EP3358575B1 - Elektrisches kabel, das resistent gegen teilentladungen ist - Google Patents
Elektrisches kabel, das resistent gegen teilentladungen ist Download PDFInfo
- Publication number
- EP3358575B1 EP3358575B1 EP18154329.9A EP18154329A EP3358575B1 EP 3358575 B1 EP3358575 B1 EP 3358575B1 EP 18154329 A EP18154329 A EP 18154329A EP 3358575 B1 EP3358575 B1 EP 3358575B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluorinated
- electrically insulating
- insulating layer
- layer
- cable according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010410 layer Substances 0.000 claims description 118
- 239000004642 Polyimide Substances 0.000 claims description 55
- 229920001721 polyimide Polymers 0.000 claims description 55
- 229920002313 fluoropolymer Polymers 0.000 claims description 31
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 28
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 28
- 239000012790 adhesive layer Substances 0.000 claims description 25
- 239000004811 fluoropolymer Substances 0.000 claims description 16
- 239000004065 semiconductor Substances 0.000 claims description 16
- 238000005245 sintering Methods 0.000 claims description 16
- -1 polytetrafluoroethylene Polymers 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 32
- 229920009441 perflouroethylene propylene Polymers 0.000 description 32
- 239000004813 Perfluoroalkoxy alkane Substances 0.000 description 8
- 229920011301 perfluoro alkoxyl alkane Polymers 0.000 description 8
- 230000007935 neutral effect Effects 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000011231 conductive filler Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 230000001955 cumulated effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001080024 Telles Species 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
- H01B3/306—Polyimides or polyesterimides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
- H01B3/445—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
- H01B7/2813—Protection against damage caused by electrical, chemical or water tree deterioration
Definitions
- the present invention relates to an electrical cable comprising an elongated electrically conductive member, an electrically insulating layer comprising polyimide (PI) surrounding said elongated electrically conductive member, and a fluorinated electrically insulating layer comprising a fluorinated polymer surrounding said electrically insulating layer comprising polyimide (PI), said layers having specific thicknesses according to the section of the elongated electrically conductive element.
- PI polyimide
- the invention typically but not exclusively applies to electrical cables used in the field of aeronautics, for example on board aircraft.
- wiring son eg more than 500 kilometers of cable in the A380
- these son comprising a conductive element surrounded by a first polyimide layer of 0.017 to 0.065 mm thick, itself surrounded by a layer of PTFE polytetrafluoroethylene with a thickness of 0.1 to 0.22 mm for conductor nominal sections ranging from 0.15 to 95 mm 2 .
- the applied voltage is of the order of 115 V (between the phase and the neutral of the three-phase system).
- the operating voltage of the aircraft cables has been increased to 230 V (between phase and neutral of the three-phase system).
- the cable mass is divided by about two.
- the relatively high voltage combined with aeronautical constraints, such as humidity, high temperature and low pressure, can generate partial discharges (DP) on electrical equipment, particularly at the surface and / or in the defects of electrical cable insulators.
- the partial discharges which are tiny electric arcs, cause over time, a degradation of the insulating material until the breakdown of the dielectric causing the possible establishment of an electric arc.
- EP 2 557 572 A1 has described an electrical cable comprising a conductive element, a layer comprising polyimide (PI) surrounding said conductive element, and a fluorinated layer comprising a fluorinated compound surrounding said layer comprising polyimide (PI), the total thickness of all fluorinated layers being at least 0.4 mm.
- the dimensions of the cable are not optimized to minimize its size and / or weight while ensuring optimal partial discharge resistance.
- the present invention aims to provide a cable that avoids all or part of the aforementioned drawbacks.
- the present invention aims to provide a cable having a footprint and / or reduced weight, while ensuring good resistance to partial discharges, especially when the cable is intended for the field of aeronautics and suffered during a flight, high temperatures (around 150 ° C), low pressures (about 145 mbar) and high voltages, such as 230 V (between phase and neutral of the three-phase system) or 400 V between phases.
