EP3629778A1 - Article générateur d'aérosol à source de chaleur isolée - Google Patents

Article générateur d'aérosol à source de chaleur isolée

Info

Publication number
EP3629778A1
EP3629778A1 EP18727803.1A EP18727803A EP3629778A1 EP 3629778 A1 EP3629778 A1 EP 3629778A1 EP 18727803 A EP18727803 A EP 18727803A EP 3629778 A1 EP3629778 A1 EP 3629778A1
Authority
EP
European Patent Office
Prior art keywords
aerosol
heat source
combustible heat
layer
ceramic paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP18727803.1A
Other languages
German (de)
English (en)
Inventor
Fabien DUC
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Philip Morris Products SA
Original Assignee
Philip Morris Products SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philip Morris Products SA filed Critical Philip Morris Products SA
Publication of EP3629778A1 publication Critical patent/EP3629778A1/fr
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40—Constructional details, e.g. connection of cartridges and battery parts
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/02—Cigars; Cigarettes with special covers
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/01—Making cigarettes for simulated smoking devices
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/10—Machines with wrapping rollers
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/22—Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/10—Devices using liquid inhalable precursors
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F42/00—Simulated smoking devices other than electrically operated; Component parts thereof; Manufacture or testing thereof
    • A24F42/10—Devices with chemical heating means
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F42/00—Simulated smoking devices other than electrically operated; Component parts thereof; Manufacture or testing thereof
    • A24F42/60—Constructional details
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F42/00—Simulated smoking devices other than electrically operated; Component parts thereof; Manufacture or testing thereof
    • A24F42/80—Manufacture

Definitions

  • the present invention relates to an aerosol-generating article comprising an aerosol- forming substrate and a combustible heat source, and a method for forming such an aerosol- generating article.
  • a number of aerosol-generating articles in which tobacco is heated rather than combusted have been proposed in the art.
  • One aim of such 'heated' aerosol-generating articles is to reduce known harmful smoke constituents of the type produced by the combustion and pyrolytic degradation of tobacco in combustible cigarettes.
  • an aerosol is generated by the transfer of heat from a combustible heat source to an aerosol-forming substrate located adjacent to the combustible heat source.
  • volatile compounds are released from the aerosol-forming substrate by heat transfer from the combustible heat source and entrained in air drawn through the aerosol-generating article. As the released compounds cool, they condense to form an aerosol that is inhaled by the user.
  • the combustion temperature of a combustible heat source for use in a heated aerosol- generating article should not be so high as to result in combustion or thermal degradation of the aerosol-forming substrate during use of the heated aerosol-generating article.
  • the combustion temperature of the combustible heat source should be sufficiently high to generate enough heat to release sufficient volatile compounds from the aerosol-forming substrate to produce an acceptable aerosol, especially during early puffs.
  • the combustion temperature of combustible heat sources for use in heated aerosol-generating articles is typically between about 600°C and 800°C.
  • an aerosol-generating article comprising an aerosol-forming substrate, a combustible heat source and at least one layer of ceramic paper circumscribing at least a portion of the length of the combustible heat source.
  • the at least one layer of ceramic paper comprises a cellulose derivative.
  • the combustible heat source may be ignited by an external heat source, such as a lighter, and may begin to combust.
  • the combusting heat source may heat the aerosol-forming substrate such that volatile compounds of the aerosol-forming substrate vaporise.
  • air may be drawn into the aerosol-generating article and mix with the vapour from the heated aerosol-forming substrate to form an aerosol.
  • the aerosol may be drawn out of the aerosol-generating article and delivered to the user for inhalation by the user.
  • the at least one layer of ceramic paper circumscribing at least part of the length of the combustible heat source may insulate the combustible heat source. This may reduce the surface temperature of the aerosol-generating article at the combustible heat source.
  • the at least one layer of ceramic paper may also allow sufficient air through the layer such that combustion of the combustible heat source may be substantially unimpeded.
  • the term 'paper' is used to describe a thin mat or sheet of fibres.
  • the papers described herein are manufactured from a pulp of fibres pressed into a thin sheet or mat.
  • the paper of the present invention may comprise woven fibres.
  • typically the paper of the present invention comprises non-woven fibres.
  • the fibres of the paper of the present invention may be randomly interwoven.
  • the papers described herein are generally thin. In other words, the thickness or depth of the mat or sheet of fibres is substantially less than the other dimensions of the mat or sheet, such as the length and width of the mat or sheet.
  • the papers described herein are flexible. In other words, the papers described herein may be bent or shaped in order to be wrapped around the circumference of a combustible heat source, such that the paper circumscribes at least a portion of the combustible heat source.
  • the term 'ceramic paper' is used to describe a paper comprising ceramic material.
  • the term 'ceramic paper' is used to describe a thin mat or sheet of fibres comprising ceramic material.
  • the terms 'ceramic paper' and 'ceramic fibre paper' are used interchangeably.
  • the ceramic paper of the present invention comprises fibres of ceramic material.
  • the ceramic paper may comprise woven fibres of ceramic material.
  • the ceramic paper may comprise nonwoven fibres of ceramic material.
  • the ceramic paper may comprise fibrous ceramic material comprising at least one of ceramic fibre batting, ceramic fibre wadding and ceramic fibre wool.
  • the ceramic paper may comprise fibres of ceramic material only. In other words, in some embodiments the ceramic paper may not comprise fibres of non-ceramic material.
  • the ceramic paper may comprise other forms of ceramic material, including particulate ceramic material.
  • the ceramic paper may comprise more than one form of ceramic material, for example, fibrous ceramic material and particulate ceramic material.
  • the ceramic material may comprise any suitable ceramic material.
  • the ceramic material may comprise crystalline ceramic materials.
  • the ceramic material may comprise semi-crystalline ceramic materials.
  • the ceramic material may comprise non-crystalline ceramic materials.
  • the ceramic material may be amorphous.
  • the ceramic material may be semi-crystalline.
  • the ceramic material may be crystalline.
  • the term 'ceramic material' encompasses glasses.
  • the term 'glass' is used to describe materials that exhibit a glass transition at a glass transition temperature.
  • the term 'glass' is used herein to describe non-crystalline or amorphous solid materials.
  • the term 'glass' also encompasses material comprising crystalline components and non-crystalline components. Glass materials comprising both crystalline and non-crystalline components may be referred to as 'glass-ceramic' materials.
  • the properties of the glass material of the present invention may be determined by the method of formation of the glass.
  • the term 'glass' encompasses glasses formed by any suitable method. Suitable methods of forming glasses include: melt quenching; physical vapour deposition; solid-state reactions, including thermochemical and mechanochemical reactions; liquid-state reactions, such as the sol-gel method; irradiation of crystalline solids, such as radiation amorphisation; and pressure amorphisation (i.e. formation under action of high pressure).
  • the ceramic material may comprise a glass.
  • the ceramic material may be a glass.
  • the glass may be a glass-ceramic material.
  • the ceramic paper may comprise glass fibres.
  • the ceramic paper may comprise glass-ceramic fibres.
  • the ceramic material may not comprise a glass.
  • the ceramic material may comprise any ceramic materials other than glasses.
  • the ceramic material may not be a glass material.
  • the ceramic material may not comprise glass fibres.
  • the ceramic material typically comprises crystalline ceramic materials.
  • the ceramic material may comprise at least one of an oxide, a carbide, a boride, a nitride and a silicide.
  • the ceramic material may comprise a metal oxide.
  • the ceramic paper may comprise at least one of silica (S1O2), calcium oxide (CaO), magnesium oxide (MgO), alumina (AI2O3) and zirconium dioxide (ZrO ⁇ ), all of which are understood to be ceramic materials.
  • the ceramic paper may comprise at least one of alkaline earth silicate wool, alumina silicate wool or polycrystalline wool.
  • the ceramic paper may comprise at least one of iron oxide (Fe203), potassium oxide (K2O), sodium oxide (Na20), all of which are understood to be ceramic materials.
  • the ceramic paper may comprise any suitable amount of fibrous material.
  • the ceramic paper may comprise at least about 40 percent by weight ceramic material; at least about 50 percent by weight ceramic material; or at least about 60 percent by weight ceramic material.
  • the ceramic paper may comprise less than about 99.99 percent by weight ceramic paper material; or less than about 95 percent by weight ceramic material.
  • the ceramic paper may comprise between about 50 percent by weight ceramic material and about 99.99 percent by weight ceramic material.
  • the ceramic paper may comprise non-fibrous material.
  • the non-fibrous material may include water.
  • the at least one layer of ceramic material according to the invention comprises a cellulose derivative binder. Binders are used in some ceramic papers to hold the ceramic material together. The provision of a binder may also improve the mechanical properties of the ceramic paper. For example, a binder may make the ceramic paper less brittle and more flexible. This may advantageously enable the at least one layer of ceramic paper to be wrapped around at least a portion of the combustible heat source.
  • the term "cellulose derivative binder” is used to describe a binder comprising a cellulose derivative.
  • the cellulose derivative binder may comprise a cellulose derivative which is formed by the addition of a particular side group to cellulose.
  • Suitable cellulose derivatives include, but are not limited to; carboxy methyl cellulose (CMC), hydroxypropyl methyl cellulose (HPMC), hydroxyethyl methyl cellulose (HEC), hydroxyethyl cellulose, cellulose acetate, cellulose ester, and cellulose ether.
