EP3764980A1 - Procédé de coloration des cheveux - Google Patents

Procédé de coloration des cheveux

Info

Publication number
EP3764980A1
EP3764980A1 EP19704586.7A EP19704586A EP3764980A1 EP 3764980 A1 EP3764980 A1 EP 3764980A1 EP 19704586 A EP19704586 A EP 19704586A EP 3764980 A1 EP3764980 A1 EP 3764980A1
Authority
EP
European Patent Office
Prior art keywords
group
formula
organic silicon
silicon compound
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19704586.7A
Other languages
German (de)
English (en)
Inventor
Torsten LECHNER
Juergen Schoepgens
Marc NOWOTTNY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3764980A1 publication Critical patent/EP3764980A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes
    • A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/884—Sequential application
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/95—Involves in-situ formation or cross-linking of polymers

Definitions

  • R 5, R 5 ', R 5 ", R 6, R 6' and R 6" independently of one another are a C 1 -C 6 -alkyl group
  • the colorant (B) (which is the ready-to-use colorant) can be formulated, for example, on the basis of an aqueous or aqueous-alcoholic carrier.
  • Suitable forms of preparation are, for example, a cream, an emulsion, a gel or a surfactant-containing foaming solution, for example a shampoo or a foam aerosol.
  • the process according to the invention may also comprise the use of a further agent, which may be, for example, an after-treatment agent (C).
  • a further agent which may be, for example, an after-treatment agent (C).
  • R 1, R 2 independently of one another represent a hydrogen atom or a C 1 -C 6 -alkyl group
  • A, A ', A ", A"' and A “" independently of one another represent a linear or branched, divalent C 1 -C 20 -alkylene group
  • R7 and Re independently represent a hydrogen atom, a Ci-Ce-alkyl group, a hydroxy-Ci-Ce-alkyl group, a C2-Ce-alkenyl group, an amino-Ci-Ce-alkyl group or a grouping of the formula (III ) stand
  • c is an integer from 1 to 3
  • c is an integer from 1 to 3
  • Pretreatment agent (A) In the first step of the process according to the invention, the pretreatment agent (A) is applied to the hair.
  • the pretreatment agent (A) itself does not dye the hair, ie it is free of coloring compounds from the group of substantive dyes and pigments.
  • the method according to the invention is characterized in that
  • a pretreatment agent (A) which contains at least one organic silicon compound of the formula (I) and / or (II) and furthermore contains no substantive dyes and no pigments and no oxidation dye precursors,
  • Direct-acting dyes are understood to mean those dyes which the person skilled in the art usually uses in the direct dyeing of hair. Common direct dyes are disclosed in the description of the colorant (B). Pigments are understood as meaning those coloring pigments which the skilled person usually uses for the temporary coloring of the hair. Typical pigments or color pigments are disclosed in the description of the colorant (B). All of these coloring compounds are not included in the pretreatment agent (A), i. the total amount of the coloring compounds from the group of substantive dyes and pigments contained in the pretreatment agent (A) is less than 0.05% by weight, preferably less than 0.01% by weight, based on the total weight of the pretreatment agent (A). %, and more preferably below 0.001% by weight.
  • the pretreatment agent (A) contains at least one organic silicon compound of the formula (I) and / or (II)
  • R 1, R 2 independently of one another represent a hydrogen atom or a C 1 -C 6 -alkyl group
  • L is a linear or branched, divalent C 1 -alko-alkylene group
  • R 3 , R 4 independently of one another represent a C 1 -C 6 -alkyl group
  • R 5, R 5 ', R 5 ", R 6, R 6' and R 6" independently of one another are a C 1 -C 6 -alkyl group
  • A, A ', A ", A"' and A “" independently of one another represent a linear or branched, bivalent C 1 -C 20 -alkylene group
  • R7 and Re independently of one another represent a hydrogen atom, a C 1 -C 6 -alkyl group, a hydroxyl group,
  • Ci-Ce-alkyl group a C2-Ce-alkenyl group, an amino-Ci-Ce-alkyl group or a group of the formula (III)
  • c is an integer from 1 to 3
  • c ' is an integer from 1 to 3
  • c is an integer from 1 to 3
  • Organic silicon compounds which are alternatively referred to as organosilicon compounds, are compounds which have either a direct silicon-carbon bond (Si-C) or in which the carbon via an oxygen, nitrogen or sulfur atom to the silicon Atom is linked.
  • Examples of a C 1 -C 6 -alkyl group are the groups methyl, ethyl, propyl, isopropyl, n-butyl, s-butyl and t-butyl, n-pentyl and n-hexyl.
  • Propyl, ethyl and methyl are preferred alkyl radicals.
  • Examples of a C2-Ce-alkenyl are vinyl, allyl, but-2-enyl, but-3-enyl and isobutenyl, preferred C 2 -C6- alkenyl radicals are vinyl and allyl.
  • a hydroxy-C 1 -C e -alkyl radical are a hydroxymethyl, a 2-hydroxyethyl, a 2-hydroxypropyl, a 3-hydroxypropyl, a 4-hydroxybutyl group, a 5-hydroxypropyl Hydroxypentyl and a 6-hydroxyhexyl group; a 2-hydroxyalkyl group is particularly preferred.
  • Examples of an amino-C 1 -C 6 -alkyl group are the aminomethyl group, the 2-aminoethyl group, the 3-aminopropyl group. The 2-aminoethyl group is particularly preferred.
  • Examples of a linear bivalent C 1 -C 20 -alkylene group are, for example, the methylene group (-CH 2 -), the ethylene group (-CH 2 -CH 2 -), the propylene group (-CH 2 -CH 2 -CH 2 -) and the butylene group (-CH 2 -). CH2-CH2-CH2).
  • the propylene group (-CH 2 -CH 2 -CH 2 -) is particularly preferred.
  • bivalent alkylene groups may also be branched. Examples of branched, divalent C 3 -C 20 -alkylene groups are (-CH 2 -CH (CH 3) -) and (-CH 2 -CH (CH 3) -CH 2 -).
  • radicals R 1 and R 2 independently of one another represent a hydrogen atom or a C 1 -C 6 -alkyl group. Most preferably, the radicals R 1 and R 2 both represent a hydrogen atom.
  • the linker -L- is a linear or branched, divalent Ci-C 2 o-alkylene group.
  • -L- is a linear, divalent Ci-C 2 o-alkylene group. More preferably, -L- is a linear divalent C 1 -C 6 -alkylene group. More preferably, -L- represents a methylene group (-CH 2 -), an ethylene group (-CH 2 -CH 2 -), a propylene group (-CH 2 -CH 2 -CH 2 -) or a butylene group (-CH 2 -CH 2 -CH 2 -CH 2 -). Most preferably, L is a propylene group (-CH 2 -CH 2 -CH 2 -).
