EP3445136B1 - Organisches elektrolumineszentes element und beleuchtungsvorrichtung damit - Google Patents

Organisches elektrolumineszentes element und beleuchtungsvorrichtung damit Download PDF

Info

Publication number
EP3445136B1
EP3445136B1 EP17782505.6A EP17782505A EP3445136B1 EP 3445136 B1 EP3445136 B1 EP 3445136B1 EP 17782505 A EP17782505 A EP 17782505A EP 3445136 B1 EP3445136 B1 EP 3445136B1
Authority
EP
European Patent Office
Prior art keywords
light emitting
light
emitting unit
charge generating
wavelength band
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP17782505.6A
Other languages
English (en)
French (fr)
Other versions
EP3445136A4 (de
EP3445136A1 (de
Inventor
Mitsuru Morimoto
Junichi Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xianyang Chvt New Display Technology Co Ltd
Original Assignee
Xianyang Chvt New Display Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xianyang Chvt New Display Technology Co Ltd filed Critical Xianyang Chvt New Display Technology Co Ltd
Publication of EP3445136A1 publication Critical patent/EP3445136A1/de
Publication of EP3445136A4 publication Critical patent/EP3445136A4/de
Application granted granted Critical
Publication of EP3445136B1 publication Critical patent/EP3445136B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/125—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light
    • H10K50/13—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light comprising stacked EL layers within one EL unit
    • H10K50/131—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light comprising stacked EL layers within one EL unit with spacer layers between the electroluminescent layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/19—Tandem OLEDs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/125—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light
    • H10K50/13—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light comprising stacked EL layers within one EL unit
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • H10K50/15—Hole transporting layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • H10K50/16—Electron transporting layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/17—Carrier injection layers
    • H10K50/171—Electron injection layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/805—Electrodes
    • H10K50/81—Anodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/805—Electrodes
    • H10K50/82—Cathodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30—Devices specially adapted for multicolour light emission
    • H10K59/32—Stacked devices having two or more layers, each emitting at different wavelengths
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30—Devices specially adapted for multicolour light emission
    • H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00—Properties of the organic materials covered by group H10K85/00
    • H10K2101/10—Triplet emission

