EP3758802A1

EP3758802A1 - Cosmetic composition to improve the resistance of a hairstyle

Info

Publication number: EP3758802A1
Application number: EP19706638.4A
Authority: EP
Inventors: Sebastian Dörr; Sophie Viala; Laurence Pottie
Original assignee: Covestro Intellectual Property GmbH and Co KG
Current assignee: Covestro Intellectual Property GmbH and Co KG
Priority date: 2018-02-27
Filing date: 2019-02-25
Publication date: 2021-01-06
Also published as: JP2021514978A; EP3530322A1; US20200390681A1; WO2019166364A1; CN111867681A

Abstract

The invention relates to a hairstyle-stabilizing composition, comprising an especially preferred amorphous, polyurethane urea with carboxyl or carboxylate groups. The invention further relates to the use of the especially preferred amorphous polyurethane urea for the production of a hairstyle-stabilizing composition, to a method for generating a water-stable hairstyle, and to a method for producing the hairstyle-stabilizing composition.

Description

Cosmetic composition for improving the durability of a hairstyle

The present invention relates to a hair styling stabilizing composition comprising a particularly preferred amorphous polyurethane urea having carboxy or carboxylate groups. Furthermore, the invention relates to the use of the special preferably amorphous polyurethaneurea for the production of a hairstyle-stabilizing composition as well as to a method for the generation of a water-stable hairstyle and to a method for the production of the hairstylist-stabilizing composition.

To design and stabilize versatile hairstyles products are used, which are known as hair fixatives. Hair fixatives are usually in the form of mousses or hair sprays, and they hardly differ in their composition. Mousse mousses are applied to damp hair as a tool to model the hairstyle. In contrast, hair sprays, hair creams, hair gels or hair waxes are applied to dry finished styled hair to fix the hairstyle for everyday wear.

In the case of hair sprays and mousses, the means for fixing or shaping the hairstyle are usually in the form of preparations which can be sprayed from aerosol containers, squeeze bottles or pump, spray or foam devices and which consist of an alcoholic, aqueous or aqueous-alcoholic solution of film-forming natural or consist of synthetic polymers. These polymers can be selected from the group of nonionic, cationic, amphoteric or anionic polymers.

As film-forming polymers, anionic or amphoteric polymers based on acrylates are frequently used in the prior art. However, the use of polyurethanes and polyurethane ureas as film formers is also known. Thus, for example, WO 2009/118105 A1 describes hair-setting compositions which obtain a polyurethaneurea which can be obtained by reacting a water-insoluble, non-water-dispersible isocyanate-functional polyurethane prepolymer with an amino-functional compound. The hair setting compositions disclosed herein are well-suited for stabilizing hairstyles until the next hair wash. However, hereby no hairstyles can be made sustainable that would outlast a hair wash.

The object of the present invention was therefore to overcome at least one disadvantage of the prior art, at least in part.

Furthermore, it was an object to provide a special composition that is hairstyle-stabilizing, particularly suitable for use on hair To achieve water resistance of the hereby formed hairstyle. In particular, it was an object to achieve a water resistance of the formed hairstyle with the special composition over several washes, in particular to bring about a water and washing resistance, the re-hairdressing of the hair after water contact or washing over at least one, preferably several water contact or washing steps makes unnecessary.

A further object was to provide a method which makes it possible to produce a water- and / or wash-resistant hairstyle, in particular to bring about resistance to water and washing, which involves re-hairing the hair after contact with water or washing via at least one, preferably several water-contact hairstyles. or washing steps unnecessary.

It is a further object of the invention to provide a process for the preparation of the particular composition having the above described properties.

An object of the invention is to provide a use of the special composition for the generation of waterproof hairstyles.

At least one of the objects is achieved by a composition according to the subject matter of claim 1 and its use for the generation of waterproof hairstyles. Particular embodiments are described in the dependent claims. Again, some of the tasks are accomplished by carrying out the process of making the particular polyurethaneurea.

[A1] A first aspect of the invention relates to a hair styling stabilizing composition comprising at least the following components:

(VI) a preferably amorphous polyurethaneurea (VI) obtainable by reacting at least

A) a preferably aliphatic polyisocyanate component having an average isocyanate functionality of> 1.8 and <2.6,

B) a polymeric polyol component,

C) an amino-functional chain extender component having at least 2 isocyanate-reactive amino groups, containing at least one amino-functional compound CI) which has no ionic or ionogenic groups and / or an amino-functional compound C2) which has ionic or ionogenic groups, D) optionally further hydrophilizing components which are different from C2),

E) optionally hydroxy-functional compounds having a molecular weight of 62 to 399 mol / g,

F) optionally a compound which has exactly one isocyanate-reactive group or a compound which has more than one isocyanate-reactive group, wherein only one of the isocyanate-reactive groups reacts under the reaction conditions selected with the isocyanate groups present in the reaction mixture, and

G) optionally an aliphatic polyisocyanate component having an average isocyanate functionality of> 2.6 and <4,

wherein the polyurethaneurea has at least one of the components C2) or D), and wherein the polyurethaneurea has carboxyl groups or carboxylate groups;

(V2) a polycarbodiimide component prepared from aliphatic or cycloaliphatic polyisocyanates.

A hairstyle-stabilizing composition is understood to mean a composition which, after application to the hair of a user and subsequent shaping of the hair, makes it possible to achieve a hairstyle, a higher water resistance or washing resistance than the hairstyle without applying the composition to the hairstyle Hair. In this case, the hairstyle-stabilizing composition can be applied as a component to the hair or as two. If the hair is treated by applying the hairstyle stabilizing composition in two steps, the polyurethaneurea (VI) is first applied to the hair as a single component and in a subsequent step the polycarbodiimide component (V2) or vice versa. If the treatment of the hair is carried out by applying the hairstylist-stabilizing composition in one step, the two components (VI) and (V2) already present mixed before treating the hair.

Water resistance is understood according to the invention to mean that the resistance of the hairstyle formed with the composition according to the invention to water is tested or determined. In this case, the hair is surrounded in a rinsing treatment at least in part with liquid water, so impregnated or rinsed here. The water can be any form of liquid water that comes in contact with hair in everyday life. examples for this are Drinking water, rainwater, swimming pool water (chlorinated, ozonated or otherwise sanitized), sea water or distilled water.

Washing resistance is understood according to the invention as meaning that the resistance of the hairstyle formed with the composition according to the invention to surfactant-containing water is tested or determined, the hair in this washing treatment being completely surrounded by the surfactant-containing water, ie rinsed therein.

Preferably, shaping the hair into a hairstyle is selected from the group consisting of: a. A smoothing of curly hair;

b. Curling in straight hair;

c. Reinforcing curls in already curly hair;

d. A combination of at least two of a. to c ..

Smoothing curly hair under a. can be carried out in any manner known to those skilled in the art, in particular by means of a smoothing device. Smoothing of curly hair preferably takes place by means of a smoothing iron, a smoothing rod or a similar smoothing device which is suitable for this purpose. Preferably, the smoothing device is designed so that it is equipped with the help of at least 150 ° C heated elements. The smoothing device is preferably suitable for smoothing curls to a degree of smoothness of at least 50%, or preferably at least 80%, or preferably at least 90%. The degree of smoothness is determined by determining the width of a strand of hair before and after smoothing by means of a ruler. A degree of smoothness of 50%, or 80%, or 90% means that the width of the strand of hair after step a. by 50%, or 80%, or 90% narrower compared to the width before step a. has become.

Curling in straight hair under b. can be carried out in any manner known to those skilled in the art, in particular by means of a curling device. Preferably, the curling of straight hair by means of a curling iron or similar curling generating device, which is suitable for this. Preferably, the curling device is designed such that it contains, for example, at temperatures of 40 to 80 ° C by means of curl-generating elements, which preferably can be easily heated. Preferably, the curler is suitable for producing curls to a degree of curl of at least 50%, or preferably at least 80%, or preferably at least 90%. The degree of curl is determined by determining the length of a strand of hair before and after curling by means of a ruler. A degree of curl of 50%, or 80%, or 90% means that the length of the strand of hair after step b. 50%, or 80%, or 90% shorter than before step b ..

Reinforcing the curls under c. is preferably done in the same way as the introduction of the curls under b. Alternatively or additionally, the strengthening of the curls under c. be carried out by the composition of the invention in preferably moist hair, the hair is then dried with or without aids. Preferably, the curler is suitable for creating curls to a curl degree of at least 30%, or preferably at least 40%, or preferably 50%. The degree of curl is determined by determining the length of a strand of hair before and after curling by means of a ruler. A degree of curl of 30%, or 40%, or 50% means that the length of the hair strand after step b. 30%, 40% or 50% shorter than before step c ..

Preferably, the shape of the finished hair remains at least 5%, preferably at least 7%, or preferably at least 10% after contact with water. In this case, the degree of preservation of the shape of the coiffured hair may preferably vary greatly depending on the type of treatment. Thus it makes a difference whether the hair was smoothed before the inventive use of the composition according to the invention or whether the hair was curled. The degree of preservation of the shape of the coiffed hair is hereinafter also referred to as "styling retention".

In the stabilization of the hairstyle by the composition according to the invention by means of a smoothing of the hair under a remains preferred. at least 50%, or preferably at least 60%, or preferably at least at least 70% or at least 80%, or at least 90% after contact with water, or the curling of the hair under b. at least 5%, or preferably at least 7%, or preferably at least 10%, or the curl under c. at least 5%, or preferably at least 7%, or preferably at least 10%.

Preferably, the hairstyle stabilizing composition has a weight ratio of the polyurethaneurea (VI) to the polycarbodiimide component (V2) in a range of 10: 1 to 1: 2, or preferably in a range of 5: 1 to 1: 1.5 , or preferably in a range of 4: 1 to 1: 1.

Preferably, the reaction mixture of (VI) and (V2) in the preparation of the hairstyle stabilizing composition has a molar ratio of the carboxy or carboxylate groups (VI) to carbodiimide groups from (V2) in a range from 5: 1 to 1: 5, or preferably in a range from 2: 1 to 1: 2, or preferably in a range from 1.3: 1 to 1: 1, 3 on.

Preferably, the polyurethaneurea (VI) of the composition is amorphous. Amorphous in the context of this invention means that the polyurethaneurea in the temperature range mentioned in the following measuring method forms no or only so small crystalline fractions that only one or more glass transition points T _{g are obtained} by means of the described DSC measurements, but no melting ranges with a melting enthalpy> 20 J / g can be found in said temperature range.

Preferably, the hairstyle stabilizing composition has a weight ratio of the polyurethaneurea (VI) to the polycarbodiimide component (V2) in a range of 80: 1 to 1.2: 1, or preferably in a range of 60: 1 to 2: 1 , or preferably in a range of 40: 1 to 4: 1.

Preferred amorphous polyurethane ureas in the context of the invention are polymeric compounds which have at least two, preferably at least three urethane groups-containing repeat units:

According to the invention, the preferably amorphous polyurethane ureas also have urea group-containing repeating units as a result of the preparation,

as formed in particular in the reaction of isocyanate-terminated prepolymers with amino-functional compounds.

Within the meaning of this invention, ionogenic groups are understood as meaning those functional groups which are capable of forming ionic groups, for example by neutralization with a base.

The polyurethaneurea (VI) according to the invention has carboxyl groups or carboxylate groups. These can be introduced into the polyurethaneurea by any of the components A) to G) or other components used. The carboxy groups or carboxylate groups are preferably introduced by component B). Preferably, the polyurethaneurea (VI) of the composition has a content of carboxy groups and / or carboxylate groups in a range of 0.01 to 10 wt%, or preferably in a range of 0.02 to 8 wt%, or preferably in a range of 0.05 to 5 wt .-%, based on the total mass of the polyurethane urea.

Examples of components which contain carboxy groups or carboxylate groups and can be used as building blocks for the preparation of (VI) are dimethylolpropionic acid, hydroxypivalic acid, natural and non-natural amino acids, such as 6-aminohexanoic acid, alanine, aspartic acid, glutamic acid, glutamine, glycine, Lysine, leucine, isoleucine or mixtures of at least two thereof.

Component A) may be any polyisocyanate that would be used by one skilled in the art. Suitable polyisocyanates which are preferred as component A) are, in particular, those known per se to the person skilled in the art, preferably aliphatic polyisocyanates having an average isocyanate functionality of> 1.8 and <2.6. The term aliphatic also encompasses cycloaliphatic and / or araliphatic polyisocyanates.

The average isocyanate functionality is understood to mean the average number of isocyanate groups per molecule.

[A2] Preferred polyisocyanates are those of the molecular weight range of 140 to 336 g / mol. In a preferred embodiment of the hairstyle stabilizing composition, the polyisocyanate is the polyisocyanate component A) selected from the group consisting of toluene-2,4-diisocyanate (TDI), 2,2'-diphenylmethane diisocyanate (2,2'-MDI), 2, 4'-diphenylmethane diisocyanate (4,4'-MDI), 4,4'-diphenylmethane diisocyanate (4,4'-MDI), 4-di-iso-cyanato-butane (BDI), 1,5-pentane diisocyanate, (PDI) 1,6-di-isocyanato-hexane (HDI), 1,3-bis (isocyanatomethyl) benzene (1,3-xylylene diisocyanate, XDI), 1,4-bis (isocyanatomethyl) benzene (1,4-xylylene diisocyanate, XDI) , 1,3-bis (1-isocyanato-1-methyl-ethyl) benzene (TMXDI), 1, 4-bis (1-isocyanato-1-methyl-ethyl) benzene (TMXDI), 4-isocyanatomethyl-l , 8-octane diisocyanate (Trisisocyanatono-man (TIN)), 2-methyl-l, 5-diisocyanatopentane, l, 5-di-isocyanato-2,2-dimethyl-pentane, 2,2,4- and 2,4 , 4-trimethyl-l, 6-diisocyanato-hexane, 1,10-di-iso-cyanato-decane and the cycloaliphatic diisocyanates 1,3- and 1,4-di-isocyanatocy clohexane, l, 4-di-isocyanato 3,3,5-tri methylcyclohexane, 1,3-diisocyanato-2 (4) -methylcyclohexane, 1-iso-cyanato-3,3,5-tri-methyl-5-isocyanatomethylcyclohexane (isophorone diisocyanate, IPDI), Isocyanato-1-methyl-4 (3) isocyanato-methyl-cyclohexane, 1,8-diisocyanato-n-pentane, 4,4'-diisocyanato-1'-bi (cyclohexyl), 4 , 4'-diisocyanato-3,3'-dimethyl-1, 1'-bi (cyclohexyl), 4,4'-diisocyanato-2,2 ', ^5,5, -tetramethyl- 1,1' bi (cyclohexyl), 4,4 'and / or 2,4'-diisocyanato-dicyclohexylmethane, 4,4'-diisocyanato-3,3'-dimethyldicyclohexylmethane, 4,4'-diisocyanato-3,3', 5,5 Tetra-methyl-dicyclohexylmethane, 1,3-diisocyanatoadamantane, and l, 3-dimethyl-5,7-diisocyanato-toadamantane or any mixtures of such isocyanates. The polyisocyanates are very particularly preferably selected from 1,4-butylene diisocyanate, 1,5-pentamethylene diisocyanate (PDI), 1,6-hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), 2,2,4- and / or 2,4,4-trimethyl-hexa-methyl-3'-diiso-cyanate, the isomeric bis (4,4'-isocyanatocyclohexyl) -methanes or mixtures thereof of any isomeric content (H12 -MDI), 1,4-cyclohexylene diisocyanate, 4-isocyanatomethyl-l, 8-octane diisocyanate (nonane triisocyanate) and alkyl 2,6-diisocyanatohexanoate (Fysin diisocyanate) with Cl-C 8 alkyl groups or mixtures of at least two thereof ,

The present invention preferably relates to the composition according to the invention, wherein the polyisocyanate A) is selected from the group consisting of 1,4-butylene diisocyanate, 1,6-hexamethylene diisocyanate (HDI), 2,2,4 and / or 2,4,4- Trimethylhexamethylendiisocyanat, the isomeric bis (4,4'-isocyanatocyclohexyl) methanes or mixtures thereof any isomer content, 1,4-cyclohexylene diisocyanate, 1,4-phenylene diisocyanate, 2,4- and / or 2,6-toluene diisocyanate, 1.5 Naphthylene diisocyanate, 2,2'-and / or 2,4'- and / or 4,4'-di-phenylmethane diisocyanate, 1,3- and / or 1,4-bis- (2-isocyanato-prop-2-yl) yl) benzene (TMXDI), 1,3-bis (isocyanatomethyl) benzene (XDI), alkyl 2,6-diisocyanatohexanoate (lysine diisocyanates) with C 1 -C 8 -alkyl groups, and also 4-isocyanatomethyl-l, 8-octanediisocyanate (nonane triisocyanate ) and triphenylmethane-4,4 ', 4 "-triisocyanate or a mixture of at least two thereof.

