EP3946230A1 - Verfahren zur behandlung von keratinmaterial - Google Patents
Verfahren zur behandlung von keratinmaterialInfo
- Publication number
- EP3946230A1 EP3946230A1 EP20707196.0A EP20707196A EP3946230A1 EP 3946230 A1 EP3946230 A1 EP 3946230A1 EP 20707196 A EP20707196 A EP 20707196A EP 3946230 A1 EP3946230 A1 EP 3946230A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- weight
- group
- acid
- stands
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 109
- 239000000463 material Substances 0.000 title claims abstract description 86
- 102000011782 Keratins Human genes 0.000 title claims abstract description 49
- 108010076876 Keratins Proteins 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 332
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 34
- 210000004209 hair Anatomy 0.000 claims abstract description 31
- 239000007859 condensation product Substances 0.000 claims abstract description 27
- -1 fatty acid triglycerides Chemical class 0.000 claims description 88
- 239000000194 fatty acid Substances 0.000 claims description 86
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 84
- 229930195729 fatty acid Natural products 0.000 claims description 84
- 229920000642 polymer Polymers 0.000 claims description 69
- 150000004665 fatty acids Chemical class 0.000 claims description 60
- 239000000049 pigment Substances 0.000 claims description 59
- 238000004040 coloring Methods 0.000 claims description 57
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 55
- 150000001875 compounds Chemical class 0.000 claims description 50
- 150000003254 radicals Chemical class 0.000 claims description 43
- 239000010445 mica Substances 0.000 claims description 41
- 229910052618 mica group Inorganic materials 0.000 claims description 41
- 150000002191 fatty alcohols Chemical class 0.000 claims description 38
- 239000000982 direct dye Substances 0.000 claims description 34
- 150000004706 metal oxides Chemical class 0.000 claims description 32
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 29
- 235000011187 glycerol Nutrition 0.000 claims description 20
- 150000002430 hydrocarbons Chemical class 0.000 claims description 20
- 229920006395 saturated elastomer Polymers 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 229910044991 metal oxide Inorganic materials 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 17
- 125000000129 anionic group Chemical group 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 16
- 238000004806 packaging method and process Methods 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 14
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 12
- 125000002091 cationic group Chemical group 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 239000008406 cosmetic ingredient Substances 0.000 claims description 11
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 10
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 8
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 claims description 7
- 235000012730 carminic acid Nutrition 0.000 claims description 7
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 claims description 7
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 claims description 7
- 239000012860 organic pigment Substances 0.000 claims description 7
- 150000004760 silicates Chemical class 0.000 claims description 7
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 claims description 7
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 6
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 claims description 6
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 6
- FZUOVNMHEAPVBW-UHFFFAOYSA-L quinoline yellow ws Chemical compound [Na+].[Na+].O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S([O-])(=O)=O)C=C(S(=O)(=O)[O-])C=C2C=C1 FZUOVNMHEAPVBW-UHFFFAOYSA-L 0.000 claims description 6
- NDDLLTAIKYHPOD-ISLYRVAYSA-N (2e)-6-chloro-2-(6-chloro-4-methyl-3-oxo-1-benzothiophen-2-ylidene)-4-methyl-1-benzothiophen-3-one Chemical compound S/1C2=CC(Cl)=CC(C)=C2C(=O)C\1=C1/SC(C=C(Cl)C=C2C)=C2C1=O NDDLLTAIKYHPOD-ISLYRVAYSA-N 0.000 claims description 5
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 5
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 claims description 5
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 5
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 claims description 5
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 5
- 229960005323 phenoxyethanol Drugs 0.000 claims description 5
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 claims description 5
- 229910000906 Bronze Inorganic materials 0.000 claims description 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 4
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 4
- 239000010974 bronze Substances 0.000 claims description 4
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 claims description 4
- DGQLVPJVXFOQEV-JNVSTXMASA-N carminic acid Chemical compound OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-JNVSTXMASA-N 0.000 claims description 4
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 4
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 4
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 4
- FHRUGNCCGSEPPE-UHFFFAOYSA-L disodium;2-(4,5-dibromo-3,6-dioxido-9h-xanthen-9-yl)benzoate;hydron Chemical compound [H+].[Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1C2=CC=C([O-])C(Br)=C2OC2=C(Br)C([O-])=CC=C21 FHRUGNCCGSEPPE-UHFFFAOYSA-L 0.000 claims description 4
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001023 inorganic pigment Substances 0.000 claims description 4
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims description 4
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- XLTMWFMRJZDFFD-UHFFFAOYSA-N 1-[(2-chloro-4-nitrophenyl)diazenyl]naphthalen-2-ol Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl XLTMWFMRJZDFFD-UHFFFAOYSA-N 0.000 claims description 3
- TXWSZJSDZKWQAU-UHFFFAOYSA-N 2,9-dimethyl-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione Chemical compound N1C2=CC=C(C)C=C2C(=O)C2=C1C=C(C(=O)C=1C(=CC=C(C=1)C)N1)C1=C2 TXWSZJSDZKWQAU-UHFFFAOYSA-N 0.000 claims description 3
- JFMYRCRXYIIGBB-UHFFFAOYSA-N 2-[(2,4-dichlorophenyl)diazenyl]-n-[4-[4-[[2-[(2,4-dichlorophenyl)diazenyl]-3-oxobutanoyl]amino]-3-methylphenyl]-2-methylphenyl]-3-oxobutanamide Chemical compound C=1C=C(C=2C=C(C)C(NC(=O)C(N=NC=3C(=CC(Cl)=CC=3)Cl)C(C)=O)=CC=2)C=C(C)C=1NC(=O)C(C(=O)C)N=NC1=CC=C(Cl)C=C1Cl JFMYRCRXYIIGBB-UHFFFAOYSA-N 0.000 claims description 3
- QQILFGKZUJYXGS-UHFFFAOYSA-N Indigo dye Chemical compound C1=CC=C2C(=O)C(C3=C(C4=CC=CC=C4N3)O)=NC2=C1 QQILFGKZUJYXGS-UHFFFAOYSA-N 0.000 claims description 3
- KWORKYDIARWARF-UHFFFAOYSA-N N-(4-chloro-2-methylphenyl)-4-[(4-chloro-2-methylphenyl)diazenyl]-3-hydroxynaphthalene-2-carboxamide Chemical compound Cc1cc(Cl)ccc1NC(=O)c1cc2ccccc2c(N=Nc2ccc(Cl)cc2C)c1O KWORKYDIARWARF-UHFFFAOYSA-N 0.000 claims description 3
- LMULDSDQRQVZMW-UHFFFAOYSA-N N-(5-chloro-2,4-dimethoxyphenyl)-4-[[5-(diethylsulfamoyl)-2-methoxyphenyl]diazenyl]-3-hydroxynaphthalene-2-carboxamide Chemical compound CCN(CC)S(=O)(=O)C1=CC=C(OC)C(N=NC=2C3=CC=CC=C3C=C(C=2O)C(=O)NC=2C(=CC(OC)=C(Cl)C=2)OC)=C1 LMULDSDQRQVZMW-UHFFFAOYSA-N 0.000 claims description 3
- 244000062793 Sorghum vulgare Species 0.000 claims description 3
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 claims description 3
- DYYWTFWWAKPJGZ-UHFFFAOYSA-L barium(2+) 4-[(2-hydroxynaphthalen-1-yl)diazenyl]-2-methylbenzenesulfonate Chemical compound [Ba++].Cc1cc(ccc1S([O-])(=O)=O)N=Nc1c(O)ccc2ccccc12.Cc1cc(ccc1S([O-])(=O)=O)N=Nc1c(O)ccc2ccccc12 DYYWTFWWAKPJGZ-UHFFFAOYSA-L 0.000 claims description 3
- 239000001055 blue pigment Substances 0.000 claims description 3
- CYHOWEBNQPOWEI-UHFFFAOYSA-L calcium 3-carboxy-1-phenyldiazenylnaphthalen-2-olate Chemical compound OC=1C(=CC2=CC=CC=C2C1N=NC1=CC=CC=C1)C(=O)[O-].OC=1C(=CC2=CC=CC=C2C1N=NC1=CC=CC=C1)C(=O)[O-].[Ca+2] CYHOWEBNQPOWEI-UHFFFAOYSA-L 0.000 claims description 3
- OVHKKOQGPOYPLY-UHFFFAOYSA-L calcium 3-oxido-4-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalene-2-carboxylate Chemical compound [Ca+2].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC(=C3O)C([O-])=O)=CC=C21 OVHKKOQGPOYPLY-UHFFFAOYSA-L 0.000 claims description 3
- QDORUQCHIMQWMJ-UHFFFAOYSA-J calcium disodium 4-carboxy-5-chloro-2-[(2-oxidonaphthalen-1-yl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].[Ca++].Oc1ccc2ccccc2c1N=Nc1cc(C([O-])=O)c(Cl)cc1S([O-])(=O)=O.Oc1ccc2ccccc2c1N=Nc1cc(C([O-])=O)c(Cl)cc1S([O-])(=O)=O QDORUQCHIMQWMJ-UHFFFAOYSA-J 0.000 claims description 3
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 claims description 3
- ONTQJDKFANPPKK-UHFFFAOYSA-L chembl3185981 Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C=C1N=NC1=CC(S([O-])(=O)=O)=C(C=CC=C2)C2=C1O ONTQJDKFANPPKK-UHFFFAOYSA-L 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 claims description 3
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 claims description 3
- NDEREBNOSVNICA-UHFFFAOYSA-L disodium 4-[(5-chloro-4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound ClC=1C(=CC(=C(C=1)N=NC1=C(C(=CC2=CC=CC=C12)C(=O)[O-])O)S(=O)(=O)[O-])C.[Na+].[Na+] NDEREBNOSVNICA-UHFFFAOYSA-L 0.000 claims description 3
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- ROVRRJSRRSGUOL-UHFFFAOYSA-N victoria blue bo Chemical compound [Cl-].C12=CC=CC=C2C(NCC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)=C1C=CC(=[N+](CC)CC)C=C1 ROVRRJSRRSGUOL-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
Definitions
- composition (A) is a low-water preparation which contains at least one organic Ci-C6-alkoxysilane, and composition (B) contains at least one nonionic surfactant in addition to water.
- a second subject of the present invention is a multi-component packaging unit (kit-of-parts) for coloring keratinous material, which, separately packaged in two packaging units, comprises the two compositions (A) and (B) described above
- Oxidation dyes are usually used for permanent, intense dyeings with good fastness properties and good gray coverage. Such colorants usually contain oxidation dye precursors, so-called developer components and coupler components, which, under the influence of oxidizing agents such as hydrogen peroxide, form the actual dyes with one another. Oxidation dyes are characterized by very long-lasting coloring results.
- color pigments are generally understood to mean insoluble, coloring substances. These are present undissolved in the form of small particles in the coloring formulation and are only deposited on the outside of the hair fibers and / or the skin surface. Therefore, they can usually be removed without residue by a few washes with detergents containing surfactants. Various products of this type are available on the market under the name of hair mascara. If the user wants particularly long-lasting coloring, the use of oxidative coloring agents has so far been his only option. However, despite multiple attempts at optimization, an unpleasant smell of ammonia or amine cannot be completely avoided with oxidative hair coloring. The hair damage still associated with the use of oxidative coloring agents also has an adverse effect on the user's hair.
- EP 2168633 B1 deals with the problem of producing long-lasting hair colorations using pigments.
- the document teaches that when a combination of pigment, organic silicon compound, hydrophobic polymer and a solvent is used, hair colors can be produced which are particularly resistant to shampooing.
- the organic silicon compounds used in EP 2168633 B1 are reactive compounds from the alkoxy-silane class. These alkoxy-silanes hydrolyze in the presence of water at high speed and - depending on the particular amounts of alkoxy-silane and water used - form hydrolysis products and / or condensation products. The influence of the amount of water used in this reaction on the properties of the hydrolysis or condensation product is described, for example, in WO 2013068979 A2.
- a film or also a coating forms on the keratin material, which completely envelops the keratin material and in this way strongly influences the properties of the keratin material.
- Possible areas of application are, for example, permanent styling or the permanent change in shape of keratin fibers.
- the keratin fibers are mechanically brought into the desired shape and then fixed in this shape by forming the above-described coating.
- Another very particularly suitable application is the coloring of keratin material;
- the coating or the film is produced in the presence of a coloring compound, for example a pigment. The film colored by the pigment remains on the keratin material or the keratin fibers and results in surprisingly wash-resistant colorations.
- the great advantage of the alkoxy-silane-based coloring principle is that the high reactivity of this class of compounds enables very fast coating. In this way, extremely good staining results can be achieved after a very short application period of just a few minutes.
- the high reactivity of the alkoxy silanes also has some disadvantages. Due to their high reactivity, the organic alkoxy-silanes cannot be made up together with larger amounts of water, since a large excess of water initiates immediate hydrolysis and subsequent polymerization. The polymerization which takes place when the alkoxy-silanes are stored in an aqueous medium is expressed in a thickening or gelling of the aqueous preparation.
- the alkoxy silanes can react not only with water, but also with other cosmetic ingredients.
- the preparations with alkoxy-silanes therefore preferably contain no further ingredients or only the selected ingredients which have been found to be chemically inert to the alkoxy-silanes.
- the concentration of the alkoxy silanes in the preparation is accordingly preferably chosen to be relatively high.
- the low-water preparations, which contain the alkoxy-silanes in relatively high concentrations, can also be referred to as “silane blends”.
- the user now has to convert this relatively highly concentrated silane blend into a ready-to-use mixture.
- this ready-to-use mixture on the one hand, the concentration of the organic alkoxy-silanes is reduced and, on the other hand, the application mixture also contains a higher proportion of water (or an alternative ingredient), which triggers the polymerization leading to the coating.
- the object of the present application was to find a method for treating keratinic material by means of which the rate of polymerization of the organic alkoxysilanes could be adapted to the conditions of use, in particular to the conditions prevailing when used on the human head.
- a process was sought by which the organic alkoxysilanes remained reactive for so long that a whole-head treatment is made possible without unduly extending the application period.
- the keratin material is treated in a method in which two compositions (A) and (B) are applied to the keratin material.
- the first composition (A) is the low-water silane blend described above.
- the second composition (B) contains water and also contains at least one nonionic surfactant.
- the two compositions (A) and (B) come into contact with one another, this contact being possible either through prior mixing of (A) and (B) or through successive application of (A) and (B) to the keratin material.
