EP3559544A1 - Structure en couches comportant des symboles pouvant être éclairés et son utilisation - Google Patents
Structure en couches comportant des symboles pouvant être éclairés et son utilisationInfo
- Publication number
- EP3559544A1 EP3559544A1 EP17822651.0A EP17822651A EP3559544A1 EP 3559544 A1 EP3559544 A1 EP 3559544A1 EP 17822651 A EP17822651 A EP 17822651A EP 3559544 A1 EP3559544 A1 EP 3559544A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- light
- symbol
- layer structure
- structure according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000010410 layer Substances 0.000 claims abstract description 170
- 239000011241 protective layer Substances 0.000 claims abstract description 24
- 239000004417 polycarbonate Substances 0.000 claims description 44
- 229920000515 polycarbonate Polymers 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- 229920000728 polyester Polymers 0.000 claims description 11
- 239000002086 nanomaterial Substances 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- 238000005034 decoration Methods 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 4
- 229920002492 poly(sulfone) Polymers 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 230000005540 biological transmission Effects 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 2
- 238000002372 labelling Methods 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 230000000644 propagated effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- -1 aromatic dicarboxylic acids Chemical class 0.000 description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 7
- 238000007650 screen-printing Methods 0.000 description 7
- 229930185605 Bisphenol Natural products 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000004926 polymethyl methacrylate Substances 0.000 description 6
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 4
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000006085 branching agent Substances 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 3
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000004973 liquid crystal related substance Substances 0.000 description 3
- 150000002763 monocarboxylic acids Chemical class 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- CJWNFAKWHDOUKL-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)phenol Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1 CJWNFAKWHDOUKL-UHFFFAOYSA-N 0.000 description 2
- ZEKCYPANSOJWDH-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-1H-indol-2-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3NC2=O)C=2C=C(C)C(O)=CC=2)=C1 ZEKCYPANSOJWDH-UHFFFAOYSA-N 0.000 description 2
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- AIXMJTYHQHQJLU-UHFFFAOYSA-N chembl210858 Chemical compound O1C(CC(=O)OC)CC(C=2C=CC(O)=CC=2)=N1 AIXMJTYHQHQJLU-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- WEDPGDLPFLPTFH-UHFFFAOYSA-N 1,2-dichlorobenzene;phenol Chemical compound OC1=CC=CC=C1.ClC1=CC=CC=C1Cl WEDPGDLPFLPTFH-UHFFFAOYSA-N 0.000 description 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- VPVTXVHUJHGOCM-UHFFFAOYSA-N 2,4-bis[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 VPVTXVHUJHGOCM-UHFFFAOYSA-N 0.000 description 1
- MAQOZOILPAMFSW-UHFFFAOYSA-N 2,6-bis[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=C(CC=3C(=CC=C(C)C=3)O)C=C(C)C=2)O)=C1 MAQOZOILPAMFSW-UHFFFAOYSA-N 0.000 description 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical class OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- VADKRMSMGWJZCF-UHFFFAOYSA-N 2-bromophenol Chemical compound OC1=CC=CC=C1Br VADKRMSMGWJZCF-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- RMGZZGUIMNISKP-UHFFFAOYSA-N 3-(2,3-dihydroxyphenoxy)benzene-1,2-diol Chemical compound OC1=CC=CC(OC=2C(=C(O)C=CC=2)O)=C1O RMGZZGUIMNISKP-UHFFFAOYSA-N 0.000 description 1
- ASURBSPIYIISGI-UHFFFAOYSA-N 4-(3,3,5-trimethylcyclohexyl)phenol Chemical compound C1C(C)(C)CC(C)CC1C1=CC=C(O)C=C1 ASURBSPIYIISGI-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- XJGTVJRTDRARGO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)(C)C1=CC=C(O)C=C1 XJGTVJRTDRARGO-UHFFFAOYSA-N 0.000 description 1
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 1
- JHSDIILQGDBNPD-UHFFFAOYSA-N 4-[2-[4-[tris[4-[2-(4-hydroxyphenyl)propan-2-yl]phenoxy]methoxy]phenyl]propan-2-yl]phenol Chemical compound C=1C=C(OC(OC=2C=CC(=CC=2)C(C)(C)C=2C=CC(O)=CC=2)(OC=2C=CC(=CC=2)C(C)(C)C=2C=CC(O)=CC=2)OC=2C=CC(=CC=2)C(C)(C)C=2C=CC(O)=CC=2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 JHSDIILQGDBNPD-UHFFFAOYSA-N 0.000 description 1
- CIEGINNQDIULCT-UHFFFAOYSA-N 4-[4,6-bis(4-hydroxyphenyl)-4,6-dimethylheptan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)CC(C)(C=1C=CC(O)=CC=1)CC(C)(C)C1=CC=C(O)C=C1 CIEGINNQDIULCT-UHFFFAOYSA-N 0.000 description 1