In addition to the abovementioned polyisocyanates, it is also possible to use modified diisocyanates which have an average isocyanate functionality> 2 and <2.6 with uretdione, isocyanurate, urethane, allophanate, biuret, iminooxadiazinedione or oxadiazinetrione structure and mixtures of these and / or the above proportionally used.

Preference is given to polyisocyanates or polyisocyanate mixtures of the abovementioned type with exclusively aliphatically or cycloaliphatically bonded isocyanate groups or mixtures of these and an average NCO functionality of the mixture of> 1.8 and <2.6 and particularly preferably> 2.0 and < 2.4.

[A3] In a preferred embodiment of the hair styling stabilizing composition, component A) contains an aliphatic or cycloaliphatic polyisocyanate. The polyisocyanate of the polyisocyanate component A) is preferably selected from the group consisting of HDI, IPDI and / or H12-MDI or their modification products, very particularly preferably selected from HDI and / or IPDI. In a particularly preferred variant, component A) comprises IPDI and HDI in a mixture.

Preferably, the weight ratio of IPDLHDI for the polyisocyanate component A) is in a range of 1.05 to 10, more preferably in a range of 1.1 to 5, and most preferably in a range of 1.1 to 1.5 ,

In a preferred embodiment, for the preparation of the preferably amorphous polyurethaneurea used according to the invention,> 5 and <40% by weight of component A) and particularly preferably> 10 and <35% by weight of component A), in each case based on the total mass of the latter, is preferred amorphous polyurethaneurea used.

Also preferred for the preparation of the preferably amorphous polyurethaneurea and the component G), an aliphatic polyisocyanate component having an average isocyanate functionality (average number of isocyanate groups per molecule) of> 2.6 and <4, preferably> 2.8 and <3.8 used. Component G) is preferably used in admixture with component A).

Particularly suitable as component G) are oligomeric diisocyanates which have a functionality of> 2.6 and <4, preferably> 2.8 and <3.8, with isocyanurate, urethane, allophanate, biuret, aminooxadiazinedione or oxadiazinetrione structure , Most preferably, G) contains isocyanurate structures.

Preferably, the aliphatic polyisocyanate component G) consists of an aliphatic or cy cloaliphatischen polyisocyanate oligomer based on HDI, IPDI and / or H12-MDI, most preferably based on HDI.

The molar ratio of the NCO groups from component A) to component G) is preferably 100: 0.5 to 100: 50; more preferably 100: 2 to 100: 15, and most preferably 100: 3 to 100: 8.

For the preparation of the preferably amorphous polyurethane urea used according to the invention, preference is given to> 0 and <10% by weight of component G) and particularly preferably> 0.1 and <3% by weight of component G, in each case based on the total mass of the preferably amorphous polyurethaneurea used.

Suitable di- or higher-functional polymeric polyols B) are compounds having at least two isocyanate-reactive hydrogen atoms and an average molecular weight preferably in a range from 400 to 10,000 g / mol, or preferably from 500 to 8,000 g / mol, or preferably from 1000 to 5000 g / mol, determined by gel permeation chromatography over polystyrene standard in tetrahydrofuran at 23 ° C. Examples of suitable structural components are polyethers, polyesters, polycarbonates, polylactones and polyamides. Preferred polyols B) have 2 to 4, more preferably 2 to 3 hydroxyl groups. Mixtures of such compounds are also possible.

Suitable polyester polyols are, in particular, linear polyester diols or else weakly branched polyester polyols, such as are known in known manner from aliphatic, cycloaliphatic or aromatic di- or polycarboxylic acids, such as, for example, Amber, methylsuccinic, glutaric, adipic, pimelic, cork, azelaic, sebacic, nonandicarboxylic, decanedicarboxylic, terephthalic, isophthalic, o-phthalic, tetrahydrophthalic, hexahydrophthalic, cyclohexanedicarboxylic, Maleic, fumaric, malonic or trimellitic acid and acid anhydrides, such as o-phthalic, trimellitic or succinic anhydride or mixtures thereof with polyhydric alcohols, such as Ethanediol, di-, tri-, tetraethylene glycol, 1,2-propanediol, di-, tri-, tetra-propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 2,3-butanediol, pentanediol 1.5, 1,6-hexanediol, 2,2-dimethyl-1,3-propanediol, 1,4-dihydroxycyclohexane, 1,4-dimethylolcyclohexane, octanediol-1,8, decanediol-1,10, dodecanediol-1 , 12 or mixtures thereof, optionally with the concomitant use of higher functional polyols, such as trimethylolpropane, glycerol or pentaerythritol, can be prepared. Of course, cycloaliphatic and / or aromatic di- and polyhydroxyl compounds are also suitable as polyhydric alcohols for the preparation of the polyester polyols. Instead of the free polycarboxylic acid, it is also possible to use the corresponding polycarboxylic acid anhydrides or corresponding polycarboxylic acid esters of lower alcohols or mixtures thereof to prepare the polyesters.

Of course, the polyester polyols may also be homopolymers or copolymers of lactones, preferably by addition of lactones or lactone mixtures such as butyrolactone, e-caprolactone and / or methyl-s-caprolactone to the suitable di- and / or higher-functional starter molecules , such as the low molecular weight, polyhydric alcohols mentioned above as synthesis components for polyesterpolyols. The corresponding polymers of e-caprolactone are preferred.

Particularly preferred are substantially linear polyester polyols containing as structural components adipic acid and 1,4-butanediol and / or 1,6-hexanediol and / or 2,2-dimethyl-1,3-propanediol.

Hydroxyl-containing polycarbonates are also suitable as polyhydroxyl components, for example those which are obtained by reacting diols, such as 1,4-butanediol and / or 1,6-hexanediol with diaryl carbonates, such as diphenyl carbonate, dialkyl carbonates, such as. For example, dimethyl carbonate or phosgene can be prepared. The at least partial use of hydroxyl-containing polycarbonates, the hydrolysis resistance of the polyurethane or polyurethane-urea dispersions can be improved.

Preference is given to polycarbonates which have been prepared by reacting 1,6-hexanediol with dimethyl carbonate.

Suitable polyether polyols are e.g. the polyaddition of the styrene oxides, ethylene oxide, propylene oxide, tetrahydrofuran, butylene oxide, epichlorohydrin, and their Mischadditions- and graft products, as well as by condensation of polyhydric alcohols or mixtures thereof and obtained by alkoxylation of polyhydric alcohols, amines and amino alcohols polyether polyols. As polyol components B) suitable polyether polyols are the homo-, mixed and graft polymers of propylene oxide and ethylene oxide, which by addition of said epoxides to low molecular weight di- or triols, as mentioned above as synthesis components for polyester or higher polyfunctional low molecular weight polyols such as Pentaerythrid or sugar or are accessible to water.

Particularly preferred di- or higher-functional polyols B) are polyester polyols, polylactones and polycarbonates.

The polymeric polyether polyols preferably used as component B) preferably have number-average molecular weights in a range of 400 to 8000 g / mol, preferably in a range of 600 to 6000 g / mol, or preferably in a range of 1000 to 3000 g / mol as determined by gel permeation chromatography over polystyrene standard in tetrahydrofuran at 23 ° C, and / or an OH functionality of preferably in a range of 1.5 to 6, or preferably in a range of 1.8 to 3, or preferably in one Range from 1.9 to 2.1. The term "polymeric" polyether polyols means here in particular that said polyols have at least two, preferably at least three interconnected repeat units.

The number average molecular weight is always determined in the context of this application by gel permeation chromatography (GPC) in tetrahydrofuran at 23 ° C. The procedure is according to DIN 55672-1: "Gel Permeation Chromatography, Part 1 - Tetrahydrofuran as Eluent" (SECurity GPC system from PSS Polymer Service, flow rate 1.0 ml / min, columns: 2xPSS SDV linear M, 8 × 300 mm, 5 μm RfD detector). In this case, polystyrene samples of known molecular weight to Calibration used. The calculation of the number average molecular weight is software-based. Baseline points and evaluation limits are defined in accordance with DIN 55672 Part 1.

Suitable polyether polyols are, for example, the per se known addition products of styrene oxide, ethylene oxide, propylene oxide, butylene oxide and / or epichlorohydrin to di- or polyfunctional starter molecules. Thus, in particular polyalkylene glycols, such as polyethylene, polypropylene and / or polybutylene glycols are applicable, in particular with the above-mentioned preferred molecular weights. As suitable starter molecules, it is possible to use all compounds known from the prior art, for example water, butyldiglycol, glycerol, diethylene glycol, trimethylolpropane, propylene glycol, sorbitol, ethylenediamine, triethanolamine, 1,4-butanediol.

[A4] In a preferred embodiment of the hair styling stabilizing composition, component B) comprises poly (propylene glycol) polyether polyols. Preferably, the hairstyle stabilizing composition comprises poly (propylene glycol) polyether polyols in a range of 50 to 100 wt%, or preferably in a range of 70 to 100 wt%, or preferably in a range of 90 to 100 wt%, particularly preferably 100% by weight, in each case based on the total weight of component B).

If component B) has more than 50% by weight of poly (propylene glycol) polyetherpolyols, based on the sum of all constituents of component B), then a small amount of component F) is optionally used or preferably component F) is not used at all. If component B) is to be more than 10% by weight, preferably more than 20% by weight or preferably more than 30% by weight, based on the sum of all constituents of component B) of poly, to prepare the hairstyle-stabilizing composition (tetramethylene) polyether polyols, it is preferred that component F) is present.

[A5] In a preferred embodiment of the hairstylist-stabilizing composition, component B) has an average molecular weight in a range of 400 to 4000 g / mol, or preferably in a range of 500 to 3500 g / mol, or preferably in a range of 800 to 3000 g / mol.

[A6] In a preferred embodiment of the composition, component B) comprises or consists of a mixture of poly (propylene glycol) polyether polyols having different average molecular weight, wherein the poly (propylene glycol) polyether polyols are at least 100 g / mol in their number average molecular weights at least 200 g / mol, or preferably by at least 400 g / mol, or preferably by at least 800 g / mol, or preferably differ by at least 1000 g / mol. The number-average molecular weights of the poly (propylene glycol) polyether polyols preferably do not differ by more than 5000 g / mol, or by more than 4000 g / mol, or by more than 3000 g / mol.

Component B) preferably comprises a mixture of poly (propylene glycol) polyether polyols I having a number-average molecular weight Mn of> 400 and <1500 g / mol, more preferably of> 600 and <1200 g / mol, most preferably of 1000 g / mol and

Poly (propylene glycol) polyether polyols II having a number average molecular weights Mn of> 1500 and <8000 g / mol, more preferably of> 1800 and <3000 g / mol, most preferably of 2000 g / mol.

The weight ratio of the poly (propylene glycol) polyether polyols I to the poly (propylene glycol) polyether polyols II is preferably in the range from 0.01 to 10, particularly preferably in the range from 0.02 to 5, very particularly preferably in the range from 0.05 to 1 ,

[A7] In another preferred embodiment of the hairstylist stabilizing composition, the polyol B) is selected from the group consisting of succinic, methylsuccinic, glutaric, adipic, pimelic, cork, azelaic, sebacic, nonandicarboxylic , Decanedicarboxylic, terephthalic, isophthalic, o-phthalic, tetrahydrophthalic, hexahydrophthalic, cyclohexanedicarboxylic, maleic, fumaric, malonic or trimellitic acid and acid anhydrides, such as o-phthalic, trimellitic or succinic anhydride or their mixtures with polyhydric alcohols, such as Ethanediol, di-, tri-, tetraethylene glycol, 1,2-propanediol, di-, tri-, tetra-propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 2,3-butanediol, pentanediol 1.5, 1,6-hexanediol, 2,2-dimethyl-1,3-propanediol, 1,4-dihydroxycyclohexane, 1,4-dimethylolcyclohexane, octanediol-1,8, decanediol-1,10, dodecanediol-1 , 12 or a mixture of at least two of them.

In the preparation of the preferably amorphous polyurethaneurea is an amino-functional chain extender component C) having at least 2 isocyanate-reactive amino groups containing at least one amino functional compound CI), which has no ionic or ionogenic groups and / or an amino-functional compound C2), the ionic or ionic groups has used.

The amino-functional compounds of component C) component are preferably selected from primary and / or secondary diamines. In particular, the amino-functional compounds C) comprise at least one diamine. [A8] In a preferred embodiment of the hairstylist-stabilizing composition, the amino-functional component C) comprises at least one amino-functional compound C2) which has ionic and / or ionogenic groups. The amino-functional compound C2) is obligatory if the component D) is not present in the aqueous polyurethane-urea dispersion for the preparation of the hairstyle-stabilizing composition according to the invention.

The amino-functional component C) preferably comprises both amino-functional compounds C2) which have ionic and / or ionogenic groups and amino-functional compounds CI) which have no ionic or ionogenic group.

For example, as component CI) organic di- or polyamines such as 1,2-ethylenediamine, 1,2- and 1,3-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, isophorone diamine (IPDA), isomer mixture of 2,2,4- and 2,4,4-trimethylhexamethylenediamine, 2-methylpentamethylenediamine, diethylenetriamine, 4,4-diaminodicyclohexylmethane and / or dimethylethylenediamine or mixtures of at least two thereof.

Preferably, the component CI) is selected from the group consisting of 1,2-ethylenediamine, bis (4-aminocyclohexyl) methane, 1,4-diaminobutane, IPDA, ethanolamine, diethanolamine and diethylenetriamine or a mixture of at least two thereof.

Preferably, the component contains CI)> 75 mol%, particularly preferably> 80 mol%, very particularly preferably> 85 mol%, more preferably> 95 mol% and further preferably 100 mol% of 1,2-ethylenediamine or IPDA or a mixture of 1,2-ethylenediamine and IPDA, wherein the sum of the two amines in relation to the total amount of CI) is preferably present in the proportions mentioned for component CI).

The hydrophilizing component C2) preferably comprises at least one anionically hydrophilizing compound. Further preferably, the hydrophilizing component comprises C2) an anionic hydrophilicizing compound to at least 80 wt .-%, or preferably at least 90 wt .-%, based on the total weight of component C2). The component C2) particularly preferably consists of exclusively anionically hydrophilicizing compounds.

Suitable anionic hydrophilizing compounds contain at least one anionic or ionogenic group which can be converted into an anionic group. Furthermore, suitable anionic hydrophilicizing compounds preferably have at least two amino groups and particularly preferably two amino groups. Particularly preferably, the hydrophilizing Component C2) an anionic hydrophilizing compound which has at least one anionic or ionogenic group and at least two amino groups or consists thereof.

