EP3603976B1 - Flüssigkeitsausstosskopf, flüssigkeitsausstossmodul und flüssigkeitsausstossverfahren - Google Patents

Flüssigkeitsausstosskopf, flüssigkeitsausstossmodul und flüssigkeitsausstossverfahren Download PDF

Info

Publication number
EP3603976B1
EP3603976B1 EP19189000.3A EP19189000A EP3603976B1 EP 3603976 B1 EP3603976 B1 EP 3603976B1 EP 19189000 A EP19189000 A EP 19189000A EP 3603976 B1 EP3603976 B1 EP 3603976B1
Authority
EP
European Patent Office
Prior art keywords
liquid
ejection
pressure chamber
pressure
ejection head
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP19189000.3A
Other languages
English (en)
French (fr)
Other versions
EP3603976A1 (de
Inventor
Yoshiyuki Nakagawa
Akiko Hammura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2019079641A external-priority patent/JP7286394B2/ja
Application filed by Canon Inc filed Critical Canon Inc
Publication of EP3603976A1 publication Critical patent/EP3603976A1/de
Application granted granted Critical
Publication of EP3603976B1 publication Critical patent/EP3603976B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14201Structure of print heads with piezoelectric elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14016Structure of bubble jet print heads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14016Structure of bubble jet print heads
    • B41J2/14032Structure of the pressure chamber
    • B41J2/1404Geometrical characteristics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14016Structure of bubble jet print heads
    • B41J2/14032Structure of the pressure chamber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/1433Structure of nozzle plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14016Structure of bubble jet print heads
    • B41J2002/14169Bubble vented to the ambience
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2202/00Embodiments of or processes related to ink-jet or thermal heads
    • B41J2202/01Embodiments of or processes related to ink-jet heads
    • B41J2202/11Embodiments of or processes related to ink-jet heads characterised by specific geometrical characteristics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2202/00Embodiments of or processes related to ink-jet or thermal heads
    • B41J2202/01Embodiments of or processes related to ink-jet heads
    • B41J2202/12Embodiments of or processes related to ink-jet heads with ink circulating through the whole print head
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2202/00Embodiments of or processes related to ink-jet or thermal heads
    • B41J2202/01Embodiments of or processes related to ink-jet heads
    • B41J2202/20Modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2202/00Embodiments of or processes related to ink-jet or thermal heads
    • B41J2202/01Embodiments of or processes related to ink-jet heads
    • B41J2202/21Line printing

