carbon atoms, alone or as a mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is less than 100°C is chosen from the group comprising linear and/or branched bioalkanes of 10 to 24 carbon atoms, alone or as a mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is less than 180°C is chosen from the group comprising linear and/or branched bioalkanes of 12 to 18 carbon atoms, alone or as a mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is less than 100°C is chosen from the group comprising linear and/or branched bioalkanes of 12 to 18 carbon atoms, alone or as a mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is lower at 180°C is selected from the group comprising dodecane, tetradecane, hexadecane, octadecane, eicosane, alone or in mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is less than 100°C is chosen from the group comprising dodecane, tetradecane, hexadecane, octadecane, eicosane, alone or as a mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is less than 180°C is chosen from the group comprising dodecane and octadecane, alone or as a mixture.
  • the composition according to the invention is characterized in that the volatile alkane whose flash point is lower than 30 to 100°C is chosen from the group comprising dodecane and octadecane, alone or as a mixture.
  • the composition according to the invention is characterized in that the partially hydrogenated vegetable oil or the mixture comprising at least one non-hydrogenated oil and at least one at least partially hydrogenated is selected from the group comprising vegetable oils having a melting point between 45 and 60°C.
  • the composition according to the invention is characterized in that the partially hydrogenated vegetable oil or the mixture comprising at least one non-hydrogenated oil and at least one at least partially hydrogenated oil is chosen from the group comprising vegetable oils having a melting point of between 45 and 55°C.
  • the composition according to the invention is characterized in that the partially hydrogenated vegetable oil is selected from the group comprising partially hydrogenated soybean oil, partially hydrogenated rapeseed oil, partially hydrogenated sunflower oil, partially hydrogenated grape seed oil, partially hydrogenated corn oil, partially hydrogenated olive oil, partially hydrogenated cottonseed oil, partially hydrogenated coconut oil, partially hydrogenated jojoba oil, and mixtures thereof.
  • the partially hydrogenated vegetable oil is selected from the group comprising partially hydrogenated soybean oil, partially hydrogenated rapeseed oil, partially hydrogenated sunflower oil, partially hydrogenated grape seed oil, partially hydrogenated corn oil, partially hydrogenated olive oil, partially hydrogenated cottonseed oil, partially hydrogenated coconut oil, partially hydrogenated jojoba oil, and mixtures thereof.
  • composition according to the invention is characterized in that the at least one wax is chosen from the group consisting of vegetable or synthetic waxes.
  • the composition according to the invention is characterized in that the at least one wax is chosen from the group comprising waxes having a melting point between 45 and 90°C.
  • the composition according to the invention is characterized in that the at least one wax is chosen from the group comprising waxes having a melting point between 60 and 90°C.
  • the composition according to the invention is characterized in that the at least one wax is chosen from the group comprising waxes having a melting point between 45 and 65°C.
  • the composition according to the invention is characterized in that the vegetable wax is chosen from the group comprising carnauba wax, sunflower wax, mimosa wax, rice wax, candelilla wax, jojoba wax, castor wax, olive wax.
  • composition according to the invention is characterized in that the synthetic wax is chosen from the group comprising paraffin, polyethylene wax, microcrystalline wax.
  • composition according to the invention is characterized in that the mixture of unsaponifiables is chosen from the group comprising unsaponifiables of sunflower oil, castor oil and olive oil.
  • composition according to the invention is characterized in that the mixture of unsaponifiables is chosen from the group comprising unsaponifiables of vegetable waxes.
  • the composition according to the invention is characterized in that the mixture of unsaponifiables is chosen from the group comprising sterols, phytosterols, tocopherols, hydrocarbons, higher alcohols: aliphatic and terpenic and their derivatives.
  • composition according to the invention is characterized in that the mixture of unsaponifiables comprises tocopherol and/or their derivatives having antioxidant properties.
  • composition according to the invention is characterized in that it is free of synthetic antioxidants.
  • Table 1 The composition obtained by mixing at 60°C has a melting point of 47°C after cooling.
  • CONSTITUENTS PRODUCTS MASS PERCENTAGES (%) FATTY ALCOHOL ALCOHOL 16/18 33 VOLATILE ALKANE_ COCONUT ALKANE 12/18 7 WAX SUNFLOWER WAX (KALHWAX 6607L) 2 PARTIALLY HYDROGENATED VEGETABLE OIL SOYA HYDRO 50 (ADM) 58
  • Shaped candles are satisfactory in terms of strength, appearance, surface and combustion.
  • Table 2 The composition obtained when mixed at 60°C has a melting point of 49°C after cooling.
  • compositions of candles shaped at a filling temperature of 70-80°C in 290g glasses with a diameter of 8.3cm are compositions of candles shaped at a filling temperature of 70-80°C in 290g glasses with a diameter of 8.3cm, the wicks used are Wedo LX 22 wicks.
  • Test 1 (outside the invention) is a candle consisting solely of partially hydrogenated vegetable oil marketed under the name NatureWaxC3. As indicated in the table above, the combustion is not good and the candle has a deep crater with numerous crystals.
  • Test 2 (outside the invention) is a candle made of partially hydrogenated vegetable oil marketed under the name NatureWaxC3 and unsaponifiables in the form of olive wax. As indicated in the table above, the combustion is not good and the candle has a low melting pool.
  • Test 3 (outside the invention) is a candle made of partially hydrogenated vegetable oil marketed under the name NatureWaxC3 and fatty alcohol. As indicated in the table above, the combustion is not good and the candle has a low melting pool.
  • Test 4 is a candle made of partially hydrogenated vegetable oil marketed as NatureWaxC3, dodecane and fatty alcohols. As shown in the table above, combustion is good and the melting pool meets commercial requirements.
  • This candle is satisfying both in its appearance and its burn.
  • Test 5 is a candle made of partially hydrogenated vegetable oil marketed as NatureWaxC3, sunflower wax, a mixture of alkanes and fatty alcohols. As shown in the table above, combustion is correct and the melting pool meets commercial requirements.
  • Test 6 is a candle consisting of partially hydrogenated vegetable oil marketed under the name NatureWaxC3, unsaponifiables in the form of olive wax, dodecane and fatty alcohols. As indicated in the table above, the combustion is good and the melting pool complies with commercial requirements.
  • This candle is satisfying both in its appearance and its burn.
  • Test 7 is a candle made of partially hydrogenated vegetable oil marketed as NatureWaxC3, sunflower wax, and a mixture of alkanes consisting of dodecane and decane. As shown in the table above, combustion is good and the melting pool meets commercial requirements.
  • This candle is satisfying both in its appearance and its burn.
  • Test 8 is a candle made of partially hydrogenated vegetable oil marketed as NatureWaxC3, candelilla wax, and a mixture of alkanes consisting of dodecane and decane. As shown in the table above, combustion is good and the melting pool meets commercial requirements.
  • This candle is satisfying both in its appearance and its burn.