Suitable anionically hydrophilicizing compounds as component C2), also referred to below as hydrophilizing agent C2), preferably contain a sulfonic acid or sulfonate group, more preferably a sodium sulfonate group. Suitable anionically hydrophilicizing compounds as component C2) are, in particular, the alkali metal salts of mono- and diaminosulfonic acids. Examples of such anionic hydrophilicizing agents are salts of 2- (2-aminoethylamino) ethanesulfonic acid, ethylenediamine-propyl- or -butylsulfonic acid or 1,2- or 1,3-propylenediamine-β-ethylsulfonic acid or mixtures of at least two thereof.

Particularly preferred anionic hydrophilicizing agents C2) are those which contain sulfonate groups as ionic groups and two amino groups, such as the salts of 2- (2-aminoethylamino) ethylsulfonic acid and 1,3-propylenediamine-β-ethylsulfonic acid. Very particular preference is given to using 2- (2-aminoethylamino) ethylsulfonic acid or salts thereof as the anionic hydrophilicizing agent C2).

Optionally, the anionic group in the component C2) may also be a carboxylate or carboxylic acid group. Examples of carboxylic acids are 6-aminohexanoic acid, alanine, aspartic acid, glutamic acid, glutamine, glycine, lysine, leucine and isoleucine or mixtures of at least two thereof. Further examples of suitable substances for component C2) are preferably selected from diaminocarboxylic acids. An example of diaminocarboxylic acids is lysine.

However, in this alternative embodiment, the carboxylic acid-based components C2) must be used in higher concentrations compared to those components C2) carrying sulfonate or sulfonic acid groups. For this reason, particularly preferred for the production of the preferably amorphous polyurethaneurea are hydrophilizing compounds which use exclusively carboxylate groups as anionic groups of component C2).

For the preparation of the preferably amorphous polyurethane urea used according to the invention, preference is given to> 0.1 and <10% by weight of component C2) and particularly preferably> 0.5 and <4% by weight of component C2), in each case based on the total mass of preferably amorphous polyurethaneurea used.

For hydrophilization it is also possible to use mixtures of anionic hydrophilicizing agents C2) and further hydrophilicizing agents D) which are different from C2). Suitable further hydrophilicizing agents D) are, for example, nonionic hydrophilizing compounds D1) and / or hydroxy-functional ionic or ionic hydrophilicizing agents D2).

[A9] In a preferred embodiment of the hairstylist-stabilizing composition, component D) is exclusively non-ionically hydrophilicizing components D1).

Suitable hydroxy-functional ionic or ionic hydrophilicizing agents as component D2) are, for example, hydroxycarboxylic acids such as mono- and dihydroxycarboxylic acids such as 2-hydroxyacetic acid, 3-hydroxypropanoic acid, 12-hydroxy-9-octadecanoic acid (ricinoleic acid), hydroxypivalic acid, lactic acid, dimethylolbutyric acid and / or dimethylolpropionic acid or mixtures from at least two of them. Hydroxypivalic acid, lactic acid and / or dimethylolpropionic acid are preferred, and dimethylolpropionic acid is particularly preferred. Preference is given to using no hydroxy-functional ionic or ionogenic hydrophilicizing agents D2), particularly preferably no hydrophilicizing agents which contain carboxylate and hydroxyl groups, for example dimethylolpropionic acid. The amount of hydroxy-functional ionic or ionic hydrophilicizing agent D2) is preferably in a range from 0 to 1% by weight, or preferably in a range from 0.01 to 0.5% by weight, based on the total mass of the preferably amorphous polyurethaneurea in which preferably contain amorphous polyurethane urea.

Suitable nonionically hydrophilicizing compounds as component D1) are e.g. Polyoxyalkylene ethers which have isocyanate-reactive groups, such as hydroxyl, amino or thiol groups. Preference is given to monohydroxy-functional polyalkylene glycols containing on average from 5 to 70, preferably from 7 to 55, ethylene oxide units per molecule, as are obtainable in a manner known per se by alkoxylation of suitable starter molecules (for example in Ullmanns Encyclopadie der technischen Chemie, 4th Edition, Volume 19 , Verlag Chemie, Weinheim pp. 31-38). These are either pure polyethylene oxide ethers or mixed polyalkylene oxide ethers, wherein they contain at least 30 mol%, preferably at least 40 mol% based on all alkylene oxide units contained in ethylene oxide units.

Particularly preferred nonionic compounds are monofunctional mixed polyalkylene oxide polyethers having from 40 to 100 mole percent ethylene oxide and from 0 to 60 mole percent propylene oxide units.

Suitable starter molecules for such nonionic hydrophilicizing agents are, in particular, saturated monoalcohols, such as methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, sec-butanol, the isomeric pentanoie, hexanoie, octanols and nonanols, n-decanol, n-dodecanol, n-tetradecanol, n-hexadecanol, n-octadecanol, cyclohexanol, the isomeric methylcyclohexanols or hydroxymethylcyclohexane, 3-ethyl-3-hydroxymethyloxetane or Tetrahydrofurfuryl alcohol, diethylene glycol monoalkyl ethers, such as diethylene glycol monobutyl ether, unsaturated alcohols such as allyl alcohol, 1,1-dimethylallyl alcohol or oleic alcohol, aromatic alcohols such as phenol, the isomeric cresols or methoxyphenols, araliphatic alcohols such as benzyl alcohol, anisalcohol or cinnamyl alcohol, secondary monoamines such as dimethylamine, diethylamine, Dipropylamine, diisopropylamine, dibutylamine, bis (2-ethylhexyl) amine, N-methyl and N-ethylcyclohexylamine or dicyclohexylamine, and heterocyclic secondary amines such as morpholine, pyrrolidine, piperidine or 1H-pyrazole. Preferred starter molecules are saturated monoalcohols of the abovementioned type. Particular preference is given to using diethylene glycol monobutyl ether, methanol or n-butanol as starter molecules.

Alkylene oxides which are suitable for the alkoxylation reaction are, in particular, ethylene oxide and propylene oxide, which can be used in any desired order or also as a mixture in the alkoxylation reaction.

Preferably, the preferably amorphous polyurethane urea contains> 0 and <20 wt .-% of component D), preferably> 0.1 and <10 wt .-% of component D) and very particularly preferably> 1 and <5 wt .-% of Component D), in each case based on the total mass of the preferably amorphous polyurethaneurea. In a further preferred embodiment, component D) is not used for the preparation of the preferably amorphous polyurethaneurea. In this case, component C2) is necessarily contained in the polyurethaneurea.

As component E) optionally polyols, in particular non-polymeric polyols, said molecular weight range of 62 to 399 mol / g having up to 20 carbon atoms, such as ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,3-butylene glycol, cyclohexanediol, 1,4-cyclohexanedimethanol, 1,6-hexanediol, neopentyl glycol, hydroquinone dihydroxyethyl ether, bisphenol A (2,2-bis (4-hydroxyphenyl) propane), hydrogenated bisphenol A (2,2-bis (4-hydroxycyclohexyl) propane), trimethylolpropane, trimethylolethane, glycerol, pentaerythritol and any mixtures thereof are used with each other.

The preferably amorphous polyurethaneurea preferably has <10% by weight of component E), or preferably <5% by weight of component E), in each case based on the total mass of the preferably amorphous polyurethaneurea. Preferably, the preferably amorphous polyurethane urea comprises component E) in a range of 0.1 to 10 wt .-%, or preferably in a range of 0.2 to 8 wt .-%, or preferably in a range of 0.1 to 5 wt .-%, based in each case on the total mass of the preferably amorphous polyurethane urea. In a further preferred embodiment, component E) is not used for the preparation of the preferably amorphous polyurethaneurea.

For the preparation of the preferably amorphous polyurethaneurea, preference is given to producing> 0.5 and <20% by weight of the sum of the components CI) and optionally E) and more preferably> 1 and <15% by weight of the sum of the components CI ) and optionally E), in each case based on the total mass of the preferably amorphous polyurethaneurea used.

Examples of di- or higher-functional polyol components having a molecular weight of from 62 to 399 which are suitable as component E) are the products listed under B), provided they have a molecular weight of from 62 to 399 g / mol. Other suitable components are the polyhydric, in particular dihydric, alcohols mentioned for the preparation of the polyesterpolyols, and also low molecular weight polyesterdiols, such as, for example, Adipic acid bis (hydroxyethyl) ester or short-chain initiated on aromatic diols homo- and Mischadditionsprodukte of ethylene oxide or propylene oxide in question. Examples of aromatic diols which can be used as starters for short-chain homopolymers and copolymers of ethylene oxide or of propylene oxide are, for example, For example, 1,4-, 1,3-, 1,2-dihydroxybenzene or 2,2-bis (4-hydroxyphenyl) propane (bisphenol A).

Furthermore, it is also possible to use monofunctional isocyanate-reactive hydroxyl group-containing compounds as component F). Examples of such monofunctional compounds are ethanol, n-butanol, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, dipropylene glycol mono-propyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, tripropylene glycol monobutyl ether, 2-ethylhexanol, 1-octanol. Dodecanol, 1-hexadecanol, which can also be used as mixtures of at least two of the mentioned. Preferably, the hairstyle stabilizing composition contains less than 10 wt .-% of component F), or preferably less than 5 wt .-% of component F), or preferably in a range of 0.01 to 5 wt .-%, each based to the total mass of the hair styling stabilizing composition, even more preferably, component F) is not used to prepare the hair styling stabilizing composition.

The hairstylist stabilizing composition preferably contains one or more auxiliary cosmetic substances V3) which are customary in cosmetics, such as antioxidants, antifoggants and / or other auxiliaries and additives such as emulsifiers, wetting agents such as surfactants, plasticizers such as glycerol, glycol and phthalate and ether, defoamers, thickeners and rheology modifiers, gelling detackifiers, surfactants, agents, humectants, filler, UV filters, film formers , Antifoam agents, coalescing agents, flavoring agents, odor absorbers, fragrances and perfumes, gelling agents and / or other polymer dispersions such as dispersions based on polyacrylates, pigments, dyes, anticorrosives, neutralizing agents, leveling agents and / or thixotropic agents, emollients, preservatives, proteins and derivatives thereof , Amino acids, vitamins, opacifiers, stabilizers, sequestering agents, complexing agents, pearlescers, esthetic enhancers, fatty acids, fatty alcohols, triglycerides, botanical extracts and clarifying agents. The compositions according to the invention preferably have one or more emulsifiers or surface-active agents.

The amounts of the various additives are known to the person skilled in the art for the field of hair cosmetics, in particular the hairstyle-stabilizing compositions, and are for example in the range of 0 to 25 wt .-%, preferably from 0 to 15 wt .-%, or preferably 0.001 to 15 wt .-%, or preferably for each individual additive each in a range of 0.001 to 5 wt .-%, or in each case preferably from 0.01 to 3 wt .-% based on the total weight of the composition.

Preferably, the hair styling stabilizing composition further comprises at least one of the following components:

V3) at least one cosmetically active substance and / or one or more auxiliary cosmetic substances,

V4) at least one solvent or thinner,

V5) at least one additional film former.

Thus, preferred hairstyle stabilizing composition in the form of oil-in-water emulsions (O / W) preferably contain at least one emulsifier having an HFB value> 7 and optionally a coemulsifier.

Advantageously, the following nonionic emulsifiers are used: a) partial fatty acid esters and fatty acid esters of polyhydric alcohols and their ethoxylated derivatives (eg glyceryl monostearate, sorbitan stearate, glyceryl stearyl citrate, sucrose stearate)

b) ethoxylated fatty alcohols and fatty acids.

Particularly advantageous nonionic O / W emulsifiers are ethoxylated fatty alcohols or fatty acids, preferably PEG-100 stearate, PEG-40 stearate, ceteareth-20, ceteth-20, steareth-20, ceteareth-12, ceteth-12, steareth-12 and esters of mono-, oligo- or polysaccharides with fatty acids, preferably cetearyl glucoside, methyl glucose distearate.

Advantageous anionic emulsifiers are soaps (eg sodium or triethanolamine salts of stearic or palmitic acid) and esters of citric acid such as glyceryl stearate citrate.

Suitable coemulsifiers for the novel O / W emulsions fatty alcohols having 8 to 30 carbon atoms, monoglycerol esters of saturated or unsaturated, branched or unbranched alkanecarboxylic acids having a chain length of 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms, propylene glycol esters of saturated or unsaturated, branched or unbranched alkanecarboxylic acids having a chain length of 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms, and sorbitan esters of saturated or unsaturated, branched or unbranched alkanecarboxylic acids having a chain length of 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms.

Particularly advantageous coemulsifiers are glyceryl monostearate, glyceryl monooleate, diglyceryl monostearate, sorbitan monoisostearate, sucrose distearate, cetyl alcohol, stearyl alcohol, behenyl alcohol, isobehenyl alcohol, and polyethylene glycol (2) stearyl ether (steareth-2).

It may be advantageous in the sense of the present invention to use further emulsifiers. Thus, for example, the water resistance of the preparations according to the invention can be further increased. Suitable emulsifiers are z. B. alkyl methicone copolyols and alkyl dimethicone copolyols, especially cetyl dimethicone copolyol, lauryl methicone copolyol, W / O emulsifiers such as sorbitan stearate, glyceryl stearate, glycerol stearate, sorbitan oleate, lecithin, glyceryl isostearate, polyglyceryl-3-oleate, polyglyceryl-3-diisostearate, PEG-7 hydrogenated castor oil, Polyglyceryl 4-isostearate, acrylate / Cio-3o-alkyl acrylate crosspolymer, sorbitan isostearate, poloxamer 101, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-3-diisostearate, polyglyceryl-4-dipolyhydroxystearate, PEG-30 dipolyhydroxystearate, diisostearoylpolyglyceryl-3-diisostearate , Glycol distearate and polyglyceryl-3-dipolyhydroxystearate. The hairstyle stabilizing compositions preferably contain thickeners, especially in the water phase, for example in an O / W composition. Advantageous thickeners are:

Crosslinked or non-crosslinked acrylic or methacrylic acid homopolymers or copolymers. These include crosslinked homopolymers of methacrylic acid or acrylic acid, copolymers of acrylic acid and / or methacrylic acid and monomers derived from other acrylic or vinyl monomers, such as C10-30 alkyl acrylates, C10-30 alkyl methacrylates and vinyl acetate.

Thickening polymers of natural origin, for example, based on cellulose, guar gum, xanthan, scleroglucan, gellan gum, rhamsan and karaya gum, alginates, maltodextrin, starch and its derivatives, locust bean gum, hyaluronic acid, carrageenan.

Nonionic, anionic, cationic or amphoteric associative polymers e.g. based on polyethylene glycols and their derivatives, or polyurethanes.

Crosslinked or non-crosslinked homopolymers or copolymers based on acrylamide or methacrylamide, such as homopolymers of 2-acrylamido-2-methylpropanesulfonic acid, copolymers of acrylamide or methacrylamide and methacryloyloxyethyltrimethylammonium chloride or copolymers of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid.

Particularly advantageous thickeners are thickening polymers of natural origin, crosslinked acrylic acid or methacrylic acid homo- or copolymers and crosslinked copolymers of 2-acrylamido-2-methylpropanesulfonic acid.

Very particularly advantageous thickeners are xanthan gum, such as the products supplied under the names Keltrol ^® and Kelza ^® from CP Kelco or the products from RHODIA with the name Rhodopol ^® and guar gum, as under the name Jaguar ^® HP105 by the company Rhodia available products.