Definitions

  • This disclosure is related to a liquid ejection head.
  • JP H06 305143 A discloses a liquid ejection unit configured to bring a liquid serving as an ejection medium and a liquid serving as a bubbling medium into contact with each other on an interface, and to eject the ejection medium with a growth of a bubble generated in the bubbling medium receiving transferred thermal energy.
  • JP H06 305143 A describes a method of forming flows of the ejection medium and the bubbling medium by applying a pressure to these media after ejection of the ejection medium, thus stabilizing the interface between the ejection medium and the bubbling medium in a liquid flow passage.
  • Liquid ejection units that are configured to bring an ejection medium and a bubbling medium in contact with each other on an interface are also known from JP H05 169663 A and WO 2018/193446 A1 .
  • US 6 331 050 B1 discloses a liquid ejection head comprising: a first liquid flow path including an ejection port; a second liquid flow path including a pressure generation element; and a movable member disposed between the first and second liquid flow paths, facing the pressure generation element and configured to be displaced to a side of the first liquid flow path because of pressure generated by the pressure generation element.
  • an object of this disclosure is to provide a liquid ejection head which is capable of stabilizing an interface between an ejection medium and a bubbling medium in a case where an ejection operation takes place, thus maintaining good ejection performances.
  • Fig. 1 is a perspective view of a liquid ejection head 1 usable in this embodiment.
  • the liquid ejection head 1 of this embodiment is formed by arraying multiple liquid ejection modules 100 in an x direction.
  • Each liquid ejection module 100 includes an element board 10 on which ejection elements are arrayed, and a flexible wiring board 40 for supplying electric power and ejection signals to the respective ejection elements.
  • the flexible wiring boards 40 are connected to an electric wiring board 90 used in common, which is provided with arrays of power supply terminals and ejection signal input terminals.
  • Each liquid ejection module 100 is easily attachable to and detachable from the liquid ejection head 1. Accordingly, any desired liquid ejection module 100 can be easily attached from outside to or detached from the liquid ejection head 1 without having to disassemble the liquid ejection head 1.
  • liquid ejection head 1 formed by arraying the multiple arrangement of the liquid ejection modules 100 (by an array of multiple modules) in a longitudinal direction as described above, even if a certain one of the ejection elements causes an ejection failure, only the liquid ejection module involved in the ejection failure needs to be replaced. Thus, it is possible to improve a yield of the liquid ejection heads 1 during a manufacturing process thereof, and to reduce costs for replacing the head.
  • Fig. 2 is a block diagram showing a control configuration of a liquid ejection apparatus 2 applicable to this embodiment.
  • a CPU 500 controls the entire liquid ejection apparatus 2 in accordance with programs stored in a ROM 501 while using a RAM 502 as a work area.
  • the CPU 500 performs prescribed data processing in accordance with the programs and parameters stored in the ROM 501 on ejection data to be received from an externally connected host apparatus 600, for example, thereby generating the ejection signals to enable the liquid ejection head 1 to perform the ejection.
  • the liquid ejection head 1 is driven in accordance with the ejection signals while a target medium for depositing the liquid is moved in a predetermined direction by driving a conveyance motor 503.
  • the liquid ejected from the liquid ejection head 1 is deposited on the deposition target medium for adhesion.
  • a liquid circulation unit 504 is a unit configured to circulate and supply the liquid to the liquid ejection head 1 and to conduct flow control of the liquid in the liquid ejection head 1.
  • the liquid circulation unit 504 includes a sub-tank to store the liquid, a flow passage for circulating the liquid between the sub-tank and the liquid ejection head 1, pumps, a flow rate control unit for controlling a flow rate of the liquid flowing in the liquid ejection head 1, and so forth. Hence, under the instruction of the CPU 500, these mechanisms are controlled such that the liquid flows in the liquid ejection head 1 at a predetermined flow rate.
  • Fig. 3 is a cross-sectional perspective view of the element board 10 provided in each liquid ejection module 100.
  • the element board 10 is formed by stacking an orifice plate 14 (an ejection port forming member) on a silicon (Si) substrate 15.
  • ejection ports 11 arrayed in the x direction eject the liquid of the same type (such as a liquid supplied from a common sub-tank or a common supply port).
  • Fig. 3 illustrates an example in which the orifice plate 14 is also provided with liquid flow passages 13.
  • the element board 10 may adopt a configuration in which the liquid flow passages 13 are formed by using a different component (a flow passage forming member) and the orifice plate 14 provided with the ejection ports 11 is placed thereon.
  • Pressure generation elements 12 are disposed, on the silicon substrate 15, at positions corresponding to the respective ejection ports 11. Each ejection port 11 and the corresponding pressure generation element 12 are located at such positions that are opposed to each other. In a case where a voltage is applied in response to an ejection signal, the pressure generation element 12 applies a pressure to the liquid in a z direction orthogonal to a flow direction (a y direction) of the liquid. Accordingly, the liquid is ejected in the form of a droplet from the ejection port 11 opposed to the pressure generation element 12.
  • the flexible wiring board 40 (see Fig. 1 ) supplies the electric power and driving signals to the pressure generation elements 12 via terminals 17 arranged on the silicon substrate 15.
  • the orifice plate 14 is provided with the multiple liquid flow passages 13 which extend in the y direction and are connected one by one to the ejection ports 11, respectively. Meanwhile, the liquid flow passages 13 arrayed in the x direction are connected to a first common supply flow passage 23, a first common collection flow passage 24, a second common supply flow passage 28, and a second common collection flow passage 29 in common. Flows of liquids in the first common supply flow passage 23, the first common collection flow passage 24, the second common supply flow passage 28, and the second common collection flow passage 29 are controlled by the liquid circulation unit 504 described with reference to Fig. 2 .
  • the liquid circulation unit 504 performs the control such that a first liquid flowing from the first common supply flow passage 23 into the liquid flow passages 13 is directed to the first common collection flow passage 24 while a second liquid flowing from the second common supply flow passage 28 into the liquid flow passages 13 is directed to the second common collection flow passage 29.
