EP3907326A1 - Staple fiber treatment agent, staple fiber, and method for manufacturing spun-lace non-woven cloth - Google Patents
Staple fiber treatment agent, staple fiber, and method for manufacturing spun-lace non-woven cloth Download PDFInfo
- Publication number
- EP3907326A1 EP3907326A1 EP19907909.6A EP19907909A EP3907326A1 EP 3907326 A1 EP3907326 A1 EP 3907326A1 EP 19907909 A EP19907909 A EP 19907909A EP 3907326 A1 EP3907326 A1 EP 3907326A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- parts
- treatment agent
- short fiber
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
- D04H1/4258—Regenerated cellulose series
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Definitions
- the present invention relates to a short fiber treatment agent, a short fiber to which the short fiber treatment agent is attached, and a method for manufacturing a spunlace nonwoven fabric using short fibers to which the short fiber treatment agent is attached.
- Natural fibers such as cotton fibers, regenerated fibers such as rayon, and synthetic fibers such as polyolefin are generally used as raw material fibers for nonwoven fabrics.
- a treatment of applying a nonwoven fabric treatment agent containing a surfactant and the like to surfaces of raw material fibers is performed in some cases to impart, to the raw material fibers, various characteristics such as lubricity and bundling properties required in manufacturing of nonwoven fabrics.
- Patent document 1 discloses a configuration of a nonwoven fabric treatment agent containing a mineral oil, a fatty acid ester, and a polyoxyalkylene polyhydric alcohol fatty acid ester.
- Patent document 2 discloses a configuration of a fiber treatment agent for hydroentanglement through highly pressurized water jets containing a polyhydric alcohol fatty acid ester sulfate salt, a mineral oil, and a polyoxyalkylene polyhydric alcohol fatty acid ester.
- the nonwoven fabric treatment agents of the related art have a problem of frequent bubble formation in water used for hydroentanglement in a step of manufacturing nonwoven fabrics, that is, a problem of foaming when the treatment agent dropped from raw material fibers is mixed into water.
- the present invention has been made in view of these circumstances, and an object thereof is to provide a short fiber treatment agent that can inhibit foaming of water used for hydroentanglement. Another object of the present invention is to provide a short fiber to which the short fiber treatment agent is attached. Still another object of the present invention is to provide a method for manufacturing a spunlace nonwoven fabric using short fibers to which the short fiber treatment agent is attached.
- a short fiber treatment agent including a specific fatty acid derivative, a specific fatty acid or oil or fat, and a specific polyhydric alcohol is definitely suitable.
- a short fiber treatment agent for solving the above-mentioned problem contains a fatty acid derivative, at least one selected from fatty acids and oils and fats, and a polyhydric alcohol excluding polyoxyethylene polyoxypropylene glycol that includes 20 oxyethylene units and 30 oxypropylene units.
- the fatty acid derivative has a structure in which an alkylene oxide is added, at a ratio of 0.1 to 30 mol, to 1 mol of a fatty acid having 12 to 24 carbon atoms.
- the fatty acids have 12 to 24 carbon atoms.
- the oils and fats are at least one selected from vegetable oils, animal oils, and hardened oils thereof.
- the polyhydric alcohol has 2 to 6 hydroxy groups in the molecule.
- the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, and the polyhydric alcohol in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 99.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, and the content of the polyhydric alcohol be 0.1 to 90 parts by mass.
- the short fiber treatment agent preferably further contains at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone.
- the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass
- the content of the fatty acid derivative be 5 to 98.89 parts by mass
- the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass
- the content of the polyhydric alcohol be 0.1 to 90 parts by mass
- the content of the lubricant be 1 to 20 parts by mass.
- the short fiber treatment agent preferably further contains an anionic surfactant.
- the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the anionic surfactant be 1 to 20 parts by mass.
- the short fiber treatment agent may have a configuration including both an anionic surfactant and at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone.
- the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass
- the content of the fatty acid derivative be 5 to 97.89 parts by mass
- the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass
- the content of the polyhydric alcohol be 0.1 to 90 parts by mass
- the content of the anionic surfactant be 1 to 20 parts by mass
- the content of the lubricant be 1 to 20 parts by mass.
- a short fiber to be treated with the short fiber treatment agent is preferably viscose rayon.
- a short fiber for solving the above-mentioned problem is a short fiber to which the short fiber treatment agent is attached.
- a method for manufacturing a spunlace nonwoven fabric for solving the above-mentioned problem includes a first step and a second step.
- the first step is a step of carding the short fibers to manufacture a web.
- the second step is a step of entangling the web obtained in the first step through water jets. That is, the method includes carding short fibers to which the short fiber treatment agent is attached to manufacture a web, and entangling the obtained web through water jets.
- the present invention succeeds in inhibiting foaming of water used for hydroentanglement when short fibers to which a short fiber treatment agent is attached are hydroentangled.
- the short fiber treatment agent contains the following fatty acid derivative, at least one selected from the following fatty acids and the following oils and fats, and the following polyhydric alcohol.
- the fatty acid derivative has a structure in which an alkylene oxide is added to 1 mol of a fatty acid having 12 to 24 carbon atoms at a ratio of 0.1 to 30 mol.
- an addition form of ethylene oxide and propylene oxide is not particularly limited and may be any form of block addition, random addition, and a combination of block addition and random addition in a case where ethylene oxide and propylene oxide are contained as an alkylene oxide.
- the fatty acids have 12 to 24 carbon atoms.
- Specific examples of fatty acids having 12 to 24 carbon atoms include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, behenic acid, lignoceric acid, and coconut fatty acids.
- the components may be used alone or in a combination of two or more kinds thereof.
- oils and fats are at least one selected from vegetable oils, animal oils, and hardened oils thereof.
- oils and fats include castor oil, sesame oil, tall oil, palm oil, palm kernel oil, coconut oil, rapeseed oil, lard, beef tallow, whale oil, and hardened oils thereof.
- the components may be used alone or in a combination of two or more kinds thereof.
- the polyhydric alcohol has 2 to 6 hydroxy groups in the molecule.
