EP3924397A4 - Lewis-basenkatalysatoren und verfahren dafür - Google Patents

Lewis-basenkatalysatoren und verfahren dafür Download PDF

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Publication number
EP3924397A4
EP3924397A4 EP20755183.9A EP20755183A EP3924397A4 EP 3924397 A4 EP3924397 A4 EP 3924397A4 EP 20755183 A EP20755183 A EP 20755183A EP 3924397 A4 EP3924397 A4 EP 3924397A4
Authority
EP
European Patent Office
Prior art keywords
methods
lewis base
base catalysts
catalysts
lewis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20755183.9A
Other languages
English (en)
French (fr)
Other versions
EP3924397A1 (de
Inventor
Georgy P. GORYUNOV
Vladislav A. Popov
Dmitry V Uborsky
Alexander Z. Voskoboynikov
John R. Hagadorn
Irene C. Cai
Jo Ann M. Canich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3924397A1 publication Critical patent/EP3924397A1/de
Publication of EP3924397A4 publication Critical patent/EP3924397A4/de
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP20755183.9A 2019-02-12 2020-02-11 Lewis-basenkatalysatoren und verfahren dafür Pending EP3924397A4 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962804389P 2019-02-12 2019-02-12
EP19179810 2019-06-12
PCT/US2020/017757 WO2020167838A1 (en) 2019-02-12 2020-02-11 Lewis base catalysts and methods thereof

Publications (2)

Publication Number Publication Date
EP3924397A1 EP3924397A1 (de) 2021-12-22
EP3924397A4 true EP3924397A4 (de) 2022-06-22

Family

ID=72044270

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20755183.9A Pending EP3924397A4 (de) 2019-02-12 2020-02-11 Lewis-basenkatalysatoren und verfahren dafür

Country Status (4)

Country Link
EP (1) EP3924397A4 (de)
CN (1) CN113423744B (de)
SG (1) SG11202108010RA (de)
WO (1) WO2020167838A1 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220139378A (ko) * 2020-02-11 2022-10-14 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법
KR20220152223A (ko) * 2020-02-11 2022-11-15 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 중합체 및 그의 균질한 제조 방법
EP4103629A4 (de) * 2020-02-11 2024-06-05 ExxonMobil Chemical Patents Inc. Mit übergangsmetall-bis(phenolat)-katalysatorkomplexen erhaltene polyethylenzusammensetzungen und verfahren zu ihrer herstellung
EP4232484A1 (de) * 2020-10-22 2023-08-30 ExxonMobil Chemical Patents Inc. Mehrzähnige lewis-basen-katalysatoren und verfahren zur verwendung davon
CN116670188A (zh) 2020-12-29 2023-08-29 埃克森美孚化学专利公司 基于聚烯烃的离子聚合物及其制备
CN118414360A (zh) 2021-12-17 2024-07-30 埃克森美孚化学专利公司 具有宽的cd和mwd的基于丙烯的共聚物的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080177020A1 (en) * 2006-09-21 2008-07-24 Theodor Agapie Non-metallocene organometallic complexes and related methods and systems
US20160289351A1 (en) * 2014-05-15 2016-10-06 Chevron Phillips Chemical Company Lp Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports
KR20180022137A (ko) * 2016-08-23 2018-03-06 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020002256A1 (en) * 1998-09-16 2002-01-03 Thomas Henry Peterson Catalyst composition for the polymerization of olefins
US6869904B2 (en) * 2002-04-24 2005-03-22 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2013048848A2 (en) * 2011-09-30 2013-04-04 Exxonmobil Chemical Patents Inc. Dynamic modulation of metallocene catalysts
US10329363B2 (en) * 2015-03-23 2019-06-25 Exxonmobil Chemical Patents Inc. Group 6 transition metal catalyst compound and use thereof
WO2018075245A1 (en) * 2016-10-19 2018-04-26 Exxonmobil Chemical Patents Inc. Mixed catalyst systems and methods of using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080177020A1 (en) * 2006-09-21 2008-07-24 Theodor Agapie Non-metallocene organometallic complexes and related methods and systems
US20160289351A1 (en) * 2014-05-15 2016-10-06 Chevron Phillips Chemical Company Lp Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports
KR20180022137A (ko) * 2016-08-23 2018-03-06 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
GOLISZ S R ET AL: "Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, UNITED STATES, vol. 42, no. 22, 24 November 2009 (2009-11-24), pages 8751 - 8762, XP001552523, ISSN: 0024-9297, [retrieved on 20091029], DOI: 10.1021/MA901659Q *
See also references of WO2020167838A1 *
THEODOR AGAPIE ET AL: "Zirconium and Titanium Complexes Supported by Tridentate LX2 Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization", ORGANOMETALLICS, AMERICAN CHEMICAL SOCIETY, US, vol. 27, no. 23, 8 December 2008 (2008-12-08), pages 6245 - 6256, XP002743333, ISSN: 0276-7333, [retrieved on 20081106], DOI: 10.1021/OM800136Y *

Also Published As

Publication number Publication date
CN113423744B (zh) 2023-05-05
WO2020167838A1 (en) 2020-08-20
SG11202108010RA (en) 2021-08-30
CN113423744A (zh) 2021-09-21
EP3924397A1 (de) 2021-12-22

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