  • Fig. 3 illustrates an example in which the ejection ports 11 and the liquid flow passages 13 arrayed in the x direction, and the first and second common supply flow passages 23 and 28 as well as the first and second common collection flow passages 24 and 29 used in common for supplying and collecting inks to and from these ports and passages are defined as a set, and two sets of these constituents are arranged in the y direction.
  • Fig. 3 illustrates the configuration in which each ejection port is located at the position opposed to the corresponding pressure generation element 12, or in other words, in a direction of growth of a bubble.
  • this embodiment is not limited only to this configuration.
  • each ejection port may be located at such a position that is orthogonal to the direction of growth of a bubble.
  • Figs. 4A to 4D are diagrams for explaining detailed configurations of each liquid flow passage 13 and of each pressure chamber 18 formed in the element board 10.
  • Fig. 4A is a perspective view from the ejection port 11 side (from a +z direction side) and Fig. 4B is a cross-sectional view taken along the IVB-IVB line shown in Fig. 4A .
  • Fig. 4C is an enlarged diagram of the neighborhood of each liquid flow passage 13 in the element board shown in Fig. 3 .
  • Fig. 4D is an enlarged diagram of the neighborhood of the ejection port in Fig. 4B .
  • the silicon substrate 15 corresponding to a bottom portion of the liquid flow passage 13 includes a second inflow port 21, a first inflow port 20, a first outflow port 25, and a second outflow port 26, which are formed in this order in the y direction.
  • the pressure chamber 18 communicating with the ejection port 11 and including the pressure generation element 12 is located substantially at the center between the first inflow port 20 and the first outflow port 25 in the liquid flow passage 13.
  • the second inflow port 21 is connected to the second common supply flow passage 28, the first inflow port 20 is connected to the first common supply flow passage 23, the first outflow port 25 is connected to the first common collection flow passage 24, and the second outflow port 26 is connected to the second common collection flow passage 29, respectively (see Fig. 3 ).
  • the first liquid 31 goes through the pressure chamber 18 and is then collected into the first common collection flow passage 24 through the first outflow port 25.
  • a second liquid 32 supplied from the second common supply flow passage 28 to the liquid flow passage 13 through the second inflow port 21 flows in the y direction (the direction indicated with arrows).
  • the second liquid 32 goes through the pressure chamber 18 and is then collected into the second common collection flow passage 29 through the second outflow port 26. That is to say, in the liquid flow passage 13, both of the first liquid and the second liquid flow in the y direction in a section between the first inflow port 20 and the first outflow port 25.
  • the pressure generation element 12 comes into contact with the first liquid 31 while the second liquid 32 exposed to the atmosphere forms a meniscus in the vicinity of the ejection port 11.
  • the first liquid 31 and the second liquid 32 flow in the pressure chamber 18 such that the pressure generation element 12, the first liquid 31, the second liquid 32, and the ejection port 11 are arranged in this order.
  • the second liquid 32 flows above the first liquid 31.
  • the first liquid 31 and the second liquid 32 flow in a laminar state.
  • the first liquid 31 and the second liquid 32 are pressurized by the pressure generation element 12 located below and are ejected upward from the bottom. Note that this up-down direction corresponds to a height direction of the pressure chamber 18 and of the liquid flow passage 13.
  • a flow rate of the first liquid 31 and a flow rate of the second liquid 32 are adjusted in accordance with physical properties of the first liquid 31 and physical properties of the second liquid 32 such that the first liquid 31 and the second liquid 32 flow in contact with each other in the pressure chamber as shown in Fig. 4D .
  • the pressure generation element 12 may still be driven in the case where it is possible to maintain the state where at least the first liquid flows mainly on the pressure generation element 12 side and the second liquid flows mainly on the ejection port 11 side.
  • the following description will be mainly focused on the example where the flow inside the pressure chamber is in the state of parallel flows and in the state of laminar flows.
  • a density of a liquid is defined as ⁇
  • a flow velocity thereof is defined as u
  • a representative length thereof is defined as d
  • a viscosity is defined as ⁇
  • a surface tension thereof is defined as y.
  • the laminar flows are more likely to be formed as the Reynolds number Re becomes smaller.
  • flows inside a circular tube are formed into laminar flows in the case where the Reynolds number Re is smaller than some 2200 and the flows inside the circular tube become turbulent flows in the case where the Reynolds number Re is larger than some 2200.
  • a height H [ ⁇ m] of the flow passage (the height of the pressure chamber) in the vicinity of the ejection port in the liquid flow passage (the pressure chamber) is in a range from about 10 to 100 ⁇ m.
  • the laminar flows can be deemed to be formed therein.
  • the liquid flow passage 13 and the pressure chamber 18 of this embodiment have rectangular cross-sections as shown in Figs. 4A to 4D , the heights and widths of the liquid flow passage 13 and the pressure chamber 18 in the liquid ejection head are sufficiently small.
  • the liquid flow passage 13 and the pressure chamber 18 can be treated like in the case of the circular tube, or more specifically, the heights of the liquid flow passage and the pressure chamber 18 can be treated as the diameter of the circular tube.
  • a distance from the silicon substrate 15 to an ejection port surface of the orifice plate 14 is defined as H [ ⁇ m] and a distance from the ejection port surface to a liquid-liquid interface between the first liquid 31 and the second liquid 32 (a phase thickness of the second liquid) is defined as h 2 [ ⁇ m].
  • a distance from the liquid-liquid interface to the silicon substrate 15 is defined as h 1 [ ⁇ m].
  • velocities of the liquids on wall surfaces of the liquid flow passage 13 and the pressure chamber 18 are assumed to be zero. Moreover, velocities and shear stresses of the first liquid 31 and the second liquid 32 at the liquid-liquid interface are assumed to have continuity.
  • ⁇ 1 represents the viscosity of the first liquid
  • ⁇ 2 represents the viscosity of the second liquid
  • Q 1 represents the flow rate (volume flow rate [um 3 /us]) of the first liquid
  • Q 2 represents the flow rate (volume flow rate [um 3 /us]) of the second liquid, respectively.