- the thicknesses of the different layers of the cable of the invention are reduced, inducing a minimum weight and / or bulk in function of the diameter (ie of the section) of the elongated electrically conductive element, while guaranteeing the absence of conditions conducive to the appearance of partial discharges.
- s (in mm 2 ) is such that 0.25 ⁇ s ⁇ 85, and preferably 1 ⁇ s ⁇ 68.
- the total thickness e 1 + e 2 (in mm) is such that e 1 + e 2 ⁇ s 'x 0.00482 + 0.33012, with s' being the cross section of the electrically conductive elongated AWG element.
- AWG means "American Wire Gauge” and refers to a unit of measurement for measuring the diameter of an electrical cable.
- a table of correspondence available in the literature makes it possible to convert the section s in mm 2 in section AWG (http://www.astm.org/Standards/B258.htm, http://www.astm.org/ Standards / B286.htm ).
- s' (in AWG) is such that -2 (ie AWG000) ⁇ s' ⁇ 24 (ie AWG24), and preferably s' (in AWG) is such that -1 (ie AWG00) ⁇ s' ⁇ 10 (ie AWG10).
- the cable of the invention makes it possible to avoid partial discharges under the conventional conditions of use. It therefore preferably has a partial peak discharge threshold voltage, peak value (also well known as the PDIV for " partial discharge inception voltage ”) greater than or equal to 800 V at a pressure of 145 mbar and a temperature of 150 ° C.
- It preferably has a threshold voltage of appearance of the partial discharges, value in volts RMS (also well known under the anglicism PDIV in V RMS for " partial discharge inception voltage in voltage root mean square ”) greater than or equal to 566 V for a sinusoidal voltage, at a pressure of 145 mbar and a temperature of 150 ° C.
- the elongated electrically conductive member is preferably central.
- the fluoropolymer is preferably a polymer obtained by polymerization of monomers among which at least one of said monomers is tetrafluoroethylene or vinyl fluoride.
- the fluoropolymer may be a fluorinated homopolymer or copolymer, and preferably it is chosen from a polytetrafluoroethylene (PTFE), a poly (tetrafluoroethylene-co-hexafluoropropylene) (FEP), a perfluoro (alkylvinyl ether) copolymer / tetrafluoroethylene (PFA), a poly (ethylene-co-tetrafluoroethylene) (ETFE) and a combination thereof.
- PTFE polytetrafluoroethylene
- FEP poly (tetrafluoroethylene-co-hexafluoropropylene)
- PFA perfluoro (alkylvinyl ether) copolymer / tetrafluoroethylene
- ETFE poly (ethylene-co-tetrafluoroethylene)
- a layer is called “comprising a fluorinated polymer” when it comprises, in mass with respect to the mass of said layer, at least about 50% of fluorinated polymer (s), preferably at least 70% about fluorinated polymer (s), and even more preferably at least about 80% fluorinated polymer (s), and even more preferably about 90% fluorinated polymer (s) , such as in particular PTFE, PFA, ETFE, FEP or a combination thereof.
- fluorinated polymer such as in particular PTFE, PFA, ETFE, FEP or a combination thereof.
- the fluoropolymer is PTFE.
- the thickness e 2 (in mm) of the fluorinated electrically insulating layer comprising a fluorinated polymer, such as, for example, PTFE, PFA, ETFE, FEP or a combination thereof, is such that 0.2000 mm ⁇ e 2 ⁇ 0.4000 mm, preferably such as 0.2000 mm ⁇ e 2 ⁇ 0.3950 mm, and more preferably such that 0.2500 mm ⁇ e 2 ⁇ 0.3850 mm.
- the thickness e 2 of the fluorinated electrically insulating layer is measured after sintering of said layer. Indeed, during sintering, the fluoropolymer may lose in volume. In particular, PTFE can lose about 25% by volume.
- the thickness e 1 + e 2 is measured after sintering of said layers.
- the fluorinated electrically insulating layer is preferably sintered.
- the fluorinated electrically insulating layer may be banded and / or extruded, and preferably banded.
- the fluorinated electrically insulating layer may correspond to the winding of one or more ribbons of fluorinated polymer (s). It is then sintered to give it its mechanical properties.
