EP3396065B1 - Brottüte und herstellungsverfahren dazu - Google Patents

Brottüte und herstellungsverfahren dazu Download PDF

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Publication number
EP3396065B1
EP3396065B1 EP18164045.9A EP18164045A EP3396065B1 EP 3396065 B1 EP3396065 B1 EP 3396065B1 EP 18164045 A EP18164045 A EP 18164045A EP 3396065 B1 EP3396065 B1 EP 3396065B1
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EP
European Patent Office
Prior art keywords
layer
cellulose
coating layer
paper
masking
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EP18164045.9A
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English (en)
French (fr)
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EP3396065A1 (de
Inventor
Dave Stappaerts
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Ace Packaging Nv
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Ace Packaging Nv
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Priority to EP20156936.5A priority Critical patent/EP3702529A1/de
Publication of EP3396065A1 publication Critical patent/EP3396065A1/de
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D21H19/68—Coatings characterised by a special visual effect, e.g. patterned, textured uneven, broken, discontinuous
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/02—Patterned paper

Definitions

  • the invention relates to a bread bag of combined layers comprising a cellulose layer and a coating layer for setting the moisture permeability, wherein the coating layer is situated on a first side of the cellulose layer.
  • the invention further relates to a method for manufacturing a bread bag, comprising the steps of:
  • Such a bread bag is known from BE 1022151 .
  • This relates to a bread bag of paper which has been treated and thereby consists of combined layers.
  • the known bread bag is provided with a coating layer of vegetable oil, such as a modified vegetable oil. With this green coating layer the bread bag meets the requirements of recyclability and can meet the requirements of compostability.
  • the coating is particularly applied on the outer side. When an imprint is desired, it is arranged under the coating. It has been found that some customers do not like the appearance of the known bread bag. It is possible that the vegetable oil, which is more viscous than a conventionally applied coating on the basis of paraffin (mineral oil), spreads out too much, as well as permeates the paper.
  • a conventional bread bag with a mineral oil-based coating however also has such aesthetic objections.
  • the invention relates for this purpose to a bread bag of combined layers comprising a cellulose layer and a coating layer for setting the moisture permeability, wherein the cellulose layer has a more closed structure on a first side than on an opposite, second side, and wherein the coating layer is situated on the first side of the cellulose layer, characterized in that the coating layer is situated on an inner side of the bread bag.
  • a masking layer is further present between the cellulose layer and the coating layer, which masking layer is provided with a predetermined pattern and wherein outside the pattern the coating layer has a boundary surface with the cellulose layer.
  • the invention relates to a method for manufacturing a bread bag of combined layers, comprising of:
  • a bread bag which is aesthetically attractive, has a desired moisture permeability and, at least in determined embodiments, is recyclable and may also be compostable in accordance with set standards.
  • the presence of the masking layer on the inner side results in a pattern which is visible from the outer side.
  • the per se transparent masking layer appears to become opaque in combination with the coating layer. This effect is based on the fact that the masking layer obstructs the oily material of the coating layer and that the paper retains its original colour at the position of the masking layer.
  • the partial penetration of the oily material of the coating layer into the cellulose layer has been found to produce an increase in the transparency of the paper in a uniformly distributed manner.
  • the thickness of the coating layer can further be limited owing to the masking layer.
  • the coating layer is applied with a thickness (or quantity) of 7-10 g/m 2 , also depending on the paper used (i.e. the type of cellulose layer and possible modifications), in a first embodiment of the invention this is limited to about 6.5 g/m 2 , generally to less than 5.5 g/m 2 .
  • the thickness of the combination of the masking layer and the coating layer is equal to at most the thickness of the coating layer in the known bread bag.
  • the oil of the coating layer in the bread bag according to the invention substantially does not permeate the paper, while this does happen in conventional bread bags with a coating layer of vegetable or mineral oil.
