EP3798290B1 - Utilisation d'un polymère cellulosique anioniquement modifié en tant qu'inhibiteurs de transfert pigmentaire pendant un processus de blanchissage de textile - Google Patents
Utilisation d'un polymère cellulosique anioniquement modifié en tant qu'inhibiteurs de transfert pigmentaire pendant un processus de blanchissage de textile Download PDFInfo
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- EP3798290B1 EP3798290B1 EP19200559.3A EP19200559A EP3798290B1 EP 3798290 B1 EP3798290 B1 EP 3798290B1 EP 19200559 A EP19200559 A EP 19200559A EP 3798290 B1 EP3798290 B1 EP 3798290B1
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- EP
- European Patent Office
- Prior art keywords
- dye
- particles
- anionically
- cellulosic polymer
- polymers
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- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000223221 Fusarium oxysporum Species 0.000 description 1
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- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 150000001204 N-oxides Chemical class 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 108091005507 Neutral proteases Proteins 0.000 description 1
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- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
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- 239000002262 Schiff base Substances 0.000 description 1
- 150000004753 Schiff bases Chemical class 0.000 description 1
- 108010022999 Serine Proteases Proteins 0.000 description 1
- 102000012479 Serine Proteases Human genes 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 241000223257 Thermomyces Species 0.000 description 1
- 241001313536 Thermothelomyces thermophila Species 0.000 description 1
- 241001494489 Thielavia Species 0.000 description 1
- ISWQCIVKKSOKNN-UHFFFAOYSA-L Tiron Chemical compound [Na+].[Na+].OC1=CC(S([O-])(=O)=O)=CC(S([O-])(=O)=O)=C1O ISWQCIVKKSOKNN-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 108090000637 alpha-Amylases Proteins 0.000 description 1
- 102000004139 alpha-Amylases Human genes 0.000 description 1
- 229940024171 alpha-amylase Drugs 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 125000000332 coumarinyl group Chemical class O1C(=O)C(=CC2=CC=CC=C12)* 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 108010005400 cutinase Proteins 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
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- 238000000227 grinding Methods 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- AWJUIBRHMBBTKR-UHFFFAOYSA-O isoquinolin-2-ium Chemical compound C1=[NH+]C=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-O 0.000 description 1
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- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 108010009355 microbial metalloproteinases Proteins 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-K pentetate(3-) Chemical compound OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O QPCDCPDFJACHGM-UHFFFAOYSA-K 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
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- 239000000700 radioactive tracer Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical group [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- YEOUFHBJWTZWCZ-UHFFFAOYSA-M sulforhodamine G Chemical compound [Na+].C=12C=C(C)C(NCC)=CC2=[O+]C=2C=C(NCC)C(C)=CC=2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O YEOUFHBJWTZWCZ-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Claims (12)
- Utilisation d'un polymère cellulosique modifié anioniquement destinée à empêcher la redéposition de colorants dans un bain de lavage de linge textile à partir de textiles colorés sur des textiles blancs ou différemment colorés également présents dans le même bain de lavage.
- Utilisation selon la revendication 1, dans laquelle le polymère cellulosique modifié anioniquement est la carboxyméthylcellulose.
- Utilisation selon la revendication 2, dans laquelle la carboxyméthylcellulose présente un degré de substitution (DS) d'au moins 0,55, et présente un degré de présence de blocs (DB) d'au moins 0,35, et présente un DS + DB qui se situe dans la plage allant de 1,05 à 2,00.
- Utilisation selon l'une quelconque revendication précédente, dans laquelle le polymère cellulosique modifié anioniquement est compris dans une composition détergente solide pour le lavage du linge.
- Utilisation selon l'une quelconque revendication précédente, dans laquelle le colorant est un colorant direct ou un colorant acide.
- Utilisation selon l'une quelconque des revendications 1 à 5, dans laquelle le colorant est un colorant de cuve ou un colorant soufré.
- Utilisation d'un polymère cellulosique modifié anioniquement comme inhibiteur de transfert de colorant pendant un procédé de lavage de linge textile.
- Utilisation selon la revendication 7, dans laquelle le polymère cellulosique modifié anioniquement est la carboxyméthylcellulose.
- Utilisation selon la revendication 8, dans laquelle la carboxyméthylcellulose présente un degré de substitution (DS) d'au moins 0,55, et présente un degré de présence de blocs (DB) d'au moins 0,35, et présente un DS + DB qui se situe dans la plage allant de 1,05 à 2,00.
- Utilisation selon l'une quelconque des revendications 7 à 9, dans laquelle le polymère cellulosique modifié anioniquement est compris dans une composition détergente solide pour le lavage du linge.
- Utilisation selon l'une quelconque des revendications 7 à 10, dans laquelle le colorant est un colorant direct ou un colorant acide.
