EP3981865A2 - Utilisation de dispersions de polyuréthane modifié par voie cationique en tant qu'assouplissant pour textiles - Google Patents
Utilisation de dispersions de polyuréthane modifié par voie cationique en tant qu'assouplissant pour textiles Download PDFInfo
- Publication number
- EP3981865A2 EP3981865A2 EP21201021.9A EP21201021A EP3981865A2 EP 3981865 A2 EP3981865 A2 EP 3981865A2 EP 21201021 A EP21201021 A EP 21201021A EP 3981865 A2 EP3981865 A2 EP 3981865A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- oil
- compound
- modified polyurethane
- cationically modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000034 method Methods 0.000 claims abstract description 34
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- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- GINSRDSEEGBTJO-UHFFFAOYSA-N thietane 1-oxide Chemical compound O=S1CCC1 GINSRDSEEGBTJO-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M toluenesulfonate group Chemical class C=1(C(=CC=CC1)S(=O)(=O)[O-])C LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- MBDOYVRWFFCFHM-UHFFFAOYSA-N trans-2-hexenal Natural products CCCC=CC=O MBDOYVRWFFCFHM-UHFFFAOYSA-N 0.000 description 1
- DKZBBWMURDFHNE-UHFFFAOYSA-N trans-coniferylaldehyde Natural products COC1=CC(C=CC=O)=CC=C1O DKZBBWMURDFHNE-UHFFFAOYSA-N 0.000 description 1
- NSSALFVIQPAIQK-UHFFFAOYSA-N trans-non-2-en-1-ol Natural products CCCCCCC=CCO NSSALFVIQPAIQK-UHFFFAOYSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 101150046896 trm1 gene Proteins 0.000 description 1
- ORHBXUUXSCNDEV-UHFFFAOYSA-N umbelliferone Chemical compound C1=CC(=O)OC2=CC(O)=CC=C21 ORHBXUUXSCNDEV-UHFFFAOYSA-N 0.000 description 1
- HFTAFOQKODTIJY-UHFFFAOYSA-N umbelliferone Natural products Cc1cc2C=CC(=O)Oc2cc1OCC=CC(C)(C)O HFTAFOQKODTIJY-UHFFFAOYSA-N 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- GDJZZWYLFXAGFH-UHFFFAOYSA-M xylenesulfonate group Chemical group C1(C(C=CC=C1)C)(C)S(=O)(=O)[O-] GDJZZWYLFXAGFH-UHFFFAOYSA-M 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- OJYLAHXKWMRDGS-UHFFFAOYSA-N zingerone Chemical compound COC1=CC(CCC(C)=O)=CC=C1O OJYLAHXKWMRDGS-UHFFFAOYSA-N 0.000 description 1
- 229930007850 β-damascenone Natural products 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the present invention relates to the use of cationically modified polyurethane dispersions as textile softeners, textile treatment agents containing at least one such cationically modified polyurethane dispersion, and methods for treating textiles using at least one such agent or at least one such cationically modified polyurethane dispersion.
- the textiles are treated with a fabric softener in a subsequent rinsing process after the actual washing and cleaning process.
- cationic fabric softening compounds for example those which have one or two long-chain alkyl groups in a molecule.
- Widely used cationic fabric softening compounds include, for example, methyl-N-(2-hydroxyethyl)-N,N-di(tallowacyloxyethyl)ammonium compounds, methyl-N-(2-hydroxyethyl)-N,N-di(tallowacyloxyethyl)- ammonium compounds or N,N-dimethyl-N,N-di(tallowacyloxyethyl)ammonium compounds.
- Esterquats (EQ), the term generally being understood to mean quaternized fatty acid triethanolamine ester salts, are widely suitable for both fiber and hair finishes and have largely eliminated the above quaternary ammonium compounds in recent years due to their better ecotoxicological compatibility market displaced.
- esterquats since most esterquats have relatively long fatty acid chains, rapid biodegradability is not always guaranteed.
- non-polar side chains can result in an overall reduced affinity for the fibers of the textile to be conditioned.
- a first object of the present invention is therefore the use of a dispersion of at least one cationically modified polyurethane as a textile softener in textile treatment processes.
- the present invention relates to a textile treatment agent comprising at least one dispersion of at least one cationically modified polyurethane.
- the invention also relates to a method for conditioning textiles, characterized in that at least one dispersion of at least one cationically modified polyurethane and/or at least one textile treatment agent, as defined herein, is used in at least one method step.
- a textile treatment agent as described herein, is in particular a fabric softener.
- Fabric softeners are added to the laundry in the last rinse cycle of the machine wash in order to prevent the "dry rigidity" effect that occurs when the laundry is drying.
- the dry rigidity is caused by the formation of hydrogen bonds between the cellulose fibers.
- the cationic active ingredients in the fabric softener penetrate the fibers or settle on the fiber surface, combine with the negative charges and thus weaken the interactions. Due to the reduced stiffness of the item of laundry, the effort required for ironing is reduced and the wearing comfort is increased.
- the agents described herein are particularly suitable for conditioning textile fabrics.
- condition in the context of the present invention, denotes the imparting of a desired property, for example, in relation to textiles, a pleasant hand, crease resistance or low static charge.
- At least one includes but is not limited to 1, 2, 3, 4, 5, 6 and more.
- the information refers to the type of ingredient and not to the absolute number of molecules.
- At least one surfactant thus means, for example, at least one type of surfactant, i.e. one type of surfactant or a mixture of several different surfactants can be meant.
- the information refers to all compounds of the type specified that are contained in the composition/mixture, i.e. the composition does not contain any other compounds of this type beyond the specified amount of the corresponding compounds.
- the number average molar mass can be determined, for example, by means of gel permeation chromatography (GPC) in accordance with DIN 55672-1:2007-08 with THF as the eluent.
- GPC gel permeation chromatography
- the mass-average molar mass M w can also be determined by GPC, as described for M n .
- alkaline earth metals are mentioned below as counterions for monovalent anions, this means that the alkaline earth metal is of course only present in half the amount of substance - sufficient for charge equalization - as the anion.
- Liquid as used in the context of the present invention means all flowable compositions (at 20°C, 1.013 bar), including gels and paste-like compositions, as well as non-Newtonian liquids that exhibit a yield point.
- Solid as used herein in the context of the present invention means a powder, granule, extrudate or compact composition.
- Phosphate-free and “phosphonate-free” as used herein means that the composition in question is essentially free of phosphates or phosphonates, i.e. in particular phosphates or phosphonates in amounts less than 0.1% by weight, preferably less than 0 .01% by weight, based on the respective composition.
- a composition according to the invention can be a one-component composition or a multi-component composition.
- the term “one-component agent” refers to an agent which consists of only a single component.
- the term "spatially separated" in relation to the components of the composition means that the individual components cannot come into contact with each other prior to use of the composition.
- the agent is provided in a multi-chamber packaging, such as a bottle, tube or pouch, in particular a two-chamber bottle or a two-chamber pouch, with each individual component being located separately from the other component(s) in a separate chamber.
- the spatial separation of individual components of the agent makes it possible on the one hand to separate incompatible ingredients from one another and on the other hand to offer several different components of the agent in combination, which are used at different times.
- component refers to a part of the agent that can be distinguished from a possibly further component of the agent on the basis of one or more characteristics, for example the type and/or amount of its ingredients, physical properties, external appearance, etc.
- Individual components of the agent can be present in liquid form, as defined herein, or in solid form, as defined herein, and advantageously spatially separated from one another.
- a textile treatment composition according to the invention is preferably a liquid textile treatment composition as defined herein.
- dispersions of cationically modified polyurethanes have a softening effect on textile fibers, in particular on cotton fibers, when they are brought into contact with laundry in the course of a rinsing process after the actual washing step. In order to be able to achieve such an effect, even low concentrations of such a dispersion are sufficient.
- the cationically modified polyurethanes are not only toxicologically safe and easily deposit on negatively charged substrates such as keratin, hair, leather and cotton, but also have an antistatic and antimicrobial effect.
- the present invention is directed to the use of a dispersion of at least one cationically modified polyurethane as a textile softener in textile treatment processes.
- the present invention relates to the use of a dispersion as described below for conditioning, in particular for softening, textiles.
- the present invention relates both to uses in which a dispersion as described herein is used in a manual textile treatment process or, preferably, in the washing machine.
- a dispersion of one or more cationically modified polyurethanes can in principle be obtained by dispersing at least one cationically modified polyurethane in an aqueous phase.
- a combination of the above approaches is also possible, in that at least one cationically modified polyurethane prepolymer is dispersed in an aqueous phase and at least one cationically modified polyurethane prepolymer is dispersed in the same aqueous phase and can then be crosslinked.
- a compound (A) suitable in the context of the present invention is a polyol comprising at least one cationic functional group, preferably a diol comprising at least one cationic functional group.
- a cationic functional group is in particular an ammonium group, preferably a quaternary ammonium group.
- Particularly suitable in the context of the following invention are those compounds (A) which are alkoxylated, in particular ethoxylated, propoxylated and/or butoxylated, dialkylammonium polyols, in particular diols.
- a commercially available example is ethoxylated cocoalkylmethylammonium methanesulfonate.
- Such compounds are available, for example, under the brand name Rewoquat® CPEM from Evonik.
- substituents are selected in the context of the present invention from halogens, e.g. CI.
- the groups defined above are unsubstituted.
- a group -O-(Y) n -H is an isocyanate-reactive functional group.
- Y in each -O-(Y) n -H group is identical, for example in some embodiments each Y in each -O-(Y) n -H group of compound (A) with each occurrence denotes an ethylene oxide- ( EO) grouping. In some other embodiments, each Y in each -O-(Y) n -H group of compound (A) with each occurrence denotes a propylene oxide (PO) moiety.
- each Y in each -O-(Y) n -H group of compound (A) with each occurrence denotes a butylene oxide (BO) moiety.