- IQNDEQHJTOJHAK-UHFFFAOYSA-N 4-[4-[2-[4,4-bis(4-hydroxyphenyl)cyclohexyl]propan-2-yl]-1-(4-hydroxyphenyl)cyclohexyl]phenol Chemical compound C1CC(C=2C=CC(O)=CC=2)(C=2C=CC(O)=CC=2)CCC1C(C)(C)C(CC1)CCC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 IQNDEQHJTOJHAK-UHFFFAOYSA-N 0.000 description 1
- BOCLKUCIZOXUEY-UHFFFAOYSA-N 4-[tris(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 BOCLKUCIZOXUEY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-Threitol Natural products OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 108010024636 Glutathione Proteins 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 1
- KPFFDTSEIOBLKX-UHFFFAOYSA-N OC1=CC=C(C=C1)C([PH2]=O)(C1=CC=C(C=C1)O)C1=CC=C(C=C1)O Chemical compound OC1=CC=C(C=C1)C([PH2]=O)(C1=CC=C(C=C1)O)C1=CC=C(C=C1)O KPFFDTSEIOBLKX-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 229920005379 Plexiglas® 8N Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- JVWLUVNSQYXYBE-UHFFFAOYSA-N Ribitol Natural products OCC(C)C(O)C(O)CO JVWLUVNSQYXYBE-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229960003180 glutathione Drugs 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000010147 laser engraving Methods 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical class CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007649 pad printing Methods 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical class C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0035—Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
- G02B6/004—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles
- G02B6/0043—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles provided on the surface of the light guide
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0058—Means for improving the coupling-out of light from the light guide varying in density, size, shape or depth along the light guide
- G02B6/006—Means for improving the coupling-out of light from the light guide varying in density, size, shape or depth along the light guide to produce indicia, symbols, texts or the like
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0081—Mechanical or electrical aspects of the light guide and light source in the lighting device peculiar to the adaptation to planar light guides, e.g. concerning packaging
- G02B6/0093—Means for protecting the light guide
Definitions
- the present invention relates to a layer construction for an illuminable belt comprising or consisting of the following layers in the order given:
- the invention further relates to an illuminable Dekoreiement with such a layer structure, as well as the use of the decorative element and the layer structure.
- a lightguide plate for a front-light type illumination unit in liquid crystal display systems comprising an alicyclic structure-containing polymer resin, and at least one of the main planar surfaces has a thin projection-and-recess shape with reflection function on.
- the object of the present invention is to provide a ceremoninclement for a bclcuchtbarcs decorative element that summarizes at least one symbol that can be made visible by illumination, and for a viewer only appears when it by at least one specially attached Lcuchtm ittcl is illuminated.
- the surface element should have a high flexibility, for example, to be able to be mounted on uneven substrates.
- the object is achieved by a layer structure for an illuminable and flexible operating element to assend or consisting of the following layers in the specified
- Sequence A) a light-conducting surface element in which light from a light source via at least one of its abutting edges can be coupled, wherein the light within the photoconductive surface element propagates laterally and is emitted at least in sections on its the symbol layer facing flat side;
- the symbol layer of the layer structure according to the invention has, at least in partial areas, a symbol in the form of an ornament, printing, painting or the like, referred to below as a symbol.
- the symbol in particular the imprint, may, for example, be a company emblem, a vehicle type or vehicle class designation, a functional status description such as "on” or "off", a text or a purely decorative pattern.
- the symbol can be displayed both positively and negatively, which means that the symbol is either self-illuminating when lit or its surroundings are lit while the symbol remains dark. If the symbol is a print, it is preferably applied by screen printing or other decorating methods, more preferably by screen printing. In a further preferred embodiment, the screen printing is transparent.