Definitions

  • the present invention relates to an organic electroluminescent (EL) element and a lighting device.
  • EL organic electroluminescent
  • An organic EL element is a self-luminous element including a light emitting layer made of an organic compound between a cathode and an anode facing each other.
  • a light emitting layer made of an organic compound between a cathode and an anode facing each other.
  • Tang et al. of Eastman Kodak Company made a structure in which: organic compounds varying in carrier transport properties were stacked one on top of another to inject electrons and holes from the cathode and the anode in a balanced manner; and the layer thickness of the organic layer provided between the cathode and the anode was set to be 200 nm or less, and thereby succeeded in achieving high luminance and high efficiency of 1000 cd/m 2 and an external quantum efficiency of 1% at an application voltage of 10 V or less, which is sufficient for practical use (see, for example, Non-patent Document 1) .
  • the organic EL element has been developed based on the aforementioned element structure proposed by Tang et al. Moreover, as an element structure of the organic EL element, there is developed an organic EL element with a multiphoton emission (MPE) structure in which a light emitting unit including at least one light emitting layer is included as a unit and an electrically-insulating charge generating layer (CGL) is disposed between multiple light emitting units (see, for example, Patent Document 1).
  • MPE multiphoton emission
  • CGL electrically-insulating charge generating layer
  • the organic EL element having a tandem structure as described above is attracting attention as a technique which can achieve long life, high luminance, and uniform light emission in a large area unachievable in the organic EL element structure of Tang et al.
  • the aforementioned organic EL element has such characteristics that high speed switching of light emission is possible and its simple element structure allows a smaller thickness .
  • the organic EL element is applied to display devices of, for example, cellular phones and vehicle devices by utilizing such excellent characteristics.
  • the organic EL element has been attracting attention as a lighting device such as, for example, a back light of a liquid crystal display and a general lighting unit by utilizing the characteristics such as surface emission and a thin structure.
  • Methods of causing the organic EL element to provide white light include a method of providing white color by mixing colors of light beams emitted from materials which emit light beams of two complementary colors such as, for example, blue light emitting layer and a yellow light emitting layer, a method of providing a white color by mixing colors of light beams emitted by three light emitting layers of red, blue, and green, and the like.
  • the method of mixing colors of light beams emitted by three light emitting layers of red, blue, and green is suitable for providing white light with the excellent color rendering property (see, for example, Patent Documents 2 and 3) .
  • the conventional organic EL element an emission spectrum of white light provided by light emission of the three light emitting layers of red, blue, and green is not necessarily sufficiently controlled from the viewpoint of achieving the high color temperature and the excellent color rendering property.
  • the conventional organic EL element does not necessarily have a sufficient performance as a light source of a lighting device.
  • Non-Patent Document 1 Appl. Phys. Lett., 51, 913 (1987 ).
  • EP2330651 A2 describes a white organic light emitting element comprising a first blue emitting unit, a second blue emitting unit and a third orange emitting unit comprising a red and a green electroluminescent layers, wherein the units are separated from each other by a charge generation layer.
  • US2014/0084269 A1 describes a white organic light emitting element comprising two fluorescent blue emitting units and one phosphorescent emitting unit comprising a red and a green electroluminescent layers.
  • EP2869355 A1 describes an OLED device emitting white light with excellent color rendering.
  • the OLED device comprises two emitting units separated by a charge generation layer.
  • the present invention is proposed in view of the existing situations described above and an object thereof is to provide an organic electroluminescent element which can provide white light with a high color temperature and an excellent color rendering property and which can also achieve high luminance light emission and long life drive, thereby being preferably used particularly as a light source of a lighting device, and a lighting device including this organic electroluminescent element.
  • the present invention provides an organic electroluminescent element as recited in claim 1.
  • a lighting device according to the claimed invention is defined in claim 10. Further details are given in the dependent claims.
  • the present invention can provide an organic electroluminescent element which can provide white light with a high color temperature and an excellent color rendering property and a lighting device including this organic electroluminescent element.
  • Fig. 1 is a schematic cross-sectional view illustrating one embodiment of an element structure of an organic EL element in the present invention.
  • the organic EL element 10 of the embodiment has a structure in which multiple light emitting units 21, 22, 23 each including a light emitting layer made of at least an organic compound are stacked one on top of another between a cathode 11 and an anode 12 and charge generating layers (CGL) 31, 32 are each sandwiched between a corresponding pair of the adjacent light emitting units, and is an organic EL element capable of providing white light by causing the multiple light emitting units 21, 22, 23 to emit light.
  • CGL charge generating layers
  • the organic EL element 10 of the embodiment includes a first light emitting unit 21, a second light emitting unit 22, and a third light emitting unit 23.
  • the first light emitting unit 21 includes a light emitting layer formed of a red phosphorescent light emitting layer which emits red light with one peak wavelength in a red wavelength band and a green phosphorescent light emitting layer which emits green light with one peak wavelength in a green wavelength band.
  • the second light emitting unit 22 includes a light emitting layer formed of a blue fluorescent light emitting layer which emits blue light with one or two peak wavelengths in a blue wavelength band.
  • the third light emitting unit 23 includes a light emitting layer formed of a blue fluorescent light emitting layer which emits blue light with one or two peak wavelengths in the blue wavelength band.
  • the first light emitting unit 21 and the second light emitting unit 22 are stacked one on top of the other with a first charge generating layer 31 sandwiched therebetween.
  • the second light emitting unit 22 and the third light emitting unit 23 are stacked one on top of the other with a second charge generating layer 32 sandwiched therebetween.
  • the organic EL element 10 of the embodiment has a structure in which the anode 12, the third light emitting unit 23, the second charge generating layer 32, the second light emitting unit 22, the first charge generating layer 31, the first light emitting unit 21, and the cathode 11 are stacked one on top of another in this order.
  • the organic EL element 10 of the embodiment has a structure in which the first light emitting unit 21, the second light emitting unit 22, and the third light emitting unit 23 are stacked one on top of another with each of the first charge generating layer 31 and the second charge generating layer 32 sandwiched between the corresponding pair of adjacent light emitting units (MPE structure).