- a first object of the present invention is a method for treating keratinic material, in particular human hair, in which the keratinic material is used
- a first composition (A) which - based on the total weight of the composition (A) - contains
- (B2) one or more nonionic surfactants.
- a first object of the present invention is a method for treating keratinic material, in particular human hair, in which the keratinic material is used
- a first composition (A) which - based on the total weight of the composition (A) - contains
- (B2) one or more nonionic surfactants.
- nonionic surfactants (B2) contained in the water-containing composition (B) reduce the rate of polymerization of the organic Ci-C6-alkoxy-silanes (A2) on contact with the composition (A).
- the reactivity of the organic Ci-C6-alkoxy-silanes (A2) could be optimally adapted to the application conditions prevailing in a whole-head hair dyeing process.
- Even more complicated or more time-consuming coloring techniques, such as the coloring of highlights specially arranged on the head could be implemented using the method according to the invention.
- Keratinic material is understood to mean hair, skin, and nails (such as fingernails and / or toenails, for example). Furthermore, wool, furs and feathers also fall under the definition of keratinic material.
- Keratinic material is preferably understood to mean human hair, human skin and human nails, in particular fingernails and toenails. Keratinic material is very particularly preferably understood to mean human hair.
- Agents for treating keratinous material are understood to mean, for example, means for coloring the keratin material, means for reshaping or shaping keratinic material, in particular keratinic fibers, or also means for conditioning or maintaining the keratinic material.
- the agents produced by the process according to the invention are particularly suitable for coloring keratinic material, in particular for coloring keratinic fibers, which are particularly preferably human hair.
- coloring is used in the context of this invention for a coloring of the keratin material, especially the hair, caused by the use of coloring compounds, such as thermochromic and photochromic dyes, pigments, mica, substantive dyes and / or oxidation dyes.
- coloring compounds such as thermochromic and photochromic dyes, pigments, mica, substantive dyes and / or oxidation dyes.
- the aforementioned coloring compounds are deposited in a particularly homogeneous and smooth film on the surface of the keratin material or diffuse into the keratin fiber.
- the film is formed in situ by oligomerization or polymerization of the organic alkoxy silane (s), and through the interaction of the coloring compound and the organic silicon compound and optionally other components, such as a film-forming polymer.
- the method according to the invention is characterized by the use of a first composition (A) on the keratinic material.
- the composition (A) is characterized in that it is low in water, preferably essentially free of water.
- the composition (A) therefore contains less than 10% by weight of water, based on the total weight of the composition (A).
- the compositions (A) are storage-stable over long periods of time.
- the first composition (A) contains - based on the total weight of the composition (A) - preferably 0.01 to 9.5% by weight, more preferably 0.01 to 8.0% by weight, even more preferably 0.01 to 6.0 and very particularly preferably 0.01 to 4.0% by weight of water (A1).
- a method according to the invention is characterized in that the first composition (A) - based on the total weight of the composition (A) - 0.01 to 9.5% by weight, preferably 0.01 to 8 , 0% by weight, more preferably 0.01 to 6.0 and very particularly preferably 0.01 to 4.0% by weight of water (A1).
- composition (A) is characterized in that it contains one or more organic C1-C6-alkoxy-silanes (A2) and / or their condensation products.
- the one or more organic Ci-C6-alkoxy-silanes are organic, non-polymeric silicon compounds, which are preferably selected from the group of silanes with one, two or three silicon atoms
- Organic silicon compounds which are alternatively referred to as organosilicon compounds, are compounds that either have a direct silicon-carbon bond (Si-C) or in which the carbon is attached via an oxygen, nitrogen or sulfur atom the silicon atom is linked.
- the organic silicon compounds according to the invention are preferably compounds which contain one to three silicon atoms.
- the organic silicon compounds particularly preferably contain one or two silicon atoms.
- silane stands for a group of chemical compounds based on a silicon backbone and hydrogen.
- the hydrogen atoms have been completely or partially replaced by organic groups such as, for example, (substituted) alkyl groups and / or alkoxy groups.
- Ci-C6-alkoxy-silanes according to the invention It is characteristic of the Ci-C6-alkoxy-silanes according to the invention that at least one C1-C6-alkoxy group is bonded directly to a silicon atom.
- the Ci-C6-alkoxy-silanes according to the invention thus comprise at least one structural unit R'R "R” 'Si-0- (Ci-C6-alkyl) where the radicals R', R "and R” 'represent the three other bond valences of the Silicon atom.
- the Ci-C6-alkoxy group or groups bonded to the silicon atom are very reactive and are hydrolyzed at high speed in the presence of water, the reaction rate also depending, among other things, on the number of hydrolyzable groups per molecule.
- the organic silicon compound preferably contains a structural unit R’R “R“ ‘Si-0-CH2-CH3.
- the radicals R ‘, R“ and R “‘ again represent the three remaining free valences of the silicon atom.
- a condensation product is understood to mean a product that is formed by the reaction of at least two organic Ci-C6-alkoxy-silanes with elimination of water and / or with elimination of a Ci-C6-alkanol.
- the condensation products can be, for example, dimers, but also trimers or oligomers, the condensation products being in equilibrium with the monomers.
- a method according to the invention is characterized in that the composition (A) contains one or more organic Ci-C6-alkoxy-silanes (A2), which are composed of silanes with one, two or three silicon atoms are selected, wherein the organic silicon compound further comprises one or more basic chemical functions.
- A2 organic Ci-C6-alkoxy-silanes
- This basic group can be, for example, an amino group, an alkylamino group or a dialkylamino group, which is preferably connected to a silicon atom via a linker.
- the basic group is preferably an amino group, a Ci-C6-alkylamino group or a di (Ci-C6) alkylamino group.
- composition (A) contains one or more organic Ci-C6-alkoxy-silanes (A2) which are selected from the group of silanes with one, two or three silicon atoms, and where the Ci-C6-alkoxy-silanes further comprise one or more basic chemical functions.
- Ci-C6-alkoxy-silanes of the formula (S-1) and / or (S-II) were used in the process according to the invention. Since, as already described above, hydrolysis / condensation begins even with traces of moisture, the condensation products of the Ci-C6-alkoxy-silanes of the formula (S-1) and / or (S-II) are also included in this embodiment.
- a method according to the invention is characterized in that the first composition (A) contains one or more organic Ci-C6-alkoxy-silanes (A2) of the formula (S-I) and / or (S-II),
- Ri, R2 independently represent a hydrogen atom or a Ci-C6-alkyl group
- L stands for a linear or branched, divalent Ci-C2o-alkylene group
- R3, R 4 independently represent a Ci-C6-alkyl group
- a stands for an integer from 1 to 3
- R5, R5 ', R5 “, R6, R6' and R6” independently represent a Ci-C6-alkyl group, A, A ', A ", A"' and A “” independently represent a linear or branched, divalent Ci-C2o-alkylene group,
- R7 and Re independently of one another represent a hydrogen atom, a Ci-C6-alkyl group, a hydroxy-Ci-C6-alkyl group, a C2-C6-alkenyl group, an amino-Ci-C6-alkyl group or a grouping of the formula (S- Ill) stand,
- Ci-C6-alkyl group examples are the groups methyl, ethyl, propyl, isopropyl, n-butyl, s-butyl and t-butyl, n-pentyl and n-hexyl.
- Propyl, ethyl and methyl are preferred alkyl radicals.
- Examples of a C2-C6 alkenyl group are vinyl, allyl, but-2-enyl, but-3-enyl and isobutenyl; preferred C2-C6 alkenyl radicals are vinyl and allyl.
- a hydroxy-Ci-C6-alkyl group are a hydroxymethyl, a 2-hydroxyethyl, a 2-hydroxypropyl, a 3-hydroxypropyl, a 4-hydroxybutyl group, a 5-hydroxypentyl and a 6-hydroxyhexyl group ; a 2-hydroxyethyl group is particularly preferred.
- Examples of an amino-Ci-C6-alkyl group are the aminomethyl group, the 2-aminoethyl group and the 3-aminopropyl group. The 2-aminoethyl group is particularly preferred.
- Examples of a linear divalent Ci-C2o-alkylene group are, for example, the methylene group (-CH2-), the ethylene group (-CH2-CH2-), the propylene group (- CH2-CH2-CH2-) and the butylene group (-CH2- CH2-CH2-CH2-).
- the propylene group (-CH2-CH2-CH2-) is particularly preferred.
- divalent alkylene groups can also be branched. Examples of branched, divalent C3-C 2 o -alkylene groups are (-CH2-CH (CH 3 ) -) and (-CH 2 -CH (CH3) -CH 2 -).
- Ri R2N-L-Si OR3) a (R4) b (Sl)
- the radicals Ri and R2 independently of one another represent a hydrogen atom or a C1-C6-alkyl group.
- the radicals Ri and R 2 are very particularly preferably both a hydrogen atom.
- the linker -L- which stands for a linear or branched, divalent Ci-C 2 o-alkylene group.
- the divalent C 1 -C 2 o-alkylene group can alternatively also be referred to as a divalent or divalent C 1 -C 2 o -alkylene group, which means that each group -L- can form two bonds.
- -L- is preferably a linear, divalent Ci-C 2 o-alkylene group. More preferably -L- stands for a linear divalent Ci-C6-alkylene group. -L- is particularly preferably a methylene group (-CH2-), an ethylene group (-CH2-CH2-), a propylene group (-CH2-CH2-CH2-) or a butylene group (-CH 2 -CH 2 -CH 2 - CH 2 -). L very particularly preferably represents a propylene group (-CH2-CH2-CH2-).
- the radicals R3 and R4 independently of one another represent a Ci-C6-alkyl group, particularly preferably R3 and R 4 independently of one another represent a methyl group or an ethyl group.
- a stands for an integer from 1 to 3, and b stands for the integer 3 - a. If a is 3, then b is 0. If a is 2, then b is 1. If a is 1, then b is 2.
- composition (A) at least one organic Ci-C6-alkoxy-silane of formula (Sl) contains, in which the radicals R 3, R 4 are each independently a methyl group or an ethyl group .
- dyeings with the best wash fastness properties could be obtained if the composition (A) contains at least one organic Ci-C6-alkoxy-silane of the formula (S1) in which the radical a stands for the number 3. In this case, the remainder b stands for the number 0.
- composition (A) contains one or more organic Ci-C6-alkoxy-silanes of the formula (S-l),
- R3, R4 independently of one another represent a methyl group or an ethyl group
- composition (A) contains at least one or more organic C1-C6-alkoxy-silanes of the formula (S-1),
- R2 both stand for a hydrogen atom
- - L stands for a linear, divalent Ci-C6-alkylene group, preferably for a propylene group (- CH2-CH2-CH2-) or for an ethylene group (-CH2-CH2-),
- R3 stands for an ethyl group or a methyl group
- R4 stands for a methyl group or for an ethyl group
- a method according to the invention is characterized in that the first composition (A) contains at least one organic C1-C6-alkoxysilane (A2) of the formula (S1) which is selected from the group from
- (3-Aminopropyl) trimethoxysilane can be purchased from Sigma-Aldrich, for example. (3-Aminopropyl) triethoxysilane is also commercially available from Sigma-Aldrich.
- composition (A) can also contain one or more organic Ci-C6-alkoxy-silanes of the formula (S-II),
- organosilicon compounds of the formula (S-II) each have the silicon-containing groups (R50) c (R6) dSi and -Si (R6 ') d' (OR5 ') c at their two ends
- each of the radicals e, f, g and h can independently stand for the number 0 or 1, with the proviso that at least one of the radicals e, f, g and h is different from 0 .
- an organic silicon compound of the formula (II) according to the invention contains at least one grouping from the group consisting of - (A) - and - [NR 7 - (A ') j- and - [0- (A ”) j- and - [NR 8 - (A '”)] -
- the radicals R5, R5', R5 "independently of one another represent a Ci-C6-alkyl group.
- the radicals R6, R6 'and R6 ′′ stand independently of one another for a Ci-C6-alkyl group.
- c stands for an integer from 1 to 3, and d stands for the integer 3 - c. If c is 3, then d is 0. If c is 2, d is 1. If c is 1, then d is 2.
- d‘ stands for the integer 3 - c ‘. If c ‘stands for the number 3, then d‘ equals 0. If c clergy stands for the number 2, then d ‘equals 1. If c ‘stands for the number 1, then d‘ is 2.
- composition (A) contains one or more organic Ci-C6-alkoxy-silanes of the formula (S-II),
- R5 and R5 ‘independently represent a methyl group or an ethyl group
- the organic silicon compounds according to the invention correspond to the formula (S-Ila) (R50) 3Si- (A) e- [NR7- (A ')] f- [0- (A ”)] g- [NR8- (A”')] h-Si (OR5 ') 3 (S- Ila).
- the radicals e, f, g and h can independently represent the number 0 or 1, at least one radical from e, f, g and h being different from zero.
- the abbreviations e, f, g and h therefore define which of the groupings - (A) e - and - [NR7- (A ')] f - and - [0- (A ”)] g - and - [ NR8- (A ”')] h - are located in the central part of the organic silicon compound of the formula (II).
- the radicals A, A ', A “, A”' and A “” stand independently of one another for a linear or branched, divalent Ci-C 2 o-alkylene group.
- the radicals A, A ', A “, A”' and A “” are preferably, independently of one another, a linear, divalent Ci-C 2 o-alkylene group.
- the radicals A, A ', A ", A"' and A "" are more preferably, independently of one another, a linear divalent Ci-C6-alkylene group.
- the divalent Ci-C 2 o -alkylene group can alternatively also be referred to as a divalent or divalent Ci- C 2 o-alkylene group, which means that each grouping A, A ', A “, A“' and A ““ two Can form bonds.
- the radicals A, A ', A “, A”' and A “” are particularly preferably, independently of one another, a methylene group (-CH2-), an ethylene group (-CH2-CH2-), a propylene group (-CH2-CH2-CH2) -) or a butylene group (-CH 2 -CH 2 -CH 2 -CH 2 -).
- the radicals A, A ', A ", A"' and A "" are very particularly preferably a propylene group (-CH2-CH2-CH2-).
- the organic silicon compound of the invention of the formula (II) contains a structural grouping - [NR7- (A ')] -.
- the organic silicon compound of the formula (II) according to the invention contains a structural grouping - [NR8- (A ”')] -.
- the radicals R7 and Rs independently of one another represent a hydrogen atom, a C1-C6-alkyl group, a hydroxy-Ci-C6-alkyl group, a C2-C6-alkenyl group, an amino-Ci-C6-alkyl group or a grouping of the Formula (S-Ill)
- the radicals R7 and R8 are very particularly preferably, independently of one another, a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a grouping of the formula (S-III).
