EP3535431A1 - Produit en acier au manganèse moyen pour utilisation à basse température et son procédé de fabrication - Google Patents
Produit en acier au manganèse moyen pour utilisation à basse température et son procédé de fabricationInfo
- Publication number
- EP3535431A1 EP3535431A1 EP17798132.1A EP17798132A EP3535431A1 EP 3535431 A1 EP3535431 A1 EP 3535431A1 EP 17798132 A EP17798132 A EP 17798132A EP 3535431 A1 EP3535431 A1 EP 3535431A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel product
- steel
- weight
- optional
- rolling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims description 25
- 229910000617 Mangalloy Inorganic materials 0.000 title description 10
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 101
- 239000010959 steel Substances 0.000 claims abstract description 101
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 32
- 239000000956 alloy Substances 0.000 claims abstract description 32
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 230000000694 effects Effects 0.000 claims abstract description 19
- 229910052742 iron Inorganic materials 0.000 claims abstract description 16
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 16
- 229910052796 boron Inorganic materials 0.000 claims abstract description 13
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 13
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 12
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 12
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 11
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 11
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 229910052718 tin Inorganic materials 0.000 claims abstract description 9
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 7
- 229910001563 bainite Inorganic materials 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 4
- 238000005096 rolling process Methods 0.000 claims description 33
- 238000000137 annealing Methods 0.000 claims description 22
- 238000005266 casting Methods 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 11
- 238000005098 hot rolling Methods 0.000 claims description 9
- 239000000155 melt Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000005246 galvanizing Methods 0.000 claims description 8
- 238000005097 cold rolling Methods 0.000 claims description 6
- 238000009749 continuous casting Methods 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 4
- 238000005554 pickling Methods 0.000 claims description 4
- 238000009489 vacuum treatment Methods 0.000 claims description 4
- 238000010891 electric arc Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000000161 steel melt Substances 0.000 claims description 3
- 238000005496 tempering Methods 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims 1
- 238000003303 reheating Methods 0.000 claims 1
- 238000004513 sizing Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 27
- 239000011572 manganese Substances 0.000 description 21
- 239000010936 titanium Substances 0.000 description 17
- 239000011651 chromium Substances 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 239000011575 calcium Substances 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000005275 alloying Methods 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 229910052748 manganese Inorganic materials 0.000 description 9
- 239000010955 niobium Substances 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
- 150000001247 metal acetylides Chemical class 0.000 description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910039444 MoC Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000794 TRIP steel Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- -1 aluminum nitrides Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/10—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
- C21D8/105—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C1/00—Manufacture of metal sheets, metal wire, metal rods, metal tubes by drawing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
- C22C38/105—Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/30—Ferrous alloys, e.g. steel alloys containing chromium with cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
- B21C37/08—Making tubes with welded or soldered seams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
- B21C37/12—Making tubes or metal hoses with helically arranged seams
- B21C37/122—Making tubes or metal hoses with helically arranged seams with welded or soldered seams
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2201/00—Treatment for obtaining particular effects
- C21D2201/02—Superplasticity
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/10—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
Definitions
- the invention relates to a medium manganese steel product for use at low temperatures and a process for its preparation in the form of a
- the invention relates to the production of a steel product from a medium manganese steel with excellent low temperature toughness and / or high strength, for use in temperature ranges to at least minus
- steel products such as steel strips (hot or cold rolled), are considered as steel products
- the steel has a notched impact strength of 70 J at -196 ° C and consists of the elements (contents in% by weight and based on the
- Molten steel C: to 0.01 to 0.06; Mn: 2.0 to 8.0; Ni: 0.01 to 6.0; Mo: 0.02 to 0.6; Si: 0.03 to 0.5; AI: 0.003 to 0.05; N: 0.0015 to 0.01; P: up to 0.02; S: up to 0.01; as well as residual iron and unavoidable impurities.
- This steel should be distinguished by the fact that it is cheaper to produce than the steels previously used for this purpose up to 9% by weight of nickel.
- a method for producing a flat steel product from the above-described high-strength medium manganese steel comprises the following steps: - heating a steel slab to a temperature of 1000 ° C to 1250 ° C, - rolling the slab with a rolling temperature of 950 ° C or less with a reduction rate (Rolling degree) of 40% or less, - cooling the rolled steel to a temperature of 400 ° C or less at a cooling rate of 2 ° K / s or more, - and after cooling, tempering the steel for 0.5 to 4 hours at a temperature between 550 ° C and 650 ° C.
- the structure of the steel points as
- a door booster tube containing, in addition to iron, the following elements: C: 0.15 to 0.25%; Mn: 3.4 to 6.1%; P: max. 0.03%; S: max. 0.03%; Si: max. 0.6%; AI: 0.05%; Ni, Cr, Mo: 0 to 1%; V: 0 to 0.15%.