- the polyhydric alcohol used in the present embodiment is selected from polyhydric alcohols excluding polyoxyethylene (in which the number of oxyethylene units is 20) polyoxypropylene (in which the number of oxypropylene units is 30) glycol.
- Specific examples of the polyhydric alcohol include ethylene glycol, propylene glycol, pentanediol, hexanediol, glycerin, pentaerythritol, sorbitol, sorbitan, polyethylene glycol, polypropylene glycol, and a reaction product of propylene glycol and an alkylene oxide.
- the components may be used alone or in a combination of two or more kinds thereof.
- the ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, and the polyhydric alcohol in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, and the polyhydric alcohol in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 99.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, and the content of the polyhydric alcohol be 0.1 to 90 parts by mass.
- the effects of the present invention can be further improved with this configuration.
- the short fiber treatment agent of the present embodiment preferably further contains at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone.
- the effects of the present invention can be further improved by blending the lubricant.
- the lubricant components may be used alone or in a combination of two or more kinds thereof.
- hydrocarbon compounds include mineral oils and paraffin wax.
- esters include butyl stearate, stearyl stearate, glycerin monooleate, glycerin trioleate, sorbitan monolaurate, sorbitan trilaurate, sorbitan monooleate, sorbitan trioleate, sorbitan monostearate, and sorbitan tristearate.
- silicones include dimethyl silicone, amino-modified silicones, and polyoxyalkylene-modified silicones.
- the ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the lubricant be 1 to 20 parts by mass, .
- the effects of the present invention can be further improved with this configuration.
- the short fiber treatment agent of the present embodiment preferably further contains an anionic surfactant.
- the effects of the present invention can be further improved by blending the anionic surfactant.
- the ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the anionic surfactant be 1 to 20 parts by mass.
- the effects of the present invention can be further improved with this configuration.
- the ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 97.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, the content of the anionic surfactant be 1 to 20 parts by mass, and the content of the lubricant be 1 to 20 parts by mass.
- the effects of the present invention can be further improved with this configuration.
- the short fiber treatment agent of the present embodiment preferably further contains a nonionic surfactant other than the above-mentioned components as another component.
- Short fibers to which the short fiber treatment agent of the present embodiment is attached are generally called staple fibers, and include no long fiber generally called filament fiber.
- the length of the short fibers in the present embodiment is not particularly limited as long as the short fibers correspond to short fibers in the art of the present invention, but the length is, for example, preferably 100 mm or shorter and more preferably 51 mm or shorter.
- fibers include natural fibers, such as cotton fibers and cotton fibers treated by exposure; regenerated fibers, such as viscose rayon fibers, high-tenacity rayon fibers, super high-tenacity rayon fibers, high-wet-modulus rayon fibers, solvent-spun rayon fibers, polynosic fibers, cupra fibers, and acetate fibers; and synthetic fibers, such as polyolefin fibers, polyester fibers, polyamide fibers, acrylic fibers, polyvinyl chloride fibers, and composite fibers composed of two or more kinds of thermoplastic resins.
- natural fibers such as cotton fibers and cotton fibers treated by exposure
- regenerated fibers such as viscose rayon fibers, high-tenacity rayon fibers, super high-tenacity rayon fibers, high-wet-modulus rayon fibers, solvent-spun rayon fibers, polynosic fibers, cupra fibers, and acetate fibers
- synthetic fibers such as polyolefin fibers, polyester fibers, poly
- viscose rayon fibers high-tenacity rayon fibers, super high-tenacity rayon fibers, high-wet-modulus rayon fibers, and solvent-spun rayon fibers are preferable, and viscose rayon fibers are particularly preferable.
- the short fiber treatment agent of the present embodiment contains a specific fatty acid derivative, at least one selected from specific fatty acids and specific oils and fats, and a specific polyhydric alcohol. Accordingly, when short fibers to which the short fiber treatment agent is attached are hydroentangled, it is possible to curb bubble formation due to mixing of the short fiber treatment agent that has dropped from the short fibers into water, that is, inhibit foaming of water used for hydroentanglement. Thereby, operation efficiency can be improved in a step of manufacturing a nonwoven fabric.
- the short fiber of the present embodiment is a short fiber to which the short fiber treatment agent of the first embodiment is attached.
- a known method such as an immersion method, a spray method, or a roller method may be applied.
- the step in which the short fiber treatment agent is applied is not particularly limited, and examples thereof include a step after a refining step, and a spinning step.
- the above-mentioned short fibers can be adopted as short fibers to be treated with the short fiber treatment agent of the present embodiment.
- the form of the short fiber treatment agent of the first embodiment when applied to the short fibers may be, for example, an organic solvent solution or an aqueous liquid.
- the short fiber treatment agent of the first embodiment be diluted with water to obtain an aqueous liquid having a concentration of 0.5% to 20% by mass, and that the aqueous liquid be applied to short fibers such that the ratio of the short fiber treatment agent of the first embodiment which does not contain a solvent is 0.1% to 1% by mass relative to the short fibers.
- a third embodiment will now be described that embodies a method for manufacturing a spunlace nonwoven fabric according to the present invention.
- a spunlace nonwoven fabric is manufactured by sequentially performing a web formation step (first step) and a hydroentanglement step (second step).
- the web formation step is a step of carding short fibers to which the above-mentioned short fiber treatment agent is attached, and thereby manufacturing a web.
- the carding can be performed using a known carding machine. Examples thereof include a flat card, a combination card, and a roller card.
- the hydroentanglement step is a step of entangling the web obtained in the web formation step through water jets. Fibers can be formed into a sheet shape when the web is subjected to highly pressurized water jets and thereby the fibers are entangled with each other due to the pressure of the water jets. A drying step or a winding step may be appropriately performed after performing the hydroentanglement step.
- the hydroentanglement can be suitably performed in the case of circulating water used in the hydroentanglement. Accordingly, texture of a spunlace nonwoven fabric can be favorable.
- the first to third embodiments may be modified as follows.
- the first to third embodiments and the following modifications can be implemented in combination with each other within a technically consistent range.
