EP4034074A1 - Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore - Google Patents

Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore

Info

Publication number
EP4034074A1
EP4034074A1 EP20739984.1A EP20739984A EP4034074A1 EP 4034074 A1 EP4034074 A1 EP 4034074A1 EP 20739984 A EP20739984 A EP 20739984A EP 4034074 A1 EP4034074 A1 EP 4034074A1
Authority
EP
European Patent Office
Prior art keywords
acid
agent
weight
group
packaging unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20739984.1A
Other languages
German (de)
English (en)
Inventor
Constanze KRUCK
Sandra Hilbig
Daniela Kessler-Becker
Melanie Moch
Susanne Dickhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP4034074A1 publication Critical patent/EP4034074A1/fr
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24—Phosphorous; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/362—Polycarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/882—Mixing prior to application

Definitions

  • the present application relates to a multi-component packaging unit (kit-of-parts) for coloring keratinic material, in particular human hair, which comprises at least two different agents (a) and (b) in separately made-up containers.
  • the agent (a) contains at least one amino-functionalized silicone polymer (a1).
  • the agent (b) is characterized in that it contains water (b1), a buffer system (b2) of at least one inorganic or organic acid (b2-l) and at least one salt of this acid (b2-II) and (b3) at least one contains coloring compound.
  • This coloring compound is very particularly preferably a pigment.
  • a second subject of this application is a method for coloring keratinic material in which the two agents (a) and (b) described above are used.
  • Oxidation dyes are usually used for permanent, intensive dyeings with good fastness properties and good gray coverage. Such colorants contain oxidation dye precursors, so-called developer components and coupler components, which, under the influence of oxidizing agents such as hydrogen peroxide, form the actual dyes with one another. Oxidation dyes are characterized by very long-lasting dyeing results.
  • color pigments are generally understood to mean insoluble, coloring substances. These are undissolved in the form of small particles in the dye formulation and are only deposited on the outside of the hair fibers and / or the surface of the skin. As a rule, they can therefore be rewashed with a few washes with detergents containing surfactants Remove without leaving any residue.
  • Various products of this type are available on the market under the name of hair mascara.
  • the particular advantage of a hair mascara product is that the coloring compounds such as pigments are only deposited in the form of a film on the surface of the keratin fiber.
  • the nature of the keratin fiber itself is therefore not changed when the product is used, so that the use of a hair mascara product is associated with particularly low damage to the hair. If the user wants his original hair color back, the color can be removed from the keratin fiber quickly, completely and without leaving any residue, without damaging the fibers or changing the original hair color.
  • the development of pigment-based keratin dyes is therefore very much in vogue.
  • coloring compounds in particular also pigments
  • these instabilities occur in particular when the pigments have been stored in an alkaline medium.
  • the color result obtained after application on the keratin material can turn out differently than desired.
  • there is still a need for optimization in the pigment-based coloring system in particular the storage stability of the formulations and the color intensities obtained with stored formulations being in need of improvement.
  • the wash fastness should be excellent, but the use of the oxidation dye precursors usually used for this purpose should be dispensed with.
  • a special focus of the task was on the achievement of storage-stable formulations with which a precisely defined, intensive color result without undesired color shifts can be achieved regardless of the period of time over which they are stored. In addition, the colorations obtained should have particularly good reproducibility.
  • the agent (a) here contains at least one amino-functionalized silicone polymer (a1).
  • the agent (b) contains water (b1), furthermore a buffer system (b2) of at least one inorganic or organic acid (b2-l) and at least one salt of this acid (b2-II), and additionally at least one coloring compound (b3) , which is particularly preferably a pigment.
  • a first subject of the present invention is a multi-component packaging unit (kit-of-parts) for coloring keratinic material, in particular human hair, comprehensively packaged separately from one another
  • (b2) a buffer system composed of at least one inorganic or organic acid (b2-l) and at least one salt of this acid (b2-ll), and (b3) at least one coloring compound.
  • the multi-component packaging unit comprises at least the two means (a) and (b), these are mixed with one another before use.
  • the application mixture produced by mixing agents (a) and (b) is then applied to the keratin material, left to act and then rinsed out again with water.
  • the work leading to this invention has shown that the color shifts that can occur after storage of the coloring compounds or pigments in the formulation were effectively prevented when the coloring compound, in particular the pigment (b3), and the amino-functionalized silicone polymer (a1) were not incorporated together in one formulation, but separately in different formulations.
  • Particularly easily reproducible color results could be obtained in particular when the agent (b) with the color-imparting compounds (b3) has a buffer system (b2) of at least one inorganic or organic acid (b2-l) and at least one salt of this acid (b2-ll ) contained in a water-containing carrier (b1).
  • Keratin material is understood to mean hair, skin, and nails (such as fingernails and / or toenails, for example). Furthermore, wool, furs and feathers also fall under the definition of keratinic material.
  • Keratinic material is preferably understood to mean human hair, human skin and human nails, in particular fingernails and toenails. Keratinic material is very particularly preferably understood to mean human hair.
  • the multi-component packaging unit comprises means (a).
  • the container can be, for example, a sachet, a bottle, a can, a jar or some other container suitable for cosmetic formulations.
  • the agent (a) is characterized by its content in the component (a1) which is essential to the invention. amino-functionalized silicone polymer (a1) on average (a)
  • the agent (a) contains at least one amino-functionalized silicone polymer.
  • the amino-functionalized silicone polymer can alternatively also be referred to as aminosilicone or amodimethicone.
  • Silicone polymers are generally macromolecules with a molecular weight of at least 500 g / mol, preferably at least 1000 g / mol, more preferably at least 2500 g / mol, particularly preferably at least 5000 g / mol, which comprise repeating organic units.
  • the maximum molecular weight of the silicone polymer depends on the degree of polymerisation (number of polymerised monomers) and the batch size and is also determined by the polymerisation method. For the purposes of the present invention, it is preferred if the maximum molecular weight of the silicone polymer is not more than 10 7 g / mol, preferably not more than 10 6 g / mol and particularly preferably not more than 10 5 g / mol.
  • the silicone polymers comprise many Si — O repeating units, it being possible for the Si atoms to carry organic radicals such as, for example, alkyl groups or substituted alkyl groups.
  • a silicone polymer is therefore also referred to as a polydimethylsiloxane.
  • these are based on more than 10 Si-O repeat units, preferably more than 50 Si-O repeat units and especially preferably more than 100 Si-O repeat units, very particularly preferably more than 500 Si-O repeat units.
  • An amino-functionalized silicone polymer is understood to mean a functionalized silicone which carries at least one structural unit with an amino group.
  • the amino-functionalized silicone polymer preferably carries a plurality of structural units each with at least one amino group.
  • An amino group is understood to mean a primary amino group, a secondary amino group and a tertiary amino group. All of these amino groups can be protonated in an acidic medium and are then in their cationic form.
  • amino-functionalized silicone polymers (a1) if they carry at least one primary, at least one secondary and / or at least one tertiary amino group. Intensive dyeings with the best wash fastness were obtained, however, if an amino-functionalized silicone polymer (a1) was used in the medium (a) which contains at least one secondary amino group.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (a) contains at least one amino-functionalized silicone polymer (a1) with at least one secondary amino group.
  • the secondary amino group (s) can be located at various positions on the amino-functionalized silicone polymer. Very particularly good effects were found when an amino-functionalized silicone polymer (a1) was used that has at least one, preferably several, structural units of the formula (Si-amino). -Amino) In the structural units of the formula (Si-amino), the abbreviations ALK1 and ALK2 stand independently of one another for a linear or branched, divalent Ci-C2o-alkylene group.
  • a multicomponent packaging unit is characterized in that the agent (a) contains at least one amino-functionalized silicone polymer (a1) which comprises at least one structural unit of the formula (Si-amino), -Amino) where
  • ALK1 and ALK2 independently of one another for a linear or branched, bivalent Ci-
  • the positions marked with an asterisk (*) indicate the bond to further structural units of the silicone polymer.
  • the silicon atom adjacent to the star can be bonded to a further oxygen atom
  • the oxygen atom adjacent to the star can be bonded to a further silicon atom or to a Ci-C6-alkyl group.
  • a divalent Ci-C2o-alkylene group can alternatively also be referred to as a divalent or double-bonded Ci-C2o-alkylene group, which means that each grouping ALK1 or AK2 can form two bonds.
  • ALK1 there is a bond from the silicon atom to the ALK1 group, and the second bond is between ALK1 and the secondary amino group.
  • ALK2 one bond is from the secondary amino group to the ALK2 moiety, and the second bond is between ALK2 and the primary amino group.
  • Examples of a linear divalent Ci-C2o-alkylene group are, for example, the methylene group (-CH2-), the ethylene group (-CH2-CH2-), the propylene group (-CH2-CH2-CH2-) and the butylene group (-CH2- CH2-CH2-CH2-).
  • the propylene group (-CH2-CH2-CH2-) is particularly preferred.
  • divalent alkylene groups can also be branched. Examples of branched, divalent C3-C2o-alkylene groups are (-CH2-CH (CH3) -) and (-CH2-CH (CH3) -CH2-).
  • the structural units of the formula (Si-amino) represent repeating units in the amino-functionalized silicone polymer (a1), so that the silicone polymer comprises several structural units of the formula (Si-amino).
  • Particularly suitable amino-functionalized silicone polymers (a1) with at least one secondary amino group are listed below.
  • the multicomponent packaging unit according to the invention comprises an agent (a) which contains at least one amino-functionalized silicone polymer (a1) which comprises structural units of the formula (Si-I) and the formula (Si-II)
  • a multicomponent packaging unit is characterized in that the agent (a) contains at least one amino-functionalized silicone polymer (a1) which comprises structural units of the formula (Si-I) and the formula (Si-II)
  • a corresponding amino-functionalized silicone polymer with the structural units (Si-I) and (Sill) is, for example, the commercial product DC 2-8566 or Dowsil 2-8566 Amino Fluid, which is sold commercially by the Dow Chemical Company and which has the name “Siloxanes and Silicones, 3 - [(2-Aminoethyl) amino] -2-methylpropyl Me, Di-Me-Siloxane ”and the CAS number 106842-44-8.
  • Another particularly preferred commercial product is Dowsil AP-8658 Amino Fluid, which is also sold commercially by the Dow Chemical Company.
  • a multicomponent packaging unit is characterized in that the agent (a) contains at least one amino-functional silicone polymer (a1) of the formula of the formula (Si-III), where m and n denote numbers which are chosen such that the sum (n + m) is in the range from 1 to 1000, n is a number in the range from 0 to 999 and m is a number in the range from 1 to
  • kit-of-parts preferred according to the invention are characterized in that the agent (a) contains at least amino-functional silicone polymer (a1) of the formula of the formula (Si-IV), in which p and q denote numbers which are chosen so that the sum (p + q) is in the range from 1 to 1000, p is a number in the range from 0 to 999 and q is a number in the range from 1 to
  • R1 and R2 which are different, denote a hydroxyl group or a C1-4 alkoxy group, at least one of the groups R1 to R2 denoting a hydroxyl group.
