EP3713541A1 - Composition cosmétique vaporisable avec effet colorant - Google Patents

Composition cosmétique vaporisable avec effet colorant

Info

Publication number
EP3713541A1
EP3713541A1 EP18762252.7A EP18762252A EP3713541A1 EP 3713541 A1 EP3713541 A1 EP 3713541A1 EP 18762252 A EP18762252 A EP 18762252A EP 3713541 A1 EP3713541 A1 EP 3713541A1
Authority
EP
European Patent Office
Prior art keywords
weight
fibers
copolymer
cosmetic composition
pigments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP18762252.7A
Other languages
German (de)
English (en)
Inventor
Diane Metten
Rolf Bayersdoerfer
Thorsten Knappe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3713541A1 publication Critical patent/EP3713541A1/fr
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/027—Fibers; Fibrils
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes

Definitions

  • the present application relates to sprayable cosmetic composition for the treatment of keratinic fibers, which in addition to a solvent and a blowing agent further fibers and at least one coloring agent.
  • These agents are suitable for a variety of cosmetic purposes, but in particular for the temporary deformation of the keratinic fibers with simultaneous coloring of the fibers.
  • the application relates to the cosmetic use of these agents and hair cosmetic methods using these agents.
  • the older German patent application DE 10 2017 205 558.8 relates to sprayable cosmetic composition for the treatment of keratinic fibers, which in addition to a solvent and a blowing agent fibers continue to contain. These agents are suitable for a variety of cosmetic purposes, but in particular for the temporary deformation of the keratinic fibers. Furthermore, this earlier German patent application relates to the cosmetic use of these agents and hair cosmetic methods using these agents.
  • compositions can be colored and / or treated with dyes or pigments and are then outstandingly suitable for a number of other cosmetic purposes and for achieving the object according to the invention.
  • the present invention is a cosmetic composition for the cosmetic treatment of keratinous fibers, containing - in each case based on their weight
  • the cosmetic composition contains fibers as its first essential ingredient.
  • the addition of these fibers influences the application properties of the sprayable hair cosmetic in a manner not expected to be expected.
  • the spray pattern and the order of the sprayed cosmetics become more uniform.
  • the addition of the fibers at the same pressure in the spraying device and the same distance from the surface to be sprayed also causes a surprising increase in the spray surface achieved.
  • the fibers are stretched, flexible structures made of fiber material with a ratio of length to diameter above 3: 1, preferably above 5: 1 and in particular above 10: 1. Fibers can absorb in the longitudinal direction no pressure, but only tensile forces.
  • the length of preferably used fibers is in the range from 1.0 to 200 ⁇ m, preferably from 2.0 to 150 ⁇ m and in particular from 5.0 to 100 ⁇ m. Of course, however, fibers of greater fiber length, such as fibers with a length above 200pm or above 300pm can be used.
  • the fiber material can be of natural or synthetic origin. Natural fibers are all those fibers which are obtained without a chemical change from vegetable, animal or mineral material.
  • Plant fibers occur in plants as vascular bundles in the stalk, in the trunk, in the bark or as seed extensions. Vegetable fibers usually consist predominantly of cellulose. Corresponding fibers are summarized under the name cellulose fibers.
  • the fibers used in the cosmetic compositions are selected from the group of fibers of natural fiber materials. Particularly preferred is the use of cellulose fibers, in particular of cotton fibers, flax fibers and Kapopkmaschinen. Furthermore, the use of animal fibers from the group of silk fibers, cashmere fibers and wool fibers is preferred. Particularly preferred is the use of cellulose fibers.
  • fibers based on synthetic fiber materials can also be used in the cosmetic compositions.
  • the group of these preferred fibers include, for example, fibers of viscose, polylactic acid, alginate, chitin or chitosan.
  • Further preferred synthetic fiber materials are polyamides, polyesters and polyhydroxyalkanoates.
  • proportions by weight of the fibers in the total weight of the cosmetic composition of 0, 1 to 5.0, preferably 0.1 to 2.0 wt .-%, particularly preferably 0.1 to 1, 0 Wt .-% and in particular 0, 1 to 0.5 wt .-% proved.
  • the cosmetic compositions contain ethanol.
  • the proportion by weight of the ethanol in the total weight of the cosmetic composition is preferably 45 to 70 wt .-%, preferably 40 to 65 wt .-% and in particular 50 to 60 wt .-%.
  • the fibers are suspended in the ethanol.
  • the third essential ingredient of the cosmetic composition is the polymer.
  • the proportion by weight of the polymer in the total weight of the composition to from 0.5 to 8.0% by weight, preferably from 1.0 to 6.0% by weight and in particular 2.0 to 4.0 wt .-% limit.
  • Polymers are used in the cosmetic compositions, for example, because of their setting and / or film-forming properties. Because of their cosmetic effect, the use of film-forming polymers is particularly preferred.