  • a method is particularly preferred, which is characterized in that the pretreatment agent (A) contains at least one organic silicon compound of the formula (I),
  • L is a linear, divalent C 1 -C 6 -alkylene group, preferably a propylene group (-CH 2 --CH 2 -CH 2 -) or an ethylene group (-CH 2 -CH 2 -).
  • L is a linear, divalent C 1 -C 6 -alkylene group, preferably a propylene group (-CH 2 --CH 2 -CH 2 -) or an ethylene group (-CH 2 -CH 2 -).
  • the radicals R3 and R4 independently of one another are a C 1 -C 6 -alkyl group. More preferably, R3 and R4 independently represent a methyl group or an ethyl group.
  • a is an integer from 1 to 3, and b is the integer 3 - a. If a stands for the number 3, then b is 0. If a stands for the number 2, then b equals 1. If a stands for the number 1, then b equals 2.
  • the pretreatment agent contains at least one organic silicon compound of the formula (I) in which the radicals R 3 , R 4 independently of one another represent a methyl group or an ethyl group.
  • the pretreatment agent contains at least one organic silicon compound of the formula (I) in which the radical a is the number 3. In this case, the rest b stands for the number 0.
  • a method is particularly preferred, which is characterized in that the pretreatment agent (A) contains at least one organic silicon compound of the formula (I),
  • R3, R4 independently of one another represent a methyl group or an ethyl group
  • R 3 , R 4 independently of one another represent a methyl group or an ethyl group
  • a method according to the invention is characterized in that the pretreatment agent (A) contains at least one organic silicon compound of the formula (I) which is selected from the group consisting of
  • (3-aminopropyl) trimethoxysilane may be purchased from Sigma-Aldrich.
  • (3-aminopropyl) triethoxysilane is commercially available from Sigma-Aldrich.
  • the pretreatment agent (A) may also contain at least one organic silicon compound of the formula (II).
  • organosilicon compounds of the formula (II) according to the invention each carry at their two ends the silicon-containing groups (R50) c (Re) dSi and -Si (Re ') d' (OR5 ') c ⁇
  • an organic silicon compound of the formula (II) according to the invention contains at least one grouping from the group of - (A) - and - [NR7- (A ') j- and - [0- (A ") j- and - [ NR 8 - (A ") j-
  • the radicals R5, R6, R5' and R6 'independently of one another represent a C-i-Ce-alkyl group. More preferably, R5, R6, R5 'and R6' independently represent a methyl group or an ethyl group.
  • c stands for an integer from 1 to 3, and d stands for the integer 3 - c. If c stands for the number 3, then d is 0. If c stands for the number 2, then d is 1. If c stands for the number 1, then d is equal to 2.
  • c ' is an integer from 1 to 3
  • d' is the integer 3 - a '. If c 'stands for the number 3, then d' is equal to 0. If c 'stands for the number 2, then d' is equal to 1. If c 'stands for the number 1, then d' is equal to 2.
  • a process according to the invention is characterized in that the pretreatment agent (A) comprises at least one organic silicon compound of the formula (II), (R50) c (R6) DSI (A) e- [NR7- (A ')] f- [0- (A ")] g- [NR8- (A'")] h-Si (R6 ') d '(0R5') c (II), where
  • R5 and R5 'independently of one another represent a methyl group or an ethyl group
  • R5 and R5 'independently of one another represent a methyl group or an ethyl group
  • the radicals e, f, g and h can independently of one another stand for the number 0 or 1, where at least one radical from e, f, g and h is different from zero.
  • the abbreviations e, f, g and h thus define which of the groupings - (A) e - and - [NR7- (A ')] f - and - [0- (A ")] g - and - [ NR8- (A "')] h - are in the middle part of the organic silicon compound of the formula (II).
  • the radicals A, A ', A “, A”' and A “" independently of one another represent a methylene group (-CH 2 -), an ethylene group (-CH 2 -CH 2 -), a propylene group (-CH 2 -CH 2 -CH 2 -) or a butylene group (-CH2-CH2-CH2-).
  • the radicals A, A ', A ", A"' and A “" represent a propylene group (-CH 2 -CH 2 -CH 2 -).
  • the organic silicon compound of the formula (II) according to the invention contains a structural grouping - [NR7- (A ')] -.
  • 3- (triethoxysilyl) -N, N-bis [3- (triethoxysilyl) propyl] -1-propanamine CAS number 18784-74-2 can be purchased from Fluorochem or Sigma-Aldrich.
  • the organic silicon compounds of formula (I) and (II) are reactive compounds.
  • the pretreatment agent (A) - based on the total weight of the pretreatment agent (A) - one or more organic silicon compounds of the formula (I) and / or (II) in a total amount of 0, 1 to 20.0 wt .-%, preferably 0.2 to 15.0 wt .-% and particularly preferably 0.2 to 2.0 wt .-%.
  • an inventive method is characterized in that the pretreatment agent (A) - based on the total weight of the pretreatment agent (A) - one or more organic silicon compounds of the formula (I) and / or (II) in a total amount of 0 , 1 to 20.0 wt .-%, preferably 0.2 to 15.0 wt .-% and particularly preferably 0.2 to 2.0 wt .-%.
  • the colorant (B), which is applied to the hair in the context of the inventive method contains at least one organic silicon compound of the formula (I) and / or (II).
  • organic silicon compound of the formula (I) and / or (II) is the same group of compounds as disclosed in the description of the pretreatment agent (A).
  • L is a linear, divalent C-i-Ce-alkylene group, preferably a propylene group (-CH 2 -CH 2 -CH 2 -) or an ethylene group (-CH 2 -CH 2 -).
  • R3, R4 independently of one another represent a methyl group or an ethyl group
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (I) which is selected from the group consisting of
  • a method which is characterized in that the organic silicon compound of the formula (I) is selected from the group is particularly preferred - (3-Aminopropy!) Trimethoxysilane
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (II),
  • R5 and R5 'independently of one another represent a methyl group or an ethyl group
  • R5 and R5 'independently of one another represent a methyl group or an ethyl group
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (II), wherein
  • R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a group of the formula (III).