- a structural composition of the steel is not described.
- U.S. Patent No. 5,310,431 discloses a corrosion-resistant martensitic steel containing, in addition to iron and impurities, the following elements: C: 0.05 to 0.15%; Cr: 2 to 15%; Co: 0.1 to 10%; Ni: 0.1 to 4%, Mo: 0.1 to 2%; Ti: 0.1 to 0.75%; B: ⁇ 0.1%; N: ⁇ 0.02%.
- the described steel may also contain, for example, ⁇ 5% Mn.
- the publication US 2014/0230971 A1 discloses a high-strength steel sheet with excellent deformation properties and a method for its production.
- the steel sheet consists of the following elements (in weight%): C: 0.03 to 0.35; Si: 0.5 to 3; Mn: 3.5 to 10; P: ⁇ 0.1; S: ⁇ 0.01; N: ⁇ 0.08.
- a microstructure is given with more than 30% ferrite and more than 10% residual austenite.
- the publication WO 2006/01 1503 A1 also describes a steel sheet whose chemical composition in% by weight is given as follows: C: 0.0005 to 0.3; Si: ⁇ 2.5; Mn: 2.7 to 5; P: ⁇ 0.15; S: ⁇ 0.015; Mo: 0.15 to 1.5; B: 0.0006 to 0.01; AI: ⁇ 0.15 and balance iron and unavoidable impurities. Characteristic of such a steel strip is a high modulus of elasticity of greater than 230 Gpa in the rolling direction.
- European Patent Application EP 2 055 797 A1 relates to a ferromagnetic, iron-based alloy whose composition contains one or more of the following elements in% by weight: Al: 0.01 to 1: 1; Si: 0.01 to 7; Cr: 0.01 to 26 and balance iron and unavoidable impurities.
- the alloy can also contain 0.01 to 5 wt .-% Mn and other elements.
- TRIP steels which have a predominantly ferritic basic structure with embedded retained austenite, which during a forming too Can convert martensite (TRIP effect). Because of its high work hardening, the TRIP steel achieves high levels of uniform elongation and tensile strength. TRIP steels are used, among other things, in structural, chassis and crash-relevant components of vehicles as sheet metal blanks as well as welded blanks.
- WO 2005/061 152 A1 discloses hot strips made of TRIP / TWIP steels with manganese contents of 9 to 30% by weight, wherein the melt is poured over a horizontal strip casting plant to a preliminary strip of between 6 and 15 mm and subsequently is rolled to a hot strip.
- the present invention based on the object to provide a steel product from a manganese-containing steel, which is inexpensive to produce and an advantageous combination of strength and
- the equation 0.1 1 ⁇ C + Al ⁇ 3 is satisfied with optional addition of one or more of the following elements: Ti, V, Cr, Cu, Nb, B, Co, W, Zr, Ca and Sn,
- the alloy composition contains at least one or more of the elements B, V, Nb, Co, W or Zr in addition to Ni, with optional addition of one or more of the following elements: Ti, Cr, Cu, Ca and Sn,
- Martensite an excellent low-temperature toughness at temperatures below room temperature to at least -196 ° C and a good combination of strength, elongation and forming properties.
- Medium manganese steel product (medium manganese steel) on the basis of the alloying elements C, Mn, Al, Mo and Si cost-effective because of an increased addition of nickel of up to 9% by weight to achieve the
- Low temperature toughness can generally be dispensed with.
- Steel product according to the invention has a stable austenite at low temperatures to at least - 196 ° C, which converts at the earliest at a deformation at low temperatures, but otherwise present metastable to stable.
- the steel product according to the invention can be used as a substitute for high-Ni-containing steels in low-temperature applications, such as in the fields of shipbuilding, boiler construction / container construction, construction machinery, transport vehicles, crane construction, mining, mechanical and plant engineering, power plant industry, oilfield pipes, Petrochemicals, wind turbines, penstocks, precision tubes, tubes in general and for the substitution of high-alloy steels, in particular Cr, CrN, CrMnN, CrNi, CrMnNi steels.
- the optionally alloyed elements advantageously have the following contents in% by weight: Ti: 0.002 to 0.5; V: 0.006 to 0.1; Cr: 0.05 to 4; Cu: 0.05 to 2; Nb: 0.003 to 0.1; B: 0.0005 to 0.014; Co: 0.003 to 3; W: 0.03 to 2; Zr: 0.03 to 1; Ca: ⁇ 0.004 and Sn: ⁇ 0.5
- the steel product according to the invention in particular in the form of a seamless tube, has a multiphase structure consisting of 2 to 90% by volume, preferably up to 80% by volume or up to 70% by volume austenite, less than 40% by volume, preferably less than 20% by volume of ferrite and / or bainite and the remainder martensite or tempered martensite and optionally a TRIP and / or TWIP effect.