- the symbol of the symbol layer by a variety of decoration methods, such as IMD (In Mold Decoration), IML (In Mold Labeling), FIM (Film Insert Molding) or screen printing, generated.
- decoration methods such as IMD (In Mold Decoration), IML (In Mold Labeling), FIM (Film Insert Molding) or screen printing, generated.
- other printing methods such as e.g. the pad printing or a painting process can be used.
- the symbol layer can also be produced by a lamination process.
- the layer structure according to the invention comprises at least one light-conducting surface element into which light from a first light source Li via at least one of its abutting edges can be coupled.
- This surface element is, for example, an optical waveguide film made of polycarbonate or PMMA.
- the light propagates within the layer, whereby it is thrown back for the most part between the interfaces of the main surfaces by total reflection.
- the light-guiding surface element the light is emitted at least in sections on its flat side facing the symbol layer. That can for example be achieved in that the surface element has nanostructures in this area. Likewise, the nanostructures may be present on the opposite or on both flat sides.
- the nanostructures can be produced by punching, V-cutting, embossing or by laser engraving. Such films are sold, for example, by the company Nicrotek.
- the light-conducting surface element thus preferably has nanostructures on the basis of which the light is emitted at least in sections on the flat side of the light-conducting surface element facing the symbol layer. A high image sharpness and a clear image are achieved by the microstructures according to the invention and by the nanostructures according to the invention.
- the symbol layer can be applied to the light-conducting surface element, the transparent intermediate layer or a cover layer.
- the cover layer serves, for example, as a printing substrate for the symbol layer. In this case, too, the symbol layer can represent an independent layer, for example a symbol punched out of an impermeable foil. If the second symbol layer represents a self-contained layer, the cover layer may be omitted.
- the transparent intermediate layer, the light-conducting surface element and / or the cover layer in the range of 400 nm to 800 nm has a transmission of at least 75%, determined according to ISO 13468 at a thickness of 1 mm, preferably at least 85%. , and a haze of at most 10%, determined according to ASTM D l 003 at a layer thickness of 1 mm, preferably of at most 5%.
- the layer construction according to the invention as a rule, all the layers are fixedly arranged and connected to one another.
- the light-conducting surface element is not glued to the overlying surface, at least in the area from which the laterally coupled-in light is emitted so that the micro- and / or nanostructures on its surface are not deactivated.
- the photoconductive surface element, the transparent intermediate layer, the protective layer and / or the cover layer can be constructed from a thermoplastic, which preferably consists of polycarbonate, polyacrylate, polymethacrylate, cycloolefin copolymers, polysulfones, polyesters, polycarbonate / polyester blends, polycarbonate / Polycyclohexylmethanolcyclohexanedicarboxylate, or polycarbonate / PBT, more preferably polycarbonate.
- a thermoplastic which preferably consists of polycarbonate, polyacrylate, polymethacrylate, cycloolefin copolymers, polysulfones, polyesters, polycarbonate / polyester blends, polycarbonate / Polycyclohexylmethanolcyclohexanedicarboxylate, or polycarbonate / PBT, more preferably polycarbonate.
- the respective layers of the layer structure are all transparent or translucent thermoplastics suitable.
- polyacrylates polymethacrylates (PMMA, commercially available as Plexiglas TM from Röhm), cycloolefin copolymers (COC, commercially available as Topas TM from Ticona, or as Zenoex TM from Nippon Zeon or Arton TM from Japan Synthetic Rubber), copolyesters (commercially available as Tritan TM from Eastman Chemical or as Ecozen TM from SK Chemicals), polysulfones (commercially available as Ultrason TM from BASF or Udel TM from Solvay), polyester, such as Polyether terephthalate (PET) or polyethylene naphthalate (PEN), polycarbonate (PC), aliphatic polycarbonate (commercially available as Durabio TM from Mitsubishi Chemical Corp.), polycarbonate / polyester blends, e.g.
- PC / PET polycarbonate / polycyclohexylmethanolcyclohexanedicarboxylate (PCCD, commercially available as Xylex TM from Sabic IP).
