EP3860553A1 - Fatty alcohol-containing, ethanolic sunscreen with a reduced tendency to stain textiles - Google Patents
Fatty alcohol-containing, ethanolic sunscreen with a reduced tendency to stain textilesInfo
- Publication number
- EP3860553A1 EP3860553A1 EP19769764.2A EP19769764A EP3860553A1 EP 3860553 A1 EP3860553 A1 EP 3860553A1 EP 19769764 A EP19769764 A EP 19769764A EP 3860553 A1 EP3860553 A1 EP 3860553A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- inci
- sunscreen
- preparation
- bis
- diethylamino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000475 sunscreen effect Effects 0.000 title claims abstract description 46
- 239000000516 sunscreening agent Substances 0.000 title claims abstract description 46
- 150000002191 fatty alcohols Chemical class 0.000 title claims abstract description 23
- 239000004753 textile Substances 0.000 title claims abstract description 16
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 claims abstract description 62
- FDATWRLUYRHCJE-UHFFFAOYSA-N diethylamino hydroxybenzoyl hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1O FDATWRLUYRHCJE-UHFFFAOYSA-N 0.000 claims abstract description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229960001630 diethylamino hydroxybenzoyl hexyl benzoate Drugs 0.000 claims abstract description 19
- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004904 UV filter Substances 0.000 claims abstract description 15
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960005193 avobenzone Drugs 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 239000002537 cosmetic Substances 0.000 claims abstract description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims description 60
- -1 2-ethylhexyloxy Chemical group 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 16
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 16
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 15
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 10
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims description 10
- PBFGMXZRJIUGKU-UHFFFAOYSA-N 3-decanoyloxybutyl decanoate Chemical compound CCCCCCCCCC(=O)OCCC(C)OC(=O)CCCCCCCCC PBFGMXZRJIUGKU-UHFFFAOYSA-N 0.000 claims description 7
- LFESLSYSZQYEIZ-UHFFFAOYSA-N 3-octanoyloxybutyl octanoate Chemical compound CCCCCCCC(=O)OCCC(C)OC(=O)CCCCCCC LFESLSYSZQYEIZ-UHFFFAOYSA-N 0.000 claims description 7
- 229940114374 butylene glycol dicaprylate Drugs 0.000 claims description 7
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims description 6
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 6
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 claims description 5
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 5
- 229960000541 cetyl alcohol Drugs 0.000 claims description 5
- 229940043348 myristyl alcohol Drugs 0.000 claims description 5
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 5
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 claims description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 4
- 239000010502 orange oil Substances 0.000 claims description 4
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229940012831 stearyl alcohol Drugs 0.000 claims description 4
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 3
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 3
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 claims description 2
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 claims description 2
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 claims description 2
- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical compound CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 claims description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 2
- 239000001244 (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one Substances 0.000 claims description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 2
- VPKMGDRERYMTJX-XEHSLEBBSA-N (e)-1-[(1r)-2,6,6-trimethylcyclohex-2-en-1-yl]pent-1-en-3-one Chemical compound CCC(=O)\C=C\[C@H]1C(C)=CCCC1(C)C VPKMGDRERYMTJX-XEHSLEBBSA-N 0.000 claims description 2
- OLUJUQKZMDLFII-UHFFFAOYSA-N 1-phenyloct-1-en-3-ol Chemical compound CCCCCC(O)C=CC1=CC=CC=C1 OLUJUQKZMDLFII-UHFFFAOYSA-N 0.000 claims description 2
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 claims description 2
- HMKKIXGYKWDQSV-SDNWHVSQSA-N 2-Pentyl-3-phenyl-2-propenal Chemical compound CCCCC\C(C=O)=C/C1=CC=CC=C1 HMKKIXGYKWDQSV-SDNWHVSQSA-N 0.000 claims description 2
- RRSYNAMOFATAOU-UHFFFAOYSA-N 2-cyano-3-(2-octan-3-ylphenyl)-3-phenylprop-2-enoic acid Chemical compound CCCCCC(CC)C1=CC=CC=C1C(=C(C#N)C(O)=O)C1=CC=CC=C1 RRSYNAMOFATAOU-UHFFFAOYSA-N 0.000 claims description 2
- JRJBVWJSTHECJK-PKNBQFBNSA-N 3-Methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one Chemical compound CC(=O)C(\C)=C\C1C(C)=CCCC1(C)C JRJBVWJSTHECJK-PKNBQFBNSA-N 0.000 claims description 2
- LZRZEWYKODIIJU-UHFFFAOYSA-N 3-hexyl-2-(9-phenylnona-6,8-dienoxy)benzoic acid Chemical compound CCCCCCC1=C(C(=CC=C1)C(=O)O)OCCCCCC=CC=CC2=CC=CC=C2 LZRZEWYKODIIJU-UHFFFAOYSA-N 0.000 claims description 2
- OXYRENDGHPGWKV-UHFFFAOYSA-N 3-methyl-5-phenylpentan-1-ol Chemical compound OCCC(C)CCC1=CC=CC=C1 OXYRENDGHPGWKV-UHFFFAOYSA-N 0.000 claims description 2
- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 claims description 2
- KKJKXQYVUVWWJP-UHFFFAOYSA-N 4-[(4,7,7-trimethyl-3-oxo-2-bicyclo[2.2.1]heptanylidene)methyl]benzenesulfonic acid Chemical class CC1(C)C2CCC1(C)C(=O)C2=CC1=CC=C(S(O)(=O)=O)C=C1 KKJKXQYVUVWWJP-UHFFFAOYSA-N 0.000 claims description 2
- YVSNOTITPICPTB-UHFFFAOYSA-N 4-methyl-2-(2-methylpropyl)oxan-4-ol Chemical compound CC(C)CC1CC(C)(O)CCO1 YVSNOTITPICPTB-UHFFFAOYSA-N 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N Cinnamyl alcohol Natural products OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 claims description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 2
- 244000183685 Citrus aurantium Species 0.000 claims description 2
- 235000007716 Citrus aurantium Nutrition 0.000 claims description 2
- 240000002319 Citrus sinensis Species 0.000 claims description 2
- 235000005976 Citrus sinensis Nutrition 0.000 claims description 2
- YEVACTAGDANHRH-UHFFFAOYSA-N Coniferan Chemical compound CCC(C)(C)C1CCCCC1OC(C)=O YEVACTAGDANHRH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005792 Geraniol Substances 0.000 claims description 2
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 claims description 2
- 235000019501 Lemon oil Nutrition 0.000 claims description 2
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 claims description 2
- 244000028419 Styrax benzoin Species 0.000 claims description 2
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 2
- SLHPMAOXNSLXEH-ZGVCCVRISA-N [(1r,2s,5r)-5-methyl-2-propan-2-ylcyclohexyl] 5-oxopyrrolidine-2-carboxylate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)C1NC(=O)CC1 SLHPMAOXNSLXEH-ZGVCCVRISA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 claims description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 2
- 229940062909 amyl salicylate Drugs 0.000 claims description 2
- 229960002130 benzoin Drugs 0.000 claims description 2
- 239000001518 benzyl (E)-3-phenylprop-2-enoate Substances 0.000 claims description 2
- 229960002903 benzyl benzoate Drugs 0.000 claims description 2
- NGHOLYJTSCBCGC-QXMHVHEDSA-N benzyl cinnamate Chemical compound C=1C=CC=CC=1\C=C/C(=O)OCC1=CC=CC=C1 NGHOLYJTSCBCGC-QXMHVHEDSA-N 0.000 claims description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 2
- DTVQVQGCVNNOSX-UHFFFAOYSA-N bis(2-ethylhexyl) 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound CCCCC(CC)COC(=O)C(C(=O)OCC(CC)CCCC)=CC1=CC=C(OC)C=C1 DTVQVQGCVNNOSX-UHFFFAOYSA-N 0.000 claims description 2
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 claims description 2
- 229940026455 cedrol Drugs 0.000 claims description 2
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 claims description 2
- NGHOLYJTSCBCGC-UHFFFAOYSA-N cis-cinnamic acid benzyl ester Natural products C=1C=CC=CC=1C=CC(=O)OCC1=CC=CC=C1 NGHOLYJTSCBCGC-UHFFFAOYSA-N 0.000 claims description 2
- 229940043350 citral Drugs 0.000 claims description 2
- 235000000484 citronellol Nutrition 0.000 claims description 2
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229960000735 docosanol Drugs 0.000 claims description 2
- HEAHZSUCFKFERC-UHFFFAOYSA-N ecamsule Chemical compound CC1(C)C2CCC1(CS(O)(=O)=O)C(=O)C2=CC(C=C1)=CC=C1C=C1C(=O)C2(CS(O)(=O)=O)CCC1C2(C)C HEAHZSUCFKFERC-UHFFFAOYSA-N 0.000 claims description 2
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 claims description 2
- 229940068171 ethyl hexyl salicylate Drugs 0.000 claims description 2
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- 229930002886 farnesol Natural products 0.000 claims description 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 2
- 229940113087 geraniol Drugs 0.000 claims description 2
- 235000019382 gum benzoic Nutrition 0.000 claims description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 2
- 229960004881 homosalate Drugs 0.000 claims description 2
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 claims description 2
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 claims description 2
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- 229940087305 limonene Drugs 0.000 claims description 2
- 229930007744 linalool Natural products 0.000 claims description 2
- 239000001627 myristica fragrans houtt. fruit oil Substances 0.000 claims description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 2