  • the silicones of the formulas (Si-III) and (Si-IV) differ in the grouping on the Si atom that carries the nitrogen-containing group:
  • R2 denotes a hydroxyl group or a C1-4 alkoxy group, while the remainder in formula (Si-IV) is a methyl group.
  • Kit-of-parts according to the invention in which an agent (a) is applied to the keratin fibers, which contains at least one amino-functional silicone polymer (a1) of the formula of the formula (Si-V), have also proven to be particularly effective with regard to the desired effects. contains in the
  • A represents a group -OH, -0-Si (CH3) 3, -0-Si (CH 3 ) 2 0H, -0-Si (CH 3 ) 2 0CH3,
  • the individual siloxane units with the indices b, c and n are randomly distributed, i.e. they do not necessarily have to be block copolymers.
  • the agent (a) can also contain one or more different amino-functionalized silicone polymers, which are represented by the formula (Si-VI)
  • R is a hydrocarbon or a hydrocarbon radical with 1 to about 6 carbon atoms
  • Q is a polar radical of the general formula -R 1 HZ, where R 1 is a divalent, connecting group which is bonded to hydrogen and the radical Z, composed of carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon , Hydrogen and nitrogen atoms, and Z is an organic, amino-functional radical containing at least one amino-functional group;
  • "a” takes values in the range of about 0 to about 2
  • "b” takes values in the range of about 1 to about 3
  • a” + "b” is less than or equal to 3
  • "c” is a number in the range from about 1 to about 3
  • x is a number in the range from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25, and
  • Non-limiting examples of the groups represented by R include alkyl groups such as methyl, ethyl, propyl, isopropyl, isopropyl, butyl, isobutyl, amyl, isoamyl, hexyl, isohexyl, and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl groups such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halogenated hydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mer
  • R 1 examples include methylene, ethylene, propylene, hexamethylene, decamethylene, - CH 2 CH (CH 3 ) CH2-, phenylene, naphthylene, -CH2CH2SCH2CH 2-, -CH2CH2OCH2-, -OCH2CH2-, -OCH 2 CH2CH2-, - CH 2 CH (CH 3) C (0) 0CH2-, - (CH 2) 3 CC (0) 0CH 2 CH 2 -, -CeH 4 C 6 H 4 -, -CeH 4 CH 2 C 6 H 4 -; and - (CH 2) 3 C (0) SCH 2 CH 2 - a.
  • Z is an organic, amino-functional radical containing at least one functional amino group.
  • One possible formula for Z is NH (CH2) z NH 2 , where z is 1 or more.
  • Another possible formula for Z is -NH (CH 2) z (CH 2) zz NH wherein both z and zz independently 1 or more, this structure diamino-ring structures comprising, as piperazinyl.
  • Most preferably Z is an -NHCH2CH 2NH2 radical.
  • Another possible formula for Z is -N (CH2) z (CH2) zzNX2 or -NX2, wherein each X of X2 is independently selected from the group consisting of hydrogen and alkyl groups having 1 to 12 carbon atoms, and zz is zero.
  • Q is most preferably a polar, amine-functional radical of the formula -CH2CH2CH2NHCH2CH2NH 2.
  • a takes values in the range from about 0 to about 2
  • b takes values in the range from about 2 to about 3
  • a "+” b is less than or equal to 3
  • c is a number ranging from about 1 to about 3.
  • c SiO ( 4-C) / 2 units ranges from about 1: 2 to 1:65, preferably from about 1: 5 to about 1:65, and most preferably from about 1:15 to about 1:20 If one or more silicones of the above formula are used, then the various variable substituents in the above formula can be different for the various silicone components that are present in the silicone mixture.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (a) is an amino-functional silicone polymer of the formula (Si-VII)
  • - G is -H, a phenyl group, -OH, -0-CH 3 , -CH 3 , -0-CH 2 CH 3 , -CH 2 CH 3 , -O-
  • n and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular assumes from 1 to 10,
  • R ' is a monovalent radical selected from o -QN (R ") - CH 2 -CH 2 -N (R") 2 o -QN (R ") 2 o -QN + (R") 3 A- o - QN + H (R ") 2 A- o -QN + H 2 (R") A- o -QN (R ”) - CH 2 -CH 2 -N + R" H 2 A-, where each Q represents one chemical bond, -CH 2 -, -CH 2 -CH 2 -, -CH 2 CH 2 CH 2 -, -C (CH 3 ) 2 -, -CH 2 CH 2 CH 2 CH 2 -, -CH 2 C ( CH 3 ) 2 -, -CH (CH 3 ) CH 2 CH 2 -,
  • R stands for identical or different radicals from the group -H, -phenyl, -benzyl, -CH 2 - CH (CH 3 ) Ph, the Ci- 2 o-alkyl radicals, preferably -CH 3 , -CH 2 CH 3 , - CH 2 CH 2 CH 3 , -CH (CH 3 ) 2 , -CH 2 CH 2 CH 2 H 3 , -CH 2 CH (CH 3 ) 2 , -CH (CH 3 ) CH 2 CH 3 , -C (CH 3 ) 3 , and A represents an anion, which is preferably selected from chloride, bromide, iodide or methosulfate.
  • Multi-component packaging unit characterized in that the agent (a) contains at least one amino-functional silicone polymer (a1) of the formula (Si-Vlla),
  • m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably assumes values from 1 to 2000, in particular from 1 to 10.
  • these silicones are referred to as trimethylsilylamodimethicones.
  • the agent (a) contains at least one amino-functional silicone polymer of the formula (Si-VIIb) R- [Si (CH3) 2-0] ni [Si (R) -0] m- [Si (CH 3 ) 2] n2-R (Si-Vllb),
  • n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2000, is preferably between 50 and 150, the sum (n1 + n2) preferably assuming values from 0 to 1999 and in particular from 49 to 149 and m preferably from 1 to 2000, in particular from 1 to 10.
  • agents (a) according to the invention which contain an amino-functional silicone polymer whose amine number is above 0.25 meq / g, preferably above 0.3 meq / g and in particular above 0.4 meq / g.
  • the amine number stands for the milli-equivalents of amine per gram of the amino-functional silicone. It can be determined by titration and also given in the unit mg KOH / g.
  • kit-of-parts in the first container can also comprise an agent (a) which contained a special 4-morpholinomethyl-substituted silicone polymer (a1).
  • This amino-functionalized silicone polymer comprises structural units of the formulas (S1-VIII) and the formula (Si-IX)
  • a very particularly preferred amino-functionalized silicone polymer is available under the name Amodimethicone / morpholinomethyl silsesquioxane copolymer known and commercially available from Wacker in the form of the raw material Belsil ADM 8301 E.
  • the 4-morpholinomethyl-substituted silicone that can be used, for example, is a silicone which has structural units of the formulas (Si-VIII), (Si-IX) and (Si-X) in which
  • R1 is -CH 3 , -OH, -OCH 3 , -O-CH2CH3, -O-CH2CH2CH3, or -0-CH (CH 3 ) 2 ;
  • R2 stands for -CH3, -OH, or -OCH3.
  • Particularly preferred agents (a) according to the invention contain at least one 4-morpholinomethyl-substituted silicone of the formula (Si-Xl)
  • R1 is -CH 3 , -OH, -OCH3, -O-CH2CH3, -O-CH2CH2CH3, or -0-CH (CH 3 ) 2 ;
  • R2 stands for -CH3, -OH, or -OCH3.
  • B represents a group -OH, -0-Si (CH3) 3, -0-Si (CH 3 ) 2 0H, -0-Si (CH 3 ) 2 0CH3,
  • Structural formula (Si-Xl) is intended to make it clear that the siloxane groups n and m do not necessarily have to be bound directly to an end group B or D, respectively. Rather, in preferred formulas (Si-VI) a> 0 or b> 0 and in particularly preferred formulas (Si-VI) a> 0 and c> 0, ie the terminal grouping B or D is preferably attached to a dimethylsiloxy grouping bound. In formula (Si-VI) too, the siloxane units a, b, c, m and n are preferably distributed randomly.
  • the agent (a) used in the multicomponent packaging unit according to the invention is very particularly preferably a concentrate which contains the amino-functionalized silicone polymer (s) (a1) in correspondingly large quantities. Particularly good dyeing results were obtained when the agent (a) - based on the total weight of the agent (a) - has one or more amino-functionalized silicone polymers (a1) in a total amount of 5 to 100% by weight, preferably 25 to 100% by weight. -%, more preferably from 50 to 100% by weight and very particularly preferably from 75 to 100% by weight.
  • the aminosilicones (a1) are either used as such, or a solubilizing agent, diluent or carrier is mixed with the aminosilicones (a1) in small amounts.
  • a multi-component packaging unit according to the invention is characterized in that the agent (a) - based on the total weight of the agent (a) - has one or more amino-functionalized silicone polymers (a1) in a total amount of 5 to 100 wt. -%, preferably from 25 to 100% by weight, more preferably from 50 to 100% by weight and very particularly preferably from 75 to 100% by weight.
  • the amino-functionalized silicone polymer (a1) - or a mixture of aminosilicones (a1) - can be used as a substance in the form of a concentrate.
  • the agent (a) is then mixed with the agent (b).
  • agent (a) can therefore additionally contain at least one solvent as an optional component.
  • Suitable solvents are, for example, solvents from the group consisting of 1,2-propylene glycol, 1,3-propylene glycol, ethylene glycol, 1,2-butylene glycol, dipropylene glycol, ethanol, isopropanol, diethylene glycol monoethyl ether, glycerol, phenoxyethanol and benzyl alcohol.
  • 1,2-propylene glycol is very particularly preferred.
  • a multicomponent packaging unit is characterized in that the agent (a) has at least one solvent from the group consisting of 1,2-propylene glycol, 1,3-propylene glycol, ethylene glycol, 1,2-butylene glycol, dipropylene glycol , Ethanol, isopropanol, diethylene glycol monoethyl ether, glycerol, phenoxyethanol and benzyl alcohol, very particularly preferably 1,2-propylene glycol.
  • 1,2-Propylene glycol is alternatively referred to as 1,2-propanediol and has the CAS numbers 57-55-6 [(RS) -1, 2-dihydroxypropane], 4254-14-2 [(R) -1 , 2-Dihydroxypropane] and 4254-15-3 [(S) -1, 2-Dihydroxypropane]
  • Ethylene glycol is alternatively also referred to as 1,2-Ethanediol and has the CAS number 107-21-1.
  • Glycerine is alternatively also known as 1, 2,3-propanetriol and has the CAS number 56-81-5.
  • Phenoxyethanol has the Cas number 122-99-6.
  • a multi-component packaging unit is characterized in that the agent (a) - based on the total weight of the agent (a) - has one or more solvents in a total amount of 1.0 to 80.0% by weight, preferably 2.0 to 50.0% by weight, more preferably 3.0 to 30.0% by weight and very particularly preferably 4.0 to 20.0% by weight.
  • a multicomponent packaging unit is characterized in that the agent (a) - based on the total weight of the agent (a) - 1.0 to 95.0% by weight, preferably 2.0 to 15.0% by weight, more preferably 3.0 to 15.0% by weight and very particularly preferably 4.0 to 10.0% by weight of 1,2-propylene glycol.
  • the agent (a) can be a concentrate which preferably contains the ingredient (a1) essential to the invention as the main component.
  • the agent additionally contains at least one solvent
  • the two main constituents (a1) and solvent are preferably contained in the agent (a).
  • a multicomponent packaging unit is characterized in that the agent (a) - based on the total weight of the agent (a) - is less than 10.0% by weight, preferably less than 5.0% by weight, more preferably contains less than 2.5% by weight and very particularly preferably less than 1.0% by weight of water.
  • a multicomponent packaging unit is characterized in that the agent (a) - based on the total weight of the agent (a) - has a water content between 0 and 10.0% by weight, preferably between 0 and 5.0% by weight, more preferably between 0 and 2.5% by weight and very particularly preferably between 0 and 1.0% by weight.
  • the homogeneity of the color result also depends on the agent in which the coloring compounds (ie the pigments) are incorporated. If the pigments were stored together with the amino silicone (a1) in the form of a premix and this was only mixed with a cosmetic carrier formulation shortly before use, the color intensity and the wash fastness could be significantly improved. However, it has been shown that this type of assembly is also associated with some disadvantages. If the mixture of aminosilicone (a1) and pigment was stored for a long period of time, the two components appeared to react with one another as a result of the storage time to take place. Although this reaction was slowed down in an anhydrous or anhydrous environment, it was still significant after storage periods of several weeks. When coloring appropriately stored agents, a very poor miscibility of the aminosilion / pigment mixture with the carrier material was observed. As a result, very inhomogeneous color results were also obtained.
  • agent (a) itself does not contain any pigments or if these are only used in very small amounts in the agent (a).
  • Very small amounts of pigment can, for example, be incorporated into agent (a) in order to color it or to give it a more aesthetic appearance.
  • a multicomponent packaging unit is characterized in that the agent (a) - based on the total weight of the agent (a) - has one or more pigments in a total content of less than 0.1 wt. %, preferably less than 0.05% by weight and very particularly preferably less than 0.01% by weight.
  • a multicomponent packaging unit is characterized in that the agent (a) - based on the total weight of the agent (a) - has a pigment content of between 0 and 0.1 wt. %, preferably between 0 and 0.05% by weight and very particularly preferably between 0 and 0.01% by weight.