Very particularly advantageous thickeners are crosslinked homopolymers of methacrylic acid or acrylic acid from Lubrizol under the names Carbopol ^® 940, Carbopol ^® 941, Carbopol ^® 980, Carbopol ^® 981, Carbopol ^® ETD 2001, Carbopol ^® EDT 2050, Carbopol ^® 2984 , Carbopol ^® 5984, and Carbopol ^® Ultrez 10 ^® from 3V under the names Synthalen K, Synthalen ^® L and Synthalen ^® MS and PROTEX under the names Modarez ^® V 1250 PX, Modarez ^® V2000 PX, Viscaron ^® A1600 PE and Viscaron ^® A700 PE are commercially available. Very particular advantageous thickeners are crosslinked copolymer of acrylic acid or

Methacrylic acid and a C 10-30 alkyl acrylate or C 10-30 alkyl methacrylate and copolymers of acrylic acid or methacrylic acid and vinyl pyrrolidone. Such copolymers are, for example, from Lubrizol under the names Carbopol ^® 1342, Carbopol ^® 1382, Pemulen ^® TRI or Pemulen ^® TR2 and from ISP under the names Ultrathix ^® P-100 (INCI: Acrylic Acid / VP Crosspolymer) commercially available.

Very particular advantageous thickeners are crosslinked copolymers of 2-acrylamido-2-methylpropanesulfonic acid. Such copolymers are, for example, by the company Clariant under the names Aristoflex ^® AVC: available (INCI Ammonium Acryloyldimethyltaurate / VP Copolymer).

If the thickeners are used, the thickeners are generally in a concentration of about 0% to 2 wt .-%, preferably 0% to 1 wt .-% or preferably in a range of 0.01 to 1 wt .-% based on the total weight of the composition according to the invention is present.

The preferred solvents as component V4) are, for example, the aliphatic alcohols having CI-4 carbon atoms, such as ethanol and isopropanol; Polyol and its derivatives such as propylene glycol, dipropylene glycol, butylene-l, 3-glycol, polypropylene glycol, glycol ethers such as alkyl (Cl-4) ethers of mono-, di- or tripropylene glycol or mono-; Di- or triethylene glycol, and mixtures thereof.

The proportion of the solvent or solvents V4) in the composition according to the invention may, for example, be in the range from 0 to 25% by weight, or preferably 0 to 15% by weight, based on the total weight of the composition.

The compositions of the invention may further contain a propellant gas.

Preferred propellants are hydrocarbons such as propane, isobutane and n-butane and mixtures thereof. Compressed air, carbon dioxide, nitrogen, nitrogen dioxide and dimethyl ether as well as mixtures of all these gases can also be used.

Of course, the person skilled in the art knows that there are nontoxic propellants per se, which would in principle be suitable for the realization of the present invention in the form of aerosol preparations, but nevertheless due to a detrimental effect on the environment or other concomitant circumstances should be waived. These are, in particular fluorocarbons and chlorofluorocarbons (CFCs) such as 1,2-difluoroethane (propellant 152 A).

Hair-styling active ingredients are furthermore preferably included in the hairstyle-stabilizing composition. As care substances cyclic polydimethylsiloxanes (cyclomethicones) or silicone surfactants (polyether-modified siloxanes) of the dimethicone copolyol or simethicone type may preferably be used. Cyclomethicone be Abil ^® K4 offered, among others, under the trade names of Goldschmidt or eg DC 244, DC 245 and DC 345 by Dow Corning. Dimethicone copolyols are z. B. under the trade name DC 193 from Dow Corning and Belsil ^® DM 6031 from Wacker offered.

surfactants

The compositions of the invention may also contain surfactants selected from the group of anionic, cationic, nonionic and / or amphoteric surfactants.

Advantageous anionic surfactants in the context of the present invention are:

Acylamino acids and their salts, such as acylglutamates, in particular sodium acylglutamate and sarcosinates, for example myristoyl sarcosine, TEA-lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,

Sulfonic acids and their salts, such as acyl isethionate, for example sodium or ammonium cocoylisothionate, sulfosuccinates, for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA sulfosuccinate, disodium PEG-5 lauryl citrate sulfosuccinate and derivatives;

Sulfuric acid esters, such as alkyl ether sulfate, for example sodium, ammonium,

Magnesium, MIPA, TIPALaureth sulfate, sodium myreth sulfate and sodium C12 to C13 pareth sulfate, and alkyl sulfates, for example, sodium, ammonium and TEA lauryl sulfate,

Taurates, for example, sodium lauroyl taurate and sodium methyl cocoyl taurate;

Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate;

Phosphoric acid esters and salts such as DEA-oleth-10 phosphate and dilaureth-4 phosphate;

Alkylsulfonates, for example sodium coconut monoglyceride sulfate, sodium C12 to C14 olefinsulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate, Acylglutamates such as di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate;

Acyl peptides, for example, palmitoyl hydrolyzed milk protein, sodium cocoyl-hydrolyzed soy protein, and sodium cocalyzed hydrolyzed collagen;

Carboxylic acids and derivatives, for example lauric acid, aluminum strearate, magnesium alkoxide and zinc undecylenate, ester carboxylic acids, for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate;

• alkylarylsulfonates.

Advantageous cationic surfactants in the context of the present invention are quaternary surfactants. Quaternary surfactants contain at least one N atom covalently linked to 4 alkyl or aryl groups. For example, alkylbetaine, alkylamidopropylbetaine and alkylamidopropylhydroxysultaine are advantageous.

Further advantageous cationic surfactants for the purposes of the present invention are also alkylamines, alkylimidazoles and ethoxylated amines and in particular their salts.

Advantageous amphoteric surfactants for the purposes of the present invention are acyl / dialkylethylenediamines, for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphoacetate, sodium acylamphopropionate, and N-coconut fatty acid amidoethyl-N-hydroxyethylglycinate sodium salts.

Further advantageous amphoteric surfactants are N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.

Advantageous active nonionic surfactants for the purposes of the present invention are alkanolamides, such as cocamide MEA / DEA / MIPA, esters formed by esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols, ethers, for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers, alkyl polyglycosides, such as lauryl glucoside, decyl glycoside and cocoglycoside, glycosides with an HLB value of at least 20 (eg, Belsil SPG ^® 128V from Wacker).

Further advantageous nonionic surfactants are alcohols and amine oxides, such as cocoamidopropylamine oxide. Among the alkyl ether sulfates, particular preference is given to sodium alkyl ether sulfates based on di- or tri-ethoxylated lauryl and myristyl alcohol. They clearly outperform the alkyl sulfates with regard to their resistance to water hardness, thickenability, low solubility and, in particular, skin and mucous membrane compatibility. Lauryl ether sulfate has better foam properties than myristyl ether sulfate, but this is inferior in mildness.

Medium and especially higher alkyl ether carboxylates are among the mildest surfactants ever, but have poor foam and viscosity behavior. They are often used in combination with alkyl ether sulfates and amphoteric surfactants.

Sulfosuccinic acid esters (sulfosuccinates) are mild and foaming surfactants are preferably used only in neutral or well-buffered products because of their poor thickenability preferably only together with other anionic and amphoteric surfactants and because of their low hydrolysis stability.

Amidopropylbetains have excellent skin and eye mucous membrane compatibility. In combination with anionic surfactants, their mildness can be synergistically improved. Preferred is the use of cocamidopropyl betaine.

Arnphotoacetates / amphodiacetates, as amphoteric surfactants, have very good skin and mucous membrane compatibility and can have a conditioning effect or increase the care effect of additives. They are similar to the betaines used to optimize alkyl ether sulfate formulations. Most preferred are sodium cocoamphoacetate and disodium cocoamphodiacetate.

Alkyl polyglycosides are mild, have good universal properties, but foam weakly. For this reason, they are preferably used in combination with anionic surfactants.

conditioners

Optionally, the compositions of the invention contain a conditioning agent. Preferred conditioning agents include, for example, all of the compounds described in Section 4 of the International Cosmetic Ingredient Dictionary and Handbook (Volume 4, ed. RC Pepe, JA Wenninger, GN McEwen, The Cosmetic, Toiletry, and Fragrance Association, 9th Edition, 2002) Hair Conditioning Agents, Humectants, Skin Conditioning Agents, Skin Conditioning Agents Emollient, Skin Conditioning Agents Humectants, SkinConditioning Agents-Miscellaneous, Skin-Conditioning Agents-Occlusive and Skin Protectans are listed as well as all in EP-A 934 956 (p.11-13) under "water soluble conditioning agent" and "oil soluble conditioning agent" on guided compounds.

Special advantageous conditioning substances are, for example, the compounds designated as polyquaternium according to INCI (in particular Polyquaternium-1 to Polyquaternium-114).

Suitable conditioning agents include, for example, polymeric quaternary ammonium compounds, cationic cellulose derivatives, chitosan derivatives, guar gum derivatives and polysaccharides, especially guar hydroxypropylammonium chloride (eg ^Jaguar® Excel, ^Jaguar® 162 from Rhodia).

Further according to the invention advantageous conditioning agents are nonionic poly-N-vinylpyrrolidone / polyvinyl acetate copolymers (for example, Luviskol ^® VA 64 from BASF AG), anionic acrylate copolymers (eg Fuviflex ^® Soft from BASF AG), and / or amphoteric amide / acrylate / methacrylate copolymers are (eg Amphomer.RTM ^® from National Starch. Further possible conditioning agents are quaternized silicones.

Optionally, conventional additives may also be included in the composition, for example to impart certain modifying properties. These may include, for example, silicones or silicone derivatives, wetting agents, humectants, plasticizers such as glycerol, glycol and phthalates and ethers, fragrances and perfumes, UV absorbers, dyes, pigments, and other colorants, anticorrosives, neutralizing agents, antioxidants, anti-sticking agents, Combining agents and conditioners, antistatic agents, brighteners, preservatives, proteins and derivatives thereof, amino acids, vitamins, emulsifiers, surfactants, viscosity modifiers, thickeners and rheology modifiers, gelling agents, opacifiers, stabilizers, surfactants, sequestering agents, chelating agents, pearlescers, aesthetic enhancers, fatty acids, Fatty alcohols, triglycerides, botanical extracts, clarifiers and film formers act.

These additives are generally present at a level of from about 0.001% to 15% by weight, preferably from 0.01% to 10% by weight, based on the total weight of the composition. Preferably, at least one additional film-forming agent of component V5) selected from the group consisting of a nonionic, an anionic, an amphoteric and / or a cationic polymer is present in the hairstylist-stabilizing composition.

The film former V5) is preferably selected from the group consisting of a polyacrylate, a polyacrylamide, a polyurethane, a polyurea, a polysiloxane or a mixture of at least two thereof. The polyacrylates also include silicone-acrylate copolymers.

Among others, to improve the resistance of decorative products to water, tears or sweat (often called water resistance), film-forming polymers are used as film formers.

The preferred film-forming polymers are polymers based on acrylates or vinylpyrrolidones. Advantageous film formers are trimethylsiloxysilicates, silicone acrylate copolymers (eg TIB4-200 from Dow Corning or KP-561 from Shin Etsu), trimethyl pentaphenyl trisiloxanes (Dow Corning 555 Cosmetic Fluid from Dow Corning Ltd.) or Vinylpyrrolidone copolymer (eg PVP / eicosene copolymer or PVP / hexadecane copolymer).

Preferably non-ionic, anionic, amphoteric and / or cationic polymers are generally used as film formers. Preferred nonionic polymers used in the hair styling stabilizing composition, either alone or in combination, preferably with anionic and / or amphoteric and / or zwitterionic polymers are preferably selected from the group consisting of:

Polyalkyloxazoline;

Vinyl acetate homopolymers or copolymers, examples of which include copolymers of vinyl acetate and acrylic esters, copolymers of vinyl acetate and ethylene, copolymers of vinyl acetate and maleic acid esters;

Acrylic acid copolymers such. B. the copolymers of alkyl acrylate and alkyl methacrylate, copolymers of alkyl acrylate and urethanes;

Copolymers of acrylonitrile and nonionic monomer selected from butadiene and (meth) acrylate; Styrene homopolymers and copolymers, which include, for example, homopolystyrene, copolymers of styrene and alkyl (meth) acrylate, Coplymerisate of styrene, alkyl methacrylate and alkyl acrylate, copolymers of styrene and butadiene, copolymers of styrene, butadiene and vinylpyridine include;

polyamides;

Vinyl lactams homopolymers or copolymers, such as vinylpyrrolidone homo- or copolymers; which include, for example, polyvinylpyrrolidone, polyvinylcaprolactam, copolymers of N-vinylpyrrolidone and vinyl acetate and / or vinyl propionate in various concentration ratios, polyvinylcaprolactam, polyvinylamides and their salts and copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminoethyl methacrylate;

polysiloxanes;

Homopolymers of N-vinylformamide such as PVF from AkzoNobel;

Polyimides such as Polyimide-1 in Ashland's Styleze ™ XT3, and

Polyurethanes as Baycusan ^® C2000 of Covestro Germany AG; or

Mixtures of at least two of the foregoing.

Particular preferred nonionic polymers are acrylic acid ester copolymers, homopolymers of vinylpyrrolidone and copolymers and polyvinylcaprolactam.

Particularly preferred nonionic polymers are homopolymers of vinylpyrrolidone z. B. Luviskol ^® K from BASF, copolymers of vinylpyrrolidone and vinyl acetate z. B. Luviskol ^® VA types of BASF or PVPVA ^® S630L the company ISP, terpolymers of vinylpyrrolidone, vinyl acetate and propionate such. B. Luviskol ^® VAP from BASF and Polyvinylcaprolactame eg Luviskol ^® PLUS from BASF.

Advantageous anionic polymers are homopolymers or copolymers with monomer units containing acid groups, which are optionally copolymerized with comonomers which contain no acid groups. Suitable monomers are unsaturated, free-radically polymerizable compounds which have at least one acid group, and in particular carboxylic acid, sulfonic acid or phosphonic acid. Examples of anionic polymers containing carboxylic acid groups are:

Acrylic acid or methacrylic acid homo- or copolymers or their salts. These include, for example, the copolymers of acrylic acid and acrylamides and / or their sodium salts, copolymers of acrylic acid and / or methacrylic acid and an unsaturated monomer selected from the group ethylenes, styrene, vinyl esters, acrylic esters, methacrylic acid esters, optionally ethoxylated compounds, copolymers of vinylpyrrolidones, acrylic acid and C1-C20 alkyl methacrylates such as Acrylidone LM ^® of the company ISP, copolymers of methacrylic acid, ethyl acrylate and tert-butyl acrylates such as Luvimer ^® 100 P from BASF;

Crotonsäurederivat homo- or copolymers or their salts. These include for example vinyl acetate / crotonic acid, vinyl acetate / acrylate and / or vinyl acetate / vinyl neodecanoate / crotonic acid copolymers, for example, Resyn ^® 28-1310 or Resyn ^® 28-2930 of the firm AkzoNobel or Fuviset CAN ^® BASF, sodium acrylate / vinyl alcohol copolymers ; unsaturated C4-C8 carboxylic acid derivatives or carboxylic anhydride copolymers selected from copolymers of maleic acid or maleic anhydride or fumaric acid or fumaric acid or itaconic acid or itaconic anhydride and at least one monomer selected from the group of vinyl esters, vinyl ethers, vinyl halide derivatives, phenylvinyl derivatives, acrylic acid, acrylic acid esters or copolymers of maleic acid or Maleic anhydride or fumaric acid or fumaric anhydride or itaconic acid or itaconic anhydride and at least one monomer selected from the group of allyl esters, methallyl esters and, if appropriate, acrylamides, methacrylamides, alpha-olefins, acrylates, methacrylates, vinylpyrrolidones. Other preferred polymers are methyl vinyl ether / maleic acid copolymers formed by hydrolysis of vinyl ether / maleic anhydride copolymers. These polymers may also be partially esterified (ethyl, isopropyl or butyl ester) or partially amidated; water soluble or dispersible anionic polyurethanes, e.g. B. Fuviset ^® PUR BASF and DynamX ^® AkzoNobel Baycusan ^® C1000, C1001 Baycusan ^®, Baycusan ^® C1003, C1004 Baycusan ^®, Baycusan ^® 0008 from Covestro Germany AG,

This preceding fist is not exhaustive and therefore not restrictive. Advantageous anionic polymers containing sulfonic acid group are salts of polyvinylsulfonic acids, polystyrenesulfonic such. For example, sodium polystyrene sulfonate or polyacrylamide sulfonic acids.