- Part of the martensite is present as tempered martensite and part of the austenite of up to 90% may be in the form of annealing or deformation twins.
- the steel may optionally comprise both a TRIP and TWIP an effect, wherein a portion of the austenite during subsequent deformation / ⁇ indentation /
- the steel product of the present invention is also characterized by increased resistance to delayed fracture and hydrogen embrittlement. This is achieved mainly by a precipitation of molybdenum carbide, which acts as a hydrogen trap.
- the steel has a high resistance to
- Liquid metal embrittlement (LME) during welding Liquid metal embrittlement (LME) during welding.
- the steel according to the invention is particularly suitable for the production of heavy plate or of hot and cold strip and welded and seamless tubes, which can be provided with metallic or non-metallic, organic or other inorganic coatings.
- the steel product at room temperature has a yield strength Rp0.2 of 450-1,150 MPa, a tensile strength Rm of 500-2,100 MPa and an elongation at break A50 of more than 6% to 45%, with higher tensile strengths tend to be associated with lower elongations at break and vice versa.
- a flat specimen with an initial measuring length A50 was used in accordance with DIN 50 125. Alloying elements are usually added to the steel in order to specifically influence certain properties. An alloying element in different steels can influence different properties. The effect and interaction generally depends substantially on the amount, the presence of other alloying elements and the dissolution state in the material.
- Carbon C is required for the formation of carbides, stabilizes the austenite and increases the strength. Higher contents of C deteriorate the welding properties and lead to the deterioration of the elongation and toughness properties, therefore, a maximum content of less than 0.3% by weight is set. In order to achieve a fine precipitation of carbides, a minimum addition of 0.01% by weight is required. For an optimal combination of mechanical
- the C content is advantageously set to 0.03 to 0.15% by weight.
- Mn stabilizes the austenite, increases strength and toughness, and optionally allows deformation-induced martensite and / or twin formation in the alloy of the present invention. Contents less than 4% by weight are not sufficient to stabilize the austenite and thus worsen the
- a range of 4 to ⁇ 8% by weight is preferred.
- Aluminum AI AI serves to deoxidize the melt.
- An AI content of 0.003 Weight% and more serves to deoxidize the melt. This results in a higher cost when casting.
- Al contents of more than 2.9% by weight deteriorate the elongation properties.
- higher Al contents significantly worsen the casting behavior in continuous casting. Therefore, a maximum content of 2.9% by weight and a minimum content of more than 0.003% by weight are set.
- the steel has an Al content of 0.03 to 0.4% by weight.
- a minimum content (in% by weight) of more than 0.1 1 and less than 3 should be maintained, whereby the strength of the austenite in particular increased by C, but the rejection of undesirable coarse carbides is suppressed by AI.
- a content of C + Al of 3% by weight or more deteriorates the
- Silicon Si Addition of Si at levels greater than 0.02% by weight inhibits carbon diffusion, reduces specific gravity, and increases strength and elongation and toughness properties. Furthermore, an improvement in cold rollability by alloying Si could be observed. Contents of more than 0.8% by weight lead to embrittlement of the material and negatively influence the hot and cold rollability as well as the coatability, for example by galvanizing. Therefore, a maximum content of 0.8% by weight and a minimum content of 0.02% by weight are set. Levels of 0.08 to 0.3% by weight have been found to be optimal.
- Mo acts as a carbide former, increasing strength and increasing resistance to hydrogen induced delayed cracking and cracking
- Phosphorus P is a trace element or trace element from iron ore and is dissolved in the iron lattice as a substitution atom. Phosphor boosts
- Solid solution solidifies the hardness and improves the hardenability.
- it is usually attempted to lower the phosphorus content as much as possible, since it is highly susceptible to segregation, among other things, by its low diffusion rate and greatly reduces the toughness.
- the addition of phosphorus to the grain boundaries can cause cracks along the grain boundaries during hot rolling.
- phosphorus increases the transition temperature from tough to brittle behavior by up to 300 ° C.
- Phosphorus content is limited to values less than 0.04% by weight.
- S S, like phosphorus, is bound as a trace element or accompanying element in iron ore or is introduced by coke during production via the blast furnace route. It is generally undesirable in steel, as it tends to segregate severely and has a strong embrittlement, which increases the elongation and elongation
- N is also a companion element of steelmaking. In the dissolved state, it improves the strength and toughness properties of steels containing more than or equal to 4% by weight of Mn. Low Mn-alloyed steels of less than 4% by weight tend to have a strong aging effect in the presence of free nitrogen. The nitrogen diffuses even at low
- the nitrogen in the form of nitrides is possible, for example, by alloying aluminum and / or titanium and Nb, V, B, aluminum nitrides in particular having a negative effect on the forming properties of the alloy according to the invention.