- the fluorinated electrically insulating layer comprises one or more ribbons of fluorinated polymer (s), preferably one or more PTFE ribbons.
- the cable may further comprise at least one fluorinated adhesive layer comprising a fluoropolymer, the fluoropolymer included in said adhesive layer being in particular identical to or different from that included in the fluorinated electrically insulating layer.
- the fluorinated adhesive layer or layers are composed of one or more fluorinated polymers. This is called fluorinated adhesive layer.
- the fluoropolymer or polymers of the fluorinated adhesive layer are chosen from poly (tetrafluoroethylene-cohexafluoropropylene) (FEP), a perfluoro (alkyl vinyl ether) / tetrafluoroethylene (PFA) copolymer, a polytetrafluoroethylene (PTFE), a poly ( ethylene-co-tetrafluoroethylene) (ETFE) and a combination thereof, said aforementioned fluorinated compounds having adhesion properties.
- FEP poly (tetrafluoroethylene-cohexafluoropropylene)
- PFA perfluoro (alkyl vinyl ether) / tetrafluoroethylene
- PTFE polytetrafluoroethylene
- ETFE ethylene-co-tetrafluoroethylene
- At least one fluorinated adhesive layer is disposed on at least one of the two faces of the electrically insulating layer comprising polyimide.
- An adhesive layer has the function of allowing adhesion between the layers that it connects or between the elongate electrically conductive element and the layer that it connects.
- the fluororesic adhesive layer is generally capable of adhering the elongated electrically conductive element to the electrically conductive layer PI insulating material or the electrically insulating layer of PI to the fluorinated electrically insulating layer (eg layer comprising PTFE, PFA, FEP, ETFE or a combination thereof).
- the fluoropolymer or polymers of the adhesive layer undergo prior treatment that gives them their adhesive property, as is the case for the Kapton FN® product marketed by the company Dupont.
- the electrically insulating layer comprising a polyimide and the fluorinated electrically insulating layer are separated by a fluorinated adhesive layer.
- the electrically insulating layer comprising a polyimide may be covered on each of its faces with a fluorinated adhesive layer, and in particular a fluorinated ethylene propylene copolymer (FEP) coating.
- FEP fluorinated ethylene propylene copolymer
- the thickness of the fluorinated adhesive layer (e.g. FEP) can range from about 2 to 2.5 ⁇ m before sintering.
- the thickness of the electrically insulating layer comprising a polyimide may range from about 20 to 30 microns, and preferably from about 23 to 27 microns.
- the electrical cable of the invention may further comprise one or more electrically insulating layers comprising additional polyimide (PI), each of the electrically insulating layers comprising a polyimide which may be covered on each of its faces with a fluorinated adhesive layer, and in particular a fluorinated ethylene propylene copolymer (FEP) coating.
- PI polyimide
- FEP fluorinated ethylene propylene copolymer
- the thickness e 1 (in mm) as defined in the invention refers to the total thickness of the electrically insulating layers comprising polyimide (PI),
- the Kapton FN® product is suitable for the present invention. It is in the form of a ribbon comprising an electrically insulating layer of polyimide (PI) covered on each of its faces with a layer of FEP (FEP / PI / FEP).
- Two electrically insulating layers comprising a polyimide can thus be obtained by winding at least two thicknesses of said tape to overlap, and a total thickness of polyimide electrically insulating layers before sintering (or after sintering) is obtained. order of about 50 to 51 microns, and a total thickness of FEP adhesive layers before sintering (or after sintering) of the order of about 9 to 10 microns.
- the thickness of the assembly FEP / PI / EFF / FEP / PI / FEP before sintering (or after sintering) is of the order of 60 microns.
- the elongate electrically conductive element that is suitable according to the invention is, for example, of the solid or multi- stranded type .
- the elongate electrically conductive member may be copper (Cu), tin-plated Cu alloy, silver-plated Cu alloy, nickel-plated Cu alloy, aluminum (Al), nickel-plated aluminum or aluminum alloy. copper-plated and nickel-plated aluminum (well known under the Anglicism " nickel plated copper clad aluminum ").
- the elongated electrically conductive element according to the invention is preferably multi-stranded.