  • the masking layer partially permeates the paper and thus limits the surface area over which oil is able to permeate the paper, and, with this, the effective permeability of the paper.
  • the coating layer is applied with a thickness which is similar to the known thickness, for instance in a quantity of more than 5 g/m 2 , such as 6-10 g/m 2 . It has been found that the combination of the masking layer and the coating layer can limit the moisture permeability further, to levels at least substantially corresponding to the moisture permeability of plastic coatings, typically below 50 g/m 2 /day or even in the order of 20-40 g/m 2 /day, in accordance with DIN 53-122-1, as will be further discussed hereinbelow.
  • the achievable values are here of course dependent on the choice of paper and, in a favourable embodiment, are achieved in combination with the use of paper which is provided with a calcium carbonate layer.
  • the reduced moisture permeability also known as water vapour permeability
  • a contribution of the masking layer to the reduction of the moisture permeability a contribution of the masking layer to the reduction of the moisture permeability
  • a correlation between thickness of the coating layer and moisture permeability, continuing to greater thicknesses of the coating layer Because of the presence of the masking layer, a coating layer of for instance 9 g/m 2 provides for a lower moisture permeability than that of 7 g/m 2 . Without masking layer, an achievable minimum in the moisture permeability is already reached at a lower quantity.
  • the pattern of the masking layer preferably comprises repetitive elements.
  • the repetitive elements preferably have a zero-dimensional or one-dimensional form, such as dots, lines, circles. It is further possible for the repetitive elements to have other forms, such as zigzag lines, stepped forms, sine shapes, rectangles, squares, triangles.
  • the repetitive elements preferably have a fixed width.
  • the repetitive elements are still more preferably situated at a uniform mutual distance, whereby a pattern of lines and intermediate spaces results.
  • the perpendicular distance between the repetitive elements is more preferably at least 4 times greater than the width of the repetitive elements.
  • the perpendicular distance is still more preferably a maximum of 3 times or even a maximum of 2 times the width of the repetitive elements.
  • a watermark can also be arranged in this way. Although the watermark formally lies on the paper, it shines through the paper and appears to be located in the paper.
  • the watermark can comprise an image or structure chosen as desired.
  • the masking layer comprises in particular a binder material.
  • the masking layer is more particularly applied as an aqueous composition.
  • Such an aqueous composition is also known as a varnish.
  • a varnish is normally mixed with a dye concentrate prior to application, in the invention the varnish is used without being mixed with dye.
  • the varnish generally comprises 50-80% binder material, 0-10% an alcohol, such as a (poly)ethylene glycol or (poly)propylene glycol, and 0-5% additives, including an antifoaming agent, a wax and a biocide.
  • the remaining part of the varnish consists of water. This water will evaporate during drying of the layer. It is also possible for the water to spread through the cellulose layer. Drying of the layer can take place in active manner (i.e. by bringing the substrate into contact with dry and/or hot air), but also in passive manner. It is not precluded per se for a (small quantity of) dye to be used as additive.
  • the varnish, and therefore the masking layer to comprise a wax.
  • a wax is deemed favourable for the humidification of the masking layer by the coating layer, which is in particular oily.
  • Favourable binder materials include polyacrylates, polyvinyl acetates, polyvinyl alcohols, polyurethanes, polyamides and also lignin, as well as copolymers therewith. At least one of a polyacrylate and a polyvinyl acetate is preferably present.
  • the use of a binder material comprising lignin, polyvinyl acetate and/or polyvinyl alcohol is preferred because these materials have a sufficient degree of biodegradability, particularly the compostability.
  • aqueous composition with a printing process.
  • Use is particularly made here of a printing process wherein a pattern is transferred with one or more rolls.
  • Examples thereof are rotogravure and flexography (abbreviated to flexo) printing. Not only is ink transferred during use of a roll, but pressure is also exerted. This is deemed advantageous because the coating layer thereby permeates even further into the cellulose layer.
