EP3924397A4 - Lewis base catalysts and methods thereof - Google Patents

Lewis base catalysts and methods thereof Download PDF

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Publication number
EP3924397A4
EP3924397A4 EP20755183.9A EP20755183A EP3924397A4 EP 3924397 A4 EP3924397 A4 EP 3924397A4 EP 20755183 A EP20755183 A EP 20755183A EP 3924397 A4 EP3924397 A4 EP 3924397A4
Authority
EP
European Patent Office
Prior art keywords
methods
lewis base
base catalysts
catalysts
lewis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20755183.9A
Other languages
German (de)
French (fr)
Other versions
EP3924397A1 (en
Inventor
Georgy P. GORYUNOV
Vladislav A. Popov
Dmitry V Uborsky
Alexander Z. Voskoboynikov
John R. Hagadorn
Irene C. Cai
Jo Ann M. Canich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3924397A1 publication Critical patent/EP3924397A1/en
Publication of EP3924397A4 publication Critical patent/EP3924397A4/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP20755183.9A 2019-02-12 2020-02-11 Lewis base catalysts and methods thereof Pending EP3924397A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962804389P 2019-02-12 2019-02-12
EP19179810 2019-06-12
PCT/US2020/017757 WO2020167838A1 (en) 2019-02-12 2020-02-11 Lewis base catalysts and methods thereof

Publications (2)

Publication Number Publication Date
EP3924397A1 EP3924397A1 (en) 2021-12-22
EP3924397A4 true EP3924397A4 (en) 2022-06-22

Family

ID=72044270

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20755183.9A Pending EP3924397A4 (en) 2019-02-12 2020-02-11 Lewis base catalysts and methods thereof

Country Status (4)

Country Link
EP (1) EP3924397A4 (en)
CN (1) CN113423744B (en)
SG (1) SG11202108010RA (en)
WO (1) WO2020167838A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230348634A1 (en) * 2020-02-11 2023-11-02 Exxonmobil Chemical Patents Inc. Propylene Polymers Obtained Using Transition Metal Bis(Phenolate) Catalyst Complexes and Homogeneous Process for Production Thereof
CA3167579A1 (en) * 2020-02-11 2021-08-19 Peijun Jiang Polyethylene compositions obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof
CN115315453A (en) * 2020-02-11 2022-11-08 埃克森美孚化学专利公司 Propylene copolymers obtained using transition metal bis (phenolate) catalyst complexes and homogeneous processes for producing the same
EP4232484A1 (en) * 2020-10-22 2023-08-30 ExxonMobil Chemical Patents Inc. Multidentate lewis base catalysts and methods for use thereof
WO2022146634A1 (en) 2020-12-29 2022-07-07 Exxonmobil Chemical Patents Inc. Polyolefin-based ionomers and production thereof
CA3241034A1 (en) 2021-12-17 2023-06-22 Exxonmobil Chemical Patents Inc. Processes for making propylene-based copolymers having broad cds and mwds

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080177020A1 (en) * 2006-09-21 2008-07-24 Theodor Agapie Non-metallocene organometallic complexes and related methods and systems
US20160289351A1 (en) * 2014-05-15 2016-10-06 Chevron Phillips Chemical Company Lp Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports
KR20180022137A (en) * 2016-08-23 2018-03-06 주식회사 엘지화학 Novel ligand compound and transition metal compound comprising the same

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020002256A1 (en) * 1998-09-16 2002-01-03 Thomas Henry Peterson Catalyst composition for the polymerization of olefins
US6897276B2 (en) * 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
EP2760895A4 (en) * 2011-09-30 2015-07-22 Exxonmobil Chem Patents Inc Dynamic modulation of metallocene catalysts
US10329363B2 (en) * 2015-03-23 2019-06-25 Exxonmobil Chemical Patents Inc. Group 6 transition metal catalyst compound and use thereof
CN110062777A (en) * 2016-10-19 2019-07-26 埃克森美孚化学专利公司 Hybrid catalyst system and its application method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080177020A1 (en) * 2006-09-21 2008-07-24 Theodor Agapie Non-metallocene organometallic complexes and related methods and systems
US20160289351A1 (en) * 2014-05-15 2016-10-06 Chevron Phillips Chemical Company Lp Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports
KR20180022137A (en) * 2016-08-23 2018-03-06 주식회사 엘지화학 Novel ligand compound and transition metal compound comprising the same

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
GOLISZ S R ET AL: "Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts", MACROMOLECULES, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, UNITED STATES, vol. 42, no. 22, 24 November 2009 (2009-11-24), pages 8751 - 8762, XP001552523, ISSN: 0024-9297, [retrieved on 20091029], DOI: 10.1021/MA901659Q *
See also references of WO2020167838A1 *
THEODOR AGAPIE ET AL: "Zirconium and Titanium Complexes Supported by Tridentate LX2 Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization", ORGANOMETALLICS, AMERICAN CHEMICAL SOCIETY, US, vol. 27, no. 23, 8 December 2008 (2008-12-08), pages 6245 - 6256, XP002743333, ISSN: 0276-7333, [retrieved on 20081106], DOI: 10.1021/OM800136Y *

Also Published As

Publication number Publication date
SG11202108010RA (en) 2021-08-30
EP3924397A1 (en) 2021-12-22
CN113423744B (en) 2023-05-05
WO2020167838A1 (en) 2020-08-20
CN113423744A (en) 2021-09-21

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