EP3371139A4 - Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein - Google Patents

Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein Download PDF

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Publication number
EP3371139A4
EP3371139A4 EP16862667.9A EP16862667A EP3371139A4 EP 3371139 A4 EP3371139 A4 EP 3371139A4 EP 16862667 A EP16862667 A EP 16862667A EP 3371139 A4 EP3371139 A4 EP 3371139A4
Authority
EP
European Patent Office
Prior art keywords
compounds
acyclic
cyclic
conversion
catalyst composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16862667.9A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP3371139A2 (en
Inventor
Larry L. Iaccino
Jeremy W. BEDARD
Karl G. Strohmaier
Machteld M. W. MERTENS
Robert T. CARR
Jane C. Cheng
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3371139A2 publication Critical patent/EP3371139A2/en
Publication of EP3371139A4 publication Critical patent/EP3371139A4/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
    • B01J29/62—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
    • B01J29/63—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7215—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L
    • C07C2529/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L containing iron group metals, noble metals or copper
    • C07C2529/62—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP16862667.9A 2015-11-04 2016-10-07 Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein Withdrawn EP3371139A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562250681P 2015-11-04 2015-11-04
EP16153721 2016-02-02
PCT/US2016/056023 WO2017078897A2 (en) 2015-11-04 2016-10-07 Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein

Publications (2)

Publication Number Publication Date
EP3371139A2 EP3371139A2 (en) 2018-09-12
EP3371139A4 true EP3371139A4 (en) 2018-09-19

Family

ID=55304862

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16862667.9A Withdrawn EP3371139A4 (en) 2015-11-04 2016-10-07 Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein

Country Status (5)

Country Link
EP (1) EP3371139A4 (ja)
JP (1) JP6824265B2 (ja)
CN (1) CN108349843A (ja)
CA (1) CA3004308C (ja)
WO (1) WO2017078897A2 (ja)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018534299A (ja) * 2015-11-04 2018-11-22 エクソンモービル ケミカル パテンツ インコーポレイテッド 非環状ｃ５化合物を環状ｃ５化合物に転化する方法およびそれに使用する触媒組成物
WO2022138746A1 (ja) * 2020-12-24 2022-06-30 Ｅｎｅｏｓ株式会社 シクロペンタジエンの製造方法

Citations (8)

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US2438404A (en) * 1948-01-20 1948-03-23 Sun Oil Co Treatment of hydrocarbons
US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
DE2535809A1 (de) * 1974-08-13 1976-03-04 Shell Int Research Verfahren zur herstellung von cyclischen c tief 5-kohlenwasserstoffen
WO1989004818A1 (en) * 1987-11-17 1989-06-01 Mobil Oil Corporation A dehydrogenation and dehydrocyclization catalyst, its synthesis and use
US4886926A (en) * 1988-06-24 1989-12-12 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
US20090062446A1 (en) * 2007-09-04 2009-03-05 General Electric Company Composition and associated method
US20130153456A1 (en) * 2011-12-15 2013-06-20 General Electric Company Containment case and method of manufacture
WO2013176712A1 (en) * 2012-05-25 2013-11-28 Exxonmobil Chemical Patents Inc. Dicyclopentadiene based resin compositions and articles manufactured therefrom

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US28341A (en) 1860-05-22 Improvement in apparatus for condensing coal-oil
US2438399A (en) 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438401A (en) 1946-02-26 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438402A (en) 1947-08-19 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438398A (en) 1947-08-19 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438403A (en) 1947-08-19 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
NL238183A (ja) 1962-08-03
NL6503410A (ja) 1963-02-21 1965-09-20
US3442795A (en) 1963-02-27 1969-05-06 Mobil Oil Corp Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom
US3308069A (en) 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US3293192A (en) 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3524820A (en) 1968-08-19 1970-08-18 Universal Oil Prod Co Preparation of rare earth metal exchanged crystalline alumino silicates
US3631209A (en) * 1970-06-22 1971-12-28 Goodyear Tire & Rubber Preparation of cycloolefins
US3766093A (en) 1972-01-07 1973-10-16 Mobil Oil Corp Treatment of organic cationcontaining zeolites
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3972832A (en) 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4246202A (en) * 1979-05-23 1981-01-20 El Paso Products Company Production of cyclic hydrocarbons from normal octenes
US4401556A (en) 1979-11-13 1983-08-30 Union Carbide Corporation Midbarrel hydrocracking
JPH03501942A (ja) * 1987-11-17 1991-05-09 モービル　オイル　コーポレーシヨン 脱水素及び脱水素環化触媒、その合成及び用途
US5192728A (en) 1988-06-24 1993-03-09 Mobil Oil Corporation Tin-colating microporous crystalline materials and their use as dehydrogenation, dehydrocyclization reforming catalysts
US5491119A (en) 1989-10-30 1996-02-13 Exxon Chemical Patents Inc. Zeolite L
CN1030329C (zh) * 1991-12-12 1995-11-22 中国石油化工总公司石油化工科学研究院 烷烃脱氢芳构化催化剂及制备方法
US5254787A (en) 1992-09-08 1993-10-19 Mobil Oil Corp. Dehydrogenation and dehydrocyclization using a non-acidic NU-87 catalyst
US9034287B2 (en) * 2013-03-13 2015-05-19 Basf Corporation Catalyst compositions, articles, methods and systems
JP2018534299A (ja) * 2015-11-04 2018-11-22 エクソンモービル ケミカル パテンツ インコーポレイテッド 非環状ｃ５化合物を環状ｃ５化合物に転化する方法およびそれに使用する触媒組成物

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438404A (en) * 1948-01-20 1948-03-23 Sun Oil Co Treatment of hydrocarbons
DE2535809A1 (de) * 1974-08-13 1976-03-04 Shell Int Research Verfahren zur herstellung von cyclischen c tief 5-kohlenwasserstoffen
WO1989004818A1 (en) * 1987-11-17 1989-06-01 Mobil Oil Corporation A dehydrogenation and dehydrocyclization catalyst, its synthesis and use
US4886926A (en) * 1988-06-24 1989-12-12 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
US20090062446A1 (en) * 2007-09-04 2009-03-05 General Electric Company Composition and associated method
US20130153456A1 (en) * 2011-12-15 2013-06-20 General Electric Company Containment case and method of manufacture
WO2013176712A1 (en) * 2012-05-25 2013-11-28 Exxonmobil Chemical Patents Inc. Dicyclopentadiene based resin compositions and articles manufactured therefrom

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
See also references of WO2017078897A2 *
V. SH. FEL'DBLYUM ET AL: "Cyclization and dehydrocyclization of C5 hydrocarbons over platinum nanocatalysts and in the presence of hydrogen sulfide", DOKLADY. CHEMISTRY, vol. 424, no. 2, February 2009 (2009-02-01), RU, pages 27 - 30, XP055267350, ISSN: 0012-5008, DOI: 10.1134/S0012500809020025 *

Also Published As

Publication number Publication date
EP3371139A2 (en) 2018-09-12
JP6824265B2 (ja) 2021-02-03
CA3004308A1 (en) 2017-05-11
WO2017078897A3 (en) 2018-03-01
CA3004308C (en) 2020-05-12
WO2017078897A2 (en) 2017-05-11
JP2019500321A (ja) 2019-01-10
CN108349843A (zh) 2018-07-31

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