EP4046515A1 - Flammhemmender schutzhandschuh - Google Patents
Flammhemmender schutzhandschuh Download PDFInfo
- Publication number
- EP4046515A1 EP4046515A1 EP22152740.1A EP22152740A EP4046515A1 EP 4046515 A1 EP4046515 A1 EP 4046515A1 EP 22152740 A EP22152740 A EP 22152740A EP 4046515 A1 EP4046515 A1 EP 4046515A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- multilayer material
- protective glove
- glove according
- aramide
- preferred
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 28
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000003063 flame retardant Substances 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 87
- 229920003235 aromatic polyamide Polymers 0.000 claims abstract description 42
- 239000000835 fiber Substances 0.000 claims abstract description 41
- 241000531908 Aramides Species 0.000 claims abstract description 28
- 210000003813 thumb Anatomy 0.000 claims abstract description 24
- 210000003811 finger Anatomy 0.000 claims abstract description 17
- 229920002681 hypalon Polymers 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 22
- 239000004952 Polyamide Substances 0.000 claims description 7
- 229920002647 polyamide Polymers 0.000 claims description 7
- 229920006376 polybenzimidazole fiber Polymers 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- 239000011241 protective layer Substances 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000011257 shell material Substances 0.000 description 15
- 239000010985 leather Substances 0.000 description 7
- 239000003779 heat-resistant material Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000004760 aramid Substances 0.000 description 2
- 210000004932 little finger Anatomy 0.000 description 2
- 229920000784 Nomex Polymers 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000004763 nomex Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01529—Protective gloves with thermal or fire protection
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0006—Gloves made of several layers of material
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B17/00—Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
- A62B17/003—Fire-resistant or fire-fighters' clothes
Definitions
- Flame retardant protective glove in the form of a finger glove, having an outer shell comprising a back side, a thumb side, an outer side and a palm side, wherein at least the material in the back side, a thumb side and a outer side comprises at least one first multilayer material, comprising an outer layer of a flame retardant material and said palm side comprising a second multilayer material different than said at least one first multilayer material.
- Flame-retardant protective gloves are a prerequisite for certain professions in order to be able to handle certain occupations that are part of the performance of duties with sufficient security. Examples of such occupational groups are fire fighters, the military, police, ambulance personnel etc. Flameproof gloves are generally known.
- a protective glove is known from SE 458 254 .
- the protective glove has the shape of a finger glove.
- the glove consists mainly of leather whose inner surface has been provided with a plastic coating.
- the glove is provided with a lining of refractory and heat-insulating material.
- Such a protective glove becomes relatively awkward due to the plastic-coated leather becoming relatively rigid.
- the combination of materials makes it difficult to wash and decontaminate.
- a similar design is known from DE 10111143 .
- a flame-retardant protective glove is obtained which in a surprising way at the same time provides good comfort, good protection, good grip ability, good wear resistance and which may securely be washed and decontaminated.
- Figs. 1 and 2 shows a preferred embodiment of a glove according to the invention from above and below, mainly intended for fire fighters and similar use.
- the glove is partly made of elastic material, which makes the glove easy to put on and take off and provides good comfort.
- the inventors have arrived at a preferred combination of layers for use in the palm side 2 of an elastic multilayer material, which well meets these complex requirements for fire fighter gloves and similar uses, e.g. meeting the requirements of European standards 420,659 and 388.
- FIG. 1 and Fig. 2 there are shown two perspective views of an exemplary fire figter glove in accordance with the invention.
- the glove comprises a palm side 2, a backside 3, an outer side 4 and a thumb side 5.
- the thumb is marked with reference sign 6 and the remaining fingers are given reference number 7. Further, there is shown that the glove also includes a cuff 8.
- the glove basically includes three different materials in the outer shell. There is a first material M1 that is used for the backside 3 in the form of a relatively large backside piece 30. There is also a part 60 made in the first material M1 that is used as one of a plurality of pieces for the thumb 6. Further, the first material M1 may also be used for the cuff 8.
- the second material M2 is used for the major part 20 of the palm side 2 and also for an inner piece 61 for the thumb 6.
- the third material M3 is used in the form of a first side piece 50 on the thumb side 5 of the glove and a second side piece 40 on the outer side 4 of the glove. Furthermore, the third material M3 is used for a plurality of finger side pieces 70, 71, 72, 73. Finally, the third material M3 is used for a third piece 63 of the thumb 6.
- a fourth material 83 for the cuff edge and for the transition zone between the cuff and the glove part.
- a fourth material 83 for the cuff edge and for the transition zone between the cuff and the glove part.
- an eyelet device 81 along the palm side of the cuff 8 to assist in putting the glove on.
- Fig. 3 there is shown a cross-sectional schematic view of the glove according to Figs. 1 and 2 along line A-A. It is shown that the glove basically comprises an outer protective shell and an inner protective insert 9.
- the insert 9 is fixated to the outer glove shell by means of seams (not shown) at the fingertip points and also a resilient seam/s 95, preferably Nomex thread, corresponding to a position adjacent the wrist.