  • Suitable polymers are permanent as well as temporary cationic, anionic, nonionic or amphoteric polymers.
  • the film-forming polymers may be of synthetic or natural origin.
  • Examples of common polymers are Acrylamide / Ammonium Acrylate Copolymer, Acrylamide / DMAPA Acrylates / Methoxy PEG Methacrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer, Acrylamidopropyltrimonium Chloride / Acrylates Copolymer, Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Acrylamide Copolymer, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / t-Butyl Acrylamide Copolymer, Acrylates Copolymer, Acrylates / C1-2 Succinates / Hydroxy Acrylates Copolymer, Acrylates / Lauryl Acrylates / Stearyl Acrylates / Ethylamine Oxide Methacrylate Copolymer, Acrylates / Octylacrylamide Copolymer, Acrylates
  • Polyperfluoroperhydrophenanthrenes Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-1 1, Polyquaternium-12, Polyquaternium-13 , Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18,
  • the polymer is selected from the group of nonionic polymers.
  • Suitable nonionic polymers are, for example:
  • Vinylpyrrolidone / vinyl ester copolymers as sold, for example, under the trademark Luviskol ® (BASF).
  • Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are preferred non-ionic polymers.
  • Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropylcellulose, as sold for example under the trademark Culminal® ® and Benecel ® (AQUALON).
  • Siloxanes These siloxanes can be both water-soluble and water-insoluble. Both volatile and nonvolatile siloxanes are suitable, nonvolatile siloxanes being understood as meaning those compounds whose boiling point is above 200 ° C. under normal pressure.
  • Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
  • Particularly preferred according to the invention are the polyvinylpyrrolidones and the vinylpyrrolidone / vinyl acetate copolymers
  • a second group of particularly preferred polymers form the amphoteric polymers.
  • Very particular preference is given to the use of a copolymer of i) N-tert-octylacrylamide, ii) acrylic acid, iii) tert-butylaminoethyl methacrylate and optionally other monomers
  • Preferred amphoteric copolymers are preferably at least 90 wt .-%, preferably at least 95 wt .-% and in particular at least 97 wt .-% of the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethyl methacrylate.
  • Corresponding copolymers can also be obtained with the exclusive use of the monomers N-tert-octylacrylamide, acrylic acid and tert-butylaminoethyl methacrylate.
  • copolymers of the monomers N-tert-octylacrylamide, acrylic acid, tert-butylaminoethyl methacrylate, methyl methacrylate and hydroxypropyl methacrylate are particularly preferred. It is particularly preferred in particular if the copolymer contains at least 90% by weight, preferably at least 95% by weight and in particular at least 97% by weight, of the monomers N-tert-octylacrylamide, acrylic acid, tert-butylaminoethyl methacrylate, Methyl methacrylate and hydroxypropyl methacrylate.
  • amphoteric copolymers described above, for example, under the name Amphomer ® (INCI name: Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer; CAS number 70801-07-9) sold by the company National Starch.
  • a fourth essential ingredient of the cosmetic compositions is the propellant. It has proven to be particularly advantageous cosmetically and technically when the proportion by weight of the blowing agent in the total weight of the composition is from 25 to 50% by weight, preferably from 30 to 50% by weight and in particular from 35 to 45% by weight.
  • Preferred propellants are selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane, isopentene, methane, ethane, dimethyl ether, nitrogen, air, oxygen, Nitrous oxide, dichlorofluoromethane, chlorodifluoromethane, chlorofluoromethane, 1,1,2,2-tetrachloro-1-fluoroethane, 1,1,2,2-tetrachloro-2-fluoroethane, 1,2,2-trichloro-1,1-difluoroethane, 1, 1, 2-trichloro-1, 2-difluoroethane, 1, 1, 1 -Trichlor-2,2-difluoroethane, 2,2-dichloro-1,1,1-trifluoroethane, 1, 2-dichloro-1 , 1, 2-trifluoroethane, 2-chloro-1, 1,
  • the cosmetic compositions according to the invention contain at least one coloring compound from the group of dyes and / or pigments.
  • the compositions of the invention contain
  • compositions of the invention may contain 0% by weight of dyes (then at least one pigment must be present in an amount of at least 0.0001
  • the dye content can also be 10 wt .-% (then no pigment can be present
  • the total amount of all dyes and pigments (also referred to as the total amount of coloring components) in the composition according to the invention 0.0001 to 10 wt .-%.
  • Preferred cosmetic compositions according to the invention are characterized in that they contain 0.0001 to 10% by weight, preferably 0.01 to 9.5% by weight, more preferably 0.05 to 9% by weight, even more preferably 0.1 to 8.5% by weight and especially 0.25 to 8% by weight of dyes).
  • Dyes are colorants, ie coloring substances, which, in contrast to pigments, are soluble in the application medium (as in water, oils or other solvents).
  • a dye or a mixture of dyes may be selected. All customary and commercially available dyes in the field of cosmetics are readily usable in the context of the present invention.