Particularly advantageous anionic polymers are acrylic acid copolymers, crotonic acid derivative copolymer, copolymers of maleic acid or maleic anhydride or fumaric acid or fumaric anhydride or itaconic acid or itaconic anhydride and at least one monomer selected from the group of vinyl esters, vinyl ethers, vinyl halide derivatives, phenylvinyl derivatives, acrylic acid, acrylic acid esters and salts of polystyrenesulfonic.

Very particularly advantageous anionic polymers are acrylate copolymers, for example, Luvimer ^® of BASF, ethyl acrylate / N-tert-butylacrylamide / acrylic acid copolymers ULTRAHOLD STRONG BASE ^®, VA / crotonate / vinyl neodecanoate copolymer such. B. Resyn ^® 28-2930 AkzoNobel, copolymers such. Z. Copolymers of methyl vinyl ether and maleic anhydride partially esterified eg GANTREZ ^® from Ashland and sodium polystyrenesulfonates, such as Flexan ^® 130 from AkzoNobel.

Advantageous amphoteric polymers can be selected from polymers containing randomly distributed units A and B in the polymer chain, wherein A represents a moiety derived from a monomer having at least one basic nitrogen atom, and B represents a moiety derived from a acidic monomer having one or more carboxy or sulfonic acid groups. Alternatively, A and B may be groups derived from zwitterionic carboxybetaine monomers or sulfobetaine monomers. A and B may also be a cationic polymer chain containing primary, secondary, tertiary or quaternary groups, wherein at least one amino group carries a carboxy group or sulfonic acid group which is bonded via a hydrocarbon group, or A and B are part of a polymer chain with ethylene a, b-dicarboxylic acid unit in which the carboxylic acid groups have been reacted with a polyamine containing one or more primary or secondary amino groups.

Preferred amphoteric polymers are:

Polymers formed in the copolymerization of a monomer derived from a vinyl compound having a carboxy group, such as, in particular, acrylic acid, methacrylic acid, maleic acid, α-chloroacrylic acid, and a basic monomer. The basic monomer is derived from a vinyl compound which is substituted and contains at least one basic atom, such as, in particular, dialkylaminoalkyl methacrylate and acrylate, dialkylaminoalkylmethacrylamide and acrylamide. Such compounds have been described in US Pat. No. 3,836,537. Polymers having units derived from: a) at least one monomer selected from acrylamides or methacrylamides substituted on the nitrogen atom with an alkyl group, b) at least one acid comonomer containing one or more reactive carboxy groups, and c) at least a basic comonomer such as esters of acrylic acid and methacrylic acid having primary, secondary, tertiary and quaternary amino substituents and the quaternization product of dimethylaminoethyl methacrylate with dimethyl sulfate or diethyl sulfate.

Particularly preferred N-substituted acrylamides or methacrylamides are compounds whose alkyl groups contain from 2 to 12 carbon atoms. Very particular preference is given to N-ethylacrylamide, N-t-butylacrylamide, N-t-octylacrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide and the corresponding methacrylamides.

Suitable acidic comonomers are in particular selected from the group of acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid and the alkyl monoesters having 1 to 4 carbon atoms of maleic acid, maleic anhydride, fumaric acid or fumaric anhydride.

Preferred basic comonomers are aminoethyl methacrylate, butylaminoethyl methacrylate, N, N-dimethylaminoethyl methacrylate, N-t-butylaminoethyl methacrylate.

Crosslinked and fully or partially acylated polyaminoamides obtained from polyaminoamides of the following general formula:

- [CO-R-CO-Z] - wherein R is a divalent group selected from a saturated dicarboxylic acid, an aliphatic mono- or dicarboxylic acid having ethylenic double bond, an ester of these acids with a lower alkanol having 1 to 6 carbon atoms or a group resulting from the addition of one of these acids to a bis-primary or bis-secondary amine, and Z is a group derived from a bis-primary, mono- or bis-secondary polyalkylenepolyamine, and preferably: a ) as a quantitative fraction of 60 to 100 mol%, the groups -NH - [(CH 2) _x -NH-] p- where x = 2 and p = 2 or 3 or x = 3 and p = 2, the group being formed of diethylenetriamine, triethylenetetramine or dipropylenetriamine; b) as a quantitative fraction from 0 to 40 mol%, the group -NH - [(CH 2) _X - NH-] p-, where x = 2 and p = 1, which is obtainable from ethylenediamine, or the group derived from piperazine dates: c) in quantitative fraction from 0 to 20 mol .-%, the group -H- (CH 2) 6 -NH-, which is obtainable from hexamethylenediamine, these polyaminoamides being crosslinked by addition of a bifunctional crosslinker, preferably selected from the group of Epihalohydrins, diepoxides, dianhydrides and bis-unsaturated derivatives, in an amount ranging from 0.025 to 0.35 mol of crosslinker per amino group of the polyaminoamide, and acylated with acrylic acid, chloroacetic acid or an alkanesulfone or salts thereof.

The saturated carboxylic acids are preferably among the acids having 6 to 10 carbon atoms, such as adipic acid, 2,2,4-trimethyladipic acid and 2,4,4-trimethyladipic acid, terephthalic acid; Acids having an ethylenic double bond, such as, for example, acrylic acid,

The alkanesultones used in the acylation are preferably propanesultone or butanesultone, the salts of the acylating agents are preferably the sodium salts or potassium salts.

Polymers with zwitterionic units of the following formula:

wherein Rn is a polymerizable unsaturated group such as acrylate, methacrylate, acrylamide or methacrylamide, y and z are integers of 1 to 3, R and Rn is a hydrogen atom, methyl, ethyl or propyl, Ru and Rn is a hydrogen atom or an alkyl group which is so it is chosen that the sum of the carbon atoms Rn and Rn does not exceed 10. Polymers containing such units may also contain units derived from non-zwitterionic monomers, such as dimethyl and diethylaminoethyl acrylate or Dimethyl and diethylaminoethyl methacrylate or alkyl acrylates or alkyl methacrylates, acrylamides or methacrylamides or vinyl acetate.

Polymers derived from chitosan containing monomer units corresponding to the following formulas:

wherein the first unit is contained in proportions of 0 to 30%, the second unit in proportions of 5 to 50% and the third unit in proportions of 30 to 90%, with the proviso that in the third unit Ri _{6 is} a group of following formula means: wherein if q = 0, the groups Rn, Ris and R ₁₉ , identically or differently each represent a hydrogen atom, methyl, hydroxy, acetoxy or amino, a monoalkylamine radical or a dialkylamine radical optionally interrupted by one or more nitrogen atoms and / or optionally with a or more groups amino, hydroxy, carboxy, alkylthio,

Sulfonic acid, alkylthio, the alkyl group of which carries an amino radical, wherein at least one of R ₁₇ , Ris and R ₁₉ in this case represents a hydrogen atom; or if q = 1, the groups R ₁₇ , Ris and R _{19 are} each a hydrogen atom, as well as the salts which form these compounds with bases or acids. Polymers which correspond to the following general formula and which are described, for example, in French patent 1 400 366:

wherein R ₂ o is a hydrogen atom, CH ₃ O, CH ₃ CH ₂ O or phenyl, R _{21 is} a hydrogen atom or a lower alkyl group such as methyl or ethyl, R _{22 is} a hydrogen atom or a lower C _1-6 alkyl group such as Is methyl or ethyl, R _{23 is} a lower C _1-6 alkyl group, such as methyl or ethyl, or a group of the formula: -R ₂₄ -N (R ₂₂ ) ₂ , where R _{24 is} a group -CH ₂ -CH ₂ , - CH _{2 is} -CH ₂ -CH ₂ - or -CH ₂ -CH (CH ₃ ) - and wherein R _{22 has} the meanings given above.

Polymers which can be formed in the N-carboxyalkylation of chitosan, such as N-carboxymethylchitosan or N-carboxybutylchitosan. Alkyl (Ci-5) vinyl ether / maleic anhydride copolymers partially partially modified by semiamidation with an N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or an N, N-dialkylaminoalcohol. These polymers may also contain other comonomers, such as vinyl caprolactam.

Very particularly advantageous amphoteric polymers are copolymers octylacrylamide / acrylates / butylamino-ethyl methacrylate copolymer, which are sold under the names AMPHOMER ^®, AMPHOMER ^® LV 71 or BALANCE ^® 47 of the company AkzoNobel commercially, and methyl methacrylate / methyl dimethylcarboxymethylammoniumethylmethacrylat copolymers.

It may be advantageous to neutralize the anionic and amphoteric polymers with suitable bases to improve their water solubility or water dispersibility.

As neutralizing agents for polymers containing acid groups, the following bases can be used: hydroxides whose cation is ammonium or an alkali metal such as. As NaOH or KOH.

Other neutralizing agents are primary, secondary or tertiary amines, amino alcohols or ammonia. Preference is given here to 2-amino-2-methyl-1,3-propanediol (AMPD), 2-amino-2-ethyl

1,3-propanediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), 2-amino-1-butanol (AB), 2-amino

1,3-propanediol, monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA), dimethyl laurylamine (DML), dimethyl myristalamine (DMM), and dimethyl stearamine ( DMS) used.

Neutralization may be partial or complete depending on the application.

Optionally usable but less preferred are cationic polymers, such as polymers containing primary, secondary tertiary and / or quaternary amino groups, which are part of the polymer chain or directly attached to the polymer chain.

Preferably, the additional film former V5) is a polyurethane which is obtainable by reacting one or more water-insoluble, non-water-dispersible, isocyanate-functional polyurethane prepolymers with one or more amino-functional compounds B), where B) can be selected from the same compounds as described for B) above , In the context of the invention, the term "water-insoluble, non-water-dispersible polyurethane prepolymer" means, in particular, that the water solubility of the prepolymer used according to the invention is less than 10 g / liter, more preferably less than 5 g / liter, at 23 ° C., and Prepolymer at 23 ° no sedimentation-stable dispersion in water, especially deionized water results. In other words, when trying to disperse in water, the prepolymer settles.

Preferably, the NCO-terminated polyurethane prepolymer is obtainable from the reaction of a reaction mixture comprising a polyisocyanate and polyol. The polyisocyanate preferably has a functionality in a range of> 1.5 to 6, or preferably from 1.8 to 5, or preferably from 2 to 4, in particular from 2. Suitable polyisocyanates are aliphatic, aromatic araliphatic or cycloaliphatic polyisocyanates. Examples of such suitable polyisocyanates are 1,4-butylene diisocyanate, 1,6-hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), 2,2,4- and / or 2,4,4-trimethyl-hexa-methylene diiso cyanate, the isomeric bis (4,4'-isocyanatocyclohexyl) methanes or mixtures thereof of any isomer content, 1,4-cyclohexylenediisocyanate, 4-isocyanatomethyl-l, 8-octanediisocyanate (nonanetriisocyanate), 1,4-phenylene-di-iso-cyanate, 2,4- and / or 2,6-toluene diisocyanate, 1,5-naphthylene diisocyanate, 2,2'-and / or 2,4'- and / or 4,4'-diphenylmethane diisocyanate, 1,3- and / or 1,4-bis (2-isocyanato-prop-2-yl) -benzene (TMXDI), 1,3-bis (isocyanato-methyl) benzene (XDI) and alkyl 2,6-diisocyanatohexanoate (lysine diisocyanates) with CI to C8 alkyl groups.

Preferably, the polyisocyanate is an aliphatic polyisocyanate. Preferred aliphatic diisocyanates are hexamethylene diisocyanate and isophorone diisocyanate and mixtures thereof.

The polyol preferably has a functionality of> 1.5 to 6 or preferably from 1.8 to 5, or preferably from 2 to 4, in particular from 2. Preferably, the polyol is selected from the group consisting of a polyether polyol, a polycarbonate polyol, a polyether polycarbonate polyol, a polyester polyol or a mixture of at least two thereof. Preferably, the polyol has a polyol containing polyoxyethylene groups. With respect to the polyols, copolymers of ethylene oxide and propylene oxide having an ethylene oxide content, based on the total amount of the oxyalkylene groups, of 60 to 85 mol% are preferred. Preference is furthermore given to polyesterpolyols preferably formed from an acid selected from the group consisting of malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid or a mixture of at least two thereof with a polyol selected from the group consisting of Ethanediol, 1,3-propanediol, 2,2-dimethyl-1,3-propanediol (neopentanediol), 1,4-butanediol, 2,2-dimethyl-1,4-butanediol, 1,5-pentanediol, 2,2 - Dimethyl-l, 4-butanediol, 1,6-hexanediol or a mixture of at least two thereof.

Preferably, in the hair styling stabilizing composition, the total amount of carbodiimides and the total amount of film formers are in a ratio of 2: 1 to 1: 4, or preferably in a ratio of 1.5: 1 to 1: 3, or preferably in a ratio of 1: 1 to 1: 3. Preferably, the hairstyle-stabilizing composition has more weight percent of film former than compounds containing at least three carbodiimide groups, also called polycarbodiimide.

Preferably, the hairstyle stabilizing composition is in the form of a spray, in particular a pump spray, an aerosol, a gel, a foam, a mousse, a lotion, a wax, in particular a flax wax, a pomade, an oil, a milk, an oil in water emulsion, an aqueous solution or a cream. The hairstylist stabilizing composition is preferably in the form of a pump spray, an aerosol, a gel, a foam, a mousse, a lotion, a wax, a pomade.

The composition of the invention may further contain a wax. In the context of the present specification, a wax is defined as a lipophilic fatty substance which is solid at room temperature (25 ° C.) and exhibits a reversible change in state solid / liquid at a melting point between 30 ° C. and 200 ° C. Above the melting point, the wax becomes low viscous and miscible with oils.

The wax is advantageously selected from the group of natural waxes such as cotton wax, carnauba wax, candelilla wax, esparto wax, Japan wax, montan wax, sugarcane wax, beeswax, wool wax, shellac, microwaxes, ceresin, ozokerite, ouricuri wax, cork fiber wax, lignite waxes, berry wax, shea butter or synthetic Waxes such as paraffin waxes, polyethylene waxes, Fischer-Tropsch synthesis waxes, hydrogenated oils, fatty acid esters and glycerides solid at 25 ° C, silicone waxes and derivatives (alkyl derivatives, alkoxy derivatives and / or esters of polymethylsiloxane) and mixtures thereof. The waxes may be in the form of stable dispersions of colloidal wax particles which may be prepared by known methods, for example, according to "Microemulsion Theory and Practice", L.M. Prince Ed., Academic Press (1977), pages 21-32.

The waxes may be contained in amounts of from 0 to 10% by weight, based on the total weight of the composition, and preferably from 0 to 5% by weight.

The cosmetically acceptable medium of the composition according to the invention preferably contains water and optionally a cosmetically acceptable water-miscible, suitable organic solvent. The water used in the composition according to the invention may be a floral water, pure demineralized water, mineral water, thermal water and / or seawater. In the case of an O / W composition as the composition of the invention, the water content in the range of 40 to 95 wt .-%, preferably in the range of 50 to 90 wt .-%, most preferably in the range of 60 to 80 wt .-% based on the total weight of the composition. In the case of a W / O composition, the water content is in the range of 0 to 60% by weight, preferably in the range of 10 to 50% by weight, more preferably in the range of 30 to 50% by weight, based on the total weight of Composition.

