EP3861146A1 - Tôle métallique revêtue, procédé de fabrication d'une telle tôle métallique revêtue et dispositif de galvanisation par immersion à chaud pour fabriquer une telle tôle métallique revêtue - Google Patents
Tôle métallique revêtue, procédé de fabrication d'une telle tôle métallique revêtue et dispositif de galvanisation par immersion à chaud pour fabriquer une telle tôle métallique revêtueInfo
- Publication number
- EP3861146A1 EP3861146A1 EP18788682.5A EP18788682A EP3861146A1 EP 3861146 A1 EP3861146 A1 EP 3861146A1 EP 18788682 A EP18788682 A EP 18788682A EP 3861146 A1 EP3861146 A1 EP 3861146A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- less
- metal sheet
- depth
- gas knife
- wsa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002184 metal Substances 0.000 title claims abstract description 98
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 98
- 238000005246 galvanizing Methods 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 36
- 238000000576 coating method Methods 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 32
- 230000006641 stabilisation Effects 0.000 claims abstract description 17
- 238000011105 stabilization Methods 0.000 claims abstract description 17
- 238000005097 cold rolling Methods 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/14—Removing excess of molten coatings; Controlling or regulating the coating thickness
- C23C2/16—Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0034—Details related to elements immersed in bath
- C23C2/00342—Moving elements, e.g. pumps or mixers
- C23C2/00344—Means for moving substrates, e.g. immersed rollers or immersed bearings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/14—Removing excess of molten coatings; Controlling or regulating the coating thickness
- C23C2/16—Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
- C23C2/18—Removing excess of molten coatings from elongated material
- C23C2/20—Strips; Plates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
Definitions
- COATED METAL SHEET METHOD TO PROVIDE SUCH A COATED METAL SHEET, AND HOT DIP GALVANIZING DEVICE TO MANUFACTURE SUCH A COATED METAL SHEET
- the invention relates primarily to a method of providing a coating on a metal sheet, wherein a cold rolled metal sheet is subjected to a hot dip galvanizing operation to provide a metal coating on the metal sheet, which hot dip galvanizing operation comprises guiding the metal sheet through a liquid bath of the metal coating with at least one stabilization roll, wherein each stabilization roll is entirely provided below a predefined depth level below surface level of the liquid bath, and wiping the metal coating that is provided on the metal sheet with at least one gas knife having an outlet to project wiping gas on the metal coating that is provided on the metal sheet that passes along the gas knife.
- Such a method of providing a coating on a metal sheet is widely known throughout the iron and steel industry; an exemplary publication showing such a method is GB 2517622.
- a problem also acknowledged in GB 2517622 is the waviness of the coated metal sheet, which causes that after providing the coated metal sheet with a film of paint its outer appearance can be less than optimal.
- One known problem is the appearance of orange skin which is particularly undesirable for outside body parts of automobiles.
- GB 2517622 does not particularly provide a workable solution for this problem, for one thing since its disclosure is obscure in relation to the waviness measure it applies.
- the invention proposes a method to manufacture a coated metal sheet, such a coated metal sheet, a hot dip galvanizing device and its combination with a cold rolling mill in accordance with one or more of the appended claims.
- Wsa is selected at a value representing a targeted maximum waviness, and values for distance D, height H and Depth are calculated.
- the method of the invention can suitably be executed by providing that D is 9 mm or less, preferably 8 mm or less, preferably 7 mm or less.
- the method of the invention can be executed by providing that H is 550 mm or less, preferably 400 mm or less, more preferably 200 mm or less.
- Depth is 150 mm or less, preferably 140 mm or less, more preferably 130 mm or less, most preferably 120 mm or less.
- Ra is determined in accordance with ISO 4287, using a cut-off of 2.5 mm.
- Ra is 4.5 pm or less, 1.5 pm or less, preferably 0.6 pm or less.
- a coated metal sheet can effectively be provided with a waviness Wsa of 0.41 pm or less, preferably 0.35 pm or less, more preferably 0.31 pm or less, more preferably 0.26 pm or less, most preferably 0.23 pm or less.
- a suitable minimum value for the targeted maximum waviness Wsa is 0.18 pm.
- hot dip galvanizing device D is 9 mm or less, preferably 8 mm or less, more preferably 7 mm or less.
- hot dip galvanizing device H is 550 mm or less, preferably 400 mm or less, more preferably 200 mm or less.
- Preferably Depth is 150 mm or less, preferably 140 mm or less, more preferably 130 mm or less, most preferably 120 mm or less.
- Ra is 4.5 pm or less, 1.5 pm or less, preferably 0.6 pm or less.
- FIG. 1 schematically shows a hot dip galvanizing device.
- a typical flow of manufacturing steps that leads to a coated metal sheet according to the invention is as follows: A metal slab is cast, and subsequently hot rolled in a hot strip mill to provide a metal strip, that is processed in a pickling line, cold rolled in a cold rolling mill, annealed in a continuous annealing line, and provided with a metal coating in a hot dip galvanizing line, temper rolled in a temper mill, shipped to customers, press formed and painted. Some of these operations can be dispensed with, while it is also possible that some other operations are added to this sequence of events. The skilled person further knows that many operations precede the casting step.