- a component generally used in treatment agents such as an antioxidant or an ultraviolet absorbent may be further added to the treatment agent of the embodiments described above for maintaining quality of the treatment agent as long as the effects of the present invention are not impaired.
- the following materials were used as raw materials for the short fiber treatment agent.
- a numerical value of each component indicates the content thereof in the short fiber treatment agent.
- a short fiber treatment agent was prepared in the same procedure as in Example 1 except that materials and mixing ratios shown in Table 1 were adopted.
- an aqueous liquid containing 10% of a short fiber treatment agent was obtained by the same procedure as in Example 1.
- Table 1 the type of each component used in the respective examples and the content (%) of each component in the treatment agent are shown in the column of "Fatty acid derivative,” the column of "Fatty acids, or oils and fats,” the column of "Polyhydric alcohol,” the column of "Lubricant,” the column of "Anionic surfactant,” and the column of "Other.”
- the aqueous liquid of the short fiber treatment agent of each of the examples shown in Table 1 was further diluted, and thereby a 0.2% emulsion of the short fiber treatment agent was prepared.
- the emulsion was applied to viscose rayon fibers having a fineness of 1.3 x 10 -4 g/m (1.2 deniers) and a fiber length of 38 mm by a spray lubrication method such that an amount attached (excluding a solvent) to the fibers was 0.2% by mass. Thereafter, humidity was controlled overnight in an atmosphere of 25°C x 40% RH using a hot air dryer at 80°C, and thereby viscose rayon fibers to which the short fiber treatment agent was attached were obtained.
- a foaming property test and a cotton odor test were conducted using the viscose rayon fibers to which the short fiber treatment agents of Examples 1 to 15 and Comparative Examples 1 to 6 were attached. The procedure of each test is shown below. Table 1 shows test results in the column of "Foaming property test” and the column of "Cotton odor test.”
- the present invention succeeds in inhibiting foaming of water used for hydroentanglement.
- the effect in which it is possible to reduce cotton odor of a fiber to which the short fiber treatment agent is attached.
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- Chemical Kinetics & Catalysis (AREA)
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- Emergency Medicine (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Description
- The present invention relates to a short fiber treatment agent, a short fiber to which the short fiber treatment agent is attached, and a method for manufacturing a spunlace nonwoven fabric using short fibers to which the short fiber treatment agent is attached.
- Natural fibers such as cotton fibers, regenerated fibers such as rayon, and synthetic fibers such as polyolefin are generally used as raw material fibers for nonwoven fabrics. A treatment of applying a nonwoven fabric treatment agent containing a surfactant and the like to surfaces of raw material fibers is performed in some cases to impart, to the raw material fibers, various characteristics such as lubricity and bundling properties required in manufacturing of nonwoven fabrics.
- In the related art, nonwoven fabric treatment agents disclosed in Patent documents 1 and 2 are known. Patent document 1 discloses a configuration of a nonwoven fabric treatment agent containing a mineral oil, a fatty acid ester, and a polyoxyalkylene polyhydric alcohol fatty acid ester. Patent document 2 discloses a configuration of a fiber treatment agent for hydroentanglement through highly pressurized water jets containing a polyhydric alcohol fatty acid ester sulfate salt, a mineral oil, and a polyoxyalkylene polyhydric alcohol fatty acid ester.
-
- Patent document 1:
International Publication No. WO 2016/104106 - Patent document 2:
Japanese Patent No. 6096061 - The nonwoven fabric treatment agents of the related art, however, have a problem of frequent bubble formation in water used for hydroentanglement in a step of manufacturing nonwoven fabrics, that is, a problem of foaming when the treatment agent dropped from raw material fibers is mixed into water.
- The present invention has been made in view of these circumstances, and an object thereof is to provide a short fiber treatment agent that can inhibit foaming of water used for hydroentanglement. Another object of the present invention is to provide a short fiber to which the short fiber treatment agent is attached. Still another object of the present invention is to provide a method for manufacturing a spunlace nonwoven fabric using short fibers to which the short fiber treatment agent is attached.
- As a result of study to solve the problem, the inventors of the present invention have found that a short fiber treatment agent including a specific fatty acid derivative, a specific fatty acid or oil or fat, and a specific polyhydric alcohol is definitely suitable.
- A short fiber treatment agent for solving the above-mentioned problem contains a fatty acid derivative, at least one selected from fatty acids and oils and fats, and a polyhydric alcohol excluding polyoxyethylene polyoxypropylene glycol that includes 20 oxyethylene units and 30 oxypropylene units. The fatty acid derivative has a structure in which an alkylene oxide is added, at a ratio of 0.1 to 30 mol, to 1 mol of a fatty acid having 12 to 24 carbon atoms. The fatty acids have 12 to 24 carbon atoms. The oils and fats are at least one selected from vegetable oils, animal oils, and hardened oils thereof. The polyhydric alcohol has 2 to 6 hydroxy groups in the molecule.
- It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, and the polyhydric alcohol in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 99.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, and the content of the polyhydric alcohol be 0.1 to 90 parts by mass.
- The short fiber treatment agent preferably further contains at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone.
- In this case, it is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the lubricant be 1 to 20 parts by mass.
- The short fiber treatment agent preferably further contains an anionic surfactant.
- In this case, it is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the anionic surfactant be 1 to 20 parts by mass.
- The short fiber treatment agent may have a configuration including both an anionic surfactant and at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone.
- In this case, it is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 97.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, the content of the anionic surfactant be 1 to 20 parts by mass, and the content of the lubricant be 1 to 20 parts by mass.
- A short fiber to be treated with the short fiber treatment agent is preferably viscose rayon.
- A short fiber for solving the above-mentioned problem is a short fiber to which the short fiber treatment agent is attached.
- A method for manufacturing a spunlace nonwoven fabric for solving the above-mentioned problem includes a first step and a second step. The first step is a step of carding the short fibers to manufacture a web. The second step is a step of entangling the web obtained in the first step through water jets. That is, the method includes carding short fibers to which the short fiber treatment agent is attached to manufacture a web, and entangling the obtained web through water jets.