  • the first liquid and the second liquid flow so as to establish a positional relationship in accordance with the flow rates and the viscosities of the respective liquids within such ranges to satisfy the above-mentioned quartic equation (formula 2), thereby forming the parallel flows with the stable interface.
  • the parallel flows of the first liquid and the second liquid in the liquid flow passage 13 or at least in the pressure chamber 18.
  • the first liquid and the second liquid are only involved in mixture due to molecular diffusion on the liquid-liquid interface therebetween, and the liquids flow in parallel in the y direction virtually without causing any mixture.
  • the flows of the liquids do not always have to establish the state of laminar flows in a certain region in the pressure chamber 18.
  • at least the flows of the liquids in a region above the pressure generation element preferably establish the state of laminar flows.
  • the stable parallel flows are formed regardless of the immiscibility as long as the (formula 2) is satisfied. Meanwhile, even in the case of oil and water, if the interface is disturbed due to a state of slight turbulence of the flow in the pressure chamber, it is preferable that at least the first liquid flow mainly on the pressure generation element and the second liquid flow mainly in the ejection port.
  • the first liquid is not limited to water
  • the "phase thickness ratio of the first liquid” will be hereinafter referred to as a "water phase thickness ratio”.
  • the water phase thickness ratio h r becomes lower as the flow rate ratio Q r grows higher. Meanwhile, at each level of the flow rate ratio Q r , the water phase thickness ratio h r becomes lower as the viscosity ratio ⁇ r grows higher.
  • the water phase thickness ratio h r (the position of the interface between the first liquid and the second liquid) in the liquid flow passage 13 (the pressure chamber) can be adjusted to a prescribed value by controlling the viscosity ratio ⁇ r and the flow rate ratio Q r between the first liquid and the second liquid.
  • Fig. 5A teaches that the flow rate ratio Q r has a larger impact on the water phase thickness ratio h r than the viscosity ratio ⁇ r does.
  • condition A, condition B, and condition C shown in Fig. 5A represent the following conditions, respectively:
  • Fig. 5B is a graph showing flow velocity distribution in the height direction (the z direction) of the liquid flow passage 13 (the pressure chamber) regarding the above-mentioned conditions A, B, and C, respectively.
  • the horizontal axis indicates a normalized value Ux which is normalized by defining the maximum flow velocity value in the condition A as 1 (a criterion).
  • the vertical axis indicates the height from a bottom surface in the case where the height H of the liquid flow passage 13 (the pressure chamber) is defined as 1 (a criterion).
  • the position of the interface between the first liquid and the second liquid is indicated with a marker.
  • the position of the interface varies depending on the conditions such as the position of the interface in the condition A being located higher than the positions of the interface in the condition B and the condition C.
  • the variations are due to the fact that, in the case where the two types of liquids having different viscosities from each other flow in parallel in the tube while forming the laminar flows, respectively (and also forming the laminar flows as a whole), the interface between those two liquids is formed at a position where a difference in pressure attributed to the difference in viscosity between the liquid balances a Laplace pressure attributed to interfacial tension.
  • the water phase thickness ratio h r is equal to 1.
  • a point P in Fig. 6 shows this state.
  • the water phase thickness ratio h r namely, the water phase thickness h 1 of the first liquid becomes smaller while the water phase thickness h 2 of the second liquid becomes larger.
  • the state of the flow of the first liquid only transitions to the state of the first liquid and the second liquid flowing in parallel while defining the interface.
  • Fig. 7A shows a state before a voltage is applied to the pressure generation element 12.
  • Fig. 7B shows a state where application of the voltage to the pressure generation element 12 has just been started.
  • the pressure generation element 12 of this embodiment is an electrothermal converter (a heater).
  • the pressure generation element 12 rapidly generates heat upon receipt of a voltage pulse in response to the ejection signal, and causes film boiling of in the first liquid in contact.
  • Fig. 7B shows the state where a bubble 16 is generated by the film boiling.
  • the interface between the first liquid 31 and the second liquid 32 moves in the z direction (the height direction of the pressure chamber) whereby the second liquid 32 is pushed out of the ejection port 11 in the z direction.
  • Fig. 7C shows a state where the volume of the bubble 16 generated by the film boiling is increased whereby the second liquid 32 is further pushed out of the ejection port 11 in the z direction.
  • Fig. 7D shows a state where the bubble 16 communicates with the atmosphere.
  • a gas-liquid interface moving from the ejection port 11 toward the pressure generation element 12 communicates with the bubble 16 at a stage of shrinkage after the bubble 16 grows to the maximum.
  • Fig. 7E shows a state where a droplet 30 is ejected.
  • the liquid having projected out of the ejection port 11 at the timing of the communication of the bubble 16 with the atmosphere as shown in Fig. 7D breaks away from the liquid flow passage 13 due to its inertial force and flies in the z direction in the form of the droplet 30.
  • the liquid in the amount consumed by the ejection is supplied from two sides of the ejection port 11 by capillary force of the liquid flow passage 13 whereby the meniscus is formed again at the ejection port 11.
  • the parallel flows of the first liquid and the second liquid flowing in the y direction are formed again as shown in Fig. 7A .
  • the ejection operation as shown in Figs. 7A to 7E takes place in the state where the first liquid and the second liquid are flowing as the parallel flows.
  • the CPU 500 circulates the first liquid and the second liquid in the liquid ejection head 1 by using the liquid circulation unit 504 while keeping the constant flow rates of these liquids. Then the CPU 500 applies the voltage to the respective pressure generation elements 12 arranged in the liquid ejection head 1 in accordance with the ejection data while maintaining the above-mentioned control.
  • the flow rate of the first liquid and the flow rate of the second liquid may not always be constant.
  • This embodiment shows the configuration in which the bubble 16 communicates with the atmosphere in the pressure chamber 18.
  • the embodiment is not limited to this configuration.
  • the bubble 16 may communicate with the atmosphere on the outside (the atmosphere side) of the ejection port 11.
  • the bubble 16 may be allowed to disappear without communicating with the atmosphere.
  • the water phase thickness ratio h r is incremented by 0.10 whereas the water phase thickness ratio h r is incremented by 0.50 from the state in Fig. 8F to the state in Fig. 8G . Note that each of the ejected droplets in Figs.
