EP4058283A1 - Procédé de fabrication d'une pièce en acier ou en aluminium - Google Patents
Procédé de fabrication d'une pièce en acier ou en aluminiumInfo
- Publication number
- EP4058283A1 EP4058283A1 EP20801324.3A EP20801324A EP4058283A1 EP 4058283 A1 EP4058283 A1 EP 4058283A1 EP 20801324 A EP20801324 A EP 20801324A EP 4058283 A1 EP4058283 A1 EP 4058283A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polymer
- sheet
- layer
- steel
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 48
- 239000010959 steel Substances 0.000 title claims abstract description 48
- 239000004411 aluminium Substances 0.000 title claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims abstract description 65
- 238000000576 coating method Methods 0.000 claims abstract description 39
- 239000011248 coating agent Substances 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000003825 pressing Methods 0.000 claims abstract description 6
- 238000005452 bending Methods 0.000 claims abstract description 4
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 4
- 229920000098 polyolefin Polymers 0.000 claims description 17
- 229920000515 polycarbonate Polymers 0.000 claims description 15
- 239000004417 polycarbonate Substances 0.000 claims description 15
- 229920000728 polyester Polymers 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000004952 Polyamide Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- -1 polyethylenes Polymers 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 4
- 239000010960 cold rolled steel Substances 0.000 claims description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 238000007739 conversion coating Methods 0.000 claims description 3
- 239000013256 coordination polymer Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 229920001634 Copolyester Polymers 0.000 claims description 2
- 229920002292 Nylon 6 Polymers 0.000 claims description 2
- 229910000937 TWIP steel Inorganic materials 0.000 claims description 2
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 238000003618 dip coating Methods 0.000 claims description 2
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 claims description 2
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 41
- 230000001050 lubricating effect Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000922 High-strength low-alloy steel Inorganic materials 0.000 description 1
- 229910000794 TRIP steel Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000013047 polymeric layer Substances 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/088—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/06—Coating on the layer surface on metal layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
Definitions
- the invention relates to a method for producing a part of steel or aluminium, for instance for automotive purposes.
- flat sheets or blanks are cut from strip material produced by the steel or aluminium manufacturers. These flat sheets or blanks have to be (de)formed before they can be used in cars or other products, for instance by pressing, deep drawing, bending or roll forming.
- the sheet or blank has to be deformed three-dimensionally in a pressing tool.
- a pressing tool high friction can exist between the sheet and the tooling; the resulting friction forces reduce the forming capacity.
- an oil layer is applied on the sheet or blank.
- part can be attached to other parts or other material in an easy way.
- a part that is degreased is not seen as the best starting point for attaching.
- the method of the invention comprising the following steps: providing a steel or aluminium sheet; providing a coating on one or both sides of the sheet, wherein the coating consists of one or more polymer layers, wherein the polymer is a thermoplastic polymer; and forming the coated sheet into a part by pressing, stamping, deep drawing, roll forming, bending, hydroforming or stretching after the polymer layer(s) have been provided on the sheet.
- the sheet will act as a lubricant between the sheet and the tool for deforming the sheet. In this way, the friction between the sheet and the tool is reduced.
- the polymer coating remains on the part produced using the tool.
- each layer consists of a polymer from the group of:
- thermoplastic polymers in each of these four groups can be used as a layer, both when the coating consists of one layer and when the coating consists of two or more layers.
- the polymer is chosen such that:
- a polyolefin is selected from the group of polyethylenes, polypropylenes, polyethylene copolymers, polypropylene copolymers, chemically modified polyolefins such as maleic anhydride grafted polyethylene or polypropylene, or is a combination of two or more of these polyolefins;
- a polyamide is selected from the group of polyamide 6 (PA6), polyamide 6.6 (PA6.6), polyamide 4.6 (PA4.6) or is a combination of two or more of these polyamides;
- a polyester is selected from the group polyethylene terephthalate (PET), polybutylene terephthalate (PBT), a copolyester containing isophthalic acid (I PA) and/or cyclohexanedimethanol (CHDM), or is a combination of two or more of these polyesters;
- PET polyethylene terephthalate
- PBT polybutylene terephthalate
- I PA isophthalic acid
- CHDM cyclohexanedimethanol
- a polycarbonate is a polycarbonate of Bisphenol A.