- PCCD polycyclohexylmethanolcyclohexanedicarboxylate
- the layers independently of one another by polycarbonates or copolycarbonates based on diphenols, poly- or copolyacrylates, poly- or copolymers of copolymethacrylates, poly- or copolymers with styrene, thermoplastic polyurethanes, polyoefins, poly- or copolycondensates of terephthalic acid or naphthalenedicarboxylic acid or mixtures thereof, preferably polycarbonates or copolycarbonates based on diphenols, poly- or copolyacrylates, poly- or Copolymethacrylate, poly- or copolycondensates of terephthalic acid or naphthalenedicarboxylic acid or mixtures thereof. Particular preference is given to using polycarbonates.
- Suitable polycarbonates are all known polycarbonates, these may be homopolycarbonates, copolycarbonates and thermoplastic polyesters. These preferably have medium Molecular weights M w of from 18,000 to 40,000 g / mol, preferably from 22,000 to 36,000 g / mol and in particular from 24,000 to 33,000 g / mol, determined by measuring the relative solution viscosity in dichloromethane or in mixtures of equal amounts by weight of phenol o-dichlorobenzene calibrated by light scattering , For the preparation of polycarbonates, see, for example, "Schnell, Chemistry and Physics of Polycarbonates, Polymer Reviews, Vol. 9, Interscience Publishers, New York, London, Sydney 1964", and "DC PREVORSEK, B.
- Preferred starting compounds are bisphenols of the general formula HO-R-OH, where R is a divalent organic radical of from 6 to 30 carbon atoms containing one or more aromatic groups.
- Such compounds are bisphenols belonging to the group of dihydroxybiphenyls, bis (hydroxyphenylalkenes, indanebisphenols, bis-hydroxyphenyl ether, bis (hydroxyphenyl) sulfones, bis (hydroxyphenyl) ketones and oc, a'-bis (hydroxyphenyl) -diisopropylbenzoie.
- Particularly preferred bisphenols which belong to the abovementioned linking groups are bisphenol-A, tctraalkyl, bi-bis-I - A, (Bisphenol M),
- Carbonic acid compounds in particular phosgene, or reacted in the melt transesterification with diphenyl carbonate or dimethyl carbonate.
- Polyester carbonates are preferably obtained by reacting the abovementioned bisphenols, at least one aromatic dicarboxylic acid and optionally carbonic acid equivalents.
- aromatic dicarboxylic acids are phthalic acid, terephthalic acid, isophthalic acid, 3,3 'or 4,4'-diphenyldicarboxylic acid and benzophenone dicarboxylic acids.
- a portion, up to 80 mole%, preferably from 20 to 50 mole%, of the carbonate groups in the polycarbonates may be replaced by aromatic dicarboxylic acid ester groups.
- Inert organic solvents used in the interfacial process include, for example, dichloromethane, the various dichloroethanes and chloropropane compounds, tetrachloromethane, trichloromethane, chlorobenzene and chlorotoluene, preferably chlorobenzene or dichloromethane or mixtures of dichloromethane and chlorobenzene.
- phase interface reaction can be accelerated by catalysts such as tertiary amines, in particular N-alkylpiperidines or onium salts.
- catalysts such as tertiary amines, in particular N-alkylpiperidines or onium salts.
- tributylamine, triethylamine and N-ethylpiperidine are used.
- the catalysts c mentioned in DE 4 238 123 A1 are preferably used.
- the polycarbonate can be deliberately and controlled branched by the use of small amounts Verwe liger.
- Some suitable branching agents are: phloroglucinol, 4,6-dimethyl-2,4,6-tri- (4-hydroxyphenyl) -hepten-2; 4,6-dimethyl-2,4,6-tri- (4-hydroxyphenyl) heptane; 1, 3,5-tri- (4-hydroxyphenyl) benzoi; 1,1,1-tris (4-hydroxyphenyl) -ethane; Tri- (4-hydroxyphenyl) -phosphinylmethane; 2,2-bis [4,4-bis (4-hydroxyphenyl) -cyclohexyl] -propane; 2,4-bis (4-hydroxyphenyl isopropyl) phenol; 2,6-bis- (2-hydroxy-5'-methyl-benzyl) -4-methyl phenol; 2- (4- Hydroxyphenyl) -2- (2,4-dihydroxyphenyl) propane; Hexa- (4-
- phenols such as phenol, alkyiphenols such as cresol and 4-tert-butylphenol, chlorophenol, bromophenol, cumylphenol or mixtures thereof are preferably used in amounts of 1 to 20 mol%, preferably 2 to 10 mol% per mole of bisphenol. Preference is given to phenol, 4-tert-butylphenol or cumylphenol.