- the organic silicon compound according to the invention contains the grouping [NR7- (A ')], but not the grouping - [NR8- (A ”')] if the radical R7 is a grouping of the formula (III), the organic silicon compound comprises 3 reactive silane groups.
- composition ⁇ ) contains one or more organic Ci-C6-alkoxy-silanes (A2) of the formula (S-II)
- R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a grouping of the formula (S-III).
- composition (A) contains one or more organic Ci-C6-alkoxy-silanes (A2) of the formula (S-II), where
- - A and A ‘independently represent a methylene group (-CH2-), an ethylene group (-CH2-CH2-) or a propylene group (-CH2-CH2-CH2),
- R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a grouping of the formula (S-III).
- organic silicon compounds of the formula (S-II) are commercially available.
- Bis (trimethoxysilylpropyl) amine with the CAS number 82985-35-1 can be purchased from Sigma-Aldrich, for example.
- Bis [3- (triethoxysilyl) propyl] amine with the CAS number 13497-18-2 can be purchased from Sigma-Aldrich, for example.
- N-methyl-3- (trimethoxysilyl) -N- [3- (trimethoxysilyl) propyl] -1-propanamine is alternatively also referred to as bis (3-trimethoxysilylpropyl) -N-methylamine and can be purchased commercially from Sigma-Aldrich or Fluorochem .
- 3- (Triethoxysilyl) -N, N-bis [3- (triethoxysilyl) propyl] -1-propanamine with the CAS number 18784-74-2 can be purchased from Fluorochem or Sigma-Aldrich, for example.
- composition (A) contains one or more organic Ci-C6-alkoxy-silanes of the formula (S-II) which are selected from the group of
- Ci-C6-alkoxy-silane (A2) of the formula (S-IV) was used in the process according to the invention
- the compounds of formula (S-IV) are organic silicon compounds selected from silanes having one, two or three silicon atoms, the organic silicon compound comprising one or more hydrolyzable groups per molecule.
- organic silicon compound or compounds of the formula (S-IV) can also be referred to as silanes of the alkyl-Ci-C6-alkoxy-silane type,
- Rg stands for a Ci-Ci2-alkyl group
- - k stands for an integer from 1 to 3
- - m stands for the integer 3 - k.
- a particularly preferred method according to the invention is characterized in that the first composition (A) contains one or more organic C1-C6-alkoxy-silanes (A2) of the formula (S-IV),
- Rg stands for a Ci-Ci2-alkyl group
- R11 stands for a Ci-C6-alkyl group
- k is an integer from 1 to 3
- Rg stands for a C1-C12-alkyl group. This Ci-Ci2-alkyl group is saturated and can be linear or branched.
- Rg is preferably a linear Ci-Cs-alkyl group.
- Rg preferably stands for a methyl group, an ethyl group, an n-propyl group, an n-butyl group, an n-pentyl group, an n-hexyl group, an n-octyl group or an n-dodecyl group.
- Rg particularly preferably represents a methyl group, an ethyl group or an n-octyl group.
- the radical R10 stands for a Ci-C6-alkyl group.
- R10 particularly preferably represents a methyl group or an ethyl group.
- the radical Rn stands for a C1-C6-alkyl group.
- Rn particularly preferably represents a methyl group or an ethyl group.
- k stands for an integer from 1 to 3, and m stands for the integer 3 - k. If k is the number 3, then m is 0. If k is the number 2, then m is 1. If k is the number 1, then m is 2.
- composition (A) contains at least one organic Ci-C6-alkoxy-silane (A2) of the formula (S-IV) in which the remainder k stands for the number 3. In this case, the remainder m stands for the number 0.
- n-propyltrimethoxysilane also called ans propyltrimethoxysilane
- n-propyltriethoxysilane also known as propyltriethoxysilane
- a method according to the invention is characterized in that the first composition (A) contains at least one organic C1-C6-alkoxysilane (A2) of the formula (S-IV) which is selected from the group of
- hydrolysis or condensation products are, for example, the following compounds:
- the hydrolysis reaction can also take place several times per Ci-C6-alkoxy-silane used:
- the hydrolysis reaction can also take place several times per Ci-C6-alkoxy-silane used:
- condensation to form a dimer is shown in each case, but further condensation to form oligomers with several silane atoms is also possible and also preferred.
- Ci-C6-alkoxysilanes of the formula (S1) which have not yet formed a condensation can take part in these condensation reactions run through reacted, partially or completely hydrolyzed Ci-C6-alkoxysilanes of the formula (S1). In this case, the Ci-C6-alkoxysilanes of the formula (S1) react with themselves.
- Ci-C6-alkoxysilanes of the formula (S1) can also take part in the condensation reactions, which condensation with not yet reacted, partially or completely hydrolyzed Ci-C6-alkoxysilanes of the formula (S-IV) run through.
- the Ci-C6-alkoxysilanes of the formula (S-1) react with the C1-C6-alkoxysilanes of the formula (S-IV).
- Ci-C6-alkoxysilanes of the formula (S-IV) can also take part in the condensation reactions, which condensation with as yet unreacted, partially or completely hydrolyzed Ci-C6-alkoxysilanes of the formula (S- IV) go through. In this case, the Ci-C6-alkoxysilanes of the formula (S-IV) react with themselves.
- composition (A) according to the invention can contain one or more organic Ci-C6-alkoxysilanes (A2) in various proportions.
- the person skilled in the art determines this as a function of the desired thickness of the silane coating on the keratin material and of the amount of the keratin material to be treated.
- composition (A) - based on its total weight - has one or more organic Ci-C6-alkoxysilanes (A2) and / or the condensation products thereof in a total amount of 30, 0 to 85.0% by weight, preferably from 35.0 to 80.0% by weight, more preferably from 40.0 to 75.0% by weight, even more preferably from 45.0 to 70.0 % By weight and very particularly preferably from 50.0 to 65.0% by weight.
- a particularly preferred method is characterized in that the first composition (A) - based on the total weight of the composition (A) - has one or more organic Ci-C6-alkoxysilanes (A2) and / or the condensation products thereof in a total amount from 30.0 to 85.0% by weight, preferably from 35.0 to 80.0% by weight, more preferably from 40.0 to 75.0% by weight, even more preferably from 45, Contains 0 to 70.0% by weight and very particularly preferably from 50.0 to 65.0% by weight.
- composition (A) Further cosmetic ingredients in composition (A)
- the composition (A) can also contain one or more further cosmetic ingredients.
- the cosmetic ingredients which can optionally be used in the composition (A) can be all suitable constituents in order to impart further positive properties to the agent.
- a solvent, a thickening or film-forming polymer, a surface-active compound from the group of nonionic, cationic, anionic or zwitterionic / amphoteric surfactants, the coloring compounds from the group of pigments, the substantive dyes, the oxidation dye precursors can be used in the composition (A) , the fatty components from the group of Cs-Cso fatty alcohols, the hydrocarbon compounds, fatty acid esters, the acids and bases belonging to the group of pH regulators, the perfumes, preservatives, plant extracts and protein hydrolysates.
- the organic Ci-C6-alkoxysilanes (A2) can react not only with water, but also with other cosmetic ingredients.
- the preparations (A) with alkoxy-silanes therefore preferably contain no further ingredients or only the selected ingredients which have been found to be chemically inert to the C1-C6-alkoxy-silanes.
- composition (A) it has proven to be very particularly preferred to use a cosmetic ingredient from the group of hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane and / or decamethylcyclopentasiloxane in composition (A).
- a method according to the invention is characterized in that the first composition (A) contains at least one cosmetic ingredient from the group consisting of hexamethyldisiloxane. Contains octamethyltrisiloxane, decamethyltetrasiloxane, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane.
- Hexamethyldisiloxane has the CAS number 107-46-0 and can be obtained commercially from Sigma-Aldrich, for example.
- Octamethyltrisiloxane has the CAS number 107-51 -7 and is also commercially available from Sigma-Aldrich.
- Decamethyltetrasiloxane has the CAS number 141-62-8 and is also commercially available from Sigma-Aldrich.
- Hexamethylcyclotrisiloxane has the CAS no. 541 -05-9.
- Octamethylcyclotetrasiloxane has the CAS no. 556-67-2.
- Decamethylcyclopentasiloxane has the CAS no. 541-02-6.
- Hexamethyldisiloxane in composition (A) has proven to be very particularly preferred. Hexamethyldisiloxane is particularly preferred - based on the total weight of the composition (A) - in amounts of 10.0 to 50.0% by weight, preferably 15.0 to 45.0% by weight, more preferably 20.0 to 40% , 0% by weight, even more preferably 25.0 to 35.0% by weight and very particularly preferably 31.0 to 34.0% by weight in the composition (A).
- a method according to the invention is characterized in that the first composition (A) - based on the total weight of the composition (A) - 10.0 to 50.0% by weight, preferably 15.0 to 45% , 0% by weight, more preferably 20.0 to 40.0% by weight, even more preferably 25.0 to 35.0% by weight and very particularly preferably 31.0 to 34.0% by weight Contains hexamethyldisiloxane.
- the method according to the invention is characterized by the use of a second composition (B) on the keratinic material, in particular on human hair.
- compositions (A) and (B) When used on the keratinous material, the compositions (A) and (B) come into contact, it being possible for this contact to be established very particularly preferably by previously mixing the two compositions (A) and (B).
- the ready-to-use keratin treatment agent is produced, i. the storage-stable or storable silane blend (A) is converted into its reactive form by contact with (B).
- the compositions (A) and (B) are mixed, a polymerization reaction starting from the alkoxy-silane monomers or alkoxy-silane oligomers starts, which finally leads to the formation of the film or the coating on the keratin material.
- composition (B) contains a great deal of water, the monomeric or oligomeric silane condensates previously present in the low-water composition (A) now polymerize very quickly to give polymers of relatively high or high molecular weight. The high molecular weight silane polymers then form the film on the keratinic material. For this reason, water (B1) is an essential ingredient of the composition (B).
- the rate of polymerization of the organic Ci-C6-alkoxy-silanes (A2) at the time of use can also be determined by the amount of water in the composition (B).
- the rate of polymerization i.e. the speed with which the coating is formed should not be too high either. For this reason, it has been found to be particularly preferred not to choose too high the amount of water in the composition (B).
- composition (B) - based on the total weight of the composition (B) - 5.0 to 90.0% by weight, preferably 15.0 to 85.0% by weight. -%, more preferably 25.0 to 80.0% by weight, even more preferably 35.0 to 75.0% by weight and very particularly preferably 45.0 to 70.0% by weight of water (B1) contains.
- a method according to the invention is characterized in that the second composition (B) - based on the total weight of the composition (B) - 5.0 to 90.0% by weight, preferably 15.0 to 85% , 0% by weight, more preferably 25.0 to 80.0% by weight, even more preferably 35.0 to 75.0% by weight and very particularly preferably 45.0 to 70.0% by weight Contains water (B1).
- Nonionic surfactants in the composition Vol
- composition (B) Another characteristic of the composition (B) is its content of at least one nonionic surfactant (B2).
- At least one nonionic surfactant (B2) optimizes the reaction rate of the organic Ci-C6-alkoxysilanes in such a way that uniform coloring is made possible on the entire head.
- composition (B) Due to its water (B1) and nonionic surfactant (B2) content, the composition (B) is in the form of an emulsion. Without being tied to this theory, it is assumed that the Ci-C6-alkoxy-silanes (A2) are embedded in the micelles or the hydrophobic areas of the emulsion. In this way, the direct environment of the Ci-C6-alkoxy-silanes (A2) is rendered hydrophobic.
- surfactants is understood to mean surface-active substances which form adsorption layers on surfaces and interfaces or can aggregate in volume phases to form micellar colloids or lyotropic mesophases.
- anionic surfactants consisting of a hydrophobic radical and a negatively charged hydrophilic head group
- amphoteric surfactants which have both a negative and a compensating positive charge
- cationic surfactants which have a positively charged hydrophilic group in addition to a hydrophobic radical
- nonionic ones Surfactants which have a hydrophobic residue and furthermore no charges, but rather molecular groups with strong dipole moments which are strongly hydrated in aqueous solution.
- Nonionic surfactants contain, for example, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups as the hydrophilic group. Such connections are for example
- alkyl adducts of 2 to 50 mol ethylene oxide and / or 0 to 5 mol propylene oxide onto linear and branched fatty alcohols having 8 to 30 carbon atoms, onto fatty acids having 8 to 30 carbon atoms and to alkylphenols with 8 to 15 carbon atoms in the alkyl group, such as the types available under the sales names Dehydol ® LS, Dehydol ® LT (Cognis),
- Hydroxy mixed ethers as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide with sorbitan fatty acid esters such as the polysorbates,
- the alkyl and alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably from glucose.
- the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
- alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4 are preferred.
- the alkyl or alkenyl radical R 4 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxo synthesis.
- the alkyl or alkenyl radical R 15 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14 carbon atoms.
- Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and their technical mixtures can be obtained as described above.
- Alkyl oligoglucosides based on hardened C12 / 14 coconut alcohol with a DP of 1 to 3 are preferred.
- R 5 CO-NR 6 - [Z] (Tnio-3) in which R 5 CO stands for an aliphatic acyl radical with 6 to 22 carbon atoms, R 6 stands for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and [Z] for represents a linear or branched polyhydroxyalkyl radical having 3 to 12 carbon atoms and 3 to 10 hydroxyl groups.
- the fatty acid N-alkyl polyhydroxyalkylamides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
- the fatty acid N-alkyl polyhydroxyalkylamides are preferably derived from reducing sugars having 5 or 6 carbon atoms, in particular from glucose.
- the preferred fatty acid N- Alkyl polyhydroxyalkylamides therefore represent fatty acid N-alkylglucamides, as represented by the formula (Tnio-4):
- Glucamides of the formula (Tnio- 4), in which R 8 stands for hydrogen or an alkyl group and R 7 CO for the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palm oleic acid, are preferably used as fatty acid N-alkyl polyhydroxyalkylamides.
- Fatty acid N-alkyl glucamides of the formula (Tnio-4), which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C12 / 14 coconut fatty acid or a corresponding derivative, are particularly preferred.
- the polyhydroxyalkylamides can also be derived from maltose and palatinose.
- nonionic surfactants are fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, mixed ethers or mixed formals, protein hydrolysates (in particular vegetable products based on wheat) and polysorbates.