  • the white light provided by light emission of the first light emitting unit 21, the second light emitting unit 22, and the third light emitting unit 23 has an emission spectrum continuous over a wavelength band of at least 380 nm to 780 nm.
  • this emission spectrum has one peak wavelength in the red wavelength band of 590 nm to 640 nm, one peak wavelength in the green wavelength band of 500 nm to 550 nm, one or two peak wavelengths in the blue wavelength band of 440 nm to 490 nm.
  • a metal with a small work function, an alloy of this metal, a metal oxide, or the like may be generally used as the cathode 11.
  • a metal forming the cathode 11 a metal single substance such as an alkaline metal such as Li, an alkaline earth metal such as Mg or Ca, a rare-earth metal such as Eu, or an alloy containing any of these metals and Al, Ag, In, or the like is used.
  • the cathode 11 may have a configuration in which an organic layer doped with a metal is used in an interface between the cathode 11 and an organic layer as disclosed in, for example, " Japanese Patent Application Publication No. Hei 10-270171 " and " Japanese Patent Application Publication No. 2001-102175 .”
  • an electrically conductive material is used as the material of the cathode 11 and the properties of the material such as the work function are not limited to particular properties.
  • the cathode 11 may have a configuration in which an organic layer in contact with the cathode 11 is made of an organic metal complex compound containing at least one type selected from the group consisting of alkali metal ions, alkaline earth metal ions, and rare-earth metal ions as disclosed in, for example, " Japanese Patent Application Publication No. Hei 11-233262 " and " Japanese Patent Application Publication No. 2000-182774 .”
  • a metal which is capable of reducing the metal ions contained in the organic metal complex compound to metal in vacuum for example, a metal (with a thermal reduction property) such as Al, Zr, Ti, and Si or an alloy containing any of these metals can be used as the cathode 11.
  • Al which is generally widely used as a wiring electrode may be used from the viewpoint of ease of vapor deposition, high light reflectance, chemical stability, and the like.
  • the material of the anode 12 is not limited to a particular material.
  • a transparent, electrically conductive material such as, for example, ITO (Indium Tin Oxide) or IZO (Indium Zinc Oxide) is used.
  • the aforementioned transparent electrically conductive material such as ITO or IZO can be used as the cathode 11 by using the aforementioned organic layer doped with a metal which is disclosed in " Japanese Patent Application No. Hei 10-270171 " as an electron injection layer.
  • a transparent organic EL element 10 by forming both of the cathode 11 and the anode 12 to be transparent (because the first light emitting unit 21, the second light emitting unit 22, the third light emitting unit 23, the first charge generating layer 31, and the second charge generating layer 32 are similarly transparent) .
  • the light can be extracted from the cathode 11 side by forming the anode 12 with the metal material and forming the cathode 11 with the transparent, electrically conductive material, which is the opposite of a general organic EL element.
  • the order of film formation does not have to start from the anode 12 side and may start from the cathode 11 side.
  • the first light emitting unit 21, the second light emitting unit 22, and the third light emitting unit 23 may employ various structures as in the conventionally well-known organic EL element 10 and may each have any layered structure as long as it includes the light emitting layer made of at least an organic compound.
  • the arrangement may be such that an electron transport layer, an electron injection layer, and the like are arranged on the cathode 11 side of each light emitting layer and a hole transport layer, a hole injection layer, and the like are arranged on the anode 12 side of the light emitting layer.
  • the electron transport layers are made of, for example, a conventionally well-known electron transport material.
  • an electron transport material with a relatively deep HOMO (Highest Occupied Molecular Orbital) level may be used out of electron transport materials generally used for organic EL elements.
  • an electron transport material with a HOMO level of at least about 6.0 eV may be used.
  • Each of the electron injection layers is provided between the cathode 11 and the electron transport layer or between at least one of the first charge generating layer 31 and the second charge generating layer 32 and the electron transport layer located on the anode 12 side to improve injection efficiency of electrons from the cathode 11 or at least one of the first charge generating layer 31 and the second charge generating layer 32.
  • An electron transport material having properties similar to the electron transport layers is generally used as the material of the electron injection layers.
  • the electron transport layers and the electron injection layers are sometimes collectively referred to as electron transport layers.
  • the hole transport layers are made of, for example, a conventionally well-known hole transport material.
  • the hole transport material is not limited to a particular material.
  • an organic compound (electron donating material) which has an ionization potential less than 5.7 eV and which has a hole transport property, that is an electron donating property may be used as the hole transport material.
  • Each of the hole injection layers is provided between the anode 12 and the hole transport layer or between at least one of the first charge generating layer 31 and the second charge generating layer 32 and the hole transport layer located on the cathode 11 side to improve injection efficiency of holes from the anode 12 or at least one of the first charge generating layer 31 and the second charge generating layer 32.
  • An electron donating material having properties similar to the hole transport layers is generally used as the material of the hole injection layers.
  • the hole transport layers and the hole injection layers are sometimes collectively referred to as hole transport layers.
  • the red phosphorescent light emitting layer and the green phosphorescent light emitting layer included in the first light emitting unit 31 generally each contain a host material which is a main component and a guest material which is a minor component as the organic compound. Emission of the red light and the green light is attributable particularly to the properties of the guest materials.
  • a material with an electron transport property, a material with a hole transport property, a material obtained by mixing these materials, or the like is used as the host material of each of the red phosphorescent light emitting layer and the green phosphorescent light emitting layer.
  • a material with an electron transport property, a material with a hole transport property, a material obtained by mixing these materials, or the like is used as the host material of each of the red phosphorescent light emitting layer and the green phosphorescent light emitting layer.
  • CBP 4,4'-biscarbazolylbiphenyl
  • BCP 2,9-dimethyl-4,7-diphenyl-9,10-phenanthroline
  • the guest material is also referred to as dopant material.
  • the guest material utilizing phosphorescent light emission is generally referred to as phosphorescent light emitting material.
  • a light emitting layer made of the phosphorescent light emitting material is referred to as phosphorescent light emitting layer.