- a group -O-(Y) n -H contains any mixture of ethylene oxide (EO), propylene oxide (PO), and butylene oxide (BO) moieties, with the total number of moieties in corresponds to a group -O-(Y) n -H n .
- at least one -O-(Y) n -H group differs from the other -(Y) n -H groups.
- a compound (A) may be a compound of formula (I) as defined above wherein in one group -O-(Y) n -HY denotes an EO moiety at each occurrence, and in another -O-(Y) n -HY Group -O-(Y) n -HY denotes a PO grouping with each occurrence and/or in a further group -O-(Y) n -HY denotes a BO grouping with each occurrence.
- all -O-(Y) n -H groups in a compound (A) are different from each other.
- all -O-(Y) n -H groups of a compound (A) are identical.
- the compound (A) is a compound of the formula (I) in which the R radicals contain no heteroatoms and/or are unsubstituted.
- the group X also contains no heteroatoms and/or is substituted, apart from the at least one group --O-(Y) n --H, ie it contains no group --N(R 1 ) 2 --, for example.
- the number of carbon atoms in the radicals R is preferably not more than 15 and/or the number of carbon atoms in the group X is preferably not more than 50, in particular not more than 40, for example not more than 30, 25 or 15, the carbon atoms of the group(s) -O-(Y) n -H of the moiety X not being included in this calculation.
- a group X contains at least one, preferably at least two, but preferably no more than 7, especially no more than 5 groups -O-(Y) n -H as defined herein.
- each R is independently H or a straight or branched chain alkyl or alkylene group.
- n in each group -O-(Y) n -H independently denotes an integer from 2 to 100, preferably from 2 to 80, more preferably from 2 to 75, for example from 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20 to 25, 30, 35, 40, 45, 50, 55, 60, 65, 70 or 75, or from 2 to 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20.
- a compound (A) of formula (I) at least one group -O-(Y) n -H, where Y denotes with each occurrence EO, and/or at least one group -O-(Y) n -H, where Y denotes each occurrence denotes PO, and/or at least one group -O-(Y) n -H, where Y denotes BO with each occurrence, and/or at least one group -O-(Y) n -H, where Y with each occurrence is independently selected from EO, PO and BO; more preferably at least one -O-(Y) n -H group, where Y at each occurrence denotes EO, and/or at least one -O-(Y) n -H group, where Y at each occurrence denotes PO; more preferably at least one group, especially at least two groups -O-(Y) n -H, where Y denotes EO at each occurrence.
- Suitable salts of compound (A) include, but are not limited to, salts of compound (A) with acids.
- acids suitable in this context are acetic acid, Formic acid, hydrochloric acid, phosphoric acid, sulfuric acid, nitric acid, nitrous acid, boric acid, carbonic acid, perchloric acid, acrylic acid, methacrylic acid, itaconic acid, maleic acid, 2-carboxyethyl acrylate, lactic acid, ascorbic acid, glycine, alanine, leucine, norleucine, phenylalanine, serine, taurine, valine , ⁇ -aminobutyric acid, palmitic acid, stearic acid, benzoic acid, mercaptoacetic acid, salicylic acid, pivalic acid, chloroacetic acid, dichloroacetic acid, trichloroacetic acid, citric acid, propionic acid, glycolic acid, 1-sulfonaphthalene, tartaric acid
- a polyisocyanate compound (B) is a compound which comprises at least two isocyanate groups.
- a compound (B) can be a diisocyanate or a triisocyanate.
- the polyisocyanate is a diisocyanate.
- the incorporation of small amounts of isocyanate having a functionality greater than two, particularly a triisocyanate, is also contemplated and may even be beneficial in certain circumstances.
- Such polyisocyanates can act as crosslinkers.
- polyisocyanate acts as a crosslinking agent
- the amount of crosslinker is usually about 0 to 5% by weight, preferably about 0 to 2% by weight, for example about 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6 , 0.7, 0.8, 0.9, 1.0, 1.2, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1 .9 or 2.0% by weight based on the total weight of the respective reaction mixture.
- Suitable diisocyanates include methylenediphenyl diisocyanate (MDI), toluene-2,4-diisocyanate (TDI), hexamethylene diisocyanate (HDI), polymeric diphenylmethane diisocyanate (PMDI), isophorone diisocyanate (IPDI) and methylene-4,4-bis(cyclohexyl)diisocyanate (H12MD1) .
- MDI methylenediphenyl diisocyanate
- TDI toluene-2,4-diisocyanate
- HDI hexamethylene diisocyanate
- PMDI polymeric diphenylmethane diisocyanate
- IPDI isophorone diisocyanate
- H12MD1 methylene-4,4-bis(cyclohexyl)diisocyanate
- the most preferred aliphatic diisocyanates include isophorone diisocyanate, hexamethylene diisocyanate, and mixtures thereof.
- Suitable polyisocyanates are commercially available, for example, under the brand name Desmodur® from Bayer AG (DE). It is of course also possible to use different compounds (C), ie different polyisocyanates, as defined above, together.
- a polyol compound (C) is a compound comprising at least two hydroxy groups, which can be selected in particular from the group consisting of polyester polyols, polyether polyols, polycarbonate polyols, polysiloxane polyols and polyolefin polyols, such as (hydrogenated ) polybutadiene polyols.
- polyester polyols which are suitable in the context of the present invention include, for example, those which can be obtained by reacting dicarboxylic acids with polyols in a polycondensation reaction.
- the dicarboxylic acids can be aliphatic, cycloaliphatic or aromatic and/or derivatives of the aforementioned such as anhydrides, esters or acid chlorides.
- succinic acid succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid or sebacic acid, phthalic acid, isophthalic acid, trimellitic acid, phthalic anhydride, tetrahydrophthalic anhydride, glutaric anhydride, maleic acid, maleic anhydride, fumaric acid, dimer fatty acids and dimethyl terephthalate.
- polystyrene resin examples include monoethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 3-methylpentane-1,5-diol, neopentyl glycol (2,2-dimethyl-1,3-propanediol), 1,6-hexanediol, 1,8-utaneglycolcyclohexanedimethanol, 2-methylpropane-1,3-diol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, polypropylene glycol, dibutylene glycol and polybutylene glycol.
- esters preferably ⁇ -caprolactone.
- crystalline/semi-crystalline polyols such as esters of 1,4-butanediol with adipic acid.
- the polyester polyol has a melting point Tm > 0°C, preferably > 40°C and/or a number-average molecular weight Mn in the range from 400 to 5000, preferably 500 to 3000 g/mol, particularly preferably 800 to 2500 g/mol. most preferably 1000 to 2000 g/mol.
- the polyether polyol can be a polyalkylene glycol homo- or copolymer, preferably a polypropylene glycol homo- or copolymer, a polyethylene glycol homo- or copolymer, a polytetramethylene glycol homo- or copolymer, or a polypropylene glycol/polyethylene glycol block copolymer.
- the polyether polyol has a number average molecular weight of 1000 to 4000, preferably 1000 to 3000 g/mol.
- Suitable polycarbonates can be obtained by reacting carbonic acid derivatives, for example diphenyl carbonate, dimethyl carbonate or phosgene, with diols.
- diols are ethylene glycol, 1,2- and 1,3-propanediol, 1,3- and 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol, neopentyl glycol, 1,4-bishydroxymethylcyclohexane, 2-methyl-1,3-propanediol, 2,2,4-trimethylpentanediol-1,3, dipropylene glycol, polypropylene glycols, dibutylene glycol, polybutylene glycols, bisphenol A, tetrabromobisphenol A and lactone-modified diols.
- the diol component can also have ether or ester groups in addition to the terminal OH groups.
- the Hydroxyl polycarbonates should be essentially linear. However, they can optionally be slightly branched through the incorporation of polyfunctional components, in particular low molecular weight polyols. Suitable examples are glycerol, trimethylolpropane, 1,2,6-hexanetriol, 1,2,4-butanetriol, trimethylolpropane, pentaerythritol, quinitol, mannitol and sorbitol, methyl glycoside, 1,3,4,6-dianhydrohexitols.
- Suitable polycarbonate polyols include, without limitation, those available under the trade names Desmophen® C3200 (Bayer) and Kuraray® C2050 (poly(3-methyl-1,5-pentanediol, 1,6-hexanediol) carbonate; Kuraray).
- amorphous polyols preferably polyether polyols such as polypropylene glycol or poly-THF, with a number-average molecular weight Mn in the range from 400 g/mol to 5000 g/mol, a crystallinity of less than 10% and a glass transition temperature Tg in the range of -120 °C to 40 °C, preferably -70 °C to 30 °C, the crystallinity and the glass transition temperature being determined by differential scanning calorimetry (DSC) according to ISO 11357.
- DSC differential scanning calorimetry
- the amorphous polyols that can be used according to the embodiments described here are preferably polyether polyols and/or have a number-average molecular weight Mn in the range from 400 g/mol to 5000 g/mol, preferably 500 to 3000 g/mol, particularly preferably 800- 2500 g/mol, most preferably 1000 to 2000 g/mol.
- "Amorphous" as used herein in relation to the polyols means that the polyol has a crystallinity of less than 10%, preferably less than 5%, more preferably less than 2% as determined by differential scanning calorimetry (DSC ) determined according to ISO 11357.
- the amorphous (polyether) polyols have a glass transition temperature Tg in the range of -120 °C to 40 °C, preferably -70 °C to 30 °C, again determined by Differential Scanning Calorimetry (DSC) according to ISO 11357.
- Tg glass transition temperature
- the reaction mixture also includes a crystalline or semi-crystalline polyol.
- the crystalline or semi-crystalline polyol is preferably a polyester polyol or polycarbonate and can have a number average molecular weight Mn in the range 400 g/mol to 5000 g/mol, preferably 500 to 3000 g/mol, more preferably 800-2500 g/mol, most preferably 1000 to 2000 g/mol.