- The present invention succeeds in inhibiting foaming of water used for hydroentanglement when short fibers to which a short fiber treatment agent is attached are hydroentangled.
- A first embodiment will now be described that embodies a short fiber treatment agent according to the present invention. The short fiber treatment agent contains the following fatty acid derivative, at least one selected from the following fatty acids and the following oils and fats, and the following polyhydric alcohol.
- The fatty acid derivative has a structure in which an alkylene oxide is added to 1 mol of a fatty acid having 12 to 24 carbon atoms at a ratio of 0.1 to 30 mol. Specific examples of fatty acid derivatives include (1) polyoxyalkylene alkyl (or alkylene) esters obtained by addition reaction of an alkylene oxide to saturated or unsaturated fatty acids, such as polyoxyethylene (in which the number n of oxyethylene units (= the number of moles of ethylene oxide added) is 20, that is, n = 20) oleate, polyoxyethylene (n = 10) oleate, polyoxyethylene (n = 30) oleate, polyoxyethylene (n = 5) stearate, polyoxyethylene (n = 10) stearate, polyoxyethylene (n = 10) lauryl esters, and polyoxyalkylene (n = 10, in which the number m of oxypropylene units (= the number of moles of propylene oxide added) is 10, that is, m = 10) stearyl esters; (2) polyalkylene glycol alkyl (or alkylene) esters obtained by addition reaction of a polyalkylene glycol to saturated or unsaturated fatty acids, such as polyethylene glycol (molecular weight: 400) monooleate, polyethylene glycol (molecular weight: 600) dioleate, polyethylene glycol (molecular weight: 1,000) monostearate, polyethylene glycol (molecular weight: 400) dilaurate, and polyethylene glycol (molecular weight: 1,000) distearate; and (3) esters of oils and fats of polyoxyalkylene obtained by addition reaction of an alkylene oxide to oils and fats, such as polyoxyethylene (n = 30) castor oil esters, polyoxyalkylene (n = 10, m = 10) castor oil esters, polyoxyethylene (n = 10) hardened castor oil esters, and a reaction product of a coconut fatty acid and 10 moles of ethylene oxide. The components may be used alone or in a combination of two or more kinds thereof. In addition, an addition form of ethylene oxide and propylene oxide is not particularly limited and may be any form of block addition, random addition, and a combination of block addition and random addition in a case where ethylene oxide and propylene oxide are contained as an alkylene oxide.
- The fatty acids have 12 to 24 carbon atoms. Specific examples of fatty acids having 12 to 24 carbon atoms include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, behenic acid, lignoceric acid, and coconut fatty acids. The components may be used alone or in a combination of two or more kinds thereof.
- The oils and fats are at least one selected from vegetable oils, animal oils, and hardened oils thereof. Specific examples of oils and fats include castor oil, sesame oil, tall oil, palm oil, palm kernel oil, coconut oil, rapeseed oil, lard, beef tallow, whale oil, and hardened oils thereof. The components may be used alone or in a combination of two or more kinds thereof.
- The polyhydric alcohol has 2 to 6 hydroxy groups in the molecule. The polyhydric alcohol used in the present embodiment is selected from polyhydric alcohols excluding polyoxyethylene (in which the number of oxyethylene units is 20) polyoxypropylene (in which the number of oxypropylene units is 30) glycol. Specific examples of the polyhydric alcohol include ethylene glycol, propylene glycol, pentanediol, hexanediol, glycerin, pentaerythritol, sorbitol, sorbitan, polyethylene glycol, polypropylene glycol, and a reaction product of propylene glycol and an alkylene oxide. The components may be used alone or in a combination of two or more kinds thereof.
- The ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, and the polyhydric alcohol in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, and the polyhydric alcohol in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 99.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, and the content of the polyhydric alcohol be 0.1 to 90 parts by mass. The effects of the present invention can be further improved with this configuration.
- The short fiber treatment agent of the present embodiment preferably further contains at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone. The effects of the present invention can be further improved by blending the lubricant. The lubricant components may be used alone or in a combination of two or more kinds thereof.
- Specific examples of hydrocarbon compounds include mineral oils and paraffin wax.
- Specific examples of esters include butyl stearate, stearyl stearate, glycerin monooleate, glycerin trioleate, sorbitan monolaurate, sorbitan trilaurate, sorbitan monooleate, sorbitan trioleate, sorbitan monostearate, and sorbitan tristearate.
- Specific examples of silicones include dimethyl silicone, amino-modified silicones, and polyoxyalkylene-modified silicones.
- The ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the lubricant be 1 to 20 parts by mass, . The effects of the present invention can be further improved with this configuration.