  • a method is particularly preferred which is characterized in that in the organic silicon compound of the formula (II)
  • R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a group of the formula (III).
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (II), wherein
  • R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (II), wherein
  • a and A 'independently of one another are a methylene group (-CH 2 -), an ethylene group (-CH 2 -CH 2 -) or a propylene group (-CH 2 -CH 2 -CH 2 -),
  • R7 represents a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (II) which is selected from the group consisting of
  • the organic silicon compounds of formula (I) and (II) are reactive compounds.
  • the colorant (B) - based on the total weight of the colorant (B) - one or more organic silicon compounds of the formula (I) and / or (II) in a total amount of 0, From 1 to 90.0% by weight, preferably from 1.0 to 80.0% by weight, more preferably from 5.0 to 50.0% by weight and most preferably from 10.0 to 30.0% by weight .-% contains.
  • a method according to the invention is characterized in that the colorant (B) - based on the total weight of the colorant (B) - one or more organic silicon compounds of formula (I) and / or (II) in a total amount of 0 From 1 to 90.0% by weight, preferably from 1.0 to 80.0% by weight, more preferably from 5.0 to 50.0% by weight and very particularly preferably from 10.0 to 30, 0 wt .-% contains.
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (I). Furthermore, it has also been found to be particularly suitable to use at least one organic silicon compound of the formula (II) in the colorant (B).
  • a method according to the invention is characterized in that the colorant (B) contains at least one organic silicon compound of the formula (II).
  • the colorant (B) additionally comprises at least one coloring compound selected from the group of substantive dyes and / or pigments.
  • Direct dyes are dyes that are applied directly to the hair and do not require an oxidative process to form the color. Direct dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones, triarylmethane dyes or indophenols.
  • Direct dyes may be subdivided into anionic, cationic and nonionic substantive dyes which are selected and used by those skilled in the art according to the requirements of the carrier base.
  • a method according to the invention is characterized in that the colorant (B) contains at least one substantive dye, which is preferably selected from the group of anionic, cationic and nonionic substantive dyes.
  • Preferred anionic substantive dyes are those having the international designations or trade names bromophenol blue, tetrabromophenol blue, Acid Yellow 1, Yellow 10, Acid Yellow 23, Acid Yellow 36, Acid Orange 7, Acid Red 33, Acid Red 52, Pigment Red 57: 1, Acid Blue 7, Acid Green 50, Acid Violet 43, Acid Black 1 and Acid Black 52 known compounds.
  • Preferred cationic substantive dyes are Basic Blue 7, Basic Blue 26, Basic Violet 2 and Basic Violet 14, Basic Yellow 57, Basic Red 76, Basic Blue 16, Basic Blue 347 (Cationic Blue 347 / Dystar), HC Blue No. 16, Basic Brown 16, Basic Brown 16, Basic Brown 17, Yellow 87, Basic Orange 31 and Basic Red 51.
  • Suitable nonionic substantive dyes are in particular nonionic nitro and quinone dyes and neutral azo dyes.
  • Preferred nonionic substantive dyes are those under the international designations or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse Orange 3, HC Red 1, HC Red 3, HC Red 10, HC Red 1, HC Red 13, HC Red BN, HC Blue 2, HC Blue 1 1, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9 known compounds , as well as 1, 4-diamino 2-nitrobenzene, 2-amino-4-nitrophenol, 1,4-bis (2-hydroxyethyl) amino-2-niirobenzene, 3-nitro-4- (2-hydroxyethyl) aminophenol, 2- (2-hydroxyethyl ) amino-4,6-dinitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitro-1-methylbenzene, 1-
  • the colorant (B) contains as direct dye at least one dye from the group of thermochromic and / or photochromic dyes.
  • a method according to the invention is characterized in that the colorant (B) contains at least one substantive dye, which is preferably selected from the group of anionic, cationic and nonionic substantive dyes.
  • a method according to the invention is characterized in that the colorant (B) contains at least one anionic substantive dye.
  • the substantive dyes may be used in an amount of 0.001 to 20 wt .-%, in particular from 0.05 to 5 wt .-%, each based on the total weight of the colorant (B).
  • the total amount of substantive dyes in the colorant (B) is preferably at most
  • pigments are understood as meaning coloring compounds which have a solubility of less than 0.1 g / l at 20 ° C. in water.
  • the water solubility can be carried out, for example, by the method described below: 0.1 g of the pigment are weighed in a beaker. A stir bar is added. It is then made up to 1 l with distilled water (20 ° C.). It is stirred for an hour. If undissolved components of the pigment are still visible in the mixture after this period, the solubility of the pigment is below 0.1 g / l.
  • Suitable color pigments may be organic and / or inorganic origin.
  • Preferred color pigments are selected from synthetic or natural inorganic pigments.
  • Inorganic color pigments of natural origin can be prepared, for example, from chalk, ocher, umber, green earth, baked Terra di Siena or graphite.
  • black pigments such as inorganic color pigments
  • B. iron oxide black colored pigments such as ultramarine or iron oxide red and fluorescent or Phosphoreszenzpigmente be used.
  • Particularly suitable are colored metal oxides, hydroxides and oxide hydrates, mixed phase pigments, sulfur-containing silicates, silicates, metal sulfides, complex metal cyanides, metal sulfates, chromates and / or molybdate.
  • Particularly preferred color pigments are black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI77289 ), Iron blue (Ferric Ferrocyanide, CI77510) and / or Carmine (Cochineal).
  • Color pigments which are likewise particularly preferred according to the invention are colored pearlescent pigments. These are usually based on mica and / or mica and may be coated with one or more metal oxides. Mica belongs to the layer silicates. The most important representatives of these silicates are muscovite, phlogopite, paragonite, biotite, lepidolite and margarite. To produce the pearlescent pigments in conjunction with metal oxides, the mica, predominantly muscovite or phlogopite, is coated with a metal oxide.
