Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
  • H01S1/00—Masers, i.e. devices using stimulated emission of electromagnetic radiation in the microwave range
  • H01S1/04—Masers, i.e. devices using stimulated emission of electromagnetic radiation in the microwave range liquid
• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
  • G01R33/00—Arrangements or instruments for measuring magnetic variables
  • G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
  • G01R33/60—Arrangements or instruments for measuring magnetic variables involving magnetic resonance using electron paramagnetic resonance
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
  • H01S1/00—Masers, i.e. devices using stimulated emission of electromagnetic radiation in the microwave range
  • H01S1/02—Masers, i.e. devices using stimulated emission of electromagnetic radiation in the microwave range solid
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
  • H01S4/00—Devices using stimulated emission of electromagnetic radiation in wave ranges other than those covered by groups H01S1/00, H01S3/00 or H01S5/00, e.g. phonon masers, X-ray lasers or gamma-ray lasers

Definitions

• the invention relates to a maser for generating coherent electromagnetic waves. Unlike a laser that emits visible light, a maser generates microwaves or radio waves.
• a maser comprises an active medium, means for generating a population inversion in the active medium, and a resonator tuned to the microwave frequency of the maser.
• Maser are used for example in communications with earth satellites, in radio astronomical reception systems and radio relay systems as amplifiers, for the operation of atomic clocks and as a generator for millimeter waves.
• a maser with an active solid state medium which can be operated at room temperature is known from document DOI: 10.1038 / nature1 1339.
• a population inversion in the active medium is generated by optical pumping using a pulsating laser.
• the maser comprises a cavity resonator tuned to the maser frequency.
• a maser is available that is capable of producing microwaves with a frequency f of about 1.42 GHz. Since relatively much energy has to be expended for optical pumping, only pulsed operation is possible.
• references DOI: 10.1038 / ncomms9251 and Nature 488, 353-356 (2012) disclose considerations of how a maser that can be operated at room temperature can be prepared using NV centers in diamonds or with the aid of optically pumped organic or maser-type lasers. capable molecules could be realized in the presence of a sapphire resonator. The smaller the frequency of a maser, the greater the wavelength of the electromagnetic waves. If a maser comprises a cavity resonator, then this must be built sufficiently large. If a population inversion is brought about by optical pumping, then the organic medium must be provided in high optical quality and quality and consequently with great technical effort. From the document DOI: 10.1038 / nphys3382 an NMR spectrometer with a high-quality electromagnetic oscillating circuit comprising a pickup coil, a capacitor and a filter coil emerges.
• a maser to solve the problem comprises an electromagnetic resonant circuit comprising a pickup coil, a capacitor and a filter coil, an active medium of organic or maser-capable molecules in the pickup coil and a population inversion device for generating a population inversion in the active medium.
• an electromagnetic resonant circuit comprising a pickup coil, a capacitor and a filter coil, an active medium of organic or maser-capable molecules in the pickup coil and a population inversion device for generating a population inversion in the active medium.
• Such a built maser can be operated at room temperature and allows continuous microwave radiation or radio wave radiation.
• the active medium can be chosen freely, so that different Maserfrequenzen can be realized.
• Using an electromagnetic resonant circuit as a resonator allows a small design even at Maser frequencies in the MHz range and in the kHz range. Frequencies from 1 kHz to 10 MHz are possible.
• the population inversion device is such that nuclear spins of the organic or maserable molecules are brought to negative spin temperature by the population inversion device and thus the population inversion is obtained.
• This refinement advantageously makes it possible to dispense with optical pumping, jet separation or DNP processes.
• a frequency range of up to four orders of magnitude can be covered, and in particular a frequency range of one kHz to 10 MHz. Despite the comparatively small frequencies, no large installation space is required because an electromagnetic resonant circuit and no cavity resonator is used.
• chemical pumping is carried out, preferably by means of parahydrogen, so as to obtain a negative nuclear spin temperature in the organic or maser-capable molecules of the active medium.
• the parahydrogen can then transfer its nuclear spin to the organic or maser-capable molecules to achieve population inversion.
• the technical complexity is low and in particular compared to the technical effort that must be operated for optical pumping. It can be provided as a maser, which is able to generate coherent electromagnetic waves continuously, so called a CW maser.
• a CW maser enables very accurate measurements over long periods, which is not possible in the same way with a pulsed maser. With such a CW maser, for example, a very accurate NMR sensor or magnetic field sensor is realized.