  • CMC carboxy methyl cellulose
  • HPMC hydroxypropyl methyl cellulose
  • HEC hydroxyethyl methyl cellulose
  • cellulose acetate cellulose ester
  • cellulose ether cellulose ether
  • the cellulose derivative binder comprises carboxy methyl cellulose.
  • the cellulose derivative binder may be dispersed in a liquid, for example water, at a concentration between about 0.01 percent by weight and about 20 percent by weight.
  • ceramic paper comprising cellulose derivative binders advantageously holds the ceramic fibres together and provides the advantageous mechanical properties described above.
  • the use of ceramic paper comprising cellulose derivative binders does not produce an unpleasant odour when the combustible heat source is ignited and combusted.
  • the at least one layer of ceramic paper may comprise any amount of cellulose derivative binder.
  • the at least one layer of ceramic paper may comprise at least about 0.01 percent by weight cellulose derivative binder, at least about 1 percent by weight cellulose derivative binder, at least about 5 percent by weight cellulose derivative binder, or at least about 10 percent by weight cellulose derivative binder.
  • the at least one layer of ceramic paper may comprise no more than or equal to about 40 percent by weight cellulose derivative binder, no more than about 30 percent by weight cellulose derivative binder, or no more than about 15 percent by weight cellulose derivative binder.
  • the at least one layer of ceramic paper may comprise between about 0.01 percent by weight and about 40 weight percent by weight cellulose derivative binder.
  • the ceramic paper may comprise non-ceramic material.
  • the non-ceramic material may include a polymeric material.
  • the non-ceramic material may include an organic material.
  • the non-ceramic material may include an inorganic material.
  • the ceramic paper may be further reinforced by additional means, such as particulate reinforcement.
  • the ceramic paper may be reinforced with particles of carbon black.
  • the ceramic paper may further include any other suitable constituents, including but not limited to titanium dioxide, aluminium trihydrate and pigments which may include iron and manganese.
  • the ceramic paper may comprise any suitable amount of non-ceramic material. In some embodiments, the ceramic paper may comprise ceramic material only. In other words, in some embodiments, the ceramic paper may not comprise any non-ceramic materials.
  • the ceramic paper may comprise about 0 percent by weight non-ceramic material.
  • the ceramic paper may comprise between 0 percent by weight non-ceramic material and about 25 percent by weight non- ceramic material.
  • the ceramic paper may comprise: at least about 0.5 percent by weight non- ceramic material; at least about 2 percent by weight non-ceramic material; at least about 10 percent by weight non-ceramic material; at least about 20 percent by weight non-ceramic material; at least about 30 percent by weight non-ceramic material; or at least about 40 percent by weight non- ceramic material; or at least about 50 percent by weight non-ceramic material.
  • the ceramic paper may comprise less than about 40 percent by weight non-ceramic material; less than about 30 percent by weight non-ceramic paper material; or less than about 15 percent by weight non- ceramic material.
  • the ceramic paper may comprise low biopersistent fibres.
  • the fibrous material of the ceramic paper may consist of low biopersistent fibres.
  • biopersistence refers to the length of time that an intact fibre remains in the lung and pleura (thorax) of a respiratory system of a human.
  • Suitable short-term tests for measuring biopersistence include short-term inhalation experiments.
  • An exemplary short-term inhalation experiment comprises exposing rodents to a known concentration of a given fibre type for 6 hours per day for 5 days followed by periodic sacrifices to determine lung fibre burden. Such a procedure is described in Bernstein, D.M., C. Morscheidt, H.-G. Grimm, P. Thevenaz, and U. Teichert. 1996. Evaluation of soluble fibers using the inhalation biopersistence model, a nine-fiber comparison. Inhalation Toxicol. 8(4):345-385.
  • Alternative suitable short-term tests of measuring biopersistence include intratracheal instillation experiments comprising dosing of rodents by intratracheal instillation with a known amount of fibre in saline and periodic sacrifices to determine lung fibre burden.
  • Findings from both short-term inhalation methods and intratracheal instillation methods may be expressed as weighted clearance half-time (WT1 ⁇ 2) or as time required to clear 90% of the fibres from the lung (T90).
  • Fibres may be regarded as having "low biopersistence” or being "low biopersistent” if a short-term biopersistence test by inhalation has shown that the fibres longer than 20 micrometres have a weighted half life of 10 days or less or a short-term biopersistence test by intratracheal instillation has shown that the fibres longer than 20 micrometres have a weighted half life of 40 days or less, as set out in Note Q of European Commission Directive 97/69/EC of 5 December 1997.
  • Fibres may also be regarded as having "low biopersistence” or being “low biopersistent” if the half life after intra-tracheal instillation of 2 mg of a fine suspension for fibres with a length of 5 ⁇ , a diameter of less than 3 ⁇ and a length-to-diameter ratio of more than 3:1 (WHO fibres) is not more than 40 days, as set out in Note Q2 of European Commission Decision 1999/836/EC of 26 October 1999 on the national provisions concerning mineral wool notified by Germany derogating from Directive 97/69/EC.
  • a material with a low biopersistence may be removed or cleared from the respiratory system of a human by a mechanism.
  • One exemplary mechanism of removal of a material from the respiratory system is physical translocation, such as by mucociliary transport.
  • Another exemplary mechanism of removal of a material from the respiratory system is chemical dissolution. If the solubility of a material in a solvent of the respiratory system is sufficiently high, the material may be regarded as being "biosoluble".
  • the ceramic paper may comprise biosoluble fibres.
  • the fibrous material of the ceramic paper may consist of biosoluble fibres.
  • biosoluble' is used to describe a material that is soluble in a biological system; in particular, it is used to describe a material that is soluble in the respiratory system of a human.
  • the biosolubility of a material in the respiratory system of a human may differ significantly from the solubility of the material in water.
  • biosoluble fibres are considered to be low biopersistent fibres.
  • a substance may be considered to be "biosoluble” if in vitro static solubility tests indicate that at least 0.1 g of that substance dissolves in 100 ml of a solvent of the respiratory system of a human. Similarly, a substance may be considered to be bioinsoluble if static solubility tests indicate that less than 0.1 g of the material dissolves in 100 ml of a solvent of the respiratory system of a human.
  • a suitable in vitro static solubility test comprises exposing a sample of the substance to be tested to a suitable solvent at a temperature of 37°C for 24 hours. After 24 hours, dissolution may be measured by determining the dissolution-fluid composition or the weight of the remaining sample. For example, elemental analysis using inductively coupled plasma spectroscopy of the dissolution fluid may be used to calculate the total mass of the dissolved sample in the dissolution fluid.
  • Suitable solvents for use as a solvent of the respiratory system of a human in in vitro static solubility tests include physiological saline solution and surrogates for solvents of the respiratory system of a human, such as known simulated lung fluids (SLF).
  • SLF simulated lung fluids
  • Known suitable SLF include artificial lysosomal fluid (ALF) with a pH of about 4.5, analogous to fluid in which inhaled particles would come into contact after phagocytosis by alveolar and interstitial macrophages in the lung, and Gamble's solution with a pH of about 7.4, analogous to the interstitial fluid deep within the lung.
  • a substance may also be considered to be "biosoluble” if in vitro dynamic solubility tests indicate that the substance exhibits a dissolution rate constant of at least 150 nanograms per square centimeter per hour (ng/cm2 hr) in a solvent of the respiratory system of a human.
  • Suitable in vitro dynamic solubility tests comprise slowly flowing a suitable solvent over a sample of the test substance and measuring dissolution of the fibre over time. The test is conducted for a long period of time, such as at least three weeks, in order to determine if dissolution of the sample is uniform over a long period of time.
  • the suitable solvent is pumped slowly over a sample of fibre which has been normalised to its surface area, such that fresh solution is always presented to the sample.
  • a particular suitable in vitro dynamic solubility test comprises flowing a suitable solvent at a temperature of 37 degrees Celsius over a sample to be tested at a rate of 5 ml. per hour for a period of 1000 hours. The solution is collected and analysed for the concentration of elements leached from the fibre sample. The solution is collected multiple times over the test period, such as two times per week, to determine if dissolution of the sample is uniform or constant over time.
  • Dissolution may be measured by determining the dissolution-fluid composition or the weight of the remaining sample. For example, elemental analysis using inductively coupled plasma spectroscopy of the dissolution fluid may be used to calculate the total mass of the dissolved sample in the dissolution fluid at specific time intervals. Since the surface area of the sample and the flow rate of the solvent are known, and the leachant concentration is determined from the dissolution measurements, these values can be used to determine a dissolution rate by known methods. The dissolution rate may be expressed in nanograms per square centimeter per hour (ng/cm 2 hr).
  • Suitable solvents for use as a solvent of the respiratory system of a human in in vitro dynamic solubility tests include physiological saline solution and SLF, as described above for the in vitro static solubility tests.
  • the biosoluble material may be any suitable biosoluble material. Suitable biosoluble materials include alkaline earth silicate materials and high-alumina low-silica materials.
  • the fibrous material comprises alkaline earth silicate fibres. In some particularly preferred embodiments, the fibrous material consists essentially of alkaline earth silicate fibres. In some particularly preferred embodiments, the fibrous material consists of alkaline earth silicate fibres. ln some embodiments of the invention, the ceramic paper may comprise about 99.99 percent by weight fibrous alkaline-earth silicate material, such as alkaline-earth silicate wool.