- The short fiber treatment agent of the present embodiment preferably further contains an anionic surfactant. The effects of the present invention can be further improved by blending the anionic surfactant. The type of anionic surfactant is not particularly limited, and examples thereof include (1) alkali metal salts of phosphoric acid esters of aliphatic alcohols, such as alkali metal salts of lauryl phosphoric acid esters, alkali metal salts of cetyl phosphoric acid esters, alkali metal salts of oleyl phosphoric acid esters, and alkali metal salts of stearyl phosphoric acid esters; (2) alkali metal salts of phosphoric acid esters in which at least one alkylene oxide selected from ethylene oxide and propylene oxide is added to aliphatic alcohols, such as alkali metal salts of polyoxyethylene (n = 5) lauryl ether phosphoric acid esters, alkali metal salts of polyoxyethylene (n = 5) oleyl ether phosphoric acid esters, and alkali metal salts of polyoxyethylene (n = 10) stearyl ether phosphoric acid esters; (3) alkali metal salts of sulfonic acid esters of aliphatic alcohols, such as alkali metal salts of lauryl sulfonic acid esters, alkali metal salts of oleyl sulfonic acid esters, alkali metal salts of stearyl sulfonic acid esters, and alkali metal salts of tetradecane sulfonic acid; (4) alkali metal salts of sulfuric acid esters of aliphatic alcohols, such as alkali metal salts of lauryl sulfuric acid esters, alkali metal salts of oleyl sulfuric acid esters, and alkali metal salts of stearyl sulfuric acid esters; (5) alkali metal salts of sulfuric acid esters in which at least one alkylene oxide selected from ethylene oxide and propylene oxide is added to aliphatic alcohols, such as alkali metal salts of polyoxyethylene (n = 3) lauryl ether sulfuric acid esters, alkali metal salts of polyoxyethylene (n = 5) lauryl ether sulfuric acid esters, alkali metal salts of polyoxyalkylene (n = 3, m = 3) lauryl ether sulfuric acid esters, alkali metal salts of polyoxyethylene (n = 3) oleyl ether sulfuric acid esters, and alkali metal salts of polyoxyethylene (n = 5) oleyl ether sulfuric acid esters; (6) alkali metal salts of sulfuric acid esters of fatty acids, such as alkali metal salts of sulfuric acid esters of fatty acids of castor oil, alkali metal salts of sulfuric acid esters of fatty acids of sesame oil, alkali metal salts of sulfuric acid esters of fatty acids of tall oil, alkali metal salts of sulfuric acid esters of fatty acids of soybean oil, alkali metal salts of sulfuric acid esters of fatty acids of rapeseed oil, alkali metal salts of sulfuric acid esters of fatty acids of palm oil, alkali metal salts of sulfuric acid esters of fatty acids of lard, alkali metal salts of sulfuric acid esters of fatty acids of beef tallow, and alkali metal salts of sulfuric acid esters of fatty acids of whale oil; (7) alkali metal salts of sulfuric acid esters of oils and fats, such as alkali metal salts of sulfuric acid esters of castor oil, alkali metal salts of sulfuric acid esters of sesame oil, alkali metal salts of sulfuric acid esters of tall oil, alkali metal salts of sulfuric acid esters of soybean oil, alkali metal salts of sulfuric acid esters of rapeseed oil, alkali metal salts of sulfuric acid esters of palm oil, alkali metal salts of sulfuric acid esters of lard, alkali metal salts of sulfuric acid esters of beef tallow, and alkali metal salts of sulfuric acid esters of whale oil; (8) alkali metal salts of fatty acids, such as alkali metal salts of lauric acid, alkali metal salts of oleic acid, and alkali metal salts of stearic acid; and (9) alkali metal salts of sulfosuccinic acid esters of aliphatic alcohols, such as alkali metal salts of dioctyl sulfosuccinic acid. The components may be used alone or in a combination of two or more kinds thereof.
- The ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, and the content of the anionic surfactant be 1 to 20 parts by mass. The effects of the present invention can be further improved with this configuration.
- The ratio among the contents of the fatty acid derivative, the fatty acids, the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent of the present embodiment is not limited. It is preferable that when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative be 5 to 97.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats be 0.01 to 10 parts by mass, the content of the polyhydric alcohol be 0.1 to 90 parts by mass, the content of the anionic surfactant be 1 to 20 parts by mass, and the content of the lubricant be 1 to 20 parts by mass. The effects of the present invention can be further improved with this configuration.
- The short fiber treatment agent of the present embodiment preferably further contains a nonionic surfactant other than the above-mentioned components as another component. Specific examples of nonionic surfactant other than the above-mentioned components include (1) polyoxyalkylene alkyl (or alkenyl) ethers obtained by addition reaction of an alkylene oxide to saturated or unsaturated aliphatic monohydric alcohols, such as polyoxyethylene (n = 10) lauryl ethers, polyoxyethylene (n = 20) stearyl ethers, polyoxyethylene (n = 30) oleyl ethers, polyoxyethylene (n = 10) alkyl (having 12 or 13 carbon atoms) ethers, and polyoxyalkylene (n = 10, m = 10) lauryl ethers; (2) polyoxyalkylene polyhydric alcohol ethers obtained by addition reaction of an alkylene oxide to aliphatic polyhydric alcohols, such as polyoxyethylene (n = 10) sorbitan monolaurate, polyoxyethylene (n = 20) sorbitan monooleate, polyoxyethylene (n = 20) sorbitan monostearate, and polyoxyethylene (n = 20) sorbitan tristearate; (3) polyoxyalkylene alkylphenol ethers obtained by addition reaction of an alkylene oxide to an alkylphenol, such as polyoxyethylene (n = 10) octylphenol ethers and polyoxyethylene (n = 10) nonylphenol ethers; and (4) polyoxyalkylene amino ethers obtained by addition reaction of an alkylene oxide to saturated or unsaturated aliphatic amines, such as polyoxyethylene (n = 5) octyl amino ethers, polyoxyethylene (n = 8) lauryl amino ethers, and polyoxyethylene (n = 20) stearyl amino ethers. The nonionic surfactants may be used alone or in a combination of two or more kinds thereof. The content of the nonionic surfactant is not limited.
- Short fibers to which the short fiber treatment agent of the present embodiment is attached are generally called staple fibers, and include no long fiber generally called filament fiber. The length of the short fibers in the present embodiment is not particularly limited as long as the short fibers correspond to short fibers in the art of the present invention, but the length is, for example, preferably 100 mm or shorter and more preferably 51 mm or shorter. Examples of fibers include natural fibers, such as cotton fibers and cotton fibers treated by exposure; regenerated fibers, such as viscose rayon fibers, high-tenacity rayon fibers, super high-tenacity rayon fibers, high-wet-modulus rayon fibers, solvent-spun rayon fibers, polynosic fibers, cupra fibers, and acetate fibers; and synthetic fibers, such as polyolefin fibers, polyester fibers, polyamide fibers, acrylic fibers, polyvinyl chloride fibers, and composite fibers composed of two or more kinds of thermoplastic resins. Among the examples, viscose rayon fibers, high-tenacity rayon fibers, super high-tenacity rayon fibers, high-wet-modulus rayon fibers, and solvent-spun rayon fibers are preferable, and viscose rayon fibers are particularly preferable.
- According to the first embodiment, the following effects can be obtained.