  • 8A to 8G is illustrated based on a result obtained by conducting a simulation while setting the viscosity of the first liquid to 1 mPa.s, the viscosity of the second liquid to 8 mPa.s, and the ejection velocity of the droplet to 11 m/s.
  • Fig. 11 is a graph representing a relation between the flow-passage (pressure-chamber) height H and the water phase thickness ratio h r in the case of fixing a ratio R of the first liquid 31 contained in the ejected droplet 30, while setting the ratio R to 0%, 20%, and 40%.
  • the required water phase thickness ratio h r becomes higher as the flow-passage (pressure-chamber) height H is larger.
  • the ratio R of the first liquid 31 contained is a ratio of the liquid having flowed in the liquid flow passage 13 (the pressure chamber) to the ejected droplet as the first liquid 31.
  • the portion of water contained in the second liquid is not included in the aforementioned ratio as a matter of course.
  • the relation between the flow-passage (pressure-chamber) height H [ ⁇ m] and the water phase thickness ratio h r draws a locus as indicated with a solid line in Fig. 11 .
  • the water phase thickness ratio h r needs to be adjusted to 0.20 or below in the case where the flow-passage (pressure-chamber) height H [ ⁇ m] is equal to 20 ⁇ m. Meanwhile, the water phase thickness ratio h r needs to be adjusted to 0.36 or below in the case where the flow-passage (pressure-chamber) height H [ ⁇ m] is equal to 33 ⁇ m. Furthermore, the water phase thickness ratio h r needs to be adjusted to nearly zero (0.00) in the case where the flow-passage (pressure-chamber) height H [ ⁇ m] is equal to 10 ⁇ m.
  • the water phase thickness ratio h r is set too low, it is necessary to increase the viscosity ⁇ 2 and the flow rate Q 2 of the second liquid relative to those of the first liquid. Such increases bring about concerns of adverse effects associated with an increase in pressure loss.
  • the flow rate ratio Q r is equal to 5 in the case where the viscosity ratio ⁇ r is equal to 10.
  • the above-mentioned (formula 3), (formula 4), and (formula 5) define the numerical values applicable to the general liquid ejection head, namely, the liquid ejection head with the ejection velocity of the ejected droplets in a range from 10 m/s to 18 m/s.
  • these numerical values are based on the assumption that the pressure generation element and the ejection port are located at the positions opposed to each other and that the first liquid and the second liquid flow such that the pressure generation element, the first liquid, the second liquid, and the ejection port are arranged in this order in the pressure chamber.
  • a first pressure difference generation mechanism to set a pressure at the first outflow port 25 lower than a pressure at the first inflow port 20 has only to be prepared in order to adjust a flow rate Q 1 of the first liquid in the liquid flow passage 13 (the pressure chamber). In this way, it is possible to generate the flow of the first liquid 31 directed from the first inflow port 20 to the first outflow port 25 (in the y direction).
  • a second pressure difference generation mechanism to set a pressure at the second outflow port 26 lower than a pressure at the second inflow port 21 has only to be prepared. In this way, it is possible to generate the flow of the second liquid 32 directed from the second inflow port 21 to the second outflow port 26 (in the y direction).
  • P1 in is the pressure at the first inflow port
  • P1 out is the pressure at the first outflow port
  • P2 in is the pressure at the second inflow port
  • P2 out is the pressure as the second outflow port 26, respectively.
  • the bubbling medium (the first liquid) of this embodiment is required to cause the film boiling in the bubbling medium in the case where the electrothermal converter generates the heat and to rapidly increase the size of the generated bubble, or in other words, to have a high critical pressure that can efficiently convert thermal energy into bubbling energy.
  • Water is particularly suitable for such a medium. Water has the high boiling point (100°C) as well as the high surface tension (58.85 dynes/cm at 100°C) despite its small molecular weight of 18, and therefore has a high critical pressure of about 22 MPa. In other words, water brings about an extremely high boiling pressure at the time of the film boiling.
  • an ink prepared by causing water to contain a coloring material such as a dye or a pigment is suitably used in an inkjet printing apparatus designed to eject the ink by using the film boiling.
  • the bubbling medium is not limited to water.
  • Other materials can also function as the bubbling media as long as such a material has a critical pressure of 2 MPa or above (or preferably 5 MPa or above).
  • Examples of the bubbling media other than water include methyl alcohol and ethyl alcohol. It is also possible to use a mixture of water and any of these alcohols as the bubbling medium.
  • the ejection medium (the second liquid) of this embodiment is not required to satisfy physical properties for causing the film boiling unlike the bubbling medium. Meanwhile, adhesion of a scorched material onto the electrothermal converter (the heater) is prone to deteriorate bubbling efficiency because of damaging flatness of a heater surface or reducing thermal conductivity thereof.
  • the ejection medium does not come into direct contact with the heater, and therefore has a lower risk of scorch of its components.
  • conditions of the physical properties for causing the film boiling or avoiding the scorch are relaxed as compared to those of an ink for a conventional thermal head. Accordingly, the ejection medium of this embodiment enjoys more freedom of the components to be contained therein. As a consequence, the ejection medium can more actively contain the components that are suitable for purposes after being ejected.
  • the ejection medium it is possible to cause the ejection medium to actively contain a pigment that has not been used previously because the pigment was susceptible to scorching on the heater.
  • a liquid other than an aqueous ink having an extremely low critical pressure can also be used as the ejection medium in this embodiment.
  • various inks having special functions, which can hardly be handled by the conventional thermal head such as an ultraviolet curable ink, an electrically conductive ink, an electron-beam (EB) curable ink, a magnetic ink, and a solid ink, can also be used as the ejection media.
  • the liquid ejection head of this embodiment can also be used in various applications other than image formation by using any of blood, cells in culture, and the like as the ejection media.
  • the liquid ejection head is also adaptable to other applications including biochip fabrication, electronic circuit printing, and so forth.
  • the mode of using water or a liquid similar to water as the first liquid (the bubbling medium) and a pigment ink having a higher viscosity than that of water as the second liquid (the ejection medium), and ejecting only the second liquid is one of effective usages of this embodiment.