  • the phosphorescent light emitting layer it is possible to utilize not only 75% of triplet excitons, which are generated by recombination of electrons and holes, but also 25% of the triplet excitons, which are generated by energy transfer from singlet excitons. Accordingly, an internal quantum efficiency of 100% can be achieved in theory. Specifically, the excitons generated by the recombination of electrons and holes are converted to light in the light emitting layer without thermal quenching or the like. In an organic metal complex including heavy atoms such as iridium or platinum, an internal quantum efficiency close to 100% is actually achieved by optimization of the element structure and the like.
  • the guest material of each phosphorescent light emitting layer is not limited to a particular material.
  • a red phosphorescent light emitting material such as Ir(piq) 3 , Ir(btpy) 3 , Ir(btp) 2 acac, or Ir (2-phq) 2 acac is used as the guest material of the red phosphorescent light emitting layer.
  • a green phosphorescent light emitting material such as Ir(ppy) 3 is used as the guest material of the green phosphorescent light emitting layer.
  • the blue fluorescent light emitting layer included in each of the second light emitting unit 22 and the third light emitting unit 23 generally contains a host material which is a main component and a guest material which is a minor component as the organic compound. Emission of the blue light is attributable particularly to the properties of the guest material.
  • blue fluorescent light emitting materials described in paragraphs [0052] to [0061] of "International Patent Application Publication No. WO2012/053216" is used as the host material and the guest material of the blue fluorescent light emitting layer.
  • a styrylamine compound, a fluoranthene compound, an aminopyrene compound, a boron complex, or the like can be used as the guest material of the blue fluorescent light emitting layer.
  • a material such as 4,4'-bis[4-(diphenylamino)styryl]biphenyl (BDAVBi) or 2,7-bis(2-[phenyl(m-tolyl)amino]-9,9-dimethyl-fluoren-7-yl ⁇ -9,9-dimethyl-fluorene (MDP3FL) can be used.
  • BDAVBi 4,4'-bis[4-(diphenylamino)styryl]biphenyl
  • MDP3FL 2,7-bis(2-[phenyl(m-tolyl)amino]-9,9-dimethyl-fluoren-7-yl ⁇ -9,9-dimethyl-fluorene
  • a vacuum deposition method, a spin coating method, or the like is used as a film forming method for layers forming the first light emitting unit 21, the second light emitting unit 22, and the third light emitting unit 23.
  • the first charge generating layer 31 and the second charge generating layer 32 are each formed of an electrically insulating layer made of an electron accepting material and an electron donating material.
  • the specific resistance of the electrically insulating layer may be preferably 1.0 ⁇ 10 2 ⁇ cm or more, or more preferably 1.0 ⁇ 10 5 ⁇ cm or more.
  • first charge generating layer 31 and the second charge generating layer 32 may each be configured such that the charge generating layer is formed of mixed layers of different materials, one component of the mixed layers is a metal oxide, and this metal oxide forms a charge transfer complex by redox.
  • the charge generating layer is formed of mixed layers of different materials
  • one component of the mixed layers is a metal oxide
  • this metal oxide forms a charge transfer complex by redox.
  • voltage is applied between the cathode 11 and the anode 12
  • charges in the charge transfer complex move toward each of the cathode 11 side and the anode 12 side.
  • first light emitting unit 21 or second light emitting unit 22 Holes are injected into one light emitting unit (first light emitting unit 21 or second light emitting unit 22) located on the cathode 11 side of the second charge generating layer 32 and electrons are injected into another light emitting unit (third light emitting unit 23) located on the anode 12 side of the second charge generating layer 32.
  • Light emission from the first light emitting unit 21, the second light emitting unit 22, and the third light emitting unit 23 can be thereby simultaneously achieved at the same current amount. Accordingly, a current efficiency and an external quantum efficiency equal to the sum of light emission efficiencies of the first light emitting unit 21, the second light emitting unit 22 and the third light emitting unit 23 can be obtained.
  • the first charge generating layer 31 and the second charge generating layer 32 may each be a laminate of an electron accepting material and an electron donating material. Effects similar to those described in paragraph [0041] can be obtained also in this case.
  • materials described in aforementioned Patent Document 1 are used as materials forming the first charge generating layer 31 and the second charge generating layer 32.
  • materials described in paragraphs [0019] to [0021] are preferably used.
  • materials described in paragraphs [0023] to [0026] of "International Patent Application Publication No. WO2010/113493 " are used as materials forming the first charge generating layer 31 and the second charge generating layer 32.
  • a compound having a structure expressed by the following formula (1) may also be used as the material forming the first charge generating layer 31 and the second charge generating layer 32.
  • substituent groups represented by R in the structure expressed by the following formula (1) are CN (cyano groups)
  • this compound is HATCN6 described above. where R represents an electron withdrawing group of F, Cl, Br, I, CN, CF 3 .
  • Fig. 2 is a graph depicting an example of an emission spectrum of white light provided by the organic EL element 10 of the embodiment.
  • the white light provided by the organic EL element 10 has an emission spectrum S continuous over the wavelength band of at least 380 nm to 780 nm as so-called visible light.
  • the emission spectrum S has one peak wavelength p 1 in the red wavelength band R of 590 nm to 640 nm, one peak wavelength p 2 in the green wavelength band G of 500 nm to 550 nm, and one peak wavelength p 3 or two peak wavelengths p 3 , p 4 in the blue wavelength band B of 440 nm to 490 nm.
  • the emission spectrum S has one bottom wavelength b 1 between the two adjacent peak wavelengths p 2 , p 3 in a blue wavelength band and a green wavelength band of 500 nm to 520 nm.
  • Both of high luminance light emission and an excellent color rendering property can be thereby achieved by appropriately controlling a ratio of the emission intensity between the peak wavelength p 2 with a high luminosity function and the peak wavelength p 3 including a short wavelength component.
  • the emission intensity of the one bottom wavelength b 1 between the two adjacent wavelengths p3, p 2 in the blue wavelength band and the green wavelength band of 500 nm to 520 nm is lower than the emission intensities of bottom wavelengths b 2 , b 3 between two adjacent peak wavelenghts (p 1 , p 2 ; p 3 , p 4 ) in the other wavelength bands (green wavelength band, red wavelength band, blue wavelength band).
  • a color temperature of the white light suitable for lighting can be thereby achieved by appropriately setting an emission intensity ratio between the peak wavelengths p 1 and p 2 forming the bottom wavelength b 2 and an emission intensity ratio between the peak wavelengths p 3 and p 4 forming the bottom wavelength b 3 .
  • a ratio of (B) to (A) ((B)/(A)) may be 0.50 or smaller, where (A) is the emission intensity of the peak wavelength having the highest emission intensity in the wavelength band of 380 nm to 780 nm (peak wavelength p 4 in Fig. 2 ) and (B) is the emission intensity of the one bottom wavelength b 1 between the two adjacent peak wavelengths p3, p2 in the blue wavelength band and the green wavelength band of 500 nm to 520 nm.