- Chain terminators and branching agents may be added separately or together with the bisphenol to the syntheses.
- polycarbonates of the multilayer product according to the invention are the homopolycarbonate based on bisphenol A, the homopolycarbonate based on l, l-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane and the copolycarbonates based on the two monomers bisphenol A. and 1, 1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane.
- the homopolycarbonate based on bisphenol A is particularly preferred.
- the polycarbonate may contain stabilizers.
- Suitable stabilizers are, for example, phosphines, phosphites or Si-containing stabilizers and further compounds described in EP 0 500 496 A1. Examples which may be mentioned are triphenyl phosphites, diphenylalkyl phosphites, phenyldiaicyl phosphites, tris (nonyiphenyl) phosphite, tetrakis (2,4-di-tert-butylphenyi) -4,4'- biphenylenediphosphonite and triarylphosphite. Particularly preferred are triphenylphosphine and tris (2,4-di-tert-butylphenyl) phosphite.
- the polycarbonate may contain from 0.01 to 0.5% by weight, based on the total weight of the polycarbonate, of esters or partial esters of monosubstituted to hexahydric alcohols, especially of glycene, pentaerythritol or guerbet alcohols.
- Monohydric alcohols are, for example, stearyl alcohol, paimityl alcohol and guerbeta alcohols.
- a dihydric alcohol is glycol.
- a trivalent alcohol is, for example, glycerine.
- Native alcohols are, for example, pentaerythritol and mesoerythritol.
- Five-chain alcohols are, for example, arabitol, ribitol and xy 1-it.
- Six-valent alcohols are, for example, mannitol and glutathione. (Sorbitol) and Dulcit.
- the esters are preferably the monoesters, diesters, triesters, tetraesters, pentaesters and hexaesters or mixtures thereof, in particular random mixtures of saturated, aliphatic C 10 to C 36 monocarboxylic acids and, if appropriate, hydroxy monocarboxylic acids, preferably with saturated, aliphatic C 14 to C32 monocarboxylic acids and optionally hydroxy monocarboxylic acids.
- the commercially available fatty acid esters in particular of pentaerythritol and of glycerol, may contain up to 60% by weight of different partial esters as a result of their manufacture.
- Saturated, aliphatic monocarboxylic acids of 10 to 36 carbon atoms are, for example, capric acid, lauric acid, myristic acid. Palm itinklare, stearic acid, hydroxystearic acid, Arachinklarc, behenic acid, lignoceric acid, cerotic acid and montan acids.
- Preferred saturated, aliphatic monocarboxylic acids having 14 to 22 carbon atoms are, for example, myristic acid, palmic acid, stearic acid, hydroxystearic acid, arachidic acid and behenic acid. Particularly preferred are saturated aliphatic monocarboxylic acids such as palmitic acid, stearic acid and hydroxystearic acid.
- the saturated, aliphatic C 20 to C 36 -carboxylic acids and the fatty acid esters are either known from the literature or can be prepared by methods known from the literature.
- pentaerythritol fatty acid esters are those of the particularly preferred monocarboxylic acids mentioned above.
- Particularly preferred are esters of pentaerythritol and glycerol with Stearic acid and palmitic acid.
- the structure according to the invention has a protective layer.
- a protective layer This is for example a scratch-resistant coated polycarbonate film, wherein the coating can be acrylate-based.
- the protective layer can also consist only of the coating which is applied to an underlying layer.
- the coating can be applied by methods such as painting, dip coating, direct coating or direct skinning with the appropriate coating.
- the transparent intermediate layer, the light-conducting surface element and / or the cover layer should have the highest possible transparency.
- this is understood to mean that the corresponding components in the range from 400 nm to 800 nm have a transmission of at least 85%, determined to ISO 13468 at a thickness of 4 mm, preferably at least 90%, and a haze of at most 5 %, determined according to ASTM D l 003 at a layer thickness of 4 mm, preferably of at most 4%.
- the transparent intermediate layer can preferably be produced by casting or back-injection.
- Foil is preferably used for the cover layer.