  • pearlescent pigments are based on natural or synthetic mica (mica) and are coated with one or more of the abovementioned metal oxides.
  • the color of the respective pigments can be varied by varying the layer thickness of the metal oxide (s).
  • a method according to the invention is characterized in that the colorant (B) comprises at least one pigment which is preferably selected from the group of colored metal oxides, metal hydroxides, metal oxide hydrates, silicates, metal sulfides, complex metal cyanides, metal sulfates, bronze pigments and / or of colored pigments based on mica or mica, which are coated with at least one metal oxide and / or one metal oxychloride.
  • the colorant (B) comprises at least one pigment which is preferably selected from the group of colored metal oxides, metal hydroxides, metal oxide hydrates, silicates, metal sulfides, complex metal cyanides, metal sulfates, bronze pigments and / or of colored pigments based on mica or mica, which are coated with at least one metal oxide and / or one metal oxychloride.
  • a method according to the invention is characterized in that the colorant (B) contains at least one pigment selected from mica or mica-based pigments which are combined with one or more metal oxides from the group consisting of titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and / or brown iron oxide (CI 77491, CI 77499), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate ( CI 77289), chromium oxide (CI 77288) and / or iron blue (Ferric Ferrocyanide, CI 77510).
  • the colorant (B) contains at least one pigment selected from mica or mica-based pigments which are combined with one or more metal oxides from the group consisting of titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and / or brown iron oxide
  • color pigments are commercially available, for example, under the trade names Rona®, Colorona®, Xirona®, Dichrona® and Timiron® from Merck, Ariabel® and Unipure® from Sensient, Prestige® from Eckart Cosmetic Colors and Sunshine® available from Sunstar.
  • Very particularly preferred color pigments with the trade name Colorona® are, for example:
  • color pigments with the trade name Xirona® are, for example:
  • color pigments with the trade name Unipure® are, for example:
  • the use of the abovementioned inorganic color pigments in the composition according to the invention is particularly preferred. Furthermore, it is preferred if the pigments used have a certain particle size. On the one hand, this particle size leads to a uniform distribution of the pigments in the polymer film formed and, on the other hand, avoids a rough hair or skin feeling after the application of the cosmetic product. It is therefore advantageous according to the invention if the at least one pigment has an average particle size D 50 of from 1.0 to 50 ⁇ m, preferably from 5.0 to 45 ⁇ m, preferably from 10 to 40 ⁇ m, in particular from 14 to 30 ⁇ m.
  • the average particle size Dso can be determined, for example, using dynamic light scattering (DLS).
  • the pigment (s) can be used in an amount of 0.001 to 20% by weight, in particular 0.05 to 5% by weight, based in each case on the total weight of the colorant (B).
  • the pretreatment agent (A) and / or the colorant (B) may also contain one or more surfactants.
  • surfactants is understood to mean surface-active substances. A distinction is made between anionic surfactants consisting of a hydrophobic radical and a negatively charged hydrophilic head group, amphoteric surfactants which carry both a negative and a compensating positive charge, cationic surfactants which, in addition to a hydrophobic radical, have a positively charged hydrophilic group, and nonionic surfactants, which have no charges but strong dipole moments and are highly hydrated in aqueous solution.
  • Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO H or -SOs ⁇ group.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyl dimethylammonium glycinate, N-acylaminopropyl N, N-dimethylammonium glycinates, for example cocoacylaminopropyl dimethylammonium glycinate, and 2-alkyl 3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the Kokosacylaminoethylhydroxyethylcarboxymethyl- glycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamido
  • Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a Cs-C24-alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SCbH group and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group.
  • amphoteric or zwitterionic surfactants are alkylbetaines, alkylamidobetaines, amino-propionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C 12 -Cis-acylsarcosine.
  • the pretreatment agent (A) and / or the colorant (B) may additionally contain at least one nonionic surfactant.
  • Suitable nonionic surfactants are alkyl polyglycosides and alkylene oxide addition products of fatty alcohols and fatty acids with in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Preparations having good properties are also obtained when they contain as nonionic surfactants fatty acid esters of ethoxylated glycerol which have been reacted with at least 2 moles of ethylene oxide.
  • the nonionic surfactants are used in a total amount of 0, 1 to 45 wt .-%, preferably 1 to 30 wt .-% and most preferably from 1 to 15 wt .-% - based on the total weight of the respective agent - used.
  • the pretreatment agent (A) and / or the dyeing agent (B) may additionally contain at least one cationic surfactant.
  • Cationic surfactants are understood to mean surfactants, ie surface-active compounds, each having one or more positive charges. Cationic surfactants contain only positive charges. Usually, these surfactants are composed of a hydrophobic part and a hydrophilic head group, wherein the hydrophobic part usually consists of a hydrocarbon skeleton (eg consisting of one or two linear or branched alkyl chains), and the positive charge (s) are located in the hydrophilic head group. Examples of cationic surfactants are examples of cationic surfactants.
  • quaternary ammonium compounds which as hydrophobic radicals can carry one or two alkyl chains having a chain length of 8 to 28 carbon atoms,
  • quaternary phosphonium salts substituted with one or more alkyl chains having a chain length of 8 to 28 C atoms or