  • the ceramic paper may comprise: between about 50 percent by weight fibrous alkaline-earth silicate material and about 99.99 percent by weight fibrous alkaline-earth silicate material.
  • the ceramic paper may comprise between about 60 percent by weight silicon dioxide and about 70 percent by weight silicon dioxide; between about 15 percent by weight calcium oxide and about 35 percent by weight calcium oxide; between about 4 percent by weight magnesium oxide and about 20 percent by weight magnesium oxide.
  • the ceramic paper may comprise: less than about
  • compositions mentioned above refers to the percentage by weight of the various components after the ceramic paper has been fired.
  • Ceramic papers comprising biosoluble ceramic fibres that are currently commercially available include: Superwool® Fibre Paper, Superwool® Fibre Flex Wrap, Superwool® HT Fibre, Superwool® Plus Fibre and Superwool® Plus 332-E; all of which are available from Morgan Advanced Materials, pic. Binder free ceramic papers may also be suitable, such as Rescor 300 BL from Final Advanced Materials, or the no-binder biosoluble fibre paper from DL-Thermal. Some binder free ceramic papers comprising at least one of: biosoluble fibres; low biopersistent fibres; and fibres comprising at least one of: silicon dioxide, calcium oxide, and magnesium oxide may be suitable. Some binder free ceramic papers comprising alkaline earth silicate fibres may be suitable.
  • the ceramic paper may comprise one or more of, biosoluble fibres and low biopersistent fibres.
  • suitable materials which are at least one of biosoluble and low biopersistent include, but are not limited, to silicon dioxide, calcium oxide, and magnesium oxide.
  • Particularly suitable materials which are at least one of biosoluble and low biopersistent include alkaline earth silicates.
  • the ceramic paper may have a low thermal conductivity.
  • the ceramic paper may be a good thermal insulator.
  • the ceramic paper may have a thermal conductivity of between about 0.5 to 2 W/mK at a temperature of about 23°C. This low thermal conductivity is observed particularly where the ceramic paper comprises woven or non-woven fibrous ceramic material. This may be due to the relatively open, highly porous structure of ceramic paper comprised of fibrous ceramic material, which reduces heat transfer by conduction.
  • the ceramic paper may have a high permeability to air. This may be due to the relatively open, highly porous structure.
  • the at least one layer of ceramic paper may be sufficiently permeable to air to enable the combustible heat source to combust substantially unimpeded.
  • the at least one layer of ceramic paper may have a permeability to air of greater than about 4000 (cm 3 /(min * cm 2 ).
  • the at least one layer of ceramic paper circumscribes at least portion of the length of the combustible heat source.
  • the at least one layer of ceramic paper of the present invention may circumscribe substantially the full length of the combustible heat source. This may enable the aerosol-generating article to benefit from the insulating properties of the ceramic paper, to reduce the surface temperature proximate to the heat source during use, and to benefit from the permeability to air of the ceramic paper, enabling sufficient ambient air to reach the combustible heat source for the combustible heat source to ignite and combust substantially unimpeded.
  • the ceramic paper may have advantageous mechanical properties.
  • the ceramic paper may be flexible and machinable due to the reinforcing effect of the ceramic material, in particular the ceramic fibres if they are present.
  • the ceramic paper may have a machinability that facilitates formation of a layer of the ceramic paper circumscribing at least a portion of the length of the heat source.
  • the term 'layer' is used to describe a body of material generally conforming to the shape of the combustible heat source.
  • the at least one layer of ceramic paper may be any suitable type of layer arranged to circumscribe the heat source. Suitable types of layer include, amongst others, wrappers and coatings.
  • the term 'coating' is used to describe a layer of material that covers and is adhered to the heat source.
  • the at least one layer of ceramic paper may be in direct contact with the combustible heat source.
  • the at least one layer of ceramic paper may be spaced apart from the combustible heat source.
  • the at least one layer of ceramic paper circumscribes at least a portion of the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe about half the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe more than half the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe between about 60 percent and about 100 percent of the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe at least about 70 percent of the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe at least about 80 percent of the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe at least about 90 percent of the length of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe substantially the length of the combustible heat source.
  • the at least one layer ceramic paper may circumscribe the entire length of the combustible heat source.
  • the term 'length' is used to describe the dimension of a component or a part of the aerosol-generating article in the longitudinal direction of the aerosol-generating article.
  • the at least one layer of ceramic paper may circumscribe about half the length of the aerosol-forming substrate.
  • the at least one layer of ceramic paper circumscribing the aerosol-forming substrate may lower the surface temperature of the aerosol-generating article at the aerosol-forming substrate.
  • the at least one layer of ceramic paper may circumscribe the combustible heat source at a downstream end of the combustible heat source. This may advantageously reduce the surface temperature of the aerosol-generating article at the portion of the combustible heat source which is nearest to the user during normal operation of the aerosol-generating article.
  • the at least one layer of ceramic paper may circumscribe the combustible heat source at an upstream end of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe the combustible heat source at the upstream end and at the downstream end.
  • Uncovered portions of the combustible heat source may be referred to herein as 'naked' portions.
  • the at least one layer of ceramic paper of the present invention may be provided to cover or circumscribe 'naked' or uncovered portions of the combustible heat source.
  • a portion of the combustible heat source may be circumscribed by at least one additional layer at the upstream end.
  • the at least one additional layer may be a layer of cigarette paper.
  • an upstream portion of the combustible heat source is a naked portion. In other words, an upstream portion of the combustible heat source is not covered by the at least one additional layer.
  • the at least one layer of ceramic paper may circumscribe the upstream portion of the combustible heat source.
  • the at least one layer of ceramic paper may circumscribe the combustible heat source from the upstream end of the at least one additional layer circumscribing the upstream portion of the combustible heat source to at or around the downstream end of the combustible heat source.
  • the combustible heat source may be circumscribed substantially along its length by a combination of the at least one additional layer at the downstream end and the at least one layer of ceramic paper at the upstream end.
  • the at least one layer of ceramic paper and the at least one additional layer may overlap along the length of the combustible heat source.
  • the combustible heat source, the aerosol-forming substrate and the at least one layer of ceramic paper may be configured to substantially prevent or inhibit the temperature of the aerosol- forming substrate from exceeding about 375°C during the combustion of the combustible heat source.
  • the combustible heat source, the aerosol-forming substrate and the at least one layer of ceramic paper may be shaped, dimensioned and arranged to substantially prevent or inhibit the temperature of the aerosol-forming substrate from exceeding about 375°C during combustion of the combustible heat source. This may preserve the integrity of the aerosol-forming substrate.
  • the aerosol-forming substrate comprises one or more aerosol-formers
  • the aerosol-formers may undergo pyrolysis above temperatures of about 375°C. At even higher temperatures, and where the aerosol-forming substrate comprises tobacco, for example, the tobacco may combust.
  • the combustible heat source, the aerosol-forming substrate and the at least one layer of ceramic paper may be configured such that during combustion of the combustible heat source the temperature of the aerosol-forming substrate at 2mm from the proximal face of the aerosol-forming substrate is at least about 100°C for a period of at least about 6 minutes.
  • the at least one layer of ceramic paper may have any suitable thickness. Generally, the at least one layer of ceramic paper is a thin layer. The thickness of the at least one layer of ceramic paper may be at least about 0.25 millimetres or at least about 0.5 millimetres. The thickness of the at least one layer of ceramic paper may be less than about 10 millimetres or less than about 5 millimetres. The at least one layer of ceramic paper may have a thickness of between about 0.25 millimetres and about 10 millimetres or between about 0.5 millimetres and about 5 millimetres.
  • the at least one layer of ceramic paper may further comprise one or more air inlets, such as one or more perforations.
  • the one or more air inlets may further increase the permeability to air of the at least one layer of ceramic paper.
  • the aerosol-generating article further comprises one or more airflow pathways along which air may be drawn through the aerosol-generating article for inhalation by a user.
  • air may be drawn into the aerosol-generating article along the one or more airflow pathways.
  • the at least one layer of ceramic paper may be isolated from the one or more airflow pathways such that, in use, air drawn through the aerosol-generating article along the one or more airflow pathways does not directly contact the at least one layer of ceramic paper.
  • the at least one layer of ceramic paper may be spaced from the one or more airflow pathways such that air drawn through the aerosol-generating article along the one or more airflow pathways does not directly contact the at least one layer of ceramic paper.
  • one or more portions of the at least one layer of ceramic paper may be covered, coated or encapsulated in a material substantially impermeable to fibres and particles.
  • the one or more portions of the at least one layer of ceramic paper that are covered, coated or encapsulated in a material substantially impermeable to fibres and particles may be located in proximity to air drawn through the aerosol-generating article along the one or more airflow pathways.
  • the covering, coating or encapsulation may isolate air drawn through the aerosol- generating article along the one or more airflow pathways from the fibres and particles of the at least one layer of ceramic paper.
  • one or more portions of the at least one layer ceramic paper may be covered in a layer of paper to isolate the at least one layer of ceramic paper from the one or more airflow pathways.
  • the layer of paper may be provided on at least one of the inner surface of the at least one layer of ceramic paper and the outer surface of the at least one layer of ceramic paper.