  • compositions according to the invention are characterized in that 0.0001 to 10% by weight, preferably 0.01 to 9.5% by weight, more preferably 0.05 to 9% by weight, even more preferably 0.1 to 8.5% by weight and in particular 0.25 to 8% by weight of pigment (s).
  • water-insoluble pigments are suitable, for example natural inorganic pigments (also referred to as mineral pigments). These pigments mainly contain sulfides and oxides. Examples of such pigments are ocher (Fe (OOH), Pigment Yellow 43), calcined sienna (Fe 2 O 3, Pigment Red 102), umber (Fe 2 O 3 x MPOS, Pigment Brown 7: x), cinnabar ( ⁇ -HgS, PR 106), Lapis lazuli (ultramarine, Na 6 Al 16 Si 6024 x Na 2 Sn; Pigment Blue 29), azurite (basic copper carbonate, Cu 3 [OH / CO 3] 2 , PB 30), green earth (FeO-containing silicate, Pigment Green 23), malachite (Cu 2 [(OH) 2 , CO3]) and carbon black (carbon (graphite), Pigment Black 9).
  • ocher Fe (OOH), Pigment Yellow 43)
  • calcined sienna
  • Synthetic inorganic pigments are produced, for example, by chemical and / or physical conversion (digestion, precipitation, annealing). These include in particular
  • White pigments titanium dioxide (T1O2), Pigment White PW 6, zinc sulfide (ZnS), PW 7, zinc oxide (ZnO), PW 4, antimony white (Sb20 3 ), PW 1 1, lithopone (ZnS / BaSC), PW 5, lead white (2PbC0 3 x Pb (OH) 2 ), PW 1),
  • subordinate white fillers (calcium carbonate, PW 18, talc, PW 26 and barium sulfate, PW
  • Black pigments (manganese black, spinel black and carbon blacks (graphite carbon);
  • Luster pigments (absorption pigments, metal pigments or metallic effect pigments and pearlescent pigments) and
  • inorganic colored pigments iron oxide pigments, iron blue pigments, ultramarine pigments and less suitable due to their toxicological properties lead chromate pigments, chromium oxide pigments, cadmium pigments and bismuth vanadate pigments.
  • Preferred synthetic inorganic pigments are metal pigments or metallic effect pigments of powdery metals or metal alloys, such as aluminum bronzes (metal: Al), gold bronzes (metal: Cu, Cu-Al or Cu-Zn alloy), silver bronzes (metal: Cu-Zn-Ni) , fire-colored bronzes (metal: oxidized Cu-Zn) and patent bronzes (metal: Cu-Zn (Ni) + dye).
  • metal bronzes metal: Al
  • gold bronzes metal: Cu, Cu-Al or Cu-Zn alloy
  • silver bronzes metal: Cu-Zn-Ni
  • fire-colored bronzes metal: oxidized Cu-Zn
  • patent bronzes metal: Cu-Zn (Ni) + dye
  • pearlescent pigments which consist of several layers with different refractive indices.
  • examples of such pearlescent pigments are magnesium stearate, zinc stearate and lithium stearate or ethylene glycol distearate or polyethylene terephthalate and pearlescent pigments, which consist essentially of mica, titanium dioxide (titanium dioxide mica), bismuth chloride oxide or guanine, and furthermore with colored oxide layers (for example iron oxides or chromium oxides ) can be coated.
  • Pearlescent pigments based on mica and on mica / metal oxide are, according to the invention, particularly preferred pearlescent pigments. Mica belongs to the layered silicates.
  • the mica predominantly muscovite or phlogopite, is coated with a metal oxide.
  • Suitable metal oxides include T1O2, Cr 2 Ü3 and Fe 2 0. 3
  • interference pigments and color luster pigments are obtained as pearlescent pigments preferred according to the invention.
  • these pearlescent pigment types also have color effects.
  • the pearlescent pigments which can be used according to the invention may additionally contain a color pigment which does not derive from a metal oxide.
  • Very particularly preferred pearlescent pigments are pigments which are marketed by Merck under the trade name Colorona®, the pigments Colorona® red-brown (47-57% by weight of muscovite mica (KH2 (AISi04) 3), 43-50% by weight.
  • % Fe2Ü3 (INCI: Iran Oxides CI 77491), ⁇ 3% by weight of T1O2 (INCI: Titanium Dioxide CI 77891), Colorona® Blackstar Blue (39-47% by weight of Muscovite Mica (KH2 (AISi04) 3), 53-61 % Fe.sub.3.sub.4 (INCI: Iran Oxides CI 77499)), Colorona.RTM.
  • % T1O2 (INCI: Titanium Dioxide CI 77891), 2-4 wt.% Prussian Blue (INCI: Ferric Ferrocyanide CI 77510)), Colorona® Chameleon (40-50 g % Muscovit Mica (KH 2 (AISi04) 3 ), 50-60% by weight Fe 2 O 3 (INCI: Iran Oxides CI 77491)) and Silk® Mica (> 98% by weight Muscovit Mica (KH2 (AISi04) 3)) are particularly preferred.
  • pigments are the coloring synthetic iron oxides. Particularly preferred representatives of this substance class are Pigment Brown 6 (CI No 77491), Pigment Red 101 (CI No 77491), Pigment Yellow 42 (CI No 77492), Pigment Black 1 1 (CI No 77499) and mixtures of these pigments.
  • Very particularly preferred pigments which can be used according to the invention are distinguished by good sprayability in the compositions according to the invention, a homogeneous spray pattern and an extremely low tendency to block the spray nozzles ("clogging").
  • extremely preferred cosmetic compositions according to the invention are characterized in that they contain at least one pigment from the group CI12490, CI14700, CI14720, CI15510, CI15985, CI45380, CI47005, CI60730, CI61565, CI73360, CI74160, CI77007, CI77019, CI77288, CI77289, CI77491, CI77492, wherein the total amount of pigment (s) from this group 0.0001 to 10 wt .-%, preferably 0.01 to 9.5 wt .-%, more preferably 0.05 to 9 wt .-%, even further preferably 0, 1 to 8.5 wt .-% and in particular 0.25 to 8 wt .-% is.