- the nitrogen content is less than 0.02% by weight. limited.
- Titanium Ti When added as an option, Ti acts as a fine grain carbide former, enhancing its strength, toughness, and elongation properties. Furthermore, Ti reduces intergranular corrosion. Contents of Ti exceeding 0.5% by weight deteriorates the elongation properties, therefore, a maximum content of Ti of 0.5% by weight is set. Optionally, a minimum content of 0.002 is set to advantageously precipitate nitrogen with Ti. Vanadium V: If added as an option, V acts as a carbide-forming agent that refines grain, thereby improving its strength, toughness, and elongation properties. Contents of V of more than 0.1% by weight give no further advantages, which is why a maximum content of 0.1% by weight is determined. Optionally, a minimum content of 0.006% by weight is set, which is necessary for a separation of very fine carbides.
- Chromium Cr With optional addition Cr increases the strength and reduces the
- Corrosion rate retards ferrite and pearlite formation and forms carbides.
- the maximum content is set at 4% by weight, as higher contents are one
- Efficacy Minimum Cr content is set at 0.05% by weight.
- Nickel Ni The optional addition of at least 0.005 wt.%, Preferably 0.01 wt.% Nickel stabilizes the austenite, especially at lower temperatures, and improves strength and
- the maximum content is set here for cost reasons to 3% by weight.
- a maximum content of Ni of 1% by weight has been found.
- a particularly inexpensive alloy system can be achieved if, in combination with manganese, the following condition is met: 6 ⁇ 1.5 Mn + Ni ⁇ 8.
- Copper Cu reduces the corrosion rate and increases the strength. Contents of more than 2% by weight deteriorate the manufacturability by forming low-melting phases during casting and hot rolling, which is why a maximum content of 2% by weight. In order to achieve a strength-increasing effect by Cu, a minimum of 0.05% by weight is set.
- Niob Nb acts as a carbide former to fine grain, thereby improving strength, toughness, and elongation properties. Contents of Nb of more than 0.1% by weight give no further advantages, which is why a maximum content of 0.1% by weight is determined. Optionally, a minimum content of 0.003% by weight is set, which is necessary for a precipitation of very fine carbides.
- Co increases the strength of the steel and stabilizes the austenite. Contents of more than 3% by weight deteriorate the elongation properties, which is why optionally a maximum content of 3% by weight is determined. Preferably, an optional minimum content of 0.003% by weight is provided, which in addition to the
- Tungsten W acts as a carbide former and increases strength. Contents of W of more than 2% by weight deteriorate the elongation properties, therefore, one
- Zirconium Zr acts as a carbide former and improves strength. Contents of Zr of more than 1% by weight deteriorate the elongation properties, therefore, a
- Ca is used to modify non-metallic oxide inclusions, which could otherwise result in undesirable alloy failure due to inclusions in the structure which act as stress concentration sites and weaken the metal composite. Furthermore, Ca improves the
- Sn Sn increases strength but, similar to copper, accumulates at higher temperatures below the scale and grain boundaries. It leads by penetration into the grain boundaries to the formation of low-melting phases and associated with cracks in the structure and solder brittleness, which is why an optional
- a steel product in the form of a flat steel product, such as hot strip, cold strip or plate, is delivered according to the invention by a method comprising the steps:
- Weight% Ti: 0.002 to 0.07; V: 0.006 to 0.1; Cr: 0.05 to 4; Ni: 0.01 to 3; Cu: 0.05 to 2; Nb: 0.003 to 0.1; B: 0.0005 to 0.014; Co: 0.003 to 3; W: 0.03 to 2; Zr: 0.03 to 1; Ca: less than 0.004; Sn: less than 0.5 on the process route
- Blast furnace steel plant or electric arc furnace steelworks each with optional vacuum treatment of the melt Pouring the molten steel into a preliminary strip by means of a horizontal or vertical continuous strip casting process, or casting the molten steel into a slab or thin slab by means of a horizontal or vertical slab or thin slab casting process,
- annealing the cold strip in an annealing plant with an annealing time of 0.3 to 24 h and temperatures of 500 ° C. to 840 ° C., preferably 520 ° C. to 600 ° C. with an annealing time of 0.5 to 6 h,
- the flat steel product having excellent low temperature toughness at temperatures below -196 ° C and a good combination of strength, elongation and forming properties.