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- 239000010668 rosemary oil Substances 0.000 claims description 2
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- 229940116411 terpineol Drugs 0.000 claims description 2
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 claims description 2
- ZDHRAACDPXUCHC-UHFFFAOYSA-N 3,4-diethyl-2-hexoxyphenol;5-methoxy-4-phenyltriazine Chemical compound COC1=CN=NN=C1C1=CC=CC=C1.CCCCCCOC1=C(O)C=CC(CC)=C1CC ZDHRAACDPXUCHC-UHFFFAOYSA-N 0.000 claims 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims 2
- KRLBLPBPZSSIGH-CSKARUKUSA-N (6e)-3,7-dimethylnona-1,6-dien-3-ol Chemical compound CC\C(C)=C\CCC(C)(O)C=C KRLBLPBPZSSIGH-CSKARUKUSA-N 0.000 claims 1
- FRGIOIALHUOUTR-UHFFFAOYSA-N 2-[4-(diethylamino)-2-hydroxybenzoyl]hexyl benzoate Chemical compound C=1C=C(N(CC)CC)C=C(O)C=1C(=O)C(CCCC)COC(=O)C1=CC=CC=C1 FRGIOIALHUOUTR-UHFFFAOYSA-N 0.000 claims 1
- ILPBINAXDRFYPL-UHFFFAOYSA-N 2-octene Chemical compound CCCCCC=CC ILPBINAXDRFYPL-UHFFFAOYSA-N 0.000 claims 1
- DCEUMOZSMAUPSP-UHFFFAOYSA-N 3,7-dimethyloct-6-enyl 3-methylbut-2-enoate Chemical compound CC(C)=CCCC(C)CCOC(=O)C=C(C)C DCEUMOZSMAUPSP-UHFFFAOYSA-N 0.000 claims 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 claims 1
- JYJAMZPYEGWUDM-UHFFFAOYSA-N 4-octanoyloxybutyl octanoate Chemical compound CCCCCCCC(=O)OCCCCOC(=O)CCCCCCC JYJAMZPYEGWUDM-UHFFFAOYSA-N 0.000 claims 1
- NXTCUULPOMSLPB-UHFFFAOYSA-N COC(C(O)=O)=CC1=CC=CC=C1.N=C=O Chemical compound COC(C(O)=O)=CC1=CC=CC=C1.N=C=O NXTCUULPOMSLPB-UHFFFAOYSA-N 0.000 claims 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 claims 1
- 241000522215 Dipteryx odorata Species 0.000 claims 1
- 240000002943 Elettaria cardamomum Species 0.000 claims 1
- 239000005770 Eugenol Substances 0.000 claims 1
- 241000004871 Evernia Species 0.000 claims 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims 1
- 235000005300 cardamomo Nutrition 0.000 claims 1
- 229960002217 eugenol Drugs 0.000 claims 1
- 229940079204 evernia prunastri extract Drugs 0.000 claims 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 1
- 235000013769 triethyl citrate Nutrition 0.000 claims 1
- 239000001069 triethyl citrate Substances 0.000 claims 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 claims 1
- 235000012141 vanillin Nutrition 0.000 claims 1
- 238000010186 staining Methods 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 4
- 238000009472 formulation Methods 0.000 abstract description 2
- FQNKTJPBXAZUGC-UHFFFAOYSA-N 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoic acid Chemical compound OC1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O FQNKTJPBXAZUGC-UHFFFAOYSA-N 0.000 abstract 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- HIPQTCQUXOFTFI-UHFFFAOYSA-N 2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)C(=O)C1=CC=CC=C1 HIPQTCQUXOFTFI-UHFFFAOYSA-N 0.000 description 6
- UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 229940081733 cetearyl alcohol Drugs 0.000 description 4
- 229940100539 dibutyl adipate Drugs 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 3
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZUYVPAKYYMBQBT-UHFFFAOYSA-N 3,4-diethyl-2-hexoxyphenol Chemical compound CCCCCCOC1=C(O)C=CC(CC)=C1CC ZUYVPAKYYMBQBT-UHFFFAOYSA-N 0.000 description 1
- AKUPYGILGNUOIG-UHFFFAOYSA-N 5-methoxy-4-phenyltriazine Chemical compound COC1=CN=NN=C1C1=CC=CC=C1 AKUPYGILGNUOIG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000548268 Citrus deliciosa Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 206010033546 Pallor Diseases 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 230000037338 UVA radiation Effects 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009692 acute damage Effects 0.000 description 1
- UBNYRXMKIIGMKK-RMKNXTFCSA-N amiloxate Chemical compound COC1=CC=C(\C=C\C(=O)OCCC(C)C)C=C1 UBNYRXMKIIGMKK-RMKNXTFCSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 210000002808 connective tissue Anatomy 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000001927 guaiacum sanctum l. gum oil Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940089456 isopropyl stearate Drugs 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- JPTOCTSNXXKSSN-UHFFFAOYSA-N methylheptenone Chemical compound CCCC=CC(=O)CC JPTOCTSNXXKSSN-UHFFFAOYSA-N 0.000 description 1
- XANYBGJNPZKYMQ-UHFFFAOYSA-N octan-3-yl 3-(4-methoxyphenyl)prop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C=CC1=CC=C(OC)C=C1 XANYBGJNPZKYMQ-UHFFFAOYSA-N 0.000 description 1
- 231100000760 phototoxic Toxicity 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 201000000849 skin cancer Diseases 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/415—Aminophenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
Definitions
- the present invention relates to an ethanolic cosmetic sunscreen composition
- UV filters selected from the group of compounds 4- (tert-butyl) -4'- methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester ( INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hydroxy] phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine ( INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine),
- UVB range wavelength: 280-320 nm
- UVA radiation wavelength: 320-400 nm
- UVA and UVB filters are in most industrialized countries in the form of positive lists such as Appendix 7 of the
- Cosmetic preparations such as sunscreen preparations which are applied to the skin come into regular contact (intentionally or unintentionally) with items of clothing and laundry items (for example towels) on which they are applied (for example as “abrasion” or because they are “sucked up” by the fibers). partly stick. In this way, depending on the type of ingredients, stains and discolouration occur, especially on light textiles.
- UVA and broadband filters such as 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoylj benzoic acid hexyl ester (INCI: Diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hydroxy] phenyl ⁇ -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: Bis-ethylhexyloxyphenol methoxyphenyl triazine)
- Stains can hardly be removed by washing with conventional detergents and intensify during the washing process through interactions with ions of the
- Methoxydibenzoylmethane (2 - [- 4- (Diethylamino) -2-hydroxybenzoylj benzoic acid hexyl ester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hydroxy ] -phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine).
- an ethanolic, cosmetic sunscreen comprising a) one or more UV filters selected from the group of the compounds 4- (tert-butyl) -4'- methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) - 2-hydroxy] phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine),
- Methoxydibenzoylmethane (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hy- droxy] -phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine), to make it easier to wash out the UV light protection filter with the
- the task is also solved by using fatty alcohols in
- Methoxydibenzoylmethane (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hy- droxy] -phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine), to reduce the textile stains caused by the sunscreen.
- the task is solved not least by a process to facilitate the
- Fatty alcohols can be added.
- fatty alcohols are understood to be linear, unbranched, long-chain primary alcohols with a carbon chain length of 12 to 30 carbon atoms (definition).
- the prior art knows DE 102016220547.1 (also published under
- an “ethanolic sunscreen” is understood to be a sunscreen that contains at least 10% by weight of ethanol, based on the total weight of the preparation. According to the invention, such an ethanolic sunscreen preferably contains from 20 to 75% by weight of ethanol and particularly preferably from 25 to 70% by weight of ethanol, in each case based on the total weight of the preparation.
- formulations “according to the invention”, “according to the invention advantageously” etc. always refer to the sunscreen according to the invention, the uses according to the invention and the method according to the invention, unless it is described differently in the individual case.
- fatty alcohols are cetyl alcohol, stearyl alcohol,
- Behenyl alcohol and / or myristyl alcohol can be used.
- cetostearyl alcohol cetearyl alcohol
- cetearyl alcohol cetearyl alcohol
- the fatty alcohols are present in a total concentration of 0.25% to 10% by weight, based on the total weight of the preparation.
- the total concentration preferred according to the invention is from 0.5% to 6% by weight, based on the total weight of the preparation.
- Embodiments of the present invention which are advantageous according to the invention are characterized in that the total concentration of the UV filters 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) - 2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hydroxy] phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) in the preparation is from 0.5 to 15% by weight, based on the total weight of the preparation. It is preferred according to the invention if the preparation according to the invention if the preparation according
- Methoxydibenzoylmethane (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - ⁇ [4- (2-ethylhexyloxy) -2-hy- droxy] -phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) d) (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: Diethylamino
- Methoxydibenzoylmethane from 1.5 to 5% by weight and for bis-ethylhexyloxyphenol
- Methoxyphenyl triazine from 0.25 to 5% by weight, based in each case on the total weight of the preparation.