  • the organic EL element 10 can thereby achieve both of the high luminance light emission and the excellent color rendering property and achieve the color temperature of white light suitable for lighting.
  • an interval between the one bottom wavelength b 2 between the peak wavelengths p 1 , p 2 adjacent to each other in the red wavelength band and the green wavelength band and the one bottom wavelength b 1 between the peak wavelengths p3, p2 adjacent to each other in the blue wavelength band and the green wavelength band of 500 nm to 520 nm may be preferably 50 nm or more, or more preferably 60 nm or more.
  • the blue light emitted by each blue fluorescent light emitting layer is an important factor for obtaining the white light with the high color temperature and the excellent color rendering property.
  • the emission spectrum S may have the one peak wavelength p 3 or the two peak wavelengths p 3 , p 4 in the blue wavelength band of 440 nm to 490 nm.
  • the organic EL element 10 of the embodiment can thereby provide the white light with the high color temperature and the excellent color rendering property.
  • the organic EL element 10 of the embodiment can provide the white light with a light color falling under one of daylight (D), neutral white (N), and white (W) among chromaticity ranges specified in "JIS Z 9112. "
  • the organic EL element 10 of the embodiment can provide the white light with an average color rendering index (Ra) of 70 or more or 80 or more.
  • the organic EL element 10 of the embodiment can provide the white light with the high color temperature and the excellent color rendering property as described above, the organic EL element 10 is preferably used as, for example, a light source of a backlight of a liquid crystal display or a lighting device such as a general lighting unit. Specifically, a lighting device including the organic EL element 10 of the embodiment can provide lighting using the white light with the high color temperature and the excellent color rendering property. Moreover, application of the organic EL element 10 of the embodiment is not limited to the light source of the lighting device and can be used in various applications.
  • a lighting device of the embodiment includes the aforementioned organic EL element 10 of the embodiment.
  • the lighting device of the embodiment may have a configuration including an optical film for improving the color rendering property, on the light extraction surface side of the aforementioned organic EL element 10 of the embodiment.
  • the color rendering property is evaluated by using the average color rendering index (Ra), and the average color rendering index (Ra) is expressed as an average value of eight types of color rendering indices (R1 to R8).
  • Ra average color rendering index
  • R9 for evaluating color reproduction of red
  • R13 for evaluating reproduction of Caucasian skin color
  • R15 for evaluating color reproduction of Japanese skin color
  • the optical film used in the lighting device of the embodiment is provided to cover a valley (bottom wavelength b 2 ) appearing in a wavelength band of 540 nm to 580 nm in the aforementioned emission spectrum S and improve the color temperature and deviation while maintaining the color rendering property.
  • an organic EL element generally emits light in a light emitting layer with a higher refractive index (refractive index of about 1.6 to 2.1) than air and it is said that only about 15% to 20% of light emitted from the light emitting layer can be extracted. This is because: light incident on an interface at an angle equal to or greater than a critical angle is totally reflected and cannot be extracted from the element; and light is totally reflected between a transparent substrate and a transparent electrode or the light emitting layer to be guided through the transparent electrode or the light emitting layer and resultantly escapes in a direction toward side surfaces of the element.
  • refractive index refractive index of about 1.6 to 2.1
  • a method for improving the extraction efficiency of the light there are, for example, the following methods: a method of making a surface of the transparent substrate rough to prevent total reflection on an interface between the transparent substrate and air (see, for example, " US Patent No. 4,774,435 ”) ; a method of providing a light condensing property to the substrate to improve the efficiency (see, for example, “ Japanese Patent Application Publication No. Sho 63-314795 “); a method of forming reflection surfaces on the side surfaces of the element and the like (see, for example, " Japanese Patent Application Publication No.
  • Hei 1-220394 a method of introducing a flat layer with an intermediate refractive index between the substrate and the light emitting body to form a reflection prevention film (see, for example, " Japanese Patent Application Publication No. Sho 62-172691 "); a method of introducing a flat layer with a lower refractive index than the substrate, between the substrate and the light emitting body (see, for example, “ Japanese Patent Application Publication No. 2001-202827 “); and a method of forming a diffraction grading between any two of the substrate, the transparent electrode layer, and the light emitting layer (including between the substrate and the outside) (see, for example, " Japanese Patent Application Publication No. Hei 11-283751 ").
  • the lighting device may have a structure in which a microlens array or the like is further provided on a surface of the aforementioned optical film.
  • the lighting device may be combined with a light condensing sheet to condense the light in a specific direction, for example, a forward direction relative to the element light emitting surface, and thereby improve the luminance in the specific direction.
  • a light diffusion film may be used together with the light condensing sheet to control a light emission angle from the organic EL element.
  • a light diffusion film LIGHT-UP
  • Kimoto Co., Ltd. or the like is used as the light diffusion film.
  • the lighting device of the embodiment can provide the white light with the high color temperature and the excellent color rendering property. Specifically, the lighting device of the embodiment can provide the white light with a light color falling under of one of daylight (D), neutral white (N), and white (W) among chromaticity ranges specified in "JIS Z 9112. " Moreover, the lighting device of the embodiment can provide the white light with an average color rendering index (Ra) of 80 or more or 85 or more.
  • R13 and R15 among the color rendering indices of the white light may each be preferably 70 or more, or more preferably 80 or more.
  • the organic EL element of the embodiment preferably employs the aforementioned element structure illustrated in Fig. 1 as the element structure for providing the white light having the emission spectrum S with the high color temperature and the excellent color rendering property as illustrated in Fig. 2
  • the element structure is not necessarily limited to that described above.
  • the element structure of the organic EL element of the embodiment can be any structure as long as it provides the white light having the emission spectrum S with the high color temperature and the excellent color rendering property as illustrated in Fig. 2 , and various element structures and materials can be employed to achieve such white light. Examples
  • Example 1 an organic EL element having an element structure illustrated in Fig. 3 was manufactured.
  • soda-lime glass substrate with a thickness of 0.7 mm on which an ITO film with a thickness of 100 nm, a width of 2 mm, and a sheet resistance of about 20 ⁇ / ⁇ was formed.