  • the agent (a) does not contain any pigments.
  • the multi-component packaging unit comprises means (b) in a second container.
  • the container can be, for example, a sachet, a bottle, a can, a jar or some other suitable container for cosmetic formulations.
  • agent (b) is a buffered formulation which can be in the form of a gel or an emulsion, for example.
  • the agent (b) is a coloring gel, a coloring gel, a coloring shampoo, a coloring foam or some other coloring, cosmetically acceptable formulation.
  • agent (b) preferably contains a high proportion of water. It has been found that the means (b) are particularly well suited for use which - based on the total weight of the means (b) - 50.0 to 98.0% by weight, preferably 60.0 to 90.0 % By weight, more preferably 70.0 to 90.0% by weight and very particularly preferably 75.0 to 90.0% by weight of water (b1).
  • a multicomponent packaging unit according to the invention is characterized in that the agent (b) - based on the total weight of the agent (b) - 50.0 to 98.0% by weight, preferably 60.0 up to 90.0% by weight, more preferably 70.0 to 90.0% by weight and very particularly preferably 75.0 to 90.0% by weight of water (b1).
  • the agent (b) of the kit-of-parts according to the invention contains at least one buffer system (b2) composed of at least one inorganic or organic acid (b2-l) and at least one salt of this acid (b2-ll).
  • a buffer or a buffer system is usually understood to mean a mixture of a weak or moderately strong acid (e.g. acetic acid) with a practically completely dissociated neutral salt of the same acid (e.g. sodium acetate). If a little base or acid is added, the pH value hardly changes (buffering).
  • the effect of the buffer substances contained in a buffer solution is based on the trapping reaction of hydrogen or hydroxide ions with the formation of weak acids or bases due to their dissociation equilibrium.
  • a buffer system can be formed from a mixture of an inorganic or organic acid and a corresponding salt of this acid.
  • Acids can be buffered by all salts from weak acids and strong bases, bases by salts from strong acids and weak bases.
  • the strong (completely dissociated into ions) hydrochloric acid can, for. B. be buffered by adding sodium acetate. According to the balance
  • hydrochloric acid is converted into weak acetic acid by sodium acetate with the formation of sodium chloride, which dissociates only to a very small extent in the presence of an excess of sodium acetate. Buffers that act against both acids and bases are mixtures of weak acids and their salts.
  • an inorganic buffer system (b2) is understood to mean a mixture of an inorganic acid (b2-1) and its conjugated corresponding inorganic base (b2-II).
  • an organic buffer system (b2) is understood to mean a mixture of an organic acid (b2-1) and its conjugated corresponding base (b2-II). Due to the organic acid residue, the conjugated corresponding base of the organic acid (b2-II) is also organic.
  • the cation present to neutralize the charge of the acid anion can be inorganic or organic.
  • inorganic acids examples include sulfuric acid (H 2 SO 4 ), hydrochloric acid (HCl) and phosphoric acid (H3PO 4 ).
  • Phosphoric acid is a moderately strong acid which is particularly preferred.
  • a particularly suitable inorganic acid (b2-l) is potassium dihydrogen phosphate.
  • Potassium dihydrogen phosphate has the empirical formula KH2PO4 and has the CAS number 7778-77-0.
  • Potassium dihydrogen phosphate has a molar mass of 136.09 g / mol. It is readily soluble in water (222 g / l at 20 ° C) and is acidic in water.
  • a 5% solution of potassium dihydrogen phosphate in water has a pH value of 4.4.
  • sodium dihydrogen phosphate Another very particularly suitable inorganic acid (b2-l) is sodium dihydrogen phosphate.
  • Sodium dihydrogen phosphate has the empirical formula NaH 2 PC> 4 and has the CAS numbers 7558-80-7 (anhydrate), 10049-21-5 (monohydrate) and 13472-35-0 (dihydrate).
  • the anhydrous sodium dihydrogen phosphate has a molar mass of 119.98 g / mol.
  • Sodium dihydrogen phosphate reacts acidic in aqueous solution.
  • Dipotassium hydrogen phosphate is particularly preferred as the corresponding salt of the aforementioned two acids (b2-II).
  • Dipotassium hydrogen phosphate has the empirical formula K2HPO4 and has the CAS numbers 7758-11-4 (anhydrous) and 16788-57-1 (trihydrate).
  • the anhydrous dipotassium hydrogen phosphate has a molar mass of 174.18 g / mol.
  • Dipotassium hydrogen phosphate has an alkaline reaction in aqueous solution.
  • Disodium hydrogen phosphate is also particularly preferred as the corresponding salt of the aforementioned two acids (b2- II).
  • Disodium hydrogen phosphate has the empirical formula Na 2 HPC> 4 and has the CAS numbers 7558-79-4 (anhydrous), 10028-24-7 (dihydrate), 7782-85-6 (heptahydrate) and 10039-32-4 (dodecahydrate) .
  • the anhydrous disodium hydrogen phosphate has a molar mass of 141.96 g / mol.
  • Disodium hydrogen phosphate has an alkaline reaction in aqueous solution.
  • organic acids (b2-l) are citric acid, succinic acid, tartaric acid, lactic acid, acetic acid, malic acid, malonic acid and maleic acid.
  • Examples of the corresponding salts of these organic acids (b2-II) are the sodium and potassium salts of citric acid, the sodium and potassium salts of succinic acid, the sodium and potassium salts of tartaric acid, the sodium and potassium salts of lactic acid, the sodium and Potassium salts of acetic acid, the sodium and potassium salts of malic acid, the sodium and potassium salts of malonic acid and the sodium and potassium salts of maleic acid
  • a buffer capacity of 1 corresponds to a buffer solution whose pH value changes by one unit when 1 mol of acid or base is added per liter of buffer solution.
  • the means (b) had a particularly high buffer capacity when the acid (b2-l) and its corresponding salt (b2-II) were used in optimally matched molar ratios. It is particularly preferred in this context if the inorganic or organic acid (b2-l) and the salt or salts of the inorganic or organic acid (b2) in a molar ratio (b2-l) / (b2-II) of 1: 15 to 15: 1, preferably from 1:10 to 10: 1, more preferably from 1: 5 to 5: 1 and very particularly preferably from 1: 3 to 1: 1.
  • the acid (b2-l) and the salt (s) (b2-ll) thereof are used either in approximately the same molar total amounts, or if the salts (b2-ll ) are contained in the mean (b) in an up to three-fold molar excess in relation to the acid (b2-l).
  • 100 g of the agent according to the invention contain 0.9 g of phosphoric acid (H3PO4) and as a buffer system (b2-l)
  • 100 g of the agent according to the invention contain as a buffer system (b2-l) 2.57 mmol of potassium dihydrogen phosphate and (b2-II) 5.12 mmol of disodium hydrogen phosphate
  • a multi-component packaging unit is characterized in that the agent (b) contains the inorganic or organic acid (s) (b2-l) and the salt or salts of this acid (s) (b2-ll) in a molar ratio (b2-l) / (b2-ll) from 1:15 to 15: 1, preferably from 1:10 to 10: 1, more preferably from 1: 5 to 5: 1 and very particularly preferably from 1: 3 to 1: 1.
  • the agent (b) contains the inorganic or organic acid (s) (b2-l) and the salt or salts of this acid (s) (b2-ll) in a molar ratio (b2-l) / (b2-ll) from 1:15 to 15: 1, preferably from 1:10 to 10: 1, more preferably from 1: 5 to 5: 1 and very particularly preferably from 1: 3 to 1: 1.
  • buffer systems (b2) can also be used:
  • a buffer system (b2) that contains at least one salt of the dihydrogen phosphate H2PO4 (b2-I) and at least one salt of the hydrogen phosphate HPO4 2 (b2-II) has proven to be particularly suitable, the salt of the dihydrogen phosphate preferably being selected from the group consisting of sodium dihydrogen phosphate and potassium dihydrogen phosphate and wherein the salt of the hydrogen phosphate is preferably selected from the group consisting of disodium hydrogen phosphate and dipotassium hydrogen phosphate.
  • a multi-component packaging unit according to the invention is characterized in that the means (b) is a
  • a buffer system which comprises succinic acid (b2-l) and a salt of succinic acid (b2-l), the salt of succinic acid (b2-ll) preferably being selected from the sodium salt of Succinic acid and the potassium salt of succinic acid.
  • a multi-component packaging unit according to the invention is characterized in that the means (b) is a
  • (b2) contains a buffer system of succinic acid (b2-l) and at least one salt of succinic acid (b2-ll).
  • the pH to which the agent (b) according to the invention is adjusted depends on the amount of acid or its salts used in the agent. It has been shown that good results could be achieved in particular when a buffer system (b2) was used in the mean (b), which enables the setting of a pH value from 6.0 to 8.0, preferably from 6.0 to 7.5, more preferably from 6.0 to 7.2 and very particularly preferably from 6.0 to 7.0 are allowed.
  • a multi-component packaging unit according to the invention is characterized in that the agent (b) has a pH of 6.0 to 8.0, preferably 6.0 to 7.5, more preferably 6.0 to 7.2 and very particularly preferably from 6.0 to 7.0.
  • the pH values in the context of the present invention are pH values that were measured at a temperature of 22 ° C.
  • the preferably highly concentrated and water-poor concentrate (a) is mixed with the actual colorant (b).
  • the aminosilicones (a1) are brought into contact with the pigments (b3) present in the buffered, water-containing medium, so that the previously described interaction of the aminosilicones (a1) and pigments (b3) only starts from this moment of mixing.
  • this type of packaging in the dyeing process leads to color results that are intense and washable, but are also characterized by particularly good storage stability and reproducibility of the color result. coloring compound (b3) in the middle (bl)
  • the agent (b) contains at least one coloring compound (b3).
  • coloring compounds are understood to mean substances which are capable of imparting coloring to the keratin material.
  • Particularly suitable coloring compounds can be selected from the group of pigments, substantive dyes, photochromic dyes and thermochromic dyes.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (b) contains at least one coloring compound (b3) from the group of pigments, substantive dyes, photochromic dyes and thermochromic dyes.
  • the agent (b) explicitly very particularly preferably contains at least one pigment (b3) as the coloring compound.
  • Pigments in the context of the present invention are understood to mean coloring compounds which at 25 ° C. in water have a solubility of less than 0.5 g / L, preferably less than 0.1 g / L, even more preferably less than 0, 05 g / L.
  • the water solubility can be achieved, for example, using the method described below: Weigh out 0.5 g of the pigment in a beaker. A stir fry is added. Then one liter of distilled water is added. This mixture is heated to 25 ° C. for one hour while stirring on a magnetic stirrer. If undissolved constituents of the pigment are still visible in the mixture after this period, the solubility of the pigment is below 0.5 g / L.
  • the mixture is filtered. Stay on top of that If the filter paper contains a proportion of undissolved pigments, the solubility of the pigment is below 0.5 g / L.
  • Suitable color pigments can be of inorganic and / or organic origin.
  • an agent (b) according to the invention is characterized in that it contains at least one coloring compound (b3) from the group of inorganic and / or organic pigments.
  • Preferred color pigments are selected from synthetic or natural inorganic pigments.
  • Inorganic color pigments of natural origin can be made from chalk, ocher, umber, green earth, burnt Terra di Siena or graphite, for example.
  • black pigments such as. B. iron oxide black, colored pigments such. B. ultramarine or iron oxide red and fluorescent or phosphorescent pigments can be used.
  • Colored metal oxides, hydroxides and oxide hydrates, mixed-phase pigments, sulfur-containing silicates, silicates, metal sulfides, complex metal cyanides, metal sulfates, metal chromates and / or metal molybdates are particularly suitable.
  • Particularly preferred color pigments are black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI77289 ), Iron blue (Ferric Ferrocyanide, CI77510) and / or carmine (Cochineal).
  • Color pigments which are likewise particularly preferred according to the invention are colored pearlescent pigments. These are usually based on mica and / or mica and can be coated with one or more metal oxides. Mica is one of the layered silicates. The most important representatives of these silicates are muscovite, phlogopite, paragonite, biotite, lepidolite and margarite. To produce the pearlescent pigments in conjunction with metal oxides, the mica, predominantly muscovite or phlogopite, is coated with a metal oxide.
  • synthetic mica coated with one or more metal oxide (s) can also be used as the pearlescent pigment.