- Crystalstalline as used herein in relation to the (polyester) polyols refers to a crystallinity of at least 90%, preferably at least 95% as determined by differential scanning calorimetry (DSC) according to ISO 11357.
- crystalline and partially crystalline (polyester) polyols can have a melting point Tm in the range from 40°C to 220°C, preferably >40°C to ⁇ 160°C, more preferably >40°C to 80°C, most preferably >40 °C to 60 °C, again determined by differential scanning calorimetry (DSC) according to ISO 11357 with a heating rate of 20K/min.
- DSC differential scanning calorimetry
- the polyols have enthalpies of fusion of more than 90 J/g, preferably more than 115 J/g. If no If a standard reference of the polyol with a known crystallinity is available for the determination by DSC, known alternative methods such as X-ray diffractometry can be used.
- low molecular weight polyols such as glycol and derivatives thereof, such as di- or triethylene glycol, 1,2- or 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, neopentyl glycol, 1,6-hexanediol, Cyclohexanedimethanol and 2,2-bis(4'hydroxycyclohexyl)propane, but also polyhydric alcohols such as trishydroxyalkylalkanes (e.g. trimethylolpropane) or tetrakishydroxyalkylalkanes (e.g. pentaerythritol).
- glycol and derivatives thereof such as di- or triethylene glycol, 1,2- or 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, neopentyl glycol, 1,6-hexanediol, Cyclo
- polyols which are hydroxy-functionalized polymers, such as hydroxy-functionalized siloxanes.
- siloxanes that can be used are hydroxy-functionalized polydimethylsiloxanes, particularly in liquid form, such as are commercially available under the name Tegomer® H-Si 2311 (Evonik, Germany) with a molecular weight Mn of about 2200 g/mol.
- Suitable polydimethylsiloxane (PDMS) polyols are, for example, in US6794445B2 described.
- Polyolefin polyols suitable in the context of the present invention are derived, for example, from oligomeric and polymeric olefins having at least two terminal hydroxyl groups.
- alpha, omega-dihydroxypolybutadiene is preferred.
- Catalysts suitable in the context of the present invention include, for example but not limited to, tin, bismuth or zinc-based catalysts, for example dibutyltin dilaurate or dimethylbis[(1-oxoneodecyl)oxy]stannane, for example commercially available from Trade name Fomrez UL28 (Momentive Performance Materials GmbH, Germany).
- Alternative catalysts with high reactivity are bismuth neodecanoate and Zn neodecanoate available under the trade names BorchiKat 315 and BorchiKat 0761 (OMG Borchers GmbH, Germany).
- Usual amounts of catalyst are in the range from about 0.001 to 5% by weight, preferably in the range from about 0.01 to about 2% by weight, for example about 0.01, 0.02, 0.05, 0. 09, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0, 1.5 or 2.0 wt. -%, each based on the total weight of the reaction mixture of polyol and isocyanate components.
- the polyisocyanate is usually used in a molar excess in relation to the OH groups of all the polyols present, i.e. the at least one compound (A) and optionally the at least one compound (C), the OH/NCO equivalent ratio preferably being 1:1. 1 to 1:4, more preferably 1:1.2 to 1:1.3.
- the amount of the at least one polyisocyanate in the reaction mixture for preparing the prepolymer is typically in the range from 10 to 20% by weight, based on the reaction mixture.
- the remainder of the reaction mixture may consist of the polyol component(s) as defined above.
- the at least one compound (A) and the optional at least one compound (C) are combined and heated to about 70 to 95°C, e.g., about 75°C while stirring the mixture under vacuum to dry. After mixing, the mixture can be cooled to about 60°C for the addition of the isocyanates.
- the polyol mixture is then combined with at least one polyisocyanate (B) in the reaction mixture to form the prepolymer.
- the prepolymer reaction generally takes place at elevated temperature, for example in the range between about 70° C. and about 95° C., particularly preferably at about 80° C., over a period of about 1 to about 24 hours.
- step b) occurs at elevated temperatures ranging from about 27 to about 95°C, preferably about 50 to about 90°C.
- the reaction is continued until the free isocyanate content is at or very close to the calculated value as determined by standard titration with dibutylamine.
- Preferred values for the content of free isocyanate in the prepolymer are in the range between 0.2 and 3% by weight, preferably 1 to 2% by weight, based on the total weight of the reaction mixture.
- the polyisocyanate is reacted in the polyurethane prepolymer-forming reaction at a concentration in excess of the stoichiometric concentration required for complete reaction with the hydroxyl groups.
- the excess used may comprise an OH/NCO equivalent ratio of 1:1.1 to 1:4.
- the amount of polyisocyanate should be from 20% to 150% above the stoichiometric concentration required for complete reaction with the hydroxyl groups.
- the cationically modified polyurethane prepolymer thus obtained is then dispersed in an aqueous phase (step b).
- a suitable solvent preferably a water-miscible, highly volatile solvent.
- the prepolymer is preferably dispersed by adding the prepolymer in the aqueous phase with stirring.
- the degree of hardness of the water used is not important for the process, so the use of distilled or deionized water is not absolutely necessary.
- the dispersing according to step b) preferably takes place at a temperature of approximately 27 to 95.degree. C., in particular at approximately 30 to 90.degree.
- aqueous phase is heated before the addition of the prepolymer and/or that the mixture of both phases is heated, for example in the course of stirring. Agitation preferably occurs for a period of time from about 1 minute to about 60 minutes, for example about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 20, 25, 30, 35, 40, 45, 50, 55 or 60 minutes, preferably using a suitable stirring or mixing device, for example a magnetic stirrer or a static mixer.
- a suitable stirring or mixing device for example a magnetic stirrer or a static mixer.
- Chain extenders suitable for this purpose include, but are not limited to, inorganic or organic polyamines having an average of about 2 or more primary and/or secondary amine groups, or combinations thereof.
- Suitable organic amines include diamines and polyamines such as, but not limited to, ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA), meta-xylylenediamine (MXDA), aminoethylethanolamine (AEEA), 2-methylpentanediamine, and the like. Mixtures of the above are also suitable.
- EDA ethylenediamine
- DETA diethylenetriamine
- TETA triethylenetetramine
- MXDA meta-xylylenediamine
- AEEA aminoethylethanolamine
- 2-methylpentanediamine 2-methylpentanediamine
- Propylenediamine, butylenediamine, hexamethylenediamine, cyclohexylenediamine, phenylenediamine, tolylenediamine, 3,3-dichlorobenzide, 4,4'-methylenebis-(2-chloroaniline), 3,3-dichloro-4,4-diaminodiphenylmethane and sulfonated primary are also suitable and/or secondary amines and the like, and mixtures thereof.
- Useful inorganic amines include hydrazine, substituted hydrazines and hydrazine reaction products and the like, and mixtures thereof.
- adipic acid dihydrazide ethylenediamine, diethylenetriamine, triethylenetetraamine, tetraethylenepentamine, pentaethylenehexamine, dipropylenetriamine, hexamethylenediamine, hydrazine, isophoronediamine, N-(2-aminoethyl adducts)-acrylamido-2-methylpropane-1-sulfonic acid (AMPS ® ) and ethylenediamine, adduct salts of (meth)acrylic acid and ethylenediamine, adducts of 1,3-propanesulfone and ethylenediamine, or any combination of these polyamines.
- bifunctional primary amines especially ethylenediamine, are used.
- the amount of chain extender used is, in various embodiments, approximately 0 to 20% by weight, preferably about 0 to 15% by weight, for example about 0, 0.1, 05, 1.0, 1.5, 2.0, 3.0, 4.0, 5.0, 6.0, 7, 0, 8.0, 9.0, 10.0, 11.0, 12.0, 13.0, 14.0 or 15.0% by weight based on the total weight of the polyurethane prepolymer.
- the reaction is continued until the free isocyanate content is at or very close to the calculated value as determined by standard titration with dibutylamine.
- Preferred values for the content of free isocyanate in the prepolymer are in the range between 0.2 and 3% by weight, preferably 1 to 2% by weight, based on the total weight of the reaction mixture.
- Any solvents and/or acids present can then be removed in vacuo.
- the amount of cationic component, i.e. the amount of compound (A), in the polyurethane polymer is about 1 to 20% by weight, for example about 1, 2, 3, 4, 5, 6, 7, 8, 9 , 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20% by weight, preferably about 1 to 8% by weight, for example about 1.5, 2.5, 3.5, 4.5, 6.5, 7.5% by weight, each based on the total weight of the final polymer.
- the number of -(Y) n -H groups, as defined above, can be from 0.1 to about 20 milliequivalents per gram of urethane polymer.
- the at least one cationically modified polyurethane is in an amount of about 1 to 50% by weight, for example about 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 20, 25, 30, 35, 40, 45 or 50% by weight, preferably about 10 to 25% by weight, for example about 10, 16, 17, 18, 19, 20, 21, 22, 23, 24 or 25% by weight, based in each case on the total weight of the dispersion, contained in the latter.
- the dispersion of at least one cationically modified polyurethane has a viscosity of approximately 100 to 1000 mPas, for example 100, 150, 200, 500, 700, 750, 800, 850, 900, 950 or 1000 mPas, preferably approximately 200 to 600 mPas , for example about 100, 150, 300, 350, 400, 450, 500, 550 or 600 mPas.
- dispersions of cationically modified polyurethanes have a softening effect on textile fibers, in particular on cotton fibers, when they are brought into contact with laundry in the course of a rinsing process after the actual washing step. In order to be able to achieve such an effect, even low concentrations of such a dispersion are sufficient.
- a dispersion of at least one cationically modified polyurethane as defined and described above can be brought into contact with the laundry to be treated/conditioned either as a component of a textile treatment agent, for example a fabric softener, or in pure form, ie not as a component of a textile treatment agent.