  • the cationic charge may also be in the form of an onium structure part of a heterocyclic ring (eg, an imidazolium or a pyridinium ring).
  • the cationic surfactant may also contain other uncharged functional groups, as is the case, for example, with esterquats.
  • the cationic surfactants are used in a total amount of from 0.1 to 45% by weight, preferably from 1 to 30% by weight and very particularly preferably from 1 to 15% by weight, based on the total weight of the respective composition.
  • the pretreatment agent (A) and / or the colorant (B) may also contain at least one anionic surfactant.
  • Anionic surfactants are surfactants with exclusively anionic charges (neutralized by a corresponding counter cation). Examples of anionic surfactants are fatty acids, alkyl sulfates, alkyl ether sulfates and ether carboxylic acids having 12 to 20 carbon atoms in the alkyl group and up to 16 glycol ether groups in the molecule.
  • the anionic surfactants are used in a total amount of 0, 1 to 45 wt .-%, preferably 1 to 30 wt .-% and most preferably from 1 to 15 wt .-% - based on the total weight of the respective agent - used.
  • the pretreatment agent (A) and / or the colorant (B) may also contain other active ingredients, auxiliaries and additives, such as solvents, fatty components such as the C8-C30 fatty alcohols, the C3-C30 fatty acids and the like reticals, Cs-Cso fatty acid monoglycerides, Cs-C3o fatty acid diglycerides, and / or coal wet substances; nonionic polymers such as vinylpyrrolidinone / vinyl acrylate copolymers, polyvinylpyrrolidinone, vinylpyrrolidinone / vinyl acetate copolymers, polyethylene glycols and polysiloxanes; additional silicones, such as volatile or nonvolatile, straight-chain, branched or cyclic, crosslinked or uncrosslinked polyalkylsiloxanes (such as dimethicones or cyclomethicones), polyarylsiloxanes and / or polyalkylarylsiloxanes, in particular polys
  • the choice of these other substances will be made by those skilled in the art according to the desired properties of the agents.
  • the additional active ingredients and auxiliaries are preferably used in the preparations according to the invention in amounts of from 0.0001 to 25% by weight, in particular from 0.0005 to 15% by weight, based on the total weight of the respective agent.
  • the performance properties of the resulting color can be further improved by choosing the optimal process conditions.
  • the pretreatment agent (A) is first applied to the hair.
  • the pretreatment agent (A) is allowed to act on the hair.
  • exposure times of 10 seconds to 10 minutes, preferably from 20 seconds to 5 minutes and most preferably from 30 seconds to 2 minutes on the hair have proven to be particularly advantageous.
  • a method according to the invention is characterized by (2) allowing the pretreatment agent (A) to act on the hair for a period of 10 seconds to 10 minutes, preferably 10 seconds to 5 minutes and most preferably 30 seconds to 2 minutes.
  • the pretreatment agent (A) can now be rinsed off the hair before the dyeing agent (B) is applied to the hair in the subsequent step.
  • step (4) the colorant (B) is then applied to the hair. After the orders, the colorant (B) is now allowed to act on the hair.
  • the inventive method allows even with a short reaction time of the colorant (B) the production of dyeings with particularly good intensity and wash fastness. Contact times of 10 seconds to 10 minutes, preferably from 20 seconds to 5 minutes and most preferably from 30 seconds to 3 minutes on the hair have been found to be particularly advantageous.
  • a method according to the invention is characterized by (5) allowing the colorant (B) to act on the hair for a period of 10 seconds to 10 minutes, preferably 20 seconds to 5 minutes, and most preferably 30 seconds to 3 minutes.
  • the pretreatment agent (A) and the colorant (B) both contain reactive organic silicon compounds of the formula (I) and / or (II) which form a film on the hair.
  • a method according to the invention is characterized in that the pretreatment agent (A) and the colorant (B) within a period of not more than 48 hours, preferably not more than 24 hours, more preferably not more than 12 hours and most preferably not more than 6 Hours are applied to the hair.
  • Multi-component packaging unit (kit-of-parts)
  • the user uses the previously described agents, the pretreatment agent (A) and the colorant (B). Both means are, as already mentioned, the ready-to-use means.
  • the organic silicon compounds of the formula (I) and (II) are reactive compounds.
  • a multicomponent packaging unit according to the invention may also contain one or more further agents in addition to the separately formulated compositions (A) and (B).
  • a separate storage of the organic silicon compounds of the formulas (I) or (II) and the color-giving compounds has been found in this context to be advantageous.
  • a second subject of the present invention is therefore a multi-component packaging unit (kit-of-parts) for dyeing human hair, comprising separately prepared from each other
  • At least one of the agents (B) and / or (B ') contains at least one coloring compound selected from the group of substantive dyes and pigments, wherein in the organic silicon compound of the formula (I)
  • R 1, R a independently of one another represent a hydrogen atom or a C 1 -C 6 -alkyl group
  • L is a linear or branched, divalent C 1 -C 20 -alkylene group
  • R 3 independently of one another represent a C 1 -C 6 -alkyl group
  • R 5, R 5 ', R 5 ", R 6, R 6' and R 6" independently of one another are a C 1 -C 6 -alkyl group
  • A, A ', A ", A"' and A “" independently of one another represent a linear or branched, divalent C 1 -C 20 -alkylene group
  • R7 and Rs are each independently a hydrogen atom, a Ci-Ce-alkyl group, a hydroxy-Ci-Ce-alkyl group, a C2-Ce-alkenyl group, an amino-Ci-Ce-alkyl group or a grouping of the formula (III ) stand
  • c ' is an integer from 1 to 3
  • c is an integer from 1 to 3
  • the agent (A) is the ready-to-use pretreatment agent (A).
  • the ready-to-use pretreatment agent (A) is prepared from the agent (A) shortly before use. This can be done, for example, by mixing the agent (A) containing the organic silicon compound of the formula (I) and / or (II) and formulated in a water-poor or anhydrous form with a further water-containing agent (A ').
  • the agent (B) may be the ready-to-use colorant (B).