  • the substrate was subjected to ultrasonic cleaning by using neutral detergent, ion-exchanged water, acetone, and isopropyl alcohol for 5 minutes for each cleaner and then subjected to spin drying and UV/O 3 treatment.
  • vapor deposition crucibles made of tantalum or alumina in a vacuum deposition apparatus were filled respectively with materials used to form layers illustrated in Fig. 3 .
  • the substrate was set in the vacuum deposition apparatus, electric power was supplied to the vapor deposition crucibles to heat them in a reduced pressure atmosphere with a degree of vacuum of 1 ⁇ 10 -4 Pa or less, and each of the layers was vapor-deposited to a predetermined film thickness at a deposition rate of 0.1 nm per second.
  • each of the layers made of two or more materials such as the light emitting layers was formed by supplying power to the corresponding vapor deposition crucibles and performing co-deposition such that the layer is formed to have a predetermined mix ratio.
  • the cathode was vapor-deposited to a predetermined film thickness at a deposition rate of 1 nm per second.
  • the organic EL element of Example 1 manufactured as described above was connected to a power supply (KEITHLEY 2425) and power with a constant current of 3 mA/cm 2 was supplied to the organic EL element of Example 1 to cause it to emit light.
  • An emission spectrum of light emitted from the organic EL element in a forward direction in this case was measured by using a multichannel analyzer (trade name: PMA-11, manufactured by Hamamatsu Photonics K.K.).
  • the emitted light color was evaluated based on the measurement result by using chromaticity coordinates in the CIE color system. Moreover, the emitted light color was classified into one of light source colors specified in "JIS Z 9112" based on the chromaticity coordinates. Furthermore, the deviation duv from a black body locus was derived based on the specifications of "JIS Z 8725.” Moreover, the average color rendering index (Ra) of the emitted light color was derived by using the method specified in "JIS Z 8726.” The results of these evaluations are collectively illustrated in Fig. 4 .
  • An organic EL element of Example 2 having an element structure illustrated in Fig. 5 was manufactured by using a manufacturing method similar to that of Example 1.
  • Example 2 the organic EL element of Example 2 was evaluated in methods similar to those in Example 1. The results of the evaluations are illustrated in Fig. 6 .
  • the organic EL elements of Examples 1 and 2 both provided the white light with the high color temperature and the excellent color rendering property. Accordingly, it was found that a lighting device including such an organic EL element of the present invention can provide lighting using the white light with the high color temperature and the excellent color rendering property.
  • Example 3 was evaluated in methods similar to those in Example 1. The results of the evaluations are illustrated in Fig. 4 .
  • Example 4 was evaluated in methods similar to those in Example 1. The results of the evaluations are illustrated in Fig. 6 .
  • a lighting device of Example 5 having an element structure illustrated in Fig. 7 was manufactured by using a manufacturing method similar to that in Example 1.
  • Example 5 was evaluated in methods similar to those in Example 1. The results of the evaluations are illustrated in Fig. 8 .
  • a lighting device of Example 6 having an element structure illustrated in Fig. 9 was manufactured by using a manufacturing method similar to that in Example 1.
  • Example 6 was evaluated in methods similar to those in Example 1. The results of the evaluations are illustrated in Fig. 10 .
  • the lighting devices of Examples 5 and 6 both provided the white light with the high color temperature and the excellent color rendering property. Accordingly, it was found that such a lighting device including the organic EL element of the present invention can provide lighting using the white light with the high color temperature and the excellent color rendering property.
  • a lighting device of Example 7 having an element structure illustrated in Fig. 11 was manufactured by using a manufacturing method similar to that in Example 1.
  • Example 7 was evaluated in methods similar to those in Example 1. The results of the evaluations are illustrated in Fig. 12 .
  • a lighting device of Comparative Example having an element structure illustrated in Fig. 13 was manufactured by using a manufacturing method similar to that in Example 1.
  • the luminance was measured for each of the lighting devices of Example 7 and Comparative Example. The results are illustrated in Table 1. Note that, in Table 1, the luminance of the lighting device of Example 7 is a relative value based on the luminance of the lighting device of Comparative Example.
  • the correlated color temperature (K) was measured for each of the lighting devices of Example 7 and Comparative Example. The results are illustrated in Table 1. The emitted light color was measured for each of the lighting devices of Example 7 and Comparative Example. The results are illustrated in Table 1.
  • the lighting devices of Example 7 and Comparative Example were each connected to a power supply (KEITHLEY 2425) and power with a constant current of 3 mA/cm 2 was supplied to each of the lighting devices of Example 7 and Comparative Example to cause it to emit light.
  • An emission spectrum of light emitted from each lighting device in a forward direction in this case was measured by using a multichannel analyzer (trade name: PMA-11, manufactured by Hamamatsu Photonics K.K.).
  • Example 7 and Comparative Example were each connected to a power supply control unit (trade name: PEL-100TB, manufactured by EHC K.K.) and power with a constant current of 10 mA/cm 2 and power with a constant current of 20 mA/cm 2 were supplied to each lighting device to perform an accelerated life test of the lighting device.
  • a power supply control unit (trade name: PEL-100TB, manufactured by EHC K.K.) and power with a constant current of 10 mA/cm 2 and power with a constant current of 20 mA/cm 2 were supplied to each lighting device to perform an accelerated life test of the lighting device.
  • Luminance and an emission spectrum of light emitted from each lighting device in a forward direction in this case were measured by using luminance values obtained by a spectroradiometer (trade name: SR-3AR, manufactured by Topcon Technohouse Corporation) at predetermined elapsed times, and a decrease rate of the luminance at each elapsed time was calculated.
  • a spectroradiometer trade name: SR-3AR, manufactured by Topcon Technohouse Corporation
  • the lighting device of Example 7 provided the white light with the high color temperature and the excellent color rendering property. Accordingly, it was found that such a lighting device including the organic EL element of the present invention can achieve lighting using the white light with the high color temperature and the excellent color rendering property.
  • the lighting device of Example 7 has 1.60 times the luminance of the lighting device of Comparative Example, the lighting device of Example 7 could achieve substantially the same luminance life as the lighting device of Comparative Example. In other words, the lighting device of Example 7 can achieve high-luminance and long-life light emission while achieving the high color temperature and the excellent color rendering property.
  • the present invention can provide an organic electroluminescent element capable of providing white light with a high color temperature and an excellent color rendering property and a lighting device including such an organic electroluminescent element.

