EP3924061A1 - Moldable gel cleanser - Google Patents

Moldable gel cleanser

Info

Publication number
EP3924061A1
EP3924061A1 EP20708622.4A EP20708622A EP3924061A1 EP 3924061 A1 EP3924061 A1 EP 3924061A1 EP 20708622 A EP20708622 A EP 20708622A EP 3924061 A1 EP3924061 A1 EP 3924061A1
Authority
EP
European Patent Office
Prior art keywords
carrageenan
personal care
care product
cleanser
jelly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20708622.4A
Other languages
German (de)
English (en)
French (fr)
Inventor
Cameron KETYER
Joseph James Greco
Oussama SALAH
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kenvue Brands LLC
Original Assignee
Johnson and Johnson Consumer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson and Johnson Consumer Inc filed Critical Johnson and Johnson Consumer Inc
Publication of EP3924061A1 publication Critical patent/EP3924061A1/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0204—Specific forms not provided for by any of groups A61K8/0208 - A61K8/14
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/733—Alginic acid; Salts thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9706—Algae
    • A61K8/9717—Rhodophycota or Rhodophyta [red algae], e.g. Porphyra
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to a personal care product particularly a moldable gel cleanser that has improved properties.
  • Foam based personal care products have a pleasant feel. Consumers particularly like high and thick foams, quick foaming action, lasting foams, and the feel of rich, luxurious, creamy foams.
  • surfactants are added to many personal care products. Surfactants play a major role in foam producing products by lowering the dynamic surface tension of the liquid- air interface to allow gas bubbles to be formed or introduced beneath the surface of the liquid. Surfactants also stabilize the foam once it is formed. However, surfactants are not without disadvantages. For example, some surfactants, such as sulfates, including alkyl sulfates and alkyl ether sulfates, are known to be irritating to the skin.
  • U.S. Published Application No. 20080206273 to Cosmetic Warriors, Ltd. discloses a cosmetic product that contains surfactant, glycerine, monopropylene glycol and optionally carrageenan.
  • the reference discloses that the inclusion of monopropylene glycol, mixed with the glycerine, has an effect upon the consistency of the jelly, resulting in the jelly having a durable and almost rubber-like texture.
  • the reference also discloses that the effects are surprising when the jelly contains a seaweed extract, since it was thought that such an extract would be destabilised by the presence of glycerine and monopropylene glycol.
  • 9,028,872 to FMC Corporation discloses a foam, methods of preparation, and uses thereof.
  • the reference discloses that the foam, which may be used in personal care applications, is preferably a polysaccharide and that examples of suitable polysaccharides for producing the foam include alginates, pectins, carrageenans, hyaluronates, chitosan and mixtures thereof.
  • U.S. Patent No. 10,064,881 to Y&B Mother's Choice Ltd. discloses compositions containing naturally-obtained plant extracts that contain naturally-obtained saponin material.
  • the reference discloses that carrageenan may be employed as a thickening agent in the compositions.
  • the present invention seeks to improve upon the previously known cosmetic jellies.
  • the moldable gel cleanser of the invention which is in fun, sensory -rich formats, promotes healthy hand-washing habits.
  • This invention is a gel cleanser of a moldable format and texture having an amount of carrageenan effective to create an enriched sensory experience for the consumer. Further, the moldable gel cleanser is free of sulfates, so it is mild for babies and toddlers.
  • the moldable gel cleanser has a gel matrix due to the presence of a potassium ion, and as such, the moldable gel cleanser has a gelatinous texture.
  • the moldable gel cleanser contains glycol, which prevents sponginess, helps with the stability and structure of, and imparts a smooth surface to, the moldable gel cleanser.
  • a personal care product comprising:
  • Carrageenan acts as a gelling agent.
  • the form of the moldable gel cleanser may differ depending on the amount of carrageenan in the product.
  • the carrageenan can be a blend of carrageenan containing kappa carrageenan and iota carrageenan. Depending on the ratio of kappa carrageenan and iota carrageenan, different forms, textures, fix syneresis and freeze thaw stability are achieved.
  • the personal care product contains at least 1.5%, but less than 2.0% kappa carrageenan. Not having enough carrageenan will cause the moldable gel cleanser to crumble upon use, while having too much carrageenan will compress the gel matrix and make it less gelatinous, minimizing the sensory experience. Most preferably, the personal care product having this form contains 1.75% kappa carrageenan.