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Cosmetics (AREA)

Claims (18)

  1. Zusammensetzung für eine Kerze, dadurch gekennzeichnet, dass sie in Massenprozent enthält:
    - 0 bis 40 % mindestens eines Fettalkohols,
    - 3 bis 10 % mindestens eines flüchtigen Alkans, dessen Flammpunkt unter 180 °C liegt,
    - 0 bis 3 % mindestens eines Wachses,
    - 0 bis 3 % mindestens einer Mischung von unverseifbaren Stoffen,
    - 47 bis 95 % mindestens eines zumindest teilweise hydrierten Pflanzenöls.
  2. Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, dass sie in Massenprozent enthält:
    - 20 bis 40 % mindestens eines Fettalkohols,
    - 3 bis 10 % mindestens eines flüchtigen Alkans, dessen Flammpunkt unter 100 °C liegt,
    - 0 bis 3 % mindestens eines Wachses,
    - 0 bis 3 % mindestens einer Mischung von unverseifbaren Stoffen,
    - 47 bis 77 % mindestens eines teilweise hydrierten Pflanzenöls.
  3. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die Kerzenzusammensetzung frei von Palmöl ist.
  4. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass der Fettalkohol aus der Gruppe ausgewählt ist bestehend aus Fettalkoholen mit 18 bis 24 Kohlenstoffatomen, einzeln oder als Mischungen.
  5. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass der Fettalkohol aus der Gruppe ausgewählt ist umfassend Octadecanol, Eicosanol, Docosanol und Tetracosanol, einzeln oder als Mischungen.
  6. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass der Fettalkohol aus der Gruppe ausgewählt ist umfassend Octadecanol und Docosanol, einzeln oder als Mischungen.
  7. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das flüchtige Alkan aus der Gruppe ausgewählt ist umfassend lineare und/oder verzweigte Bioalkane mit 10 bis 24 Kohlenstoffatomen, einzeln oder als Mischung.
  8. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das flüchtige Alkan aus der Gruppe ausgewählt ist umfassend lineare und/oder verzweigte Bioalkane mit 12 bis 18 Kohlenstoffatomen, einzeln oder als Mischung.
  9. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das flüchtige Alkan aus der Gruppe ausgewählt ist umfassend Dodecan, Tetradecan, Hexadecan, Octadecan, Eicosan, einzeln oder als Mischung.
  10. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das flüchtige Alkan, dessen Flammpunkt unter 180 °C liegt, aus der Gruppe ausgewählt ist umfassend Dodecan und Octadecan, einzeln oder als Mischung.
  11. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das teilweise hydrierte Pflanzenöl aus der Gruppe der Pflanzenöle mit einem Schmelzpunkt zwischen 45 und 60 °C ausgewählt ist.
  12. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das teilweise hydrierte Pflanzenöl ausgewählt ist aus der Gruppe umfassend teilweise hydriertes Sojaöl, teilweise hydriertes Rapsöl, teilweise hydriertes Sonnenblumenöl, teilweise hydriertes Traubenkernöl, teilweise hydriertes Maisöl, teilweise hydriertes Olivenöl, teilweise hydriertes Baumwollsamenöl, teilweise hydriertes Kokosnussöl, teilweise hydriertes Jojobaöl und Mischungen davon.
  13. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das mindestens eine Wachs aus der Gruppe ausgewählt ist bestehend aus pflanzlichen oder synthetischen Wachsen mit einem Schmelzpunkt zwischen 45 und 90 °C.
  14. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das pflanzliche Wachs aus der Gruppe ausgewählt ist umfassend Carnaubawachs, Sonnenblumenwachs, Mimosenwachs, Reiswachs, Candellilawachs, Jojobawachs, Rizinuswachs, Olivenwachs.
  15. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das synthetische Wachs aus der Gruppe ausgewählt ist umfassend Paraffin, Polyethylenwachs, mikrokristallines Wachs.
  16. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die mindestens eine Mischung von unverseifbaren Stoffen ausgewählt ist aus der Gruppe umfassend unverseifbare Stoffe aus Sonnenblumenöl, Rizinusöl und Olivenöl.
  17. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die Mischung von unverseifbaren Stoffen ausgewählt ist aus der Gruppe umfassend unverseifbare Stoffe von Pflanzenwachsen.
  18. Zusammensetzung nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die Mischung von unverseifbaren Stoffen ausgewählt ist aus der Gruppe umfassend Sterole, Phytosterole, Tocopherole, höhere aliphatische und/oder Terpenalkoholen und deren Derivate.
EP21749866.6A 2020-08-03 2021-08-03 Zusammensetzung für kerze Active EP4189050B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2008255A FR3113064B1 (fr) 2020-08-03 2020-08-03 Composition BIOSOURCEE pour bougie
PCT/EP2021/071684 WO2022029133A1 (fr) 2020-08-03 2021-08-03 Composition pour bougie