  • Particularly preferred pearlescent pigments are based on natural or synthetic mica (mica) and are coated with one or more of the aforementioned metal oxides. The color of the respective pigments can be varied by varying the layer thickness of the metal oxide (s).
  • a multicomponent packaging unit is characterized in that the agent (b) contains at least one coloring compound (b3) from the group of inorganic pigments, which is preferably selected from the group of colored metal oxides, metal hydroxides, metal oxide hydrates, silicates, metal sulfides, complex metal cyanides, metal sulfates, bronze pigments and / or from colored pigments based on mica or mica coated with at least one metal oxide and / or a metal oxychloride.
  • the agent (b) contains at least one coloring compound (b3) from the group of inorganic pigments, which is preferably selected from the group of colored metal oxides, metal hydroxides, metal oxide hydrates, silicates, metal sulfides, complex metal cyanides, metal sulfates, bronze pigments and / or from colored pigments based on mica or mica coated with at least one metal oxide and / or a metal oxychloride.
  • an agent (b) according to the invention is characterized in that it contains at least one coloring compound (b3) from the group of pigments which is selected from pigments based on mica or mica which are mixed with one or more metal oxides from the Group of titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and / or brown iron oxide (CI 77491, CI 77499), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007 , Pigment Blue 29), chromium oxide hydrate (CI 77289), chromium oxide (CI 77288) and / or iron blue (Ferric Ferrocyanide, CI 77510) are coated.
  • color pigments are commercially available, for example, under the trade names Rona®, Colorona®, Xirona®, Dichrona® and Timiron® from Merck, Ariabel® and Unipure® from Sensient, Prestige® from Eckart Cosmetic Colors and Sunshine® available from Sunstar.
  • Colorona® Particularly preferred color pigments with the trade name Colorona® are, for example:
  • color pigments with the trade name Unipure® are, for example:
  • the agent (b) according to the invention can also contain one or more color-imparting compounds (b3) from the group of organic pigments
  • the organic pigments according to the invention are correspondingly insoluble, organic dyes or color lakes, for example from the group of nitroso, nitro, azo, xanthene, anthraquinone, isoindolinone, isoindoline, quinacridone, perinone, perylene -, Diketopyrrolopyorrole, indigo, thioindido, dioxazine, and / or triarylmethane compounds can be selected.
  • Particularly suitable organic pigments are, for example, carmine, quinacridone, phthalocyanine, sorghum, blue pigments with the color index numbers CI 42090, CI 69800, CI 69825, CI 73000, CI 74100, CI 74160, yellow pigments with the color index numbers CI 11680 , CI 11710, CI 15985, CI 19140, CI 20040, CI 21100, CI 21108, CI 47000, CI 47005, green pigments with the color index numbers CI 61565, CI 61570, CI 74260, orange pigments with the color index numbers CI 11725 , CI 15510, CI 45370, CI 71105, red pigments with the color index numbers CI 12085, CI 12120, CI 12370, CI 12420, CI 12490, CI 14700, CI 15525, CI 15580, CI 15620, CI 15630, CI 15800
  • a multicomponent packaging unit is characterized in that the agent (b) contains at least one coloring compound (b3) from the group of organic pigments, which is preferably selected from the group of carmine, quinacridone, phthalocyanine, Sorgho, blue pigments with the color index numbers CI 42090, CI 69800, CI 69825, CI 73000, CI 74100, CI 74160, yellow pigments with the color index numbers CI 11680, CI 11710, CI 15985, CI 19140, CI 20040, CI 21100, CI 21108, CI 47000, CI 47005, green pigments with the color index numbers CI 61565, CI 61570, CI 74260, orange pigments with the color index numbers CI 11725, CI 15510, CI 45370, CI 71105, red pigments with the Color index numbers CI 12085, CI 12120, CI 12370,
  • the organic pigment can also be a colored lacquer.
  • the term colored lacquer is understood to mean particles which comprise a layer of absorbed dyes, the unit of particles and dye being insoluble under the above-mentioned conditions.
  • the particles can be, for example, inorganic substrates, which can be aluminum, silica, calcium borosilicate, calcium aluminum borosilicate or also aluminum.
  • the alizarin color varnish for example, can be used as the color varnish.
  • the use of the aforementioned pigments in agent (b) is very particularly preferred. It is also preferred if the pigments used have a certain particle size. It is therefore advantageous according to the invention if the at least one pigment has an average particle size D50 of from 1.0 to 50 ⁇ m, preferably from 5.0 to 45 ⁇ m, more preferably from 10 to 40 ⁇ m, in particular from 14 to 30 ⁇ m.
  • the mean particle size D50 can be determined using dynamic light scattering (DLS), for example.
  • a corresponding complex mitallcyanid is, for example, Unipure Blue LC 689, which is also referred to as ammonium iron (3+) hexakis (cyano-C) ferrate (4-) and has the CAS number 25869-00-5.
  • An alternative name for this is Pigment Blue 27.
  • the organic pigment with the color index number CI 69800 can be obtained under the trade name Paliogen Blue L 6387, for example.
  • Alternative names are Pigment Blue 60 and Indanthron.
  • the organic pigment with the color index number CI 19140 can be purchased commercially, for example, under the trade name Unipure Yellow LC 125. An alternative name for this is FD&C Yellow 5, Aluminum Lake.
  • the coloring compounds (b3) represent the third essential ingredient of the invention in agent (b).
  • the pigment or pigments are very particularly preferably used in certain quantity ranges in agent (b). Particularly good results have been obtained when the agent (b) - based on the total weight of the agent (b) - contains one or more pigments (b3) in a total amount of 0.05 to 10.0% by weight, preferably 0.1 to 7.0% by weight, more preferably from 0.2 to 5.0% by weight and very particularly preferably from 0.3 to 3.0% by weight.
  • an agent according to the invention is characterized in that the agent (b) - based on the total weight of the agent (b) - contains one or more pigments (b3) in a total amount of 0.05 to 10.0 wt %, preferably 0.1 to 7.0% by weight, more preferably from 0.2 to 5.0% by weight and very particularly preferably from 0.3 to 3.0% by weight.
  • the agent (b) can also contain one or more substantive dyes as coloring compounds (b3).
  • Substantive dyes are dyes that are absorbed directly onto the hair and do not require an oxidative process to develop the color. Substantive dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones, triarylmethane dyes or indophenols.
  • the substantive dyes for the purposes of the present invention have a solubility in water (760 mmHg) at 25 ° C. of more than 0.5 g / L and are therefore not to be regarded as pigments.
  • the substantive dyes preferably have a solubility in water (760 mmHg) at 25 ° C. of more than 1.0 g / l.
  • Substantive dyes can be divided into anionic, cationic and nonionic substantive dyes.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (b) contains at least one coloring compound (b3) from the group of anionic, nonionic and cationic substantive dyes.
  • Suitable cationic substantive dyes are, for example, Basic Blue 7, Basic Blue 26, HC Blue 16, Basic Violet 2 and Basic Violet 14, Basic Yellow 57, Basic Red 76, Basic Blue 16, Basic Blue 347 (Cationic Blue 347 / Dystar), HC Blue No. 16, Basic Blue 99, Basic Brown 16, Basic Brown 17, Basic Yellow 57, Basic Yellow 87, Basic Orange 31, Basic Red 51 Basic Red 76.
  • Nonionic nitro and quinone dyes and neutral azo dyes can be used as nonionic substantive dyes.
  • Suitable nonionic substantive dyes are those under the international names or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse Orange 3, HC Red 1, HC Red 3, HC Red 10, HC Red 11, HC Red 13, HC Red BN, HC Blue 2, HC Blue 11, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9 known compounds, as well 1,4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1,4-bis- (2-hydroxyethyl) -amino-2-nitrobenzene, 3-nitro-4- (2-hydroxyethyl) -aminophenol, 2- (2-hydroxyethyl) amino-4,6-dinitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitro-1-methylbenzen
  • Anionic substantive dyes are also referred to as acid dyes.
  • Acid dyes are understood to mean substantive dyes which have at least one carboxylic acid group (-COOH) and / or one sulfonic acid group (-SO3H). Depending on the pH, the protonated forms (-COOH, -SO3H) of the carboxylic acid or sulfonic acid groups are in equilibrium with their deprotonated forms (-COO-, -SO3 present). The proportion of protonated forms increases with decreasing pH. If substantive dyes are used in the form of their salts, the carboxylic acid groups or sulfonic acid groups are in deprotonated form and are neutralized with corresponding stoichiometric equivalents of cations to maintain electrical neutrality. Acid dyes according to the invention can also be used in the form of their sodium salts and / or their potassium salts.
  • the acid dyes for the purposes of the present invention have a solubility in water (760 mmHg) at 25 ° C. of more than 0.5 g / L and are therefore not to be regarded as pigments.
  • the acid dyes preferably have a solubility in water (760 mmHg) at 25 ° C. of more than 1.0 g / l.
  • alkaline earth salts such as calcium salts and magnesium salts
  • aluminum salts of acid dyes often have poorer solubility than the corresponding alkali salts. If the solubility of these salts is below 0.5 g / L (25 ° C, 760 mmHg), they do not fall under the definition of a substantive dye.
  • acid dyes are their ability to form anionic charges, the carboxylic acid or sulfonic acid groups responsible for this usually being linked to different chromophoric systems.
  • Suitable chromophoric systems are found, for example, in the structures of nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinone dyes, triarylmethane dyes, xanthene dyes, rhodamine dyes, oxazine dyes and / or indophenol dyes.
  • the agent (b) contains at least one anionic substantive dye (b3) which is selected from the group of nitrophenyl
  • Suitable acid dyes are, for example, one or more compounds from the following group: Acid Yellow 1 (D&C Yellow 7, Citronin A, Ext. D&C Yellow No. 7, Japan Yellow 403, C1 10316, COLIPA No. B001), Acid Yellow 3 (COLIPA n °: C 54, D&C Yellow N ° 10, Quinoline Yellow, E104, Food Yellow 13), Acid Yellow 9 (C1 13015), Acid Yellow 17 (C1 18965), Acid Yellow 23 (COLIPA n ° C 29 , Covacap Jaune W 1100 (LCW), Sicovit Tartrazine 85 E 102 (BASF), Tartrazine, Food Yellow 4, Japan Yellow 4, FD&C Yellow No.
  • Acid Yellow 1 D&C Yellow 7, Citronin A, Ext. D&C Yellow No. 7, Japan Yellow 403, C1 10316, COLIPA No. B001
  • Acid Yellow 3 (COLIPA n °: C 54, D&C Yellow N ° 10, Quinoline Yellow, E104, Food Yellow 13), Acid Yellow 9 (C
  • Acid Yellow 36 (CI 13065), Acid Yellow 121 (CI 18690) , Acid Orange 6 (CI 14270), Acid Orange 7 (2-Naphthol orange, Orange II, C1 15510, D&C Orange 4, COLIPA n ° C015), Acid Orange 10 (Cl 16230; Orange G sodium salt), Acid Orange 11 (CI 45370), Acid Orange 15 (CI 50120), Acid Orange 20 (CI 14600), Acid Orange 24 (BROWN 1; CI 20170; KATSU201; nosodiumsalt; Brown No.201; RESORCIN BROWN; ACID ORANGE 24; Japan Brown 201 ; D&C Brown No.1), Acid Red 14 (Cl14720), Aci d Red 18 (E124, Red 18; CI 16255), Acid Red 27 (E 123, CI 16185, C-Red 46, Echtrot D, FD&C Red Nr.2, Food Red 9, Naphtholrot S), Acid Red 33 (Red 33, Fuchsia Red, D&C Red 33,
  • Acid Green 50 (Brillantklare indispensable BS, Cl 44090, Acid Brilliant Green BS, E 142), Acid Black 1 (Black n ° 401, Naphthalene Black 10B, Amido Black 10B, CI 20470, COLIPA n ° B15), Acid Black 52 (CI 15711), Food Yellow 8 (CI 14270), Food Blue 5, D&C Yellow 8, D&C Green 5, D&C Orange 10, D&C Orange 11, D&C Red 21, D&C Red 27, D&C Red 33, D&C Violet 2 and / or D&C Brown 1.
  • the water solubility of the anionic substantive dyes can be determined, for example, in the following way. 0.1 g of the anionic substantive dye are placed in a beaker. A stir bar is added. Then 100 ml of water are added. This mixture is heated to 25 ° C. on a magnetic stirrer while stirring. It is stirred for 60 minutes. The aqueous mixture is then assessed visually. If there are still undissolved residues, the amount of water is increased - for example in steps of 10 ml. Water is added until the amount of dye used has completely dissolved. If the dye-water mixture cannot be assessed visually due to the high intensity of the dye, the mixture is filtered.
  • the solubility test is repeated with a larger amount of water.
  • the solubility of the dye is 1.0 g / L.
  • Acid Yellow 1 is called 8-hydroxy-5,7-dinitro-2-naphthalenesulfonic acid disodium salt and has a solubility in water of at least 40 g / L (25 ° C).
  • Acid Yellow 3 is a mixture of the sodium salts of mono- and sisulfonic acids of 2- (2-quinolyl) -1 H-indene-1,3 (2H) -dione and has a water solubility of 20 g / L (25 ° C).
  • Acid Yellow 9 is the disodium salt of 8-hydroxy-5,7-dinitro-2-naphthalenesulfonic acid, its water solubility is above 40 g / L (25 ° C).
  • Acid Yellow 23 is the trisodium salt of 4,5-dihydro-5-oxo-1- (4-sulfophenyl) -4 - ((4-sulfophenyl) azo) - 1 H-pyrazole-3-carboxylic acid and at 25 ° C well in Water soluble.