• the active medium is a liquid. It can be compared to a gaseous medium achieve high spin densities, which is to provide a CW laser with little technical effort can. Compared to a solid, significantly less energy has to be expended for creating a population inversion. This is another reason why it is possible to provide a CW maser without having to spend too much effort.
• the active medium is a solid, in particular consisting of or comprising soft polymers.
• the population inversion device is such that the corresponding organic or maserable molecules of the liquid are separated to provide a negative spin temperature medium.
• a separation process is carried out in an embodiment for hydrogen so that the parahydrogen contained in the hydrogen is separated.
• This separated parahydrogen is chemically pumped to produce a negative spin temperature in the active medium.
• parahydrogen can be obtained by conversion. Such a conversion is generally carried out at low temperatures.
• Negative spin temperatures occur when the higher energy level a nuclear spin can occupy is more heavily occupied than the lower energy level. With more than one type of spin, it is also possible to create more complex non-equilibrium populations with a higher multipole order or a partial population inversion prevails. A maser from such states has not yet been demonstrated. This fundamentally different principle in addition to the conventional population inversion could be realized by the present invention. This represents a partial population inversion in the sense of the present invention.
• the organic or maser-capable molecules with negative spin temperature are polarized.
• the geomagnetic field or a magnetic field which is weaker by a magnetic shield than the earth's magnetic field, is sufficient.
• polarization is meant an ordered alignment of nuclear spins in the active medium.
• An inverted dipole state (EinspinSullivan) is also called population inversion, which corresponds to a negative spin temperature.
• a high degree of polarization is more favorable than a low degree of polarization. Therefore, a hyperpolarization, ie an ordered alignment of nuclear spins in the active medium far beyond the thermal equilibrium, is to be preferred.
• organic molecules with which the invention has been implemented is pyridine, ie C 5 H 5 N or acetonitrile, ie CH 3 CN. These were dissolved in a solvent, namely in methanol.
• the pickup coil is preferably small.
• An installation space reduction of the pickup coil and thus also of the active mashed medium advantageously improves the coupling of the active mashed medium to the resonator.
• the quality of the maser known from the prior art increases with the space available. The latter applies, for example, to the maser known from the publication DOI: 10.10.38 / MPHYS3382.
• Filter coil and capacitance therefore preferably have a high quality of at least 100, advantageously of at least 200, particularly preferably of at least 500.
• the quality of the resonant circuit is at least 100, advantageously at least 200, particularly preferably at least 300.
• the filter coil has a grounded center tap in order to obtain a suitable electromagnetic resonant circuit in a technically simple manner.
• the quality of the filter coil and the quality of the capacitor generally exceed the quality of the pickup coil, preferably by a multiple, at least twice, particularly preferably at least three times.
• a pickup is a
• the pickup coil can have only a few turns, for example up to 10 turns.
• Wires or strands of pickup coil and / or filter coil may be made of copper, silver or gold, for example.
• the pickup coil and / or filter coil comprises strands whose thin wires are electrically insulated, in particular by insulating lacquer layers, so as to arrive at a further improved electromagnetic resonant circuit.
• Existing strands are therefore preferably high frequency resistant.
• the center tap is preferably located exactly in the middle of the filter coil. Due to the center tap parasitic oscillation tendencies of the resonant circuit are suppressed and especially good if the center tap is located exactly in the middle. This has a positive effect.
• the center tap is realized in one embodiment by an additional wire or an additional strand. One end of the additional wire or the additional strand is connected to ground, that is grounded. In addition, one end of the other wire of the filter coil is connected to ground. For example, two electrical conductors (in particular first and second wires or first and second wires) are twisted together or twisted together to produce one another. Subsequently, the two twisted electrical conductors are wound to the coil. The end of the first electrical conductor (wire or stranded wire) and the
• the second electrical conductor (wire or strand) are then grounded. The other two ends then form the electrical connections of the coil. If the aforementioned two electrical conductors are the same length, then the center tap is located exactly in the middle.
• the filter coil is shielded in particular by an electrical and / or magnetic shielding. Walls of the shield are magnetic shielded
• Mu metal or iron preferably high permeability iron.
• a magnetic shield is preferably formed by a substantially magnetically closed chamber or closed box.
• the maser works without such a shield. This is realized in the example.
• Magnetic shielding advantageously protects against electromagnetic interference and thus contributes to the improvement of the signal-to-noise ratio.