  • the cellulose layer has a reduced porosity underneath the masking layer as well, and becomes substantially impermeable to the oily coating layer.
  • an imprint is present on the second, preferably more open side of the cellulose layer, which is situated on an outer side of the bread bag. Arranging of the imprint on the outer side is commercially desirable and has been found to be effective, despite the fact that the second side is more open.
  • the imprint is preferably arranged before the coating layer is applied.
  • the paper of combined layers further comprises a sub-layer on the first side, which gives the paper a more closed structure on that side.
  • the sub-layer forms part of the cellulose layer.
  • the sub-layer comprises a filler material or a fibrous material in addition to cellulose.
  • the sub-layer comprises calcium carbonate in addition to cellulose, resulting in a calcium carbonate layer.
  • the more closed structure is obtained by processing the cellulose layer, for instance by subjecting it to additional calendering or providing it with a machine glazing. Combinations and/or further constituents are not precluded.
  • the sub-layer is more preferably a calcium carbonate layer which ensures that the paper is more closed on the first side than on the second side.
  • This is generally bleached paper.
  • a very low water vapour permeability in the order of 50-100 g/m 2 /day or even 50-75 g/m 2 /day is obtained, wherein the vapour permeability is measured in accordance with DIN 53-122-1 at 25°C and at 75% relative humidity.
  • the vapour permeability is also known in the field as the MVTR (moisture vapour transmission rate). This low vapour permeability is advantageous because it makes paper bags an effective alternative to conventional plastic bread bags, which have a vapour permeability of about 30 g/m 2 /day.
  • the further decrease of the MVTR appears to be partially related to the fact that the coating layer does not permeate through the whole bread bag.
  • the oil When permeating into the paper, the oil apparently creates hydrophobic pores, through which vapour diffuses and thus no longer adheres to the rather hydrophilic cellulose.
  • the surface on the first side of the cellulose layer more preferably has a surface roughness below 120 ml/min, preferably below 100 ml/min or even below 80 ml/min, for instance between 15 and 70 ml/min, such as 20-50 ml/min.
  • the surface roughness is here determined in accordance with ISO 8791-2 and is also known as the Roughness Bendtsen.
  • This low surface roughness on the first side is for instance achieved with the above stated calcium carbonate layer.
  • Such a surface roughness has generally been found too low to arrange an imprint thereon. That is to say, the imprint may spread due to vibrations of the printing machine used for the printing, more particularly a printing machine for flexography, such as for instance a stack type printing machine with individual impression cylinders.
  • the surface of the paper has a surface roughness on the second side of at least 100 ml/min in accordance with ISO 8791-2. This makes the second side highly suitable for arranging of an imprint.
  • Unbleached paper is generally less smooth on the first side. It can particularly be felt that it has ridges on the first side. Upon inspection with a microscope, these ridges are found to vary in height. The paper is not substantially flat, but comprises microscopic ridges and valleys. For this reason a greater quantity of coating layer generally has to be used for this type of paper than for bleached paper. It has however been found that in application according to the invention of the masking layer on the first side with a more closed structure, the oil of the coating layer nevertheless hardly permeates through the paper. The oil appears to accumulate in the valleys, at the surface.
  • the quantity of long fibres in the paper of the combined layers is preferably at least 40%.
  • the quantity of long fibres is more preferably at least 50%, still more preferably at least 70%.
  • 'short fibre' refers to cellulose originating from for instance hardwood or recycled paper and having a length in the order of 0.5-3 mm, more specifically 0.7-2.5 mm and a diameter for instance 20-30 ⁇ m.
  • 'Long fibre' refers to cellulose primarily originating from softwood and more particularly having a length in the order of 2.5-5.0 mm, more specifically 2.7-4.5 mm, and a diameter of for instance 30-45 ⁇ m.