  • the ready-to-use colorant (B) is prepared from the agent (B) shortly before use. This can be done, for example, by mixing the agent (B) containing the organic silicon compound of the formula (I) and / or (II) and formulated in a water-poor or anhydrous form with another hydrous agent (B ').
  • a preferred embodiment is therefore a multi-component packaging unit (kit-of-parts) for dyeing human hair, comprising separately packaged
  • a first container containing a substantially anhydrous agent (A) containing at least one organic silicon compound of formula (I) and / or (II) and further containing no substantive dyes and no pigments, and
  • the agents (B) and / or (B ') contains at least one coloring compound selected from the group of substantive dyes and pigments, and wherein the organic silicon compound of the formula (I) and / or (II) are the compounds which already described above.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (A) is substantially anhydrous and preferably - based on the total weight of the agent (A) - less than 5.0 wt .-% , more preferably less than 2.5 wt .-%, even more preferably less than 1, 0 wt .-% and most preferably less than 0.1 wt .-% water.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (B) is substantially anhydrous and preferably - based on the total weight of the agent (B) - less than 5.0 wt .-% , more preferably less than 2.5 wt .-%, even more preferably less than 1, 0 wt .-% and most preferably less than 0.1 wt .-% water.
  • the agents (A) and / or (B) may be in the form of a powder, for example. It is also possible to provide the agent (A) and / or (B) as a paste or as an oil. In this case, the organic silicon compounds of the formula (I) may be incorporated in an inert cosmetic carrier. In particular, fat components have proven suitable as inert cosmetic carriers.
  • fat components are understood as meaning organic compounds having a solubility in water at room temperature (22 ° C.) and atmospheric pressure (760 mmHg) of less than 1% by weight, preferably less than 0.1% by weight.
  • the definition of fat ingredients explicitly includes only uncharged (i.e., nonionic) compounds.
  • Fat ingredients have at least one saturated or unsaturated alkyl group having at least 8 C atoms.
  • the molecular weight of the fat constituents is at most 5000 g / mol, preferably at most 2500 g / mol and more preferably at a maximum of 1000 g / mol.
  • the fat components are neither polyoxyalkylated nor polyglycerylated compounds.
  • the preferred fat constituents are the constituents from the group of the C8-C30 fatty alcohols, the Ce-C3o fatty acid ethers, the Ce-Cso fatty acid monoglycerides, the Cs-C3o fatty acid diglycerides and / or or hydrocarbons understood.
  • the preferred fat constituents are the constituents from the group of the C8-C30 fatty alcohols, the Ce-C3o fatty acid ethers, the Ce-Cso fatty acid monoglycerides, the Cs-C3o fatty acid diglycerides and / or or hydrocarbons understood.
  • nonionic substances are explicitly considered as fat constituents.
  • Charged compounds such as fatty acids and their salts are not understood as a fat ingredient.
  • the Cs-C30 fatty alcohols may be saturated, mono- or polyunsaturated, linear or branched fatty alcohols having 8 to 30 carbon atoms.
  • Examples of preferred linear, saturated Cs-Cso fatty alcohols are dodecan-1-ol (dodecyl alcohol, lauryl alcohol), tetradecan-1-ol (tetradecyl alcohol, myristyl alcohol), hexadecan-1-ol (hexadecyl alcohol, cetyl alcohol, palmityl alcohol), octadecane 1-ol (octadecyl alcohol, stearyl alcohol), arachyl alcohol (eicosa n-1-ol), heneicosyl alcohol (heneicosan-1-ol) and / or behenyl alcohol (docosan-1-ol).
  • Preferred linear, unsaturated fatty alcohols are (9Z) octadec-9-en-1-ol (oleyl alcohol), (9E) octadec-9-en-1-ol (elaidyl alcohol), (9Z, 12Z) octadeca-9 , 12-diene-1-ol (linoleyl alcohol), (9Z, 12Z, 15Z) - octadeca-9,12,15-triene-1-ol (linolenoyl alcohol), gadoleyl alcohol ((9Z) -eicos-9-ene).
  • the preferred representatives of branched fatty alcohols are 2-octyl-dodecanol, 2-hexyl-dodecanol and / or 2-butyl-dodecanol.
  • a C8-C30 fatty acid glycerol is understood as meaning the triester of the trihydric alcohol glycerol with three equivalents of fatty acid. Both structurally identical and different fatty acids within a triglyceride molecule can be involved in the ester formation.
  • fatty acids are to be understood as meaning saturated or unsaturated, unbranched or branched, unsubstituted or substituted Cs-C30-carboxylic acids.
  • Unsaturated fatty acids may be monounsaturated or polyunsaturated.
  • For an unsaturated fatty acid its C-C double bond (s) may have the cis or trans configuration.
  • the fatty acid triglycerides are characterized by particular suitability in which at least one of the ester groups is formed starting from glycerol with a fatty acid which is selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosaic acid (lignoceric acid), Octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid ], Elaidic acid [(9E) -octadec-9-enoic acid, erucic acid [(13Z) -doco
  • the fatty acid triglycerides may also be of natural origin.
  • the fatty acid triglycerides or mixtures thereof occurring in soybean oil, peanut oil, olive oil, sunflower oil, macadamia nut oil, moringa oil, apricot kernel oil, marula oil and / or optionally hardened castor oil are particularly suitable for use in the product according to the invention.
  • a C8-C30 fatty acid monoglyceride is understood as meaning the monoester of the trivalent alcohol glycerol with one equivalent of fatty acid. In this case, either the middle hydroxyl group of the glycerol or the terminal hydroxyl group of the glycerol may be esterified with the fatty acid.
  • the Ce-Cso-fatty acid monoglycerides are characterized by particular suitability in which a hydroxy group of glycerol is esterified with a fatty acid, the fatty acids being selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosaic acid ( Lignoceric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec 9-enoic acid], elaidic acid [(9E) -octadec-9-enoic acid], erucic
  • a ce-cao fatty acid diglyceride is meant the diester of the trihydric alcohol glycerol with two equivalents of fatty acid.
  • either the middle and one terminal hydroxy group of glycerol may be esterified with two equivalents of fatty acid, or both terminal hydroxy groups of glycerol are esterified with one fatty acid.