  • agents according to the invention contain at least one starch compound.
  • This starch compound may be the sole polymer in the compositions of this invention, but it is preferred to employ the starch compound in addition to the preferred film-forming polymers described above.
  • the wording "as an additional ingredient” therefore means “in addition to” all other mandatory ingredients mentioned above.
  • Preferred cosmetic compositions according to the invention are characterized in that they contain as further constituent 1, 0 to 10 wt .-%, preferably 2.0 to 6.0 wt .-% and in particular 3.0 to 5.0 wt .-% of at least one Contain starch compound
  • Starch is a reserve carbohydrate that is stored by many plants in the form of usually 1 to 200 miti large starch granules (granules) in various parts of plants, for example, in tubers or roots, cereal seeds, fruits and in the marrow.
  • Starch belongs to the family of homoglycans and is a polycondensation product of D-glucose.
  • Preferred starches according to the invention are selected from at least one polycondensation product of D-glucose obtained from native and / or physically modified starch from potatoes, corn, rice, peas, acorns, chestnuts, barley, wheat, bananas, sago, millet, sorghum, oats, rye , Beans, sweet potatoes, maranta or manioc and their mixtures.
  • native starch is meant a starch which is isolated from starch-containing plants and which has not been physically or chemically modified after isolation and purification.
  • physically modified starch is understood as meaning a starch which has undergone at least one physical modification after the isolation.
  • Physical modification here is to be understood as the modification using pressure and / or heat and / or light.
  • a modification by means of chemical and enzymatic reactions for example the hydrolysis of the starch, does not fall under the term of physical modification.
  • a preferred physical modification is the application of heat, especially the cooking of the native starch.
  • Preferred embodiments of the present invention are therefore characterized in that the compositions contain at least one starch selected from chemically and / or physically modified rice starches, in particular from physically modified rice starch.
  • compositions according to the invention contain the ingredient (s) in the form of a starch-dye compound, preferably in the form of colored and / or pigmented rice starch.
  • the composition of the starch particles themselves has proven to be relevant for the cosmetic effect. Therefore, preferably used particles have a certain proportion of the native and / or physically modified starch, in particular rice starch. It is thus preferred according to the invention, when the starch-dye compound at least one starch, in particular a physically modified rice starch, in a total amount of 70 to 96 wt .-%, in particular from 80 to 94 wt .-%, each based on the total weight of the particle (compounds).
  • the use of particles that have a high Containing by weight of physically modified rice starch leads to particularly homogeneous spray patterns and preferred adhesion of the color on the keratinic fibers.
  • cosmetic compositions according to the invention which contain the ingredients (a) and (e) or (f) in the form of a fiber-dye compound, preferably in the form of colored and / or pigmented fibers.
  • Preferred cosmetic compositions contain as further constituent at least one ester oil.
  • the group of ester oils includes in particular esters of C6-C30-fatty acids with C2-C30-fatty alcohols, preferably monoesters of the fatty acids with alcohols having 2 to 24 C-atoms.
  • Exemplary Esteröle are isopropyl myristate (IPM Rilanit ®), isononanoic acid C16-18 alkyl ester (Cetiol ® SN), 2-ethylhexyl palmitate (Cegesoft ® 24), stearic acid-2-ethylhexyl ester (Cetiol ® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkohol- caprate / caprylate (Cetiol ® LC), n-butyl stearate, oleyl erucate (Cetiol ® J 600), isopropyl palmitate (IPP Rilanit ®), oleyl Oleate (Cetiol ®), lauric acid hexyl ester (Cetiol ® A), di-n-butyl adipate (Cetiol ® B), my
  • the proportion by weight of the ester oil in the total weight of the cosmetic preparation is preferably from 0.01 to 1, 0 wt .-%, preferably 0.02 to 0.6 wt .-% and in particular 0.03 to 0.2 wt .-%.
  • the fibers described at the beginning as the first essential component of the cosmetic compositions can be modified in different ways. Such modifications relate, for example, to the above-described length of the fibers or their length to diameter ratio.
  • compositions Another possibility for influencing the technical and cosmetic properties of the compositions lies in the modification of the surface properties of the fibers used.
  • hydrophobized fibers are used.
  • the hydrophobing causes a water-repellent finish of the fiber.
  • Suitable hydrophobing agents are, for example, paraffins or waxes but also film-forming silicones.
  • the fibers may be advantageous if the fibers have a certain oil absorption capacity. This oil absorption capacity can be influenced by means of the previously described hydrophobization of the fibers. Preference is given to the use of hydrophobized or non-hydrophobized fibers having an oil absorption capacity above 0.2 g of jojoba oil per gram of fibers.