- a dispersion as described herein of at least one cationically modified polyurethane polymer is used in pure form, it is sufficient if the dispersed, cationically modified polyurethane is present in an amount of about 1 to 50% by weight, for example about 1, 2, 3, 4, 5 , 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 20, 25, 30, 35, 40, 45 or 50% by weight, preferably about 10 to 25% by weight, for example about 10, 16, 17, 18, 19, 20, 21, 22, 23, 24 or 25% by weight, based in each case on the total weight of the dispersion.
- Advantageous amounts of a dispersion as described above are in the range from about 0.5 to 50 ml, preferably in the range from about 1 to 50 ml, for example about 1, 2, 3, 4, 5, 6, 7, 8, 9, 0 , 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 25, 30, 35, 40, 45 or 50 ml, more preferably in the range of about 3 to 30 ml to the amount of dispersion that is sufficient for the treatment/conditioning of a normal laundry load of approx. 1-5 kg and is accordingly introduced into the fabric softener compartment of a washing machine or used in the course of a manual washing process following the actual laundry cleaning process using a detergent.
- the present invention is also directed in a further aspect to a textile treatment agent comprising at least one dispersion of at least one cationically modified polyurethane as defined and described herein.
- a textile treatment agent is a fabric softener.
- other types of textile treatment agents such as textile sprays, for example ironing sprays, and the like, are also contemplated.
- a dispersion as described herein of at least one cationically modified polyurethane, or a mixture of several such dispersions is part of a textile treatment agent, for example a fabric softener, it is preferably in an amount of about 5 to 25% by weight, more preferably in an amount of about 6 to 15% by weight, for example in an amount of approximately 6, 7, 8, 9, 10, 11, 12, 13, 14 or 15% by weight, based in each case on the total weight of the composition.
- the agents according to the invention can contain other ingredients, for example at least one other component, preferably at least two other components, which further improve the performance and/or aesthetic properties of the agent.
- compositions according to the invention can of course comprise one or, preferably, several of these adjuvants.
- a "softening compound” within the meaning of the present invention is a compound that is able to soften textile fabrics or create this impression for the consumer.
- This designation correspondingly also includes a dispersion of at least one cationically modified polyurethane, as described above.
- at least one further plasticizing compound i.e. a plasticizing compound, which is used in addition to, in other words in combination with, the at least one dispersion of at least one cationically modified polyurethane, as defined herein, is preferably selected from the Group of quaternary ammonium compounds, selected in particular from the group of ester quats.
- esters of quaternary ammonium polyols particularly quaternary ammonium diols and/or triols such as triethanolmethylammonium or diethanoldimethylammonium, with fatty acids.
- esterquats in cosmetic products, detergents and aftertreatment agents, especially in fabric softeners, is known in the prior art. These contribute to improving the soft handle, reducing the static charging of the textile fabric and reducing the drying time.
- the textile treatment agent according to the invention contains at least one ester quat of the formula (I) N + (R1) 4-n ((CH 2 ) m -OC(O)-R 2 ) n X- where (I), each R 1 independently of one another is substituted or unsubstituted, linear or branched alkyl or alkenyl, preferably unsubstituted or hydroxy-substituted alkyl of 1 to 10 carbon atoms; each R 2 is linear or branched, substituted or unsubstituted alkyl or alkenyl, or substituted or unsubstituted (hetero)aryl of up to 26 carbon atoms, preferably linear unsubstituted C 10-26 alkyl; n is 1, 2, 3 or 4, preferably 1, 2 or 3; m is an integer from 1 to 20, preferably from 1 to 4; and X - is any anion.
- esterquats are bis(acyloxyethyl)hydroxyethylmethylammonium compounds.
- the counterion is preferably methosulfate.
- esterquats are commercially available, for example, under the trade name Dehyquart® AU-57 (BASF SE, DE).
- the textile treatment agent contains, based on the total weight of the agent, at least 4% by weight of at least one other softening compound as defined above, in particular at least one compound of the formula (I), for example in amounts of up to 60% by weight, preferably up to 30% by weight, based in each case on the total weight of the textile treatment composition.
- an agent according to the invention comprises at least one fragrance.
- fragrances or fragrances or perfume oils can be used as fragrances or fragrances or perfume oils.
- perfume oils for the purposes of this invention, the terms “fragrance(s)”, “fragrances” and “perfume oil(s)” are used synonymously. This means in particular all those substances or mixtures thereof which are perceived by humans and animals as an odour, in particular by humans as a pleasant odour.
- Perfumes, perfume oils or perfume oil components can be used as fragrance components.
- Perfume oils or fragrances can, according to the invention, contain individual fragrance compounds, e.g. B. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type.
- Perfume compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3-(4-isopropyl-phenyl)-2-methylpropanal), ethylvanillin, florhydral ( 3-(3-isopropylphenyl)butanal), Helional (3-(3,4-methylenedioxyphenyl)-2-methylpropanal), Heliotropin, Hydroxycitronellal, Lauraldehyde, Lyral (3- and 4-(4-Hydroxy-4-methylpentyl)- 3-cyclohexene-1-carboxaldehyde), methyl nonylacetaldehyde, Lilial (3-(4-tert-butylphenyl)-2-methylpropanal), phenylacetaldehyde, undecylene aldehyde, vanillin
- Perfume compounds of the ketone type are, for example, methyl beta-naphthyl ketone, musk indanone (1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-inden-4-one), Tonalide (6-acetyl-1,1,2,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso-damascone, damascenone, methyldihydrojasmonate, menthone, carvone, camphor, koavone (3rd ,4,5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta-ionone, gamma-methyl-ionone, fleuramon (2-heptylcyclopentanone), dihydrojasmon, cis-jasmon , iso-E-
- Perfume compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butylcyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenylpentanol, 3-octanol, 3-phenylpropanol, 4-heptenol, 4-isopropylcyclohexanol, 4-tert-butylcyclohexanol, 6 ,8-dimethyl-2-nona-nol, 6-nonen-1-ol, 9-decen-1-ol, ⁇ -methylbenzyl alcohol, ⁇ -terpineol, amyl salicylate, benzyl alcohol, benzyl salicylate, ⁇ -terpineol,
- Perfume compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate (DMBCA), phenylethyl acetate, benzyl acetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzyl salicylate, cyclohexyl salicylate, floramat, melusate and jasmacyclate.
- DMBCA dimethylbenzylcarbinyl acetate
- benzyl acetate ethylmethylphenylglycinate
- allylcyclohexylpropionate styrallylpropionate
- benzyl salicylate cyclohexyl salicylate,
- the ethers include, for example, benzyl ethyl ether and ambroxan.
- the hydrocarbons mainly include terpenes such as limonene and pinene.
- fragrance oils are preferably used, which together produce an appealing fragrance.
- Such a mixture of fragrances can also be referred to as a perfume or perfume oil.
- Perfume oils of this kind can also contain natural mixtures of fragrances, such as are obtainable from vegetable sources.
- Fragrances of plant origin include essential oils such as angelica root oil, anise oil, arnica flower oil, basil oil, bay oil, champaca flower oil, citrus oil, noble fir oil, noble pine cone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac oil, gurjun balm oil, helichrysum oil, ho oil , ginger oil, iris oil, jasmine oil, cajeput oil, sweet flag oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine needle oil, copaiva balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, labdanum oil, lavender oil, lemongrass oil, linden blossom oil, lime oil, tangerine oil, lemon balm oil, mint oil, musk seed oil , muscatel oil, myrrh oil, clove oil, ner
- the adherent fragrances that can be used in the context of the present invention include, for example, the essential oils such as angelica root oil, anise oil, arnica flower oil, basil oil, bay oil, Bergamot oil, champaca blossom oil, noble fir oil, noble pine cone oil, elemi oil, eucalyptus oil, fennel oil, spruce needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurjun balm oil, helichrysum oil, ho oil, ginger oil, iris oil, cajeput oil, sweet flag oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, Pine needle oil, copalva balsam oil, coriander oil, spearmint oil, cumin oil, cumin oil, lavender oil, lemongrass oil, lime oil, mandarine oil, lemon balm oil, musk seed oil, myrrh oil, clove oil, neroli oil, ni
- High-boiling or solid fragrances of natural or synthetic origin include, for example: ambrettolide, ⁇ -amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol, Bornyl acetate, ⁇ -bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate,
- the more volatile fragrances include, in particular, the lower-boiling fragrances of natural or synthetic origin, which can be used alone or in mixtures.
- Examples of more volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linyl acetate and linyl propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.
- Perfume compounds of the aldehyde type which can preferably be used are hydroxycitronellal ( CAS 107-75-5 ), helional ( CAS 1205-17-0 ), citral (5392-40-5), bourgeonal (18127-01-0), triplal ( CAS 27939-60-2 ), Ligustral ( CAS 68039-48-5 ), vertocitral ( CAS 68039-49-6 ), Florhydral ( CAS 125109-85-5 ), citronellal ( CAS 106-23-0 ), citronellyloxyacetaldehyde ( CAS 7492-67-3 ).
- the content of such a fragrance which can also be present in the form of a perfume oil or as a component of a perfume oil composition, is such as described above, preferably between about 0.0001 and 5% by weight, more preferably between about 0.001 and 3.0% by weight, preferably between about 0.005 and 1.5% by weight, even more preferably between about 0.01 and 1.0% by weight, for example about 0.001, 0.002, 0.003, 0.004, 0.005, 0.006, 0.007, 0.008, 0.009, 0.01, 0.02, 0.03, 0.04, 0.05, 0, 06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9 or 1.0% by weight, based in each case on the total weight of the agent according to the invention.
- Microcapsule refers to capsules with micron-scale core-shell morphology having a capsule shell that completely encloses a core.
- “Completely encloses” or “completely surrounds” as used herein in relation to the microcapsules means that the core is completely surrounded by the shell, i.e. in particular not embedded in a matrix in such a way that it is exposed at any point.