The composition may further be foamed with a propellant gas. The emulsions described above may be stabilized by O / W, W / O or W / Si emulsifier, thickener (such as hydrodispersion) or solids (such as Pickering emulsion).

The composition may contain one or more emulsifiers or surfactants.

Thus, in particular oil-in-water emulsions (O / W) preferably contain at least one emulsifier with an HLB value> 7 and optionally a co-emulsifier.

Advantageously, the following nonionic emulsifiers are used:

• a) partial fatty acid esters and fatty acid esters of polyhydric alcohols and their ethoxylated

Derivatives (eg glyceryl monostearate, sorbitan stearate, glyceryl stearyl citrate, sucrose stearate)

B) ethoxylated fatty alcohols and fatty acids.

Suitable coemulsifiers for the novel O / W emulsions fatty alcohols having 8 to 30 carbon atoms, monoglycerol esters of saturated or unsaturated, branched or unbranched alkanecarboxylic acids having a chain length of 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms, propylene glycol esters of saturated or unsaturated, branched or unbranched alkanecarboxylic acids having a chain length of 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms, and sorbitan esters of saturated or unsaturated, branched or unbranched Alkan carboxylic acids having a chain length of 8 to 24 carbon atoms, in particular 12 to 18 carbon atoms, are used.

It may be advantageous in the sense of the present invention to use further emulsifiers. Thus, for example, the water resistance of the preparations according to the invention can be further increased. Suitable emulsifiers are z. B. alkyl methicone copolyols and alkyl dimethicone copolyols, especially cetyl dimethicone copolyol, lauryl methicone copolyol, W / O emulsifiers such as sorbitan stearate, glyceryl stearate, glycerol stearate, sorbitan oleate, lecithin, glyceryl isostearate, polyglyceryl-3-oleate, polyglyceryl-3-diisostearate, PEG-7 hydrogenated castor oil, Polyglyceryl-4-isostearate, acrylate / Cio so-alkyl acrylate crosspolymer, sorbitan isostearate, poloxamer 101, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-3-diisostearate, polyglyceryl-4-dipolyhydroxystearate, PEG-30-dipolyhydroxystearate, diisostearoylpolyglyceryl-3-diisostearate, Glycol distearate and polyglyceryl-3-dipolyhydroxystearate.

Component F) is preferably compounds which have exactly one isocyanate-reactive group or compounds which have more than one isocyanate-reactive group, with only one of the isocyanate-reactive groups reacting under the reaction conditions selected with the isocyanate groups present in the reaction mixture.

The isocyanate-reactive groups of component F) can be any functional group which can react with an isocyanate group, for example hydroxyl groups, thiol groups or primary and secondary amino groups.

Isocyanate-reactive groups within the meaning of the invention are particularly preferably primary or secondary amino groups which react with isocyanate groups to form urea groups. In addition to the amino group, compounds of component F) may also contain other isocyanate-reactive groups, such as, for example, OH groups, with only one of the isocyanate-reactive groups reacting under the reaction conditions selected with the isocyanate groups present in the reaction mixture. This can be done, for example Reaction of corresponding amino alcohols at relatively low temperatures, for example at 0 to 60 ° C, preferably at 20 to 40 ° C. Preference is given to working in the absence of catalysts which would catalyze the reaction of isocyanate groups with alcohol groups.

Examples of suitable compounds of component F) are primary / secondary amines, such as methylamine, ethylamine, propylamine, butylamine, octylamine, laurylamine, stearylamine, isononyloxypropylamine, dimethylamine, diethylamine, dipropylamine, dibutylamine, N-methyl-aminopropylamine, diethyl (methyl) aminopropylamine , Morpholine, piperidine, diethanolamine, 3-amino-1-methylaminopropane, 3-amino-1-ethylaminopropane, 3-amino-1-cyclohexylaminopropane, 3-amino-1-methylaminobutane, 6-aminohexanoic acid, alanine, aspartic acid, glutamic acid, glutamine , Glycine, ethanolamine, 3-aminopropanol, neopentanolamine or mixtures of at least two thereof.

Suitable monofunctional compounds are also ethanol, n-butanol, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, dipropylene glycol mono-propyl ether, propylene glycol monobutyl ether,

Dipropylene glycol monobutyl ether, tripropylene glycol monobutyl ether, 2-ethylhexanol, 1-octanol, 1-dodecanol, 1-hexadecanol.

For the preparation of the preferably amorphous polyurethaneurea, preference is given to producing> 0.1 and <20% by weight of component F) and particularly preferably> 0.3 and <10% by weight of component G), in each case based on the total mass of the preferably amorphous one Polyurethanurea, used.

The component G) is preferably used and the molar ratio of component F) to component G) is preferably 5: 1 to 1: 5, more preferably 1.5: 1 to 1: 4 and most preferably 1: 1 to 1: third

For the preparation of the preferably amorphous polyurethaneurea, the components A) to G) are preferably used in the following amounts, the individual amounts always adding up to 100% by weight:

From 5 to 40% by weight of component A),

55 to 90% by weight of component B),

0.5 to 20% by weight of the sum of the components CI) and, if appropriate, E), 0.1 to 10% by weight of component C2),

0 to 20% by weight of component D),

0.1 to 20% by weight of component F) and 0 to 10% by weight of component G).

From 10 to 35% by weight of component A),

60 to 85% by weight of component B),

1 to 15% by weight of the sum of the components CI) and, if appropriate, E),

0.5 to 4% by weight of component C2),

0 to 10% by weight of component D),

0.3 to 10% by weight of component F) and 0.1 to 3% by weight of component G).

Preferably, the hairstyle stabilizing composition comprises a polyurethaneurea obtainable by reacting at least

A) a preferably aliphatic polyisocyanate component having an average isocyanate functionality of> 1.8 and <2.6, which is selected from HDI, IPDI and / or H12-MDI or their modification products,

B) a polymeric polyol component which preferably contains carboxy or carboxylate groups,

C) an amino-functional chain extender component having at least 2 isocyanate-reactive primary and / or secondary amino groups, containing at least one amino-functional compound CI) which has no ionic or ionogenic groups and / or one amino-functional compound C2) which has ionic or ionogenic groups, D) optionally further hydrophilizing components which are different from C2),

F) optionally a compound which has exactly one isocyanate-reactive group, or a compound which has more than one isocyanate-reactive group, wherein only one of the isocyanate-reactive groups reacts under the reaction conditions selected with the isocyanate groups present in the reaction mixture, and

G) optionally an aliphatic polyisocyanate component having an average isocyanate functionality of> 2.6 and <4, wherein the component G) of an aliphatic or cycloaliphatic polyisocyanate oligomer with isocyanurate, urethane, allophanate, biuret, iminooxadiazinedione or Oxadiazintrione structure exists.

Preferably, the hair styling stabilizing composition comprises a preferably amorphous polyurethaneurea obtainable by reacting at least

A) a preferred aliphatic polyisocyanate component which is a mixture of IPDI and HDI,

B) a polymeric polyether-polyol component which is a mixture of at least two poly (propylene glycol) polyether polyols and wherein the poly (propylene glycol) polyether polyols differ in their number average molecular weights,

C) an amino-functional chain extender component having 2 isocyanate-reactive primary and / or secondary amino groups, containing at least one amino-functional compound CI) which has no ionic or ionogenic groups and / or one amino-functional compound C2) which has ionic or ionogenic groups,

D) optionally further hydrophilizing components which are different from C2), which are non-ionically hydrophilicizing components D1),

F) optionally a compound having exactly one isocyanate-reactive group, or a compound having more than one isocyanate-reactive group, wherein only one of isocyanate-reactive groups react under the reaction conditions selected with the present in the reaction mixture isocyanate groups, wherein the isocyanate-reactive group is a primary and / or secondary amino and / or hydroxy group, and

G) optionally an aliphatic polyisocyanate component having an average isocyanate functionality of> 2.6 and <4, wherein the component G) of an aliphatic or cycloaliphatic polyisocyanate oligomer with isocyanurate, urethane, allophanate, biuret, iminooxadiazinedione or Oxadiazintrionstruktur, based on HDI, fPDI and / or H12-MDI consists.

Preferably, the hairstyle-stabilizing composition is suitable for the treatment of hair, in particular for maintaining the structure of changes in the color and / or shape of the hair. In particular, in the treatment of the hair with the hairstyle-stabilizing composition another hair cosmetic application is made. The further hair cosmetic application may be any application to the hair which results in a change in the color and / or shape of the hair. By treating the hair with the composition of the invention it is preferably achieved that the hair has a higher structural stability to water, e.g. in the form of a jet of water e.g. when showering, bathing or swimming, or hair care products such as shampoo, hair fixatives, etc. receives, has a low swelling and a good feel. Preferably, the hair cosmetic application is selected from the group consisting of

(A) dyeing at least a part of the hair,

(B) a permanent wave treatment of the hair,

(C) a treatment with a curling iron,

(D) straightening the hair,

(E) a permanent smoothing of the hair,

(F) a hairdressing of the hair,

(G) a hair extension,

(H) a hair shortening,

(I) a combination of at least two applications selected from (A) to (G).

The treatment of hair with the hairstyle stabilizing composition of the invention preferably takes place using elevated temperature. The application of elevated temperature may involve both the hair to be treated and the hairstyle stabilizing composition or both. Preferably, the application of elevated temperature selected from the group consisting of heating the hairstyle stabilizing composition before application on the hair, heating the hair before treatment with the hairstyle-stabilizing composition, heating the hair after treatment with the hairstyle-stabilizing composition, heating the hair during treatment with the hairstyle-stabilizing composition or a combination of at least two of these take place. Preferably, the application of elevated temperature takes place by heating the hair styling stabilizing composition or heating the hair before treating the hair with the hair styling stabilizing composition. The application of elevated temperature optionally takes place before, during and / or after the treatment of hair with the hairstyle stabilizing composition according to the invention. Preferably, the hair to be treated, upon application of elevated temperature, is contacted with a composition having a temperature in a range of 30 to 250 ° C, or preferably in a range of 40 to 230 ° C, or preferably in a range of 50 to 200 ° C, or preferably in a range of 60 to 180 ° C. Preferably, the heating of the hair styling stabilizing composition prior to treatment of the hair takes place therewith, preferably in a range of 30 to 100 ° C, or preferably in a range of 35 to 90 ° C, or preferably in a range of 40 to 80 ° C instead of. Preferably, the elevated temperature is supplied to the hair via heated air or a heated surface. The elevation of the temperature is preferably achieved by an agent selected from the group consisting of a hair dryer, a straightener, a spiked iron, a drying hood, a Fockenstab or a combination of at least two thereof. The specified temperature ranges for the elevated temperature is preferably the temperature of the agent immediately before it is brought into contact with the hair. The heating of the hairstyle stabilizing composition may also be by heating the hair prior to treatment with the hairstyle stabilizing composition, especially if the hair is treated with an agent having a temperature greater than 100 ° C.

The duration of the application of elevated temperature is preferably in a range of 1 second to 3 hours, or preferably in a range of 5 seconds to 2 hours, or preferably in a range of 10 seconds to 1 hour, or preferably in a range of 20 Seconds to 50 minutes. Depending on the nature of the design of the hairstyle, for example, smoothing of the hair or Fockung of the hair, the application of the elevated temperature can be designed for different lengths and at different temperatures. For example, it is preferred to use a temperature of more than 200 ° C. several times, preferably 2 to 10 times for a few seconds, preferably 2 to 30 seconds, or preferably 3 to 10 seconds, during the smoothing of the hair. On the other hand, it is preferable that the temperature when designing dies in a range of 50 to Keep 100 ° C and to carry out an application of the temperature in a range of 10 to 120 minutes, or preferably in a range of 30 to 100 minutes.

The polycarbodiimide component (V2) is prepared from aliphatic or cycloaliphatic polyisocyanates.

The aliphatic or cycloaliphatic polyisocyanates are preferably selected from the group consisting of methylene diisocyanate, dimethylene diisocyanate, trimethylene diisocyanate, tetra methylene diisocyanate, pentamethylene diisocyanate, dipropyl ether diisocyanate, 2,2-dimethylpentane diisocyanate, 3-methoxyhexane diisocyanate, octamethylene diisocyanate, 2,2,4-trimethyl- pentane diisocyanate, nonamethylene diisocyanate, decamethylene diisocyanate, 3-butoxyhexane diisocyanate, 1,4-butylene glycol dipropyl ether diisocyanate, thiodihexyl diisocyanate, metaxylylene diisocyanate, paraxylylene diisocyanate, tetramethylxylylene diisocyanate, 4,4'-dicyclohexylmethane diisocyanate (H12MDI), isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), hydrogenated xylylene diisocyanate (H6XDI), 1,12-diisocyanate dodecane (DDI), nor-bornane diisocyanate (NB DI) and 2,4-bis (8-isocyanatoctyl) -1,3-dioctylcyclobutane (OCDI) or a mixture of at least two of them. Particularly preferred are isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), hydrogenated xylylene diisocyanate (I kXDI), 4,4'-dicyclohexylmethane diisocyanate (H12MDI). Most preferably, the cycloaliphatic polyisocyanate is 4,4'-dicyclohexylmethane diisocyanate (H12MDI).

[A1] In a preferred embodiment of the composition, the polycarbodiimide component (V2) comprises polycarbodiimide compounds containing at least three carbodiimide groups, constructed according to the formula (I),

R ⁴ - [R ¹ - N = C = N] _n - R ⁵ (I), where n is an integer from 3 to 100, preferably from 3 to 50, or preferably from 3 to 20, or preferably from 3 to 10 stands,

R ¹ and R ⁵ each independently represent linear or branched, aliphatic or cycloaliphatic, optionally substituted groups having 4 to 100, or preferably from 4 to 50, or preferably from 4 to 20 C-atoms.

R ^{4 is} linear or branched, aliphatic or cycloaliphatic, optionally substituted groups having 1 to 100, or preferably from 1 to 50, or preferably from 1 to 20 C-atoms. Suitable substituents of the radicals R ⁴ and / or R ⁵ in the context of the invention are numerous organic groups, for example alkyl, cycloalkyl, aryl, alkoxy, halogen, ether, thioether, thiourethane, disulfide, sulfoxide , Sulfone, sulfonate, amino, aldehyde, keto, carboxylic ester, carboxylic acid, carbonate, carboxylate, cyano, alkylsilane and alkoxysilane groups, urethane groups, allophanate groups, biuret groups, urea groups and carboxylamide groups. In particular, a part, also called a substituent, of the radicals R ¹ , R ⁴ or R ⁵ , preferably of the radicals R ⁴ and / or R ^{5 is} selected from the group consisting of a polyethylene glycol group, a polypropylene group, a methoxy group, an ethoxy group, a butoxy group , a methoxypolyethyleneglycol group, a urethane group, an alkyl group, a cycloalkyl group or a combination of at least two thereof.

Furthermore, at least one of the radicals R ¹ , R ⁴ or R ⁵ , preferably the radicals R ⁴ and / or R ⁵ , preferably has both an alkyl and a cycloalkyl group. In addition, it is preferred that at least one, more preferably both, of R ⁴ or R ⁵ , at least one of the groups, preferably at least two of the groups selected from the group consisting of a urethane group, a polyethylene glycol group (PEG), a polypropylene group (PPG ), a methoxy group, an ethoxy group, an alkyl group and a cycloalkyl group or a combination of at least two thereof. In particular, it is preferred that the radicals R ⁴ and / or R ^{5 have} an alkyl group, a cycloalkyl group, a urethane group, a PEG group and a methoxy group, preferably in exactly this order. Both radicals R ⁴ and / or R ⁵ preferably contain at least one urethane group and at least one group which is a radical derived from a C 1 to C 30 alcohol or a C 1 to C 30 monoalkoxyethylene glycol.