  • the second liquid may adopt the same liquid as one of those cited as the examples of the first liquid. For instance, even if both of the two liquids are inks each containing a large amount of water, it is still possible to use one of the inks as the first liquid and the other ink as the second liquid depending on situations such as a mode of usage.
  • the necessity of causing the two liquids to flow in the liquid flow passage (the pressure chamber) in such a way as to form the parallel flows may be determined based on the critical pressure of the liquid to be ejected.
  • the second liquid may be determined as the liquid to be ejected while the bubbling material serving as the first liquid may be prepared only in the case where the critical pressure of the liquid to be ejected is insufficient.
  • Figs. 12A and 12B are graphs representing relations between a water content rate and a bubbling pressure at the time of the film boiling in the case where diethylene glycol (DEG) is mixed with water.
  • the horizontal axis in Fig. 12A indicates a mass ratio (in percent by mass) of water relative to the liquid, and the horizontal axis in Fig. 12B indicates a molar ratio of water relative to the liquid.
  • the bubbling pressure at the time of the film boiling becomes lower as the water content rate (content percentage) is lower.
  • the bubbling pressure is reduced more as the water content rate becomes lower, and ejection efficiency is deteriorated as a consequence.
  • the molecular weight of water (18) is substantially smaller than the molecular weight of diethylene glycol (106). Accordingly, even if the mass ratio of water is around 40 wt%, its molar ratio is about 0.9 and the bubbling pressure ratio is kept at 0.9. On the other hand, if the mass ratio of water falls below 40 wt%, the bubbling pressure ratio sharply drops together with the molar concentration as apparent from Figs. 12A and 12B .
  • the necessity of forming the parallel flows in the flow passage can be determined based on the critical pressure of the liquid to be ejected (or on the bubbling pressure at the time of the film boiling).
  • the ultraviolet curable ink is of a 100-percent solid type.
  • Such ultraviolet curable inks can be categorized into an ink formed from a polymerization reaction component without a solvent, and an ink containing either water being of a solvent type or a solvent as a diluent.
  • the ultraviolet curable inks actively used in recent years are 100-percent solid ultraviolet curable inks formed from non-aqueous photopolymerization reaction components (which are either monomers or oligomers) without containing any solvents.
  • the typical ultraviolet curable ink contains monomers as a main component, and also contains small amounts of a photopolymerization initiator, a coloring material, and other additives including a dispersant, a surfactant, and the like.
  • the components of this ink include the monomers in a range from 80 to 90 wt%, the photopolymerization initiator in a range from 5 to 10 wt%, the coloring material in a range from 2 to 5 wt%, and other additives for the rest.
  • the first liquid is a clear ink and the second liquid is cyan ink (or magenta ink)
  • the first liquid is yellow ink and the second liquid is magenta
  • a range of color reproduction expressed on a print medium can be expanded more than the related art by appropriately adjusting the mixing ratio.
  • the configuration of this embodiment is also effective in the case of using two types of liquids that are desired to be mixed together immediately after the ejection instead of mixing the liquids immediately before the ejection.
  • image printing where it is desirable to deposit a high-density pigment ink with excellent chromogenic properties and a resin emulsion (resin EM) excellent in image robustness such as abrasion resistance on a print medium at the same time.
  • resin EM resin emulsion
  • a pigment component contained in the pigment ink and a solid component contained in the resin EM tend to develop agglomeration at a close interparticle distance, thus causing deterioration in dispersibility.
  • the high-density EM emulsion
  • the high-density pigment ink is used as the second liquid thereof and the parallel flows are formed by controlling the flow velocities of these liquids, then the two liquids are mixed with each other and agglomerated together on the printing medium after being ejected.
  • this embodiment exerts an effect of generating the flows of the two liquids in the pressure chamber regardless of the mode of the pressure generation element.
  • this embodiment also functions effectively in the case of a configuration to use a piezoelectric element as the pressure generation element, for instance, where the limitation in the critical pressure or the problem of the scorch is not concerned in the first place.
  • the stable interface can be formed at the time of ejecting the liquids. If the liquids are not flowing during the ejection operation of the liquids, the interface is prone to be disturbed as a consequence of generation of the bubble, and the printing quality may also be affected in this case.
  • driving the pressure generation element 12 while allowing the liquids to flow as described in this embodiment it is possible to suppress the turbulence of the interface due to the generation of the bubble. Since the stable interface is formed, the content rate of various liquids contained in the ejected liquid is stabilized and the printing quality is also improved, for example.
  • the liquids are caused to flow before driving the pressure generation element 12 and to flow continuously even during the ejection, it is possible to reduce time for forming the meniscus again in the liquid flow passage (the pressure chamber) after the ejection of the liquids.
  • the flows of the liquids are created by using a pump or the like loaded in the liquid circulation unit 504 before the driving signal is inputted to the pressure generation element 12. As a consequence, the liquids are flowing at least immediately before the ejection of the liquids.
  • the first liquid and the second liquids flowing in the pressure chamber are circulated between the pressure chamber and an outside unit. If the circulation is not conducted, a large amount of any of the first liquid and the second liquid having formed the parallel flows in the liquid flow passage and the pressure chamber but having not been ejected would remain inside. Accordingly, the circulation of the first liquid and the second liquid with the outside unit makes it possible to use the liquids that have not been ejected in order to form the parallel flows again.
  • the ejection method is not limited to the configuration in which the pressure generation element and the ejection port are located at the positions opposed to each other. It is also possible to adopt a so-called side-shooter mode in which the ejection port is located at a position at an angle equal to or below 90 degrees with respect to a direction of pressure generation by the pressure generation element.