- the thickness e 2 designates the thickness of the fluorinated electrically insulating layer cumulated with the respective thicknesses of the other optional fluorinated layers, in particular comprising at least one fluorinated homo- or copolymer such as in particular PTFE, PFA, ETFE, FEP or a combination thereof.
- the thickness e 2 denotes the thickness of the fluorinated electrically insulating layer cumulated with the thicknesses of the fluorinated adhesive layers.
- the fluorinated electrically insulating layer is the outermost fluorinated layer of the cable.
- the cable further comprises one or more other fluorinated layers (i.e. additional fluorinated layers).
- the cable may comprise at least one additional fluorinated layer, in particular chosen from a fluorinated semiconductor layer, another fluorinated electrically insulating layer and an outer fluoride (superficial) layer capable of being labeled (ie a marking layer ), and preferably a fluorinated semiconductor layer.
- additional fluorinated layer in particular chosen from a fluorinated semiconductor layer, another fluorinated electrically insulating layer and an outer fluoride (superficial) layer capable of being labeled (ie a marking layer ), and preferably a fluorinated semiconductor layer.
- the fluorinated semiconductor layer may comprise at least one fluorinated polymer, the fluorinated compound included in said semiconductor layer being in particular identical to or different from that included in the fluorinated electrically insulating layer.
- the fluorinated semiconductor layer may be in the form of a ribbon, an extrudate, a varnish, or a combination thereof.
- a layer is semiconductive when its electrical conductivity is at least 0.001 Sm -1 (siemens per meter).
- the fluorinated semiconductor layer when in the form of a ribbon or extrudate, it may be composed of at least one fluorinated polymer or copolymer and from 0.1% to 40% by weight approximately charging (electrically) conductive, with respect to the total mass of said fluorinated semiconductor layer.
- the fluorinated semiconductor layer When the fluorinated semiconductor layer is in the form of a varnish, it may be composed of at least one fluorinated polymer or copolymer, of the FEP, PFA or PTFE dispersions type, and from 0.1% to About 40% by weight of (electrically) conductive filler, based on the total mass of said fluorinated semiconductor layer.
- the fluorinated semiconductor layer comprises at least about 10% by mass of electrically conductive filler, and even more preferably at least about 25% by mass of electrically charged filler. conductive, relative to the total mass of said fluorinated semiconductor layer.
- the electrically conductive filler may advantageously be chosen from carbon blacks, carbon nanotubes and a mixture thereof.
- the fluorinated semiconductor layer has a longitudinal resistivity of 0.04 to 100 Ohm.m, and preferably 0.06 to 0.6 Ohm.m.
- the outer layer (surface) capable of being marked may be in the form of a ribbon, an extrudate or a varnish. It may in particular comprise at least one fluorinated polymer or copolymer, such as, for example, PTFE, FEP, PFA, ETFE, and at least one metal complex-type pigment.
- the thickness e 2 denotes the thickness of the fluorinated electrically insulating layer cumulated with the thicknesses of the other fluorinated layers such as those mentioned above (layer of fluorinated marking, fluorinated semiconductor layer, other fluorinated electrically insulating layer, etc ).
- the other fluorinated layers of the cable of the invention are preferably sintered (e.g. fluoridated adhesive layer (s)).
- the electrically insulating layer comprising polyimide may be made by taping (winding a polyimide tape), by coating varnish (mixture of components polymerizing in situ ) or by extrusion, according to techniques known to those skilled in the art.
- the cable comprising the above-mentioned characteristics is intended to be used in the field of aeronautics, in particular at 230 V (between the phase and the neutral of the three-phase system) and is in particular intended to equip the aircraft.
- the figure 1 illustrates a cross-sectional view of an electrical cable at the insulation stage (without sheath) according to a preferred embodiment of the invention.
- the hook up wire or the power cable 1, shown in FIG. figure 1 comprises: a central elongate electrically conductive element 2, in particular of copper or aluminum, of multi-stranded type, and, successively and coaxially around this central elongated electrically conductive element 2, a first FEP adhesive layer 5a, an electrically insulating layer of polyimide (PI) 3, a second FEP adhesive layer 5b and an electrically insulating PTFE layer 4, here representing the outer layer of the cable 1.