The polycarbodiimide component containing at least three carbodiimide groups, also referred to below as polycarbodiimide, is preferably a water-soluble or water-dippable compound.

The polycarbodiimide contained in the composition of the present invention preferably has a molecular weight M _w (determined by GPC) in a range of 300 to 500,000 g / mol, or preferably in a range of 500 to 300,000 g / mol, or preferably in a range of 1000 to 200,000 g / mol.

A preferred process for the preparation of aqueous dispersions of polycarbodiimides comprises at least one step, wherein in the at least one step at least one aliphatic or cycloaliphatic polyisocyanate at a temperature in the range of 160 to 230 ° C in the presence of carbodiimidization catalyst to a polycarbodiimide having an average functionality greater than 3, preferably from 3 to 100, or preferably from 3 to 50, or preferably from 3 to 20, or preferably from 3 to 10, carbodiimide units is reacted. Preferably, the reaction gases are temporarily or permanently removed. The amount of carbodiimidization catalyst is preferably 50 to 3000 ppm, based on the molar amount of polyisocyanate.

For the purposes of the present invention, the average functionality of carbodiimide units means the average number of carbodiimide units. The average functionality can also be a fractional number. The average functionality is preferably 3 to 50, or preferably 3 to 20, or preferably 3 to 10. The higher the functionality, the lower the dispersibility of the hydrophilized polycarbodiimide in water.

The carbodiimidization catalyst is preferably an organophosphorus compound, more preferably organophosphorus compounds selected from the group consisting of phosphine oxide, phospholane oxide and phospholene oxide, and also their sulfo and imino analogs. The phosphane, phospholene and phospholane oxides, sulfides and imino derivatives can be generated in situ, inter alia, from corresponding precursors with trivalent phosphorus, such as phosphanes, phospholanes and phospholens. The phospholene oxide is preferably selected from the group consisting of 3-methyl-1-phenyl-2-phospholene 1-oxide, 3-methyl-1-ethyl-2-phospholene 1-oxide, 1,3-dimethyl-2-phospholene 1-oxide, 1-phenyl-2-phospholene 1-oxide, 1-ethyl-2-phospholene 1-oxide, 1-methyl-2-phospholene 1-oxide. Further suitable catalysts and preferred embodiments of the process for the preparation of the polycarbodiimide are described in WO 2011/120928 A2

A preferred process for the preparation of aqueous dispersions of polycarbodiimide comprises the steps of: a) reacting at least one aliphatic or cycloaliphatic polyisocyanate at a temperature in the range of 160 to 230 ° C in the presence of 50 to 3000 ppm (ppm = part per million, 1 ppm = 0.0001%, molar proportions) Carbodiimidisierungskatalysator based on the molar amount of polyisocyanate to a polycarbodiimide, preferably with an average functionality of 3 to 20 carbodiimide units is reacted, the reaction gases are temporarily or permanently targeted removed from the reaction medium, b) reacting the in step a) obtained polycarbodiimide with at least one hydrophilic compound which carries at least isocyanate and / or carbodiimide reac tionable group, for example, but not limited thereto, selected from the group consisting of Polyethoxymonoolen, Polyethoxydiolen, Polyethoxypolypropoxy monools, Polyethoxypolypropoxydiols, polyethoxymonoamines, polyethoxydiamines,

Polyethoxypolypropoxymonoaminen, Polyethoxypolypropoxydiaminen, Hydroxyalkylsulfonaten, Aminalkylsulfonaten, Polyethoxymono- and -dithiolen, Polyethoxymono- and - dicarboxylic acids, mono- and dihydroxycarboxylic acids or their salts to a hydrophilized carbodiimide, optionally further reacting the unreacted isocyanate groups with other isocyanate-reactive compounds, such as for example with water, alcohols, thiols, amines, mineral and carboxylic acids and c) dispersing the compound obtained in step b) in water.

The reaction of the isocyanate-group-containing polycarbodiimide obtained in step a) is preferably carried out in such a manner that 10 to 70 mole percent (mol .-%) of the isocyanate groups present in the polycarbodiimide with at least one hydrophilic compound as substep bl) of Step b) are reacted, wherein the hydrophilic compound is selected from the group consisting of Polyethoxymonoolen, Polyethoxydiolen, Polyethoxypolypropoxymonoolen, Polyethoxypolypropoxydiolen, Polyethoxymono-amines,

Polyethoxydiaminen, Polyethoxypolypropoxymonoaminen, Polyethoxypoly-propoxydiaminen, Hydroxyalkylsulfonaten, Aminalkylsulfonaten, Polyethoxymono- and -dithiolen, Polyethoxymono- and -dicarbonsäuren. In step b2) of step b), 30 to 90 mol% of the remaining isocyanate groups are then reacted with at least one isocyanate-reactive compound, for example, polyethoxymonools, polyethoxydiols,

Polyethoxypolypropoxymonools, Polyethoxypolypropoxydiolen, Polyethoxymonoaminen,

Polyethoxydiaminen, Polyethoxypolypropoxymonoaminen, Polyethoxypolypropoxydiaminen, hydroxyalkylsulfonates, Aminalkylsulfonaten, Polyethoxymono- and -dithiolen, polyethoxy-mono- and -dicarbonsäuren, water, Ci to C ₃₀ alcohols, Ci to C ₃₀ thiols, amines, maleic and carboxylic acids.

The reaction of the polycarbodiimides in sub-step b1) of step b) is preferably carried out using at least one compound selected from the group of the compounds corresponding to general formula (III):

R ⁶ - O - (CH ₂ --CH ₂ - O) _m - H (III)

with R ⁶ = C ¹ to C ₃₀ alkyl or acyl group and m = 4 to 30 particularly preferably with at least one compound selected from the group corresponding to the formula (III), wherein R ^{6 is} a methyl group and m = 10 to 30.

Very particular preference is given to monomethoxypolyethylene glycol with m = 15-20.

Preferred CI to C30 alcohols which can be used for further reaction of the isocyanate groups present in the polycarbodiimide and not completely reacted with the hydrophilic compounds in step b2) of step b) are preferably water, low molecular weight monoalcohols or else diols having a molecular weight of preferably From 32 to 500, more preferably from 62 to 300 g / mol. Very particular preference is given to short-chain monoalcohols, ie branched or unbranched monoalcohols having 1 to 30 C atoms, such as methanol, ethanol, propanol, 1-butanol, 1-pentanol, 1-hexanol, cyclohexanol, cyclohexylmethanol, 2-ethylhexanol, dodecanol, stearyl alcohol or oleyl alcohol , their mixtures with each other and mixtures of their isomers and short-chain dialcohols having 2 to 60 carbon atoms such as 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, cyclohexanediol, cyclohexanedimethanol, 1,8-octanediol, 1,9 Nonadiol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, tricyclodecanedimethanol, the mixture of which is used with one another and mixtures of their isomers.

The sequence of sub-steps b1) and b2) of step b) can be determined so that sub-step b1) can take place before sub-step b2), both simultaneously or in the reverse order.

Optionally, the aqueous dispersion of hydrophilicized polycarbodiimide is adjusted in a step d) to a pH in the range of 7 to 12 (at 23 ° C), more preferably in the range of 8 to 11. For this, amine solutions, bases and conventional buffer solutions can be used.

Composition comprises the compound containing at least three carbodiimide groups, the general Formal (II):

wherein R ₂ and R ₃ , independently of one another, represent one of a compound selected from the group consisting of a monoalkoxy-poly (ethylene glycol) according to the general formula (III)

R ⁶ - O - (CH ₂ --CH ₂ - O) _m - H (III) with R ⁶ = C 1 to C 30 alkyl or acyl group and m = 4 to 30 and a radical derived from C 1 to C 30 alcohol or a C 1 to C 30 monoalkoxyethylene glycol.

The aqueous polycarbodiimide dispersions and / or solutions prepared by the process described above usually have a solids content of from 10 to 80% by weight, preferably from 20 to 60% by weight and more preferably from 30 to 50% by weight.

The hairstylist-stabilizing composition preferably contains the compound containing the carbodiimide, also called polycarbodiimide (V2), of the formula (I) or (III) in a range from 0.01 to 50% by weight, preferably in a range from 0, From 05 to 30% by weight, or preferably in a range of from 0.1 to 20% by weight, or preferably in a range of from 0.5 to 10% by weight, based on the total weight of the hair styling stabilizing composition. Depending on the application of the hair styling stabilizer composition, for example in hair application products, the preferred amounts of polycarbodiimides can vary widely. Hair application products are products such as hair styling, hair care or hair coloring products. In addition, the hairstyle stabilizing composition may also include coloring matter and may be a mascara, a mascara, a shampoo, a setting agent, a coloring agent, each of which may be in the form of a spray, lotion, cream, foam, solution, emulsion or wax Be part of such. The hairstylist stabilizing composition preferably contains the polycarbodiimide in a range of 0.1 to 10 wt%, or preferably in a range of 0.2 to 8 wt%, or preferably in a range of 0.5 to 5 Wt .-%, based on the total weight of the hairstyle-stabilizing composition, for example in shampoos. The hairstylist stabilizing composition preferably contains the polycarbodiimide in a range of 0.5 to 30 wt%, or preferably in a range of 1 to 20 wt%, or preferably in a range of 2 to 15 wt%. , based on the total weight of the hair styling stabilizing composition, in hair dyeing products.

All mentioned and described in connection with the hairstyle stabilizing composition according to the invention components, their preferred amounts and their properties are freely combinable and selectable.

[A12] Another object of the invention relates to a use of at least one polyurethaneurea (VI), optionally together with a polycarbodiimide (V2), for producing a hairstyle-stabilizing composition which is suitable for generating hairstyles in a water-stable manner, the polyurethaneurea (VI) being obtainable by implementing at least A) a polyisocyanate component having an average isocyanate functionality of> 1.8 and <2.6,

B) a polymeric polyol component,

C) an amino-functional chain extender component having at least 2 isocyanate-reactive amino groups, containing at least one amino-functional compound CI) which has no ionic or ionogenic groups and / or an amino-functional compound C2) which has ionic or ionogenic groups,

D) optionally further hydrophilizing components which are different from C2),

wherein the polyurethaneurea has at least one of the components C2) or D), and wherein the polyurethaneurea has carboxyl groups or carboxylate groups.

What is meant by a water-stable hairstyle has already been described for the hairstyle-stabilizing composition according to the invention. All properties mentioned for the hairstylist-stabilizing composition, constituents of components, preferred proportions of components, in particular of components (VI), A) to G) and (V2) also apply to the use of the polyurethaneurea (VI), optionally with the polycarbodiimide (V2) as described for the hairstyle stabilizing composition of the present invention.

[A13] Another object of the invention is the use of the hairstyle stabilizing composition according to the invention for improving the water resistance of hairstyles produced. Again, for the description and definition of water resistance on the Description of hairstyles, their preparation and properties related to the hairstyle stabilizing composition of the invention.

A further subject matter of the invention relates to a method for shaping a hairstyle, in particular for water-resistant and / or wash-resistant shaping of hair into a hairstyle, with at least the following steps:

Fl) treating the hair of a user with a hairstyle stabilizing composition;

F2) Optionally heat treating the hair of the user, wherein step F2) can take place before and / or after step Fl);

F3) shaping the hair into a hairstyle;

F4) Optionally, drying the hair;

F5) Optionally, contacting the hair with water before or after any of steps Fl) to F4), preferably before step Fl);

F6) optionally at least once repeating at least part of steps F4) and F5).

By bringing the hair into contact with water under point F5), according to the invention, it is understood that at least part of the hair shaped in step F3) is immersed in water. What is meant by water has already been defined above. In this case, a washing process with surfactant-containing water, also called shampooing, is preferably included in the contacting of the hair. The treatment in step Fl) with the composition according to the invention can be carried out in one or in two steps. If the treatment in step Fl) takes place in two steps, the polyurethaneurea (VI) is first applied to the hair as a single component and in a subsequent step the polycarbodiimide component (V2) or vice versa. If the treatment in step Fl) is carried out in one step, the two components (VI) and (V2) are already mixed. Preferably, step F5) is carried out before step Fl), ie the composition according to the invention is introduced into the wet hair.

Preferably, the design of the hairstyle first step F5) is performed, then step Fl), then step F3) and then optionally step F2) or F4). Preferably, step F3) is carried out together with step F3), in particular when the hair is directly connected to the means for Design of the hair is heated. Advantageously, the hairstyle can now be repeated over several steps F5), in particular in the form of shampooing, without the hairstyle having to be completely redesigned. Preferably, the hairstyle remains after each step F5) at least 50%, or preferably at least 70%, or at least 90% compared to the state before the previous step F5) exist.

A further subject matter of the invention relates to a method for producing a hairstyle stabilizing composition with at least the following steps: i. Producing a polyurethaneurea (VI) from an isocyanate group-containing prepolymer a., Which is obtainable from the reaction of at least the components

A) at least one polyisocyanate having a functionality of> 1.5 to <6, preferably from> 1.5 to <3; With

B) at least one polyol having a functionality of> 1.5 to <6, preferably from> 1.5 to <3; ii. Reaction of the prepolymer a. with at least

C) a mixture C) of primary and / or secondary amino-functional compounds CI) and of primary and / or secondary diamino compounds C2) to the polyurethaneurea (VI); iii. Mixing the polyurethaneurea (VI) with at least one polycarbodiimide (V2) prepared from aliphatic or cycloaliphatic polyisocyanates to obtain the hairstylist-stabilizing composition.

The polyurethaneurea (VI) is preferably the polyurethaneurea (VI) described in connection with the hairstyle-stabilizing composition according to the invention. The polycarbodiimide (V2) is preferably the polycarbodiimide (V2) described in connection with the hairstyling stabilizing composition according to the invention. Preferably, all components, their properties, their preferred amounts thereof in all the combinations mentioned also for the same named components in connection with the inventive method for producing a hairstyle-stabilizing composition transferable. Also for the selection and production of the individual components under step i. to iii. Reference is made to the description of the hairstyle stabilizing composition of the invention. The conditions under which component A) with B) in step i. reacted are well known to those skilled in the art. The reaction is preferred the component A) and B) at a temperature in a range of 30 to 100 ° C, preferably in a range of 40 to 90 ° C. The components D) to F), if used at all, preferably together with the component C) in step ii. used. Component G) is, if used at all, preferably with the components A) and B) in step i. used.

Another object of the invention relates to a kit, comprising at least the components (VI) and (V2), in particular

(V 1) a polyurethaneurea obtainable by reacting at least

A) a polyisocyanate component having an average isocyanate functionality of> 1.8 and <2.6,

B) a polymeric polyol component,

D) optionally further hydrophilizing components which are different from C2),

wherein at least one of the components C2) or D) is contained in the hairstyle stabilizing composition, wherein the polyurethaneurea dispersion has carboxyl groups or carboxylate groups, and (V2) a polycarbodiimide component prepared from aliphatic or cycloaliphatic polyisocyanates.