- the layers independently of one another have the following thicknesses:
- Interlayer of 100 to 1000 ⁇ m, preferably of 250 to 500 ⁇ m, has a conductive surface element of 0.075 to 1000 ⁇ m, preferably of 250 to 750 ⁇ m,
- Cover layer from 100 to 1,000 ⁇ m. preferably from 250 to 500 ⁇ m, as well
- Another object of the present invention relates to an illuminable decorative element to summarize a layer structure according to the invention and at least one light source, which is preferably designed as a light emitting diode, in particular as a laser diode, filament lamp or gas discharge lamp.
- the illuminable Dckorelement is preferably operable in at least two Bctriebs / urisen, wherein in a first operating / ustand a light source lights and in a second operating state, the Lichtquel le is not lit.
- a plurality of actuators for example a switch, can be displayed in an aesthetically pleasing manner in a simple manner, without requiring the use of liquid crystal units or the like for this purpose.
- Eg egg ne complicated electronics ebenfal ls is not erforderl for the operation of the inventive luminous decorative element due to its egg nfachen structure.
- the illuminable decorative element according to the invention has a high flexibility on it, which also makes it possible to realize non-planar structures, such as vaults.
- the invention further relates to a method for the produc- tion of a layer structure according to the invention, in which
- Another object of the invention betri fft the use of a layer structure according to the invention as a decorative element, especially in the automotive sector, for office supplies and electronic devices, especially computers and Mobilfunkclefonc.
- the invention relates to the use of a decorative element according to the invention as a component in an electrical switch.
- the invention relates to a layer structure (S) for a lightable control element comprising or ordering from the following layers in the stated sequence:
- the invention relates to a layer structure according to embodiment 1, characterized in that the second symbol layer (1) on the photoconductive surface element (3), the transparent intermediate layer (2) or a cover layer (5) is applied.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the transparent intermediate layer (2), the light-conducting surface element (3) and / or the covering layer (5) in the region from 400 nm to 800 nm, a transmittance of at least 85%, best imt ISO 13468 at a thickness of 4 mm, preferably, at least 90%, and a haze of at most 5%, determined according to ASTM D l 003 at a layer thickness of 4 mm, preferably of at most 4%, iron.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the all layers are fixedly arranged on one another and / or connected to one another.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the light-conducting surface element (3) nanostructures /, on the basis of which the light on the symbol layer (1) facing flat side of the photoconductivemonyneiements (3) at least partially emitted becomes.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the light-conducting surface element (3), the transparent intermediate layer (2), the protective layer (6) and / or the cover layer (8) consists of a Thermoplastics are preferably composed of polycarbonate, polyacrylate, Polymethacryiat, Cyclooiefin copolymers, polysulfones, polyesters, polycarbonate polyester blends, polycarbonate / polycyclohexylmethanolcyclohexandicarboxyiat, or polycarbonate / PBT, more preferably selected from polycarbonate.
- a Thermoplastics are preferably composed of polycarbonate, polyacrylate, Polymethacryiat, Cyclooiefin copolymers, polysulfones, polyesters, polycarbonate polyester blends, polycarbonate / polycyclohexylmethanolcyclohexandicarboxyiat, or polycarbonate / PBT, more
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the symbol of the symbol layer (1) by a printing process, in particular screen printing, laminating, painting, IMD (In Mold Decoration), IML (In Mold Labcling) or FIM (Fi im Insert Molding) can be generated.
- a printing process in particular screen printing, laminating, painting, IMD (In Mold Decoration), IML (In Mold Labcling) or FIM (Fi im Insert Molding) can be generated.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the transparent intermediate layer (2) can be produced by casting behind or injection molding.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the cover layer (8) is a film.
- the invention relates to a layer structure according to one of the preceding embodiments, characterized in that the layers independently of one another have the following thicknesses:
- Symboilic from 2 to 80 ⁇ ⁇ , preferably, from 1 2 to 50 ⁇ ,
- Interlayer (2) of 100 to 1000 ⁇ ⁇ . preferably from 250 to 500 ⁇ m,
- LIH conductive surface element (3) from 0.075 to 1000 ⁇ m. preferably from 250 to 750 ⁇ m.
- Cover layer (5) of 100 to 1,000 ⁇ m, preferably of 250 to 500 ⁇ m, as well as
- the invention relates to an illuminable decorative element comprising a layer structure (S) according to one of embodiments 1 to 10 and at least one light source (4), which are preferably designed as a light emitting diode, in particular as a laser diode, Glühfadcnlampc or gas discharge lamp, wherein the decorative element is preferably operable in at least two operating states, wherein in a first operating state, a light source (4) lights and in a second operating state, the light source (4) does not light.