  • the cellulose layer has a weight which is higher than 20 g/m 2 and lower than 70 g/m 2 , the weight preferably lying between 35 g/m 2 and 60 g/m 2 . It is very important for the paper to have a Gurley (ISO 5636-5) air resistance of at least 30 seconds. There are likewise types of paper with such an air resistance of more than 100 sec or even more than 150 sec. Such paper types with a Gurley air resistance of at least 100 seconds are preferred.
  • the opacity in accordance with ISO 2471 preferably lies between 50 and 85%, more particularly between 60 and 75%. Use can be made of unbleached paper and of bleached paper. In forming of the bread bag it is further possible for a window to be arranged, as is per se known to the skilled person.
  • the term 'structure' refers to the microstructure of the paper, which can be more closed, less closed or closed, depending on the type of paper, surface treatment and so on.
  • a more closed structure can be obtained by the use of a specific layer or coating, but also by a heat treatment.
  • the glue used during manufacture of the cellulose layer also affects the degree to which the microstructure is open.
  • the specific layer is often a calcium carbonate layer, but can also comprise filler materials other than calcium carbonate, such as for instance TiO2 in order to make the paper extra white.
  • An example of a treatment is machine glazing.
  • the coating layer comprises a vegetable oil.
  • vegetable oils are, among others, palm oil, soybean oil, sunflower oil, olive oil, almond oil, canola oil, linseed oil, corn oil.
  • the oil is preferably applied as an ester of the fatty acid, for instance as a glyceride of the fatty acid, as is known to the skilled person.
  • the coating layer is more preferably applied at an increased temperature, such as a temperature above 100°C. This results in a reduction of the viscosity of the vegetable oil. It is moreover suspected that at the increased temperature the oil also mixes at least partially with the masking layer or at least a top layer thereof. This is advantageous for the bonding. It is not precluded that this mixing further reduces the permeation of the oil toward the cellulose layer.
  • a favourable effect of the masking layer is that the required quantity of coating layer decreases. There are several reasons for this; firstly, the paper of cellulose layer and masking layer is less open; less is thus needed in order to form a coating layer. The masking layer is moreover deemed to have a suitable surface over which the coating layer can extend. An even layer is thus formed quickly.
  • Paper comprising a cellulose layer and optionally further layers, such as a calcium carbonate layer, is generally used as a starting point.
  • the paper is here already provided with a more closed structure on the first side than on the second side.
  • the masking layer and, if applicable, the imprint are then applied to either side of the paper. This is followed by the coating layer.
  • This coating layer is preferably applied using a roller, as further elucidated in the application BE1022151 , at a temperature above 100°C.
  • the paper with imprint, masking layer and coating layer is complete, it is processed into bread bags. If desired, a strip of plastic can be adhered to a strip of paper beforehand. This makes it possible to manufacture window bags.
  • the process for manufacturing bread bags from paper is per se known. Bread bags are distinguished from other bags, such as bags for flour, by the shape of the bag and/or the properties of the paper.
  • the paper of combined layers according to the invention including a masking layer and a coating layer is also suitable for other applications.
  • An example is the use as packaging paper for vegetables and fruit, sliced meats and/or cheese.
  • This invention can also serve for vegetable and fruit bags (the same bag as the bread bag); the coating layer here provides for a water barrier for the wet vegetables and fruit. It is here also advantageous for the coating layer to be situated on the inner side of the bag.
  • the paper of combined layers according to the invention is cardboard.
  • the cellulose layer is multilayer paper.
  • the multilayer paper preferably has a weight here of at least 179 g/m 2 .
  • the cardboard is more preferably chosen from corrugated board (with a specific weight of up to 600 g/m 2 ) or solid board (with a specific weight of up to 1000 g/m 2 ), and is provided on the second side with an additional layer of paper on which an imprint can be arranged.
  • Application is expected particularly as cardboard in the food sector, such as for instance as paper trays.