- alkylene oxide addition products with saturated C 8 -030 fatty alcohols with 2 to 40 moles of ethylene oxide per C8-O30 fatty alcohol have proven particularly suitable.
- a method according to the invention is characterized in that the second composition (B) contains one or more nonionic surfactants (B2) from the group of alkylene oxide addition products with saturated C 2 -C 30 fatty alcohol, each with 2 to 40 mol Contains ethylene oxide per Ci 2 - ⁇ 30 fatty alcohol.
- B2 nonionic surfactants
- C8-O30 fatty alcohols are compounds with a linear or branched, saturated or unsaturated Cs-C3o-alkyl chain, which are substituted with a hydroxyl group.
- Ci 2 - ⁇ 30 fatty alcohols examples include octane-1-ol, dodecane-1-ol (dodecyl alcohol, lauryl alcohol), tetradecane-1-ol (tetradecyl alcohol, myristyl alcohol), hexadecane-1-ol (hexadecyl alcohol, cetyl alcohol , Palmityl alcohol), octadecan-1-ol (octadecyl alcohol, stearyl alcohol), arachyl alcohol (eicosan-1 -ol), heneicosyl alcohol (heneicosan-1 -ol) and / or behenyl alcohol (docosan-1 -ol).
- Preferred linear, unsaturated fatty alcohols are (9Z) -Octadec-9-en-1-ol (oleyl alcohol), (9 £) -Octadec-9-en-1 -ol (elaidyl alcohol), (9Z, 12Z) -Octadeca-9 , 12-dien-1-ol (linoleyl alcohol), (9Z, 12Z, 15Z) -octadeca-9,12,15-trien-1 -ol (linolenoyl alcohol), gadoleyl alcohol ((9Z) -Eicos-9-en-1 - ol), arachidon alcohol ((5Z, 8Z, 1 1 Z, 14Z) -Eicosa-5,8,1 1, 14-tetraen-1 -ol), erucyl alcohol ((13Z) -Docos- 13-en-1 - ol) and / or brassidyl alcohol ((13E) -Docosen-1
- branched fatty alcohols are 2,6,8-trimethyl-nonan-4-ol, 2-octyl-dodecanol, 2-hexyl-dodecanol and / or 2-butyl-dodecanol.
- Ra represents a saturated or unsaturated, straight or branched C12-C30-alkyl group
- n is an integer from 2 to 40, preferably an integer from 2 to 20 and particularly preferably an integer from 2 to 5.
- a method according to the invention is characterized in that the second composition (B) contains at least one nonionic surfactant of the formula (T-1),
- Ra represents a saturated or unsaturated, straight or branched C12-C30-alkyl group
- n is an integer from 2 to 40.
- the radical Ra can stand for a saturated or unsaturated, unbranched or branched Cs-Cso-alkyl group.
- the radical Ra very particularly preferably stands for a saturated, branched Cs-Cso-alkyl group.
- a method according to the invention is characterized in that the second composition (B) contains at least one nonionic surfactant of the formula (T-1), where the radical Ra stands for a saturated, branched Cs- Cso-alkyl group.
- the remainder Ra can stand for
- the radical n can stand for an integer from 2 to 10.
- N particularly preferably stands for an integer from 2 to 20, even more preferably from 2 to 12, explicitly very particularly preferably from 2 to 6.
- a method according to the invention is characterized in that the second composition (B) contains at least one nonionic surfactant of the formula (T1), where the radical n is an integer from 2 to 20, preferably from 2 to 12 , explicitly very particularly preferably from 2 to 6.
- a particularly suitable nonionic surfactant (B2) of this type is, for example, a- [3,5-dimethyl-1 - (2-methylpropyl) hexyl] -w-hydroxy-poly (oxy-1, 2-ethanediyl), which under the Trade names Polyethylene glycol trimethylnonyl ether; Polyoxyethylene 2,6,8-trimethyl-4-nonyl ether; Polyoxyethylene trimethyl nonyl ether; Surfactant WK; TMN 10; TMN 3; TMN 6; TX 3; TX 3 (polyoxyalkylenes); TX 6; Tergitol 100; Tergitol TMN; Tergitol TMN 10; Tergitol, TMN 100X; Tergitol TMN 3; Tergitol TMN 6 or trimethylnonanol polyethylene glycol can be purchased commercially.
- the CAS number of this surfactant is 60828-78-6.
- a possible supplier is the Dow company.
- the degree of ethoxylation is 3 and the INCI name is lsolaureth-3.
- the second composition (B) - based on the total weight of the composition (B) - has one or more nonionic surfactants (B2) in a total amount of 0.5 to 20.0% by weight, preferably of 1.0 to 10.0% by weight, more preferably from 1.5 to 8.0% by weight and very particularly preferably from 2.0 to 7.0% by weight.
- a method according to the invention is characterized in that the second composition (B) - based on the total weight of the composition (B) - has one or more nonionic surfactants (B2) in a total amount of 0.5 to 20 , 0% by weight, preferably from 1.0 to 10.0% by weight, more preferably from 1.5 to 8.0% by weight and very particularly preferably from 2.0 to 7.0% by weight % contains.
- composition (B) can optionally also contain one or more further hydrophobic constituents or fat constituents.
- the fat components are also hydrophobic substances which, in the presence of water, can form emulsions with the formation of micelle systems.
- the Ci-C6-alkoxysilanes - either in the form of their monomers or optionally in the form of their condensed oligomers - are embedded in this hydrophobic environment or in the micelle systems, so that changed the polarity of their environment. Due to the hydrophobic character of the fat constituents, the surroundings of the Ci-C6-alkoxysilanes are also hydrophobized. It is assumed that the polymerization reaction of the Ci-C6-alkoxysilanes leading to the film or coating takes place in an environment of reduced polarity at a reduced rate.
- the fat constituents contained in the composition (B) are very particularly preferably selected from the group of the C 2 -C 30 fatty alcohols, the C 2 -C 30 fatty acid triglycerides, the C 12 -C 30 fatty acid monoglycerides, the C 2 -C 30 fatty acid diglycerides and / or of hydrocarbons.
- a method according to the invention is characterized in that the second composition (B) has one or more fat components from the group of the Ci 2 -C30 fatty alcohols, the Ci 2 -C3o fatty acid triglycerides, the Ci2- C30 fatty acid monoglycerides containing Ci 2 -C3o fatty acid diglycerides and / or the hydrocarbons.
- Particularly preferred fat constituents in this context are understood to be the constituents from the group of the C 2 -C 30 fatty alcohols, the C 2 -C 30 fatty acid triglycerides, the C 12 -C 30 fatty acid monoglycerides, the C 2 -C 30 fatty acid diglycerides and / or the hydrocarbons .
- nonionic substances are explicitly considered as fat components.
- Charged compounds such as fatty acids and their salts are not understood as a fat component.
- the Ci 2 -C30 fatty alcohols can be saturated, mono- or polyunsaturated, linear or branched fatty alcohols with 12 to 30 carbon atoms.
- Ci 2 -C30 fatty alcohols examples include dodecan-1 -ol (dodecyl alcohol, lauryl alcohol), tetradecan-1 -ol (tetradecyl alcohol, myristyl alcohol), hexadecan-1-ol (hexadecyl alcohol, cetyl alcohol, palmityl alcohol), Octadecan-1 -ol (octadecyl alcohol, stearyl alcohol), arachyl alcohol (eicosan-1-ol), heneicosyl alcohol (heneicosan-1 -ol) and / or behenyl alcohol (docosan-1-ol).
- dodecan-1 -ol dodecyl alcohol, lauryl alcohol
- tetradecan-1 -ol tetradecyl alcohol, myristyl alcohol
- hexadecan-1-ol hexadecyl alcohol, cetyl alcohol, palmityl alcohol
- Preferred linear, unsaturated fatty alcohols are (9Z) -Octadec-9-en-1-ol (oleyl alcohol), (9 £) -Octadec-9-en-1 -ol (elaidyl alcohol), (9Z, 12Z) -Octadeca-9 , 12-dien-1-ol (linoleyl alcohol), (9Z, 12Z, 15Z) -octadeca-9,12,15-trien-1 -ol (linolenoyl alcohol), gadoleyl alcohol ((9Z) -Eicos-9-en-1 - ol), arachidon alcohol ((5Z, 8Z, 1 1 Z, 14Z) -Eicosa-5,8,1 1, 14-tetraen-1 -ol), erucyl alcohol ((13Z) -Docos- 13-en-1 - ol) and / or brassidyl alcohol ((13E) -Docosen-1
- the preferred representatives of branched fatty alcohols are 2-octyl-dodecanol, 2-hexyl-dodecanol and / or 2-butyl-dodecanol.
- the polarity of the composition (B) can be optimally adjusted and the rate of polymerization of the Ci-C6-alkoxysilanes can be adapted particularly well to the particular application conditions selected.
- Ci 2 -C 30 fatty alcohol in the composition (B) creates an emulsion system in which the alkoxysilanes (A2) can be embedded particularly well.
- the second composition (B) contains one or more Ci 2 -C30 fatty alcohols from the group of dodecan-1-ol (dodecyl alcohol, lauryl alcohol), tetradecan-1-ol (tetradecyl alcohol, Myristyl alcohol), Hexadecan-1-ol (hexadecyl alcohol, cetyl alcohol, palmityl alcohol), octadecan-1-ol
- a method according to the invention is characterized in that the second composition (B) comprises one or more C12-C30 fatty alcohols from the group
- Dodecan-1-ol (dodecyl alcohol, lauryl alcohol),
- Tetradecan-1-ol tetradecyl alcohol, myristyl alcohol
- Hexadecan-1-ol hexadecyl alcohol, cetyl alcohol, palmityl alcohol
- Octadecan-1-ol octadecyl alcohol, stearyl alcohol
- Arachyl alcohol eicosan-1-ol
- Gadoleyl alcohol ((9Z) -Eicos-9-en-1-ol)
- Arachidonic alcohol ((5Z, 8Z, 11 Z, 14Z) -Eicosa-5,8,11, 14-tetraen-1-ol),
- the second composition (B) - based on the total weight of the composition (B) - one or more C 2 -C 30 fatty alcohols in a total amount of 2.0 to 50.0% by weight, preferred from 4.0 to 40.0 wt%, more preferably from 6.0 to 30.0% by weight, even more preferably from 8.0 to 20.0% by weight and very particularly preferably from 10.0 to 15.0% by weight.
- a method according to the invention is characterized in that the second composition (B) - based on the total weight of the composition (B) - one or more Ci 2 -C30 fatty alcohols in a total amount of 2.0 to 50.0% by weight, preferably from 4.0 to 40.0% by weight, more preferably from 6.0 to 30.0% by weight, even more preferably from 8.0 to 20.0% by weight. -% and very particularly preferably from 10.0 to 15.0% by weight.
- the composition (B) can also contain at least one C 2 -C 30 fatty acid triglyceride, the C 2 -C 30 fatty acid monoglyceride and / or C12-C30 fatty acid diglyceride.
- a Ci 2 -C 30 fatty acid triglyceride is understood to mean the triester of the trihydric alcohol glycerol with three equivalents of fatty acid. Both structurally identical and different fatty acids within a triglyceride molecule can be involved in the ester formation.
- fatty acids are saturated or unsaturated, unbranched or branched, unsubstituted or substituted C 2 -C 3 carboxylic acids.
- Unsaturated fatty acids can be monounsaturated or polyunsaturated. In the case of an unsaturated fatty acid, its CC double bond (s) can have the cis or trans configuration.
- the fatty acid triglycerides are characterized by their particular suitability, in which at least one of the ester groups is formed starting from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (Stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid] , Elaidic acid [(9E) - octadec-9-enoic acid], erucic acid [(13
- the fatty acid triglycerides can also be of natural origin.
- the fatty acid triglycerides or mixtures thereof occurring in soybean oil, peanut oil, olive oil, sunflower oil, macadamia nut oil, moringa oil, apricot kernel oil, marula oil and / or optionally hydrogenated castor oil are particularly suitable for use in the product according to the invention.
- a Ci 2 -C30 fatty acid monoglyceride is understood to mean the monoester of the trihydric alcohol glycerol with one equivalent of fatty acid. Either the middle hydroxyl group of the glycerol or the terminal hydroxyl group of the glycerol can be esterified with the fatty acid.
- the Ci 2 -C30 fatty acid monoglyceride are particularly suitable, in which a hydroxyl group of the glycerine is esterified with a fatty acid, the fatty acids being selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid ( Lignoceric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6- octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec- 9-enoic acid], elaidic acid [(9E) -octadec-9-enoic acid],
- Ci 2 -C 30 fatty acid diglyceride is understood to mean the diester of the trihydric alcohol glycerol with two equivalents of fatty acid. Either the middle and one terminal hydroxyl group of the glycerol can be esterified with two equivalents of fatty acid, or both terminal hydroxyl groups of the glycerol are esterified with one fatty acid each.
- the glycerine can be esterified with two structurally identical as well as with two different fatty acids.
- the fatty acid diglycerides are characterized by their particular suitability, in which at least one of the ester groups is formed from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (Stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid] , Elaidic acid [(9E) - octadec-9-enoic acid], erucic acid [(13Z)
- composition (B) contained at least one Ci 2 -C30 fatty acid monoglyceride, which is selected from the monoesters of glycerol with one equivalent of fatty acid from the group of dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (Palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [9-enoic acid] (9Z) - Octadec-9-enoic acid], elaidic acid [(9E) -octadec-9-
- a method according to the invention is characterized in that the second composition (B) contains at least one C12-C30 fatty acid monoglyceride which is selected from the monoesters of glycerol with one equivalent of fatty acid from the group consisting of dodecanoic acid, tetradecanoic acid, Hexadecanoic acid, tetracosanoic acid, octadecanoic acid, eicosanoic acid and / or docosanoic acid.
- the second composition (B) contains at least one C12-C30 fatty acid monoglyceride which is selected from the monoesters of glycerol with one equivalent of fatty acid from the group consisting of dodecanoic acid, tetradecanoic acid, Hexadecanoic acid, tetracosanoic acid, octadecanoic acid, eicosanoic acid and / or docosanoic acid.
- the speed of the film formation starting from the Ci-C6-alkoxy-silanes can also be determined to a particularly large extent by choosing the appropriate amounts of Ci 2 -C30 fatty acid mono-, Ci 2 -C3o fatty acid and / or Ci 2 -C3o fatty acid triglycerides . For this reason, it has proven to be particularly preferred to use one or more Ci 2 -C30 fatty acid mono-, C12-C30 fatty acid di- and / or Ci 2 -C30 fatty acid triglycerides in very specific quantity ranges in the composition (B).