  • compositions may comprise surfactant as another optional ingredient.
  • surfactant for example, to allow for uniform suspension of the fibers in the cosmetic composition or to enhance the cosmetic effect of the composition, the compositions may comprise surfactant as another optional ingredient.
  • nonionic or cationic surfactants is preferred.
  • Preferred cationic surfactants are selected from the group of quaternary ammonium compounds.
  • Preferred quaternary ammonium compounds are again ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g.
  • the use of cetyltrimethylammonium chloride is very particularly preferred.
  • the proportion by weight of the surfactant in the total weight of the cosmetic composition is preferably 0.05 to 2.0 wt .-%, preferably 0.1 to 1, 5 wt .-% and in particular 0.2 to 1, 0 wt .-%.
  • hydrophilized fibers are used in the cosmetic compositions.
  • Corresponding fibers have an increased water absorption capacity compared to the non-hydrophilized fibers.
  • the water adsorption capacity (20 ° C.) of preferred fibers is preferably above 5.0% by weight, preferably above 7.0% by weight and in particular above 9.0% by weight of the inherent weight of the fibers.
  • preferred cosmetic compositions contain at least one perfume.
  • the agent may contain, for example, at least one protein hydrolyzate and / or one of its derivatives.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • the molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.
  • the agent according to the invention may further comprise at least one vitamin, a provitamin, a vitamin precursor and / or one of their derivatives.
  • vitamins, provitamins and vitamin precursors are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • panthenol is panthenol, caffeine, nicotinamide and sorbitol.
  • compositions according to the invention may further contain at least one plant extract, but also mono- or oligosaccharides and / or lipids.
  • Aerosol dispensing containers are particularly suitable for dispensing and applying the cosmetic compositions.
  • a further subject of the application are accordingly the cosmetic agent comprising
  • the cosmetic compositions according to the invention can be produced in a customary manner. As a rule, all components of the cosmetic composition, with the exception of the propellant, are introduced into a suitable pressure-resistant container. This is then closed with a valve. Finally, by conventional techniques, the desired amount of propellant is charged.
  • pressure-resistant containers are vessels of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated on the outside with plastic, in question in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic aspects, handiness, printability, etc. play a role.
  • Special internal protective lacquers ensure corrosion resistance compared to the composition in the pressure vessel.
  • the valves used on an internally painted valve disc, wherein the coating and valve material are compatible with each other. If aluminum valves are used, their valve plates can be internally z. B. be coated with Micoflex paint. If tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).
  • the multi-chamber dispenser can also be designed so that one chamber, the compressed propellant and another chamber is filled with the remaining components of the composition according to the invention.
  • a multi-chamber dispenser is for example a so-called bag-in-can packaging.
  • the spray rate of the cosmetic compositions is preferably 6.5 to 10.0 g / 10 s.
  • the agents according to the invention are particularly suitable for cleaning, refreshing and deodorising keratinous fibers.
  • Corresponding uses of the cosmetic compositions are further objects of this application.
  • a final subject of this application is a method for the temporary deformation of keratinic fibers, in particular human hair, in which a cosmetic composition according to the invention is applied to keratinic fibers.
  • a cosmetic composition according to the invention is applied to keratinic fibers.
  • constituents of this composition their proportions by weight and preferred embodiments mutatis mutandis the above applies.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
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  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Compositions cosmétiques pour le traitement cosmétique de fibres kératiniques, comprenant – dans tous les cas sur la base de leur poids - : (a) des fibres (b) éthanol (c) au moins un polymère (d) gaz propulseur (e) de 0 à 10% en poids de colorant(s) (f) de 0 à 10% en poids de pigment(s), sous réserve que la somme des quantités des ingrédients (e) et (f) soit de 0,0001 à 10% en poids, augmentant le volume de la chevelure et entraînant une augmentation de l'abondance et la sensation « d'avoir plus de cheveux ». La coloration des produits permet en même temps la couverture d'endroits chauves, sans déteindre sur les mains, les vêtements ou l'oreiller.
EP18762252.7A 2017-11-21 2018-08-27 Composition cosmétique vaporisable avec effet colorant Pending EP3713541A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102017220773.6A DE102017220773A1 (de) 2017-11-21 2017-11-21 Sprühbares kosmetisches Mittel mit Farbeffekt
PCT/EP2018/072964 WO2019101379A1 (fr) 2017-11-21 2018-08-27 Composition cosmétique vaporisable avec effet colorant