- fatty alcohols myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol are preferred according to the invention
- the advantageous use concentration according to the invention for diethylamino hydroxybenzoyl hexyl benzoate is from 0.5 to 10% by weight and for bis-ethylhexyloxyphenol methoxyphenyl triazine from 0.25 to 5% by weight, in each case based on the total weight of the preparation.
- the fatty alcohols myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol are preferably used in a concentration of 0.25 to 10% by weight, based on the total weight of the preparation.
- the advantageous use concentration for butyl is according to the invention
- Methoxydibenzoylmethane from 0.6 to 5% by weight, for diethylamino hydroxybenzoyl hexyl benzoate from 0.5 to 4.9% by weight and for bis-ethylhexyloxyphenol methoxyphenyl triazine from 0.25 to 5% by weight, each based on the total weight of the Preparation.
- the fatty alcohols myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol are preferably used in a concentration of 0.25 to 10% by weight, based on the total weight of the preparation.
- the advantageous use concentration according to the invention for diethylamino hydroxybenzoyl hexyl benzoate is from 0.5 to 10% by weight based on the total weight of the preparation.
- Advantageous embodiments of the present invention are characterized in that the ethanol content of the preparation is from 25 to 70% by weight, based on the total weight of the preparation.
- a preparation is considered transparent if it is possible for
- the preparation does not contain a 3- (4-methylbenzylidene) camphor, 2-hydroxy-4-methoxybenzophenone (INCI: oxybenzone), phenylene-1,4-bis- (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 1, 4-di (2-oxo-10-sulfo-3-bornylidene-methyl) -benzene and its salts; 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid salts; 2-methyl-5- (2-oxo-3-bornylidene methyl) sulfonic acid salts, 3-benzylidene camphor;
- Terephthalic dicampher sulfonic acid 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester; 4-methoxybenzalmalonic acid di (2-ethylhexyl) ester; Contains 4-methoxycinnamic acid isoamyl ester and 4-methoxycinnamic acid ethylhexyl ester, so it is free of these ingredients.
- the preparation contains 2-ethylhexyl 2-hydroxybenzoate (INCI: ethylhexyl salicylate) and / or 3,3, 5-trimethylcyclohexyl 2-hydroxybenzoate (INCI: homosalate).
- preparation according to the invention contains 2-ethylhexyl 2-hydroxybenzoate, its advantageous use concentration according to the invention is from 2.5 to 9% by weight, based on the total weight of the preparation.
- the preparation according to the invention contains 3,3,5-trimethylcyclohexyl 2-hydroxybenzoate, its advantageous use concentration according to the invention is from 3 to 10% by weight, based on the total weight of the preparation.
- Embodiments of the present invention which are advantageous according to the invention are characterized in that the preparation is free from ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: octocrylene). In addition, it is advantageous according to the invention if the preparation according to the invention does not contain octyldodecanol.
- Embodiments of the present invention which are advantageous according to the invention are characterized in that the preparation comprises one or more perfume substances selected from the group consisting of the compounds limonene, citral, linalool, alpha-isomethylionone, geraniol, citronellol, 2-isobutyl-4-hydroxy-4-methyltetrahydropyran, 2 -tert-pentylcyclohexyl acetate, 3-methyl-5-phenyl-1-pentanol, 7-acetyl-1, 1, 3,4,4,6-hexamethyltetralin, adipic acid diester, alpha-amylcinnamaldehyde, alpha-methylionone, amyl C butylphenylmethylpropionalcinnamal,
- the preparation contains acrylates / octylacrylamides copolymer.
- the advantageous amount according to the invention is
- the preparation according to the invention contains less than 3.0% by weight of water, based on the total weight of the preparation.
- Cocoglyceride (INCI Cocoglycerides), Caprylic / Capric Triglyceride (INCI: Caprylic / Capric Triglyceride), C12-15 Contains alkyl benzoate, di-n-butyl adipate and / or butylene glycol dicaprylate / dicaprate (INCI: Butylene Glycol Dicaprylate / Dicaprate).
- test formulas are applied to the stain monitors using PMMA plates (3 mg / cm 2 ). Four spots are created per formula.
- the stains are left to dry overnight.
- the l * , a * and b * values are measured as in 1) and the staining (in particular the b * value) is calculated before or after the washing process.
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- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to an ethanolic cosmetic sunscreen comprising a) one or more UV filters selected from the group of compounds 4-(tert-butyl)-4'- methoxydibenzoylmethane (INCI Butyl Methoxydibenzoylmethane), hexyl (2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) and 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine), b) ethanol in a minimum amount of 10% by weight, based on the total weight of the formulation, c) one or more fatty alcohols, and to the use of the fatty alcohols for reducing the textile staining caused by the sunscreen.
Description
Beschreibung description
Fettalkohol-haltiges, ethanolisches Sonnenschutzmittel mit reduzierter Neigung zur Fatty alcohol-containing, ethanolic sunscreen with a reduced tendency to
Textilverfleckung Textile stains
Die vorliegende Erfindung betrifft ein ethanolisches, kosmetisches Sonnenschutzmittel enthaltend The present invention relates to an ethanolic cosmetic sunscreen composition
a) einen oder mehrere UV-Filter gewählt aus der Gruppe der Verbindungen 4-(tert.-Butyl)-4’- methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2- hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine), a) one or more UV filters selected from the group of compounds 4- (tert-butyl) -4'- methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester ( INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine ( INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine),
b) Ethanol in einer Mindestmenge von 10 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, b) ethanol in a minimum amount of 10% by weight, based on the total weight of the preparation,
c) einen oder mehrere Fettalkohole, c) one or more fatty alcohols,
sowie die Verwendung der Fettalkohole zur Reduzierung der durch das Sonnenschutzmittel ausgelösten Textilverfleckungen. and the use of fatty alcohols to reduce textile stains caused by the sunscreen.
Der Trend weg von der vornehmen Blässe hin zur„gesunden, sportlich braunen Haut“ ist seit Jahren ungebrochen. Um diese zu erzielen setzen die Menschen ihre Haut der The trend away from the elegant pallor towards "healthy, sporty brown skin" has been going on for years. To achieve this, people put their skin on the
Sonnenstrahlung aus, da diese eine Pigmentbildung im Sinne einer Melaninbildung hervorruft. Die ultraviolette Strahlung des Sonnenlichtes hat jedoch auch eine schädigende Wirkung auf die Haut. Neben der akuten Schädigung (Sonnenbrand) treten Langzeitschäden wie ein erhöhtes Risiko an Hautkrebs zu erkranken bei übermäßiger Bestrahlung mit Licht aus dem UVB-Bereich (Wellenlänge: 280-320 nm) auf. Die übermäßige Einwirkung der UVB- und UVA- Strahlung (Wellenlänge: 320-400 nm) führt darüber hinaus zu einer Schwächung der elastischen und kollagenen Fasern des Bindegewebes. Dies führt zu zahlreichen Solar radiation, since this causes pigment formation in the sense of melanin formation. However, the ultraviolet radiation from sunlight also has a damaging effect on the skin. In addition to acute damage (sunburn), long-term damage such as an increased risk of developing skin cancer occurs with excessive exposure to light from the UVB range (wavelength: 280-320 nm). The excessive exposure to UVB and UVA radiation (wavelength: 320-400 nm) also leads to a weakening of the elastic and collagen fibers of the connective tissue. This leads to numerous
phototoxischen und photoallergischen Reaktionen und hat eine vorzeitige Hautalterung zur Folge. phototoxic and photoallergic reactions and results in premature skin aging.
Zum Schutz der Haut wurde daher eine Reihe von Lichtschutzfiltersubstanzen entwickelt, die in kosmetischen Zubereitungen eingesetzt werden können. Diese UVA- und UVB-Filter sind in
den meisten Industrieländern in Form von Positivlisten wie dem Anlage 7 der To protect the skin, a number of light protection filter substances have therefore been developed that can be used in cosmetic preparations. These UVA and UVB filters are in most industrialized countries in the form of positive lists such as Appendix 7 of the
Kosmetikverordnung zusammengefasst. Cosmetics regulation summarized.
Die Vielzahl an kommerziell erhältlichen Sonnenschutzmitteln darf jedoch nicht darüber hinwegtäuschen, dass diese Zubereitungen des Standes der Technik eine Reihe von However, the large number of commercially available sunscreens must not hide the fact that these preparations of the prior art are a number of
Nachteilen aufweisen. Have disadvantages.