- (1) The short fiber treatment agent of the present embodiment contains a specific fatty acid derivative, at least one selected from specific fatty acids and specific oils and fats, and a specific polyhydric alcohol. Accordingly, when short fibers to which the short fiber treatment agent is attached are hydroentangled, it is possible to curb bubble formation due to mixing of the short fiber treatment agent that has dropped from the short fibers into water, that is, inhibit foaming of water used for hydroentanglement. Thereby, operation efficiency can be improved in a step of manufacturing a nonwoven fabric.
- A second embodiment will now be described that embodies a short fiber according to the present invention. The short fiber of the present embodiment is a short fiber to which the short fiber treatment agent of the first embodiment is attached. As a method of applying the short fiber treatment agent, a known method such as an immersion method, a spray method, or a roller method may be applied. The step in which the short fiber treatment agent is applied is not particularly limited, and examples thereof include a step after a refining step, and a spinning step.
- The above-mentioned short fibers can be adopted as short fibers to be treated with the short fiber treatment agent of the present embodiment.
- The form of the short fiber treatment agent of the first embodiment when applied to the short fibers may be, for example, an organic solvent solution or an aqueous liquid. In a method of treating short fibers, it is preferable that the short fiber treatment agent of the first embodiment be diluted with water to obtain an aqueous liquid having a concentration of 0.5% to 20% by mass, and that the aqueous liquid be applied to short fibers such that the ratio of the short fiber treatment agent of the first embodiment which does not contain a solvent is 0.1% to 1% by mass relative to the short fibers.
- A third embodiment will now be described that embodies a method for manufacturing a spunlace nonwoven fabric according to the present invention.
- A spunlace nonwoven fabric is manufactured by sequentially performing a web formation step (first step) and a hydroentanglement step (second step).
- The web formation step is a step of carding short fibers to which the above-mentioned short fiber treatment agent is attached, and thereby manufacturing a web. The carding can be performed using a known carding machine. Examples thereof include a flat card, a combination card, and a roller card.
- The hydroentanglement step is a step of entangling the web obtained in the web formation step through water jets. Fibers can be formed into a sheet shape when the web is subjected to highly pressurized water jets and thereby the fibers are entangled with each other due to the pressure of the water jets. A drying step or a winding step may be appropriately performed after performing the hydroentanglement step.
- According to the second and third embodiments, the following effects can be obtained in addition to the effects of (1).
- (2) Since it is possible to inhibit foaming of water used in hydroentanglement, the hydroentanglement can be suitably performed in the case of circulating water used in the hydroentanglement. Accordingly, texture of a spunlace nonwoven fabric can be favorable.
- (3) It is possible to reduce cotton odor of a short fiber to which the short fiber treatment agent is attached can be reduced.
- The first to third embodiments may be modified as follows. The first to third embodiments and the following modifications can be implemented in combination with each other within a technically consistent range.
- - A component generally used in treatment agents such as an antioxidant or an ultraviolet absorbent may be further added to the treatment agent of the embodiments described above for maintaining quality of the treatment agent as long as the effects of the present invention are not impaired.
- Examples will now be given below to described the features and effects of the present invention more specifically, but the present invention is not limited to these examples. In the following description of working examples and comparative examples, "part" means "part by mass," and "%" means "% by mass."
- The following materials were used as raw materials for the short fiber treatment agent. A numerical value of each component indicates the content thereof in the short fiber treatment agent.
-
- Fatty acid derivative: polyoxyethylene (n = 20) oleate (A-1) 20%
- Oils and fats: beef tallow (B-1) 5%
- Polyhydric alcohol: ethylene glycol (C-1) 70%
- Lubricant: stearyl stearate (D-1) 2%
- Anionic surfactant: potassium salts of lauryl phosphoric acid ester (E-1) 3%
- 900 parts of water was added to 100 parts of the short fiber treatment agent prepared such that the mixing ratios was as described above, the mixture was stirred at 50°C, and thereby an aqueous liquid containing 10% of the short fiber treatment agent was prepared.
- A short fiber treatment agent was prepared in the same procedure as in Example 1 except that materials and mixing ratios shown in Table 1 were adopted. In addition, an aqueous liquid containing 10% of a short fiber treatment agent was obtained by the same procedure as in Example 1. In Table 1, the type of each component used in the respective examples and the content (%) of each component in the treatment agent are shown in the column of "Fatty acid derivative," the column of "Fatty acids, or oils and fats," the column of "Polyhydric alcohol," the column of "Lubricant," the column of "Anionic surfactant," and the column of "Other."
- The aqueous liquid of the short fiber treatment agent of each of the examples shown in Table 1 was further diluted, and thereby a 0.2% emulsion of the short fiber treatment agent was prepared. The emulsion was applied to viscose rayon fibers having a fineness of 1.3 x 10-4 g/m (1.2 deniers) and a fiber length of 38 mm by a spray lubrication method such that an amount attached (excluding a solvent) to the fibers was 0.2% by mass. Thereafter, humidity was controlled overnight in an atmosphere of 25°C x 40% RH using a hot air dryer at 80°C, and thereby viscose rayon fibers to which the short fiber treatment agent was attached were obtained.
- A foaming property test and a cotton odor test were conducted using the viscose rayon fibers to which the short fiber treatment agents of Examples 1 to 15 and Comparative Examples 1 to 6 were attached. The procedure of each test is shown below. Table 1 shows test results in the column of "Foaming property test" and the column of "Cotton odor test."
- First, 20 g of the viscose rayon fibers was put into 150 g of water. The viscose rayon fibers were taken out after 15 minutes and squeezed using a hand juicer. 10 g of the squeezed liquid was put in a 25 ml graduated cylinder equipped with a stopper, shaken vigorously for 30 seconds, allowed to stand still for 30 seconds, and then shaken vigorously again for 30 seconds. After being allowed to stand still for 5 minutes, the height from the liquid surface to the top surface of foam was measured.
-
- oo (excellent): the height from the liquid surface to the top surface of foam was less than 1 mm.
- ○ (good): the height from the liquid surface to the top surface of foam was 1 mm or more and less than 2 mm.