  • Acid Orange 7 is the sodium salt of 4 - [(2-Hydroxy-1-naphthyl) azo] benzene sulfonate. Its water solubility is more than 7 g / L (25 ° C).
  • Acid Red 18 is the trinity salt of 7-hydroxy-8 - [(E) - (4-sulfonato-1-naphthyl) -diazenyl)] - 1,3-naphthalenedisulfonate and has a very high solubility in water of more than 20 wt. %.
  • Acid Red 33 is the diantrium salt of 5-amino-4-hydroxy-3- (phenylazo) -naphthalene-2,7-disulphonate, its water solubility is 2.5 g / L (25 ° C).
  • Acid Red 92 is the disodium salt of 3, 4, 5, 6-tetrachloro-2- (1, 4,5,8-tetrabromo-6-hydroxy-3-oxoxanthen-9-yl) benzoic acid, its water solubility is specified with more than 10 g / L (25 ° C).
  • Acid Blue 9 is the disodium salt of 2 - ( ⁇ 4- [N-ethyl (3-sulfonatobenzyl] amino] phenyl ⁇ ⁇ 4 - [(N-ethyl (3-sulfonatobenzyl) imino] -2,5-cyclohexadiene-1- ylidene ⁇ methyl) benzene sulfonate and has a water solubility of more than 20% by weight (25 ° C).
  • a multicomponent packaging unit is therefore characterized in that the agent (b) contains at least one substantive dye (b3) selected from the group consisting of Acid Yellow 1, Acid Yellow 3, Acid Yellow 9 , Acid Yellow 17, Acid Yellow 23, Acid Yellow 36, Acid Yellow 121, Acid Orange 6, Acid Orange 7, Acid Orange 10, Acid Orange 11, Acid Orange 15, Acid Orange 20, Acid Orange 24, Acid Red 14, Acid Red, Acid Red 27, Acid Red 33, Acid Red 35, Acid Red 51, Acid Red 52, Acid Red 73, Acid Red 87, Acid Red 92, Acid Red 95, Acid Red 184, Acid Red 195, Acid Violet 43, Acid Violet 49, Acid Violet 50, Acid Blue 1, Acid Blue 3, Acid Blue 7, Acid Blue 104, Acid Blue 9, Acid Blue 62, Acid Blue 74, Acid Blue 80, Acid Green 3, Acid Green 5, Acid Green 9, Acid Green 22, Acid Green 25, Acid Green 50, Acid Black 1, Acid Black 52, Food Yellow 8, Food Blue 5, D&C Yellow 8, D&C Green 5, D&C Orange 10, D&C Orange 11, D & C Red 21, D&C Red 27, D&C Red
  • the substantive dyestuff (s) can be used in various amounts in the means (b), depending on the desired color intensity. Good results could be obtained when using the remedy (b) - based on the total weight of the agent (b) - one or more substantive dyes (b3) in a total amount of 0.01 to 10.0% by weight, preferably 0.1 to 8.0% by weight %, more preferably from 0.2 to 6.0% by weight and very particularly preferably from 0.5 to 4.5% by weight.
  • agent (b) can also contain at least one photochromic or thermochromic dye as the coloring compound (b3).
  • Photochromic dyes are dyes that react to exposure to UV light (sunlight or black light) with a reversible change in color.
  • the UV light changes the chemical structure of the dyes and thus their absorption behavior (photochromism).
  • Thermochromic dyes are dyes that react to changes in temperature with a reversible change in color. The change in temperature changes the chemical structure of the dyes and thus their absorption behavior (thermochromism).
  • the agent (b) can - based on the total weight of the agent (b) - one or more photochromic dyes (b3) in a total amount of from 0.01 to 10.0% by weight, preferably from 0.1 to 8.0 % By weight, more preferably from 0.2 to 6.0% by weight and very particularly preferably from 0.5 to 4.5% by weight
  • the agent (b) can - based on the total weight of the agent (b) - one or more thermochromic dyes (b3) in a total amount of from 0.01 to 10.0% by weight, preferably from 0.1 to 8.0 % By weight, more preferably from 0.2 to 6.0% by weight and very particularly preferably from 0.5 to 4.5% by weight
  • the agent (b) can optionally also contain at least one fat component.
  • the use of at least one fat component means that the agent (b) is in the form of an emulsion which enables particularly good and rapid mixing with the agent (a).
  • the fat components are hydrophobic substances which, in the presence of water, can form emulsions with the formation of micellar systems.
  • fat components are organic compounds with a solubility in water at room temperature (22 ° C) and atmospheric pressure (760 mmHg) of less than 1% by weight, preferably less than 0.1% by weight Understood.
  • the definition of fat components explicitly includes only uncharged (ie non-ionic) compounds.
  • Fat components have at least one saturated or unsaturated alkyl group with at least 12 carbon atoms.
  • the molecular weight of the fat constituents is a maximum of 5000 g / mol, preferably a maximum of 2500 g / mol and particularly preferably a maximum of 1000 g / mol.
  • the fat components are neither polyoxyalkylated nor polyglycerylated compounds.
  • the fat ingredients contained in the agent (b) optionally are most preferably selected from the group of C 2 -C30 fatty alcohols, the C 2 -C3o-fatty acid triglycerides, monoglycerides of Ci -C3o 2-fatty acid, fatty acid diglycerides of the C-2 -C3o and / or the hydrocarbons.
  • a multicomponent packaging unit is characterized in that the agent (b) has one or more fat components from the group of the C 2 -C 30 fatty alcohols, the C 12 -C 30 fatty acid triglycerides, the C 2 -C 30 Fatty acid monoglycerides containing Ci 2 -C3o fatty acid diglycerides and / or the hydrocarbons.
  • Particularly preferred fat constituents in this context are the constituents from the group of the Ci 2 -C30 fatty alcohols, the Ci 2 -C3o fatty acid triglycerides, the Ci 2 -C3o fatty acid monoglycerides, the Ci 2 -C3o fatty acid diglycerides and / or understood the hydrocarbons.
  • the present invention only nonionic substances are explicitly considered as fat components. Charged compounds such as fatty acids and their salts are not understood as a fat component.
  • the Ci 2 -C30 fatty alcohols can be saturated, mono- or polyunsaturated, linear or branched fatty alcohols with 12 to 30 carbon atoms.
  • Ci 2 -C30 fatty alcohols examples include dodecan-1-ol (dodecyl alcohol, lauryl alcohol), tetradecan-1-ol (tetradecyl alcohol, myristyl alcohol), hexadecan-1-ol (hexadecyl alcohol, cetyl alcohol, palmityl alcohol), Octadecan-1-ol (octadecyl alcohol, stearyl alcohol), arachyl alcohol (eicosan-1-ol), heneicosyl alcohol (heneicosan-1-ol) and / or behenyl alcohol (docosan-1-ol).
  • dodecan-1-ol dodecyl alcohol, lauryl alcohol
  • tetradecan-1-ol tetradecyl alcohol, myristyl alcohol
  • hexadecan-1-ol hexadecyl alcohol, cetyl alcohol, palmityl alcohol
  • Octadecan-1-ol o
  • Preferred linear, unsaturated fatty alcohols are (9Z) -octadec-9-en-1-ol (oleyl alcohol), (9 E)-octadec-9-en-1-ol (elaidyl alcohol), (9Z, 12Z) -octadeca-9 , 12-dien-1-ol (linoleyl alcohol), (9Z, 12Z, 15Z) -octadeca-9,12,15-trien-1-ol (linolenoyl alcohol), gadoleyl alcohol ((9Z) -Eicos-9-en-1 - ol), arachidonic alcohol ((5Z, 8Z, 11Z, 14Z) -Eicosa-5,8,11, 14-tetraen-1-ol), erucyl alcohol ((13Z) -Docos-13-en-1-ol) and / or brassidyl alcohol ((13E) -docosen-1-ol).
  • the preferred representatives of branched fatty alcohols are 2-octyl-dodecanol, 2-hexyl-dodecanol and / or 2-butyl-dodecanol.
  • the agent (b) contains one or more Ci 2 -C30 fatty alcohols from the group of dodecan-1-ol (dodecyl alcohol, lauryl alcohol), tetradecan-1-ol (tetradecyl alcohol , Myristyl alcohol), hexadecan-1-ol (hexadecyl alcohol, cetyl alcohol, palmityl alcohol), octadecan-1-ol (octadecyl alcohol, stearyl alcohol), arachyl alcohol (eicosan-1-ol), heneicosyl alcohol (heneicosan-1-alcohol), Docosan-1-ol), (9Z) -Octadec-9-en-1-ol (oleyl alcohol), (9E) -Octadec-9-en-1-ol (elaidyl alcohol), (9Z, 12Z) -Octadeca-9 , 12-dien-1-ol
  • a multicomponent packaging unit according to the invention is characterized in that the second agent (b) contains one or more C 2 -C 30 fatty alcohols from the group of dodecan-1-ol (dodecyl alcohol, lauryl alcohol),
  • Tetradecan-1-ol tetradecyl alcohol, myristyl alcohol
  • Hexadecan-1-ol hexadecyl alcohol, cetyl alcohol, palmityl alcohol
  • Octadecan-1-ol octadecyl alcohol, stearyl alcohol
  • Arachyl alcohol eicosan-1-ol
  • Gadoleyl alcohol ((9Z) -Eicos-9-en-1-ol)
  • Arachidonic alcohol ((5Z, 8Z, 11Z, 14Z) -Eicosa-5,8,11, 14-tetraen-1-ol),
  • 2-octyl-dodecanol Contains 2-hexyl-dodecanol and / or 2-butyl-dodecanol.
  • Ci 2 -C30 fatty alcohols in very specific quantity ranges.
  • the agent (b) - based on the total weight of the agent (b) - prefers one or more Ci 2 -C30 fatty alcohols in a total amount of 2.0 to 50.0% by weight from 3.0 to 30.0% by weight, more preferably from 4.0 to 20.0% by weight, even more preferably from 5.0 to 15.0% by weight and very particularly preferably from 5, Contains 0 to 10.0% by weight.
  • the agent (b) can also contain at least one Ci 2 -C 30 fatty acid triglyceride, the Ci 2 -C 30 fatty acid monoglyceride and / or Ci 2 -C 30 fatty acid diglyceride.
  • a Ci 2 -C 30 fatty acid triglyceride is understood to mean the triester of the trihydric alcohol glycerol with three equivalents of fatty acid. Both structurally identical and different fatty acids within a triglyceride molecule can be involved in the formation of esters.
  • fatty acids are to be understood as meaning saturated or unsaturated, unbranched or branched, unsubstituted or substituted C 2 -C 3 -carboxylic acids.
  • Unsaturated fatty acids can be monounsaturated or polyunsaturated. In the case of an unsaturated fatty acid, its CC double bond (s) can have the cis or trans configuration.
  • the fatty acid triglycerides are particularly suitable, in which at least one of the ester groups is formed starting from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (Stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid] , Elaidic acid [(9E) - octadec-9-enoic acid], erucic acid [(13Z) -Do
  • the fatty acid triglycerides can also be of natural origin.
  • the fatty acid triglycerides or mixtures thereof occurring in soybean oil, peanut oil, olive oil, sunflower oil, macadamia nut oil, moringa oil, apricot kernel oil, marula oil and / or optionally hydrogenated castor oil are particularly suitable for use in the product according to the invention.
  • a Ci 2 -C30 fatty acid monoglyceride is understood to mean the monoester of the trihydric alcohol glycerol with one equivalent of fatty acid. Either the middle hydroxyl group of the glycerol or the terminal hydroxyl group of the glycerol can be esterified with the fatty acid.
  • the Ci 2 -C30 fatty acid monoglyceride are particularly suitable, in which a hydroxyl group of the glycerol is esterified with a fatty acid, the fatty acids being selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid ( Lignoceric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6- octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec- 9-enoic acid], elaidic acid [(9E) -octadec-9-enoic acid],
  • Ci 2 -C 30 fatty acid diglyceride is understood to mean the diester of the trihydric alcohol glycerol with two equivalents of fatty acid. Either the middle and one terminal hydroxyl group of the glycerol can be esterified with two equivalents of fatty acid, or both terminal hydroxyl groups of the glycerol are esterified with one fatty acid each.
  • the glycerine can be esterified with two structurally identical as well as with two different fatty acids.
  • the fatty acid diglycerides are particularly suitable in which at least one of the ester groups is formed from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (Stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid] , Elaidic acid [(9E) - octadec-9-enoic acid], erucic acid [(13Z) -Docos-13-
  • the agent (b) contained at least one C12-C30 fatty acid monoglyceride, which is selected from the monoesters of glycerol with one equivalent fatty acid from the group of dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid ( Palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9-enoic acid]) 9Z) - Octadec-9-enoic acid], elaidic acid [(9E) -octadec-9-en
  • a multicomponent packaging unit is characterized in that the second agent (b) contains at least one C 2 -C 30 fatty acid monoglyceride, which is selected from the monoesters of glycerol with one equivalent of fatty acid from the group of dodecanoic acid , Tetradecanoic acid, hexadecanoic acid, tetracosanoic acid, octadecanoic acid, eicosanoic acid and / or docosanoic acid.
  • the second agent (b) contains at least one C 2 -C 30 fatty acid monoglyceride, which is selected from the monoesters of glycerol with one equivalent of fatty acid from the group of dodecanoic acid , Tetradecanoic acid, hexadecanoic acid, tetracosanoic acid, octadecanoic acid, eicosanoic acid and / or docosanoic acid.
  • the agent (b) - based on the total weight of the agent (b) - has one or more Ci 2 -C30 fatty acid mono-, Ci 2 -C3o- Fatty acid di- and / or Ci 2 -C3o fatty acid triglycerides in a total amount of 0.1 to 20.0% by weight, preferably 0.3 to 15.0% by weight, more preferably 0.5 to 10.0% by weight .-% and very particularly preferably from 5.0 to 9.0% by weight.
  • a multi-component packaging unit is characterized in that the agent (b) - based on the total weight of the agent (b) - one or more Ci 2 -C30 fatty acid mono-, Ci 2 -C3o fatty acid di - And / or Ci 2 -C3o fatty acid triglycerides in a total amount of 0.1 to 20.0 wt .-%, preferably 0.3 to 15.0 wt .-%, more preferably 0.5 to 10.0 wt. -% and very particularly preferably from 5.0 to 9.0% by weight.