- the capsule shell is designed in such a way that the release of the content is controlled, i.e. the content is not spontaneously released in an uncontrolled manner independently of a release stimulus. For this reason, the capsule shell is preferably essentially impermeable to the encapsulated contents.
- the core can be solid, liquid and/or gas, but is preferably solid and/or liquid.
- the microcapsules are preferably essentially spherical and have diameters in the range from 0.01 to 1000 ⁇ m, in particular from 0.1 to 500 ⁇ m.
- Capsule shell and capsule core consist of different materials, in particular the capsule shell is preferably solid under standard conditions (20° C., 1013 mbar), the core preferably solid and/or liquid, in particular liquid.
- encapsulation material for microcapsules suitable in the context of the present invention, e.g. B. high molecular weight compounds of animal or vegetable origin, z. B. Protein compounds (gelatine, albumin, casein), cellulose derivatives (methyl cellulose, ethyl cellulose, cellulose acetate, cellulose nitrate, carboxymethyl cellulose) and in particular synthetic polymers (e.g. polyamides, polyolefins, polyesters, polyurethanes, epoxy resins, silicone resins and condensation products of carbonyl and NH group-containing compounds) can be used.
- synthetic polymers e.g. polyamides, polyolefins, polyesters, polyurethanes, epoxy resins, silicone resins and condensation products of carbonyl and NH group-containing compounds
- the shell material can be selected from, for example, polyacrylates; polyethylene; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyureas; polyurethanes; polyolefins; polysaccharides; epoxy resins; vinyl polymers; urea crosslinked with formaldehyde or glutaraldehyde; melamine crosslinked with formaldehyde; Gelatin polyphosphate coacervates, optional crosslinked with glutaraldehyde; gelatin gum arabic coacervates; silicone resins; polyamines reacted with polyisocyanates; acrylate monomers polymerized by free radical polymerization; Silk; Wool; Gelatin; cellulose; proteins; and blends and copolymers of the foregoing.
- polyacrylates polyethylene; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyureas; polyurethanes; polyolefins; polysaccharides;
- Polyacrylates polyethylene, polyamides, polystyrenes, polyisoprenes, polycarbonates, polyesters, polyureas, polyurethanes, polyolefins, epoxy resins, vinyl polymers and urea and/or melamine crosslinked with formaldehyde or glutaraldehyde are particularly preferred.
- the known microencapsulation processes are suitable for producing suitable microcapsules.
- B. the encapsulation of the encapsulated phase by encapsulation with film-forming polymers (as z. B. previously mentioned), which are reflected after emulsification and coacervation or interfacial polymerisation on the material to be encapsulated takes place.
- the phase to be encapsulated is a benefit agent composition, preferably a perfume composition, usually in the form of a perfume oil.
- the capsules can release the encapsulated benefit agents via a variety of mechanisms.
- capsules that have a mechanically stable capsule shell, but which then becomes permeable to the contained agents due to one or more environmental influences, such as changes in temperature or ionic strength or the pH value of the surrounding medium, are used will.
- Stable capsule wall materials are also possible, through which the at least one beneficial agent, for example a perfume oil and possibly other beneficial agents, can diffuse over time.
- the capsules can preferably release the at least one beneficial agent contained in the event of a change in the pH value or the ionic strength of the environment, a change in temperature, exposure to light, diffusion and/or mechanical stress.
- the capsules are fragile, i.e. they can release entrapped agent due to mechanical stress such as friction, pressure or shear stress which ruptures the shell of the capsules.
- the capsule is thermally unstable, i.e. enclosed substances can be released if the capsules are at a temperature of at least 70°C, preferably at least 60°C, preferably at least 50°C and in particular at least 40° C is exposed.
- the capsule may become permeable to the enclosed benefit agent(s) after exposure to radiation of a certain wavelength, preferably exposure to sunlight.
- the capsules are fragile and at the same time thermally unstable and/or unstable to radiation of a specific wavelength.
- Suitable microcapsules can be water-soluble and/or water-insoluble, but the capsules are preferably water-insoluble.
- the water-insolubility of the capsules has the advantage that these washing, cleaning or other treatment applications can survive and are thus able to release the at least one beneficial agent only after the aqueous washing, cleaning or treatment process, such as during drying by a mere increase in temperature or by exposure to the sun or, in particular, by friction on the surface.
- capsules means, in particular, those capsules which, when attached to a surface treated therewith (e.g. textile surface), can be opened or ruptured by mechanical rubbing or by pressure, so that the contents can be released only as a result of a mechanical effect, e.g. if you dry your hands with a towel on which such capsules are deposited.
- a surface treated therewith e.g. textile surface
- friable capsules can have an average diameter dso of ⁇ 250 ⁇ m, preferably in the range from 1 to 100 ⁇ m, preferably between 3 and 95 ⁇ m, in particular between 4 and 90 ⁇ m, for example between 5 and 80 ⁇ m, for example between 5 and 40 have microns.
- the d 50 value indicates the diameter that results when 50% by weight of the capsules have a smaller diameter and 50% by weight of the capsules have a larger diameter than the determined d 50 value.
- the d 90 value of the particle size distribution of the microcapsules is ⁇ 70 ⁇ m, preferably ⁇ 60 ⁇ m, particularly preferably ⁇ 50 ⁇ m.
- the d 90 value of the particle size distribution is the value at which 90% of all particles are smaller and 10% of the particles are larger than this value.
- the core or (filled) cavity enclosing shell of the capsules preferably has an average thickness in the range between about 50 and 500 nm, preferably between about 100 nm and about 250 nm specified ranges relating to the mean diameter and relating to the average thickness.
- the d 50 value indicates the diameter that results when 50% by weight of the capsules have a smaller diameter and 50% by weight of the capsules have a larger diameter than the determined d 50 value. It is furthermore preferred that the d 90 value of the particle size distribution of the microcapsules is ⁇ 70 ⁇ m, preferably ⁇ 60 ⁇ m, particularly preferably ⁇ 50 ⁇ m. The d 90 value of the particle size distribution is the value at which 90% of all particles are smaller and 10% of the particles are larger than this value.
- the diameter of the capsules or the particle size of the microcapsules can be determined using customary methods. It can be determined, for example, with the aid of dynamic light scattering, which is usually carried out on dilute suspensions containing, for example, 0.01 to 1% by weight of capsules. can be carried out. It can also be done by evaluating light microscopic or electron microscopic images of capsules.
- a microcapsule according to the invention has an average diameter dso of approximately 1 to 80 ⁇ m, preferably approximately 5 to 40 ⁇ m, in particular approximately 20 to 35 ⁇ m, for example approximately 22 to approximately 33 ⁇ m.
- the wall material of the microcapsules preferably comprises polyurethanes, polyolefins, polyamides, polyesters, polysaccharides, epoxy resins, silicone resins and/or polycondensation products from carbonyl compounds and compounds containing NH groups.
- melamine-urea-formaldehyde microcapsules or melamine-formaldehyde microcapsules or urea-formaldehyde microcapsules can preferably be used.
- Microcapsules based on melamine-formaldehyde resins are particularly preferred.
- microcapsule manufacture as such has long been well known to those skilled in the art. Particularly suitable methods for microcapsule production are in principle z. Am U.S. 3,516,941 , in U.S. 3,415,758 or also in EP 0 026 914 A1 described. The latter describes, for example, microcapsule production by acid-induced condensation of melamine-formaldehyde precondensates and/or their C1-C4-alkyl ethers in water, in which the hydrophobic material forming the capsule core is dispersed, in the presence of a protective colloid.
- Suitable thickeners include, for example, Aerosil types (hydrophilic silicic acids), polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose, methyl cellulose, hydroxypropyl, hydroxypropylmethyl and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono - and diesters of fatty acids, polyacrylates (e.g.
- surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with concentrated Homolog distribution or alkyl oligoglucosides and electrolytes such as common salt and ammonium chloride.
- the at least one thickener is a nonionic thickener, in particular selected from the group consisting of hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), hydroxypropylmethyl cellulose (HPMC), methyl cellulose (MC), guar, guar derivatives (such as Jaguar HP105 ( Rhodia); hydroxypropyl guar) and mixtures of the aforementioned nonionic thickeners.
- HEC hydroxyethyl cellulose
- HPC hydroxypropyl cellulose
- HPMC hydroxypropylmethyl cellulose
- MC methyl cellulose
- guar derivatives such as Jaguar HP105 ( Rhodia); hydroxypropyl guar
- cationic thickeners can also be used.
- suitable cationic thickeners include, for example, those available under the tradename Rheavis ® CSP (BASF).
- the at least one nonionic or cationic thickener is present in the composition in an amount of 0.1 to 10% by weight, based on the total weight of the formulation.
- the agent contains at least one emulsifier.
- the at least one emulsifier is preferably a nonionic emulsifier and has an HLB value of at least 12.0, preferably at least 13.0, more preferably at least 14.0 and most preferably at least 15.0.
- HLB hydrophilic-lipophilic balance
- Low HLB values describe lipophilic substances
- high HLB values describe hydrophilic substances.
- defoamers typically have HLB values in the range of 1.5 to 3 and are insoluble in water.
- Emulsifiers for w/o emulsions typically have HLB values in the range 3-8, whereas emulsifiers for o/w emulsions typically have HLB values in the range 8-18.
- Detergents typically have HLB values in the range of 13-15 and solubilizers in the range of 12-18.
- the addition products of ethylene oxide and/or propylene oxide onto fatty alcohols, fatty acids, alkylphenols or castor oil are known, commercially available products. These are homologous mixtures whose average degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and/or propylene oxide and substrate, with which the addition reaction is carried out corresponds.
- C12/18 fatty acid mono- and diesters of addition products of ethylene oxide to glycerol are from DE 2024051 PS is known as a refatting agent for cosmetic preparations.