- × (poor): the height from the liquid surface to the top surface of foam was 2 mm or more.
- 20 g of the viscose rayon fibers was put into 150 g of water. After it was sealed for 30 minutes, 10 testers each checked it for odor.
-
- ○○ (excellent): 2 or fewer testers judged that there was odor.
- ○ (good): 3 to 6 testers judged that there was odor.
- × (poor): 7 or more testers judged that there was odor.
- In Table 1, the following symbols are used:
- A-1: polyoxyethylene (n = 20) oleate;
- A-2: polyoxyethylene (n = 5) stearate;
- A-3: polyoxyethylene (n = 10) stearate;
- A-4: polyethylene glycol (molecular weight: 400) dilaurate;
- A-5: polyethylene glycol (molecular weight: 1,000) distearate;
- A-6: a reaction product of a coconut fatty acid and 10 moles of ethylene oxide;
- A-7: polyethylene glycol (molecular weight: 600) dioleate;
- A-8: polyoxyethylene (n = 10) oleate;
- A-9: polyoxyethylene (n = 30) oleate;
- A-10: polyethylene glycol (molecular weight: 400) monooleate;
- B-1: beef tallow;
- B-2: stearic acid;
- B-3: palmitic acid;
- B-4: coconut oil;
- B-5: palm oil;
- B-6: behenic acid;
- B-7: hardened palm oil;
- B-8: hardened castor oil;
- B-9: castor oil;
- B-10: oleic acid;
- B-11: lard;
- B-12: tall oil;
- B-13: lauric acid;
- B-14: coconut fatty acid;
- C-1: ethylene glycol;
- C-2: polyethylene glycol (molecular weight: 400);
- C-3: polypropylene glycol (molecular weight: 600);
- C-4: propylene glycol;
- C-5: polyethylene glycol (molecular weight: 600);
- C-6: a reaction product of propylene glycol and an alkylene oxide (average molecular weight: 3,000);
- C-7: polyethylene glycol (molecular weight: 2,000);
- C-8: sorbitan;
- C-9: sorbitol;
- C-10: glycerin;
- D-1: stearyl stearate;
- D-2: mineral oil (viscosity: 500 seconds);
- D-3: dimethyl silicone;
- D-4: mineral oil (viscosity: 180 seconds);
- D-5: amino silicone;
- D-6: paraffin wax;
- D-7: mineral oil (viscosity: 60 seconds);
- D-8: glycerin monooleate;
- D-9: mineral oil (viscosity: 80 seconds);
- D-10: sorbitan tristearate;
- D-11: sorbitan monostearate;
- E-1: potassium salt of lauryl phosphoric acid;
- E-2: sodium salt of dioctyl sulfosuccinate;
- E-3: sodium salt of tetradecane sulfonate;
- E-4: sodium oleate;
- E-5: sodium salt of sulfuric acid ester of beef tallow;
- E-6: potassium stearate;
- F-1: polyoxyethylene (n = 5) stearyl ether;
- F-2: polyoxyethylene (n = 20) sorbitan monostearate;
- F-3: polyoxyethylene (n = 20) sorbitan tristearate;
- F-4: polyoxyethylene (n = 20) sorbitan monostearate.
- As can be clearly seen from the results in Table 1, the present invention succeeds in inhibiting foaming of water used for hydroentanglement. In addition, there is the effect in which it is possible to reduce cotton odor of a fiber to which the short fiber treatment agent is attached.
Claims (11)
- A short fiber treatment agent comprising:a fatty acid derivative;at least one selected from fatty acids and oils and fats; anda polyhydric alcohol excluding polyoxyethylene polyoxypropylene glycol that includes 20 oxyethylene units and 30 oxypropylene units, whereinthe fatty acid derivative has a structure in which an alkylene oxide is added, at a ratio of 0.1 to 30 mol, to 1 mol of a fatty acid having 12 to 24 carbon atoms,the fatty acids have 12 to 24 carbon atoms,the oils and fats are at least one selected from vegetable oils, animal oils, and hardened oils thereof, andthe polyhydric alcohol has 2 to 6 hydroxy groups in the molecule.
- The short fiber treatment agent according to claim 1, wherein when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, and the polyhydric alcohol in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative is 5 to 99.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats is 0.01 to 10 parts by mass, and the content of the polyhydric alcohol is 0.1 to 90 parts by mass.
- The short fiber treatment agent according to claim 1, further comprising at least one lubricant selected from a hydrocarbon compound, an ester excluding the oils and fats, and a silicone.
- The short fiber treatment agent according to claim 3, wherein when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative is 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats is 0.01 to 10 parts by mass, the content of the polyhydric alcohol is 0.1 to 90 parts by mass, and the content of the lubricant is 1 to 20 parts by mass.
- The short fiber treatment agent according to claim 1, further comprising an anionic surfactant.
- The short fiber treatment agent according to claim 5, wherein when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, and the anionic surfactant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative is 5 to 98.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats is 0.01 to 10 parts by mass, the content of the polyhydric alcohol is 0.1 to 90 parts by mass, and the content of the anionic surfactant is 1 to 20 parts by mass.
- The short fiber treatment agent according to claim 3, further comprising an anionic surfactant.
- The short fiber treatment agent according to claim 7, wherein when the total content of the fatty acid derivative, the at least one selected from the fatty acids and the oils and fats, the polyhydric alcohol, the anionic surfactant, and the lubricant in the short fiber treatment agent is taken as 100 parts by mass, the content of the fatty acid derivative is 5 to 97.89 parts by mass, the content of the at least one selected from the fatty acids and the oils and fats is 0.01 to 10 parts by mass, the content of the polyhydric alcohol is 0.1 to 90 parts by mass, the content of the anionic surfactant is 1 to 20 parts by mass, and the content of the lubricant is 1 to 20 parts by mass.
- The short fiber treatment agent according to any one of claims 1 to 8, wherein a short fiber to be treated is viscose rayon.
- A short fiber to which the short fiber treatment agent according to any one of claims 1 to 9 is attached.