• Walls of the shield are preferably double-walled or inside a can is a second can, which is held by the first box by spacers at a distance. Inside the second can is the filter coil.
• the shield therefore particularly preferably consists of a double-walled chamber or double-walled box.
• the filter coil can be magnetically shielded from a magnetic B 0 field which is used in the case of NMR or ESR. This shielding causes more
• the walls of a double wall of the magnetic shield or the walls of one or two doses of the magnetic shield are advantageously 1 mm to 3 mm thick, for example 1, 5 mm thick.
• Walls of an electrical shield are preferably up to 3 mm thick and / or at least 0.5 mm thick. Walls of an electrical shield are
• Walls of an electrical shield are preferably made of copper.
• the shield is preferably grounded.
• the outer can is always earthed. But it can also be grounded alternatively or additionally an inner box.
• the pickup coil is separated from an excitation coil used for NMR or ESR spectroscopy. It is then so a second coil available, as
• Excitation coil for the implementation of NMR or ESR spectroscopy is used. This makes it possible to optimize the measuring device independently of the excitation coil, which enables an improved signal-to-noise ratio.
• the pickup coil is preferably located within the excitation coil. The distance between
• Excitation coil and pickup coil is advantageously at least 5 mm, preferably at least 10 mm, to a disadvantageous coupling between the two coils
• Pickup coil on the one hand and capacitor and filter coil on the other hand are connected in an advantageous embodiment by a particularly low-loss electrical transfer line with each other. This is achieved by means of a transfer line consisting of a good electrical conductor, for example by means of a copper conductor
• Transfer line by a large cross-section of a transfer line of, for example, at least 1 mm 2 , by a looping or twirling of the two electrical conductors of the transfer line and / or by a suitable electrical insulation,
• Each individual conductor may be in a teflon sheath for insulation and / or both electrical conductors of the transfer line together.
• a conductor may be formed of a wire or a stranded wire.
• a transfer line is preferably to be formed from two strands twisted together, which preferably comprises the aforementioned Teflon sheaths, so as to be particularly low-loss
• the transfer line is formed by two strands, then said cross section of at least 1 mm 2 refers to the sum of the cross sections of the strands of the two strands, including optionally available insulators.
• Leads of the transfer line are in turn preferably electrically insulated from each other, in particular by lacquer surface coating and / or performed high-frequency resistant to provide a low-loss transfer line, resulting in a further improved signal-to-noise ratio.
• the pickup coil is preferably formed by a strand, that is to say from an electrical conductor consisting of thin individual wires.
• the individual wires of the strand are advantageously electrically isolated from each other. The surfaces of the individual wires are therefore advantageously provided with an electrically insulating lacquer.
• the strand is preferably high frequency resistant.
• Suitable toroidale- or cylindrical filter coil with winding has
• the filter coil should follow an alternating magnetic field with the smallest possible power loss or a poor AC loss.
• the filter coil must have a negligible magnetic stray field and the AC resistance of the winding should be as low as possible.
• Other losses such as dielectric losses or losses in the magnetic core of the filter coil should also be minimized.
• the distance between the pickup coil on the one hand and capacitor and filter coil on the other hand at least 5 cm, preferably at least 50 cm, more preferably at least 60 cm. This reduces a mutual interfering magnetic influence between a B 0 field, as in the case of ESR or NMR spectroscopy, and the generally shielded filter coil. It is achieved that a
• Shielding does not adversely affect the B 0 field. It is further avoided that the shield is adversely saturated by the B 0 field.
• the capacity is advantageously tunable to easily adjust a suitable resonance.
• the capacitance is formed from a large number of individual capacitors which are suitably connected in parallel with one another and can be connected in such a way as to be able to change the capacitance as required.
• high-quality commercially available capacitors can be used to provide a tunable one
• the invention particularly relates to a maser with an electromagnetic resonant circuit comprising a pickup coil, a capacitor and a filter coil, an active medium of maser-capable molecules in the pickup coil and a Occupation inversion means for generating a population inversion, namely a partial population inversion in the active medium.
• the population inversion device is preferably such that nuclear spins of the molecules can be brought to negative spin temperature.
• the population inversion device is preferably arranged to create a complex nonequilibrium population (multipole order).
• the maser is preferably such that the population inversion means comprises parahydrogen for generating a population inversion in the active medium such that the molecules can be brought to negative spin temperature.
• the maser is preferably such that a complex spin order can be generated on the maser-active molecules.