- Alkyl and/or alkenyl oligoglycosides their preparation and their use are known from the prior art. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols having 8 to 18 carbon atoms.
- glycoside residue both monoglycosides, in which a cyclic sugar residue is glycosidically bonded to the fatty alcohol, and oligomeric glycosides with a degree of oligomerization of preferably up to about 8 are suitable.
- the degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products.
- Suitable partial glycerides are hydroxystearic hydroxystearic acid diglyceride, isostearic acid, Isostearinklarediglycerid monoglyceride, oleic acid diglyceride, Ricinolklaremoglycerid, Ricinolklarediglycerid, Linolklaremonoglycerid, Linolklarediglycerid, Linolenchuremonoglycerid, Linolenchurediglycerid, Erucaklaklaremonoglycerid, E-rucaklarediglycerid, Weinchuremonoglycerid, Weinklaklarediglycerid, Citronenklamonoglycerid, Citronendiglycerid, ⁇ pfelklaklamonoglycerid, Apfelklakladrediglycerid well as their technical Mixtures that may contain small amounts of triglycerides as a result of the manufacturing process. Addition products of 1 to 30, preferably 5 to 10, moles of ethylene oxide onto
- sorbitan esters sorbitan-noisostearat, sorbitan sesquiisostearate, Amrtrat Sorbitan, sorbitan triisostearate, sorbitan monooleate, sorbitan, sorbitan, Sorbitanmonoerucat, Sorbitansesquierucat, Sorbitandierucat, Sorbitantrierucat, Sorbitanmonoricinoleat, Sorbitansesquiricinoleat, Sorbitandiricinoleat, Sorbitantriricinoleat, Sorbitanmonohydroxystearat, Sorbitansesquihydroxystearat, Sorbitandihydroxystearat, Sorbitantrihydroxystearat, Sorbitanmonotartrat, Sorbitansesq, Sorbitan itartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan citrate, sorbitan tric
- polyglycerol esters are polyglyceryl-2 dipolyhydroxystearates ( Dehymuls® PGPH), polyglycerol-3-diisostearates ( Lameform® TGI), polyglyceryl-4 isostearates ( Isolan® GI 34), polyglyceryl-3 oleates, diisostearoyl polyglyceryl-3 diisostearates (Isolan ® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care ® 450), Polyglyceryl-3 Beeswax (Cera Bellina ® ), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010/90), Polyglyceryl-3 Cetyl Ether (Chimexane ® NL) , Polyglyceryl-3 distearate (Cremophor ® GS 32) and polyglyceryl polyricinoleate (Admul ® WOL 1403)
- polystyrene resin examples include the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like, optionally reacted with 1 to 30 moles of ethylene oxide.
- the agent according to the invention can also contain other emulsifiers, for example cationic or anionic emulsifiers.
- the known cationic emulsifiers include fatty acid amidoamines and/or their quaternization products.
- Fatty acid amidoamines which are suitable as cationic emulsifiers are condensation products of fatty acids with optionally ethoxylated di- or oligoamines which preferably follow the formula (II), R 1 CO-NR 2 -[(A)-NR 3 ] n -R 4 (II) in which R 1 CO is a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms, R 2 is hydrogen or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms, R 3 and R 4 are each independently hydrogen , a (CH 2 CH 2 O) m H group or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms, A is a linear or branched alkylene group having 1 to 6 carbon atoms, n is a number from 1 to 4 and m is a number from 1 up to 30.
- R 1 CO is a linear or branched, saturated or unsatur
- Typical examples are condensation products of caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures with ethylenediamine, propylenediamine, diethylenetriamine, dipropylenetriamine, triethylenetetramine, tripropylenetetramine and their adducts with 1 to 30, preferably 5 to 15 and in particular 8 to 12 mol ethylene oxide.
- the use of ethoxylated fatty acid amidoamines is preferred because in this way the hydrophilicity of the emulsifiers can be
- fatty acid amidoamines it is also possible to use their quaternization products, which are obtained by reacting the amidoamines with suitable alkylating agents, such as, for example, methyl chloride or, in particular, dimethyl sulfate, using processes known per se.
- suitable alkylating agents such as, for example, methyl chloride or, in particular, dimethyl sulfate
- the quaternization products preferably follow the formula (III), [R 1 CO-NR 2 - [(A) -N + R 3 R 6 ) n -R 4 ]X - (III), in which R 1 CO represents a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms, R 2 is hydrogen or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms, R 3 is hydrogen, a (CH 2 CH 2 O) m H group or an optionally hydroxy-substituted alkyl radical 1 to 4 carbon atoms, R 4 is R 1 CO, hydrogen, a (CH 2 CH 2 O) m H group or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms, R 6 is an alkyl radical having 1 to 4 carbon atoms, A is a linear or branched alkylene group having 1 to 6 carbon atoms, n is a number from 1 to 4, m is
- Suitable for this purpose are, for example, the methylation products of the preferred fatty acid amidoamines already mentioned above. Furthermore, mixtures of fatty acid amidoamines and their quaternization products can also be used, which are particularly easy to prepare by not carrying out the quaternization completely, but only to a desired degree.
- the agent can contain the fatty acid amidoamines and/or their quaternization products in amounts of 0.1% by weight to 50% by weight, preferably 1% by weight to 30% by weight and in particular 2% by weight to 10% by weight. -% - based on the final concentration - included.
- Betaines are known surfactants which are mainly produced by carboxyalkylation, preferably carboxymethylation, of amine compounds.
- the starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mole of salt being formed per mole of betaine.
- unsaturated carboxylic acids such as acrylic acid, is also possible.
- betaines are the carboxyalkylation products of secondary and especially tertiary amines which follow the formula (IV), R 7 -N + (R 8 )(R 9 )-(CH 2 ) p COOA (IV) where R 7 for alkyl and/or alkenyl radicals having 6 to 22 carbon atoms, R 8 for hydrogen or alkyl radicals with 1 to 4 carbon atoms, R 9 for alkyl radicals with 1 to 4 carbon atoms, p for numbers from 1 to 6 and A for an alkali - and/or alkaline earth metal or ammonium.
- Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C 12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, Stearylethylmethylamine, oleyldimethylamine, C 16/18 -tallow alkyldimethylamine and technical mixtures thereof.
- carboxyalkylation products of amidoamines which follow the formula (V), R 10 CO-NH-(CH 2 ) m -N + (R 8 )(R 9 )-(CH 2 ) p COOA (V), in which R 10 CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m is a number from 1 to 3 and R 3 , R 9 , p and A are as defined above.
- Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid as well their technical mixtures, with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminoethylamine and N,N-diethylaminopropylamine, which are condensed with sodium chloroacetate.
- Preference is given to using a condensation product of C 8/18 coconut fatty acid N,N-dimethylaminopropylamide with sodium chloro
- suitable starting materials are also imidazolines which follow the formula (VI), in which R 5 is an alkyl group having 5 to 21 carbon atoms, R 6 is a hydroxyl group, an OCOR 5 or NHCOR 5 group and m is 2 or 3.
- These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyvalent amines, such as aminoethylethanolamine (AEEA) or diethylenetriamine.
- AEEA aminoethylethanolamine
- the corresponding carboxyalkylation products are mixtures of different open-chain betaines.
- Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably imidazolines based on lauric acid or, in turn, C 12/14 coconut fatty acid, which are then betainized with sodium chloroacetate.
- a composition according to the invention can contain the betaines in amounts of 0.1 to 50% by weight, preferably 1 to 30% by weight and in particular 2 to 10% by weight, based on the final concentration.
- the agent according to the invention may contain combinations of nonionic emulsifiers with other nonionic emulsifiers, anionic emulsifiers and/or cationic emulsifiers, the HLB value of the emulsifier mixture of the (at least one) first and (at least one) second emulsifier preferably being at least 12, 0, more preferably at least 14.0, most preferably at least 15.0.
- the ratio of the first is Emulsifier to the second emulsifier while 0.9 to 0.1 to 0.9 to 0.1.
- the second emulsifier is also a nonionic emulsifier.
- the agent also contains at least one non-aqueous solvent selected from (poly)alkylene glycols or alcohols, for example from the group of mono- or polyhydric alcohols.
- non-aqueous solvent selected from (poly)alkylene glycols or alcohols, for example from the group of mono- or polyhydric alcohols.
- Alkanolamines or glycol ethers are also suitable, provided they are miscible with water in the concentration range used.
- the solvents are preferably selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, diglycol, propyl or butyl diglycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol monobutyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, dipropylene glycol methyl or ethyl ether, methoxy, ethoxy or butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol tbutyl ether, and mixtures of these solvents.
- the at least one non-aqueous solvent is selected from ethanol, propylene glycol, dipropyl,
- the agent also contains at least one hydrotrope.
- suitable hydrotropes are, in particular, aromatic alkyl sulfonates, such as in particular toluene sulfonates, cumene sulfonates, xylene sulfonates and others.
- the at least one hydrotrope is in particular an aromatic alkylsulfonic acid or an ester or salt thereof, preferably selected from p-toluenesulfonic acid methyl ester, p-toluenesulfonic acid monohydrate and p-cumenesulfonic acid or the corresponding salts, in particular the sodium salts.
- pH adjusters In order to bring the pH of the agent according to the invention into the desired range, the use of pH adjusters can be indicated. All known acids or bases can be used here, provided that their use is not prohibited for technical or ecological reasons or for reasons of consumer protection. The amount of these extenders does not usually exceed 1% by weight of the total formulation.
- Colorants are added to the composition of the invention to improve the aesthetic appeal of the product and to provide the consumer with a visually "typical and distinctive" product.
- the content of dyes is usually less than 0.01% by weight of the composition formulation.
- Preferred dyes the selection of which presents no difficulty to the person skilled in the art, have a high storage stability and are insensitive to the other ingredients of the agents and to light, and do not have any pronounced substantivity to textile fibers so as not to stain them.