- Endge sleepges not already on the hot or cold strip but optionally only after the tube made, wherein the annealing of the tube in an annealing at an annealing time of 0.3 to 24 h and temperatures of 500 ° C to 840 ° C, preferably 520 ° C to 600 ° C with an annealing time of 0.5 to 6 h.
- the tube may have a one- or two-sided organic or inorganic
- Typical thickness ranges for pre-strip are 1 mm to 35 mm and for slabs and thin slabs 35 mm to 450 mm. It is preferably provided that the slab or thin slab is hot rolled into a heavy plate having a thickness of about 3 mm to 200 mm or a hot strip having a thickness of 0.8 mm to 28 mm, or the preliminary near-cast cast slab into a hot strip having a thickness of 0.8 mm to 3 mm is hot rolled.
- the cold strip according to the invention has a thickness of at most 3 mm, preferably 0.1 mm to 1, 4 mm.
- the cold rolling of the hot strip may take place at room temperature or advantageously at elevated temperature before the first pass, in one or more rolling passes.
- Cold rolling at elevated temperature is advantageous to reduce rolling forces and promote the formation of twinned twins (TWIP effect).
- Advantageous temperatures of the rolling stock before the first pass are 60 ° C to 450 ° C.
- the steel strip can be dressed after cold rolling, thereby adjusting the surface texture (topography) needed for the final application.
- the casting can be done for example by means of the Pretex® method.
- the flat steel product thus produced receives a surface refinement, for example by electrolytic galvanizing or hot-dip galvanizing and instead of galvanizing or additively a coating on an organic or inorganic basis.
- the coating systems may, for example, organic coatings, plastic coatings or paints or other inorganic coatings such as iron oxide layers be.
- the flat steel product produced according to the invention can be used both as sheet metal,
- Sheet metal section or board used or further processed to a longitudinal or spiral seam welded pipe used or further processed to a longitudinal or spiral seam welded pipe.
- Ti 0.002 to 0.07
- V 0.006 to 0.1
- Cr 0.05 to 4
- Cu 0.05 to 2
- Nb 0.003 to 0.1
- B 0.0005 to 0.014
- Co 0.003 to
- the equation 0.1 1 ⁇ C + Al ⁇ 3 is satisfied, with optional addition of one or more of the following elements: Ti: 0.002 to 0.07; V: 0.006 to 0.1; Cr: 0.05 to 4; Cu: 0.05 to 2; Nb: 0.003 to 0.1; B: 0.0005 to 0.014; Co: 0.003 to 3; W: 0.03 to 2; Zr: 0.03 to 1; Ca: less than 0.004; Sn: less than 0.5,
- the alloy composition contains, besides Ni, at least one or more of the elements B, V, Nb, Co, W or Zr, with optional addition of one or more of the following elements: Ti: 0.002 to 0.07; Cr: 0.05 to 4; Cu: 0.05 to 2; Ca: less than 0.004; Sn: less than 0.5 via the process route blast furnace steelworks or electric arc furnace steelworks each with optional vacuum treatment of the melt;
- Hot rolling into a seamless tube for example in a plug mill, cross-rolling mill, release mill, die mill, rolling mill, continuous rolling mill, Pilger rolling mill or a bumper system with, for example, the following procedure: Production of a hollow block from a bloom, subsequent elongation
- Hydroforming optionally at a temperature from room temperature to below Ac3 temperature, preferably 60 ° C to 450 ° C.
- a solid block (round cast bar) is essentially understood to mean a continuous casting section produced by round continuous casting which already has a desired length.
- the elongation at break A50 of the X8Ni9 was converted according to DIN ISO 2566/1 from the breaking elongation A5,65 according to the standard to a sample cross section of 20 mm.