- a layer structure (S) according to one of embodiments 1 to 10 and at least one light source (4), which are preferably designed as a light emitting diode, in particular as a laser diode, Glühfadcnlampc or gas discharge lamp, wherein the decorative element is preferably operable in at least two operating states, wherein in a first operating state, a light source (4) lights and in a second operating state, the light source (4) does not light.
- the invention relates to a method for producing a
- the invention relates to the use of a layer structure according to one of the embodiments 1 to 10 as a decorative element, in particular in Automotive sector, for office supplies and electronic devices, in particular computers and mobile phones.
- the invention relates to the use of a decorative element according to embodiment 1 1 as a component in an electrical switch.
- Fig. L an inventive illuminable decorative element in a lateral sectional view.
- Fig. 1 an inventive illuminable decorative element is shown in lateral sectional representation.
- the delta element comprises a layer structure S according to the invention and a light source 4.
- the layer structure S according to the invention orders from the following layers in the stated sequence:
- a light-conducting surface element 3 is coupled into the light from the light source 4 via one of its abutting edges, wherein the light propagates laterally within the light-emitting surface element 3 and is cut-out on its flat side facing away from the symbol layer 1, this region being indicated by arrows, indicating the light radiation;
- the transparent intermediate layer 2 is connected to the non-aligning surface element 3 only in the region in which the light is not emitted from the flat side of the light-emitting surface element 3.
- the nanostructures on the surface of the light-guiding surface element 3 are filled by the adhesive, as a result of which the light emission in this area is greatly reduced or possibly even completely lost.
- the light is coupled by means of the light source 4 of the light-conducting surface element 3 facing flat side of the first symbol layer 1.
- Light-sensitive surface element 3 Makrofol TM LM 907 from Covestro AG, Germany, with a surface embossing for light extraction, manufactured by the Fa. Nicrotek, PR China
- Light source 4 LED, light color white transparent cover layer 5: Makrofol TM SR 908 1 -4 250 ⁇ , PC / PMMA
- the polycarbonate layer is 205 ⁇ thick, the PMMA layer 45 ⁇ m thick.
- Protective Layer 6 PMMA based solvent containing lacquer system l-FHC 338,
- the illuminable decorative element is operable in several operating states.
- the light source 4 is operated in a ei most operating state. In this state is on the
- the Lichtquel le 4 is turned off, whereby the symbol of the first symbol layer 1 from the outside is not or only slightly visible.
- several operating states such as a switch, are displayed in an aesthetically pleasing manner, without requiring the use of liquid crystal units or the like.
- a complicated electronics is also not required for the operation of the illuminable decorative element according to the invention due to its simple structure.
- the flexibility of the layer structure according to the invention also allows the realization of non-planar structures as well as an attachment of the layer structure to non-planar substrates. As a result, for example, illuminated arched structures or switches can be realized, which are difficult or impossible to be realized by remplissigkristailan Attachesysteme.
- the production of the layer structure S is carried out as follows:
- the transparent cover layer 5 is coated with a protective layer 6 in the coating process.
- a Rolienbe Anlagenungs vide is used.
- the film with the coating represents an intermediate product, ie a finished semi-finished product, which is used in the further process.
- the composite of transparent cover layer 5 and protective layer 6 is then provided by means of screen printing with a transparent printing as a symbol layer 1.