- these groups of polyolefins, polyamides, polyesters and polycarbonates are suitable as a layer on a steel or aluminium sheet that is to be deformed, in view of their adherence properties on steel and aluminium, and/or in view of their lubricating properties relative to the deformation tool.
- the polymer coating is suitable to act as a lubricant, it is advantageous when the coated sheet is formed free from an applied lubricant or oil.
- an applied lubricant or oil there is no need to apply a layer of an oil or other lubricant on the strip or sheet, and thus also no need to remove this layer after the sheet has been formed or deformed into a part.
- not using an applied lubricant or oil means a reduction in processing steps and thus a reduction in cost.
- a so-called “oil-free press shop” is seen as advantageous by the industry.
- the sheet When using the polymer coated sheet according to the invention for deep drawing, for instance, the sheet is deformed between a punch and a die, while the circumference of the sheet or blank is kept under a compression force by a blank holder.
- the distance between the punch and the die is larger than the thickness of the polymer coated sheet, that is the combined thickness of the sheet and the polymer coating. In this way the polymer coating can act as a lubricant.
- the polymer coating with remain adhered to the sheet and deforms together with the sheet.
- the distance between the punch and the die is approximately 1.2 times the thickness of the polymer coated sheet, so between 1.1 and 1.4 times the thickness of the polymer coated sheet.
- the steel sheet is cut from a hot-rolled steel strip or from a hot-rolled and subsequently cold-rolled steel strip.
- a hot-rolled or cold-rolled strip to cut the sheet from is the easiest and most cost-effective way to provide a sheet for the present method.
- Such a strip can be produced in the required composition and with the required properties.
- the steel sheet can for instance be a formable steel sheet for outer panels for automotive purposes, a high strength steel sheet for the chassis of a car, or a steel sheet for the white goods industry. Such sheet are known as such to the skilled person.
- the hot rolled or cold rolled strip has a width of less than 600 mm.
- Steel strips having this width are suitable to cut out sheets or blanks that can be formed by for instance deep drawing.
- the hot rolled or cold rolled steel strip preferably has a thickness of at least 0,66 mm, preferably a thickness of at least 0,68 mm.
- the strip has a maximum thickness of 4 mm, because thicker sheets or blanks are difficult to form and took heavy for use.
- the high strength steel sheet used can be a HSLA steel, a AHSS or a UHSS, such as a DP steel, a CP steel or a TRIP steel, which usually have a thickness between 0,8 and 2,5 mm.
- a HSLA steel a HSSS or a UHSS
- DP steel a DP steel
- CP steel a CP steel or a TRIP steel
- Such steel types are known to the person skilled in the art and ned no further elucidation.
- steel sheet for outer panels which are made from a mils steel such as DX or BH steel, which sheets usually have a thickness between 0,7 and 1 ,5 mm.
- standard cold rolled steel sheets or blanks can be used.
- the steel sheet consists of a steel having a UTS of at least 600 MPa, more preferably a UTS of at least 800 MPa, preferably the steel sheet being a AHSS or UHSS such as DP, CP, TRIP, TWIP steel.
- AHSS AHSS
- UHSS such as DP, CP, TRIP, TWIP steel
- the steel sheet is coated with a metal or metal alloy layer that is present between the steel sheet and the one or more polymer layers, preferably the steel sheet is coated with a zinc or zinc alloy layer, more preferably the zinc or zinc alloy layer being a EG or GA or Gl or ZM applied layer and/or the steel sheet is treated with an adhesion promotor or conversion coating, and wherein the steel sheet coated with a GA or Gl or ZM layer is preferably coated by hot dip coating.
- a metal or metal alloy it is almost always a requirement that the steel sheet is coated with a metal or metal alloy to reduce or prevent corrosion.
- a conversion coating or adhesion promotor is often required when a polymer coating must be applied on a metal or metal alloy that is present on the steel sheet.
- the aluminium sheet consists of AA5xxx, AL6xxx or AA7xxx. These aluminium alloys are frequently used in the automotive industry for outer panels or chassis components.
- the polymer coating consists of more than one layer, in which the layer contacting the metal sheet is a (co)polyester or a chemically modified polyolefin or a polycarbonate.