- A method for manufacturing a spunlace nonwoven fabric, the method comprising a first step and a second step, whereinthe first step is a step of carding short fibers according to claim 10 to manufacture a web, andthe second step is a step of entangling the web obtained in the first step through water jets.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2019000238A JP6533020B1 (en) | 2019-01-04 | 2019-01-04 | Process for producing short fiber treating agent, short fiber and spunlace nonwoven fabric |
PCT/JP2019/050497 WO2020141592A1 (en) | 2019-01-04 | 2019-12-24 | Staple fiber treatment agent, staple fiber, and method for manufacturing spun-lace non-woven cloth |
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EP3907326A4 EP3907326A4 (en) | 2022-04-20 |
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EP (1) | EP3907326A4 (en) |
JP (1) | JP6533020B1 (en) |
CN (1) | CN111757954B (en) |
TW (1) | TWI727563B (en) |
WO (1) | WO2020141592A1 (en) |
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CN114341422B (en) * | 2019-09-06 | 2023-12-19 | 松本油脂制药株式会社 | Fiber treating agent for high-pressure water jet and application thereof |
JP6812039B1 (en) * | 2020-04-10 | 2021-01-13 | 竹本油脂株式会社 | Viscose rayon Non-woven fabric treatment agent, viscose rayon Non-woven fabric treatment agent aqueous solution, viscose rayon, and method for producing viscose rayon for non-woven fabric |
JP6906822B1 (en) * | 2020-10-30 | 2021-07-21 | 竹本油脂株式会社 | Method for manufacturing short fiber treatment agents, synthetic fibers, and non-woven fabrics |
JP7029834B1 (en) * | 2021-06-04 | 2022-03-04 | 竹本油脂株式会社 | Synthetic fiber treatment agent, fiber first treatment agent, fiber second treatment agent, synthetic fiber treatment agent aqueous solution, fiber treatment method, and fiber |
JP7086423B1 (en) * | 2021-07-09 | 2022-06-20 | 竹本油脂株式会社 | Staple treatment agent, aqueous solution of staple fiber treatment agent, staple fiber treatment method, staple fiber manufacturing method, and staple fiber |
JP7252684B1 (en) | 2022-09-12 | 2023-04-05 | 竹本油脂株式会社 | Processing agent for viscose rayon, viscose rayon, viscose rayon staple fiber, and method for producing spunlace nonwoven fabric |
JP7311196B1 (en) | 2022-10-31 | 2023-07-19 | 竹本油脂株式会社 | Treatment agent for rayon spunlace, composition containing treatment agent for rayon spunlace, first treatment agent for rayon spunlace, composition containing first treatment agent for rayon spunlace, method for producing spunlace nonwoven fabric |
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JPS57175324A (en) * | 1981-04-21 | 1982-10-28 | Tiger Vacuum Bottle Ind | Electric rice cooker |
US5258129A (en) * | 1987-12-02 | 1993-11-02 | Takemoto Yushi Kabushiki Kaisha | Fluid-permeable agent for non-woven sheets of polyolefin fibers and method of application thereof |
DE3932032A1 (en) * | 1989-09-26 | 1991-04-04 | Peter Dr Kuhnle | Absorbent textile sheet, esp. for prodn. of medical compresses - by laying raw cotton fibres into a mat, wetting with aq. detergent, compacting with a water jet, boiling, scouring, washing and/or bleaching |
US7846462B2 (en) * | 2003-12-22 | 2010-12-07 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal care implement containing a stable reactive skin care and cleansing composition |
JP5213291B1 (en) * | 2012-09-28 | 2013-06-19 | 竹本油脂株式会社 | Synthetic fiber treatment agent, synthetic fiber treatment aqueous solution, synthetic fiber treatment method and synthetic fiber |
JP5213288B1 (en) * | 2012-11-26 | 2013-06-19 | 竹本油脂株式会社 | Synthetic fiber processing method, synthetic fiber, synthetic fiber spinning method and spun yarn |
JP6096061B2 (en) * | 2013-06-11 | 2017-03-15 | 松本油脂製薬株式会社 | Fiber treatment agent for high pressure water entanglement and its use |
JP5903450B2 (en) * | 2014-02-04 | 2016-04-13 | 松本油脂製薬株式会社 | Treatment agent for synthetic fibers and use thereof |
JP6720083B2 (en) | 2014-12-24 | 2020-07-08 | 松本油脂製薬株式会社 | Nonwoven fabric manufacturing treatment agent and its use |
CN106176291A (en) * | 2015-05-06 | 2016-12-07 | 金红叶纸业集团有限公司 | Hand-mouth baby wet tissue compositional liquor and wet tissue |
JP6979580B2 (en) * | 2016-09-02 | 2021-12-15 | ダイワボウレーヨン株式会社 | Rayon fiber for air-laid non-woven fabric and its manufacturing method, air-laid non-woven fabric and its manufacturing method, and water-melting paper |
JP6132966B1 (en) * | 2016-10-26 | 2017-05-24 | 竹本油脂株式会社 | Fiber treatment agent for spunlace and method for producing spunlace nonwoven fabric |
JP6454047B1 (en) * | 2018-06-28 | 2019-01-16 | 竹本油脂株式会社 | Viscose rayon nonwoven treatment agent and viscose rayon |
-
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- 2019-01-04 JP JP2019000238A patent/JP6533020B1/en active Active
- 2019-12-24 WO PCT/JP2019/050497 patent/WO2020141592A1/en unknown
- 2019-12-24 CN CN201980013978.2A patent/CN111757954B/en active Active
- 2019-12-24 EP EP19907909.6A patent/EP3907326A4/en active Pending
- 2019-12-25 TW TW108147485A patent/TWI727563B/en active
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JP6533020B1 (en) | 2019-06-19 |
WO2020141592A1 (en) | 2020-07-09 |
TW202031964A (en) | 2020-09-01 |
CN111757954B (en) | 2021-07-06 |
EP3907326A4 (en) | 2022-04-20 |
TWI727563B (en) | 2021-05-11 |
CN111757954A (en) | 2020-10-09 |
JP2020109221A (en) | 2020-07-16 |
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