Kosmetische Zubereitungen wie Sonnenschutzzubereitungen, die auf die Haut aufgetragen werden, kommen regelmäßig (beabsichtigt oder unbeabsichtigt) mit Kleidungsstücken und Wäschestücken (z.B. Handtücher) in Kontakt, an denen sie (z.B. als„Abrieb“ oder weil sie von den Faserstoffen„aufgesaugt“ werden) zum Teil haften bleiben. Auf diese Weise entstehen, je nach Art der Inhaltsstoffe, insbesondere auf hellen Textilien Flecken und Verfärbungen. Diese Verfärbungen werden insbesondere durch nicht-wasserlösliche UVA- und Breitbandfilter wie 4- (tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4- (Diethylamino)-2-hydroxybenzoylj Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)- 1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) hervorgerufen. Die Cosmetic preparations such as sunscreen preparations which are applied to the skin come into regular contact (intentionally or unintentionally) with items of clothing and laundry items (for example towels) on which they are applied (for example as “abrasion” or because they are “sucked up” by the fibers). partly stick. In this way, depending on the type of ingredients, stains and discolouration occur, especially on light textiles. These discolorations are caused in particular by non-water-soluble UVA and broadband filters such as 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoylj benzoic acid hexyl ester (INCI: Diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: Bis-ethylhexyloxyphenol methoxyphenyl triazine)
Verfleckungen sind durch Waschen mit herkömmlichen Waschmitteln kaum zu entfernen und verstärken sich während des Waschprozesses durch Wechselwirkungen mit Ionen des Stains can hardly be removed by washing with conventional detergents and intensify during the washing process through interactions with ions of the
Waschwassers sogar noch. Wash water even more.
Zwar wurde in jüngerer Zeit eine Reihe von Lösungswegen entwickelt, dieses A number of possible solutions have been developed recently, this
Textilverfleckungsproblem durch die Auswahl bestimmter Inhaltsstoffe für Sonnenschutzmittel in den Griff zu bekommen. Nachteilig an diesen Lösungen ist jedoch der Umstand, dass sie nur in Emulsionssystemen wirksam sind, bei Gelen und Sprays auf Ethanol-Basis jedoch versagen.Get a grip on textile staining problems by selecting certain ingredients for sunscreens. A disadvantage of these solutions, however, is the fact that they are only effective in emulsion systems, but fail with gels and sprays based on ethanol.
Da diese meist transparenten Sonnenschutzmittel sich jedoch beim Verbraucher wachsender Beliebtheit erfreuen, war es die Aufgabe der vorliegenden Erfindung, ein solches ethanolisches Sonnenschutzmittel mit reduzierter Neigung zur Textilverfleckung zu entwickeln. Insbesondere war es die Aufgabe ein Sonnenschutzmittel auf Ethanol-Basis mit reduzierter Textilverfleckung zu entwickeln, welches einen oder mehrere UV-Filter gewählt aus der Gruppe der However, since these mostly transparent sunscreens are becoming increasingly popular with consumers, it was the object of the present invention to develop such an ethanolic sunscreen with a reduced tendency to stain textiles. In particular, the task was to develop an ethanol-based sunscreen with reduced textile staining, which selected one or more UV filters from the group of
Verbindungen 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Compounds 4- (tert-butyl) -4’-methoxydibenzoylmethane (INCI butyl
Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2-hydroxybenzoylj Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hy- droxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) enthält. Methoxydibenzoylmethane), (2 - [- 4- (Diethylamino) -2-hydroxybenzoylj benzoic acid hexyl ester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy ] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine).
Gelöst wird die Aufgabe durch ein ethanolisches, kosmetisches Sonnenschutzmittel enthaltend a) einen oder mehrere UV-Filter gewählt aus der Gruppe der Verbindungen 4-(tert.-Butyl)-4’-
methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2- hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), The object is achieved by an ethanolic, cosmetic sunscreen comprising a) one or more UV filters selected from the group of the compounds 4- (tert-butyl) -4'- methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) - 2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine),
b) Ethanol in einer Mindestmenge von 10 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, b) ethanol in a minimum amount of 10% by weight, based on the total weight of the preparation,
c) einen oder mehrere Fettalkohole. c) one or more fatty alcohols.
Gelöst wird die Aufgabe ferner durch die Verwendung von Fettalkoholen in ethanolischen, kosmetischen Sonnenschutzmitteln enthaltend einen oder mehrere UV-Filter aus der Gruppe der Verbindungen 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl The problem is also solved by the use of fatty alcohols in ethanolic, cosmetic sunscreens containing one or more UV filters from the group of compounds 4- (tert-butyl) -4’-methoxydibenzoylmethane (INCI butyl
Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hy- droxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), zur Erleichterung der Auswaschbarkeit der UV-Lichtschutzfilter aus mit dem Methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hy- droxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine), to make it easier to wash out the UV light protection filter with the
Sonnenschutzmittel kontaminierten Textilien. Sunscreen contaminated textiles.
Gelöst wird die Aufgabe darüber hinaus durch die Verwendung von Fettalkoholen in The task is also solved by using fatty alcohols in
ethanolischen, kosmetischen Sonnenschutzmitteln enthaltend einen oder mehrere UV-Filter aus der Gruppe der Verbindungen 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl ethanolic, cosmetic sunscreens containing one or more UV filters from the group of compounds 4- (tert-butyl) -4’-methoxydibenzoylmethane (INCI butyl
Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hy- droxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), zur Reduzierung der durch das Sonnenschutzmittel ausgelösten Textilverfleckungen. Methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hy- droxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine), to reduce the textile stains caused by the sunscreen.
Gelöst wird die Aufgabe nicht zuletzt durch ein Verfahren zur Erleichterung der The task is solved not least by a process to facilitate the
Auswaschbarkeit von UV-Filter-Rückständen aus Textilien, die mit einem ethanolischen, kosmetischen Sonnenschutzmittel kontaminiert wurden, wobei dem ethanolischem Washability of UV filter residues from textiles that have been contaminated with an ethanolic, cosmetic sunscreen, the ethanolic
Sonnenschutzmittel enthaltend einen oder mehrere UV-Filter aus der Gruppe der Verbindungen 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2- [-4- (Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)- 1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), ein oder mehrere Sunscreen containing one or more UV filters from the group of the compounds 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2- [-4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI : Diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI : Bis-ethylhexyloxyphenol methoxyphenyl triazine), one or more
Fettalkohole zugesetzt werden. Fatty alcohols can be added.
Als Fettalkohole werden erfindungsgemäß linear-unverzweigte, langkettige primäre Alkohole mit einer Kohlenstoff-Kettenlänge von 12 bis 30 C-Atomen verstanden (Definition).
Zwar kennt der Stand der Technik die DE 102016220547.1 (auch veröffentlicht unter According to the invention, fatty alcohols are understood to be linear, unbranched, long-chain primary alcohols with a carbon chain length of 12 to 30 carbon atoms (definition). The prior art knows DE 102016220547.1 (also published under
EP3311791 ), welche ethanolische Sonnenschutzmittel mit Ölkomponenten mit einem EP3311791), which ethanolic sunscreen with oil components with a
Kontaktwinkel von größer/gleich 44° zur Reduzierung der Textilverfleckung offenbart, doch konnte diese Schrift nicht den Weg zur vorliegenden Erfindung weisen, da die dort offenbarten Zubereitungen Octyldodecanol enthalten, eine sekundäre Alkoholverbindung, die (siehe Vergleichsversuche) signifikant stärkere Textilflecken zeigt. Contact angle of greater than or equal to 44 ° to reduce the staining of textiles was disclosed, but this document could not point the way to the present invention, since the preparations disclosed therein contain octyldodecanol, a secondary alcohol compound which (see comparative experiments) shows significantly stronger textile stains.
Darüber hinaus kennt der Stand der Technik die EP2288416, FR 2976178, WO2017/140442, WO 2012/149355 und DE 102013215831 , die ebenfalls nicht den Weg zur vorliegenden Erfindung weisen konnten. In addition, the prior art knows EP2288416, FR 2976178, WO2017 / 140442, WO 2012/149355 and DE 102013215831, which likewise could not point the way to the present invention.
Als„ethanolisches Sonnenschutzmittel“ wird im Rahmen der vorliegenden Erfindung ein Sonnenschutzmittel verstanden, dass mindestens 10 Gewichts-% Ethanol, bezogen auf das Gesamtgewicht der Zubereitung, enthält. Erfindungsgemäß bevorzugt enthält ein solches ethanolisches Sonnenschutzmittel von 20 bis 75 Gewichts-% Ethanol und besonders bevorzugt von 25 bis 70 Gewichts-% Ethanol, jeweils bezogen auf das Gesamtgewicht der Zubereitung. In the context of the present invention, an “ethanolic sunscreen” is understood to be a sunscreen that contains at least 10% by weight of ethanol, based on the total weight of the preparation. According to the invention, such an ethanolic sunscreen preferably contains from 20 to 75% by weight of ethanol and particularly preferably from 25 to 70% by weight of ethanol, in each case based on the total weight of the preparation.
Die Formulierungen„erfindungsgemäß“,„erfindungsgemäß vorteilhaft“ etc. beziehen sich im Rahmen der vorliegenden Offenbarung immer auf das erfindungsgemäße Sonnenschutzmittel, die erfindungsgemäßen Verwendungen und das erfindungsgemäße Verfahren, wenn es im Einzelfall nicht anders beschrieben wird. Within the scope of the present disclosure, the formulations “according to the invention”, “according to the invention advantageously” etc. always refer to the sunscreen according to the invention, the uses according to the invention and the method according to the invention, unless it is described differently in the individual case.