- the elongation characteristics stand for the elongation in the rolling direction.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016120895 | 2016-11-02 | ||
PCT/EP2017/077628 WO2018083035A1 (fr) | 2016-11-02 | 2017-10-27 | Produit en acier au manganèse moyen pour utilisation à basse température et son procédé de fabrication |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3535431A1 true EP3535431A1 (fr) | 2019-09-11 |
EP3535431B1 EP3535431B1 (fr) | 2021-06-09 |
Family
ID=60331577
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17798132.1A Active EP3535431B1 (fr) | 2016-11-02 | 2017-10-27 | Produit d'acier à teneur en manganèse intermédiaire pour application à basse température et son procédé de fabrication |
Country Status (10)
Country | Link |
---|---|
US (1) | US11352679B2 (fr) |
EP (1) | EP3535431B1 (fr) |
JP (1) | JP2020500262A (fr) |
KR (1) | KR20190082804A (fr) |
CN (1) | CN109923233A (fr) |
AU (1) | AU2017353259B2 (fr) |
CA (1) | CA3042120C (fr) |
DK (1) | DK3535431T3 (fr) |
RU (1) | RU2728054C1 (fr) |
WO (1) | WO2018083035A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4299768A1 (fr) * | 2022-06-29 | 2024-01-03 | Benteler Steel/Tube GmbH | Procédé de fabrication d'un tube en acier et tube en acier |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210062726A (ko) * | 2017-03-01 | 2021-05-31 | 에이케이 스틸 프로퍼티즈 인코포레이티드 | 극도로 높은 강도를 갖는 프레스 경화 강 |
CN110184543B (zh) * | 2019-07-04 | 2021-07-20 | 广西大学 | 一种低镍高强汽车钢板及其制造方法 |
CN110527908A (zh) * | 2019-09-06 | 2019-12-03 | 武汉科技大学 | 一种中碳微纳结构贝氏体钢及其热处理方法 |
WO2022018504A1 (fr) | 2020-07-24 | 2022-01-27 | Arcelormittal | Feuille d'acier laminée à chaud et traitée thermiquement et son procédé de fabrication |
CN111961982B (zh) * | 2020-09-15 | 2022-02-01 | 东北大学 | 高扩孔率高强度高延伸率的热轧中锰钢板及其制备方法 |
CN113502440A (zh) * | 2021-02-26 | 2021-10-15 | 上海交通大学 | 一种节镍型超低温用高强钢及其热处理工艺 |
US20220314377A1 (en) * | 2021-04-06 | 2022-10-06 | GM Global Technology Operations LLC | High-strength steel sheet blank having decarburized outer layers |
CN113549745B (zh) * | 2021-07-27 | 2022-09-13 | 内蒙古工业大学 | 一种低成本第三代汽车钢加工工艺 |
KR102699825B1 (ko) * | 2022-03-15 | 2024-08-27 | 한양대학교 에리카산학협력단 | 니켈(Ni)-알루미늄(Al)계 석출물을 포함하는 중망간강과 그 제조 방법 |
CN118422057A (zh) * | 2024-04-30 | 2024-08-02 | 武汉科技大学 | 一种具有良好冲击磨料磨损性能的中锰钢 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4257808A (en) * | 1979-08-13 | 1981-03-24 | The United States Of America As Represented By The United States Department Of Energy | Low Mn alloy steel for cryogenic service and method of preparation |
US5256219A (en) | 1990-10-24 | 1993-10-26 | Mannesmann Aktiengesellschaft | Steel reinforcement tube |
US5310431A (en) | 1992-10-07 | 1994-05-10 | Robert F. Buck | Creep resistant, precipitation-dispersion-strengthened, martensitic stainless steel and method thereof |
JP2001192773A (ja) | 2000-01-13 | 2001-07-17 | Sumitomo Metal Ind Ltd | ラインパイプ用鋼 |
JP2005002385A (ja) * | 2003-06-10 | 2005-01-06 | Sumitomo Metal Ind Ltd | 成形性と靱性に優れた鋼管とその製造方法 |
JP4079053B2 (ja) * | 2003-08-18 | 2008-04-23 | Jfeスチール株式会社 | エアバッグ用高強度高靭性継目無鋼管の製造方法 |
WO2005061152A1 (fr) | 2003-12-23 | 2005-07-07 | Salzgitter Flachstahl Gmbh | Procede pour produire des feuillards a chaud a partir d'un acier leger |
WO2006011503A1 (fr) | 2004-07-27 | 2006-02-02 | Nippon Steel Corporation | Plaque d'acier à module de young élevé, tôle d'acier galvanisé à chaud utilisant celle-ci, alliage de tôle d'acier galvanisé à chaud, tube d'acier à module de young élevé et procédé de fabrication de ceux-ci |
RU2269588C1 (ru) | 2004-10-25 | 2006-02-10 | Федеральное Государственное Унитарное Предприятие "Центральный Научно-Исследовательский Институт Конструкционных Материалов "Прометей" (Фгуп "Цнии Км "Прометей") | Хладостойкая сталь высокой прочности |
JP5215855B2 (ja) | 2006-08-23 | 2013-06-19 | 独立行政法人科学技術振興機構 | Fe基合金及びその製造方法 |
KR101330903B1 (ko) | 2008-11-05 | 2013-11-18 | 혼다 기켄 고교 가부시키가이샤 | 고강도 강판 및 그 제조 방법 |
RU2414520C1 (ru) | 2009-06-29 | 2011-03-20 | Открытое акционерное общество "Северсталь" (ОАО "Северсталь") | Сталь конструкционная с высокой ударной вязкостью при криогенных температурах |
JP5392717B2 (ja) * | 2009-09-18 | 2014-01-22 | 東洋鋼鈑株式会社 | 給油パイプ |