- the second composition (B) - based on the total weight of the composition (B) - has one or more Ci 2 -C30 fatty acid mono-, Ci 2 -C3o -Fatty acid di- and / or Ci 2 -C3o-fatty acid triglycerides in a total amount of 0.1 to 20.0% by weight, preferably 0.3 to 15.0% by weight, more preferably 0.5 to 10.0 % By weight and very particularly preferably from 0.8 to 5.0% by weight.
- a method according to the invention is characterized in that the second composition (B) - based on the total weight of the composition (B) - one or more Ci 2 -C30 fatty acid mono-, C12-C30 fatty acid and / or Ci 2 -C3o fatty acid triglycerides in a total amount of 0.1 to 20.0% by weight, preferably 0.3 to 15.0% by weight, more preferably 0.5 to 10.0% by weight and very particularly preferably from 0.8 to 5.0% by weight.
- the Ci 2 -C30 fatty acid mono-, Ci 2 -C3o fatty acid di- and / or Ci 2 -C3o fatty acid triglycerides can be used as sole fat constituents in the compositions (B). However, it is particularly preferred to incorporate at least one Ci 2 -C30 fatty acid mono-, Ci 2 -C3o fatty acid and / or C12 -C30 fatty acid triglyceride in combination with at least one Ci 2 -C30 fatty alcohol in the composition (B) .
- Composition (B) can also contain at least one hydrocarbon as a very particularly preferred fat component.
- Hydrocarbons are compounds with 8 to 80 C atoms that consist exclusively of carbon and hydrogen.
- aliphatic hydrocarbons such as mineral oils, liquid paraffin oils (e.g. Paraffinium Liquidum or Paraffinum Perliquidum), isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), petrolatum and polydecene are particularly preferred.
- Paraffinum Liquidum and Paraffinium Perliquidum have proven to be particularly suitable in this context.
- the hydrocarbon is very particularly preferably Paraffinum Liquidum, also called white oil.
- Paraffinum Liquidum is a mixture of purified, saturated, aliphatic hydrocarbons, which mostly consists of hydrocarbon chains with a carbon chain distribution of 25 to 35 carbon atoms.
- composition (B) contained at least one hydrocarbon selected from the group of mineral oils, liquid paraffin oils, isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), petrolatum and polydecene.
- hydrocarbon selected from the group of mineral oils, liquid paraffin oils, isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), petrolatum and polydecene.
- a method according to the invention is characterized in that the second composition (B) contains at least one fat component from the group of hydrocarbons.
- the rate of film formation starting from the Ci-C6-alkoxy-silanes can also be determined to a particularly large extent by choosing the suitable amounts of hydrocarbons used. For this reason it has proven to be very particularly preferred to use one or more hydrocarbons in very specific quantity ranges in the composition (B).
- the second composition (B) - based on the total weight of the composition (B) - has one or more hydrocarbons in a total amount of 0.5 to 20.0 % By weight, preferably from 1.0 to 15.0% by weight, more preferably from 1.5 to 10.0% by weight and very particularly preferably from 2.0 to 8.0% by weight.
- a method according to the invention is characterized in that the second composition (B) - based on the Total weight of the composition (B) - one or more hydrocarbons in a total amount of 0.5 to 20.0% by weight, preferably 1.0 to 15.0% by weight, more preferably from 1.5 to 10.0 % By weight and very particularly preferably from 2.0 to 8.0% by weight.
- the hydrocarbon or hydrocarbons can be used as the sole fat constituent in the compositions (B). However, it is very particularly preferred to incorporate at least one hydrocarbon in combination with at least one further constituent in the compositions (B).
- Composition (B) very particularly preferably contains at least one fat component from the group of C 2 -C 30 fatty alcohols and at least one further fat component from the group of hydrocarbons.
- Protic solvents have at least one hydroxyl group. Without being tied to this theory, it is assumed that the solvents can also react with the C 1 -C 6 alkoxysilanes via their hydroxyl group (s), but the reaction between the solvent and the C 1 -C 6 alkoxysilanes is slower than the analogous reaction between water and C1-C6 alkoxysilanes. In total, the hydrolysis and / or the condensation reaction of the Ci-C6-alkoxysilanes is reduced in this way.
- Suitable solvents are, for example, 1,2-propylene glycol, 1,3-propylene glycol, ethylene glycol, 1,2-butylene glycol, dipropylene glycol, ethanol, isopropanol, diethylene glycol monoethyl ether, glycerol, phenoxyethanol and / or benzyl alcohol.
- a method according to the invention is characterized in that the second composition (B) has at least one solvent from the group consisting of 1,2-propylene glycol, 1,3-propylene glycol, ethylene glycol, 1,2-butylene glycol, dipropylene glycol, Contains ethanol, isopropanol, diethylene glycol monoethyl ether, glycerine, phenoxyethanol and / or benzyl alcohol.
- compositions (B) which contain 1,2-propylene glycol as solvent are very particularly preferred.
- 1,2-Propylene glycol is alternatively referred to as 1,2-propanediol and has the CAS numbers 57-55-6 [(RS) -1, 2-dihydroxypropane], 4254-14-2 [(R) -1, 2 -Dihydroxypropane] and 4254-15- 3 [(S) -1, 2-dihydroxypropane]
- Ethylene glycol is alternatively also known as 1,2-ethanediol and has the CAS number 107-21-1.
- Glycerine is alternatively also known as 1, 2,3-Propanetriol designates and bears the CAS number 56-81-5. Phenoxyethanol has the Cas number 122-99-6.
- the rate of the film formation starting from the Ci-C6-alkoxy-silanes can be determined particularly strongly. For this reason it has proven to be very particularly preferred to use one or more solvents in very specific quantity ranges.
- the second composition (B) - based on the total weight of the composition (B) - has one or more solvents in a total amount of from 1.0 to 35.0% by weight, preferably from 4.0 to 25.0% by weight, more preferably from 8.0 to 20.0% by weight, and very particularly preferably from 10.0 to 15.0% by weight.
- the second composition (B) - based on the total weight of the composition (B) - one or more solvents from the group
- composition (B) can also contain one or more further cosmetic ingredients.
- the cosmetic ingredients that can optionally be used in the composition (B) can be all suitable constituents in order to impart further positive properties to the agent.
- a solvent, a thickening or film-forming polymer, a surface-active compound from the group of nonionic, cationic, anionic or zwitterionic / amphoteric surfactants, the coloring compounds from the group of pigments, the substantive dyes, the oxidation dye precursors can be used in the composition (A) , the fatty components from the group of Cs-Cso fatty alcohols, the hydrocarbon compounds, fatty acid esters, the acids belonging to the group of pH regulators and bases contained in perfumes, preservatives, plant extracts and protein hydrolysates.
- the composition (B) can very particularly preferably contain at least one coloring compound from the group of pigments and / or substantive dyes.
- compositions (A) and / or (B) can have an influence on the previously described hydrolysis or condensation reactions occurring during use. It was found here that alkaline pH values in particular stop condensation at the oligomer stage. The more acidic the reaction mixture, the stronger the condensation appears to be and the higher the molecular weight of the silane condensates formed during the condensation. For this reason, it is preferred that the compositions (A) and / or (B) have a pH of from 7.0 to 12.0, preferably from 7.5 to 11.5, more preferably from 8.5 to 1 1, 0 and very particularly preferably from 9.0 to 1 1, 0 have.
- the water content of the composition (A) is a maximum of 10.0% by weight and is preferably set even lower.
- the water content of the composition (B) can also be selected to be low.
- the measurement of the pH value with the usual methods known from the prior art can prove difficult.
- the pH values according to the invention are those values which were obtained after mixing or diluting the preparation in a weight ratio of 1: 1 with distilled water.
- the corresponding pH value is measured accordingly after, for example, 50 g of the composition according to the invention have been mixed with 50 g of distilled water.
- a method according to the invention is characterized in that the composition (A) and / or (B) according to the Dilution with distilled water in a weight ratio of 1: 1 has a pH of 7.0 to 11.5, more preferably 8.5 to 11.0 and very particularly preferably 9.0 to 11.0.
- the pH values in the context of the present invention are pH values that were measured at a temperature of 22 ° C.
- Ammonia, alkanolamines and / or basic amino acids can be used as alkalizing agents.
- Alkanolamines can be selected from primary amines with a C2-C6-alkyl parent structure which carries at least one hydroxyl group.
- Preferred alkanolamines are selected from the group which is formed from 2-aminoethan-1 -ol (monoethanolamine), 3-aminopropan-1 -ol, 4-aminobutan-1 -ol, 5-aminopentan-1 -ol, 1-aminopropane -2-ol, 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol, 3-amino-2-methylpropan-1-ol, 1 -Amino-2-methyl-propan-2-ol, 3-aminopropan-1, 2-diol, 2-amino-2-methylpropan-1, 3-diol.
- amino acid in the context of the invention is an organic compound which in its structure contains at least one amino group which can be protonated and at least one —COOH or one —SOsH group.
- Preferred amino acids are aminocarboxylic acids, in particular ⁇ - (alpha) -amino carboxylic acids and w-aminocarboxylic acids, ⁇ -aminocarboxylic acids being particularly preferred.
- basic amino acids are to be understood as meaning those amino acids which have an isoelectric point p1 of greater than 7.0.
- Basic ⁇ -aminocarboxylic acids contain at least one asymmetric carbon atom.
- both possible enantiomers can be used equally as specific compounds or mixtures thereof, in particular as racemates.
- the basic amino acids are preferably selected from the group that is formed from arginine, lysine, ornithine and histidine, particularly preferably from arginine and lysine.
- an agent according to the invention is therefore characterized in that the alkalizing agent is a basic amino acid from the group arginine, lysine, ornithine and / or histidine.
- Inorganic alkalizing agents can also be used.
- Inorganic alkalizing agents which can be used according to the invention are preferably selected from the group formed by sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide, sodium phosphate, potassium phosphate, sodium silicate, sodium metasilicate, potassium silicate, sodium carbonate and potassium carbonate.
- Very particularly preferred alkalizing agents are ammonia, 2-aminoethan-1-ol (monoethanolamine), 3-aminopropan-1-ol, 4-aminobutan-1 -ol, 5-aminopentan-1 -ol, 1-aminopropan-2-ol, 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol, 3-amino-2-methylpropan-1-ol, 1-amino-2- methylpropan-2-ol, 3-aminopropan-1, 2-diol, 2-amino-2-methylpropan-1, 3-diol, arginine, lysine, ornithine, histidine, sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide, sodium phosphate, potassium phosphate, Sodium silicate, sodium metasilicate, potassium silicate, sodium carbonate and potassium carbonate.
- Acidifying agents preferred according to the invention are pleasure acids, such as citric acid, acetic acid, malic acid or tartaric acid, and also dilute mineral acids.
- the method according to the invention comprises the application of the two compositions (A) and (B) to the keratinic material. It is essential for the method that the compositions (A) and (B) come into contact with one another on the keratinic material. As already described, this contact can be created either by mixing (A) and (B) beforehand or by applying (A) and (B) successively to the keratin material.
- composition (B) containing water (B1) and nonionic surfactants (B2) can in particular have an optimal influence on the low-water silane blend (ie on the composition (A)) when the Compositions (A) and (B) were mixed together before use.
- This mixing can be done, for example, by stirring or spilling. It is particularly advantageous to pack the two compositions (A) and (B) separately in two containers, and then transfer the entire amount of the composition (A) from its container to the container in which the second container is located before use Composition (B) is located.
- a method according to the invention is characterized in that a composition is applied to the keratinic material is applied, which was prepared immediately before use by mixing the first composition (A) and the second composition (B).
- compositions (A) and (B) can be mixed with one another in different proportions.
- the composition (A) is particularly preferably used in the form of a relatively highly concentrated, low-water silane blend which is quasi diluted by mixing with the composition (B). For this reason, it is particularly preferred to mix the composition (A) with an excess weight of the composition (B). For example, 1 part by weight (A) can be mixed with 20 parts by weight (B), or 1 part by weight (A) is mixed with 10 parts by weight (B), or 1 part by weight (A) is mixed with 5 parts by weight (B).
- a method according to the invention is characterized in that a composition is applied to the keratinic material which, immediately before use, is obtained by mixing the first composition (A) and the second composition (B) in a quantity ratio (A) / (B) from 1: 5 to 1:20.
- composition (A) in a weight excess in relation to the composition (B).
- 20 parts by weight (A) can be mixed with 1 part by weight (B), or 10 parts by weight (A) are mixed with 1 part by weight (B), or 5 parts by weight (A) are mixed with 1 part by weight (B).
- compositions (A) and (B) successively to the keratin material, so that the contact of (A) and (B) does not come about until the keratin material.
- the two compositions (A) and (B) can be used on the keratinic material.
- the third composition (C) can be, for example, a composition which contains at least one coloring compound from the group of pigments and / or substantive dyes.
- a method according to the invention in which the keratin material is applied is particularly preferred
- At least one coloring compound from the group of pigments and / or substantive dyes is selected from the group of pigments and / or substantive dyes.
- compositions (A), (B) and (C) it is particularly preferred to produce a mixture of the three compositions (A), (B) and (C) before use and then to apply this mixture to the keratin material.
- a method according to the invention is characterized in that a composition is applied to the keratinic material which, immediately before use, is produced by mixing the first composition (A) with the second composition (B) and a third composition (C ) was obtained,
- the third composition (C) contains at least one coloring compound from the group of pigments and / or substantive dyes.
- coloring the keratin material it can also be particularly preferred to produce a mixture immediately before use by mixing the first composition (A) and the second composition (B) and to apply this mixture of (A) and (B) to the keratin material.
- the third composition (C) with the coloring compounds can then subsequently be applied to the keratin material.
- a method according to the invention is characterized in that a composition is applied to the keratinic material which was obtained immediately before use by mixing the first composition (A) with the second composition (B) and subsequently thereafter the composition (C) is applied to the keratinous material.
- a particularly preferred method according to the invention is characterized in that, in a first step, a composition is applied to the keratinic material which was prepared immediately before use by mixing the first composition (A) and the second composition (B), and in a second step the third composition (C) is applied to the keratin material.
- compositions (A) and (B) - or (A), (B) and (C) - a fourth composition (D) can also be applied to the keratin material in the method according to the invention.