  • the glycerol may be esterified with two structurally identical as well as with two different fatty acids.
  • the fatty acids are particularly suitable in which at least one of the ester groups is formed starting from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), Tetracosaic acid (lignoceric acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) Octadec-9-enoic acid], elaidic acid [(9E) -octadec-9-enoic acid], erucic acid [(13Z) -docos-13-enoic acid], linoleic
  • Ce-Cso-fatty acid esters are understood as meaning, in particular, the esters of Ce-C30-fatty acids with aliphatic C 1 -C 10 -alcohols.
  • the Ci-Cio alcohols can be linear. From a chain length of 3 C-atoms, the alcohols can also be branched.
  • Particularly suitable Cs-Cso fatty acid esters may be selected from the group consisting of isopropyl myristate (isopropyl myristate) and isopropyl stearate (isopropyl stearate).
  • Hydrocarbons are exclusively compounds consisting of the atoms carbon and hydrogen with 8 to 80 carbon atoms. Preference is given in this context in particular aliphatic hydrocarbons such as mineral oils, liquid paraffin oils (eg Paraffinium Liquidum or Paraffinum Perliquidum), isoparaffin oils, semi-solid paraffin oils, paraffin waxes, hard paraffin (Paraffinum Solidum), Vaseline and Polydecene.
  • Paraffinum Liquidum is a mixture of purified, saturated, aliphatic hydrocarbons, consisting mostly of hydrocarbon chains with a C-chain distribution of 25 to 35 carbon atoms.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the cosmetic preparation (A) one or more fat constituents from the group of Ce-Cso fatty alcohols, the Cs-C3o-Fettsä u retrig ly ce rid e, the Ce-C3o-fatty acid remonog lyce ride containing Cs-Cso fatty acid diglycerides, the Cs-Cso fatty acid esters and / or hydrocarbons.
  • Ce-C30 fatty alcohols and the hydrocarbons are particularly suitable as inert cosmetic carriers.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (A) contains one or more fat constituents from the group of Cs-C30 fatty alcohols and / or hydrocarbons.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (B) contains one or more fatty constituents from the group of Ce-Cso-fatty alcohols and / or hydrocarbons.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (A ') - based on the total weight of the agent (A') - 50 to 100 wt .-%, preferably 50 to 95 wt .-%, more preferably 60 to 95 wt .-% and most preferably 70 to 95 wt .-% water.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (B ') - based on the total weight of the agent (B') - 50 to 100 wt .-%, preferably 50 to 95 wt .-%, more preferably 60 to 95 wt .-% and most preferably 70 to 95 wt .-% water.
  • aqueous agents (A ') and / or (B') may also contain at least one acid.
  • Suitable acids can be selected from the organic and inorganic acids. Suitable organic acids are lactic acid, citric acid, tartaric acid, malic acid, 1-hydroxyethane-1, 1-diphosphonic acid, 2,6-dipicolinic acid, benzoic acid, maleic acid, succinic acid, oxalic acid, Ascorbic acid, phytic acid and / or gluconic acid. Suitable inorganic acids are phosphoric acid, sulfuric acid and hydrochloric acid.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (A ') at least one acid from the group of lactic acid, citric acid, tartaric acid, malic acid, 1-hydroxyethane-1, 1-diphosphonic acid, 2 , 6-dipicolinic acid, benzoic acid, phosphoric acid, sulfuric acid, hydrochloric acid, maleic acid, succinic acid, oxalic acid, ascorbic acid, phytic acid and / or gluconic acid.
  • the agent (A ') at least one acid from the group of lactic acid, citric acid, tartaric acid, malic acid, 1-hydroxyethane-1, 1-diphosphonic acid, 2 , 6-dipicolinic acid, benzoic acid, phosphoric acid, sulfuric acid, hydrochloric acid, maleic acid, succinic acid, oxalic acid, ascorbic acid, phytic acid and / or gluconic acid.
  • a multi-component packaging unit is particularly preferred, which is characterized in that the agent (B ') at least one acid from the group of lactic acid, citric acid, tartaric acid, malic acid, 1-hydroxyethane-1, 1-diphosphonic acid, 2 , 6-dipicolinic acid, benzoic acid, phosphoric acid, sulfuric acid, hydrochloric acid, maleic acid, succinic acid, oxalic acid, ascorbic acid, phytic acid and / or gluconic acid.
  • the agent (B ') at least one acid from the group of lactic acid, citric acid, tartaric acid, malic acid, 1-hydroxyethane-1, 1-diphosphonic acid, 2 , 6-dipicolinic acid, benzoic acid, phosphoric acid, sulfuric acid, hydrochloric acid, maleic acid, succinic acid, oxalic acid, ascorbic acid, phytic acid and / or gluconic acid.
  • the ready-to-use colorant (B) was prepared.
  • the agents (B) and (B ') were each shaken together for 3 minutes. Then the colorant (B) was allowed to stand for about 5 minutes and then applied to strands of hair. 2.
  • the pretreatment agent (A) and the colorant (B) were each applied with a brush to strands of hair (Kerling 6-0) and allowed to act for the specified period of time.
  • the hair strands were each first washed with water and then washed with a shampoo and dried. Afterwards, the strands were visually evaluated. Thereafter, the strands were washed several times with a shampoo and visually scored again.
  • Example E1 the tresses were treated with the pretreatment agent (A).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne un procédé de coloration des cheveux, consistant notamment à appliquer sur les cheveux un agent de prétraitement (A), qui contient au moins un composé de silicium organique de formule (I) et/ou (II) et ne contient en outre aucun colorant direct ni aucun pigment, et un agent de coloration (B), qui contient au moins un composé de silicium organique de formule (I) et/ou (II) et qui contient en outre au moins un composé colorant choisi dans le groupe des colorants directs et/ou des pigments, les composés de silicium organiques des formules (I) et (II) étant définis comme suit : R1R2N-L-Si(OR3)a(R4)b (l), (R5O)c(R6)dSi-(A)e-[NR7-(A')]f-[O-(A")]g-[NR8-(A"')]h-Si(R6')d'(OR5')c' (II).
EP19704586.7A 2018-03-14 2019-02-07 Procédé de coloration des cheveux Withdrawn EP3764980A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102018203838.4A DE102018203838A1 (de) 2018-03-14 2018-03-14 Verfahren zum Färben von Haaren
PCT/EP2019/052975 WO2019174824A1 (fr) 2018-03-14 2019-02-07 Procédé de coloration des cheveux