  • the layer of paper may be provided on both the inner and outer surfaces of the at least one layer of ceramic paper.
  • the layer of paper may comprise laminated paper.
  • the layer of paper may be co-laminated with the at least one layer ceramic paper.
  • the layer of paper may be provided on only a portion of the at least one layer of ceramic paper that is adjacent the airflow pathways.
  • the at least one layer of ceramic paper may be substantially combustion resistant.
  • the term 'combustion-resistant' refers to a material that remains substantially intact during ignition and combustion of the combustible heat source.
  • the provision of at least one layer of combustion resistant ceramic paper circumscribing at least a portion of the length of the combustible heat source may advantageously prevent flames or smoke being emitted from the layer. This may substantially prevent or inhibit undesirable emissions or odours being released from the layer during the combustion of the combustible heat source.
  • the aerosol-generating article further comprises one or more non-combustible, substantially air impermeable barriers between the combustible heat source and the aerosol forming substrate.
  • the one or more non-combustible, substantially air impermeable barriers between the combustible heat source and the aerosol forming substrate isolate the combustible heat source from the one or more airflow pathways such that, in use, air drawn through the aerosol-generating article along the one or more airflow pathways does not directly contact the combustible heat source.
  • An aerosol-generating article comprises an aerosol- forming substrate.
  • the term 'aerosol-forming substrate' is used to describe a substrate capable of releasing volatile compounds upon heating, which can form an aerosol.
  • the aerosols generated from aerosol-forming substrates of aerosol-generating articles according to the invention may be visible or invisible and may include vapours (for example, fine particles of substances, which are in a gaseous state, that are ordinarily liquid or solid at room temperature) as well as gases and liquid droplets of condensed vapours.
  • the aerosol-forming substrate may be solid.
  • the aerosol-forming substrate may be solid at room temperature.
  • the aerosol-forming substrate may comprise at least one aerosol-former and at least one material capable of emitting volatile compounds in response to heating.
  • the at least one aerosol-former may be any suitable known compound or mixture of compounds that, in use, facilitates formation of a dense and stable aerosol and that is substantially resistant to thermal degradation at the operating temperature of the aerosol-generating article.
  • Suitable aerosol-formers are well known in the art and include, for example, polyhydric alcohols, esters of polyhydric alcohols, such as glycerol mono-, di- or triacetate, and aliphatic esters of mono- , di- or polycarboxylic acids, such as dimethyl dodecanedioate and dimethyl tetradecanedioate.
  • Exemplary aerosol-formers for use in aerosol-generating articles according to the invention are polyhydric alcohols or mixtures thereof, such as triethylene glycol, 1 ,3-butanediol and, glycerine.
  • the material capable of emitting volatile compounds in response to heating may be a charge of plant-based material, for example a charge of homogenised plant-based material.
  • the aerosol-forming substrate may comprise one or more materials derived from plants including, but not limited to: tobacco; tea, for example green tea; peppermint; laurel; eucalyptus; basil; sage; verbena; and tarragon.
  • the plant based-material may comprise additives including, but not limited to, humectants, flavourants, binders and mixtures thereof.
  • the plant-based material may consist of essentially of tobacco material, optionally homogenised tobacco material.
  • Aerosol-generating articles according to the invention may comprise aerosol-forming substrates comprising nicotine.
  • aerosol-generating articles according to the invention comprise aerosol-forming substrates comprising tobacco.
  • the aerosol-forming substrate may be circumscribed by a filter plug wrap.
  • An aerosol-generating articles comprises a combustible heat source arranged to heat the aerosol-forming substrate and isolated from the one or more airflow pathways.
  • the combustible heat source may comprise a body of combustible material.
  • the body of combustible material may have a substantially constant diameter.
  • the body of combustible material may have a constant diameter along its length. This advantageously may simplify the processes involved in manufacturing the combustible heat source and aerosol-generating article.
  • the body of combustible material may form a substantially circularly cylindrical body having a substantially constant diameter along its length.
  • the combustible heat source may be a carbonaceous heat source.
  • the term 'carbonaceous' is used to describe a combustible heat source comprising carbon.
  • combustible carbonaceous heat sources for use in aerosol-generating articles according to the invention have a carbon content of at least about 35 percent, more preferably of at least about 40 percent, most preferably of at least about 45 percent by dry weight of the 30 combustible heat source.
  • the combustible heat source according to the present invention may be a combustible carbon-based heat source.
  • the term 'carbon-based heat source' is used to describe a heat source comprised primarily of carbon.
  • Combustible carbon-based heat sources for use in aerosol-generating articles according to the invention may have a carbon content of at least about 50 percent, preferably of at least about 60 percent, more preferably of at least about 70 percent, most preferably of at least about 80 percent by dry weight of the combustible carbon-based heat source.
  • the combustible heat source of the present invention is isolated from the one or more airflow pathways through the aerosol-generating article.
  • the term 'airflow pathway' is used to describe a route along which air may be drawn through the aerosol-generating article for inhalation by a user.
  • the terms 'upstream' and 'downstream' are used to describe relative directions and positions of components of the aerosol-generating article in relation to the direction air flows through the one or more airflow pathways when a user draws on the aerosol-generating article. Isolation of the combustible heat source from the one or more airflow pathways of the aerosol-generating article may substantially prevent or inhibit activation of combustion of the combustible heat source during puffing by a user.
  • This may substantially prevent or inhibit spikes in the temperature of the aerosol-forming substrate during puffing by a user. This may substantially prevent or inhibit combustion or pyrolysis of the aerosol-forming substrate under intense puffing regimes. This may substantially prevent or inhibit changes in the composition of the aerosol generated by the aerosol-generating article due to a user's puffing regime.
  • Isolation of the combustible heat source from the one or more airflow pathways may also substantially prevent or inhibit combustion and decomposition products, and other materials formed during ignition and combustion of the combustible heat source, from entering air drawn through the aerosol-generating article along the one or more airflow pathways.
  • the isolated combustible heat source of the present invention may comprise a blind heat source.
  • a blind heat source As used herein, the term 'blind' is used to describe a combustible heat source in which air drawn through the aerosol-generating article for inhalation by a user does not pass through an airflow channel along the combustible heat source. As such, heat transfer between the blind combustible heat source and the aerosol-forming substrate occurs predominantly by conductive heat transfer.
  • convective heat transfer between the combustible heat source and the aerosol-forming substrate is reduced or minimised.
  • Reducing convective heat transfer between the combustible heat source and the aerosol-forming substrate may substantially prevent or inhibit spikes in the temperature of the aerosol forming substrate during puffing by a user. This may substantially prevent or inhibit combustion or pyrolysis of the aerosol-forming substrate under intense puffing regimes. This may substantially prevent or inhibit changes in the composition of the aerosol generated by the aerosol- generating article due to a user's puffing regime. This may also substantially prevent or inhibit combustion and decomposition products, and other materials formed during ignition and combustion of the combustible heat source, from entering air drawn through the aerosol-generating article along the one or more airflow pathways.
  • the isolated combustible heat source of the present invention may comprise a non-blind heat source.
  • a non-blind heat source As used herein, the term 'non-blind' is used to describe a heat source in which air drawn through the aerosol-generating article for inhalation by a user passes through one or more airflow channels along the heat source.
  • heat transfer between the non-blind combustible heat source and the aerosol-forming substrate may occur both by conductive heat transfer and by convective heat transfer along the one or more airflow channels.
  • the term 'airflow channel' is used to describe a channel extending along the length of a combustible heat source through which air may be drawn downstream for inhalation by a user.
  • the aerosol-generating article of the present invention may not comprise one or more airflow channels.
  • the one or more non-combustible, substantially air impermeable barriers between the combustible heat source and the aerosol forming substrate may comprise a first barrier that abuts one or both of a proximal end of the combustible heat source and a distal end of the aerosol- forming substrate.
  • the first barrier may facilitate isolation of the combustible heat source from the one or more airflow pathways of the aerosol-generating article.
  • the first barrier may reduce the maximum temperature to which the aerosol-forming substrate is exposed during ignition or combustion of the combustible heat source, and may substantially prevent or inhibit thermal degradation or combustion of the aerosol-forming substrate during use of the aerosol-generating article.
  • non-combustible is used to describe a material that is substantially non-combustible at temperatures reached by the combustible heat source during combustion or ignition thereof.
  • air impermeable' is used to describe a material that substantially prevents or inhibits the passage of air therethrough.
  • the first barrier may abut one or both of the proximal end of the combustible heat source and the distal end of the aerosol-forming substrate.
  • the first barrier may be adhered or otherwise affixed to one or both of the proximal end of the combustible heat source and the distal end of the aerosol-forming substrate.
  • the first barrier may comprise a first barrier coating provided on a proximal face of the combustible heat source.
  • the first barrier may comprise a first barrier coating provided on at least substantially the entire proximal face of the combustible heat source.
  • the first barrier may comprise a first barrier coating provided on the entire proximal face of the combustible heat source.
  • the first barrier coating may be formed and applied to the proximal face of the combustible heat source by any suitable method, such as the methods described in WO- A1-2013120855.
  • the first barrier may have a low thermal conductivity or a high thermal conductivity.
  • the first barrier may have a thermal conductivity of between about 0.1 W/m.K and about 200 W/m.K.
  • the thickness of the first barrier may be suitably adjusted to achieve good aerosol- generating performance.