- the fourth composition (D) is particularly preferably used in a dyeing process in order to seal the previously obtained dyeings again.
- the composition (D) can contain, for example, at least one film-forming polymer.
- composition (D) which contains
- compositions (A) and (B) - or additionally optionally (C) and / or (D) - in a dyeing process one or more coloring compounds can be used.
- preparation (B) and / or preparation (C) which is optionally used can additionally contain at least one coloring compound.
- the coloring compound or compounds can preferably be selected from the pigments, the substantive dyes, the oxidation dyes, the photochromic dyes and the thermochromic dyes, particularly preferably from pigments and / or substantive dyes.
- Pigments in the context of the present invention are understood to mean coloring compounds which at 25 ° C. in water have a solubility of less than 0.5 g / L, preferably less than 0.1 g / L, even more preferably less than 0, 05 g / L.
- the water solubility can be achieved, for example, using the method described below: Weigh out 0.5 g of the pigment in a beaker. A stir fry is added. Then one liter of distilled water is added. This mixture is heated to 25 ° C. for one hour while stirring on a magnetic stirrer. If undissolved constituents of the pigment are still visible in the mixture after this period, the solubility of the pigment is below 0.5 g / L.
- the mixture is filtered. If a proportion of undissolved pigments remains on the filter paper, the solubility of the pigment is below 0.5 g / L.
- Suitable color pigments can be of inorganic and / or organic origin.
- an agent according to the invention is characterized in that it contains at least one color-imparting compound from the group of inorganic and / or organic pigments.
- Preferred color pigments are selected from synthetic or natural inorganic pigments.
- Inorganic color pigments of natural origin can be made from chalk, ocher, umber, green earth, burnt Terra di Siena or graphite, for example.
- black pigments such as B. iron oxide black, colored pigments such.
- B. ultramarine or iron oxide red and fluorescent or phosphorescent pigments can be used.
- Colored metal oxides, hydroxides and oxide hydrates, mixed-phase pigments, sulfur-containing silicates, silicates, metal sulfides, complex metal cyanides, metal sulfates, metal chromates and / or molybdates are particularly suitable.
- Particularly preferred color pigments are black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI77289 ), Iron blue (Ferric Ferrocyanide, CI77510) and / or carmine (Cochineal).
- Coloring compounds from the group of pigments which are likewise particularly preferred according to the invention are colored pearlescent pigments. These are usually based on mica and / or mica and can be coated with one or more metal oxides. Mica is one of the layered silicates. The most important representatives of these silicates are muscovite, phlogopite, paragonite, biotite, lepidolite and margarite. To produce the pearlescent pigments in conjunction with metal oxides, the mica, predominantly muscovite or phlogopite, is coated with a metal oxide.
- a method according to the invention is characterized in that the composition (B) and / or the composition (C) contains at least one coloring compound from the group of inorganic pigments, which is selected from the group of colored metal oxides, Metal hydroxides, metal oxide hydrates, silicates, metal sulfides, complex metal cyanides, metal sulfates, Bronze pigments and / or of colored pigments based on mica or mica, which are coated with at least one metal oxide and / or a metal oxychloride.
- the group of inorganic pigments which is selected from the group of colored metal oxides, Metal hydroxides, metal oxide hydrates, silicates, metal sulfides, complex metal cyanides, metal sulfates, Bronze pigments and / or of colored pigments based on mica or mica, which are coated with at least one metal oxide and / or a metal oxychloride.
- synthetic mica coated with one or more metal oxide (s) can also be used as a pearlescent pigment.
- Particularly preferred pearlescent pigments are based on natural or synthetic mica (mica) and are coated with one or more of the aforementioned metal oxides. The color of the respective pigments can be varied by varying the layer thickness of the metal oxide (s).
- the composition (B) and / or the composition (C) according to the invention is characterized in that it contains at least one coloring compound from the group of pigments, which is selected from the group of colored metal oxides, metal hydroxides, metal oxide hydrates, Silicates, metal sulfides, complex metal cyanides, metal sulfates, bronze pigments and / or from coloring compounds based on mica or mica coated with at least one metal oxide and / or one metal oxychloride.
- a composition (B) and / or composition (C) according to the invention is characterized in that it contains at least one coloring compound which is selected from mica- or mica-based pigments which are mixed with one or more metal oxides from the group made of titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and / or brown iron oxide (CI 77491, CI 77499), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI 77289), chromium oxide (CI 77288) and / or iron blue (Ferric Ferrocyanide, CI 77510) are coated.
- at least one coloring compound which is selected from mica- or mica-based pigments which are mixed with one or more metal oxides from the group made of titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and
- color pigments are commercially available under the trade names Rona®, Colorona®, Xirona®, Dichrona® and Timiron® from Merck, Ariabel® and Unipure® from Sensient, Prestige® from Eckart Cosmetic Colors and Sunshine® available from Sunstar.
- Colorona® Particularly preferred color pigments with the trade name Colorona® are, for example:
- the agent according to the invention or the preparation according to the invention can also contain one or more coloring compounds from the group of organic pigments
- the organic pigments according to the invention are correspondingly insoluble, organic dyes or color lakes, for example from the group of nitroso, nitro, azo, xanthene, anthraquinone, isoindolinone, isoindoline, quinacridone, perinone, perylene -, Diketopyrrolopyorrole, indigo, thioindido, dioxazine, and / or triarylmethane compounds can be selected.
- Particularly suitable organic pigments are, for example, carmine, quinacridone, phthalocyanine, sorghum, blue pigments with the color index numbers CI 42090, CI 69800, CI 69825, CI 73000, CI 74100, CI 74160, yellow pigments with the color index numbers CI 1 1680, CI 11710, CI 15985, CI 19140, CI 20040, CI 21 100, CI 21 108, CI 47000, CI 47005, green pigments with the color index numbers CI 61565, CI 61570, CI 74260, orange pigments with the color index Numbers CI 1 1725, CI 15510, CI 45370, CI 71 105, red pigments with the Color Index numbers CI 12085, CI 12120, CI 12370, CI 12420, CI 12490, CI 14700, CI 15525, CI 15580, CI 15620, CI 15630, CI 15
- a method according to the invention is characterized in that the composition (B) and / or the composition (C) contains at least one coloring compound from the group of organic pigments, which is selected from the group of carmine, quinacridone, Phthalocyanine, Sorgho, blue pigments with the color index numbers CI 42090, CI 69800, CI 69825, CI 73000, CI 74100, CI 74160, yellow pigments with the color index numbers CI 1 1680, CI 1 1710, CI 15985, CI 19140, CI 20040, CI 21 100, CI 21 108, CI 47000, CI 47005, green pigments with the color index numbers CI 61565, CI 61570, CI 74260, orange pigments with the color index numbers CI 1 1725, CI 15510, CI 45370, CI 71 105, red pigments with the color index numbers CI 12085, CI 12120, CI 12370
- the organic pigment can also be a colored lacquer.
- the term “colored lacquer” is understood to mean particles which comprise a layer of absorbed dyes, the unit composed of particles and dye being insoluble under the above-mentioned conditions.
- the particles can be, for example, inorganic substrates, which can be aluminum, silica, calcium borosilicate, calcium aluminum borosilicate or also aluminum.
- the alizarin color varnish for example, can be used as the color varnish.
- the use of the aforementioned pigments in the agents according to the invention is particularly preferred because of their excellent light and temperature stability. It is also preferred if the pigments used have a certain particle size. This particle size leads, on the one hand, to a uniform distribution of the pigments in the polymer film formed and, on the other hand, avoids a rough hair or skin feel after the cosmetic agent has been applied. It is therefore advantageous according to the invention if the at least one pigment has an average particle size D50 of 1.0 to 50 ⁇ m, preferably 5.0 to 45 ⁇ m, more preferably 10 to 40 ⁇ m, in particular 14 to 30 ⁇ m.
- the mean particle size D50 can be determined, for example, using dynamic light scattering (DLS).
- the pigment or pigments can be used in an amount of from 0.001 to 20% by weight, in particular from 0.05 to 5% by weight, based in each case on the total weight of the agent or preparation according to the invention.
- the agents according to the invention can also contain one or more substantive dyes as coloring compounds.
- Direct dyes are dyes that are absorbed directly onto the hair and do not require an oxidative process to develop the color.
- Substantive dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones, triarylmethane dyes or indophenols.
- the substantive dyes for the purposes of the present invention have a solubility in water (760 mmHg) at 25 ° C. of more than 0.5 g / L and are therefore not to be regarded as pigments.
- the substantive dyes preferably have a solubility in water (760 mmHg) at 25 ° C. of more than 1.0 g / l.
- the substantive dyes particularly preferably have a solubility in water (760 mmHg) at 25 ° C. of more than 1.5 g / l.
- Substantive dyes can be divided into anionic, cationic and nonionic substantive dyes.
- an agent according to the invention is characterized in that it contains at least one anionic, cationic and / or nonionic substantive dye as the coloring compound.
- a method according to the invention is characterized in that the composition (B) and / or the composition (C) contains at least one coloring compound from the group of anionic, nonionic and / or cationic substantive dyes.
- Suitable cationic substantive dyes are, for example, Basic Blue 7, Basic Blue 26, Basic Violet 2 and Basic Violet 14, Basic Yellow 57, Basic Red 76, Basic Blue 16, Basic Blue 347 (Cationic Blue 347 / Dystar), HC Blue No. 16, Basic Blue 99, Basic Brown 16, Basic Brown 17, Basic Yellow 57, Basic Yellow 87, Basic Orange 31, Basic Red 51 Basic Red 76
- Nonionic nitro and quinone dyes and neutral azo dyes can be used as nonionic substantive dyes.
- Suitable nonionic substantive dyes are those under the international names or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse Orange 3, HC Red 1, HC Red 3, HC Red 10, HC Red 1 1, HC Red 13, HC Red BN, HC Blue 2, HC Blue 1 1, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9 known compounds , as well as 1, 4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1, 4-bis (2-hydroxyethyl) amino-2-nitrobenzene, 3-nitro-4- (2-hydroxyethyl) - aminophenol, 2- (2-
- Acid dyes are taken to mean substantive dyes which have at least one carboxylic acid group (-COOH) and / or one sulfonic acid group (-SO3H).
- -COOH carboxylic acid group
- -SO3H sulfonic acid group
- the protonated forms (-COOH, -SO3H) of the carboxylic acid or sulfonic acid groups are in equilibrium with their deprotonated forms (-COO-, -S03 _ ). The proportion of protonated forms increases with decreasing pH.
- Acid dyes according to the invention can also be used in the form of their sodium salts and / or their potassium salts.
- the acid dyes for the purposes of the present invention have a solubility in water (760 mmHg) at 25 ° C. of more than 0.5 g / L and are therefore not to be regarded as pigments.
- the acid dyes preferably have a solubility in water (760 mmHg) at 25 ° C. of more than 1.0 g / l.
- alkaline earth salts such as calcium salts and magnesium salts
- aluminum salts of acid dyes often have a poorer solubility than the corresponding alkali salts. If the solubility of these salts is below 0.5 g / L (25 ° C, 760 mmHg), they do not fall under the definition of a substantive dye.
- An essential feature of the acid dyes is their ability to form anionic charges, the carboxylic acid or sulfonic acid groups responsible for this usually being linked to different chromophoric systems.
- Suitable chromophoric systems are found, for example, in the structures of nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinone dyes, triarylmethane dyes, xanthene dyes, rhodamine dyes, oxazine dyes and / or indophenol dyes.
- Acid Yellow 1 (D&C Yellow 7, Citronin A, Ext. D&C Yellow No. 7, Japan Yellow 403, CI 10316, COLIPA n ° B001), Acid Yellow 3 (COLIPA n °: C 54, D&C Yellow N ° 10, Quinoline Yellow, E104, Food Yellow 13), Acid Yellow 9 (CI 13015), Acid Yellow 17 (CI 18965), Acid Yellow 23 (COLIPA n ° C 29, Covacap Jaune W 1 100 (LCW), Sicovit Tartrazine 85 E 102 (BASF), Tartrazine, Food Yellow 4, Japan Yellow 4, FD&C Yellow No.
- Acid Yellow 1 (D&C Yellow 7, Citronin A, Ext. D&C Yellow No. 7, Japan Yellow 403, CI 10316, COLIPA n ° B001), Acid Yellow 3 (COLIPA n °: C 54, D&C Yellow N ° 10, Quinoline Yellow, E104, Food Yellow 13), Acid Yellow 9 (CI 13015), Acid Yellow 17 (CI 18965), Acid Yellow 23 (COLIPA
- Acid Yellow 36 (CI 13065), Acid Yellow 121 ( CI 18690), Acid Orange 6 (CI 14270), Acid Orange 7 (2- Naphthol orange, Orange II, CI 15510, D&C Orange 4, COLIPA n ° C015), Acid Orange 10 (Cl 16230; Orange G sodium salt), Acid Orange 1 1 (CI 45370), Acid Orange 15 (CI 50120), Acid Orange 20 (CI 14600), Acid Orange 24 (BROWN 1; CI 20170; KATSU201; nosodiumsalt; Brown No.201; RESORCIN BROWN; ACID ORANGE 24 ; Japan Brown 201; D & C Brown No.1), Acid Red 14 (CI14720), acid red 18 (E124, red 18; C1 16255), Acid Red 27 (E 123, C1 16185, C-Red 46, Echtrot D, FD&C Red Nr.2, Food Red 9, Naphtholrot S), Acid Red 33 (Red 33, Fuchsia Red, D&C Red 33, C1 17200
- Acid Green 50 (Brillantklare indispensable BS, Cl 44090, Acid Brilliant Green BS, E 142), Acid Black 1 (Black n ° 401, Naphthalene Black 10B, Amido Black 10B, CI 20 470, COLIPA n ° B15), Acid Black 52 (CI 1571 1), Food Yellow 8 (CI 14270), Food Blue 5, D&C Yellow 8, D&C Green 5, D&C Orange 10, D&C Orange 1 1, D&C Red 21, D&C Red 27, D&C Red 33, D&C Violet 2 and / or D&C Brown 1.
- the water solubility of the anionic substantive dyes can be determined, for example, in the following way. 0.1 g of the anionic substantive dye are placed in a beaker. A stir bar is added. Then 100 ml of water are added. This mixture is heated to 25 ° C. on a magnetic stirrer while stirring. It is stirred for 60 minutes. The aqueous mixture is then assessed visually. If there are still undissolved residues, the amount of water is increased - for example in steps of 10 ml. Water is added until the amount of dye used has completely dissolved. If the dye-water mixture cannot be assessed visually due to the high intensity of the dye, the mixture is filtered.