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • General Engineering & Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Electroluminescent Light Sources (AREA)

Claims (13)

  1. Organisches elektrolumineszentes Element (10), dadurch gekennzeichnet, dass es eine Struktur aufweist, die eine Vielzahl von lichtemittierenden Einheiten (21, 22, 23) umfasst, die zwischen einer Kathode (11) und einer Anode (12) gestapelt sind, und mit einer ladungserzeugenden Schicht (31, 32) vorgesehen ist, die zwischen jeder benachbarten lichtemittierenden Einheit (21, 22, 23) angeordnet wird, wobei jede lichtemittierende Einheit (21, 22, 23) mindestens eine lichtemittierende Schicht umfasst, die aus organischen Verbindungen besteht; wobei das organische elektrolumineszente Element (10) weißes Licht mittels Licht emittiert, das von der Vielzahl von lichtemittierenden Einheiten (21, 22, 23) emittiert wird; wobei die Vielzahl von lichtemittierenden Einheiten (21, 22, 23) die folgenden umfasst:
    eine erste lichtemittierende Einheit (21), die eine lichtemittierende Schicht mit einer roten phosphoreszierenden Schicht und einer grünen phosphoreszierenden Schicht umfasst, wobei die rote phosphoreszierende Schicht rotes Licht mit einer Spitzenwellenlänge im roten Wellenlängenbereich emittiert und die grüne phosphoreszierende Schicht grünes Licht mit 1 Spitzenwellenlänge im grünen Wellenlängenbereich emittiert;
    eine zweite lichtemittierende Einheit (22), die eine lichtemittierende Schicht mit einer blau fluoreszierenden lichtemittierenden Schicht umfasst, wobei die blau fluoreszierende lichtemittierende Schicht blaues Licht mit 1 oder 2 Spitzenwellenlängen im blauen Wellenlängenbereich emittiert; und
    eine zweite lichtemittierende Einheit (23), die eine lichtemittierende Schicht mit einer blau fluoreszierenden lichtemittierenden Schicht umfasst, wobei die blau fluoreszierende lichtemittierende Schicht blaues Licht mit 1 oder 2 Spitzenwellenlängen im blauen Wellenlängenbereich emittiert.
    Das organische elektrolumineszente Element (10) weist eine Struktur auf, wobei die erste lichtemittierende Einheit (21) und die zweite lichtemittierende Einheit (22) sandwichartig mit einer ersten ladungserzeugenden Schicht (31) als Zwischenschicht laminiert sind und die zweite lichtemittierende Einheit (22) und die dritte lichtemittierende Einheit (23) sandwichartig mit einer zweiten ladungserzeugenden Schicht (32) als Zwischenschicht laminiert sind; und
    die Anode (12), die dritte lichtemittierende Einheit (23), die zweite ladungserzeugende Schicht (32), die zweite lichtemittierende Einheit (22), die erste ladungserzeugende Schicht (31), die erste lichtemittierende Einheit (21) und die Kathode (11) nacheinander laminiert sind,
    wobei die erste lichtemittierende Einheit (21), die zweite lichtemittierende Einheit (22) und die dritte lichtemittierende Einheit (23) das weiße Licht mit einem kontinuierlichen lichtemittierenden Spektrum im Wellenlängenbereich von mindestens 380 nm bis 780 nm emittieren, und das lichtemittierende Spektrum eine Spitzenwellenlänge im roten Wellenlängenbereich von 590 nm bis 640 nm, eine Spitzenwellenlänge im grünen Wellenlängenbereich von 500 nm bis 550 nm und 1 oder 2 Spitzenwellenlängen im blauen Wellenlängenbereich von 440 nm bis 490 nm aufweist, wobei das lichtemittierende Spektrum eine lokale minimale Lichtstärke bei einer Spitzen-Tal-Wellenlänge im Bereich von 500 nm bis 520 nm zwischen zwei benachbarten Spitzenwellenlängen im blauen Wellenlängenbereich und dem grünen Wellenlängenbereich aufweist;
    wobei die Lichtstärke bei der Spitzen-Tal-Wellenlänge geringer ist als eine beliebige zweite lokale minimale Lichtstärke zwischen zwei benachbarten Spitzenwellenlängen in dem roten Wellenlängenbereich, dem grünen Wellenlängenbereich oder dem blauen Wellenlängenbereich.
  2. Organisches elektrolumineszente Element (10) nach Anspruch 1, dadurch gekennzeichnet, dass die Lichtstärke einer Spitzenwellenlänge mit der höchsten Lichtstärke in dem Wellenlängenbereich von 380 nm bis 780 nm auf (A) eingestellt ist und dass die Lichtstärke der Spitzen-Tal-Wellenlängen auf (B) eingestellt ist, wobei das Verhältnis (B)/(A) von (B) zu (A) gleich oder kleiner als 0,50 ist.
  3. Organisches elektrolumineszente Element (10) nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Wellenlänge, die der zweiten lokalen minimalen Lichtstärke zwischen den benachbarten Spitzenwellenlängen in dem roten Wellenlängenbereich und dem grünen Wellenlängenbereich entspricht, von den Spitzen-Tal-Wellenlängen um ein Intervall gleich oder größer als 50 nm beabstandet ist.
  4. Organisches elektrolumineszente Element (10) nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Lumineszenzfarbe des weißen Lichts die Tageslichtfarbe D in dem in "JIS Z9112" spezifizierten Chromatizitätsbereich ist, und dass der durchschnittliche Farbwiedergabeindex Ra des weißen Lichts 70 oder mehr beträgt.
  5. Organisches elektrolumineszente Element (10) nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass jede der ladungserzeugenden Schichten (31, 32) eine elektrisch isolierende Schicht umfasst, wobei die elektrisch isolierende Schicht aus einer elektronenaufnehmenden Substanz und einer elektronenabgebenden Substanz besteht und einen spezifischen Widerstand von 1,0 × 102 Ω·cm oder mehr aufweist.
  6. Organisches elektrolumineszentes Element (10) nach Anspruch 5, dadurch gekennzeichnet, dass die elektrisch isolierende Schicht einen spezifischen Widerstand von 1,0 × 105 Ω·cm oder mehr aufweist.
  7. Organisches elektrolumineszentes Element (10) nach einem der Ansprüche 1-4, dadurch gekennzeichnet, dass
    jede der ladungserzeugenden Schichten (31, 32) eine gemischte Schicht umfasst, die aus unterschiedlichen Substanzen besteht, wobei eine Komponente der gemischten Schicht ein Metalloxid ist und das Metalloxid einen Ladungsübertragungskomplex durch eine Redoxreaktion bildet; und
    sich die Ladung in dem Ladungsübertragungskomplex in Richtung der Kathodenseite bzw. der Anodenseite bewegt, wenn eine Spannung zwischen der Kathode (11) und der Anode (12) angelegt wird, wodurch die Injektion von Löchern in eine lichtemittierende Einheit (21, 22, 23), die sich auf der ladungserzeugenden Schicht (31, 32) nahe der Kathodenseite befindet, und die Injektion von Elektronen in die anderen lichtemittierenden Einheiten (21, 22, 23), die sich auf der ladungserzeugenden Schicht (31, 32) nahe der Anodenseite befinden, bewirkt werden.
  8. Organisches elektrolumineszentes Element (10) nach einem der Ansprüche 1-4, dadurch gekennzeichnet, dass
    jede der ladungserzeugenden Schichten (31, 32) ein Laminat umfasst, das aus einer elektronenaufnehmenden Substanz und einer elektronenabgebenden Substanz besteht; und
    sich die Ladung an der Grenzfläche zwischen der elektronenaufnehmenden Substanz und der elektronenspendenden Substanz, die aus der Reaktion der Bewegung von Elektronen zwischen der elektronenaufnehmenden Substanz und der elektronenspendenden Substanz resultiert, jeweils in Richtung der Kathodenseite bzw. der Anodenseite bewegt, wenn eine Spannung zwischen der Kathode (11) und der Anode (12) angelegt wird, wodurch die Injektion von Löchern in eine lichtemittierende Einheit (21, 22, 23), die sich auf der ladungserzeugenden Schicht (31, 32) nahe der Kathode befindet, und die Injektion von Elektronen in die anderen lichtemittierenden Einheiten (21, 22, 23), die sich auf der ladungserzeugenden Schicht (31, 32) nahe der Anodenseite befinden, bewirkt werden.
  9. Organisches elektrolumineszentes Element (10) nach einem der Ansprüche 1-8, dadurch gekennzeichnet, dass die ladungserzeugende Schicht (31, 32) eine Verbindung umfasst, die eine in der folgenden Strukturformel (1) gezeigte Struktur aufweist,
    Figure imgb0004
     wobei sich R auf die elektronenabsorbierenden Gruppen von F, Cl, Br, I, CN, CF3 bezieht.
  10. Beleuchtungsvorrichtung, dadurch gekennzeichnet, dass sie ein organisches elektrolumineszentes Element (10) nach einem der Ansprüche 1 bis 9 umfasst.
  11. Beleuchtungsvorrichtung nach Anspruch 10, dadurch gekennzeichnet, dass ein optischer Film auf der Seite für Lichtgewinnung des organischen elektrolumineszentes Elements (10) vorgesehen ist.
  12. Beleuchtungsvorrichtung nach Anspruch 10 oder 11, dadurch gekennzeichnet, dass die Lumineszenzfarbe des weißen Lichts eine der Tageslichtfarben D, Tageslichtweiß N, Weiß W in dem in "JIS Z9112" spezifizierten Chromatizitätsbereich ist, und dass der durchschnittliche Farbwiedergabeindex Ra des weißen Lichts 80 oder mehr beträgt.
  13. Beleuchtungsvorrichtung nach einem der Ansprüche 10-12, dadurch gekennzeichnet, dass R13 und R15 im Farbwiedergabeindex von weißem Licht jeweils 70 oder mehr betragen.
EP17782505.6A 2016-04-14 2017-04-14 Organisches elektrolumineszentes element und beleuchtungsvorrichtung damit Active EP3445136B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016081204A JP5991686B1 (ja) 2016-04-14 2016-04-14 有機エレクトロルミネッセント素子および照明装置
PCT/JP2017/015268 WO2017179692A1 (ja) 2016-04-14 2017-04-14 有機エレクトロルミネッセント素子および照明装置