Publications (2)

Publication Number Publication Date
EP4189050A1 EP4189050A1 (de) 2023-06-07
EP4189050B1 true EP4189050B1 (de) 2024-10-30

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EP21749866.6A Active EP4189050B1 (de) 2020-08-03 2021-08-03 Zusammensetzung für kerze

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US (1) US12157867B2 (de)
EP (1) EP4189050B1 (de)
FR (1) FR3113064B1 (de)
WO (1) WO2022029133A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2623948A (en) * 2022-10-28 2024-05-08 Nyita Collection Ltd Candle composition and method

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WO2003012016A1 (en) 2001-08-02 2003-02-13 Archer Daniels Midland Company Vegetable fat-based candles
JP2003206494A (ja) * 2002-01-11 2003-07-22 Kameyama Kk 植物性ロウソク組成物
US6773469B2 (en) * 2002-11-12 2004-08-10 Cargill, Incorporated Triacylglycerol based wax for use in candles
US7846372B1 (en) 2003-07-03 2010-12-07 SoyBasics, LLC Method of making a vegetable oil-based candle
US7588607B1 (en) * 2005-03-16 2009-09-15 Daniel S. Cap Candlewax compositions with improved scent-throw
WO2008115604A1 (en) 2007-03-22 2008-09-25 Smith Mountain Industries Candle composition
MX2009013820A (es) * 2007-06-15 2010-03-10 Elevance Renewable Sciences Composiciones de cera hibrida para usarse en articulos de cera moldeados por compresion tales como velas.
DE102007056171A1 (de) * 2007-11-21 2009-05-28 Vollmar Creationen In Wachs Gmbh Kerzenkörper
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FR3021217B1 (fr) * 2014-05-26 2016-06-24 Philippe Berodias Bougie huile de bain
KR20180023887A (ko) * 2015-03-25 2018-03-07 캔들-라이트 컴퍼니, 엘엘씨 다중불포화도가 낮은 식물성유 및 젤화제를 포함하는 양초 제품
US20160348031A1 (en) * 2015-05-29 2016-12-01 Beautyavenues Llc Candle containing non-ionic emulsifer
KR101839237B1 (ko) 2016-11-08 2018-04-26 주식회사 엘지생활건강 식물성 왁스를 포함하는 양초 조성물

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Publication number Publication date
US12157867B2 (en) 2024-12-03
WO2022029133A1 (fr) 2022-02-10
FR3113064A1 (fr) 2022-02-04
US20240301321A1 (en) 2024-09-12
EP4189050A1 (de) 2023-06-07
FR3113064B1 (fr) 2023-06-30

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