- Fig. 4 there is shown a more detailed cross-sectional view along lines B-B in Fig. 3 , in order to in more detail explain the different materials used for a glove according to the invention.
- the inset 9 may be produced in a large variety of different materials in accordance with the invention, depending on different needs for different uses of a glove according to the invention.
- the glove is intended for firefighting purposes and provided with preferred combination of materials, without any limitation to such a combination, wherein the combination of materials of the glove 1 may provide protection against harmful biological agents, cuts by hand-held chainsaws, high-pressure jets and bullet wounds or knife stabs.
- first shell material M1 comprising an outer protective layer part 30, se Fig. 5 , comprising a basic protective layer 30B and coating 30A.
- first shell material M1 comprises a basic protective layer 30B including 70-80% aramide fibers, suitably Para-aramide fibres, and 20-30% other strong fibres, e.g. polybenzimidazole fibres, preferably in the form of a half cardigan stitch-knitted fabric.
- aramide fibers are para Aramide fibers.
- the coating 30A preferably comprises silicone.
- the weight being in the range of 300 - 600 g/m 2 , preferably at least 400 g/m 2 and a thickness of between 0,8 to 1,8 mm, preferably larger than 1 mm and maximum 1,5 mm.
- the elongation at break ⁇ is of at least 50% in all directions, preferably at least 70% in all directions.
- the first multilayer material M1 has a larger elongation at break ⁇ W in a width wise direction W than the elongation at break ⁇ F in a length wise direction W, wherein preferably ⁇ w > 1,1 - 2 ⁇ F .
- the cuff piece 80 and a thumb piece part 61 may be made in the same material M1.
- the outer shell of the palm side 2 of the glove comprises two parts 20, 61 made of the second material M2.
- the large palm part 20, see Fig 5 covers most of the palm of the hand and also includes an inner part for the fingers 7.
- a thumb piece part 61, see Fig 8 is also made of the second material M2, to provide a really good grip.
- the second material M2 comprises a multilayer, cohesive material, having an outer coated layer 20A of a flame retardant resilient material comprising Chlorosulfonated Polyethylene and a second, base layer 20B including at least 80% aramide fibers, suitably Para-aramide fibers, preferably at least 90% Para-aramide fibers and more preferred 100% Para-aramide fibers.
- the Aramide fibers are para Aramide fibers.
- the second multilayer material M2 preferably is in the form of an interlock knitted fabric, which provides very good bond for the coated outer layer 20A.
- the second multilayer material M2 has its largest elongation at break ⁇ F in a length wise direction F
- the first multilayer material M1 has its largest elongation at break ⁇ W in a width wise direction W.
- the third material M3 in the outer shell also comprises a multilayer, cohesive material, having an outer layer of a flame retardant material comprising Polyamide fibers and a second layer comprising aramide fibres.
- the Aramide fibers are para Aramide fibers.
- the third material M3 includes around 50-70 % Polyamide fibers and 30-50% Para-aramide fibers, Preferably the amount of Polyamide fibers is larger than the amount of Para-aramide fibers.
- the third multilayer material M3 has a surfacic mass of between 300 to 800 g/m 2 , preferably 400 to 600 g/m 2 .
- the seams between the parts are preferably made as double seams, and by the use of a sewing thread made from 90-100% spun meta aramid fiber, preferably using a vertically integrated aramid manufacturing system.
- a membrane 90 arranged as an outer layer all around the insert 9.
- it is a copolyamide membrane 90 that is elastic in all directions with high vapor permeability, having a melting temperature above 100 ° C, suitably up to 120° C, and a wash resistance of at least 60° C.
- the membrane is also completely fogging-free.
- the insert 9 at the back side 3 includes two layers 91A, 91B of a heat resistant material, preferably PAN/PES of about 120 to 200 g/m 2 .
- a liner 92 preferably including about 50 -70% Aramid and 30-50% glass, of about 250 to 350 g/m 2 .
- the insert 9 preferably has a larger amount of heat resistant material at the back side 3 than at the palm side 2.
- a glove according to the invention presents a surprising combination of desired properties for a flame retardant glove, for which there has been a long felt need.
- the invention is not limited by the above shown but can be varied within the scope of the appended claims. Those skilled in the art will recognize, for example, that the exact design of various components may be varied in many ways. Thus, it is understood, for example, that the glove also retains its basic functionality if having two or more of the fingers integrated to form a common space for two or more fingers, e.g. in the form of a thumb glove.
- One variant is, for example, to leave only the index finger and thumb free while the little finger, ring finger and middle finger are combined in a wide finger.