- Foam inhibitors that can be used in the agent according to the invention are, for example, soaps, paraffins or silicone oils, which can optionally be applied to carrier materials.
- Suitable antiredeposition agents, also referred to as soil repellents are, for example, nonionic cellulose ethers, such as methylcellulose and methylhydroxypropylcellulose, with a proportion of 15 to 30% by weight of methoxy groups and 1 to 15% by weight of hydroxypropyl groups, based in each case on the nonionic cellulose ether and those from the prior art known polymers of phthalic acid and/or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and/or polyethylene glycol terephthalates or anionically and/or nonionically modified derivatives of these. Particularly preferred of these are the sulfonated derivatives of the phthalic and terephthalic acid polymers.
- Suitable enzymes are in particular those from the class of hydrolases, such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases contribute to the removal of soiling such as protein, fat or starchy soiling and graying in the wash. Cellulases and other glycosyl hydrolases can also help to retain the color and increase the softness of the textile by removing pilling and microfibrils. Oxyreductases can also be used to bleach or to inhibit color transfer.
- hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases contribute to the removal of soiling such as protein, fat or starchy soiling and graying in the wash. Cellulases and other glycosyl hydrolases can also help to retain the color
- Enzymatic active ingredients obtained from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens are particularly suitable.
- Proteases of the subtilisin type and in particular proteases which are obtained from Bacillus lentus are preferably used.
- enzyme mixtures for example of protease and amylase or protease and lipase or lipolytic acting enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and/or lipase-containing mixtures or Mixtures with lipolytic enzymes are of particular interest.
- lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proven to be suitable in some cases.
- Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
- Cellobiohydrolases, endoglucanases and ⁇ -glucosidases, which are also called cellobiases, or mixtures of these are preferably used as cellulases. Since different types of cellulase differ in their CMCase and Avicelase activities, the desired activities can be set by mixing the cellulases in a targeted manner.
- the enzymes can be adsorbed on carriers or embedded in encapsulating substances in order to protect them against premature decomposition.
- the proportion of the enzymes, enzyme mixtures or enzyme granules can be, for example, about 0.1 to 5% by weight, preferably 0.12 to about 2% by weight.
- Optical brighteners can be added to the agents according to the invention in order to eliminate graying and yellowing of the treated textiles. These substances attach to the fiber and cause lightening and feigned bleaching by converting invisible ultraviolet radiation into visible longer wavelength light, with the ultraviolet light absorbed from sunlight being emitted as a faint bluish fluorescence and pure with the yellow hue of graying or yellowed laundry results in white.
- Suitable compounds come, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (flavonic acids), 4,4'-distyrylbiphenylene, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalic acid imides, benzoxazole , benzisoxazole and benzimidazole systems as well as pyrene derivatives substituted by heterocycles.
- the optical brighteners are usually used in amounts of between 0.1% by weight and 0.3% by weight, based on the finished agent.
- the task of graying inhibitors is to keep the dirt that has been detached from the fibers suspended in the liquor and thus prevent the dirt from being reattached.
- Water-soluble colloids of mostly organic nature are suitable for this purpose, for example the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether sulfonic acids of starch or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
- Water-soluble polyamides containing acidic groups are also suitable for this purpose. Soluble starch preparations and starch products other than those mentioned above, such as degraded starches, aldehyde starches, etc., can also be used.
- cellulose ethers such as carboxymethyl cellulose (Na salt), methyl cellulose, hydroxyalkyl cellulose and mixed ethers such as methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl carboxymethyl cellulose and mixtures thereof are preferably used in amounts of 0.1 to 5% by weight, based on the formulation of the agent.
- the agents according to the invention can contain synthetic anti-crease agents. These include, for example, synthetic products based on fatty acids, fatty acid esters. Fatty acid amides, alkylol esters, alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid esters.
- the agent can contain antimicrobial agents.
- antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostatics and bactericides, fungistatics and fungicides, etc.
- Important substances from these groups are, for example, benzalkonium chlorides.
- Preferred compounds within the scope of the present invention are, for example, alkyl aryl sulfonates, halophenols and phenolmercuric acetate, although these compounds can also be dispensed with entirely in the agents according to the invention.
- the agent according to the invention can contain preservatives, with preference being given to using only those which have little or no skin-sensitizing potential.
- preservatives examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynylbutylcarbamate, sodium N-(hydroxymethyl)glycinate, biphenyl-2-ol, and mixtures thereof.
- a suitable preservative is the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl ® K 500 from Schuelke & Mayr), which can be used in a pH range of up to 7.
- preservatives based on organic acids and/or their salts are suitable for preserving the agent.
- the agent can contain antioxidants.
- This class of compounds includes, for example, substituted phenols, hydroquinones, catechols and aromatic amines as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
- Antistatic agents increase the surface conductivity and thus enable an improved flow of charges that have formed.
- External antistatic agents are generally substances with at least one hydrophilic molecular ligand and form a more or less hygroscopic film on the surface. These mostly surface-active antistatic agents can be divided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
- External antistatic agents are, for example, in the patent applications FR 1,156,513 , GB 873 214 and GB 839 407 described.
- the lauryl (or Stearyl)dimethylbenzylammonium chlorides are suitable as antistatic agents for textiles, with an additional finishing effect being achieved.
- the agent according to the invention can also contain UV absorbers which are absorbed by the treated textiles and improve the lightfastness of the fibers.
- Compounds which have these desired properties are, for example, the compounds and derivatives of benzophenone having substituents in the 2- and/or 4-position which are effective through radiationless deactivation.
- substituted benzotriazoles acrylates phenyl-substituted in the 3-position (cinnamic acid derivatives), optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and endogenous urocanic acid.
- a composition according to the invention can contain a dye transfer inhibitor.
- the dye transfer inhibitor is a polymer or copolymer of cyclic amines such as vinyl pyrrolidone and/or vinyl imidazole.
- Polymers useful as dye transfer inhibitors include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP/PVI), polyvinylpyridine N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures from it.
- Polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI) or copolymers of vinylpyrrolidone and vinylimidazole (PVP/PVI) are particularly preferably used as color transfer inhibitors.
- the polyvinylpyrrolidones (PVP) used preferably have an average molecular weight of 2,500 to 400,000 and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan® HP 50 or Sokalan® HP 53 available.
- the copolymers of vinylpyrrolidone and vinylimidazole (PVP/PVI) used preferably have a molecular weight in the range from 5,000 to 100,000.
- a PVP/PVI copolymer is commercially available, for example from BASF under the name Sokalan® HP 56.
- the amount of color transfer inhibitor is preferably from 0.01% by weight to 2% by weight, preferably from 0.05% by weight to 1% by weight and more preferably from 0. 1% to 0.5% by weight.
- enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance that yields hydrogen peroxide in water can also be used as color transfer inhibitor.
- a mediator compound for the peroxidase for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, it also being possible to use the polymeric color transfer inhibitors mentioned above.
- Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
- EDTA ethylenediaminetetraacetic acid
- NTA nitrilotriacetic acid
- anionic polyelectrolytes such as polymaleates and polysulfonates.
- a preferred class of complexing agents are the phosphonates, which are present in preferred agents in amounts of 0.01% by weight to 2.5% by weight, preferably 0.02% by weight to 2% by weight and in particular from 0 .03% by weight to 1.5% by weight are contained.
- These preferred compounds include, in particular, organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri(methylenephosphonic acid) (ATMP), diethylenetriaminepenta(methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2,4 -tricarboxylic acid (PBS-AM), which are mostly used in the form of their ammonium or alkali metal salts.
- organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri(methylenephosphonic acid) (ATMP), diethylenetriaminepenta(methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane
- the textile treatment agents described herein are preferably prepackaged to form dosage units.
- These dosing units preferably include the amount of washing or care-active substances required for one cleaning cycle.
- suitable dosage units have a weight between 12 and 30 g, for example.
- the volume of the aforementioned dosing units and their three-dimensional shape are selected with particular preference in such a way that the prefabricated units can be dosed via the dosing chamber of a washing machine.
- the volume of the dosage unit is therefore preferably between 10 and 35 ml, preferably between 12 and 30 ml.
- the agents according to the invention in particular the prefabricated dosage units, particularly preferably have a water-soluble coating.
- a composition as described herein is in the form of a unit dose as previously described.
- such an agent according to the invention is in particular encased in a water-soluble film.
- the water-soluble cover is preferably formed from a water-soluble film material which is selected from the group consisting of polymers or polymer mixtures.
- the cover can be formed from one or from two or more layers of the water-soluble film material.
- the water-soluble film material of the first layer and the further layers, if any, can be the same or different. Films are particularly preferred which can be glued and/or sealed to form packaging such as tubes or pillows after they have been filled with an agent.
- the foils are in the form of multi-chamber pouches.
- the water-soluble coating contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
- Water-soluble coatings that contain polyvinyl alcohol or a polyvinyl alcohol copolymer have good stability with sufficiently high water solubility, especially cold water solubility.
- Suitable water-soluble films for producing the water-soluble casing are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range from 10,000 to 1,000,000 gmol -1 , preferably from 20,000 to 500,000 gmol -1 , particularly preferably from 30,000 to 100,000 gmol -1 and in particular from 40,000 to 80,000 gmol -1 .
- Polyvinyl alcohol is usually produced by hydrolysis of polyvinyl acetate, since the direct synthesis route is not possible. The same applies to polyvinyl alcohol copolymers which are correspondingly produced from polyvinyl acetate copolymers. It is preferred if at least one layer of the water-soluble coating comprises a polyvinyl alcohol whose degree of hydrolysis is 70 to 100 mol %, preferably 80 to 90 mol %, particularly preferably 81 to 89 mol % and in particular 82 to 88 mol %.