  • the Ci 2 -C30-Fettklamono-, Ci 2 -C3o-Fettklaredi- and / or Ci 2 -C3o-Fettklaretriglyceride can be used as sole fat constituents in the mean (b). However, it is particularly preferred to use at least one Ci 2 -C30 fatty acid mono-, Ci 2 -C3o fatty acid and / or Ci 2 -C3o fatty acid triglyceride in combination with at least one Ci 2 -C30 fatty alcohol in the agent (b) to incorporate.
  • the agent (b) can also contain at least one hydrocarbon.
  • Hydrocarbons are compounds with 8 to 80 C atoms consisting exclusively of the atoms carbon and hydrogen.
  • aliphatic hydrocarbons such as mineral oils, liquid paraffin oils (for example Paraffinium Liquidum or Paraffinum Perliquidum), isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), petrolatum and polydecenes.
  • Liquid paraffin oils (Paraffinum Liquidum and Paraffinium Perliquidum) have proven to be particularly suitable in this context.
  • the hydrocarbon is very particularly preferably Paraffinum Liquidum, also called white oil.
  • Paraffinum Liquidum is a mixture of purified, saturated, aliphatic hydrocarbons, which for the most part consists of hydrocarbon chains with a carbon chain distribution of 25 to 35 carbon atoms.
  • agent (b) contained at least one hydrocarbon selected from the group of mineral oils, liquid paraffin oils, isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), petrolatum and polydecene.
  • hydrocarbon selected from the group of mineral oils, liquid paraffin oils, isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), petrolatum and polydecene.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (b) contains at least one fat component from the group of hydrocarbons.
  • the agent (b) - based on the total weight of the agent (b) - has one or more hydrocarbons in a total amount of 0.5 to 20.0 wt %, preferably 1.0 to 15.0% by weight, more preferably from 1.5 to 10.0% by weight and very particularly preferably from 2.0 to 8.0% by weight.
  • a multicomponent packaging unit is characterized in that the agent (b) - based on the total weight of the agent (b) - has one or more hydrocarbons in a total amount of 0.5 to 20.0 wt. -%, preferably 1.0 to 15.0% by weight, more preferably from 1.5 to 10.0% by weight and very particularly preferably from 2.0 to 8.0% by weight.
  • the agent (b) in the form of an emulsion.
  • the agent (b) therefore very particularly preferably additionally contains at least one surfactant.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (b) contains at least one surfactant.
  • surfactants is understood to mean surface-active substances which form adsorption layers on surfaces and interfaces or can aggregate in volume phases to form micellar colloids or lyotropic mesophases.
  • anionic surfactants consisting of a hydrophobic residue and a negatively charged hydrophilic head group
  • amphoteric surfactants which carry both a negative and a compensating positive charge
  • cationic surfactants which have a positively charged hydrophilic group in addition to a hydrophobic residue
  • nonionic surfactants which have no charges but rather strong dipole moments and are strongly hydrated in aqueous solution.
  • a multicomponent packaging unit is characterized in that the agent (b) contains at least one nonionic surfactant.
  • Nonionic surfactants contain, for example, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups as the hydrophilic group. Such connections are for example
  • Hydroxy mixed ethers as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide with sorbitan fatty acid esters, such as, for example, the polysorbates,
  • the alkyl and alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably from glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4 are preferred.
  • the alkyl or alkenyl radical R 4 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as those used, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's Oxo synthesis can be obtained.
  • the alkyl or alkenyl radical R 15 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms.
  • Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and technical mixtures thereof which can be obtained as described above.
  • Alkyl oligoglucosides based on hardened C12 / 14 coconut alcohol with a DP of 1 to 3 are preferred.
  • R 5 CO-NR 6 - [Z] (Tnio-3) in which R 5 CO stands for an aliphatic acyl radical with 6 to 22 carbon atoms, R 6 for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and [Z] for represents a linear or branched polyhydroxyalkyl radical having 3 to 12 carbon atoms and 3 to 10 hydroxyl groups.
  • the fatty acid N-alkyl polyhydroxyalkylamides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the fatty acid N-alkyl polyhydroxyalkylamides are preferably derived from reducing sugars having 5 or 6 carbon atoms, in particular from glucose.
  • the preferred fatty acid N-alkyl polyhydroxyalkylamides are therefore fatty acid N-alkyl glucamides, as represented by the formula (Tnio-4):
  • Glucamides of the formula (Tnio- 4), in which R 8 stands for hydrogen or an alkyl group and R 7 CO for the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palm oleic acid, are preferably used as fatty acid N-alkyl polyhydroxyalkylamides.
  • the polyhydroxyalkylamides can also be derived from maltose and palatinose.
  • the sugar surfactants can be contained in the agents used according to the invention preferably in amounts of 0.1-20% by weight, based on the total agent. Quantities of 0.5-15% by weight are preferred, and quantities of 0.5-7.5% by weight are very particularly preferred.
  • nonionic surfactants are fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, mixed ethers or mixed formals, protein hydrolyzates (in particular vegetable products based on wheat) and polysorbates.
  • alkylene oxide addition products with saturated linear fatty alcohols and fatty acids with 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid and the sugar surfactants have proven to be preferred nonionic surfactants. Preparations with excellent properties are also obtained if they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
  • the alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl and 1-myristyl are particularly preferred. When using so-called "oxo alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.
  • the compounds with alkyl groups used as surfactants can each be uniform substances. However, it is generally preferred to start with native vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal” homolog distribution and those with a narrow homolog distribution can be used.
  • “Normal” homolog distribution is understood to mean mixtures of homologs which are obtained in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts. Narrowed homolog distributions are obtained, however, if, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates as Catalysts are used. The use of products with a narrow homolog distribution can be preferred.
  • a multicomponent packaging unit according to the invention is characterized in that the agent (b) contains at least one nonionic surfactant of the formula (Tl),
  • Rb stands for a saturated or unsaturated, unbranched or branched C8-C24-alkyl group, preferably a saturated, unbroken Ci- to Cie-alkyl group, and m stands for an integer from 10 to 40, preferably an integer from 20 to 35 and particularly preferably the number 30.
  • a particularly suitable nonionic surfactant of this type is ceteareth-30.
  • Ceteareth-30 is a mixture of cetyl alcohol and stearyl alcohol, each of which is ethoxylated with 30 units of ethylene oxide. The mixture of cetyl alcohol and stearyl alcohol is called cetearyl alcohol. Ceteareth-30 has the CAS number 68439- 49-6 and can be purchased, for example, under the trade name Eumulgin B3 from BASF.
  • the nonionic surfactants are preferably used in the suitable quantity ranges in the agent (b).
  • the agent (b) - based on the total weight of the agent (b) - can further contain one or more nonionic surfactants in a total amount of 0.1 to 20% by weight, preferably 0.2 to 10% by weight preferably from 0.3 to 5% by weight and very particularly preferably from 0.4 to 2.5% by weight.
  • agents (a) and (b) are mixed and a ready-to-use coloring agent is produced in this way.
  • the agent (a) is preferably the concentrate of an aminosilicone (a1), which comes into contact with the buffered formulation containing the coloring compounds (i.e. the pigments) (b3) shortly before use.
  • Mixing initiates the reaction or interaction of the aminosilicones (a1) with the pigments (b3) which, under the conditions of use, ultimately leads to a conglomeration, addition or aggregation of (a1) and (b3) and in this way presumably leads to the pigments immobilized on the surface of the keratin fibers.
  • a multicomponent packaging unit according to the invention is characterized in that the total content of amino-functionalized silicone polymers on average (b) - based on the total weight of the composition (b) - is below 1.0 wt. %, preferably below 0.5% by weight, more preferably below 0.1% by weight and very particularly preferably below 0.01% by weight.
  • a multicomponent packaging unit is characterized in that the agent (b) - based on the total weight of the agent (a) - has one or more amino-functionalized silicone polymers in a total amount of 0 to 1.0 % By weight, preferably from 0 to 0.5% by weight, more preferably from 0 to 0.1% by weight and very particularly preferably from 0 to 0.01% by weight.
  • agent (b) does not contain any amino-functionalized silicone polymers.
  • agents (a) and / or (b) can also contain further optional ingredients.
  • the means (a) can contain a film-forming polymer.
  • the film-forming polymer can, for example, be selected from the group consisting of polyvinylpyrrolidone (PVP), vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / styrene copolymers, vinylpyrrolidone / ethylene copolymers, vinylpyrrolidone / propylene copolymers, vinylpyrrolidone / vinylcaprolacten , Vinylpyrrolidone / vinylformamide copolymers and / or vinylpyrrolidone / vinyl alcohol copolymers, explicitly very particularly preferably polyvinylpyrrolidone (PVP).
  • PVP polyvinylpyrrolidone
  • suitable film-forming polymers can be selected from the group of copolymers of acrylic acid, copolymers of methacrylic acid, homopolymers or copolymers of acrylic acid esters, homopolymers or copolymers of methacrylic acid esters, homopolymers or copolymers of acrylic acid amides, homopolymers or copolymers of Methacrylic acid amides, copolymers of vinyl pyrrolidone, copolymers of vinyl alcohol, copolymers of vinyl acetate, homopolymers or copolymers of ethylene, homopolymers or copolymers of propylene, homopolymers or copolymers of styrene, polyurethanes, polyesters and / or polyamides .
  • the film-forming polymers which are selected from the group of synthetic polymers, polymers obtainable by free radical polymerization or natural polymers have proven to be particularly suitable.
  • film-forming polymers can be selected from the homopolymers or copolymers of olefins, such as cycloolefins, butadiene, isoprene or styrene, vinyl ethers, vinyl amides, the esters or amides of (meth) acrylic acid with at least one Ci-C2o-alkyl group, a Aryl group or a C2-C10 hydroxyalkyl group.
  • Further film-forming polymers can be selected from the homo- or copolymers of isooctyl (meth) acrylate; isononyl (meth) acrylate; 2-ethylhexyl (meth) acrylate; Lauryl (meth) acrylate); isopentyl (meth) acrylate; n-butyl (meth) acrylate); isobutyl (meth) acrylate; Ethyl (meth) acrylate; Methyl (meth) acrylate; tert-butyl (meth) acrylate; Stearyl (meth) acrylate; Hydroxyethyl (meth) acrylate; 2-hydroxypropyl (methacrylate; 3-hydroxypropyl (meth) acrylate and / or mixtures thereof).
  • Further film-forming polymers can be selected from the homo- or copolymers of (meth) acrylamide; N-alkyl- (meth) acrylamides, in particular those with C2-C18 alkyl groups, such as, for example, N-ethyl-acrylamide, N-tert-butyl-acrylamide, N-octyl-acrylamide; N-di (C1-C4) alkyl (meth) acrylamide.
  • anionic copolymers are, for example, copolymers of acrylic acid, methacrylic acid or their Ci-C6-alkyl esters, as sold under the INCI declaration Acrylates Copolymers.
  • a suitable commercial product is, for example Aculyn ® 33 of the Rohm & Haas company.
  • copolymers of acrylic acid, methacrylic acid or their Ci-C6-alkyl esters and the esters of an ethylenically unsaturated acid and an alkoxylated fatty alcohol are also preferred.
  • Suitable ethylenically unsaturated acids are in particular acrylic acid, methacrylic acid and itaconic acid; suitable alkoxylated fatty alcohols are, in particular, steareth-20 or ceteth-20.
  • Particularly preferred polymers on the market are, for example, Aculyn® 22 (Acrylates / Steareth-20 Methacrylate Copolymer), Aculyn®28 (Acrylates / Beheneth-25 Methacrylate Copolymer), Structure 2001® (Acryla-tes / Steareth-20 Itaconate Copolymer), Structure 3001® (Acrylates / Ceteth-20 Itaconate Copolymer), Structure Plus® (Acrylates / Aminoacrylates C10-30 Alkyl PEG-20 Itaconate Copolymer), Carbopol® 1342, 1382, Ultrez 20, Ultrez 21 (Acrylates / C 10 -30 Alkyl Acrylate Crosspolymer), Synthalen W 2000® (Acrylates / Palmeth-25 Acrylate Copolymer) or the Soltex OPT (Acrylates / C 12-22 Alkyl methacrylate Copolymer) sold by Rohme and Haas.