- the various layers are obtained by taping.
- the cable is then heat-treated to sinter the outer layer of PTFE. For this, a temperature above 340 ° C is applied.
- the FEP / PI / FEP assembly preferably corresponds to Kapton FN® tape from Dupont comprising a 25.4 ⁇ m thick layer of PI coated on each of its faces with a 2.5 ⁇ m FEP layer. thick before sintering.
- the electrical cable thus isolated is heat-treated in an oven at a temperature above the melting temperature of the PTFE, ie at a temperature above 340 ° C, for obtain sintering of PTFE and layers of FEP.
- this single heat treatment step which includes the heat-sealing step of the polyimide and the sintering step of PTFE and FEP layers, it ensures the adhesion of all the thicknesses of ribbons.
- the heat treatment leads to the cohesion of the electrically insulating layer of PTFE on the electrically insulating layer PI and the bonding of the electrically insulating layer PI on itself and on the elongated electrically conductive element.
- Table 1 two cables according to the invention are illustrated and for comparison two cables as described in FIG. EP 2 557 572 A1 , with for each of the cables the total thickness of the electrically insulating layers of PI after sintering, the thickness of the fluorinated layers after sintering (adhesive layers and electrically insulative fluorinated layer), their section in mm 2 and in AWG (which corresponds to the most close to the section in mm 2 for multi-strand conductors) and their emergence voltage of PDIV discharges in V RMS.
- two layers of Kapton FN® ribbon from Dupont were used for overlap.
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Insulated Conductors (AREA)
- Organic Insulating Materials (AREA)
- Laminated Bodies (AREA)
Claims (14)
- Elektrisches Kabel (1) umfassend:- ein längliches elektrisch leitendes Element (2) mit einem Querschnitt s (en mm2),- eine elektrisch isolierende Schicht, umfassend Polyimid (PI) (3), die das längliche elektrisch leitende Element (2) umgibt und eine Stärke e1 (in mm) hat, und- eine fluorierte elektrisch isolierende Schicht, umfassend ein fluoriertes Polymer (4), die die elektrisch isolierende Schicht umgibt, die Polyimid (PI) (3) umfasst,dadurch gekennzeichnet, dass die Stärke e2 (in mm) der fluorierten elektrisch isolierenden Schicht unter 0,4000 mm beträgt und die Gesamtstärke e1 + e2 (in mm) derart ist, dass e1 + e2 ≥ -0,02140 x In (s) + 0,41613 ist.
- Elektrisches Kabel nach Anspruch 1, dadurch gekennzeichnet, dass s derart ist, dass 0,25 ≤ s ≤ 85 ist.
- Elektrisches Kabel nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass es eine Schwellenspannung aufweist, bei der Teilentladungen vorkommen, Wert in Volt RMS über oder gleich 566 V bei einem Druck von 145 mbar und einer Temperatur von 150 °C.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das fluorierte Polymere aus einem Polytetrafluorethylen (PTFE), einem Poly(tetrafluorethylen-co-hexafluorpropylen) (FEP), einem Copolymer Perfluor(alkyvinylether)/Tetrafluorethylen (PFA), einem Poly(ethylen-co-tetrafluorethylen) (ETFE) und einer ihrer Kombinationen ausgewählt ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das fluorierte Polymer das PTFE ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die Stärke e2 der fluorierten elektrisch isolierenden Schicht, die ein fluoriertes Polymer (4) umfasst, derart ist, dass 0,2000 mm ≤ e2 ≤ 0,3950 mm ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die Stärke e2 der fluorierten elektrisch isolierenden Schicht (4) nach Sintern der Schicht gemessen wird.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die fluorierte elektrisch isolierende Schicht (4) bandagiert ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass es ferner mindestens eine fluorierte Haftschicht umfasst, umfassend ein fluoriertes Polymer (5a, 5b), wobei das fluorierte Polymer, das in der Haftschicht (5a, 5b) enthalten ist, identisch mit oder unterschiedlich von dem ist, das in der fluorierten elektrisch isolierenden Schicht (4) enthalten ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die elektrisch isolierende Schicht, die ein Polyimid (3) umfasst, auf jeder ihrer Seiten mit einer fluorierten Haftschicht (5a, 5b) bedeckt ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass das längliche elektrisch leitende Element (2) Kupfer (Cu), einer verzinnten Cu-Legierung, einer versilberten Cu-Legierung, einer vernickelten Cu-Legierung, Aluminium (Al), vernickeltem Aluminium oder verkupfertem und vernickeltem Aluminium entspricht.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass die fluorierte elektrisch isolierende Schicht (4) gesintert ist.