JP5287770B2 (ja) * | 2010-03-09 | 2013-09-11 | Jfeスチール株式会社 | 高強度鋼板およびその製造方法 |
EP2383353B1 (fr) * | 2010-04-30 | 2019-11-06 | ThyssenKrupp Steel Europe AG | Acier à résistance élevée comprenant du Mn, produit plat en acier composé d'un tel acier et son procédé de fabrication |
JP5540885B2 (ja) * | 2010-05-20 | 2014-07-02 | 新日鐵住金株式会社 | 溶融めっき熱延鋼板およびその製造方法 |
KR101271974B1 (ko) * | 2010-11-19 | 2013-06-07 | 주식회사 포스코 | 극저온 인성이 우수한 고강도 강재 및 그 제조방법 |
PL2692895T3 (pl) * | 2011-03-28 | 2018-07-31 | Nippon Steel & Sumitomo Metal Corporation | Blacha stalowa cienka walcowana na zimno i sposób jej wytwarzania |
JP5440672B2 (ja) | 2011-09-16 | 2014-03-12 | Jfeスチール株式会社 | 加工性に優れた高強度鋼板およびその製造方法 |
DE102012013113A1 (de) | 2012-06-22 | 2013-12-24 | Salzgitter Flachstahl Gmbh | Hochfester Mehrphasenstahl und Verfahren zur Herstellung eines Bandes aus diesem Stahl mit einer Mindestzugfestigkleit von 580MPa |
KR101510505B1 (ko) * | 2012-12-21 | 2015-04-08 | 주식회사 포스코 | 우수한 도금성과 초고강도를 갖는 고망간 용융아연도금강판의 제조방법 및 이에 의해 제조된 고망간 용융아연도금강판 |
CN103422017A (zh) | 2013-08-01 | 2013-12-04 | 天津钢管集团股份有限公司 | 输送温度低于-130℃环境用无缝钢管及其制造方法 |
CN104131225B (zh) * | 2014-07-30 | 2016-08-24 | 宝山钢铁股份有限公司 | 低成本超低温镍钢及其制造方法 |
MX2019001521A (es) * | 2016-08-22 | 2019-05-15 | Jfe Steel Corp | Pieza automotriz con soldadura por resistencia. |
-
2017
- 2017-10-27 RU RU2019116309A patent/RU2728054C1/ru active
- 2017-10-27 US US16/346,761 patent/US11352679B2/en active Active
- 2017-10-27 KR KR1020197014457A patent/KR20190082804A/ko not_active IP Right Cessation
- 2017-10-27 AU AU2017353259A patent/AU2017353259B2/en active Active
- 2017-10-27 DK DK17798132.1T patent/DK3535431T3/da active
- 2017-10-27 CA CA3042120A patent/CA3042120C/fr active Active
- 2017-10-27 CN CN201780067719.9A patent/CN109923233A/zh active Pending
- 2017-10-27 EP EP17798132.1A patent/EP3535431B1/fr active Active
- 2017-10-27 JP JP2019522842A patent/JP2020500262A/ja active Pending
- 2017-10-27 WO PCT/EP2017/077628 patent/WO2018083035A1/fr active Search and Examination
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4299768A1 (fr) * | 2022-06-29 | 2024-01-03 | Benteler Steel/Tube GmbH | Procédé de fabrication d'un tube en acier et tube en acier |
Also Published As
Publication number | Publication date |
---|---|
JP2020500262A (ja) | 2020-01-09 |
DK3535431T3 (da) | 2021-08-16 |
CN109923233A (zh) | 2019-06-21 |
US11352679B2 (en) | 2022-06-07 |
WO2018083035A1 (fr) | 2018-05-11 |
EP3535431B1 (fr) | 2021-06-09 |
AU2017353259A1 (en) | 2019-05-09 |
AU2017353259B2 (en) | 2022-12-22 |
KR20190082804A (ko) | 2019-07-10 |
RU2728054C1 (ru) | 2020-07-28 |
US20190264297A1 (en) | 2019-08-29 |
CA3042120C (fr) | 2022-08-09 |
CA3042120A1 (fr) | 2018-05-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3535431B1 (fr) | Produit d'acier à teneur en manganèse intermédiaire pour application à basse température et son procédé de fabrication | |
DE69617002T4 (de) | Verfahren zur herstellung von hochfesten nahtlosen stahlrohren mit hervorragender schwefel induzierter spannungsrisskorossionsbeständigkeit | |
EP2383353B1 (fr) | Acier à résistance élevée comprenant du Mn, produit plat en acier composé d'un tel acier et son procédé de fabrication | |
EP3504349B1 (fr) | Procédé de fabrication d'une bande d'acier à résistance très élevée présentant des propriétés améliorées lors du traitement ultérieur et une telle bande d'acier | |
EP3332047B1 (fr) | Procédé de fabrication d'un produit plat en acier laminé flexible et son utilisation | |
EP3332046B1 (fr) | Acier au manganèse à haute résistance contenant de l'aluminium, procédé de fabrication d'un produit plat en acier à partir de cet acier et produit plat en acier fabriqué d'après celui-ci | |
EP2905348B1 (fr) | Produit en acier plat de haute résistance avec une structure bainitique-martensitique et procédé de fabrication d'un tel produit acier plat | |
EP3512967B1 (fr) | Procédé pour la fabrication d'une pièce façonnée en un produit plat en acier contenant du manganèse et pièce correspondante | |
EP3512968B1 (fr) | Procédé pour fabriquer un produit plat en acier à partir d'un acier au manganèse et produit plat en acier résultant | |