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EP3713541A1 true EP3713541A1 (fr) 2020-09-30

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US (1) US20210077363A1 (fr)
EP (1) EP3713541A1 (fr)
DE (1) DE102017220773A1 (fr)
WO (1) WO2019101379A1 (fr)

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Publication number Priority date Publication date Assignee Title
DE102019218857A1 (de) * 2019-12-04 2021-06-10 Henkel Ag & Co. Kgaa Verfahren zur Färbung von Keratinmaterial, umfassend die Anwendung eines organischen C1-C6-Alkoxysilans und Fasern
US11931433B2 (en) 2020-02-28 2024-03-19 Church & Dwight Co., Inc. Dry shampoo composition

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Publication number Priority date Publication date Assignee Title
DE19640099A1 (de) * 1996-09-28 1998-04-09 Wella Ag Verwendung von wasserunlöslichen Fasern in kosmetischen Mitteln zur Behandlung, Gestaltung oder Pflege der Frisur
JPH11158034A (ja) * 1997-11-26 1999-06-15 Kao Corp 微小繊維含有スプレー組成物
GB0201743D0 (en) * 2002-01-25 2002-03-13 Unilever Plc Cosmetic or personal care composition
ES2826898T3 (es) * 2016-04-15 2021-05-19 Manel Torres Composiciones pulverizables para peinar el pelo
DE102017205558A1 (de) 2017-03-31 2018-10-04 Henkel Ag & Co. Kgaa Sprühbares kosmetisches Mittel

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US20210077363A1 (en) 2021-03-18
WO2019101379A1 (fr) 2019-05-31

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