Publications (3)

Publication Number Publication Date
EP3445136A1 EP3445136A1 (de) 2019-02-20
EP3445136A4 EP3445136A4 (de) 2019-11-20
EP3445136B1 true EP3445136B1 (de) 2022-02-23

Family

ID=56921058

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17782505.6A Active EP3445136B1 (de) 2016-04-14 2017-04-14 Organisches elektrolumineszentes element und beleuchtungsvorrichtung damit

Country Status (5)

Country Link
US (1) US10879496B2 (de)
EP (1) EP3445136B1 (de)
JP (1) JP5991686B1 (de)
CN (1) CN109076673B (de)
WO (1) WO2017179692A1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6155378B1 (ja) 2016-12-27 2017-06-28 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子、照明装置、ディスプレイ装置
JP6151847B1 (ja) * 2016-12-27 2017-06-21 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子および照明装置
JP6142070B1 (ja) 2016-12-27 2017-06-07 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子および照明装置
JP6151845B1 (ja) * 2016-12-27 2017-06-21 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子、照明装置、ディスプレイ装置
CN107579096B (zh) * 2017-07-24 2019-04-12 武汉华星光电半导体显示技术有限公司 一种oled显示面板及相应的驱动方法和驱动装置
CN109004092A (zh) * 2018-06-29 2018-12-14 云谷（固安）科技有限公司 有机电致发光器件和有机电致发光装置
KR20220091899A (ko) * 2020-12-24 2022-07-01 엘지디스플레이 주식회사 표시패널과 이를 포함하는 표시장치 및 이의 제조방법
CN112736206A (zh) * 2020-12-25 2021-04-30 安徽熙泰智能科技有限公司 一种白光oled器件结构

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3933591B2 (ja) * 2002-03-26 2007-06-20 淳二 城戸 有機エレクトロルミネッセント素子
WO2006008977A1 (ja) 2004-07-16 2006-01-26 Konica Minolta Holdings, Inc. 有機エレクトロルミネッセンス素子、画像表示素子および照明装置
US7504657B2 (en) 2004-07-23 2009-03-17 Konica Minolta Holdings, Inc. Organic electroluminescent element, display and illuminator
US8026510B2 (en) * 2004-10-20 2011-09-27 Dai Nippon Printing Co., Ltd. Organic electronic device and method for producing the same
JP5061423B2 (ja) 2005-04-05 2012-10-31 コニカミノルタホールディングス株式会社 有機エレクトロルミネッセンス素子
KR100796615B1 (ko) * 2006-12-22 2008-01-22 삼성에스디아이 주식회사 유기전계발광소자 및 그의 제조방법
EP2444470B1 (de) 2007-08-31 2016-10-26 Semiconductor Energy Laboratory Co., Ltd. Lichtemittierendes element, lichtemittierende vorrichtung und elektronisches gerät
JP5104136B2 (ja) * 2007-09-04 2012-12-19 セイコーエプソン株式会社 発光素子、発光装置および電子機器
JP5102666B2 (ja) 2008-03-18 2012-12-19 パナソニック株式会社 有機エレクトロルミネッセンス素子及び照明装置
WO2010016990A1 (en) * 2008-08-08 2010-02-11 University Of North Texas Organic light-emitting diodes from homoleptic square planar complexes
JP5054737B2 (ja) 2009-08-05 2012-10-24 財団法人山形県産業技術振興機構 有機エレクトロルミネッセンス素子
KR101073540B1 (ko) 2009-12-04 2011-10-14 삼성모바일디스플레이주식회사 유기 발광 장치
US20130240850A1 (en) * 2012-03-13 2013-09-19 The Regents Of The University Of Michigan Ultra-high efficiency (125%) phosphorescent organic light emitting diodes using singlet fission
JP5889730B2 (ja) 2012-06-27 2016-03-22 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子及び照明装置
US9577221B2 (en) * 2012-09-26 2017-02-21 Universal Display Corporation Three stack hybrid white OLED for enhanced efficiency and lifetime
KR102174919B1 (ko) 2013-12-03 2020-11-05 엘지디스플레이 주식회사 유기 발광 소자 및 유기 발광 표시장치
JP5735162B1 (ja) 2014-07-18 2015-06-17 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子及び照明装置
KR102317991B1 (ko) * 2014-11-28 2021-10-27 엘지디스플레이 주식회사 유기발광 표시장치
KR102381626B1 (ko) * 2014-12-17 2022-04-01 엘지디스플레이 주식회사 유기발광 표시장치
JP6022015B2 (ja) * 2015-10-27 2016-11-09 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子及び照明装置
JP6155378B1 (ja) * 2016-12-27 2017-06-28 Ｌｕｍｉｏｔｅｃ株式会社 有機エレクトロルミネッセント素子、照明装置、ディスプレイ装置

Also Published As

Publication number Publication date
WO2017179692A1 (ja) 2017-10-19
US10879496B2 (en) 2020-12-29
CN109076673B (zh) 2021-07-20
EP3445136A4 (de) 2019-11-20
EP3445136A1 (de) 2019-02-20
JP5991686B1 (ja) 2016-09-14
JP2017191734A (ja) 2017-10-19
CN109076673A (zh) 2018-12-21
US20190148676A1 (en) 2019-05-16

Similar Documents

Publication Publication Date Title
EP3445136B1 (de) Organisches elektrolumineszentes element und beleuchtungsvorrichtung damit
EP2869355B1 (de) Organisches elektrolumineszentes element und beleuchtungsvorrichtung damit
JP5698135B2 (ja) 白色燐光有機発光装置
KR101702673B1 (ko) 복사 방출 장치
JP5735162B1 (ja) 有機エレクトロルミネッセント素子及び照明装置
US11024822B2 (en) Organic electroluminescent element, lighting device, and display device
US20180047926A1 (en) Organic electroluminescent element and lighting device
CN110291844B (zh) 有机电致发光装置、显示装置和照明装置
CN110352628B (zh) 有机电致发光装置和照明装置
JP5857006B2 (ja) 有機エレクトロルミネッセント素子及び照明装置
CN110115108B (zh) 有机电致发光器件和照明装置
JP6022015B2 (ja) 有機エレクトロルミネッセント素子及び照明装置
CN110140427B (zh) 有机电致发光器件和照明装置
CN110121919B (zh) 有机电致发光器件、照明装置和显示装置
CN111742617A (zh) 有机电致发光元件、显示装置和照明装置
JP2008135547A (ja) 有機ｅｌ素子

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20181012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20191022

RIC1 Information provided on ipc code assigned before grant

Ipc: H01L 51/52 20060101ALI20191016BHEP

Ipc: F21K 2/00 20060101ALI20191016BHEP

Ipc: H05B 33/02 20060101ALI20191016BHEP

Ipc: H01L 51/50 20060101ALI20191016BHEP

Ipc: H05B 33/12 20060101AFI20191016BHEP

Ipc: F21Y 115/15 20160101ALI20191016BHEP

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: XIANYANG CHVT NEW DISPLAY TECHNOLOGY CO., LTD.

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20211214

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1471481

Country of ref document: AT

Kind code of ref document: T

Effective date: 20220315

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602017053745

Country of ref document: DE

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG9D

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20220223

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1471481

Country of ref document: AT

Kind code of ref document: T

Effective date: 20220223

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220623

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220523

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220523

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220524

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220623

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602017053745

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20220430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220414

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220430

26N No opposition filed

Effective date: 20221124

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220414

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20170414

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220223

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240319

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240409

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240430

Year of fee payment: 8