- the symbol layer 1 is weak to barely visible in the off state of the LED as a homogeneous image.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16206167 | 2016-12-22 | ||
LU100064 | 2017-02-09 | ||
PCT/EP2017/083356 WO2018114828A1 (fr) | 2016-12-22 | 2017-12-18 | Structure en couches comportant des symboles pouvant être éclairés et son utilisation |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3559544A1 true EP3559544A1 (fr) | 2019-10-30 |
Family
ID=60888408
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17822651.0A Withdrawn EP3559544A1 (fr) | 2016-12-22 | 2017-12-18 | Structure en couches comportant des symboles pouvant être éclairés et son utilisation |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3559544A1 (fr) |
WO (1) | WO2018114828A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102021121853A1 (de) * | 2021-08-24 | 2023-03-02 | Lisa Dräxlmaier GmbH | Beleuchtungseinrichtung sowie verfahren zum herstellen einer beleuchtungseinrichtung |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW222292B (fr) | 1991-02-21 | 1994-04-11 | Ciba Geigy Ag | |
DE4238123C2 (de) | 1992-11-12 | 2000-03-09 | Bayer Ag | Verfahren zur Herstellung von thermoplastischen Polycarbonaten |
KR20030075153A (ko) | 2001-01-31 | 2003-09-22 | 제온 코포레이션 | 도광판 및 조명유닛 |
US7273308B2 (en) * | 2001-07-23 | 2007-09-25 | Ledi Lite Ltd. | Internal illumination based sign device |
ES2290379T3 (es) * | 2003-05-12 | 2008-02-16 | 3M Innovative Properties Company | Placa de matricula iluminada para vehiculos y vehiculo provisto con la misma. |
DE102009028937A1 (de) * | 2009-08-27 | 2011-03-03 | Evonik Röhm Gmbh | Schild für KFZ-Kennzeichen umfassend mindestens eine transluzente, retroreflektierende Schicht |
EP2535914B1 (fr) * | 2011-06-13 | 2017-09-06 | BlackBerry Limited | Ensemble formant éclairage de touches |
DE102014112470B4 (de) * | 2014-08-29 | 2018-06-21 | Lisa Dräxlmaier GmbH | Ausstattungsteil mit leuchtender sichtseite |
-
2017
- 2017-12-18 WO PCT/EP2017/083356 patent/WO2018114828A1/fr unknown
- 2017-12-18 EP EP17822651.0A patent/EP3559544A1/fr not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
WO2018114828A1 (fr) | 2018-06-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2197656B1 (fr) | Procédé de réalisation d'une pièce mince emboutie en matière thermoplastique | |
US6458913B1 (en) | Insert molded article | |
US11745671B2 (en) | Backlit vehicle interior panel with specialty materials | |
DE102012105412A1 (de) | Beleuchtbares Verkleidungsbauteil für ein Fahrzeug und Verfahren zu dessen Herstellung | |
KR101983403B1 (ko) | 부분 전기도금을 위한 전기도금될 수 있는 투명 플라스틱 필름 | |
EP3849771B1 (fr) | Surmoulage de feuille tempéré dynamique par injection | |
DE102005047615A1 (de) | Lichtstreuende Kunststoffzusammensetzung mit hoher Helligkeit und deren Verwendung in Flachbildschirmen | |
WO2018073087A1 (fr) | Structure en couches comportant des symboles pouvant être illuminés et son utilisation | |
US6893689B2 (en) | Heat-absorbent multi-layer structure | |
DE10159373A1 (de) | Mehrschichtiges Erzeugnis | |
WO2018114828A1 (fr) | Structure en couches comportant des symboles pouvant être éclairés et son utilisation | |
EP3097595B1 (fr) | Dispositif protegé contre le rayonnement uv pour oleds | |
WO2013107777A1 (fr) | Feuille plastique pour impression par transfert thermique par diffusion de colorants | |
EP4201664A1 (fr) | Couvercle d'affichage et de lumière à décor tridimensionnel | |
US10131123B2 (en) | Multi-layer film composite having a polycarbonate layer | |
EP4035145B1 (fr) | Surface de conception métallisée transparente | |
WO2000073386A1 (fr) | Matieres a mouler en polycarbonate servant a la realisation de produits attirant peu la poussiere | |
US20050013970A1 (en) | Multi-layer product in which the co-extruded side is easily recognizable | |
DE202020101945U1 (de) | LED-Beleuchtungselemente auf Basis von Mehrschichtkörpern mit Massivsteinoptik | |
WO2015110425A1 (fr) | Film protecteur anti-uv pour oled | |
EP4201671A1 (fr) | Couvercle de capteur éclairé avec décor tridimensionnel | |
US20240246482A1 (en) | Vehicle roof assembly comprising a patterned transparent panel and method of providing a pattern on a transparent element | |
EP4398228A1 (fr) | Structure optique comprenant une couche texturée à plusieurs microperforations | |
DE102021133402A1 (de) | Verkleidungskomponente und Kraftfahrzeug | |
EP3805841A1 (fr) | Dispositif d'affichage pourvu de disque de recouvrement en une seule pièce, en particulier pour l'habitacle des véhicules automobiles |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20190722 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20220316 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
18W | Application withdrawn |
Effective date: 20240201 |