Landscapes

  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)
  • Ink Jet (AREA)

Claims (9)

  1. Flüssigkeitsausstoßkopf (1) mit:
    einer Druckkammer (18), die so konfiguriert ist, dass sie im Inneren eine erste Flüssigkeit (31) und eine zweite Flüssigkeit (32) fließen lässt;
    einem Druckerzeugungselement (12), das so konfiguriert ist, dass es auf die erste Flüssigkeit (31) einen Druck aufbringt;
    einer Ausstoßöffnung (11), die so konfiguriert ist, dass sie die zweite Flüssigkeit (32) ausstößt;
    einer ersten Zuflussöffnung (20), durch die die erste Flüssigkeit (31) in die Druckkammer (18) fließt;
    einer zweiten Zuflussöffnung (21), durch die die zweite Flüssigkeit (32) in die Druckkammer (18) fließt;
    einer ersten Ausflussöffnung (25), durch die die erste Flüssigkeit (32) aus der Druckkammer (18) herausfließt; und
    einer zweiten Ausflussöffnung (26), durch die die zweite Flüssigkeit (32) aus der Druckkammer (18) herausfließt,
    wobei die zweite Zuflussöffnung (21), die erste Zuflussöffnung (20), die erste Ausflussöffnung (25) und die zweite Ausflussöffnung (26) ausgebildet sind, indem sie in der Druckkammer (18) in der Fließrichtung (y) der ersten Flüssigkeit (31) und der zweiten Flüssigkeit (32) in der Aufzählungsreihenfolge angeordnet sind, und
    die erste Flüssigkeit (31) und die zweite Flüssigkeit (32), die in der Druckkammer (18) fließen, miteinander in Kontakt stehen und zwischen der Druckkammer (18) und einer Außeneinheit zirkuliert werden,
    dadurch gekennzeichnet, dass
    der Flüssigkeitsausstoßkopf (1) so konfiguriert ist, dass er die zweite Flüssigkeit (32) aus der Ausstoßöffnung (11) ausstößt, indem er bewirkt, dass das Druckerzeugungselement (12) auf die erste Flüssigkeit (31) in einem Zustand einen Druck aufbringt, in dem die erste Flüssigkeit (31), eine Ausstoßrichtung (z) der zweiten Flüssigkeit (32) aus der Ausstoßöffnung (11) kreuzend, in der Fließrichtung (y) fließt, während sie sich mit dem Druckerzeugungselement (12) in Kontakt befindet, und in dem die zweite Flüssigkeit (32) in der Druckkammer (18) in der Fließrichtung (y) entlang der ersten Flüssigkeit (31) fließt.
  2. Der Flüssigkeitsausstoßkopf (1) nach Anspruch 1, wobei der Flüssigkeitsausstoßkopf (1) so konfiguriert ist, dass er die erste Flüssigkeit (31) und die zweite Flüssigkeit (32) dazu bringt, in der Druckkammer (18) laminare Strömungen auszubilden.
  3. Der Flüssigkeitsausstoßkopf (1) nach Anspruch 1 oder 2, wobei der Flüssigkeitsausstoßkopf (1) so konfiguriert ist, dass er die erste Flüssigkeit (31) und die zweite Flüssigkeit (32) dazu bringt, in der Druckkammer (18) parallele Strömungen auszubilden.
  4. Flüssigkeitsausstoßkopf (1) nach einem der Ansprüche 1 bis 3, wobei der Flüssigkeitsausstoßkopf (1) so konfiguriert ist, dass er die erste Flüssigkeit (31) und die zweite Flüssigkeit (32) dazu bringt, in der Druckkammer (18) Seite an Seite in der Ausstoßrichtung (z) der zweiten Flüssigkeit (32) zu fließen.
  5. Flüssigkeitsausstoßkopf (1) nach Anspruch 4, wobei der Flüssigkeitsausstoßkopf (1) einen Ausdruck erfüllt, der wie folgt definiert ist: h 1 / h 1 + h 2 0.1390 + 0.0155 H ,
    Figure imgb0008
    wobei H [µm] eine Höhe der Druckkammer (18) in der Ausstoßrichtung (z) der zweiten Flüssigkeit (32) ist und h1 [µm] eine Dicke der ersten Flüssigkeit (31) in der Druckkammer (18) in der Ausstoßrichtung (z) der zweiten Flüssigkeit (32) ist und h2 eine Dicke der zweiten Flüssigkeit (32) in der Druckkammer (18) in der Ausstoßrichtung (z) der zweiten Flüssigkeit (32) ist.
  6. Flüssigkeitsausstoßkopf (1) nach einem der Ansprüche 1 bis 5, wobei der Flüssigkeitsausstoßkopf (1) so konfiguriert ist, dass er eine Durchflussmenge der zweiten Flüssigkeit (32) dazu bringt, größer oder gleich einer Durchflussmenge der ersten Flüssigkeit (31) in der Druckkammer (18) zu sein.
  7. Flüssigkeitsausstoßkopf (1) nach einem der Ansprüche 1 bis 6, wobei der Flüssigkeitsausstoßkopf (1) so konfiguriert ist, dass er verhindert, dass die erste Flüssigkeit (31) in eine Flüssigkeit gelangt, die aus der Ausstoßöffnung (11) ausgestoßen werden soll.
  8. Flüssigkeitsausstoßkopf (1) nach einem der Ansprüche 1 bis 7, wobei der Flüssigkeitsausstoßkopf (1) die erste Flüssigkeit (31) umfasst und die erste Flüssigkeit (31) entweder Wasser oder eine wässrige Flüssigkeit mit einem kritischen Druck von größer oder gleich 2 MPa ist.
  9. Flüssigkeitsausstoßkopf (1) nach einem der Ansprüche 1 bis 8, wobei der Flüssigkeitsausstoßkopf (1) durch Anordnung mehrerer Flüssigkeitsausstoßmodule (100) ausgebildet ist.
EP19189000.3A 2018-07-31 2019-07-30 Flüssigkeitsausstosskopf, flüssigkeitsausstossmodul und flüssigkeitsausstossverfahren Active EP3603976B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018143884 2018-07-31
JP2019079641A JP7286394B2 (ja) 2018-07-31 2019-04-18 液体吐出ヘッド、液体吐出モジュール、液体吐出装置および液体吐出方法