  • Suitable polymers based on vinyl monomers are the homo- and copolymers of N-vinylpyrrolidone, vinylcaprolactam, vinyl (C1-C6) alkyl pyrrole, vinyl oxazole, vinyl thiazole, of vinyl pyrimidine, of vinyl imidazole.
  • copolymers octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer such as is sold commercially by NATIONAL STARCH under the trade names AMPHOMER® or LOVOCRYL® 47, or the copolymers of acrylates / octylacrylamides under the trade names, are also very particularly suitable DERMACRYL® LT and DERMACRYL® 79 are distributed by NATIONAL STARCH.
  • Suitable polymers based on olefins are the homo- and copolymers of ethylene, propylene, butene, isoprene and butadiene.
  • block copolymers which comprise at least one block of styrene or the derivatives of styrene can be used as film-forming hydrophobic polymers.
  • These block copolymers can be copolymers which, in addition to a styrene block, contain one or more other blocks, such as, for example, styrene / ethylene, styrene / ethylene / butylene, styrene / butylene, styrene / isoprene, styrene / butadiene.
  • Corresponding polymers are sold commercially by BASF under the trade name “Luvitol HSB”.
  • a multi-component packaging unit is characterized in that the agent (a) and / or (b) contains at least one film-forming polymer selected from the group consisting of polyvinylpyrrolidone (PVP), vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / styrene Copolymers, Vinyl pyrrolidone / ethylene copolymers, vinyl pyrrolidone / propylene copolymers, vinyl pyrrolidone / vinyl caprolactam copolymers, vinyl pyrrolidone / vinyl formamide copolymers and / or vinyl pyrrolidone / vinyl alcohol copolymers, copolymers of acrylic acid, copolymers of methacrylic acid, the of acrylic acid esters, homopolymers or copolymers of methacrylic acid esters, homopolymers or copolymers of acrylic acid amides, homopolymers or copolymers,
  • the film-forming polymer (s) are preferably used in certain quantity ranges in agents (a) and / or (b).
  • agent (b) - based on the total weight of the agent (b) - has one or more polymers in a total amount of 0.1 to 25.0 wt. -%, preferably from 0.2 to 20.0% by weight, more preferably from 0.5 to 15.0% by weight and very particularly preferably from 1.0 to 7.0% by weight.
  • the agents can additionally contain one or more surfactants.
  • surfactants is understood to mean surface-active substances. A distinction is made between anionic surfactants consisting of a hydrophobic residue and a negatively charged hydrophilic head group, amphoteric surfactants, which carry both a negative and a compensating positive charge, cationic surfactants, which have a positively charged hydrophilic group in addition to a hydrophobic residue, and nonionic surfactants, which have no charges but rather strong dipole moments and are strongly hydrated in aqueous solution.
  • Zwitterionic surfactants are surface-active compounds which have at least one quaternary ammonium group and at least one -COO (_) or -S03 (_) group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinates, for example coconut alkyl dimethylammonium glycinate, N-acyl aminopropyl-N, N-dimethylammonium glycinate, for example cocoacylaminopropyl dimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazolines, each with 8 to 18 carbon atoms in the alkyl or acyl group, and cocoacylamino ethyl hydroxyethyl carboxymethyl glycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name
  • Ampholytic surfactants are surface-active compounds which, in addition to a Cs - C24 - alkyl or acyl group, contain at least one free amino group and at least one —COOH or —SOsH group and are capable of forming internal salts are.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids, each with about 8 to 24 C. Atoms in the alkyl group.
  • amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C12-Cie acylsarcosine.
  • the agents can also contain at least one cationic surfactant.
  • Cationic surfactants are understood as meaning surfactants, that is to say surface-active compounds, each with one or more positive charges. Cationic surfactants only contain positive charges. These surfactants are usually made up of a hydrophobic part and a hydrophilic head group, the hydrophobic part usually consisting of a hydrocarbon structure (e.g. consisting of one or two linear or branched alkyl chains), and the positive charge (s) are located in the hydrophilic head group. Examples of cationic surfactants are examples of cationic surfactants.
  • Quaternary ammonium compounds which can carry one or two alkyl chains with a chain length of 8 to 28 carbon atoms as hydrophobic radicals,
  • the cationic charge can also be part of a heterocyclic ring (e.g. an imidazolium ring or a pyridinium ring) in the form of an onium structure.
  • the cationic surfactant can also contain other uncharged functional groups, as is the case, for example, with ester quats.
  • the cationic surfactants are used in a total amount of 0.1 to 45% by weight, preferably 1 to 30% by weight and very particularly preferably 1 to 15% by weight, based on the total weight of the respective agent.
  • the agents according to the invention can furthermore also contain at least one anionic surfactant.
  • Anionic surfactants are surface-active agents with exclusively anionic charges (neutralized by a corresponding counter cation).
  • anionic surfactants are fatty acids, alkyl sulfates, alkyl ether sulfates and ether carboxylic acids with 12 to 20 carbon atoms in the alkyl group and up to 16 glycol ether groups in the molecule.
  • the anionic surfactants are used in a total amount of 0.1 to 45% by weight, preferably 1 to 30% by weight and very particularly preferably 1 to 15% by weight, based on the total weight of the agent in question.
  • the agents can also contain other active ingredients, auxiliaries and additives, such as solvents, fatty components such as Cs-Cso fatty alcohols, C8-C30 fatty acid triglycerides, C8-C30 fatty acid monoglycerides, C8-C3o fatty acid diglycerides and / or the hydrocarbons; Polymers; Structurants such as glucose, maleic acid and lactic acid, hair conditioning compounds such as phospholipids, for example lecithin and cephalins; Perfume oils, dimethyl isosorbide and cyclodextrins; fiber structure-improving active ingredients, in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fruit sugar and lactose; Dyes for coloring the agent; Anti-dandruff ingredients such as Piroctone Olamine, Zinc Omadine and Climbazole; Amino acids and oligopeptides; Protein hydrolysates based on
  • the person skilled in the art will select these additional substances in accordance with the desired properties of the agents. With regard to further optional components and the amounts of these components used, express reference is made to the relevant manuals known to the person skilled in the art.
  • the additional active ingredients and auxiliaries are used in the preparations according to the invention preferably in amounts of from 0.0001 to 25% by weight, in particular from 0.0005 to 15% by weight, based on the total weight of the respective agent.
  • the agent (a) particularly preferably consists essentially of the ingredients (a1) and optionally alkalizing agents (a2). If the agent (a) should therefore contain one of the further optional ingredients described above, these are particularly preferably used in the agent (a) only in very small amounts.
  • the multi-component packaging unit according to the invention of the first subject of the invention is ideal for use in a method for coloring keratinic material, in particular human hair.
  • a second subject of the present application is therefore a method for coloring keratinic material, in particular human hair, comprising the following steps:
  • step (1) of the method according to the invention the agent (a) is provided.
  • the means (a) is preferably present in a packaging unit or a container and in this way can be made available to the user.
  • step (2) of the method according to the invention the agent (b) is provided.
  • This means (b) is also preferably located in the container of the kit-of-parts and is made available to the user in this way.
  • step (3) of the process according to the invention a ready-to-use mixture is produced by mixing agents (a) and (b).
  • agent (a) is preferably a concentrate, it has proven to be very particularly preferred to use the agent (a) in small amounts and to dilute them with comparatively higher amounts of the coloring agent (b). With an amount ratio (a) / (b) of 1: 120, for example 1 g of agent (a) can be mixed with 120 g of agent (b).
  • agent (a) can be mixed with 100 g of agent (b).
  • agent (a) With an amount ratio (a) / (b) of 1:15, for example, 15 g of agent (a) can be mixed with 75 g of agent (b).
  • agent (a) can be mixed with 100 g of agent (b).
  • the application mixture prepared from (a) and (b) preferably has a pH value adjusted to be slightly acidic to slightly alkaline.
  • the application mixture very particularly preferably has a pH of 6.0 to 8.0.
  • step (4) of the method according to the invention the application mixture produced in step (4) is applied to the keratinic material, which is very particularly preferably human hair.
  • the application mixture is preferably applied to the keratin material within a period of from 1 to 120 minutes, preferably from 1 to 60 minutes, more preferably from 1 to 30 minutes and very particularly preferably from 1 to 15 minutes after its preparation in step (3) the hair) applied.
  • a method according to the invention is characterized by
  • step (5) of the method according to the invention the application mixture is allowed to act on the keratinic material after its application.
  • different exposure times of, for example, 30 seconds to 60 minutes are conceivable.
  • a great advantage of the dyeing system according to the invention is that an intense color result can be achieved even in very short periods of time after short exposure times. For this reason, it is advantageous if the application mixture remains on the keratin material for comparatively short periods of time from 30 seconds to 15 minutes, preferably from 30 seconds to 10 minutes, and particularly preferably from 1 to 5 minutes after its application.
  • a method according to the invention is characterized by
  • step (5) Action of the application mixture applied in step (5) on the keratinous material for a period of 30 seconds to 15 minutes, preferably from 30 seconds to 10 minutes, and particularly preferably from 1 to 5 minutes
  • the application mixture can only be washed out with water, i.e. without the aid of an aftertreatment agent or a shampoo.
  • an aftertreatment agent or conditioner in step (6) is also conceivable in principle.
  • a method according to the invention is characterized by
  • the method according to the invention comprises steps (1) to (6).
  • step (1) the agent (a) is provided
  • step (2) comprises the provision of the agent (b).
  • step (1) can take place before step (2), steps (1) and (2) and (3) can run simultaneously or step (2) takes place before step (1).
  • the means (a) and (b) are made available to the user in a multi-component packaging unit, three means are provided at the same time, and it is up to the user which means he takes out of the packaging first.
  • the preparation of an application mixture by mixing agents (a) and (b) in step (3) can only take place after the two agents (a) and (b) and have been provided.
  • the application mixture can only be applied in step (4) after it has been produced in step (3).
  • the application mixture can only take effect in step (5) after it has been applied to the keratin material, and the application mixture is rinsed out in step (6) after it has acted in step (5).
  • Each application mixture was applied to locks of hair (Kerling, Euronaturhaar white, liquor ratio: 1 g application mixture per g hair lock). The application mix was allowed to act for three minutes. Following this, the locks of hair were washed out thoroughly (1 minute) with water, dried and then assessed visually under a daylight lamp.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne une unité d'emballage à plusieurs éléments ("kit d'éléments") pour la coloration de matières kératiniques, en particulier de cheveux humains, qui comprend des contenants fabriqués séparément, - un premier contenant renfermant un agent (a), ledit agent (a) contenant : (a1) au moins un polymère de silicone fonctionnalisée par un groupe amino, et un second contenant comprenant un agent (b), ledit agent (b) contenant : (B1) de l'eau et (b2) un système tampon composé d'au moins un acide inorganique ou organique (b2-I) et d'au moins un sel dudit acide (b2-II), et (b3) au moins un composé chromophore. L'invention concerne également un procédé correspondant faisant appel aux deux agents (a) et (b).
EP20739984.1A 2019-09-23 2020-07-13 Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore Pending EP4034074A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102019214469.1A DE102019214469A1 (de) 2019-09-23 2019-09-23 Kit und Verfahren zum Färben von keratinischem Material mit Aminosilikon und farbgebender Verbindung
PCT/EP2020/069716 WO2021058157A1 (fr) 2019-09-23 2020-07-13 Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore

Publications (1)

Publication Number Publication Date
EP4034074A1 true EP4034074A1 (fr) 2022-08-03

Family

ID=71608004

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20739984.1A Pending EP4034074A1 (fr) 2019-09-23 2020-07-13 Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore

Country Status (6)

Country Link
US (1) US11766396B2 (fr)
EP (1) EP4034074A1 (fr)
JP (1) JP2022548398A (fr)
CN (1) CN114423407A (fr)
DE (1) DE102019214469A1 (fr)
WO (1) WO2021058157A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2656050T3 (es) 2011-07-06 2018-02-22 Glaxosmithkline Biologicals Sa Composiciones de combinación inmunogénica y usos de las mismas
DE102019214467A1 (de) 2019-09-23 2021-03-25 Henkel Ag & Co. Kgaa Kit und Verfahren zum Färben von keratinischem Material mit Aminosilikon und farbgebender Verbindung
DE102022200866A1 (de) * 2022-01-26 2023-07-27 Henkel Ag & Co. Kgaa Verfahren zur Färbung von Keratinfasern, umfassend die Anwendung eines Färbemittels mit Aminosilikon und Pigment und eines Shampoos mit Aminosilikon

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19738866A1 (de) 1997-09-05 1999-03-11 Henkel Kgaa Schaumarme Tensidmischungen mit Hydroxymischethern
DE102007040314A1 (de) * 2007-08-24 2009-02-26 Henkel Ag & Co. Kgaa Kit zur Bereitstellung von Färbemitteln
DE102013226102A1 (de) * 2013-12-16 2015-06-18 Henkel Ag & Co. Kgaa Saure Mittel zum Färben von Keratinfasern enthaltend spezielle Aminosilikone und Säurefarbstoffe
DE102014218006A1 (de) * 2014-09-09 2016-03-10 Henkel Ag & Co. Kgaa Verpackungseinheit (Kit-of-parts) mit speziellen aminierten Siliconpolymeren
DE102016202649A1 (de) * 2016-02-22 2017-08-24 Henkel Ag & Co. Kgaa Haarfärbemittel enthaltend direktziehende Farbstoffe und anorganische Puffersysteme
DE102018203837A1 (de) * 2018-03-14 2019-09-19 Henkel Ag & Co. Kgaa Kit zum Färben von Haaren

Also Published As

Publication number Publication date
DE102019214469A1 (de) 2021-03-25
JP2022548398A (ja) 2022-11-18
WO2021058157A1 (fr) 2021-04-01
CN114423407A (zh) 2022-04-29
US20220347079A1 (en) 2022-11-03
US11766396B2 (en) 2023-09-26

Similar Documents

Publication Publication Date Title
EP4034074A1 (fr) Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore
WO2021104709A1 (fr) Procédé de décoloration de matière kératinique ayant été colorée par l'application d'un pigment
EP4034076A1 (fr) Produit pour colorer une matière kératinique, contenant de l'aminosilicone, un composé chromophore et de l'huile d'ester
EP4065077A1 (fr) Agent de coloration de matière kératinique, contenant de l'aminosilicone, un composé chromophore et un tensioactif contenant du phosphore
WO2021104702A1 (fr) Procédé d'amélioration de la sensation tactile de matières kératiniques colorées, en particulier des cheveux humains
EP4034075A1 (fr) Kit et procédé de coloration de matières kératiniques au moyen d'aminosilicone et d'un composé chromophore
WO2020254012A1 (fr) Procédé de coloration d'une matière kératinique par mélange préalable d'un composée aminosilicone et d'un composée colorant
EP4167940A1 (fr) Substance pour colorer des fibres de kératine, contenant des émulsifiants non ioniques spécifiques, des pigments et des aminosilicones
EP3986373A1 (fr) Produit de coloration d'une matière kératinique comprenant des aminosilicones et des pigments dans des rapports pondéraux spécifiques
WO2020254009A1 (fr) Procédé de coloration d'une matière kératinique
EP4034258A1 (fr) Produit pour colorer une matière kératinique, contenant de l'aminosilicone, un composé chromophore et un ester d'acide gras éthoxylé
WO2021104700A1 (fr) Procédé d'amélioration de la rétention de couleur de matières kératiniques colorées, en particulier des cheveux humains
WO2021058206A1 (fr) Nécessaire et procédé de coloration de matières kératiniques au moyen d'aminosilicone et d'un composé chromophore
EP4034260A1 (fr) Procédé de coloration de matières kératiniques au moyen d'un prémélange d'aminosilicone et d'un composé chromophore
WO2021058159A1 (fr) Produit pour colorer une matière kératinique, contenant de l'aminosilicone, un composé chromophore et un ester d'acide carbonique organique
WO2021254721A1 (fr) Agent de coloration de fibres kératiniques contenant des pigments et des alkylméthicones en c2-c30
EP4065075A1 (fr) Procédé de décoloration de matière kératinique qui a été colorée à l'aide d'une amino silicone et d'un pigment
EP4167948A1 (fr) Agent de coloration de matière kératinique, en particulier de cheveux humains, contenant des aminosilicones, des pigments et des alkylpolyglycosides

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20220222

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230530

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20231002