  • the first barrier may have a thickness of between about 10 microns and about 500 microns.
  • the first barrier may be formed from one or more suitable materials that are substantially thermally stable and non-combustible at temperatures achieved by the combustible heat source during ignition and combustion.
  • suitable materials include, but are not limited to, clays (such as, for example, bentonite and kaolinite), glasses, minerals, ceramic materials, resins, metals and combinations thereof.
  • Materials from which the first barrier may be formed include clays and glasses. More materials from which the first barrier may be formed include copper, aluminium, stainless steel, alloys, alumina (AI2O3), resins, and mineral glues.
  • the first barrier coating may advantageously act as a thermal link between the combustible heat source and the aerosol-forming substrate. This may improve conductive heat transfer from the combustible heat source to the aerosol-forming substrate.
  • the aerosol-generating article may further comprise one or more air inlets downstream from a proximal end of the combustible heat source.
  • the one or more air inlets are between a proximal end of the combustible heat source and a proximal end of the aerosol-generating article.
  • the one or more air inlets may be arranged such that air may be drawn into the one or more airflow pathways of the aerosol-generating article, though the one or more air inlets, without being drawn through the combustible heat source. This may substantially prevent or inhibit spikes in the temperature of the aerosol-forming substrate during puffing by a user.
  • the one or more air inlets may comprise any suitable air inlets through which air may be drawn into the aerosol-generating article.
  • suitable air inlets include holes, slits, slots or other apertures.
  • the number, shape, size and arrangement of the air inlets may be suitably adjusted to achieve a good aerosol-generating performance.
  • the one or more air inlets may be arranged at the aerosol-forming substrate.
  • the one or more air inlets may be arranged between a distal end of the aerosol-forming substrate and a proximal end of the aerosol-forming substrate.
  • the filter plug wrap may be provided with one or more openings to allow air into the aerosol-forming substrate.
  • the one or more openings may be slits, slots or other suitable apertures through which air may be drawn into the aerosol-forming substrate. The number, shape, size and arrangement of the openings may be suitably adjusted to achieve a good aerosol-generating performance.
  • the combustible heat source may comprise one or more airflow channels.
  • the combustible heat source may be a non-blind heat source.
  • the one or more airflow channels may extend along the length of the combustible heat source.
  • the one or more airflow channels may form part of the one or more airflow pathways of the aerosol-generating article.
  • the combustible heat source comprises one or more airflow channels in the aerosol- generating article
  • the one or more non-combustible, substantially air impermeable barriers between the combustible heat source and the aerosol forming substrate may further comprise a second barrier between the combustible heat source and the one or more airflow channels of the combustible heat source.
  • the second barrier may facilitate isolation of the combustible heat source from the one or more airflow pathways of the aerosol-generating article.
  • the second barrier may reduce the maximum temperature to which the aerosol-forming substrate is exposed during ignition or combustion of the combustible heat source, and so help to avoid or reduce thermal degradation or combustion of the aerosol-forming substrate during use of the aerosol-generating article.
  • the second barrier may be adhered or otherwise affixed to the combustible heat source.
  • the second barrier may comprise a second barrier coating provided on an inner surface of the one or more airflow channels.
  • the second barrier may comprise a second barrier coating provided on at least substantially the entire inner surface of the one or more airflow channels.
  • the second barrier may comprise a second barrier coating provided on the entire inner surface of the one or more airflow channels.
  • the second barrier coating may be provided by insertion of a liner into the one or more airflow channels.
  • a liner may be inserted into each of the one or more airflow channels.
  • the second barrier may advantageously substantially prevent or inhibit combustion and decomposition products formed during ignition and combustion of the combustible heat source of aerosol-generating articles according to the invention from entering air drawn downstream along the one or more airflow channels.
  • the second barrier may have a low thermal conductivity or a high thermal conductivity.
  • the second barrier may have a low thermal conductivity.
  • the thickness of the second barrier may be suitably adjusted to achieve good aerosol- generating performance.
  • the second barrier may have a thickness of between about 30 microns and about 200 microns. In an embodiment, the second barrier has a thickness of between about 30 microns and about 100 microns.
  • the second barrier may be formed from one or more suitable materials that are substantially thermally stable and non-combustible at temperatures achieved by the combustible heat source during ignition and combustion.
  • suitable materials include, but are not limited to, for example: clays; metal oxides, such as iron oxide, alumina, titania, silicon dioxide, silica-alumina, zirconia and ceria; zeolites; zirconium phosphate; and other ceramic materials or combinations thereof.
  • Materials from which the second barrier may be formed include clays, glasses, aluminium, iron oxide and combinations thereof.
  • catalytic ingredients such as ingredients that promote the oxidation of carbon monoxide to carbon dioxide, may be incorporated in the second barrier. Suitable catalytic ingredients include, but are not limited to, for example, platinum, palladium, transition metals and their oxides.
  • aerosol-generating articles according to the invention comprise a first barrier between a downstream end of the combustible heat source and an upstream end of the aerosol- forming substrate and a second barrier between the combustible heat source and one or more airflow channels along the combustible heat source
  • the second barrier may be formed from the same or different material or materials as the first barrier
  • the second barrier coating may be applied to the inner surface of the one or more airflow channels by any suitable method, such as the methods described in US-A-5,040,551 and WO-A1 -2013120855.
  • the aerosol-generating article may further comprise one or more additional layers circumscribing at least a proximal portion of the combustible heat source and a distal portion of the aerosol-forming substrate.
  • the one or more additional layers may comprise at least one of: a heat- conducting element to transfer heat from the combustible heat source to the aerosol-forming substrate; and a layer of cigarette paper.
  • the heat-conducting element may circumscribe only a distal portion of the aerosol-forming substrate.
  • the heat-conducting element may circumscribe substantially the length of the aerosol- forming substrate.
  • the heat-conducting element may be in direct contact with at least one of the combustible heat source and the aerosol-forming substrate.
  • the heat-conducting element may not be in direct contact with either of the combustible heat source and the aerosol-forming substrate.
  • the heat-conducting element may provide a thermal link between the combustible heat source and the aerosol-forming substrate.
  • the heat-conducting element may be substantially combustion-resistant.
  • Suitable heat-conducting elements may include: metal foil wrappers or metal alloy foil wrappers.
  • the metal foil wrappers may include: aluminium foil wrappers, steel foil wrappers, iron foil wrappers and copper foil wrappers.
  • the heat-conducting element may comprise a tube of aluminium.
  • the proximal portion of the combustible heat source circumscribed by the heat-conducting element may be between about 2 millimetres and about 8 millimetres in length or between about 3 millimetres and about 5 millimetres in length.
  • the distal portion of the combustible heat source not surrounded by the heat-conducting element may be between about 4 millimetres and about 15 millimetres in length or between about 4 millimetres and about 8 millimetres in length.
  • the layer of cigarette paper may circumscribe at least a proximal portion of the combustible heat source, the length of aerosol-forming substrate and any other components of the aerosol- generating article arranged proximal to the aerosol-forming substrate.
  • the layer of cigarette paper may circumscribe substantially the length of the combustible heat source.
  • the layer of cigarette paper may be provided with ventilation, such as perforations, holes or slits, at the combustible heat source to enable air to pass through the layer of cigarette paper to the combustible heat source.
  • the number, shape, size and location of the openings may be suitably adjusted to achieve a good aerosol-generating performance.
  • the layer of cigarette paper may be tightly wrapped around the combustible heat source and the aerosol-forming substrate such that the layer of cigarette paper grips and secures the combustible heat source and the aerosol-forming substrate when the aerosol-generating article is assembled.
  • the at least one layer of ceramic paper may be a radially outer layer.
  • the radially outer layer of ceramic paper may overly at least a portion of the one or more additional layers.
  • the one or more additional layers may be arranged between the combustible heat source and the at least one layer of ceramic paper.
  • the heat conducting element may be a radially inner layer and the at least one layer of ceramic paper may be a radially outer layer, circumscribing at least a portion of the heat conducting element.
  • the terms 'radially outer' and 'radially inner' are used to indicate the relative distances of components of the aerosol-generating article from the longitudinal axis of the aerosol- generating article.
  • the term 'radial' is used to describe the direction perpendicular to the longitudinal axis of the aerosol-generating article that extends in the direction between the proximal end and the distal end of the aerosol-generating article.
  • the one or more additional layers may be radially outer layers.
  • the one or more additional layers may overlay at least a portion of the at least one layer of ceramic paper.
  • the at least one layer of ceramic paper may be secured or attached to one or more other components or parts of the aerosol-generating article.
  • the at least one layer of ceramic paper may be secured to any suitable component of the aerosol-generating article.
  • the at least one layer of ceramic paper may be secured to at least one of the combustible heat source, the aerosol-forming substrate and the one or more additional layers.
  • the at least one layer of ceramic paper may be secured to one or more components of the aerosol-generating article by any suitable means.
  • the at least one layer of ceramic paper may be secured using an adhesive. Suitable adhesives may exhibit high temperature resistance, such as silicate glue. Where the one or more additional layers are radially outer layers, the one or more additional layers may be tightly wrapped around at least a portion of the at least one layer of ceramic paper.
  • the at least one layer of ceramic paper may be integral with the combustible heat source.