Es ist erfindungsgemäß vorteilhaft, wenn als Fettakohole Cetylalkohol, Stearylalkohol, It is advantageous according to the invention if the fatty alcohols are cetyl alcohol, stearyl alcohol,
Behenylalkohol und/oder Myristylalkohol eingesetzt werden. Als Mischung kann beispielsweise Cetostearylalkohol (=Cetearylalkohol) eingesetzt werden. Behenyl alcohol and / or myristyl alcohol can be used. For example, cetostearyl alcohol (= cetearyl alcohol) can be used as a mixture.
Dabei ist es erfindungsgemäß von Vorteil, wenn die Fettalkohole in einer Gesamtkonzentration von 0.25% bis 10% Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, in dieser enthalten sind. Die erfindungsgemäß bevorzugte Gesamtkonzentration beträgt dabei von 0.5% bis 6% Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung. It is advantageous according to the invention if the fatty alcohols are present in a total concentration of 0.25% to 10% by weight, based on the total weight of the preparation. The total concentration preferred according to the invention is from 0.5% to 6% by weight, based on the total weight of the preparation.
Erfindungsgemäß vorteilhafte Ausführungsformen der vorliegenden Erfindung sind dadurch gekennzeichnet, dass die Gesamtkonzentration an den UV-Filtern 4-(tert.-Butyl)-4’-methoxydi- benzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2- hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) in der Zubereitung von 0,5 bis 15 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, beträgt.
Es ist erfindungsgemäß bevorzugt, wenn die erfindungsgemäße Zubereitung Embodiments of the present invention which are advantageous according to the invention are characterized in that the total concentration of the UV filters 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) - 2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) in the preparation is from 0.5 to 15% by weight, based on the total weight of the preparation. It is preferred according to the invention if the preparation according to the invention
a) entweder eine Kombination aus 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4- methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin a) either a combination of 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine
oder or
b) eine Kombination aus (2-[-4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxyj- phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) b) a combination of (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2- hydroxyj-phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine)
oder or
c) eine Kombination aus 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl c) a combination of 4- (tert-butyl) -4’-methoxydibenzoylmethane (INCI butyl
Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hy- droxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) enthält. d) (2-[-4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hy- droxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) d) (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: Diethylamino
Hydroxybenzoyl Hexyl Benzoate) ohne 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4- methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) enthält. Hydroxybenzoyl hexyl benzoate) without 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} - 6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine).
Im Falle a) ist beträgt die erfindungsgemäß vorteilhafte Einsatzkonzentration für Butyl In case a), the advantageous use concentration for butyl is according to the invention
Methoxydibenzoylmethane von 1.5 bis 5 Gewichts-% und für Bis-Ethylhexyloxyphenol Methoxydibenzoylmethane from 1.5 to 5% by weight and for bis-ethylhexyloxyphenol
Methoxyphenyl Triazin von 0.25 bis 5 Gewichts-%, jeweils bezogen auf das Gesamtgewicht der Zubereitung. Methoxyphenyl triazine from 0.25 to 5% by weight, based in each case on the total weight of the preparation.
Für diese Kombination werden erfindungsgemäß bevorzugt die Fettalkohole Myristylalkohol, Cetylalkohol, Cetearylalkohol, Stearylalkohol For this combination, the fatty alcohols myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol are preferred according to the invention
in einer Konzentration von 0,25 bis 10 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung eingesetzt. used in a concentration of 0.25 to 10% by weight, based on the total weight of the preparation.
Im Falle b) ist beträgt die erfindungsgemäß vorteilhafte Einsatzkonzentration für Diethylamino Hydroxybenzoyl Hexyl Benzoate von 0,5 bis 10 Gewichts-% und für Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin von 0,25 bis 5 Gewichts-%, jeweils bezogen auf das Gesamtgewicht der Zubereitung. In case b), the advantageous use concentration according to the invention for diethylamino hydroxybenzoyl hexyl benzoate is from 0.5 to 10% by weight and for bis-ethylhexyloxyphenol methoxyphenyl triazine from 0.25 to 5% by weight, in each case based on the total weight of the preparation.
Für diese Kombination werden erfindungsgemäß bevorzugt die Fettalkohole Myristylalkohol, Cetylalkohol, Cetearylalkohol, Stearylalkohol in einer Konzentration von 0,25 bis 10 Gewichts- %, bezogen auf das Gesamtgewicht der Zubereitung eingesetzt.
Im Falle c) ist beträgt die erfindungsgemäß vorteilhafte Einsatzkonzentration für Butyl For this combination, the fatty alcohols myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol are preferably used in a concentration of 0.25 to 10% by weight, based on the total weight of the preparation. In case c), the advantageous use concentration for butyl is according to the invention
Methoxydibenzoylmethane von 0,6 bis 5 Gewichts-%, für Diethylamino Hydroxybenzoyl Hexyl Benzoate von 0,5 bis 4,9 Gewichts-% und für Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin von 0,25 bis 5 Gewichts-%, jeweils bezogen auf das Gesamtgewicht der Zubereitung. Methoxydibenzoylmethane from 0.6 to 5% by weight, for diethylamino hydroxybenzoyl hexyl benzoate from 0.5 to 4.9% by weight and for bis-ethylhexyloxyphenol methoxyphenyl triazine from 0.25 to 5% by weight, each based on the total weight of the Preparation.
Für diese Kombination werden erfindungsgemäß bevorzugt die Fettalkohole Myristylalkohol, Cetylalkohol, Cetearylalkohol, Stearylalkohol in einer Konzentration von 0,25 bis 10 Gewichts- %, bezogen auf das Gesamtgewicht der Zubereitung eingesetzt. For this combination, the fatty alcohols myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol are preferably used in a concentration of 0.25 to 10% by weight, based on the total weight of the preparation.
Im Fall d) ist beträgt die erfindungsgemäß vorteilhafte Einsatzkonzentration für Diethylamino Hydroxybenzoyl Hexyl Benzoate von 0,5 bis 10 Gewichts-% bezogen auf das Gesamtgewicht der Zubereitung. In case d) the advantageous use concentration according to the invention for diethylamino hydroxybenzoyl hexyl benzoate is from 0.5 to 10% by weight based on the total weight of the preparation.
Vorteilhafte Ausführungsformen der vorliegenden Erfindung sind dadurch gekennzeichnet, dass der Ethanolgehalt der Zubereitung von 25 bis 70 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, beträgt. Advantageous embodiments of the present invention are characterized in that the ethanol content of the preparation is from 25 to 70% by weight, based on the total weight of the preparation.
Es ist darüber hinaus erfindungsgemäß besonders vorteilhaft, wenn das ethanolische It is also particularly advantageous according to the invention if the ethanolic
Sonnenschutzmittel transparent ist. Sunscreen is transparent.
Dabei gilt eine Zubereitung erfindungsgemäß als transparent, wenn es möglich ist bei According to the invention, a preparation is considered transparent if it is possible for
Tageslicht durch eine mit der erfindungsgemäßen Zubereitung gefüllten Einmal-Küvette (Firma Brand, 2,5ml, Wellenlängenbereich: 220nm-900nm) mit dem bloßen Auge zu schauen. To see daylight with the naked eye through a disposable cuvette filled with the preparation according to the invention (Brand, 2.5 ml, wavelength range: 220 nm-900 nm).
Schriftzeichen (Schrifttyp Arial Schriftgröße 8), die sich unmittelbar hinter der Einmal-Küvette befinden, müssen klar erkennbar und lesbar sein. Characters (Arial font size 8) that are immediately behind the disposable cuvette must be clearly recognizable and legible.
Vorteilhaft im Sinne der vorliegenden Erfindung ist es auch, wenn die Zubereitung kein 3-(4- Methylbenzyliden)-campher, 2-Hydroxy-4-methoxybenzophenon (INCI: Oxybenzon), Phenylen- 1 ,4-bis-(2-benzimidazyl)-3,3’-5,5’-tetrasulfonsäuresalze; 1 ,4-di(2-oxo-10-Sulfo-3-bornyliden- methyl)-Benzol und dessen Salze; 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäuresalze; 2- Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäuresalze, 3-Benzylidencampher; It is also advantageous in the sense of the present invention if the preparation does not contain a 3- (4-methylbenzylidene) camphor, 2-hydroxy-4-methoxybenzophenone (INCI: oxybenzone), phenylene-1,4-bis- (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 1, 4-di (2-oxo-10-sulfo-3-bornylidene-methyl) -benzene and its salts; 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid salts; 2-methyl-5- (2-oxo-3-bornylidene methyl) sulfonic acid salts, 3-benzylidene camphor;
Terephthalidendicampher-sulfonsäure; 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester; 4- Methoxybenzalmalon-säuredi(2-ethylhexyl)ester; 4-Methoxyzimtsäure-isoamylester und 4- Methoxyzimtsäureethylhexylester enthält, also frei von diesen Inhaltsstoffen ist. Terephthalic dicampher sulfonic acid; 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester; 4-methoxybenzalmalonic acid di (2-ethylhexyl) ester; Contains 4-methoxycinnamic acid isoamyl ester and 4-methoxycinnamic acid ethylhexyl ester, so it is free of these ingredients.