- FIG 1 shows a hot dip galvanizing device 1 1 to provide a metal coating on one surface 12 or both surfaces 12, 13 of a moving metal sheet 14, comprising a tank 15 that holds a liquid bath of the metal coating 16 that is to be provided on the moving metal sheet 14.
- Figure 1 shows the application of a stabilization roll 17 and a sink roll 21 to guide the moving metal sheet 14 through the bath, wherein the stabilization roll 17 is provided at a predefined depth (Depth) below a surface level 18 of the liquid bath.
- This Depth is defined as the distance between the surface level 18 of the liquid bath and an upper edge of the stabilization roll 17. It is remarked that the application of plural stabilization rolls is also possible, wherein then the Depth-parameter relates to the uppermost stabilization roll.
- Above the liquid bath at least one gas knife 19 is provided, which has an outlet 20 to project -in known way- wiping gas on the metal coating provided on the surface or surfaces 12, 13 of the metal sheet 15 that passes along the gas knife 19.
- Figure 1 shows both the height H of the gas knife or knives 19 above the liquid bath with reference to its surface level 18, and the distance D of the shown two air knives 19 with reference to the metal sheet 14.
- Table 1 shows the influence of the height H of the gas knife 19 above the liquid bath, and the influence of the distance D from sheet 14 to knife 19 in relation to the waviness Wsa of the coated metal sheet 14.
- Table 2 shows the influence of the height H of the gas knife 19 above the liquid bath and the Depth of the at least one stabilizing roll 17 below the surface level 18 of the liquid bath.
- Table 3 shows the influence of the roughness Ra of the last working rolls in the cold rolling mill in relation to X and their impact on the waviness of the product.
- stabilization roll 17 is preferably provided at a depth D below surface level 18 of the liquid bath at a value of equal or less than 150 mm, preferably at a value equal or less than 140 mm, more preferably at a value equal or less than 130 mm, most preferably at a value equal or less than 120 mm.
- Table 3 shows a calculation of the parameters to arrive at a target Wsa and it also shows the measured waviness as Realised Wsa.
- X D * ln(H * Depth), and Ra stands for the roughness of the working rolls in the last stand of the cold rolling mill.
- the stabilization roll 17 is preferably provided at a depth D below surface level 18 of the liquid bath of the metal coating 16 in dependence of the roughness Ra of the final working rolls of the cold rolling mill in order to achieve a maximum waviness Wsa of the coated metal sheet. Further preferred values of the roughness Ra are equal or less than 4.5 pm, equal or less than 1.5 pm, and more preferably 0.6 pm or less.
- the method of coating a metal sheet according to the invention results in a coated metal sheet with a waviness value Wsa equal or less than 0.41 pm; preferably equal or less than 0.35 pm; more preferably equal or less than 0.31 pm; more preferably equal or less than 0.26 pm; most preferably equal or less than 0.23 pm.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Abstract
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2018/076874 WO2020069734A1 (fr) | 2018-10-02 | 2018-10-02 | Tôle métallique revêtue, procédé de fabrication d'une telle tôle métallique revêtue et dispositif de galvanisation par immersion à chaud pour fabriquer une telle tôle métallique revêtue |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3861146A1 true EP3861146A1 (fr) | 2021-08-11 |
Family
ID=63878634
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18788682.5A Pending EP3861146A1 (fr) | 2018-10-02 | 2018-10-02 | Tôle métallique revêtue, procédé de fabrication d'une telle tôle métallique revêtue et dispositif de galvanisation par immersion à chaud pour fabriquer une telle tôle métallique revêtue |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3861146A1 (fr) |
WO (1) | WO2020069734A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115233129A (zh) * | 2022-07-18 | 2022-10-25 | 首钢京唐钢铁联合有限责任公司 | 一种带钢、带钢热镀锌的控制方法和装置 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0707897B1 (fr) * | 1993-04-28 | 2001-01-03 | Kawasaki Steel Corporation | Procede utilisant la technique de l'essuyage par gaz pour reguler la quantite de placage adherant a un feuillard |
WO2014135753A1 (fr) * | 2013-03-06 | 2014-09-12 | Arcelormittal Investigacion Y Desarrollo, S.L. | Procédé de réalisation d'une tôle à revêtement znal avec un essorage optimisé, tôle, pièce et véhicule correspondants |
CN109844159B (zh) * | 2016-10-17 | 2021-09-07 | 塔塔钢铁艾默伊登有限责任公司 | 用于涂漆零件的钢 |
EP3382054A1 (fr) * | 2017-03-30 | 2018-10-03 | Tata Steel IJmuiden B.V. | Feuille de métal revêtue, procédé pour produire une telle feuille de métal revêtue et dispositif de galvanisation par immersion à chaud pour la fabrication d'une telle feuille de métal revêtue |
-
2018
- 2018-10-02 EP EP18788682.5A patent/EP3861146A1/fr active Pending
- 2018-10-02 WO PCT/EP2018/076874 patent/WO2020069734A1/fr unknown
Also Published As
Publication number | Publication date |
---|---|
WO2020069734A1 (fr) | 2020-04-09 |
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