Publications (1)

Publication Number Publication Date
EP3764980A1 true EP3764980A1 (fr) 2021-01-20

Family

ID=65365953

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19704586.7A Withdrawn EP3764980A1 (fr) 2018-03-14 2019-02-07 Procédé de coloration des cheveux

Country Status (6)

Country Link
US (1) US20200397684A1 (fr)
EP (1) EP3764980A1 (fr)
JP (1) JP2021517567A (fr)
CN (1) CN111885995A (fr)
DE (1) DE102018203838A1 (fr)
WO (1) WO2019174824A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019214470A1 (de) * 2019-09-23 2021-03-25 Henkel Ag & Co. Kgaa Kit und Verfahren zum Färben von keratinischem Material mit Aminosilikon und farbgebender Verbindung
DE102019219707A1 (de) * 2019-12-16 2021-06-17 Henkel Ag & Co. Kgaa Verfahren zum Färben von keratinischem Material, umfassend die Anwendung von einer siliciumorganischen Verbindung, Schellack, einer farbgebenden Verbindung und eines Nachbehandlungsmittels
DE102019219704A1 (de) * 2019-12-16 2021-06-17 Henkel Ag & Co. Kgaa Verfahren zum Färben von keratinischem Material, umfassend die Anwendung von einer siliciumorganischen Verbindung, eines Hydroxycarbonsäureesters, C1-C10-Alkohols und einer farbgebenden Verbindung
DE102019219709A1 (de) * 2019-12-16 2021-06-17 Henkel Ag & Co. Kgaa Verfahren zum Färben von keratinischem Material, umfassend die Anwendung von einer siliciumorganischen Verbindung, eines Hydroxycarbonsäureesters, einer farbgebenden Verbindung und eines Nachbehandlungsmittels

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2891143B1 (fr) * 2005-09-23 2007-11-16 Oreal Composition cosmetique comprenant un compose organique du silicium, et procede de mise en forme des cheveux
EP2168633B1 (fr) * 2008-09-30 2016-03-30 L'Oréal Composition cosmétique comprenant un composé organique du silicium comportant au moins une fonction basique, un polymère filmogène hydrophobe, un pigment et un solvant volatil
FR2936413B1 (fr) * 2008-09-30 2010-10-22 Oreal Utilisation d'une composition comprenant un compose organique du silicium comportant une fonction basique en pre traitement d'une composition comprenant un polymere filmogene hydrophobe, un pigment et un solvant volatil

Also Published As

Publication number Publication date
CN111885995A (zh) 2020-11-03
WO2019174824A1 (fr) 2019-09-19
US20200397684A1 (en) 2020-12-24
DE102018203838A1 (de) 2019-09-19
JP2021517567A (ja) 2021-07-26

Similar Documents

Publication Publication Date Title
EP3764980A1 (fr) Procédé de coloration des cheveux
EP4034076A1 (fr) Produit pour colorer une matière kératinique, contenant de l'aminosilicone, un composé chromophore et de l'huile d'ester
WO2021058157A1 (fr) Kit et procédé pour la coloration de matières kératiniques faisant appel à une silicone aminée et un composé chromophore
EP3764979A1 (fr) Kit de coloration des cheveux
EP4065070A1 (fr) Procédé d'amélioration de la sensation tactile de matières kératiniques colorées, en particulier des cheveux humains
EP4065077A1 (fr) Agent de coloration de matière kératinique, contenant de l'aminosilicone, un composé chromophore et un tensioactif contenant du phosphore
WO2021058230A1 (fr) Procédé de coloration de matières kératiniques au moyen d'un prémélange d'aminosilicone et d'un composé chromophore
WO2020254103A1 (fr) Produit de coloration d'une matière kératinique comprenant des aminosilicones et des pigments dans des rapports pondéraux spécifiques
WO2021058241A1 (fr) Kit et procédé de coloration de matières kératiniques au moyen d'aminosilicone et d'un composé chromophore
EP4167940A1 (fr) Substance pour colorer des fibres de kératine, contenant des émulsifiants non ioniques spécifiques, des pigments et des aminosilicones
EP3986362A1 (fr) Procédé de coloration d'une matière kératinique par mélange préalable d'un composée aminosilicone et d'un composée colorant
WO2021104700A1 (fr) Procédé d'amélioration de la rétention de couleur de matières kératiniques colorées, en particulier des cheveux humains
EP4034258A1 (fr) Produit pour colorer une matière kératinique, contenant de l'aminosilicone, un composé chromophore et un ester d'acide gras éthoxylé
WO2020254009A1 (fr) Procédé de coloration d'une matière kératinique
EP3986371A1 (fr) Produit de coloration d'une matière kératinique comprenant une aminosilicone, un composé colorant, un conservateur et un alcool gras éthoxylé
WO2021254721A1 (fr) Agent de coloration de fibres kératiniques contenant des pigments et des alkylméthicones en c2-c30
WO2020254102A1 (fr) Produit de coloration d'une matière kératinique comprenant une aminosilicone, un composé colorant, un conservateur et un constituant gras
WO2021058159A1 (fr) Produit pour colorer une matière kératinique, contenant de l'aminosilicone, un composé chromophore et un ester d'acide carbonique organique
WO2022167185A1 (fr) Agent de coloration de matières kératiniques, contenant au moins deux composés organosiliciés différents l'un de l'autre, au moins un pigment et au moins un composant gras liquide et/ou un solvant
WO2021058206A1 (fr) Nécessaire et procédé de coloration de matières kératiniques au moyen d'aminosilicone et d'un composé chromophore
EP4167948A1 (fr) Agent de coloration de matière kératinique, en particulier de cheveux humains, contenant des aminosilicones, des pigments et des alkylpolyglycosides

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20200824

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20220901