- the solubility test is repeated with a larger amount of water. If 0.1 g of the anionic substantive dye dissolves in 100 ml of water at 25 ° C., the solubility of the dye is 1.0 g / l.
- Acid Yellow 1 is called 8-hydroxy-5,7-dinitro-2-naphthalenesulfonic acid disodium salt and has a solubility in water of at least 40 g / L (25 ° C).
- Acid Yellow 3 is a mixture of the sodium salts of mono- and sisulfonic acids of 2- (2-quinolyl) -1H-indene-1,3 (2H) -dione and has a water solubility of 20 g / L (25 ° C).
- Acid Yellow 9 is the disodium salt of 8-hydroxy-5,7-dinitro-2-naphthalenesulfonic acid, its water solubility is above 40 g / L (25 ° C).
- Acid Yellow 23 is the trisodium salt of 4,5-dihydro-5-oxo-1 - (4-sulfophenyl) -4 - ((4-sulfophenyl) azo) -1H-pyrazole-3-carboxylic acid and is good at 25 ° C soluble in water.
- Acid Orange 7 is the sodium salt of 4 - [(2-Hydroxy-1-naphthyl) azo] benzene sulfonate. Its water solubility is more than 7 g / L (25 ° C).
- Acid Red 18 is the trinity salt of 7-hydroxy-8 - [(E) - (4-sulfonato-1-naphthyl) -diazenyl)] - 1,3-naphthalenedisulfonate and has a very high solubility in water of more than 20 wt. %.
- Acid Red 33 is the diantrium salt of 5-amino-4-hydroxy-3- (phenylazo) -naphthalene-2,7-disulphonate, its water solubility is 2.5 g / L (25 ° C).
- Acid Red 92 is the disodium salt of 3,4,5,6-tetrachloro-2- (1,4,5,8-tetrabromo-6-hydroxy-3-oxoxanthen-9-yl) benzoic acid, its water solubility is specified with greater than 10 g / L (25 ° C).
- Acid Blue 9 is the disodium salt of 2 - ( ⁇ 4- [N-ethyl (3-sulfonatobenzyl] amino] phenyl ⁇ ⁇ 4 - [(N-ethyl (3-sulfonatobenzyl) imino] -2,5-cyclohexadiene-1 - ylidene ⁇ methyl) benzene sulfonate and has a water solubility of more than 20% by weight (25 ° C).
- thermochromic dyes can also be used. Thermochromism includes the property of a material to change its color reversibly or irreversibly depending on the temperature. This can be done both by changing the intensity and / or the wavelength maximum.
- Photochromism includes the property of a material to change its color reversibly or irreversibly depending on the exposure to light, in particular UV light. This can be done both by changing the intensity and / or the wavelength maximum.
- preparations described above in particular preparations (B), (C) and (D), very particularly preferably preparation (D), can contain at least one film-forming polymer.
- Polymers are understood to mean macromolecules with a molecular weight of at least 1000 g / mol, preferably of at least 2500 g / mol, particularly preferably of at least 5000 g / mol, which consist of identical, repeating organic units.
- the polymers of the present invention can be synthetically produced polymers which are produced by polymerizing one type of monomer or by polymerizing different types of monomers which are structurally different from one another. If the polymer is produced by polymerizing one type of monomer, it is called a homo-polymer. If structurally different types of monomers are used in the polymerization, the resulting polymer is referred to as a copolymer.
- the maximum molecular weight of the polymer depends on the degree of polymerisation (number of polymerised monomers) and the batch size and is also determined by the polymerisation method. For the purposes of the present invention, it is preferred if the maximum molecular weight of the film-forming, hydrophobic polymer (c) is not more than 10 7 g / mol, preferably not more than 10 6 g / mol and particularly preferably not more than 10 5 g / mol amounts.
- a film-forming polymer is understood to mean a polymer which is able to form a film on a substrate, for example on a keratinic material or a keratinous fiber.
- the formation of a film can be detected, for example, by viewing the keratin material treated with the polymer under a microscope.
- the film-forming polymers can be hydrophilic or hydrophobic. In a first embodiment, it can be preferred to use at least one hydrophobic, film-forming polymer in preparation (B), (C) and / or (D), very particularly in preparation (D).
- a hydrophobic polymer is understood to mean a polymer that has a solubility in water at 25 ° C. (760 mmHg) of less than 1% by weight.
- the water solubility of the film-forming, hydrophobic polymer can be determined, for example, in the following way. 1.0 g of the polymer are placed in a beaker. Make up to 100 g with water. A stir bar is added and the mixture is warmed to 25 ° C on a magnetic stirrer while stirring. It is stirred for 60 minutes. The aqueous mixture is then assessed visually. If the polymer-water mixture cannot be assessed visually due to the high turbidity of the mixture, the mixture is filtered. If a proportion of undissolved polymer remains on the filter paper, the solubility of the polymer is less than 1% by weight.
- the polymers of the acrylic acid type, the polyurethanes, the polyesters, the polyamides, the polyureas, the cellulose polymers, the nitro-cellulose polymers, the silicone polymers, the polymers of the acrylamide type and the polyisoprenes can be mentioned here in particular .
- Particularly suitable film-forming, hydrophobic polymers are, for example, polymers from the group of copolymers of acrylic acid, copolymers of methacrylic acid, homopolymers or copolymers of acrylic acid esters, homopolymers or copolymers of methacrylic acid esters, homopolymers or copolymers of acrylic acid amides, homopolymers or copolymers of methacrylic acid amides, copolymers of vinyl pyrrolidone, copolymers of vinyl alcohol, copolymers of vinyl acetate, homopolymers or copolymers of ethylene, homopolymers or copolymers of propylene, homopolymers or copolymers of styrene, polyurethanes, polyesters and / or the polyamides.
- an agent according to the invention is characterized in that it contains at least one film-forming, hydrophobic polymer (c) which is selected from the group of copolymers of acrylic acid, copolymers of methacrylic acid, homopolymers or copolymers of acrylic acid esters, homopolymers or copolymers of methacrylic acid esters, homopolymers or copolymers of acrylic acid amides, homopolymers or copolymers of methacrylic acid amides, copolymers of vinyl pyrrolidone, copolymers of vinyl alcohol, copolymers of vinyl acetate, homopolymers or copolymers of ethylene or homopolymers Copolymers of propylene, homopolymers or copolymers of styrene, polyurethanes, polyesters and / or polyamides.
- the film-forming hydrophobic polymers which are selected from the group of synthetic polymers, the polymers obtainable by free radical polymerization or the natural polymers
- suitable film-forming hydrophobic polymers can be selected from the homopolymers or copolymers of olefins, such as cycloolefins, butadiene, isoprene or styrene, vinyl ethers, vinyl amides, the esters or amides of
- Further film-forming hydrophobic polymers can be selected from the homo- or
- Further film-forming hydrophobic polymers can be selected from the homo- or
- Alkyl groups such as, for example, N-ethyl-acrylamide, N-tert-butyl-acrylamide, le N-octyl-acrylamide; N-di (C1-C4) alkyl (meth) acrylamide.
- anionic copolymers are, for example, copolymers of acrylic acid, methacrylic acid or their Ci-C6-alkyl esters, as sold under the INCI declaration Acrylates Copolymers.
- a suitable commercial product is, for example Aculyn ® 33 from Rohm & Haas.
- copolymers of acrylic acid, methacrylic acid or their Ci-C6-alkyl esters and the esters of an ethylenically unsaturated acid and an alkoxylated fatty alcohol are also preferred.
- Suitable ethylenically unsaturated acids are, in particular, acrylic acid, methacrylic acid and itaconic acid;
- suitable alkoxylated fatty alcohols are, in particular, steareth-20 or ceteth-20.
- Aculyn ® 22 (Acrylates / Steareth-20 Methacrylate Copolymer), Aculyn ® 28 (Acrylates / Beheneth-25 Methacrylate Copolymer), Structure 2001 ® (Acrylates / steareth-20 itaconate Copolymer), Structure 3001 ® (Acrylates / Ceteth-20 Itaconate Copolymer), Structure Plus ® (Acrylates / Aminoacrylates C10-30 Alkyl PEG-20 Itaconate Copolymer), Carbopol® 1342, 1382, Ultrez 20, Ultrez 21 (Acrylates / C 10 -30 Alkyl Acrylate Crosspolymer), Synthalen W 2000® (Acrylates / Palmeth-25 Acrylate Copolymer) or the Soltex OPT (Acrylates / C 12-22 Alkyl methacrylate Copolymer) sold by Rohme and Haas.
- Suitable polymers based on vinyl monomers are the homo- and copolymers of N-vinylpyrrolidone, vinylcaprolactam, vinyl (C1 -C6) alkyl pyrrole, vinyl oxazole, vinyl thiazole, of vinylpyrimidine, of vinylimidazole.
- copolymers octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer such as is sold commercially by NATIONAL STARCH under the trade names AMPHOMER® or LOVOCRYL® 47, or the copolymers of acrylates / octylacrylamides under the trade names, are also very particularly suitable DERMACRYL® LT and DERMACRYL® 79 are distributed by NATIONAL STARCH.
- Suitable polymers based on olefins are the homo- and copolymers of ethylene, propylene, butene, isoprene and butadiene.
- block copolymers which comprise at least one block made of styrene or the derivatives of styrene can be used as film-forming hydrophobic polymers.
- These block copolymers can be copolymers which, in addition to a styrene block, contain one or more other blocks, such as, for example, styrene / ethylene, styrene / ethylene / butylene, styrene / butylene, styrene / isoprene, styrene / butadiene.
- Corresponding polymers are sold commercially by BASF under the trade name “Luvitol HSB”.
- preparation (B), (C) and / or (D), very particularly preparation (D), contained at least one film-forming polymer selected from the group that of homopolymers and copolymers of acrylic acid, homopolymers and copolymers of methacrylic acid, homopolymers and copolymers of acrylic acid esters, homopolymers and copolymers of methacrylic acid esters, homopolymers and copolymers of acrylic acid amides, homopolymers and copolymers of methacrylic acid amides, of Homopolymers and copolymers of vinyl pyrrolidone, homopolymers and copolymers of vinyl alcohol, homopolymers and copolymers of vinyl acetate, homopolymers and copolymers of ethylene, homopolymers and copolymers of propylene, homopolymers and copolymers of styrene, polyurethanes, polyesters and polyamides.
- film-forming polymer selected from the group that of homopoly
- a method according to the invention is characterized in that preparation (B), (C) and / or (D), very particularly preparation (D), contains at least one film-forming polymer selected from the group of Homopolymers and copolymers of acrylic acid, the homopolymers and copolymers of methacrylic acid, the homopolymers and copolymers of acrylic acid esters, the homopolymers and copolymers of methacrylic acid esters, homopolymers and copolymers of acrylic acid amides, homopolymers and copolymers of methacrylic acid amides, homopolymers and copolymers of vinyl pyrrolidone, homopolymers and copolymers of vinyl alcohol, homopolymers and copolymers of vinyl acetate, homopolymers and copolymers of ethylene , homopolymers and copolymers of propylene, homopolymers and copolymers of styrene, polyurethanes, polyesters and
- At least one hydrophilic, film-forming polymer in preparation (B), (C) and / or (D), very particularly in preparation (D).
- a hydrophilic polymer is understood to mean a polymer that has a solubility in water at 25 ° C. (760 mmHg) of more than 1% by weight, preferably more than 2% by weight.
- the water solubility of the film-forming hydrophilic polymer can be determined, for example, in the following way. 1.0 g of the polymer are placed in a beaker. Make up to 100 g with water. A stir bar is added and the mixture is warmed to 25 ° C on a magnetic stirrer while stirring. It is stirred for 60 minutes. The aqueous mixture is then assessed visually. A completely dissolved polymer appears homogeneous under a markoscopy. If the polymer-water mixture cannot be assessed visually due to the high turbidity of the mixture, the mixture is filtered. If no undissolved polymer remains on the filter paper, the solubility of the polymer is more than 1% by weight.
- Nonionic, anionic and cationic polymers can be used as film-forming, hydrophilic polymers.
- Suitable film-forming, hydrophilic polymers can, for example, from the group of polyvinyl pyrrolidone (co) polymers, polyvinyl alcohol (co) polymers, vinyl acetate (co) polymers, carboxyvinyl (co) polymers, acrylic acid (co) Polymers, methacrylic acid (co) polymers, natural gums, polysaccharides and / or acrylamide (co) polymers can be selected.
- PVP polyvinylpyrrolidone
- / or a vinylpyrrolidone-containing copolymer as the film-forming hydrophilic polymer.
- an agent according to the invention is characterized in that it contains (c) at least one film-forming, hydrophilic polymer selected from the group consisting of polyvinylpyrrolidone (PVP) and the copolymers of polyvinylpyrrolidone. It is also preferred if the agent according to the invention contains polyvinylpyrrolidone (PVP) as the film-forming, hydrophilic polymer. Surprisingly, the washfastness of the dyeings that could be obtained with agents containing PVP (b9) was also very good.
- polyvinylpyrrolidones are available, for example, under the name Luviskol® K from BASF SE, in particular Luviskol® K 90 or Luviskol® K 85 from BASF SE.
- the polymer PVP K30 which is sold by Ashland (ISP, POI Chemical), can also be used as another polyvinylpyrrolidone (PVP) that is explicitly very particularly suitable.
- PVP K 30 is a polyvinylpyrrolidone which is very soluble in cold water and has the CAS number 9003-39-8.
- the molecular weight of PVP K 30 is approx. 40,000 g / mol.
- polyvinylpyrrolidones are the substances known under the trade names LUVITEC K 17, LUVITEC K 30, LUVITEC K 60, LUVITEC K 80, LUVITEC K 85, LUVITEC K 90 and LUVITEC K 115 and available from BASF.
- film-forming hydrophilic polymers from the group of copolymers of polyvinylpyrrolidone has also led to particularly good and washable color results.
- Vinylester vinylpyrrolidone copolymers can be mentioned, as they are sold for example under the trademark Luviskol ® (BASF) in this context.
- Luviskol ® VA 64 and Luviskol ® VA 73, each vinyl pyrrolidone / vinyl acetate copolymers, are particularly preferred nonionic polymers.
- styrene / VP copolymer and / or a vinylpyrrolidone-vinyl acetate copolymer and / or a VP / DMAPA acrylates copolymer and / or a VP / vinyl caprolactam / DMAPA acrylates copolymer are very particularly preferably used in the cosmetic compositions .