  • the masking layer and the coating layer to be situated on the side which comes into contact with the foodstuff. The combination ensures that mineral oils from the cellulose layer (i.e. the cardboard) are unable to permeate into the foodstuff.
  • the masking layer furthermore provides a neat appearance.
  • Fig. 1A shows a bread bag 10 in a first embodiment.
  • Fig. 1B shows the same bread bag 10 in a slightly opened position.
  • the bread bag is made of paper with a first side 11 and a second side 12.
  • the first side 11 is here situated on the inner side of bread bag 10.
  • the paper has a more closed structure on the first side 11 than on the second side 12.
  • an imprint 15 has been arranged on the paper, here in the form of a letter B.
  • Bread bag 10 is provided with a lower edge 21 and an upper edge 22, a front side 24 and a rear side (not numbered). Side flaps 23 are present between front side 24 and the rear side.
  • Bread bag 10 is made by providing a sheet of paper with folds in suitable manner and then glueing a first side edge to a second side edge, thus forming a sleeve. After separating a strip of paper into individual units, a part of front side 24 is folded along lower edge 21 and glued on the rear side.
  • the type of bread bag with an upper edge 22 which rises from front side to rear side in two steps is very favourable for this purpose.
  • Print 15 is generally arranged on the first side and covered with a coating layer.
  • the coating layer traditionally comprises a mineral oil, although good results have also been achieved with a vegetable oil. After application, the oil soaks into the paper. Owing to the oil, the water vapour permeability is set, such that bread maintains a crispy crust without drying out too quickly.
  • Fig. 2 shows the paper which is used in the bread bag 10 according to the invention.
  • This paper is also referred to as a package of combined layers.
  • the primary layer thereof is the cellulose layer 13, which is provided on one side with a smooth, treated sub-layer 14.
  • This sub-layer 14 is obtained by adding calcium carbonate on that side and/or by extra calendering and/or by filling with filler materials and/or refining fibres.
  • This sub-layer 14 is for instance a layer which is filled with calcium carbonate (i.e. a cellulose layer comprising calcium carbonate, in short calcium carbonate layer).
  • sub-layer 14 is obtained by extra addition of short fibres and filler materials and additional calendering of paper.
  • Cellulose layer 13 is chosen such that it is suitable for packaging foodstuff and is normally supplied including sub-layer 14 by a paper manufacturer.
  • sub-layer 14 is situated on first side 11, i.e. the side which will be situated on the inner side of bread bag 10 after folding and glueing.
  • the imprint is arranged on second side 12, which will later serve as outer side. Unlike before, this is the second side 12 with a more open structure than first side 11.
  • a masking layer 16 is arranged on first side 11, particularly as a water-based layer of technical varnish. In the illustrated embodiment the varnish is free of dye concentrate. Addition of a dye is however not absolutely precluded.
  • Masking layer 16 is preferably applied by means of flexography.
  • a coating layer 17 which comprises an oily material such as paraffin or vegetable oil.
  • the oils are in particular modified in usual manner, i.e. into esters, for instance with glycerol.
  • Coating layer 17 is preferably applied by having a roller run through a bath of melted oil and transferring the coating layer from the roller to the paper.
  • the presence of masking layer 16 makes the paper less accessible to the oil of coating layer 17 on the second side. This has the result that less oil permeates the cellulose layer and that surprisingly good properties are obtained.
  • the water vapour permeability has decreased greatly and the aesthetic properties of the bread bag are better.
  • the masking layer permeates partially into cellulose layer 13, 14 and there further closes pores of the cellulose layer 14.
  • the coating layer moreover appears to form a better layer. This may be enhanced by interaction at the boundary surface of coating layer 17 and masking layer 16.
  • Fig. 3 shows schematically a detail of bread bag 10 is shown in Fig. 1A .
  • This shows the pattern which results from the use of the combination of masking layer 16 and coating layer 17 on first side 11 of the paper, which is situated on the inner side of bread bag 10.