  • the term 'integral' is used to describe a layer that is in direct contact with the combustible heat source and attached to the combustible heat source without the aid of an extrinsic adhesive or other intermediate connecting material.
  • the at least one layer of ceramic paper may be formed from a strip of ceramic paper having opposing ends.
  • the strip of ceramic paper may be wrapped around the combustible heat source such that the opposing ends of the strip overlap.
  • the overlapping opposing ends of the strip may be secured together using an adhesive or any other suitable means. This may secure the at least one layer of ceramic paper on the combustible heat source.
  • an intermediate layer may be provided between the at least one layer of ceramic paper and at least one of the combustible heat source, the aerosol-forming substrate and the one or more additional layers.
  • the intermediate layer may be adjacent to the at least one layer of ceramic paper.
  • the intermediate layer may be in contact with the at least one layer of ceramic paper.
  • the intermediate layer may be arranged radially inward of the at least one layer of ceramic paper.
  • the intermediate layer may be an adhesive layer.
  • the adhesive layer may comprise any suitable adhesive. Suitable adhesives may exhibit high temperature resistance, such as silicate glue.
  • the adhesive layer may be arranged between the at least one layer of ceramic paper and the combustible heat source and may attach the at least one layer of ceramic paper to the combustible heat source.
  • the adhesive layer may be arranged between the at least one layer of ceramic paper and the one or more additional layers and may attach the at least one layer of ceramic paper to the one or more additional layers.
  • the adhesive layer may be arranged between the at least one layer of ceramic paper and the aerosol-forming substrate and may attach the at least one layer of ceramic paper to the aerosol-forming substrate.
  • the at least one layer of ceramic paper may be formed from a strip of ceramic paper having opposing ends.
  • the strip of ceramic paper may be wrapped around the combustible heat source such that the opposing ends of the strip abut and do not overlap.
  • An adhesive layer may be provided on the side of the strip facing the combustible heat source, at least at the opposing ends of the strip. The adhesive layer may secure the strip of ceramic paper to the combustible heat source, at least at the opposing ends of the strip.
  • the aerosol-generating article may comprise a heat conducting member arranged between the combustible heat source and the aerosol-forming substrate.
  • the heat conducting member may be the first barrier, described above.
  • the aerosol-generating article may comprise a heat conducting member and a first barrier.
  • the heat conducting member may comprise similar material to the heat conducting element.
  • the aerosol-generating article may comprise a heat conducting member and a heat conducting element. The provision of at least one of the heat- conducting element and the heat conducting member may facilitate conductive heat transfer between the combustible heat source and the aerosol-forming substrate.
  • the aerosol-generating article may further comprise any other suitable components.
  • the aerosol-generating article may comprise at least one of: a transfer element; an aerosol-cooling element; a spacer element; and a mouthpiece.
  • the one or more further components may be arranged coaxially with the combustible heat source and the aerosol-forming substrate.
  • the one or more further components may be arranged proximal to the aerosol-forming substrate.
  • the one or more further components may be arranged in any suitable order.
  • the aerosol-generating article may further comprise: a transfer element adjacent to the proximal end of the aerosol-forming substrate; an aerosol-cooling element adjacent to the proximal end of the transfer element; a spacer element adjacent to the proximal end of the aerosol-cooling element; and a mouthpiece adjacent to the proximal end of the spacer element.
  • proximal' and 'distal' are used to describe the relative positions of components, or portions of components, of aerosol-generating articles according to invention.
  • the proximal end of a component of the aerosol-generating article is the end of that component that is nearest the mouth end of the aerosol-generating article and the distal end of a component of the aerosol-generating article is the end of the component that is furthest from the mouth end of the aerosol-generating article.
  • the combustible heat source is arranged at the distal end of the aerosol-generating article.
  • a method of forming an aerosol-generating article comprises: arranging a combustible heat source to heat an aerosol-forming substrate; and circumscribing at least part of the length of the combustible heat source with at least one layer of ceramic paper comprising a cellulose derivative binder.
  • the step of circumscribing at least a portion of the length of the combustible heat source with at least one layer of ceramic paper may comprise: providing a strip of ceramic paper comprising a cellulose derivative binder having opposing ends; wrapping the strip around the combustible heat source such that the combustible heat source is circumscribed by at least one layer of ceramic paper; overlapping the opposing ends of the strip; and securing together the overlapping ends to secure the at least one layer of ceramic paper to the combustible heat source.
  • the overlapping ends of the strip of ceramic paper may be secured together using any suitable means.
  • the overlapping ends of the strip of ceramic paper may be secured together using adhesive.
  • Suitable adhesives should have high temperature resistance and include silica glue.
  • the step of circumscribing at least a portion of the length of the combustible heat source with at least one layer of ceramic paper may comprise: providing a strip ceramic paper comprising a cellulose derivative binder having opposing ends; applying an layer of adhesive to one side of the strip at least at each of the opposing ends; arranging the strip with the adhesive layer facing the combustible heat source; wrapping the strip around the combustible heat source such that at least a portion of the length of the combustible heat source is circumscribed by at least one layer of ceramic paper; abutting the opposing ends of the strip without overlapping the opposing ends; and securing the strip to the combustible heat source with the adhesive layer.
  • the at least one layer of ceramic paper may be laminated with an additional layer, such as a layer of cigarette paper.
  • the at least one layer of ceramic paper may be laminated with the additional layer before the at least one layer of ceramic paper is applied to the combustible heat source.
  • a strip of the co-laminated paper comprising the at least one layer of ceramic paper and the additional layer may be wrapped around the combustible heat source in the same manner as the strip of ceramic paper.
  • the co-laminated paper may be arranged such that the at least one layer of ceramic paper faces the combustible heat source.
  • the at least one layer of ceramic paper may be arranged radially inwards of the additional layer.
  • the co-laminated paper may be arranged such that the additional layer faces the combustible heat source.
  • cellulose derivative binder may be used as a binder in other layers used to circumscribe at least a portion of the length of a combustible heat source of an aerosol-generating article.
  • a cellulose derivative binder may be used in a layer of any fibrous material.
  • a cellulose derivative binder may be used in a layer of fibrous material comprising ceramic fibres.
  • a cellulose derivative binder may be used in a layer of fibre-reinforced aerogel.
  • the term 'aerogel' is used to describe an open-celled foam.
  • the aerogel may be mesoporous.
  • the term 'mesoporous' refers to a material that contains pores ranging from about 2 nanometres to about 50 nanometres in diameter.
  • the aerogel may comprise a network of interconnected structures, the network of interconnected structures may be nanostructures.
  • the aerogel may exhibit a porosity of about 50 percent or more.
  • the aerogel may exhibit a porosity of about 90 percent or more.
  • the aerogel may be formed by removing the liquid component from a conventional gel.
  • a conventional gel will be understood to mean a semi-solid colloidal suspension of a solid dispersed in a liquid.
  • Aerogels typically have very low thermal conductivities. Without wishing to be bound by theory, conductive heat transfer is inhibited in aerogels due to their high porosity while convective heat transfer is inhibited in aerogels due the small diameter of the pores. The small diameter of the pores restricts air movement through the aerogel.
  • the term 'fibre-reinforced aerogel' refers to a composite material comprising an aerogel matrix reinforced with a fibrous material.
  • Figure 1 shows a schematic representation of a first embodiment of an aerosol-generating article according to the present invention comprising a blind combustible heat source
  • Figure 2 shows the temperature profiles of aerosol-generating articles similar to that shown in Figure 1 at a first position in the articles;
  • Figure 3 shows the temperature profiles of aerosol-generating articles similar to that shown in Figure 1 at a second position in the articles;
  • Figure 4 shows the temperature profiles of the aerosol-generating articles similar to that shown in Figure 1 at a third position in the articles;
  • Figure 5 shows the temperature profiles of further aerosol-generating articles similar to that shown in Figure 1 at the third position in the articles, one of the aerosol-generating articles comprising a ceramic paper having biosoluble alkaline earth silicate fibres and
  • Figure 6 shows a schematic representation of a second embodiment of an aerosol- generating article according to the present invention comprising a non-blind combustible heat source.
  • FIG. 1 shows a schematic representation of an aerosol-generating article 2.
  • the aerosol- generating article 2 comprises a combustible heat source 3.
  • the combustible heat source 3 comprises a substantially circularly cylindrical body of carbonaceous material, having a length of about 10 millimetres.
  • the combustible heat source 3 is a blind heat source. In other words, the combustible heat source 3 does not comprise any air channels extending therethrough.
  • the aerosol-generating article 2 further comprises an aerosol-forming substrate 4.
  • the aerosol-forming substrate 4 is arranged at a proximal end of the combustible heat source 3.
  • the aerosol-forming substrate 4 comprises a substantially circularly cylindrical plug of tobacco material 18 circumscribed by filter plug wrap 19.
  • a non-combustible, substantially air impermeable first barrier 6 is arranged between the proximal end of the combustible heat source 3 and a distal end of the aerosol-forming substrate 4.
  • the first barrier 6 comprises a disc of aluminium foil.
  • the first barrier 6 also forms a heat- conducting member between the combustible heat source 3 and the aerosol-forming substrate 4, for conducting heat from the proximal face of the combustible heat source 3 to the distal face of the aerosol-forming substrate 4.
  • a heat-conducting element 9 circumscribes a proximal portion of the combustible heat source 3 and a distal portion of the aerosol-forming substrate 4.