Hingegen sind die erfindungsgemäß vorteilhaften Ausführungsformen der vorliegenden In contrast, the advantageous embodiments of the present invention
Erfindung dadurch gekennzeichnet, dass die Zubereitung 2-Ethylhexyl 2-hydroxybenzoat (INCI: Ethylhexyl Salicylate) und/oder 3,3, 5-Trimethylcyclohexyl 2-hydroxybenzoat (INCI: Homosalate) enthält.
Enthält die erfindungsgemäße Zubereitung 2-Ethylhexyl 2-hydroxybenzoat, so beträgt dessen erfindungsgemäß vorteilhafte Einsatzkonzentration von 2,5 bis 9 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung. Invention characterized in that the preparation contains 2-ethylhexyl 2-hydroxybenzoate (INCI: ethylhexyl salicylate) and / or 3,3, 5-trimethylcyclohexyl 2-hydroxybenzoate (INCI: homosalate). If the preparation according to the invention contains 2-ethylhexyl 2-hydroxybenzoate, its advantageous use concentration according to the invention is from 2.5 to 9% by weight, based on the total weight of the preparation.
Enthält die erfindungsgemäße Zubereitung 3,3,5-Trimethylcyclohexyl 2-hydroxybenzoat, so beträgt dessen erfindungsgemäß vorteilhafte Einsatzkonzentration von 3 bis 10 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung. If the preparation according to the invention contains 3,3,5-trimethylcyclohexyl 2-hydroxybenzoate, its advantageous use concentration according to the invention is from 3 to 10% by weight, based on the total weight of the preparation.
Erfindungsgemäß vorteilhafte Ausführungsformen der vorliegenden Erfindung sind dadurch gekennzeichnet, dass die Zubereitung frei ist von Ethylhexyl-2-cyano-3,3-diphenylacrylat (INCI: Octocrylen). Darüber hinaus ist es erfindungsgemäß von Vorteil, wenn die erfindungsgemäße Zubereitung kein Octyldodecanol enthält. Embodiments of the present invention which are advantageous according to the invention are characterized in that the preparation is free from ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: octocrylene). In addition, it is advantageous according to the invention if the preparation according to the invention does not contain octyldodecanol.
Erfindungsgemäß vorteilhafte Ausführungsformen der vorliegenden Erfindung sind dadurch gekennzeichnet, dass die Zubereitung einen oder mehrere Parfümstoffe gewählt aus der Gruppe der Verbindungen Limonen, Citral, Linalool, alpha-lsomethylionon, Geraniol, Citronellol, 2-lsobutyl-4-hydroxy-4-methyltetrahydropyran, 2-tert-Pentylcyclohexylacetat, 3-Methyl-5-phenyl- 1-pentanol, 7-Acetyl-1 ,1 ,3,4,4,6-hexamethyltetralin, Adipinsäurediester, alpha- Amylcinnamaldehyd, Alpha-Methylionon, Amyl C Butylphenylmethylpropionalcinnamal, Embodiments of the present invention which are advantageous according to the invention are characterized in that the preparation comprises one or more perfume substances selected from the group consisting of the compounds limonene, citral, linalool, alpha-isomethylionone, geraniol, citronellol, 2-isobutyl-4-hydroxy-4-methyltetrahydropyran, 2 -tert-pentylcyclohexyl acetate, 3-methyl-5-phenyl-1-pentanol, 7-acetyl-1, 1, 3,4,4,6-hexamethyltetralin, adipic acid diester, alpha-amylcinnamaldehyde, alpha-methylionone, amyl C butylphenylmethylpropionalcinnamal,
Amylsalicylat, Amylcinnamylalkohol, Anisalkohol, Benzoin, Benzylalkohol, Benzylbenzoat, Benzylcinnamat, Benzylsalicylat, Bergamotöl, bitteres Orangenöl, Butylphenylmethylpropioal, Cardamomöl, Cedrol, Cinnamal, Cinnamylalkohol, Citronellylmethylcrotonat, Citronenöl, Coumarin, Diethylsuccinat, Ethyllinalool, Eugenol, Evernia Furfuracea Extract, Evernia Prunastri Extract, Farnesol, Guajakholzöl, Hexylcinnamal, Hexylsalicylat, Hydroxycitronellal, Lavendelöl, Lemonenöl, Linaylacetat, Mandarinenöl, Menthyl PCA, Methylheptenon, Muskatnussöl, Rosma- rinöl, süßes Orangenöl, Terpineol, Tonkabohnenöl, Triethylcitrat und/oder Vanillin enthält. Amyl salicylate, amyl cinnamyl alcohol, anise alcohol, benzoin, benzyl alcohol, benzyl benzoate, benzyl cinnamate, benzyl salicylate, bergamot oil, bitter orange oil, butylphenylmethylpropioal, cardamomoline oil, cedrol, cinnamal, cinnamyl alcohol, citotonatoloalolinolethyl, citronatolinolinolethyl, citronatoluronol , Farnesol, Guaiac wood oil, Hexylcinnamal, Hexylsalicylat, Hydroxycitronellal, Lavender oil, Lemon oil, Linaylacetat, Mandarine oil, Menthyl PCA, Methylheptenon, Nutmeg oil, Rosemary oil, Sweet orange oil, Terpineol, Toncabin oil and Triethyl contains.
Außerdem ist es erfindungsgemäß vorteilhaft, wenn die Zubereitung Acrylates/Octylacrylamide Copolymer enthält. In einem solchen Falle beträgt die erfindungsgemäß vorteilhafte It is also advantageous according to the invention if the preparation contains acrylates / octylacrylamides copolymer. In such a case, the advantageous amount according to the invention is
Einsatzkonzentration von 0,5 bis 4 Gewichts-%, bezogen auf das Gesamtgewicht der Use concentration of 0.5 to 4% by weight, based on the total weight of the
Zubereitung. Preparation.
Es ist erfindungsgemäß von Vorteil, wenn die erfindungsgemäße Zubereitung weniger als 3,0 Gewichts-% Wasser, bezogen auf das Gesamtgewicht der Zubereitung enthält. It is advantageous according to the invention if the preparation according to the invention contains less than 3.0% by weight of water, based on the total weight of the preparation.
Nicht zuletzt ist es erfindungsgemäß vorteilhaft, wenn die Zubereitung Cocoglyceride (INCI Cocoglycerides), Capryl/Caprinsäuretriglyceride (INCI: Caprylic/Capric Triglyceride), C12-15
Alkylbenzoat, Di-n-Butyladipat und/oder Butylenglycol Dicaprylate/Dicaprate (INCI: Butylene Glycol Dicaprylate/Dicaprate) enthält.
Last but not least, it is advantageous according to the invention if the preparation Cocoglyceride (INCI Cocoglycerides), Caprylic / Capric Triglyceride (INCI: Caprylic / Capric Triglyceride), C12-15 Contains alkyl benzoate, di-n-butyl adipate and / or butylene glycol dicaprylate / dicaprate (INCI: Butylene Glycol Dicaprylate / Dicaprate).
Vergleichsversuch Comparison test
Mit den folgenden Vergleichsversuchen konnte die positive Wirkung der Fettalkohole auf die Textilverfleckung gezeigt werden: The following comparative experiments were able to show the positive effect of fatty alcohols on textile staining:
Durchführung des Waschversuchs Carrying out the washing test
Fleckenmonitor: Stain monitor:
Trockene, vorgewaschene Baumwolllappen Dry, pre-washed cotton rags
1 ) Die Versuchsformeln werden mithilfe von PMMA-Platten auf die Fleckenmonitore appliziert (3mg/ cm2). Pro Formel werden vier Flecken erzeugt. 1) The test formulas are applied to the stain monitors using PMMA plates (3 mg / cm 2 ). Four spots are created per formula.
Die Flecken werden über Nacht trocknen gelassen. The stains are left to dry overnight.
2) Mithilfe eines Spectralflash 600 (Datacolor International) werden die I*-, a*- und b*- Werte sowohl des nicht befleckten Baumwolllappens als auch die der getrockneten Flecken aufgenommen. 2) Using a Spectralflash 600 (Datacolor International), the I * , a * and b * values of both the non-stained cotton rag and those of the dried stains are recorded.
3) Die Baumwolllappen werden in einer Waschmaschine mit sauberer Beiladung gewaschen (60°C; 2h Baumwollprogramm). Pro Waschgang werden 75g festes Vollwaschmittel verwendet. 3) The cotton rags are washed in a washing machine with a clean load (60 ° C; 2-hour cotton program). 75g solid detergent are used per wash.
4) Nachdem sie über Nacht getrocknet sind, werden wie unter 1 ) die l*-,a*- und b*- Werte gemessen und die Verfleckung (insbesondere der b*Wert) vor, bzw. nach dem Waschvorgang berechnet.
4) After they have dried overnight, the l * , a * and b * values are measured as in 1) and the staining (in particular the b * value) is calculated before or after the washing process.