- Another variant is that only the little finger and ring finger 3 are integrated into one and the same space.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Gloves (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE2150111A SE544620C2 (en) | 2021-02-01 | 2021-02-01 | Flame retardant multilayer protective glove comprising a palm part arranged with aramide fibers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP4046515A1 true EP4046515A1 (de) | 2022-08-24 |
EP4046515B1 EP4046515B1 (de) | 2024-10-09 |
Family
ID=80113484
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP22152740.1A Active EP4046515B1 (de) | 2021-02-01 | 2022-01-21 | Flammhemmender schutzhandschuh |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP4046515B1 (de) |
SE (1) | SE544620C2 (de) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5020161A (en) | 1989-09-29 | 1991-06-04 | E. I. Dupont De Nemours And Company | Waterproof glove for protective coveralls |
WO1997047212A1 (en) | 1996-06-10 | 1997-12-18 | W.L. Gore & Associates, Inc. | Multi-layered barrier glove |
DE10111143A1 (de) | 2001-03-08 | 2002-09-26 | Watex Gmbh | Textiler Schutzhandschuh für Feuerwehren oder dergleichen |
US20090222980A1 (en) * | 2005-04-29 | 2009-09-10 | Helmut Klug | Piece of Garment |
US20170280795A1 (en) * | 2016-04-01 | 2017-10-05 | Showa Glove Co. | Glove |
US20190343201A1 (en) | 2013-03-07 | 2019-11-14 | AIRBOSS Engineered Products, Inc. | Personal protective equipment for cbrn or other protection |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5070540A (en) * | 1983-03-11 | 1991-12-10 | Bettcher Industries, Inc. | Protective garment |
SE458254B (sv) * | 1986-12-11 | 1989-03-13 | Osmo Nevalainen | Skyddshandske |
DE29501651U1 (de) * | 1995-02-02 | 1995-04-13 | Handschuhfabrik Seiz GmbH & Co. KG, 72555 Metzingen | Schutzhandschuh |
JP6599119B2 (ja) * | 2015-04-01 | 2019-10-30 | ショーワグローブ株式会社 | 手袋の製造方法 |
-
2021
- 2021-02-01 SE SE2150111A patent/SE544620C2/en unknown
-
2022
- 2022-01-21 EP EP22152740.1A patent/EP4046515B1/de active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5020161A (en) | 1989-09-29 | 1991-06-04 | E. I. Dupont De Nemours And Company | Waterproof glove for protective coveralls |
WO1997047212A1 (en) | 1996-06-10 | 1997-12-18 | W.L. Gore & Associates, Inc. | Multi-layered barrier glove |
DE10111143A1 (de) | 2001-03-08 | 2002-09-26 | Watex Gmbh | Textiler Schutzhandschuh für Feuerwehren oder dergleichen |
US20090222980A1 (en) * | 2005-04-29 | 2009-09-10 | Helmut Klug | Piece of Garment |
US20190343201A1 (en) | 2013-03-07 | 2019-11-14 | AIRBOSS Engineered Products, Inc. | Personal protective equipment for cbrn or other protection |
US20170280795A1 (en) * | 2016-04-01 | 2017-10-05 | Showa Glove Co. | Glove |
Also Published As
Publication number | Publication date |
---|---|
SE544620C2 (en) | 2022-09-27 |
SE2150111A1 (en) | 2022-08-02 |
EP4046515B1 (de) | 2024-10-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4454611A (en) | Heat resistant protective hand covering | |
US4433439A (en) | Heat resistant protective hand covering | |
US5539928A (en) | Firefighter garment with low friction liner system | |
US11779069B2 (en) | Glove thermal protection system | |
US9655393B2 (en) | Layered structural fire glove | |
EP2285247B1 (de) | Schutzkleidung mit geringen reibungsmerkmalen | |
US5740551A (en) | Multi-layered barrier glove | |
US5819316A (en) | Firefighter garment with low friction liner system | |
CA2633173C (en) | Protective garments that provide thermal protection and are relatively lightweight and flexible | |
EP1914333A1 (de) | Hitzebeständigestuch und davon gebrauch machende kleidung und handschuhe | |
JP2008266841A (ja) | 消防服素材 | |
KR101614873B1 (ko) | 소방복 및 화학보호복의 특수복용 원단 및 이에 의해 제조된 특수복 | |
US20110271419A1 (en) | Shirt with reinforced front | |
EP4046515B1 (de) | Flammhemmender schutzhandschuh | |
KR20200009032A (ko) | 보호용 의복 | |
EP0606405A1 (de) | Hitzebeständiger, schnittwiderstandsfähiger und gegen durchstossen beständiger handschutz | |
BE1027761B1 (nl) | Brandwerende handschoen samengesteld uit een gelamineerd textielsysteem | |
KR100629459B1 (ko) | 방열복의 피복 적층구조 | |
CN208064530U (zh) | 隐蔽式防护服 | |
CN214710679U (zh) | 复合多层结构的消防手套 | |
CN213441467U (zh) | 纳米隔热手套面料 | |
US7426753B1 (en) | Protective garment | |
RU2705266C1 (ru) | Латы-перчатки огнестойкие с дополнительной функцией освещения | |
US20240334994A1 (en) | Protective apparel | |
RU2126643C1 (ru) | Защитная перчатка |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20230118 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20240624 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602022006558 Country of ref document: DE |