• the population inversion device comprises a catalyst for the generation of a population inversion, in particular a partial population inversion in the active medium or for the generation of a higher order non-equilibrium population.
• the active medium is in particular a liquid.
• a solid can also be beneficial.
• the solid consists of soft polymers or comprises soft polymers.
• the active medium comprises methanol.
• the active medium comprises an organic solvent such as methanol, preferably d4-methanol.
• the active medium in one embodiment comprises pyridine or acetonitrile.
• the active medium in one embodiment comprises substances that can be hyperpolarized with parahydrogen.
• the active medium in one embodiment comprises PHIP (parahydrogen induced polarization) - active substances.
• the active medium comprises SABRE (signal amplification by reversible exchange) - active substances.
• the active medium in one embodiment comprises nitrogen-containing compounds.
• the active medium in one embodiment comprises one or more N-heterocyclic compounds and / or nitriles.
• the active medium in one embodiment comprises pyridine and / or acetonitrile.
• the active medium in one embodiment comprises [IrcI (cod) (IMes)].
• the maser is operated in continuous operation.
• FIG. 1 shows the structure of a maser according to the invention with an electromagnetic resonant circuit comprising a cylindrical coil acting as a pickup coil 1, a tunable capacitance 2 and a filter coil 3 with a ferrite core 4.
• the quality of capacitance and cylindrical coil is about 300.
• the pickup coil comprises approx. 100 turns of copper and has an inner diameter of about 1 cm and a height of about 1 cm.
• the quality of the filter coil was 340.
• An active medium 5 of dissolved in a liquid organic or maser-capable molecules is located in a vessel 6.
• the vessel 6 is disposed within the pickup coil 1.
• a device 7 for generating parahydrogen which is passed from the device 7 via a line 8 by means of a arranged at the end of the line 8 hollow needle 9 into the vessel 6 into it.
• the nuclear spins of the organic or maser-capable molecules are brought to a partial population inversion.
• a special case of this is the negative spin temperature.
• the supply of parahydrogen is controlled by a valve 10.
• a pressure gauge 1 1 monitors the pressure in the vessel 6 and in the conduit 21 to monitor and control the supply of parahydrogen into the vessel 6.
• Another needle valve 12 and a valve 13 may contribute to the control.
• a transfer line 14 is formed from two strands twisted together, which provides for a relatively large distance (> 10 cm) between the pickup 1 on the one hand and capacity and filter coil on the other hand.
• a differential amplifier 15 is connected to the filter coil 3 to amplify signals of the pickup coil 1 as needed.
• Pickup coil 1, transfer line 14, tunable capacitance 2, filter coil 3 together with ferrite core 4 and differential amplifier 15 are located within a shield 16. Outside the shield 16 is an operating and / or evaluation that represent the signals amplified by the differential amplifier 15 and / or can evaluate.
• the electronics comprise an NMR operating unit 17 and a data acquisition device 18.
• the shield 16 extends into a cylindrical coil 19 so that the vessel 6 is located centrally within the cylindrical coil 19.
• a static magnetic field B 0 is generated.
• the liquid active medium comprised 0.5 cm 3 d 4 -methanol, in which in some cases a few ⁇ pyridine and in another case a few ⁇ acetonitrile were dissolved. Further, the liquid active medium included some mg of [IrCl (cod) (IMes)] as a catalyst.
• the cylindrical coil produced a static magnetic field B 0 of approximately 1-16 mT.
• the design achieved a value ⁇ / ⁇ ⁇ 10 "6 cm “ 3 .

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• Physics & Mathematics (AREA)
• Electromagnetism (AREA)
• Optics & Photonics (AREA)
• Condensed Matter Physics & Semiconductors (AREA)
• General Physics & Mathematics (AREA)
• Investigating Or Analyzing Materials By The Use Of Magnetic Means (AREA)
• Pyridine Compounds (AREA)
• Control Of Motors That Do Not Use Commutators (AREA)

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• 2016
  • 2016-03-22 DE DE102016204733.7A patent/DE102016204733B4/de not_active Expired - Fee Related
  • 2016-12-21 EP EP16828726.6A patent/EP3398234A1/de not_active Withdrawn
  • 2016-12-21 WO PCT/EP2016/082050 patent/WO2017114703A1/de unknown
  • 2016-12-21 CN CN201680076474.1A patent/CN108475894B/zh active Active
  • 2016-12-21 JP JP2018533753A patent/JP6876706B2/ja active Active
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