- a polyvinyl alcohol-containing film material suitable for producing the water-soluble casing can also have a polymer selected from the group consisting of (meth)acrylic acid-containing (co)polymers, polyacrylamides, oxazoline polymers, polystyrene sulfonates, polyurethanes, polyesters, polyethers, polylactic acid or mixtures of the above Polymers can be added.
- a preferred additional polymer are polylactic acids.
- preferred polyvinyl alcohol copolymers include dicarboxylic acids as further monomers. Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and mixtures thereof, with itaconic acid being preferred.
- Polyvinyl alcohol copolymers which are also preferred include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its ester.
- Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylic acid esters, methacrylic acid esters or mixtures thereof.
- the film material contains further additives.
- the film material can contain, for example, plasticizers such as dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, glycerol, sorbitol, mannitol or mixtures thereof.
- Further additives include, for example, release aids, fillers, crosslinking agents, surfactants, antioxidants, UV absorbers, anti-blocking agents, anti-adhesive agents or mixtures thereof.
- Suitable water-soluble films for use in the water-soluble wrappers of the water-soluble packages of the invention are films sold by MonoSol LLC, for example, under the designation M8630, C8400 or M8900.
- Other suitable films include Solublon® PT, Solublon® GA, Solublon® KC or Solublon® KL films from Aicello Chemical Europe GmbH or Kuraray VF-HP films.
- the use of the textile treatment agent according to the invention, as described above, for textile care and or conditioning purposes, as defined herein, is another subject of Invention.
- the present invention relates to the use of an agent as described herein for conditioning, in particular for softening textiles.
- the present invention relates to uses in which a textile treatment agent as described herein is used in a manual textile treatment process or, preferably, in the washing machine.
- Another subject of the invention is a manual or preferably machine method for conditioning textiles, characterized in that at least one dispersion of at least one cationically modified polyurethane and/or at least one textile treatment agent, as described herein, is used in at least one method step.
- the present invention relates to a method for applying a dispersion of at least one cationically modified polyurethane to textiles, wherein the dispersion in pure form or as a component of a textile treatment agent, as described herein, is given together with the textiles in a household washing machine or an industrial washing machine and a washing program is subjected, so that the dispersion of at least one cationically modified polyurethane is released into the rinsing liquor and can then be reflected on the textiles.
- a dispersion of a cationically modified polyurethane or a textile treatment agent containing such a dispersion can in principle also be used advantageously in combination with other textile detergents and/or care agents in corresponding processes.
- the present invention relates in particular to those methods in which, in addition to the at least one dispersion or the at least one textile treatment agent, as described herein, a detergent is also used.
- 2,3-Dihydroxy-N,N,N-trimethylpropane-1-ammonium chloride (10 g, 59 mmol) and 1,2-epoxybutane (20.6 mL, 236 mmol) were prepared in the presence of potassium hydroxide (200 mg, 0 6 mmol) at 120 °C for 24 h in an autoclave.
- Arkema Realkyd XTR 20112 75.22 g, Mw 2074 g/mol; adipic acid/butylene glycol polyester polyol
- Arkema Realkyd XTR 10110 6.45 g, Mw 1000 g/mol; adipic acid/butylene glycol polyester polyol
- cationic ammonium diol 2.44 g, Mw 400 g/mol
- K-HN-8200 4.08 g, Mw 1941 g/mol; polyether , Mn approximately 2000 g/mol, 80% EO, Hannong Chemicals.
- the heterogeneous mixture was heated to 75°C (bath temperature) until Realkyd XTR 20112 and XTR 10110 fused with the rest of the components.
- the mixture was dried under vacuum for 1-2 h.
- the mixture was allowed to cool to 60°C.
- DN-980S (0.35 g, 504 g/mol; hexamethylene diisocyanate-based isocyanurate-type polyisocyanate, manufactured by DIC Corporation, isocyanate group content 21 wt%, non-volatile content: 100 wt%), isophorone diisocyanate (5.50 g , Mw 222.29 g/mol) and hexamethylene diisocyanate (6.25, Mw 168 g/mol) were added to the reaction mixture. Then the mixture was heated to 85°C and the catalyst (DBTDL catalyst, 3.8 mg dissolved in 3.87 g acetone) was added. Thereafter, the reaction was left at 85°C for 3 hours. Acetone (123.7g) was added in two portions and stirred to obtain a clear solution. The solution was stored overnight under a nitrogen atmosphere.
- DBTDL catalyst 3.8 mg dissolved in 3.87 g acetone
- reaction mixture was heated to 40°C and warm water (111 g) added and the emulsion stirred at 400 rpm for 10 min.
- Acetone was removed under vacuum pressure to obtain the final waterborne polyurethane dispersion.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102020126698.7A DE102020126698A1 (de) | 2020-10-12 | 2020-10-12 | Verwendung von kationisch modifizierten Polyurethan-Dispersionen als Textilweichmacher |
Publications (2)
Publication Number | Publication Date |
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EP3981865A2 true EP3981865A2 (fr) | 2022-04-13 |
EP3981865A3 EP3981865A3 (fr) | 2022-04-20 |
Family
ID=78078151
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP21201021.9A Pending EP3981865A3 (fr) | 2020-10-12 | 2021-10-05 | Utilisation de dispersions de polyuréthane modifié par voie cationique en tant qu'assouplissant pour textiles |
Country Status (3)
Country | Link |
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US (1) | US20220112442A1 (fr) |
EP (1) | EP3981865A3 (fr) |
DE (1) | DE102020126698A1 (fr) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1156513A (fr) | 1956-07-24 | 1958-05-19 | Préparation permettant d'éliminer l'électricité statique des fibres textiles de synthèse | |
DE1165574B (de) | 1960-08-08 | 1964-03-19 | Dehydag Gmbh | Verfahren zur Herstellung von als Emulgiermittel fuer Salbengrundlagen dienenden Mischestern |
US3415758A (en) | 1960-03-09 | 1968-12-10 | Ncr Co | Process of forming minute capsules en masse |
US3516941A (en) | 1966-07-25 | 1970-06-23 | Minnesota Mining & Mfg | Microcapsules and process of making |
DE2024051A1 (de) | 1970-05-16 | 1971-12-09 | Henkel & Cie GmbH, 4000 Dusseldorf Holthausen | Kosmetische Zubereitungen, insbesondere kosmetische Reinigungsmittel, mit einem Ge halt an Ruckfettungsmitteln |
EP0026914A1 (fr) | 1979-10-08 | 1981-04-15 | BASF Aktiengesellschaft | Procédé de fabrication de microcapsules, microcapsules obtenues selon ce procédé, utilisation des microcapsules pour la préparation de papiers d'enregistrement sensibles à la pression et système d'enregistrement sensible à la pression |
US6794445B2 (en) | 2002-04-17 | 2004-09-21 | Goldschmidt Ag | Aqueous polysiloxane-polyurethane dispersion, its preparation and use in coating compositions |
WO2016200761A2 (fr) | 2015-06-12 | 2016-12-15 | The Procter & Gamble Company | Compositions de parfum et leurs utilisations |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE572404A (fr) | 1957-10-31 | |||
GB873214A (en) | 1958-08-20 | 1961-07-19 | British Nylon Spinners Ltd | Non-ionic detergent compositions |
DE10215522A1 (de) * | 2002-04-09 | 2003-10-30 | Basf Ag | Kationisch modifizierte anionische Polyurethandispersionen |
US7906476B2 (en) * | 2005-02-11 | 2011-03-15 | Invista North America S.A.R.L. | Fabric care compositions |
GB0512095D0 (en) * | 2005-06-14 | 2005-07-20 | Unilever Plc | Fabric softening composition |
US9994800B2 (en) * | 2015-03-26 | 2018-06-12 | The Procter & Gamble Company | Fabric care compositions comprising organosiloxane polymers with an amine-containing end cap |
-
2020
- 2020-10-12 DE DE102020126698.7A patent/DE102020126698A1/de not_active Withdrawn
-
2021
- 2021-10-05 EP EP21201021.9A patent/EP3981865A3/fr active Pending
- 2021-10-11 US US17/498,009 patent/US20220112442A1/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1156513A (fr) | 1956-07-24 | 1958-05-19 | Préparation permettant d'éliminer l'électricité statique des fibres textiles de synthèse | |
US3415758A (en) | 1960-03-09 | 1968-12-10 | Ncr Co | Process of forming minute capsules en masse |
DE1165574B (de) | 1960-08-08 | 1964-03-19 | Dehydag Gmbh | Verfahren zur Herstellung von als Emulgiermittel fuer Salbengrundlagen dienenden Mischestern |
US3516941A (en) | 1966-07-25 | 1970-06-23 | Minnesota Mining & Mfg | Microcapsules and process of making |
DE2024051A1 (de) | 1970-05-16 | 1971-12-09 | Henkel & Cie GmbH, 4000 Dusseldorf Holthausen | Kosmetische Zubereitungen, insbesondere kosmetische Reinigungsmittel, mit einem Ge halt an Ruckfettungsmitteln |
EP0026914A1 (fr) | 1979-10-08 | 1981-04-15 | BASF Aktiengesellschaft | Procédé de fabrication de microcapsules, microcapsules obtenues selon ce procédé, utilisation des microcapsules pour la préparation de papiers d'enregistrement sensibles à la pression et système d'enregistrement sensible à la pression |
US6794445B2 (en) | 2002-04-17 | 2004-09-21 | Goldschmidt Ag | Aqueous polysiloxane-polyurethane dispersion, its preparation and use in coating compositions |
WO2016200761A2 (fr) | 2015-06-12 | 2016-12-15 | The Procter & Gamble Company | Compositions de parfum et leurs utilisations |
Also Published As
Publication number | Publication date |
---|---|
EP3981865A3 (fr) | 2022-04-20 |
US20220112442A1 (en) | 2022-04-14 |
DE102020126698A1 (de) | 2022-04-14 |
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