  • masking layer 16 is applied in a pattern of parallel lines.
  • On the inner side 11 of bread bag 10 the pattern is visible as dark lines 121 alternated with light lines. Dark lines 121 correspond to the positions where coating layer 17 is in contact with the cellulose layer.
  • the light lines correspond to the positions where masking layer 16 is in contact with the cellulose layer.
  • Line pattern 111 has also been found to be visible on the first side, but in a lighter shade. It is thus well possible to arrange an imprint on second side 12 without it being disrupted by line pattern 111.

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Claims (15)

  1. Brottüte aus kombinierten Schichten, die eine Zelluloseschicht und eine Überzugschicht zum Festlegen der Feuchtigkeitsdurchlässigkeit aufweisen, wobei die Zelluloseschicht auf einer ersten Seite eine geschlossenere Struktur als auf einer entgegengesetzten zweiten Seite hat, und wobei die Überzugschicht auf der ersten Seite der Zelluloseschicht gelegen ist, dadurch gekennzeichnet, dass
    - die Überzugschicht auf einer Innenseite der Brottüte gelegen ist,
    - eine Maskierungsschicht zwischen der Zelluloseschicht und der Überzugschicht vorhanden ist, wobei die Maskierungsschicht mit einem vorgegebenen Muster versehen ist, wobei die Überzugschicht außerhalb des Musters eine Grenzoberfläche mit der Zelluloseschicht hat.
  2. Brottüte nach Anspruch 1, dadurch gekennzeichnet, dass das Muster der Maskierungsschicht ein sich wiederholender Aufbau ist und sich wiederholende Elemente aufweist, wobei das sich wiederholende Element vorzugsweise eine Linie ist.
  3. Brottüte nach den Ansprüchen 1 - 2, wobei die Maskierungsschicht auf der ersten Seite 10 - 75% der Zelluloseschicht bedeckt.
  4. Brottüte nach den Ansprüchen 1 - 3, wobei die Maskierungsschicht ein Bindematerial aufweist, wobei das Bindematerial die Zelluloseschicht vorzugsweise lokal imprägniert.
  5. Brottüte nach Anspruch 4, dadurch gekennzeichnet, dass das Bindematerial wenigstens ein Material aufweist, das aus der Gruppe ausgewählt wird, die aus Polyvinylacetat, Acrylat-(Co-)Polymeren, Polyamid, Polyurethan besteht, und/oder wobei das Bindematerial ein Ligninharz aufweist.
  6. Brottüte nach den Ansprüchen 1 - 5, wobei die Überzugschicht ein Pflanzenöl aufweist und/oder wobei die Überzugschicht ein Gewicht von 1 - 5 g/m2 hat.
  7. Brottüte nach den Ansprüchen 1 - 6, wobei die Zelluloseschicht auf ihrer ersten Seite eine Unterschicht aufwiest, die das Papier auf der ersten Seite geschlossener macht.
  8. Brottüte nach Anspruch 7, wobei die Unterschicht neben Zellulose ein Füllmaterial oder ein faseriges Material aufweist, und/oder wobei diese Unterschicht neben Zellulose Kalziumkarbonat aufweist, woraus sich eine Kalziumkarbonatschicht ergibt.
  9. Brottüte nach den Ansprüchen 1 - 8, wobei die Zelluloseschicht eine Mischung aus langen Fasern und kurzen Zellulosefasern mit wenigstens 40% langen Fasern aufweist, und/oder wobei die Zelluloseschicht ungebleichte Fasern aufweist, und/oder wobei die Zelluloseschicht ein Gewicht von maximal 70 g/m2 hat.