WO2018083028A1 (fr) | Tube sans soudure en acier au manganèse moyen et procédé de fabrication | |
EP3927862A1 (fr) | Produit en acier constitué d'acier léger de construction contenant du manganèse, et son procédé de fabrication | |
WO2019115551A1 (fr) | Produit plat en acier laminé à chaud, à rigidité élevée, doté d'une résistance à la fissuration de bords élevée ainsi que d'une capacité de durcissement à la cuisson élevée, procédé de fabrication d'un tel produit plat en acier | |
WO2022184580A1 (fr) | Produit plat en acier laminé à froid et son procédé de production | |
WO2018050637A1 (fr) | Procédé de fabrication d'une bande laminée à chaud ou à froid et/ou d'un produit plat en acier laminé de manière flexible constitué par un acier contenant du manganèse, hautement solide et produit plat en acier ainsi obtenu | |
WO2018050634A1 (fr) | Procédé pour la fabrication d'une pièce façonnée à partir d'un produit plat en acier à teneur moyenne en manganèse et pièce correspondante | |
EP3469108B1 (fr) | Procédé de fabrication d'une bande d'acier laminée à froid présentant des propriétés trip à partir d'un acier à résistance élevée contenant du manganèse | |
DE102016115618A1 (de) | Verfahren zur Herstellung eines höchstfesten Stahlbandes mit verbesserten Eigenschaften bei der Weiterverarbeitung und ein derartiges Stahlband | |
WO2024046913A1 (fr) | Procédé de fabrication d'un produit plat en acier laminé à froid |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20190521 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20200511 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: B21C 37/08 20060101ALN20210205BHEP Ipc: C22C 38/16 20060101ALI20210205BHEP Ipc: C21D 1/26 20060101ALI20210205BHEP Ipc: C21D 8/10 20060101ALN20210205BHEP Ipc: C22C 38/04 20060101ALI20210205BHEP Ipc: C22C 38/22 20060101ALI20210205BHEP Ipc: C22C 38/06 20060101ALI20210205BHEP Ipc: C22C 38/08 20060101ALI20210205BHEP Ipc: C22C 38/30 20060101ALI20210205BHEP Ipc: C22C 38/14 20060101ALI20210205BHEP Ipc: B21C 37/12 20060101ALN20210205BHEP Ipc: C22C 38/02 20060101ALI20210205BHEP Ipc: C22C 38/18 20060101ALI20210205BHEP Ipc: C22C 38/20 20060101ALI20210205BHEP Ipc: C22C 38/00 20060101AFI20210205BHEP Ipc: C21D 8/02 20060101ALI20210205BHEP Ipc: C21D 6/00 20060101ALI20210205BHEP Ipc: C22C 38/10 20060101ALI20210205BHEP Ipc: C21D 9/46 20060101ALN20210205BHEP Ipc: C22C 38/12 20060101ALI20210205BHEP Ipc: C21D 9/08 20060101ALN20210205BHEP |
|
INTG | Intention to grant announced |
Effective date: 20210223 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1400557 Country of ref document: AT Kind code of ref document: T Effective date: 20210615 Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502017010631 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 Effective date: 20210813 |
|
REG | Reference to a national code |
Ref country code: FI Ref legal event code: FGE |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210909 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210910 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210909 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20211011 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502017010631 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20220310 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20211027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211027 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211027 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211027 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230513 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20171027 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20231019 Year of fee payment: 7 Ref country code: FR Payment date: 20231026 Year of fee payment: 7 Ref country code: FI Payment date: 20231020 Year of fee payment: 7 Ref country code: DK Payment date: 20231024 Year of fee payment: 7 Ref country code: DE Payment date: 20231020 Year of fee payment: 7 Ref country code: AT Payment date: 20231020 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20231019 Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210609 |