- a (co)polyester or a chemically modified polyolefin or a polycarbonate is very suitable as layer in direct contact with the metal sheet in view of its bonding properties.
- the polymer coating consists of more than two layers, in which the outermost layer, facing away from the metal sheet, is a (co)polyester or a chemically modified polyolefin or a polycarbonate.
- a (co)polyester or a chemically modified polyolefin or a polycarbonate is also very suitable as outermost layer in view of its adhesion properties to other materials.
- the outermost layer, facing away from the metal sheet contains certain additives to reduce the friction coefficient of the coating, such as insoluble ‘anti-block’ particles and organic slip additives.
- additives which are known per se, improves the lubricating effect of the polymer coating by reducing the friction coefficient thereof.
- the polymer coating consists of one layer that is a (co)polyester or a chemically modified polyolefin or a polycarbonate. Using only one layer as a coating simplifies the production process of the strip or sheet to a certain extent.
- a polymer coating has a layer contacting the metal sheet with a thickness between 2 and 10 pm, and the polymer coating has a thickness between 10 and 200 pm.
- the polymer coating has a thickness between 10 and 90 pm , more preferably a thickness between 10 and 70 pm. These thicknesses provide the polymer coating with a good strength during deformation, such that disruption of the coating is reduced. Especially thinner polymer coatings are less likely to deform during the forming process.
- a further layer is attached to the part, which further layer at least partly consists of a polymer and optionally further consists of flexible material such a fibres, to form a steel-polymer hybrid part.
- a polymer coating on the part that is formed in accordance with the invention thus has the further advantage that a further layer can be easily attached to the formed part.
- the coating on the part consists of a polymer
- the further layer at least partly consists of a polymer as well. Adhesion between the coating and the further layer can thus be realised by choosing suitable polymers for both the coating and the further layer.
- a further layer is attached to the polymer coated sheet before the forming of a part, which further layer at least partly consists of a polymer and optionally further consists of flexible material such a fibres, to form a steel-polymer hybrid part.
- the part that is formed is directly a hybrid part, without any further processing step. Since the adhering of a further layer to a flat sheet is much easier than the adhering to a formed sheet, this is an advantageous method. Of course the further layer has to be able to withstand the forming step.
- any of the above inventive methods it is possible, after the forming of a part from the polymer coated sheet, to apply a polymer three-dimensional body against the polymer layer of the part, preferably by injection moulding in a die for forming the part.
- the part that is formed has a side that is provided with an at least partially polymeric layer, it is possible to apply the three-dimensional body to the part.
- Injection moulding is a suitable way to apply the three-dimensional body, because a very good adherence can be obtained.
- the part is painted after the preceding steps have been performed. This is often needed when the part is used for automotive purposes, but also for other purposes.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19208941 | 2019-11-13 | ||
PCT/EP2020/081808 WO2021094404A1 (fr) | 2019-11-13 | 2020-11-11 | Procédé de fabrication d'une pièce en acier ou en aluminium |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4058283A1 true EP4058283A1 (fr) | 2022-09-21 |
Family
ID=68581459
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20801324.3A Withdrawn EP4058283A1 (fr) | 2019-11-13 | 2020-11-11 | Procédé de fabrication d'une pièce en acier ou en aluminium |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP4058283A1 (fr) |
WO (1) | WO2021094404A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023222211A1 (fr) | 2022-05-18 | 2023-11-23 | Eos Imaging | Méthode d'imagerie radiologique avec image de scannogramme à plusieurs niveaux d'énergie |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8724240D0 (en) * | 1987-10-15 | 1987-11-18 | Metal Box Plc | Laminated metal sheet |
FR2866592B1 (fr) * | 2004-02-19 | 2007-06-08 | Usinor | Procede de fabrication d'une piece composite |
AU2012280627B2 (en) * | 2011-07-07 | 2016-01-21 | Tata Steel Nederland Technology B.V. | Polyamide-imide coated substrate |
-
2020
- 2020-11-11 EP EP20801324.3A patent/EP4058283A1/fr not_active Withdrawn
- 2020-11-11 WO PCT/EP2020/081808 patent/WO2021094404A1/fr unknown
Also Published As
Publication number | Publication date |
---|---|
WO2021094404A1 (fr) | 2021-05-20 |
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