  10. Verfahren zur Herstellung einer Brottüte aus kombinierten Schichten, das aufweist:
    - Bereitstellen einer Zelluloseschicht mit einer ersten Seite und einer zweiten Seite, wobei die Zelluloseschicht auf der ersten Seite eine geschlossenere Struktur als auf der zweiten Seite hat;
    - Aufbringen einer Maskierungsschicht auf der ersten Seite gemäß einem vorgegebenen Muster;
    - Aufbringen einer Überzugschicht über der Maskierungsschicht in einer Weise, dass die Überzugschicht eine Grenzoberfläche mit der Zelluloseschicht hat;
    - Ausbilden von Brottüten aus den kombinierten Schichten.
  11. Verfahren nach Anspruch 10, wobei die Maskierungsschicht als eine wässrige Zusammensetzung aufgebracht wird, während die Überzugschicht eine ölige Verbindung aufweist.
  12. Verfahren nach Anspruch 11, wobei die Überzugschicht ein Pflanzenöl aufweist.
  13. Verfahren nach den Ansprüchen 10 - 12, wobei die Maskierungsschicht in einem sich wiederholenden Aufbau mittels Flexodruck aufgebracht wird.
  14. Verfahren nach den Ansprüchen 10 - 13, wobei auf der zweiten Seite der Zelluloseschicht, vorzugsweise, bevor die Maskierungsschicht aufgebracht wird, ein Aufdruck angeordnet wird.
  15. Papier aus kombinierten Schichten, die eine Zelluloseschicht und eine Überzugschicht zum Festlegen der Feuchtigkeitsdurchlässigkeit aufweisen, wobei die Zellulose auf einer ersten Seite eine geschlossenere Struktur als auf einer entgegengesetzten zweiten Seite hat, und wobei die Überzugschicht auf der ersten Seite der Zelluloseschicht gelegen ist, dadurch gekennzeichnet, dass zwischen der Zelluloseschicht und der Überzugschicht eine Maskierungsschicht vorhanden ist, wobei diese Maskierungsschicht mit einem vorgegebenen Muster versehen ist, wobei die Überzugschicht außerhalb des Musters eine Grenzoberfläche mit der Zelluloseschicht hat.
EP18164045.9A 2017-03-24 2018-03-26 Brottüte und herstellungsverfahren dazu Active EP3396065B1 (de)

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BE1026680B1 (nl) 2018-10-04 2020-05-07 Ace Packaging Nv Broodzak en werkwijze voor het vervaardigen ervan
EP3632449A1 (de) 2018-10-05 2020-04-08 Bio Minerals N.V. Kielelsäuren zur verwendung bei der behandlung von parodontitis
DE102019118425A1 (de) 2019-07-08 2021-01-14 Constantia Pirk Gmbh & Co. Kg Multifunktionales Barrierepapier und Verfahren zu dessen Herstellung
BE1027759B1 (nl) 2019-11-15 2021-06-17 Ace Packaging N V Werkwijze voor het vervaardigen van een zakvormige verpakking
BE1029333B1 (nl) * 2021-04-23 2022-11-28 Ace Packaging N V Werkwijze voor het aanbrengen van een deklaag op een verpakkingsmateriaal, en deklaagaanbrenginrichting
BE1029886B1 (nl) * 2021-10-28 2023-05-30 Ace Packaging N V Verpakkingspapier met transparante zone, werkwijze voor het vervaardigen van verpakkingspapier met transparante zone, en verpakking omvattende dergelijk verpakkingspapier

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US4773677A (en) * 1987-05-13 1988-09-27 Polaroid Corporation Unitary laminated identification card and insignia
US5639539A (en) * 1995-11-29 1997-06-17 Imperial Wallcoverings Wall covering
EP1261672A2 (de) * 1999-12-17 2002-12-04 Archer-Daniels-Midland Company Glyzeridbasierte beschichtungswachse
BE1022151B1 (nl) 2013-07-15 2016-02-19 Ace Packaging Nv Zak voor het bewaren van brood.
BE1023191B1 (nl) * 2015-05-20 2016-12-15 Ace Packaging Nv Werkwijze voor de vervaardiging van een verpakking voor brood

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