  • the heat-conducting element 9 comprises a tube of aluminium foil. The heat-conducting element 9 is in direct contact with the proximal portion of the combustible heat source 3 and the filter plug wrap 19 of the aerosol-forming substrate 4.
  • the aerosol-generating article 2 further comprises various other components arranged proximal to the aerosol-forming substrate 4, including: a transfer element 1 1 arranged at the proximal end of the aerosol-forming substrate 4; an aerosol-cooling element 12 arranged at the proximal end of the transfer element 1 1 ; a spacer element 13 arranged at the proximal end of the aerosol-cooling element 1 1 ; and a mouthpiece 10 arranged at a proximal end of the spacer element 13.
  • the components of the aerosol-generating article 2 are wrapped in a layer of cigarette paper 7.
  • the layer of cigarette paper 7 circumscribes the heat conducting element 9, but does not extend beyond the distal end of the heat conducting element 9, over the distal portion of the combustible heat source 3.
  • the aerosol-generating article 2 further comprises a layer of ceramic paper 5.
  • the layer of ceramic paper 5 circumscribes substantially the length of the combustible heat source 3 and a distal portion of the layer of cigarette paper 7, the heat- conducting element 9 and the aerosol-forming substrate 4.
  • the layer of ceramic paper 5 is the radially outer layer at the distal end of the aerosol-generating article 2.
  • the layer of ceramic paper 5 comprises between about 60 percent by weight silicon dioxide and about 70 percent by weight silicon dioxide; between about 16 percent by weight calcium oxide and about 22 percent by weight calcium oxide and between about 12 percent by weight magnesium oxide and about 19 percent by weight magnesium oxide.
  • the layer of ceramic paper 5 also comprises aluminium oxide.
  • the layer of ceramic paper 5 also comprises a cellulose derivative binder.
  • the cellulose derivative binder comprises CMC dispersed in water at a concentration of 8 weight percent.
  • a plurality of air inlets 8 are arranged at the aerosol-forming substrate 4 to allow ambient air to be drawn into the aerosol-generating article 2.
  • the air inlets 8 comprise a plurality of perforations through the layer of cigarette paper 7 and the underlying layer of plug wrap 19 that circumscribes the aerosol-forming substrate 4.
  • the air inlets 8 are arranged between the distal face and the proximal face of the aerosol-forming substrate 4.
  • ambient air may be drawn into the aerosol-generating article 2 through the air inlets 8.
  • the air drawn into the aerosol-generating article 2 may flow along an airflow pathway of the aerosol-generating article 2, from the air inlets 8, through the aerosol-forming substrate 4, the transfer element 1 1 , the cooling element 12 and the spacer element 13 to the mouthpiece 10, and out of the mouthpiece 10 to the user for inhalation.
  • the general direction of the airflow through the aerosol-generating article 2 is indicated by the arrows.
  • a user may ignite the combustible heat source 3 by exposing the combustible heat source 3 to an external heat source, such as a lighter.
  • the combustible heat source 3 may ignite and combust and heat may be transferred from the combustible heat source 3 to the aerosol- forming substrate 4, via conduction through the heat-conducting member 6 and the heat- conducting element 9. Volatile components of the heated aerosol-forming substrate 4 may be vapourised.
  • a user may draw on the mouthpiece 10 of the aerosol-generating article 2, drawing ambient air into the airflow pathway of the aerosol-generating article 2, through the air inlets 8.
  • the vapour from the heated aerosol-forming substrate 4 may be entrained in the air drawn through the aerosol-forming substrate 4 and may be drawn with the air towards the mouthpiece 10. As the vapour is drawn towards the mouthpiece 10, the vapour may cool to form an aerosol. The aerosol may be drawn out of the mouthpiece 10 and be delivered to the user for inhalation.
  • the substantially air-impermeable first barrier 6 inhibits air being drawn through the combustible heat source 3 and into the aerosol-forming substrate 4. As such, the first barrier 6 substantially isolates the airflow pathway of the aerosol-generating article 2 from the combustible heat source 3.
  • the layer of ceramic paper 5 extends over a minor portion of the distal end of the aerosol-forming substrate 4. As such, the layer of ceramic paper 5 is spaced from the air inlets 8. This spacing substantially isolates the layer of ceramic paper 5 from the air inlets 8, such that air drawn through the airflow pathway of the aerosol-generating article 2 does not come into contact with the layer of ceramic paper 5.
  • the layer of ceramic paper may be in close proximity to the air inlets.
  • portions of the layer of ceramic paper that are in close proximity to the air inlets may be coated in a material substantially impermeable to fibres and particles. This may substantially isolate the portions of the layer of ceramic paper that are in close proximity to the air inlets, such that air drawn through the airflow pathway of the aerosol-generating article does not come into contact with the layer of ceramic paper.
  • Figure 2 shows the temperature measured at a position 2 millimetres from the distal end of the combustible heat source, which corresponds to position Ti shown in Figure 1. In other words, Figure 2 shows the temperature at the distal end of the combustible heat source.
  • Figure 3 shows the temperature measured at a position 5 millimetres from the distal end of the combustible heat source, which corresponds to position T2 shown in Figure 1 .
  • Figure 3 shows the temperature approximately half way along the length of the combustible heat source.
  • Figure 4 shows the temperature measured at a position 1 1 millimetres from the distal end of the combustible heat source, which corresponds to position T3 in Figure 1 .
  • Figure 4 shows the temperature at the distal end of the aerosol-forming substrate.
  • the "SMAR" line shows the temperature profile of the aerosol-generating article with a "naked” combustible heat source.
  • the "SMAR" line 22 shows the temperature profile of the aerosol-generating article with no layer of material circumscribing substantially the length of the combustible heat source.
  • the "ceramic paper 1 " line, labelled as 21 , shows the temperature profile of the aerosol-generating article with a layer of ceramic paper circumscribing substantially the length of the combustible heat source.
  • the ceramic paper circumscribing substantially the length of the combustible heat source in the "ceramic paper 1 " test was Superwool® Plus Fibre available from Morgan Advanced Materials, pic.
  • the "ceramic paper 2" line shows the temperature profile of the aerosol-generating article with a layer of ceramic paper circumscribing substantially the length of the combustible heat source.
  • the ceramic paper circumscribing substantially the length of the combustible heat source in the "ceramic paper 2" test was CFP Ceramic Fibre Paper available from Ningbo Firewheel Thermal Insulation & Sealing Co., Ltd.
  • the "glass paper” line shows the temperature profile of the aerosol-generating article with a layer of ceramic paper circumscribing substantially the length of the combustible heat source.
  • the ceramic paper circumscribing substantially the length of the combustible heat source in the "glass paper” test was ceramic paper comprising glass fibres.
  • the aerosol-generating articles having a layer of material circumscribing substantially the length of the aerosol-generating article to exhibit temperatures profiles substantially similar to or exceeding the temperature profile 20 of the aerosol-generating article with the naked combustible heat source, with no layer of material circumscribing substantially the length of the combustible heat source.
  • the combustible heat source exhibits a similar or greater temperature than the naked combustible heat source, this indicates that the layer of material circumscribing substantially the length of the combustible heat source does not substantially inhibit combustion of the combustible heat source.
  • the temperature profiles 21 , 22, 23 of the aerosol-generating article having a layer of ceramic paper circumscribing substantially the length of the combustible heat source are substantially similar to the temperature profile 20 of the aerosol- generating article with no layer of material circumscribing substantially the length of the combustible heat source at all three tested locations of the aerosol-generating article for the majority of the combustion time of the combustible heat source.
  • the temperature profiles 21 and 22 of the aerosol-generating article having a layer of ceramic paper circumscribing substantially the length of the combustible heat source actually exceeds the temperature profile 20of the aerosol-generating article with no layer of material circumscribing substantially the length of the combustible heat source for some periods of time during the aerosol-generating experience.
  • providing at least one layer of ceramic paper circumscribing substantially the length of the combustible heat source advantageously does not substantially impede combustion of the combustible heat source.
  • providing the layer of ceramic paper may increase the temperature of the combustible heat source for periods of time during combustion of the combustible heat source.
  • Figure 5 shows a graph of further experimental data collected as described above for three specific aerosol-generating articles. Similar to Figure 4, Figure 5 shows the temperature at the distal end of the aerosol-forming substrate, measured at a position 1 1 millimetres from the distal end of the combustible heat source, which corresponds to position T3 in Figure 1. The temperature profiles were again measured using electronic temperature probes that were inserted approximately 2 millimetres deep into the aerosol-forming substrate of the aerosol-generating articles.
  • the "SMAR" line shows the temperature profile of the aerosol- generating article with a "naked” combustible heat source.
  • the "SMAR" line 22 shows the temperature profile of the aerosol-generating article with no layer of material circumscribing substantially the length of the combustible heat source.
  • the "glass paper” line shows the temperature profile of the aerosol-generating article with a layer of ceramic paper circumscribing substantially the length of the combustible heat source.
  • the ceramic paper circumscribing substantially the length of the combustible heat source in the "glass paper” test was ceramic paper comprising glass fibres.
  • the ceramic paper comprising glass fibres had a thickness of about 1 millimetre and a length of about 5.5 millimetres, extending from the distal end of the combustible heat source over the entire length of the combustible heat source and the distal end of the aerosol-forming substrate.