  • the personal care product contains about 0.63% to about 0.75% kappa carrageenan.
  • CaCl2 at 0.1%-0.5% which makes kappa carrageenan brittle and crumbly, can be used to increase surface area post crush in the crumble form.
  • the personal care product contains 1.5% to 2.0%, and more preferably 1.75%, carrageenan in a ratio of 50:50 - 75:25 iota
  • carrageenan kappa carrageenan. Iota carrageenamkappa carrageenan in ratio of 75:25 results in a smooth jello texture. More preferably, the blend of carrageenan contains kappa carrageenan: iota carrageenan in a ratio of 0.88:2.62.
  • the personal care product contains 0.25% to 1.0%, and more preferably 0.5%, of a source of potassium ion.
  • the source of potassium ion is potassium sorbate.
  • the potassium sorbate also acts as preservative in the moldable gel cleanser of the invention.
  • the personal care product contains 2.5% to 7%, more preferably 5% to 6%, glycol.
  • the glycol is butylene glycol.
  • Glycol acts as a humectant in the moldable gel cleanser of the invention.
  • the personal care product also contains 10% to 30%, more preferably 15% to 25%, surfactant.
  • the surfactant is a surfactant system that comprises sodium methyl cocoyl taurate, cocamidopropyl betaine and decyl glucoside. More preferably, the surfactant system comprises sodium methyl cocoyl taurate, cocamidopropyl betaine and decyl glucoside in a 1:2: 1 (anionic:amphoteric:non-ionic) ratio. Decyl glucoside boosts foaming in the moldable gel cleanser of the invention.
  • a method of manufacturing a personal care product comprising: a carrageenan, a source of potassium ion, a glycol, and, preferably, a surfactant.
  • the surface area of the moldable gel cleanser can be maximized to enhance foaming and decrease slip.
  • the strong, durable multi-use form of the moldable gel cleanser of the present invention is particularly useful as a personal care product because it does not readily break-down in the way that a conventional cosmetic jelly does. It is therefore particularly suitable for use as a shower gel or body wash, where it can be applied in a somewhat similar fashion to a conventional bar of soap. All of the moldable gel cleanser forms are also suitable for use as, for example, a hair wash. DETAILED DESCIRPTION OF THE INVENTION
  • Carrageenans are linear sulfated polysaccharides that are extracted from red edible seaweeds. Carrageenans are chains of D-galactopyranosyl units joined with alternating a-1,3 and b-1,4 glycosidic linkages. There are three main varieties of carrageenan, which differ in their degree of sulfation. Kappa-carrageenan has one sulfate group per disaccharide, iota- carrageenan has two, and lambda-carrageenan has three.
  • Flash foaming refers to the foam formation behavior of a substance during foaming, i.e., the amount of foam produced dependent on time or energy input.
  • “Gel” is a soft, partially transparent semisolid substance.
  • “Gelling agent” is a substance added to a composition to provide the texture of a gel.
  • “Humectant” is a substance that retains moisture.
  • SLS sodium lauryl sulfate
  • SLES sodium laureth sulfate
  • “Surfactants” are compounds that lower the surface tension (or interfacial tension) between two liquids, between a gas and a liquid, or between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming agents, and dispersants.
  • a moldable gel cleanser according to an embodiment of the present invention is formed from components in Table 1, wherein percentages are given by weight.
  • a crushable, single use (crumble) moldable gel cleanser is formed from components in Table 3, wherein percentages are given by weight.
  • Table 3 Crumble 1 :2: 1 SMCT:CAPB:DG crumble 8% glycerin
  • a Jell-0®-like moldable gel cleanser according to an embodiment of the present invention is formed from the components in Table 4, wherein percentages are given by weight.
  • a method of manufacturing a moldable gel cleanser according to the present invention and based upon the above stated groups of components is as follows:
  • Carrageenan forms solid jellies.
  • Potassium sorbate is a good preservative/crosslinker.
  • Glycinates are incompatible, as demonstrated using potassium cocoyl glycinate.
  • Iota carrageenan does not work well on its own. A blend of iota carrageenan and kappa carrageenan works well.
  • PEG-80 and any polyethoxylated chemicals are incompatible with carrageenan.
  • the optimal carrageenan ratio for an iota/kappa blend is 0.88:2.62.
  • Foam height testing is a valuable method to objectively quantify foaming performance. It is performed by a tumbling instrument to ensure reproducibility. This method involves inverting cylinders for 32 cycles with 90g water and lOg product. Data are collected after 2, 4, 8, 16 and 32 cycles.
  • EIT epidermal irritation testing