Ethanolisches Gel: Ethanolic gel:
*= alle Zubereitungen enthielten jewei s die gleichen Mengen an Dibutyl Adipate, Cocoglycerides, * = all preparations contained the same amounts of dibutyl adipate, cocoglycerides,
C12-15 Alkyl benzoate und Butylene Glycol Dicaprylate/Dicaprate Ergebnisse siehe auch Abbildung 1
C12-15 alkyl benzoate and butylene glycol dicaprylate / dicaprate results see also Figure 1
Ethanolisches Spray: Ethanolic spray:
*= alle Zubereitungen enthielten jeweils die gleichen Mengen an Dibutyl Adipate, Cocoglycerides, C12-15 Alkyl benzoate und Butylene Glycol Dicaprylate/Dicaprate * = all preparations contained the same amounts of dibutyl adipate, cocoglycerides, C12-15 alkyl benzoate and butylene glycol dicaprylate / dicaprate
Ergebnisse siehe auch Abbildung 2
Results see also Figure 2
Beispiele Examples
Die nachfolgenden Beispiele sollen die vorliegende Erfindung verdeutlichen, ohne sie einzu- schränken. Alle Mengenangaben, Anteile und Prozentanteile sind, soweit nicht anders an- gegeben, auf das Gewicht und die Gesamtmenge bzw. auf das Gesamtgewicht der Zube- reitungen bezogen. The following examples are intended to illustrate the present invention without restricting it. Unless otherwise stated, all quantities, proportions and percentages are based on the weight and the total quantity or on the total weight of the preparations.
Ethanolisches Spray: Ethanolic spray:
*= alle Zubereitungen enthielten jeweils die gleichen Mengen an Dibutyl Adipate, Cocoglycerides, C12-15 Alkyl benzoate und Butylene Glycol Dicaprylate/Dicaprate * = all preparations contained the same amounts of dibutyl adipate, cocoglycerides, C12-15 alkyl benzoate and butylene glycol dicaprylate / dicaprate
Ethanolisches Gel: Ethanolic gel:
*= alle Zubereitungen enthielten jeweils die gleichen Mengen an Cocoglycerides, Isopropyl Stearate
Ethanolisches Gel: * = all preparations contained the same amounts of cocoglycerides, isopropyl stearate Ethanolic gel:
*= alle Zubereitungen enthielten jeweils die gleichen Mengen an Dibutyl Adipate, Cocoglycerides, C12-15 Alkyl benzoate und Butylene Glycol Dicaprylate/Dicaprate
* = all preparations contained the same amounts of dibutyl adipate, cocoglycerides, C12-15 alkyl benzoate and butylene glycol dicaprylate / dicaprate
Claims
1. Ethanolisches, kosmetisches Sonnenschutzmittel enthaltend 1. Containing ethanolic, cosmetic sunscreen
a) einen oder mehrere UV-Filter gewählt aus der Gruppe der Verbindungen 4-(tert.- Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4- (Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino a) one or more UV filters selected from the group of the compounds 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester ( INCI: Diethylamino
Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}- 6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), Hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} - 6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: Bis -Ethylhexyloxyphenol methoxyphenyl triazine),
b) Ethanol in einer Mindestmenge von 10 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, b) ethanol in a minimum amount of 10% by weight, based on the total weight of the preparation,
c) einen oder mehrere Fettalkohole. c) one or more fatty alcohols.
2. Verwendung von Fettalkoholen in ethanolischen, kosmetischen Sonnenschutzmitteln enthaltend einen oder mehrere UV-Filter aus der Gruppe der Verbindungen 4-(tert.- Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4- (Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino 2. Use of fatty alcohols in ethanolic, cosmetic sunscreens containing one or more UV filters from the group of compounds 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino ) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino
Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}- 6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), zur Erleichterung der Auswaschbarkeit der UV-Lichtschutzfilter aus mit dem Sonnenschutzmittel kontaminierten Textilien. Hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} - 6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: Bis -Ethylhexyloxyphenol Methoxyphenyl Triazin), to make it easier to wash out the UV light protection filter from textiles contaminated with the sunscreen.
3. Verwendung von Fettalkoholen in ethanolischen, kosmetischen Sonnenschutzmitteln enthaltend einen oder mehrere UV-Filter aus der Gruppe der Verbindungen 4-(tert.- Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4- (Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino 3. Use of fatty alcohols in ethanolic, cosmetic sunscreens containing one or more UV filters from the group of compounds 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (diethylamino ) -2-hydroxybenzoyl] benzoic acid hexyl ester (INCI: diethylamino
Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}- 6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), zur Reduzierung der durch das Sonnenschutzmittel ausgelösten Hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} - 6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: Bis -Ethylhexyloxyphenol Methoxyphenyl Triazin), to reduce the amount of sunscreen
T extilverfleckungen T exquisite stains
4. Verfahren zur Erleichterung der Auswaschbarkeit von UV-Filter-Rückständen aus 4. Process to facilitate the wash-out of UV filter residues
Textilien, die mit einem ethanolischen, kosmetischen Sonnenschutzmittel kontaminiert wurden, wobei dem ethanolischem Sonnenschutzmittel enthaltend einen oder mehrere UV-Filter aus der Gruppe der Verbindungen 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[-4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) und 2,4- Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin), ein oder mehrere Fettalkohole zugesetzt werden.
Textiles that have been contaminated with an ethanolic, cosmetic sunscreen, the ethanolic sunscreen containing one or more UV filters from the group of compounds 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2- [-4- (Diethylamino) -2-hydroxybenzoyl] hexanoate (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate) and 2,4- bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine), one or more fatty alcohols can be added.
5. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass als Fettakohole Cetylalkohol, Stearylalkohol, Behenylalkohol und/oder Myristylalkohol eingesetzt werden. 5. Sunscreen, method or use according to one of the preceding claims, characterized in that cetyl alcohol, stearyl alcohol, behenyl alcohol and / or myristyl alcohol are used as fatty alcohols.
6. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 6. Sunscreen, method or use according to any of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Fettalkohole in einer Claims, characterized in that the fatty alcohols in one
Gesamtkonzentration von 0,25 bis 10 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, in dieser enthalten sind. Total concentration of 0.25 to 10% by weight, based on the total weight of the preparation, is contained therein.
7. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 7. Sunscreen, method or use according to any of the preceding
Ansprüche, dadurch gekennzeichnet, dass der Ethanolgehalt der Zubereitung 20 von bis 75 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, beträgt. Claims, characterized in that the ethanol content of the preparation 20 is from up to 75% by weight, based on the total weight of the preparation.
8. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Gesamtkonzentration an den UV-Filtern 4-(tert.-Butyl)-4’-methoxydibenzoylmethan (INCI Butyl Methoxydibenzoylmethane), (2-[- 4-(Diethylamino)-2-hydroxybenzoyl] Benzoesäurehexylester (INCI: Diethylamino 8. Sunscreen, process or use according to one of the preceding claims, characterized in that the total concentration of the UV filters 4- (tert-butyl) -4'-methoxydibenzoylmethane (INCI butyl methoxydibenzoylmethane), (2 - [- 4- (Diethylamino) -2-hydroxybenzoyl] hexyl benzoate (INCI: diethylamino
Hydroxybenzoyl Hexyl Benzoate) und 2,4-Bis-{[4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl}- 6-(4-methoxyphenyl)-1 ,3,5-triazin (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazin) in der Zubereitung von 0,5 bis 15 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, beträgt. Hydroxybenzoyl hexyl benzoate) and 2,4-bis - {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} - 6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: Bis -Ethylhexyloxyphenol methoxyphenyl triazine) in the preparation from 0.5 to 15% by weight, based on the total weight of the preparation.
9. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 9. Sunscreen, method or use according to any of the preceding
Ansprüche, dadurch gekennzeichnet dass das ethanolische Sonnenschutzmittel transparent ist. Claims, characterized in that the ethanolic sunscreen is transparent.
10. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 10. Sunscreen, method or use according to any of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung kein 3-(4-Methylbenzyliden)- campher, 2-Hydroxy-4-methoxybenzophenon (INCI: Oxybenzon), Phenylen-1 ,4-bis-(2- benzimidazyl)-3,3’-5,5’-tetrasulfonsäuresalze; 1 ,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)- Benzol und dessen Salze; 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäuresalze; 2- Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäuresalze, 3-Benzylidencampher; Claims, characterized in that the preparation is not a 3- (4-methylbenzylidene) camphor, 2-hydroxy-4-methoxybenzophenone (INCI: oxybenzone), phenylene-1,4, bis (2-benzimidazyl) -3,3 ' -5,5'-tetrasulfonic acid salts; 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene and its salts; 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid salts; 2-methyl-5- (2-oxo-3-bornylidene methyl) sulfonic acid salts, 3-benzylidene camphor;
Terephthalidendicampher-sulfonsäure; 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)- ester; 4-Methoxybenzalmalon-säuredi(2-ethylhexyl)ester; 4- Terephthalic dicampher sulfonic acid; 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester; 4-methoxybenzalmalonic acid di (2-ethylhexyl) ester; 4-
Methoxyzimtsäureisoamylester und 4-Methoxyzimtsäureethylhexylester enthält, also frei von diesen Inhaltsstoffen ist. Contains isocyanate methoxycinnamate and ethyl hexyl 4-methoxycinnamate, so it is free of these ingredients.
11. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 11. Sunscreen, method or use according to any of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung 2-Ethylhexyl 2- hydroxybenzoat (INCI: Ethylhexyl Salicylate) und/oder 3,3, 5-Trimethylcyclohexyl 2- hydroxybenzoat (INCI: Homosalate) enthält. Claims, characterized in that the preparation contains 2-ethylhexyl 2-hydroxybenzoate (INCI: ethylhexyl salicylate) and / or 3,3, 5-trimethylcyclohexyl 2-hydroxybenzoate (INCI: homosalate).
12. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 12. Sunscreen, method or use according to one of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung frei ist von Ethylhexyl-2- cyano-3,3-diphenylacrylat (INCI: Octocrylen).
Claims, characterized in that the preparation is free of ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: octocrylene).
13. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Zubereitung kein Octyldodecanol enthält.13. Sunscreen, method or use according to one of the preceding claims, characterized in that the preparation contains no octyldodecanol.
14. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 14. Sunscreen, method or use according to one of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung einen oder mehrere Claims, characterized in that the preparation one or more
Parfümstoffe gewählt aus der Gruppe der Verbindungen Limonen, Citral, Linalool, alpha- Perfumes selected from the group of the compounds limonene, citral, linalool, alpha-
Isomethylionon, Geraniol, Citronellol, 2-lsobutyl-4-hydroxy-4-methyltetrahydropyran, 2- tert-Pentylcyclohexylacetat, 3-Methyl-5-phenyl-1-pentanol, 7-Acetyl-1 , 1 ,3, 4,4,6- hexamethyltetralin, Adipinsäurediester, alpha-Amylcinnamaldehyd, Alpha-Methylionon, Amyl C Butylphenylmethylpropionalcinnamal, Amylsalicylat, Amylcinnamylalkohol, Anisalkohol, Benzoin, Benzylalkohol, Benzylbenzoat, Benzylcinnamat, Benzylsalicylat,Isomethyl ionone, geraniol, citronellol, 2-isobutyl-4-hydroxy-4-methyltetrahydropyran, 2-tert-pentylcyclohexyl acetate, 3-methyl-5-phenyl-1-pentanol, 7-acetyl-1, 1, 3, 4,4, 6- hexamethyltetralin, adipic acid diester, alpha-amylcinnamaldehyde, alpha-methylionone, amyl C butylphenylmethylpropionalcinnamal, amyl salicylate, amylcinnamyl alcohol, anise alcohol, benzoin, benzyl alcohol, benzyl benzoate, benzyl cinnamate, benzyl salicylate
Bergamotöl, bitteres Orangenöl, Butylphenylmethylpropioal, Cardamomöl, Cedrol, Cinnamal, Cinnamylalkohol, Citronellylmethylcrotonat, Citronenöl, Coumarin, Bergamot oil, bitter orange oil, butylphenylmethylpropioal, cardamom oil, cedrol, cinnamal, cinnamyl alcohol, citronellylmethyl crotonate, lemon oil, coumarin,
Diethylsuccinat, Ethyllinalool, Eugenol, Evernia Furfuracea Extract, Evernia Prunastri Extract, Farnesol, Guajakholzöl, Hexylcinnamal, Hexylsalicylat, Hydroxycitronellal, Lavendelöl, Lemonenöl, Linaylacetat, Mandarinenöl, Menthyl PCA, Methylheptenon, Diethylsuccinate, Ethyllinalool, Eugenol, Evernia Furfuracea Extract, Evernia Prunastri Extract, Farnesol, Guajakholzöl, Hexylcinnamal, Hexylsalicylat, Hydroxycitronellal, Lavenderelöl, Lemonenöl, Linaylacetat, Mandarinenöl, Menthyl PCA, Methylhepten
Muskatnussöl, Rosmarinöl, süßes Orangenöl, Terpineol, Tonkabohnenöl, Triethylcitrat und/oder Vanillin enthält. Contains nutmeg oil, rosemary oil, sweet orange oil, terpineol, tonka bean oil, triethyl citrate and / or vanillin.
15. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 15. Sunscreen, method or use according to one of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung Acrylates/Octylacrylamide Copolymer enthält. Claims, characterized in that the preparation contains acrylates / octylacrylamides copolymer.
16. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 16. Sunscreen, method or use according to any one of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung weniger als 3,0 Gewichts-% Wasser, bezogen auf das Gesamtgewicht der Zubereitung enthält. Claims, characterized in that the preparation contains less than 3.0% by weight of water, based on the total weight of the preparation.
17. Sonnenschutzmittel, Verfahren oder Verwendung nach einem der vorhergehenden 17. Sunscreen, method or use according to any of the preceding
Ansprüche, dadurch gekennzeichnet, dass die Zubereitung Cocoglyceride (INCI Claims, characterized in that the preparation of cocoglycerides (INCI
Cocoglycerides), Capryl/Caprinsäuretriglyceride (INCI: Caprylic/Capric Triglyceride), C12-15 Alkylbenzoat, Di-n-Butyladipat und/oder Butylenglycol Dicaprylate/Dicaprate (INCI: Butylene Glycol Dicaprylate/Dicaprate) enthält.
Cocoglycerides), Capryl / Caprinsäuretriglyceride (INCI: Caprylic / Capric Triglyceride), C12-15 alkylbenzoate, Di-n-Butyladipat and / or Butylenglycol Dicaprylate / Dicaprate (INCI: Butylene Glycol Dicaprylate / Dicaprate) contains.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102018216823.7A DE102018216823A1 (en) | 2018-10-01 | 2018-10-01 | Fatty alcohol-containing, ethanolic sunscreen with a reduced tendency to stain textiles |
| PCT/EP2019/074493 WO2020069838A1 (en) | 2018-10-01 | 2019-09-13 | Fatty alcohol-containing, ethanolic sunscreen with a reduced tendency to stain textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3860553A1 true EP3860553A1 (en) | 2021-08-11 |
Family
ID=67988981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19769764.2A Pending EP3860553A1 (en) | 2018-10-01 | 2019-09-13 | Fatty alcohol-containing, ethanolic sunscreen with a reduced tendency to stain textiles |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3860553A1 (en) |
| DE (1) | DE102018216823A1 (en) |
| WO (1) | WO2020069838A1 (en) |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4671222B2 (en) | 2005-03-16 | 2011-04-13 | 株式会社資生堂 | Skin preparation |
| CA2702608C (en) | 2007-10-30 | 2016-05-10 | Gojo Industries, Inc. | Hydroalcoholic gel compositions for use with dispensers |
| DE102010008320A1 (en) * | 2010-02-17 | 2011-08-18 | Beiersdorf AG, 20253 | Use of substances to improve the washability of textile stains caused by UV filters |
| BR112013027893B1 (en) * | 2011-04-27 | 2018-05-08 | Isp Investments Inc | anhydrous sunscreen product |
| FR2976178B1 (en) | 2011-06-09 | 2013-09-27 | Oreal | SOLAR ANHYDROUS CREAM COMPRISING A NON-EMULSIFYING ORGANOSOLYSILOXANE ELASTOMER, A MATIFYING AGENT, AN ORGANIC NON-SILICONE OIL THICKENER |
| US9526925B2 (en) * | 2012-05-17 | 2016-12-27 | Edgewell Personal Care Brands, Llc | Viscous alcohol-containing sunscreen compositions |
| DE102013215831A1 (en) | 2013-08-09 | 2015-02-12 | Beiersdorf Ag | Gel-shaped, alcoholic sunscreen |
| DE102015208869A1 (en) * | 2015-05-13 | 2016-11-17 | Beiersdorf Ag | Alcohol-containing, octocrylene-free sunscreen |
| DE102016202334A1 (en) | 2016-02-16 | 2017-08-17 | Zf Friedrichshafen Ag | Subassembly for a drive unit, drive unit, powertrain test bench and modular system |
| DE102016211238A1 (en) * | 2016-06-23 | 2017-12-28 | Beiersdorf Ag | Sunscreen with reduced textile stain |
| DE102016220547A1 (en) * | 2016-10-20 | 2018-04-26 | Beiersdorf Ag | Ethanolic sunscreen with reduced tendency to textile staining |
| FR3060997B1 (en) | 2016-12-23 | 2019-05-31 | L'oreal | COMPOSITION COMPRISING BAICALIN |
| FR3073400B1 (en) | 2017-11-15 | 2024-08-09 | Oreal | COSMETIC EMULSION CONTAINING A GEMINE SURFACTANT AND A LIPOPHILIC POLYMER |
-
2018
- 2018-10-01 DE DE102018216823.7A patent/DE102018216823A1/en not_active Withdrawn
-
2019
- 2019-09-13 EP EP19769764.2A patent/EP3860553A1/en active Pending
- 2019-09-13 WO PCT/EP2019/074493 patent/WO2020069838A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE102018216823A1 (en) | 2020-04-02 |
| WO2020069838A1 (en) | 2020-04-09 |
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