- Utilisation selon l'une quelconque des revendications 7 à 10, dans laquelle le colorant est un colorant de cuve ou un colorant soufré.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19200559.3A EP3798290B1 (fr) | 2019-09-30 | 2019-09-30 | Utilisation d'un polymère cellulosique anioniquement modifié en tant qu'inhibiteurs de transfert pigmentaire pendant un processus de blanchissage de textile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19200559.3A EP3798290B1 (fr) | 2019-09-30 | 2019-09-30 | Utilisation d'un polymère cellulosique anioniquement modifié en tant qu'inhibiteurs de transfert pigmentaire pendant un processus de blanchissage de textile |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3798290A1 EP3798290A1 (fr) | 2021-03-31 |
EP3798290B1 true EP3798290B1 (fr) | 2022-08-17 |
Family
ID=68104506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19200559.3A Active EP3798290B1 (fr) | 2019-09-30 | 2019-09-30 | Utilisation d'un polymère cellulosique anioniquement modifié en tant qu'inhibiteurs de transfert pigmentaire pendant un processus de blanchissage de textile |
Country Status (1)
Country | Link |
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EP (1) | EP3798290B1 (fr) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0265257B1 (fr) | 1986-10-24 | 1992-03-04 | Unilever Plc | Composition détergente |
CN108048236A (zh) | 2017-12-01 | 2018-05-18 | 纳爱斯浙江科技有限公司 | 一种含有羧甲基纤维素的液体洗涤剂及其制备方法 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK0493398T3 (da) | 1989-08-25 | 2000-05-22 | Henkel Research Corp | Alkalisk, proteolytisk enzym og fremgangsmåde til fremstilling deraf |
AU2310099A (en) | 1999-01-13 | 2000-08-01 | Procter & Gamble Company, The | Detergent compositions having a cellulose polymer |
EP2022841B1 (fr) | 2004-02-03 | 2013-04-03 | The Procter and Gamble Company | Composition destinée à une utilisation pour le lavage ou le traitement de tissus |
BRPI0512776A (pt) | 2004-07-05 | 2008-04-08 | Novozymes As | variante de uma alfa-amilase tipo termamil originária, construto de dna, vetor de expressão recombinante, célula, composição, aditivo de detergente, composição detergente, composição de lavagem de roupa manual ou automática, uso de uma variante de alfa-amilase ou composição, e, método de produzir uma variante |
EP1693440A1 (fr) | 2005-02-22 | 2006-08-23 | The Procter & Gamble Company | Compositions de lavage |
EP1867707B1 (fr) | 2006-06-16 | 2011-09-07 | The Procter & Gamble Company | Compositions de lavage |
DE602006020853D1 (de) | 2006-07-07 | 2011-05-05 | Procter & Gamble | Waschmittelzusammensetzungen |
BRPI0720944B1 (pt) | 2007-01-19 | 2017-05-30 | Procter & Gamble | composição para tratamento na lavagem de roupas compreendendo um agente branqueador de substratos celulósicos |
ES2401836T3 (es) | 2007-11-26 | 2013-04-24 | Basf Se | Proceso de matización mejorado |
PL2247275T3 (pl) | 2008-02-15 | 2018-05-30 | The Procter And Gamble Company | Cząstka przenosząca |
EP2135933B1 (fr) * | 2008-06-20 | 2013-04-03 | The Procter and Gamble Company | Composition de lavage |
EP2138565A1 (fr) | 2008-06-25 | 2009-12-30 | The Procter and Gamble Company | Procédé de séchage par atomisation |
EP2138567A1 (fr) | 2008-06-25 | 2009-12-30 | The Procter & Gamble Company | Procédé de séchage par atomisation |
CN102216439A (zh) | 2008-11-14 | 2011-10-12 | 宝洁公司 | 包含聚合物和酶的组合物 |
EP2302025B1 (fr) * | 2009-09-08 | 2016-04-13 | The Procter & Gamble Company | Composition de détergent pour linge comprenant des particules de cellulose de carboxyméthyle fortement solubles dans l'eau |
JP5882904B2 (ja) | 2009-12-09 | 2016-03-09 | ザ プロクター アンド ギャンブルカンパニー | 布地ケア製品及びホームケア製品 |
MX2012007168A (es) | 2009-12-21 | 2012-07-23 | Danisco Us Inc | Composiciones de detergentes que contienen lipasa thermobifida fusca y metodos de uso de esta. |
US20120101018A1 (en) | 2010-10-22 | 2012-04-26 | Gregory Scot Miracle | Bis-azo colorants for use as bluing agents |
EP2502980A1 (fr) | 2011-03-25 | 2012-09-26 | The Procter & Gamble Company | Particules de détergent pour le lavage du linge, séchées par atomisation |
JP5883127B2 (ja) | 2011-06-03 | 2016-03-09 | ザ プロクター アンド ギャンブルカンパニー | 染料を含むランドリーケア組成物 |
EP2751263A1 (fr) | 2011-08-31 | 2014-07-09 | Danisco US Inc. | Compositions et procédés comprenant un variant d'enzyme lipolytique |
DK2623586T3 (da) | 2012-02-03 | 2017-11-13 | Procter & Gamble | Sammensætninger og fremgangsmåder til overfladebehandling med lipaser |
EP2875111A1 (fr) | 2012-05-16 | 2015-05-27 | Novozymes A/S | Composition comprenant une lipase et procédés d'utilisation associés |
ES2535580T3 (es) | 2012-06-01 | 2015-05-12 | The Procter & Gamble Company | Proceso de secado por pulverización |
DE102012212727A1 (de) * | 2012-07-19 | 2014-01-23 | Henkel Ag & Co. Kgaa | Flüssiges Waschmittel mit verbesserter Farbübertragungsinhibierung |
US20140162929A1 (en) | 2012-12-06 | 2014-06-12 | The Procter & Gamble Company | Soluble pouch comprising hueing dye |
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2019
- 2019-09-30 EP EP19200559.3A patent/EP3798290B1/fr active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0265257B1 (fr) | 1986-10-24 | 1992-03-04 | Unilever Plc | Composition détergente |
CN108048236A (zh) | 2017-12-01 | 2018-05-18 | 纳爱斯浙江科技有限公司 | 一种含有羧甲基纤维素的液体洗涤剂及其制备方法 |
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