Publications (2)

Publication Number Publication Date
EP3603976A1 EP3603976A1 (de) 2020-02-05
EP3603976B1 true EP3603976B1 (de) 2023-05-03

Family

ID=67544000

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19189000.3A Active EP3603976B1 (de) 2018-07-31 2019-07-30 Flüssigkeitsausstosskopf, flüssigkeitsausstossmodul und flüssigkeitsausstossverfahren

Country Status (3)

Country Link
EP (1) EP3603976B1 (de)
CN (1) CN110774761B (de)
PH (1) PH12019000273A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021178459A (ja) * 2020-05-13 2021-11-18 キヤノン株式会社 液体吐出ヘッド、液体吐出装置、液体吐出モジュールおよび液体吐出ヘッドの製造方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3095842B2 (ja) * 1991-12-26 2000-10-10 株式会社リコー インクジェット記録装置
JPH06305143A (ja) * 1993-04-23 1994-11-01 Canon Inc 液体吐出方法、液体吐出ユニットおよびインクジェット記録装置
TW365578B (en) * 1995-04-14 1999-08-01 Canon Kk Liquid ejecting head, liquid ejecting device and liquid ejecting method
JPH1024565A (ja) * 1996-07-11 1998-01-27 Canon Inc 可動部材を備えた液体吐出ヘッド用液体と液体吐出ヘッド、画像形成方法および該液体吐出ヘッドを用いたヘッドカートリッジと記録装置
JPH1024582A (ja) * 1996-07-12 1998-01-27 Canon Inc 液体吐出ヘッド並びに該液体吐出ヘッドの回復方法及び製造方法、並びに該液体吐出ヘッドを用いた液体吐出装置
JPH11105276A (ja) * 1997-09-30 1999-04-20 Minolta Co Ltd インクジェット記録装置
JPH11227210A (ja) * 1997-12-05 1999-08-24 Canon Inc 液体吐出ヘッド、該ヘッドの製造方法、ヘッドカートリッジおよび液体吐出装置
US6217157B1 (en) * 1998-06-22 2001-04-17 Canon Kabushiki Kaisha Liquid discharging head and liquid discharging apparatus
IL127484A (en) * 1998-12-09 2001-06-14 Aprion Digital Ltd Laser container printing method and method
KR20010045299A (ko) * 1999-11-04 2001-06-05 윤종용 잉크역류 방지용 네크부를 구비한 열압축방식의잉크분사장치
EP1177902A1 (de) * 2000-07-31 2002-02-06 Canon Kabushiki Kaisha Flüssigkeitsausstosskopf,Verfahren zur Herstellung eines Flüssigkeitsausstosskopfes, Kassette mit darauf montiertem Flüssigkeitsausstosskopf und Flüssigkeitsausstossvorrichtung
US7470308B2 (en) * 2004-02-10 2008-12-30 Fujifilm Corporation Method of producing magnetic particles and reaction method using microreactor and microreactor
JP2007112099A (ja) * 2005-10-24 2007-05-10 Riso Kagaku Corp インクジェット記録装置
GB0712861D0 (en) * 2007-07-03 2007-08-08 Eastman Kodak Co Continuous ink jet printing of encapsulated droplets
US20140022313A1 (en) * 2012-07-19 2014-01-23 Zhanjun Gao Liquid dispenser including asymmetric nozzle actuator configuration
EP3209419A4 (de) * 2014-10-22 2018-10-03 The Regents of The University of California Hochauflösender mikrotröpfchendrucker
IL269987B2 (en) * 2017-04-16 2024-02-01 Precise Bio Inc Method and system for laser induced forward transfer containing a microfluidic ink head with a regenerative interlayer

Also Published As

Publication number Publication date
EP3603976A1 (de) 2020-02-05
PH12019000273A1 (en) 2020-02-10
CN110774761B (zh) 2021-10-19
CN110774761A (zh) 2020-02-11

Similar Documents

Publication Publication Date Title
EP3603977B1 (de) Flüssigkeitsausstosskopf und flüssigkeitsausstossmodul
US11260658B2 (en) Liquid ejection head, liquid ejection apparatus, and liquid ejection module
US11007773B2 (en) Liquid ejection head, liquid ejection module, and liquid ejection apparatus
EP3603978B1 (de) Flüssigkeitsausstosskopf und flüssigkeitsausstossmodul
EP3603976B1 (de) Flüssigkeitsausstosskopf, flüssigkeitsausstossmodul und flüssigkeitsausstossverfahren
KR102526041B1 (ko) 액체 토출 헤드, 액체 토출 장치, 및 액체 토출 모듈
CN113665244A (zh) 液体排出头、排出设备、排出模块和液体排出头制造方法
CN113173006B (zh) 液体排出头
CN113173005B (zh) 液体排出头和液体排出模块
EP3771565B1 (de) Flüssigkeitsausstosskopf, flüssigkeitsausstossvorrichtung und flüssigkeitsausstossmodul

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20200805

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20201208

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20230207

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602019028279

Country of ref document: DE

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1564256

Country of ref document: AT

Kind code of ref document: T

Effective date: 20230515

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG9D

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20230503

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1564256

Country of ref document: AT

Kind code of ref document: T

Effective date: 20230503

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230904

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230803

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230903

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230804

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20230620

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602019028279

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20230731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230730

26N No opposition filed

Effective date: 20240206

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20230803

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20230503