  • the "biosoluble fibres” line shows the temperature profile of the aerosol-generating article with a layer of ceramic paper circumscribing substantially the length of the combustible heat source.
  • the ceramic paper circumscribing substantially the length of the combustible heat source in the "biosoluble fibres" test was Superwool® Plus Fibre available from Morgan Advanced Materials, pic.
  • Superwool® Plus Fibre comprises biosoluble alkaline earth silicate fibres.
  • the ceramic paper comprising biosoluble fibres had a thickness of about 0.5 millimetres and a length of about 5.5 millimetres, extending from the distal end of the combustible heat source over the entire length of the combustible heat source and the distal end of the aerosol- forming substrate.
  • the temperature profile 32 of the aerosol-generating article having the layer of ceramic paper comprising biosoluble alkaline earth silicate fibres has been found to be indicate a higher temperature after a time period of around 200 seconds than both the temperature profile 30 of the aerosol-generating article with no layer of material circumscribing substantially the length of the combustible heat source and the temperature profile 31 of the aerosol-generating article with a layer of ceramic paper comprising glass fibres after a period of 200 seconds.
  • the smoking time may be increased by providing an aerosol-forming article with a layer of ceramic paper comprising biosoluble alkaline earth silicate fibres circumscribing substantially the length of the combustible heat source, even compared to articles having a layer of ceramic paper comprising glass fibres circumscribing substantially the length of the combustible heat source.
  • Aerosol-generating articles according to the invention were tested by observing their effect from placing them on Whatmann papers after the heat source was ignited.
  • the aerosol-generating articles were conditioned for 24 hours at about 23°C ⁇ 3°C and 55% ⁇ 5% relative humidity.
  • the conditioned aerosol-generating articles were lit, using an electric lighter, and left to combust for a period of 2 minutes.
  • the aerosol-generating articles were placed on a stack of Whatmann papers for a period of 10 minutes.
  • the aerosol-generating article having the layer of ceramic paper circumscribing substantially the length of the combustible heat source did not produce a hole in any of the Whatmann papers and produced a small area of browning in the top paper. This result shows that having the layer of ceramic paper circumscribing substantially the length of the combustible heat source reduces the surface temperature proximate to the heat source.
  • FIG. 6 A schematic representation of a second embodiment of an aerosol-generating article according to the present invention is shown in Figure 6.
  • the aerosol-generating article 102 is substantially similar to the aerosol-generating article 2 shown in Figure 1.
  • the aerosol-generating article 102 comprises a combustible heat source 103, an aerosol-forming substrate 104, a layer of ceramic paper 105 and a layer of cigarette paper 107 arranged similarly to the corresponding components of the aerosol-generating article 2 shown in Figure 1.
  • combustible heat source 103 is a non-blind heat source.
  • the non-blind heat source 103 comprises an annular body
  • the passage 1 16 forms part of the airflow pathway through the aerosol- generating article and enables air to be drawn from the proximal end of the aerosol-generating article, through the combustible heat source 103, and to the aerosol-forming substrate 104.
  • the layer of ceramic paper 105 is spaced from the airflow pathway through the aerosol-generating article 102 such that air drawn through the airflow pathway does not come into contact with the layer of ceramic paper 105.
  • a non-combustible, substantially air impermeable, first barrier 106 is arranged between the proximal end of the combustible heat source 103 and the distal end of the aerosol-forming substrate 104, similar to the first barrier 6 described above in relation to Figure 1. However, unlike the first barrier 6 described above, the first barrier 106 includes an aperture 120, aligned with the passage 1 16, to enable air to pass from the passage 1 16 to the aerosol-forming substrate 104.
  • a non-combustible, substantially air impermeable, second barrier 1 17 is coated on the inner surface of the passage 1 16.
  • the second barrier 1 17 isolates air passing through the passage
  • the aerosol-generating article 102 does not comprise air inlets arranged at the aerosol-forming substrate 104.
  • ambient air may be drawn into the aerosol-generating article 102 through the passage 1 16 through the heat source 103.
  • the air drawn into the aerosol-generating article 102 may flow along an airflow pathway of the aerosol- generating article 102, through the passage 1 16, through the aerosol-forming substrate 104, the transfer element, the cooling element and the spacer element to the mouthpiece, and out of the mouthpiece to the user for inhalation.
  • the general direction of the airflow through the aerosol- generating article 102 is indicated by the arrows.
  • air inlets may also be provided in the aerosol-generating article, in addition to the air passage through the combustible heat source.

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Paper (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)
  • Medicinal Preparation (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un article générateur d'aérosol (2) qui comprend un substrat formant un aérosol (4), une source de chaleur combustible (3) et au moins une couche de papier céramique (5) entourant au moins une partie de la longueur de la source de chaleur combustible (3). La au moins une couche de papier céramique (5) comprend un liant dérivé de la cellulose.
EP18727803.1A 2017-05-31 2018-05-30 Article générateur d'aérosol à source de chaleur isolée Pending EP3629778A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17173843 2017-05-31
PCT/EP2018/064297 WO2018220082A1 (fr) 2017-05-31 2018-05-30 Article générateur d'aérosol à source de chaleur isolée

Publications (1)

Publication Number Publication Date
EP3629778A1 true EP3629778A1 (fr) 2020-04-08

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EP18727803.1A Pending EP3629778A1 (fr) 2017-05-31 2018-05-30 Article générateur d'aérosol à source de chaleur isolée

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US (1) US20200196660A1 (fr)
EP (1) EP3629778A1 (fr)
JP (1) JP7414527B2 (fr)
KR (1) KR20200011941A (fr)
CN (1) CN110602954A (fr)
AR (1) AR111898A1 (fr)
BR (1) BR112019022734A2 (fr)
TW (1) TW201904453A (fr)
WO (1) WO2018220082A1 (fr)

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BR112018073559B1 (pt) * 2016-05-31 2023-01-24 Philip Morris Products S.A. Artigo gerador de aerossol e método de formação do artigo gerador de aerossol
CN109497611B (zh) * 2018-12-12 2021-03-16 湖北中烟工业有限责任公司 一种改进的加热不燃烧卷烟用降温嘴棒
ES2951999T3 (es) * 2019-05-24 2023-10-26 Philip Morris Products Sa Nuevo sustrato generador de aerosol
MX2021014916A (es) * 2019-06-10 2022-01-18 Philip Morris Products Sa Envoltura estable para articulo generador de aerosol.
US12075819B2 (en) * 2019-07-18 2024-09-03 R.J. Reynolds Tobacco Company Aerosol delivery device with consumable cartridge
CN114554882A (zh) 2019-10-14 2022-05-27 菲利普莫里斯生产公司 具有不可燃涂层的气溶胶生成制品
CN113907446A (zh) * 2020-07-07 2022-01-11 中国烟草总公司郑州烟草研究院 炭加热卷烟

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US4771795A (en) * 1986-05-15 1988-09-20 R. J. Reynolds Tobacco Company Smoking article with dual burn rate fuel element
US5040551A (en) 1988-11-01 1991-08-20 Catalytica, Inc. Optimizing the oxidation of carbon monoxide
EP0399252A3 (fr) * 1989-05-22 1992-04-15 R.J. Reynolds Tobacco Company Article à fumer avec matériau isolant
US5129409A (en) * 1989-06-29 1992-07-14 R. J. Reynolds Tobacco Company Extruded cigarette
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US5065776A (en) * 1990-08-29 1991-11-19 R. J. Reynolds Tobacco Company Cigarette with tobacco/glass fuel wrapper
US5105837A (en) * 1990-08-28 1992-04-21 R. J. Reynolds Tobacco Company Smoking article with improved wrapper
TW201340892A (zh) * 2012-02-13 2013-10-16 Philip Morris Prod 包括隔離可燃熱源之吸煙製品
TWI639391B (zh) 2012-02-13 2018-11-01 菲利浦莫里斯製品股份有限公司 包括隔離可燃熱源之吸煙製品
TWI657753B (zh) * 2013-09-02 2019-05-01 瑞士商菲利浦莫里斯製品股份有限公司 具有不重疊且徑向分離的雙導熱元件之煙品
TWI657755B (zh) 2013-12-30 2019-05-01 Philip Morris Products S. A. 包含隔熱可燃熱源之煙品
US20170205117A1 (en) * 2016-01-18 2017-07-20 Unifrax I Llc Thermal insulation composite for solar thermal tower, solar thermal tower and energy generation system
TW201801618A (zh) 2016-05-31 2018-01-16 菲利浦莫里斯製品股份有限公司 具有一絕緣的熱源之氣溶膠產生物件
BR112018073559B1 (pt) 2016-05-31 2023-01-24 Philip Morris Products S.A. Artigo gerador de aerossol e método de formação do artigo gerador de aerossol

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RU2019142656A (ru) 2021-06-30
CN110602954A (zh) 2019-12-20
JP2020521441A (ja) 2020-07-27
RU2019142656A3 (fr) 2021-09-22
TW201904453A (zh) 2019-02-01
WO2018220082A1 (fr) 2018-12-06
JP7414527B2 (ja) 2024-01-16
KR20200011941A (ko) 2020-02-04
US20200196660A1 (en) 2020-06-25
BR112019022734A2 (pt) 2020-05-12
AR111898A1 (es) 2019-08-28

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