The constituents, their proportions and the process for the preparation of components (VI) and (V2) correspond to those described in connection with the hair styling stabilizing composition of the invention components A) to G). The components (VI) and (V2) are preferably processed according to the inventive method for producing the hairstyle stabilizing composition according to the invention. In particular, the two components (VI) and (V2) form the composition according to the invention after they have been mixed. As already described above, the two components (VI) and (V2) can be mixed, at least in part, before, during or after shaping the hairstyle. Thus, the components (VI) and (V2) can be mixed and applied to the hair at an appropriate time, but it can also be one of the components (VI) or (V2) applied before the design of the hair and the other component after that. It is also conceivable that both components (VI) and (V2) are applied to the hair simultaneously or successively after the design of the hairstyle. In order to achieve a particularly long-lasting effect of the hairstyle stabilization by the hairstylist-stabilizing composition, care should always be taken that the two components (VI) and (V2) can touch or mix sufficiently. The two components (VI) and (V2) can be packaged as a kit in a common container, which provides the two components in separate containers, or be packaged completely separate from each other in separate containers.

methods:

Unless otherwise indicated, all percentages are by weight and total or by total weight of the compositions.

Unless otherwise noted, all analytical measurements refer to measurements taken at temperatures of 23 ° C.

The solids and solid contents were determined according to DIN EN ISO 3251 by heating a balanced sample to 105 ° C to constant weight. At constant weight, the solids content was calculated by reweighing the sample.

NCO values were determined volumetrically in accordance with DIN-EN ISO 11909, unless expressly stated otherwise. The control of free NCO groups was carried out by IR spectroscopy (band at 2260 cm ¹ ).

The indicated viscosities were determined by means of rotational viscometry according to DIN 53019 at 23 ° C. using a rotational viscometer from Anton Paar Germany GmbH, Ostfildern, DE (1 Pa s = 1 N / m ² * s).

The determination of the average particle sizes (indicated by the number average) of the polyurethane dispersions was carried out after dilution with deionized water by means of laser correlation spectroscopy (instrument: Malvern Zetasizer 1000, Malver Inst. Limited).

The pH was measured on the undiluted sample according to the method described in DIN ISO 976.

experiments

For the experiments from Examples 1 and 2 either Euro hair strands were wavy (18 cm total length, 8 cm wide, 1.0 g +/- 0.2 weight) used or smooth Euro hair strands (19 cm total length, 3 cm Width, 1.0 g +/- 0.2 weight). The length of the strands is L0.

Preparation or curling or straightening of hair strands (step 0)):

Prior to the experiments as described in Examples 1 and 2, the hair tresses were washed for 1 minute with 0.3 g of a commercial silicone-free shampoo (Syoss "Volume Lift Shampoo") at 38 ° C. The hair tresses were then rinsed for 1 minute at 38 ° C and combed through with a conventional comb (wide side). The hair strands were then dried for 1 minute at about 75 ° C using a hair dryer.

Used substances

The tested substances are named with the following abbreviations:

Product A: Dispercoll U XP 2643, from Covestro Deutschland AG, aqueous polyurethane

Dispersion, solids content 40%, (VI)

Product B: Desmodur XP 2802, from Covestro Deutschland AG, aliphatic polycarbodiimide,

Solids content 40% in water, (V2)

Product C: Baycusan C1008, INCI: Polyurethane-48 from Covestro Deutschland AG, aqueous

Dispersion, solids content 30%

Product D: Luviflex Soft (INCI: Acrylate copolymer), from BASF AG, Germany Product E: Amphomer (INCI: Ocylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer), 100% adjusted to pH 9.6 with AMP (Amino Methylpropanol), 2% by weight, from Akzonobel

Product F: Syntran PC 5100 (INCI: Polyacrylate 21 (and) acrylates / dimethylaminoethyl

Methacrylate copolymer), commercially available from the supplier Interpolymer, aqueous solution, solids content 25%

Curling:

Designing a hairstyle: shaping the strands into curls (step 1)

A washed strand of hair (European smooth strands of hair prepared as described in step 0 was placed in a dish placed on a balance. A 2% by weight (solids) aqueous solution was distributed over the entire length of the hair strand so that the solution was as homogeneous as possible Then the hair strand was combed until it was completely wetted, then the strand was smoothed out with two fingers, which was then rotated on a cold corrugator with a gap between 2 and 3 mm The strand of hair was fastened by means of a rubber, all finished strands were then hung in the 50% humidity chamber and the strands were dried in the humidity chamber for at least 18 hours.

After drying, the strands were unwound on one side counterclockwise. The length of the strands was determined as LS.

Example 1: High moisture curl retention of product

A and product B (polycabodiimides) alone and in blends

Moisture Test (Moisture Test): The curls were hung in a 90% humidity chamber at 30 ° C following the preparation of step 0. The humidity was adjusted with distilled water. Thereafter, the curl-holding capacity with a centimeter scale fixedly installed in the humidity chamber was suspended at predetermined time intervals: 10 minutes, 20 minutes, 30 minutes, 45 minutes, 60 minutes, 2 hours, 3 hours, 4 hours, 5 hours, 6 hours and 24 hours certainly. Based on the 24 h value, the LT value was determined.

L0 = length of hair strand before any treatment

LS = Length of the hair strand after step 1 but before the moisture test

LT = length of the curl after moisture test (here after 24 hours at 30 ° C and 90% humidity)

(L0 - LT)

Curl retention in% = 100 x --- ---

Table 1: Results with different ^eg inventive and non-inventive mixtures ^neg treated hair and the curl retention capacity at high humidity

Table 1 shows examples of mixtures 1-b to 1-d according to the invention in comparison with noninventive mixtures of components (VI) in the form of product A 1-a and (v 2) in the form of product B 1-e. It can be clearly seen that product A not according to the invention alone has a very low moisture resistance for hair curled into curls, as shown in example 1-a. The same applies to the non-inventive product B alone in Example l.e. In both examples, Figures 1-a and 1-e, only curl retention is achieved by or less than 30%. By applying the mixture according to the invention of the components (VI) as product A and (V2) as product B, the water resistance could be significantly increased, as shown in the percent curl retention capacities of 47 to 73% for the mixtures lb to 1-d. In addition, it can be seen that the curl holding capacity with a 1: 1 mixture 1-b of component (VI) and (V2) has a maximum for the measured mixtures.

Example 2: curl retention in water

Treatment in Water: Following preparation as described in step 0, European smooth hair strands were applied with 1 g solution of mixtures 2-a to 2-c and distributed in the hair as described in step 1. Subsequently, their curl retention capacity in water was determined.

2-a ^eg : product A: product B in a ratio of 1: 1, 2% by weight of pesticide content

2-b ^neg : product D: product B in a ratio of 1: 1, 2 wt .-% pesticide content

2-c ^neg : product P: product B in a ratio of 1: 1, 2 wt .-% pesticide content

The hair curl was immersed in a 38 ° C water bath for 30 seconds to determine curl retention in water. Then the curl was removed from the water bath, hung up wet and the length of the curl was measured immediately (LT wet). Thereafter, the curl was completely air-dried at room temperature and again determined its length (LT dry).

L0 = length of the strand of hair before any treatment (= 19 cm)

LS = Length of the hair strand after treatment (curly) before the test LT wet = length of wet curl right after 30 seconds in the water bath

LT dry = length of curl after 30 seconds in water bath and drying at room temperature

(L0-LT wet)

Water resistance (wet) in% = 100 x

(L0 - LS)

(L0-LT dry)

Water resistance (dry) in% = 100 x

(L0 - LS)

Table 2: Results of treated with various ^eg inventive and non-inventive mixtures ^neg hair and their water treatment

Although the three blends 2-a to 2-c lead to similar curl-retaining power, Blend 2-a (according to the invention) allows markedly better water resistance measured with both wet and dry hair.

Example 3: Water resistance and shampoo resistance of smoothed hair

After preparation, as described in step 0), the wet hair strands (European curly hair strands (B0 = 4 to 5 cm width) with one of the mixtures 3-a (inventive), 3 b, or 3c (non-inventive Comparative Examples Thereafter, the hair was dried with the hair dryer at 75 ° C. for 3 minutes and smoothed at 230 ° C. for 5 × 3 seconds with a commercially available flat iron and then completely dried at 23 ° C. for 12 hours at 56% relative humidity.

3-a: Product A: Product B in the ratio 1: 1, 2 wt .-% solids content

3-b: product C: product B in the ratio 1: 1, 2 wt .-% solids content

3-c: product F: product B in the ratio 1: 1, 2 wt .-% solids content

Water Resistance: The width of the respective smoothed tress was determined to determine BG. Thereafter, the tress was immersed for 30 seconds in a water bath at 38 ° C, then The tress was hung and completely air-dried at room temperature. The width of the tress was then measured again to determine BW.

Table 3: Results of different ^eg inventive and non-inventive mixtures ^neg treated and smoothed hair as well as their water treatment

Wash Resistance: The width of the smoothed tress was measured to determine BG. Thereafter, the tress was washed for 1 minute at 38 ° C with a commercial shampoo (Syoss Volume Lift). Then the hair was rinsed with water for about 30 seconds. Then the tress was hung up and completely dried at room temperature. Finally, the width of the strand was measured to determine BST.

When the tress was still smooth (<4 cm), the same tress was shampooed again and washfastness determined again by determining the B2ST width.

Table 3: results of the invention with different ^eg and non-inventive ^neg

Mixtures of treated and smoothed hair as well as their shampoo treatment

The mixture 3-c showed neither water nor shampoo resistance. Blend 2-b has shown better water and shampoo resistance, however, the hairs tend to stick together, resulting in a not very aesthetic appearance of the hair. The mixture 3-a (according to the invention) shows on the smoothed hair, however, a very good water and shampoo resistance (even after 2 shampoo treatments) the smoothing of the hair, without the hair stuck together. In addition, the hair treated with the 3-a mixture felt very gentle (like healthy hair) and looked very natural.

Claims

Claims:

1. A hairstylist-stabilizing composition comprising at least the following components:

(V 1) a polyurethaneurea obtainable by reacting at least

B) a polymeric polyol component,

D) optionally further hydrophilizing components which are different from C2),

wherein the polyurethaneurea has at least one of the components C2) or D), and wherein the polyurethaneurea has carboxyl groups or carboxylate groups

2. The composition of claim 1, wherein the polyisocyanate A) is selected from the group consisting of 1,4-butylene diisocyanate, 1,6-hexamethylene diisocyanate (HDI), 2,2,4 and / or 2,4,4-trimethylhexamethylene diisocyanate which isomeric bis (4,4'-isocyanatocyclo) hexyl) methanes or mixtures thereof of any isomer content, 1,4-cyclohexylenediisocyanate, 1,4-phenylenediisocyanate, 2,4- and / or 2,6-toluene diisocyanate, 1,5-naphthylene diisocyanate, 2,2'- and / or 2,4'- and / or 4,4'-diphenylmethane diisocyanate, 1,3- and / or 1,4-bis (2-isocyanato-prop-2-yl) -benzene (TMXDI), l, 3 Bis (isocyanatomethyl) benzene (XDI), alkyl 2,6-diisocyanatohexanoate (lysine diisocyanates) with C 1 -C 8 -alkyl groups, and also 4-isocyanatomethyl-1, 8-octane diisocyanate (nonane triisocyanate) and triphenylmethane 4,4 ', 4 " triisocyanate or a mixture of at least two thereof.

3. The composition according to any one of the preceding claims, wherein the polyisocyanate of the polyisocyanate component A) is selected from an aliphatic or cycloaliphatic polyisocyanate.

4. The composition according to any one of the preceding claims, wherein the component B) contains or consists of poly (propylene glycol) polyether polyols.

The composition of any one of the preceding claims, wherein component B) has an average molecular weight in a range of 400 to 4000 g / mol.

6. The composition according to any one of the preceding claims, wherein component B) contains or consists of a mixture of poly (propylene glycol) polyether polyols, wherein the poly (propylene glycol) polyether polyols differ in their number average molecular weights by at least 100 g / mol.

The composition of any one of the preceding claims, wherein the polyol B) is selected from the group consisting of succinic, methylsuccinic, glutaric, adipic, pimelic, cork, azelaic, sebacic, nonandicarboxylic, decanedicarboxylic -, terephthalic, isophthalic, o-phthalic, tetrahydrophthalic, hexahydrophthalic, cyclohexanedicarboxylic, maleic, fumaric, malonic or trimellitic acid and acid anhydrides, such as o-phthalic, trimellitic or succinic anhydride or mixtures thereof with polyhydric alcohols, such as Ethanediol, di-, tri-, tetraethylene glycol, 1,2-propanediol, di-, tri-, tetra-propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 2,3-butanediol, pentanediol 1.5, 1,6-hexanediol, 2,2-dimethyl-1,3-propanediol, 1,4-dihydroxycyclohexane, 1,4-dimethylolcyclohexane, octanediol-1,8, decanediol-1,10, dodecanediol-1 , 12 or a mixture of at least two of them.

8. The composition according to any one of the preceding claims, wherein the component C) at least one amino functional compound CI), which has no ionic or ionic groups and an amino-functional compound C2), which has ionic or ionogenic groups.

9. The composition according to any one of the preceding claims, wherein it is the component D) exclusively nonionic hydrophilicizing components Dl).

10. The composition according to any one of the preceding claims, wherein the polycarbodiimide component (V2) polycarbodiimide compounds containing at least three carbodiimide groups, corresponding to the formula (I),

R ⁴ - [R ¹ - N = C = N] "- R ⁵ (I), wherein n is an integer from 3 to 100, preferably from 3 to 50, or preferably from 3 to 20, or preferably from 3 to 10,

R ¹ and R ⁵ each independently represent linear or branched, aliphatic or cyclo-aliphatic, optionally substituted groups having 4 to 100, or preferably from 4 to 50, or preferably from 4 to 20 C-atoms.

R ^{4 is} linear or branched, aliphatic or cyclo-aliphatic, optionally substituted groups having 1 to 100, or preferably from 1 to 50, or preferably from 1 to 20 C-atoms.

11. Use of at least one polyurethaneurea (VI), optionally together with a polycarbodiimide (V2), for the production of a hairstyle-stabilizing composition which is suitable for generating hairstyles water-stable, wherein the polyurethaneurea (VI) is obtainable by reacting at least

B) a polymeric polyol component,

D) optionally further hydrophilizing components which are different from C2), E) optionally hydroxy-functional compounds having a molecular weight of 62 to 399 mol / g,

A use of the hairstylist stabilizing composition according to any one of claims 1 to 10 for improving the water resistance of hairstyles.

13. A method of designing a hairstyle with at least the steps:

Fl) treating the hair of a user with a hairstyle stabilizing composition according to any one of claims 1 to 10;

F2) optionally heat treating the hair of the user, wherein step F2) before and / or after step Fl) can take place;

F3) shaping the hair into a hairstyle;

F4) optionally drying the hair;

F5) optionally contacting the hair with water;

F6) optionally at least once repeating at least part of steps F4) and F5.

14. A method of making a hairstyle stabilizing composition comprising at least the steps of: i. Producing a polyurethaneurea (VI) from an isocyanate group-containing

Prepolymer a., Which is obtainable from the reaction of at least the components

A) at least one polyisocyanate having a functionality of> 1.5 to <6; With B) at least one polyol having a functionality of> 1.5 to <6; ii. Reaction of the prepolymer a. with at least

C) a mixture C) of primary and / or secondary amino-functional compound CI) and of primary and / or secondary diamino compounds C2) to the polyurethaneurea (VI); iii. Mixing the polyurethaneurea (VI) with at least one polycarbodiimide (V2) prepared from aliphatic or cycloaliphatic polyisocyanates to obtain the

Hairstyle-stabilizing composition.

15. A kit comprising at least the components:

(V3) a polyurethaneurea obtainable by reacting at least

B) a polymeric polyol component,

D) optionally further hydrophilizing components which are different from C2),

wherein at least one of the components C2) or D) is contained in the adhesive, wherein the polyurethaneurea dispersion has carboxyl groups or carboxylate groups, as well as

(V4) a polycarbodiimide component prepared from aliphatic or cycloaliphatic polyisocyanates.