- Vinylpyrrolidone-vinyl acetate copolymers are sold under the name Luviskol® VA by BASF SE.
- a VP / vinyl caprolactam / DMAPA Acrylates copolymer is sold by Ashland Inc. under the trade name Aquaflex® SF-40.
- a VP / DMAPA Acrylates copolymer is sold, for example, under the name Styleze CC-10 by Ashland and is a highly preferred vinylpyrrolidone-containing copolymer.
- copolymers of polyvinylpyrrolidone that can be mentioned are the copolymers which are obtained by reacting N-vinylpyrrolidone with at least one further monomer the group consisting of V-vinylformamide, vinyl acetate, ethylene, propylene, acrylamide, vinylcaprolactam, vinylcaprolactone and / or vinyl alcohol.
- an agent according to the invention is characterized in that it contains at least one film-forming, hydrophilic polymer which is selected from the group consisting of polyvinylpyrrolidone (PVP), vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / styrene copolymers, vinylpyrrolidone / Ethylene copolymers, vinyl pyrrolidone / propylene copolymers, vinyl pyrrolidone / vinyl caprolactam copolymers,
- PVP polyvinylpyrrolidone
- vinylpyrrolidone / vinyl acetate copolymers vinylpyrrolidone / styrene copolymers
- vinylpyrrolidone / Ethylene copolymers vinyl pyrrolidone / propylene copolymers
- vinyl pyrrolidone / vinyl caprolactam copolymers PVP
- Vinyl pyrrolidone / vinyl formamide copolymers and / or vinyl pyrrolidone / vinyl alcohol copolymers are examples of vinyl pyrrolidone / vinyl formamide copolymers and / or vinyl pyrrolidone / vinyl alcohol copolymers.
- Another suitable copolymer of vinyl pyrrolidone is the polymer known under the INCI name maltodextrin / VP copolymer.
- the preparation (B), (C) and / or (D), very particularly the preparation (D), contain at least one nonionic, film-forming, hydrophilic polymer.
- a nonionic polymer is understood to mean a polymer which in a protic solvent - such as, for example, water - does not carry structural units with permanently cationic or anionic groups under standard conditions, which have to be compensated by counterions while maintaining electrical neutrality.
- Cationic groups include, for example, quaternized ammonium groups, but not protonated amines.
- Anionic groups include, for example, carboxyl and sulfonic acid groups.
- the agents are very particularly preferred which contain, as the nonionic, film-forming, hydrophilic polymer, at least one polymer selected from the group consisting of
- Another particularly preferred polymer is selected from the polymers with the INCI name VP / Methacrylamide / Vinyl Imidazole Copolymer, which are available, for example, under the trade name Luviset Clear from BASF SE.
- Another very particularly preferred nonionic, film-forming, hydrophilic polymer is a copolymer of N-vinylpyrrolidone and N, N-dimethylaminiopropyl methacrylamide, which, for example, with the INCI name VP / DMAPA Acrylates Copolymer z. B. is sold under the trade name Styleze®CC 10 by the company ISP.
- a cationic polymer according to the invention is the copolymer of N-vinylpyrrolidone, N-vinylcaprolactam, N- (3-dimethylaminopropyl) methacrylamide and 3- (methacryloylamino) propyl-lauryl-dimethylammonium chloride (INCI name: Polyquaternium-69), which, for example, under the trade name AquaStyle ® 300 (28-32% by weight of active substance in an ethanol-water mixture, molecular weight 350,000) is sold by ISP.
- AquaStyle ® 300 28-32% by weight of active substance in an ethanol-water mixture, molecular weight 350,000
- hydrophilic polymers are, for example
- Vinylpyrrolidone-vinylimidazolium methochloride copolymers as offered under the names Luviquat ® FC 370, FC 550 and the INCI name Polyquaternium-16 as well as FC 905 and HM 552,
- Vinylpyrrolidone-vinyl caprolactam-acrylate terpolymers such as those offered by Acrylklareestern and acrylamides as the third monomer commercially, for example under the name Aqua Flex ® SF 40th
- Polyquaternium-1 1 is the reaction product of diethyl sulfate with a copolymer of vinyl pyrrolidone and dimethylaminoethyl methacrylate.
- Suitable commercial products are available, for example, under the names Dehyquart® CC 11 and Luviquat® PQ 11 PN from BASF SE or Gafquat 440, Gafquat 734, Gafquat 755 or Gafquat 755N from Ashland Inc.
- Polyquaternium-46 is the reaction product of vinyl caprolactam and vinyl pyrrolidone with methyl vinyl imidazolium methosulfate and is available, for example, under the name Luviquat® Hold available from BASF SE. Polyquaternium-46 is preferably used in an amount of 1 to 5% by weight, based on the total weight of the cosmetic composition. It is very particularly preferred that Polyquaternium-46 is used in combination with a cationic guar compound. It is even highly preferred that Polyquaternium-46 is used in combination with a cationic guar compound and Polyquaternium-11.
- Acrylic acid polymers for example, which can be present in uncrosslinked or crosslinked form, can be used as suitable anionic film-forming, hydrophilic polymers.
- Corresponding products are sold commercially, for example, under the trade names Carbopol 980, 981, 954, 2984 and 5984 by Lubrizol or also under the names Synthalen M and Synthalen K by 3V Sigma (The Sun Chemicals, Inter Harz).
- Suitable film-forming, hydrophilic polymers from the group of natural gums are xanthan gum, gellan gum, carob gum.
- Suitable film-forming, hydrophilic polymers from the group of the polysaccharides are hydroxyethyl cellulose, hydroxypropyl cellulose, ethyl cellulose and carboxymethyl cellulose.
- Suitable film-forming, hydrophilic polymers from the group of acrylamides are, for example, polymers which are produced starting from monomers of (meth) acrylamido-C1-C4-alkyl-sulfonic acid or the salts thereof.
- Corresponding polymers can be selected from the polymers of polyacrylamidomethanesulfonic acid, polyacrylamidoethanesulfonic acid, polyacrylamidopropanesulfonic acid, poly2-acrylamido-2-methylpropanesulfonic acid, poly-2-methylacrylamido-2-methylpropanesulfonic acid and / or poly-2-methylacrylamido-n-butanesulfonic acid.
- Preferred polymers of the poly (meth) arylamido-C1 -C4-alkyl-sulfonic acids are crosslinked and at least 90% neutralized. These polymers can be crosslinked or else uncrosslinked.
- Crosslinked and completely or partially neutralized polymers of the poly-2-acrylamido-2-methylpropanesulfonic acid type are known under the INCI names "Ammonium Polyacrylamido-2-methylpropanesulphonate” or "Ammonium Polyacryldimethyltauramide”.
- Another preferred polymer of this type is the crosslinked poly-2-acrylamido-2methyl-propanesulphonic acid polymer sold by Clamant under the trade name Hostacerin AMPS, which is partially neutralized with ammonia.
- a method according to the invention is characterized in that preparation (B), (C) and / or (D), very particularly preparation (D), contains at least one anionic, film-forming polymer.
- the preparation (B), (C) and / or (D), especially the preparation (D), contains at least one film-forming polymer which contains at least one structural unit of the formula (Pl) and at least one structural unit of the formula (P-II)
- M stands for a hydrogen atom or for ammonium (NFU), sodium, potassium, 14 magnesium or 14 calcium.
- a method according to the invention is characterized in that preparation (B), (C) and / or (D), very particularly preparation (D), contains at least one film-forming polymer which has at least one structural unit of the formula ( Pl) and at least one structural unit of the formula (Pl I)
- M stands for a hydrogen atom or for ammonium (NFU), sodium, potassium, 1 magnesium or 14 calcium.
- the structural unit of the formula (P-1) is based on an acrylic acid unit.
- the structural unit of the formula (PI) is based on the ammonium salt of acrylic acid. If M stands for a sodium counterion, the structural unit of the formula (PI) is based on the sodium salt of acrylic acid.
- the structural unit of the formula (P-1) is based on the potassium salt of acrylic acid.
- the structural unit of the formula (P-1) is based on the magnesium salt of acrylic acid.
- the structural unit of the formula (P-1) is based on the calcium salt of acrylic acid.
- the film-forming polymer (s) according to the invention are preferably used in certain quantity ranges in preparations (B), (C) and / or (D) according to the invention.
- preparations (B), (C) and / or (D) according to the invention it has proven to be particularly preferred to solve the problem according to the invention if the preparation - based in each case on its total weight - has one or more film-forming polymers in a total amount of 0.1 to 18.0% by weight, preferably 1 , 0 to 16.0% by weight, more preferably from 5.0 to 14.5% by weight and very particularly preferably from 8.0 to 12.0% by weight.
- a method according to the invention is characterized in that preparation (B), (C) and / or (D) - based on their respective
- Total weight - one or more film-forming polymers in a total amount of 0.1 to 18.0% by weight, preferably from 1.0 to 16.0% by weight, more preferably from 5.0 to 14.5% by weight % and very particularly preferably from 8.0 to 12.0% by weight.
- Multi-component packaging unit (kit-of-parts)
- a second subject matter of the present invention is a multi-component packaging unit (kit-of-parts) for treating keratinous material, comprehensively packaged separately from one another
- compositions (A) and (B) already being disclosed in detail in the description of the first subject matter of the invention.
- the multicomponent packaging unit according to the invention can also comprise a third packaging unit containing a cosmetic preparation (C).
- preparation (C) very particularly preferably contains at least one coloring compound.
- the inventive composition very particularly preferably contains at least one coloring compound.
- Multi-component packaging unit (kit-of-parts) packaged separately from one another a third container with a third composition (C), the third composition (C) already in detail in the description of the first
- the multicomponent packaging unit according to the invention can also comprise a fourth packaging unit containing a cosmetic preparation (D).
- the preparation (D) very particularly preferably contains at least one film-forming polymer.
- Multi-component packaging unit (kit-of-parts) packaged separately from one another a fourth container with a fourth composition (D), the fourth composition (D) already in detail in the description of the first
- a reactor with a heatable / coolable outer shell and a capacity of 10 liters was filled with 4.67 kg of methyltrimethoxysilane (34.283 mol). 1.33 kg (3-aminopropyl) triethoxysilane (6.008 mol) were then added with stirring. This mixture was stirred at 30 ° C. Then 670 ml of distilled water (37.18 mol) were added dropwise with vigorous stirring, the temperature of the reaction mixture being kept at 30 ° C. with external cooling. After the addition of water had ended, stirring was continued for a further 10 minutes. A vacuum of 280 mbar was then applied and the reaction mixture was heated to a temperature of 44.degree.
- compositions (B) were prepared (unless stated otherwise, all data are in% by weight).
- composition (C) The following compositions were prepared (unless otherwise stated, all data are in% by weight).
- the ready-to-use composition was prepared by mixing 1.5 g of the composition (A), 20.0 g of the composition (B) and 1.5 g of the composition (C). The compositions (A), (B) and (C) were each shaken for 1 minute, then this ready-to-use agent was dyed onto two strands of hair (Kerling, Euronaturhaar white).
- the ready-to-use composition was applied to a first strand (strand 1), allowed to act for 1 min and then rinsed out. 10 minutes after the end of the spillage, the ready-to-use composition was applied to a second strand (strand 2), left to act for 1 min and then rinsed out.
- composition (D) was then applied to each lock of hair, left to act for 1 minute and then also rinsed out with water.
- the two colored tresses were each dried and compared visually under a daylight lamp.
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102019204809.9A DE102019204809A1 (de) | 2019-04-04 | 2019-04-04 | Erhöhung der Stabilität von Mitteln zur Behandlung von Keratinmaterial |
PCT/EP2020/054103 WO2020200575A1 (de) | 2019-04-04 | 2020-02-17 | Verfahren zur behandlung von keratinmaterial |
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Publication Number | Publication Date |
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EP3946230A1 true EP3946230A1 (de) | 2022-02-09 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP20707196.0A Pending EP3946230A1 (de) | 2019-04-04 | 2020-02-17 | Verfahren zur behandlung von keratinmaterial |
Country Status (6)
Country | Link |
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US (1) | US20220192957A1 (de) |
EP (1) | EP3946230A1 (de) |
JP (1) | JP2022526580A (de) |
CN (1) | CN113710221A (de) |
DE (1) | DE102019204809A1 (de) |
WO (1) | WO2020200575A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102021201928A1 (de) * | 2021-03-01 | 2022-09-01 | Henkel Ag & Co. Kgaa | Produkt mit Spendersystem zur Behandlung von Keratinmaterial |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19738866A1 (de) | 1997-09-05 | 1999-03-11 | Henkel Kgaa | Schaumarme Tensidmischungen mit Hydroxymischethern |
ES2573052T3 (es) | 2008-09-30 | 2016-06-03 | L'oreal | Composición cosmética integrada por un compuesto orgánico de silicio, -con al menos una función básica-, un polímero filmógeno hidrófobo, un pigmento y un solvente volátil |
FR2944965B1 (fr) * | 2009-04-30 | 2012-08-10 | Oreal | Eclaircissement et/ou coloration de fibres keratiniques humaines au moyen d'une composition anhydre comprenant un compose amino-trialcoxy silane ou -trialcenyloxy silaneet dispositif |
FR2944964B1 (fr) * | 2009-04-30 | 2011-05-27 | Oreal | Eclaircissement et/ou coloration de fibres keratiniques humaines au moyen d'une composition comprenant un amino-trialcoxy silane ou amino-trialcenyloxy silane |
FR2982155B1 (fr) | 2011-11-09 | 2014-07-18 | Oreal | Composition cosmetique comprenant au moins un alcoxysilane |
-
2019
- 2019-04-04 DE DE102019204809.9A patent/DE102019204809A1/de not_active Withdrawn
-
2020
- 2020-02-17 JP JP2021558894A patent/JP2022526580A/ja active Pending
- 2020-02-17 EP EP20707196.0A patent/EP3946230A1/de active Pending
- 2020-02-17 WO PCT/EP2020/054103 patent/WO2020200575A1/de unknown
- 2020-02-17 US US17/601,011 patent/US20220192957A1/en active Pending
- 2020-02-17 CN CN202080026666.8A patent/CN113710221A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
JP2022526580A (ja) | 2022-05-25 |
CN113710221A (zh) | 2021-11-26 |
US20220192957A1 (en) | 2022-06-23 |
DE102019204809A1 (de) | 2020-10-08 |
WO2020200575A1 (de) | 2020-10-08 |
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