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)
EP20708622.4A 2019-02-15 2020-02-11 Moldable gel cleanser Pending EP3924061A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962806024P 2019-02-15 2019-02-15
PCT/IB2020/051095 WO2020165773A1 (en) 2019-02-15 2020-02-11 Moldable gel cleanser

Publications (1)

Publication Number Publication Date
EP3924061A1 true EP3924061A1 (en) 2021-12-22

Family

ID=69740416

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20708622.4A Pending EP3924061A1 (en) 2019-02-15 2020-02-11 Moldable gel cleanser

Country Status (9)

Country Link
US (1) US11253440B2 (enrdf_load_stackoverflow)
EP (1) EP3924061A1 (enrdf_load_stackoverflow)
KR (1) KR20210127208A (enrdf_load_stackoverflow)
CN (1) CN113423471A (enrdf_load_stackoverflow)
AU (1) AU2020222315B2 (enrdf_load_stackoverflow)
BR (1) BR112021016099A8 (enrdf_load_stackoverflow)
CA (1) CA3129747A1 (enrdf_load_stackoverflow)
MX (1) MX2021009817A (enrdf_load_stackoverflow)
WO (1) WO2020165773A1 (enrdf_load_stackoverflow)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025133975A1 (en) * 2023-12-20 2025-06-26 Kenvue Brands Llc Hair cleansing formulation

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031206A (zh) * 2009-09-29 2011-04-27 强生消费者公司 含水凝胶相颗粒的皂条

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8628068D0 (en) * 1986-11-24 1986-12-31 Unilever Plc Aqueous gel comprising carrageenan
GB9807269D0 (en) * 1998-04-03 1998-06-03 Unilever Plc Detergent compositions
KR20030025269A (ko) * 2000-07-14 2003-03-28 존슨 앤드 존슨 컨수머 캄파니즈, 인코포레이티드 자가 발포성 세정 겔
DE10127104A1 (de) * 2001-06-02 2002-12-05 Wella Ag Zweiphasiges Haargel
GB2421432A (en) 2004-12-23 2006-06-28 Cosmetic Warriors Ltd Cosmetic jelly
AU2007224137A1 (en) 2006-03-01 2007-09-13 Fmc Biopolymer As Biodegradable foam
FR2954162B1 (fr) * 2009-12-23 2012-03-09 Oreal Composition cosmetique comprenant au moins deux gommes de carraghenanes
EP2648809B1 (en) 2010-12-09 2019-04-03 Y&B Mother's Choice Ltd. Natural formulations

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031206A (zh) * 2009-09-29 2011-04-27 强生消费者公司 含水凝胶相颗粒的皂条

Also Published As

Publication number Publication date
BR112021016099A8 (pt) 2022-10-11
WO2020165773A1 (en) 2020-08-20
US20200261328A1 (en) 2020-08-20
BR112021016099A2 (enrdf_load_stackoverflow) 2021-11-09
CN113423471A (zh) 2021-09-21
KR20210127208A (ko) 2021-10-21
MX2021009817A (es) 2021-09-08
CA3129747A1 (en) 2020-08-20
AU2020222315B2 (en) 2025-08-21
US11253440B2 (en) 2022-02-22
AU2020222315A1 (en) 2021-08-12

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