- Elektrisches Kabel nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, dass es ferner mindestens eine fluorierte halbleitende Schicht umfasst.
- Elektrisches Kabel nach Anspruch 13, dadurch gekennzeichnet, dass die fluorierte halbleitende Schicht mindestens ein fluoriertes Polymer umfasst, wobei die fluorierte Verbindung, die in der halbleitenden Schicht enthalten ist, mit der identisch ist, die in der fluorierten elektrisch isolierenden Schicht (4) enthalten ist, oder sich davon unterscheidet.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1750942A FR3062748B1 (fr) | 2017-02-03 | 2017-02-03 | Cable electrique resistant aux decharges partielles |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3358575A1 EP3358575A1 (de) | 2018-08-08 |
EP3358575B1 true EP3358575B1 (de) | 2019-11-06 |
Family
ID=59031067
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18154329.9A Active EP3358575B1 (de) | 2017-02-03 | 2018-01-31 | Elektrisches kabel, das resistent gegen teilentladungen ist |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3358575B1 (de) |
FR (1) | FR3062748B1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202020005038U1 (de) * | 2019-12-11 | 2021-03-12 | Hew-Kabel Gmbh | Isoliertes elektrisch leitfähiges Element |
FR3113979A1 (fr) * | 2020-09-04 | 2022-03-11 | Nexans | Câble électrique limitant les décharges partielles |
FR3123138A1 (fr) * | 2021-05-21 | 2022-11-25 | Nexans | Câble électrique limitant les décharges partielles |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE375594T1 (de) * | 2001-04-17 | 2007-10-15 | Judd Wire Inc | Mehrschichtiges isolationssystem für elektrische leiter |
FR2921511B1 (fr) * | 2007-09-21 | 2010-03-12 | Nexans | Cable electrique resistant a la propagation d'arc electrique |
FR2979032B1 (fr) * | 2011-08-09 | 2013-07-26 | Nexans | Cable electrique resistant aux decharges partielles |
-
2017
- 2017-02-03 FR FR1750942A patent/FR3062748B1/fr not_active Expired - Fee Related
-
2018
- 2018-01-31 EP EP18154329.9A patent/EP3358575B1/de active Active
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
FR3062748B1 (fr) | 2019-04-05 |
FR3062748A1 (fr) | 2018-08-10 |
EP3358575A1 (de) | 2018-08-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2557572B1 (de) | Teilentladungsbeständiges elektrisches kabel | |
EP2571688B1 (de) | Hochtemperaturisolierband und damit ummantelter draht oder kabel | |
EP2765581B1 (de) | Elektrisches Kabel, das resistent gegen Teilentladungen ist | |
US9208925B2 (en) | High performance, high temperature wire or cable | |
EP2445716B1 (de) | Leichtgewichtige hochtemperaturbeständige leistungsstarke folie, band oder ummantelung für drahtisolierung | |
EP2040267B1 (de) | Stromkabel, das gegen die fortpflanzung von lichtbögen resistent ist | |
EP3358575B1 (de) | Elektrisches kabel, das resistent gegen teilentladungen ist | |
US20060137898A1 (en) | Electrical cables | |
GB2492087A (en) | High temperature and flame resistant insulating tape for wire or cable | |
EP3398194A1 (de) | Feuerbeständige isolierschicht für ein kabel | |
EP3422366A1 (de) | Kabel, das ein elektrisch leitendes element umfasst, das metallisierte karbonfasern enthält | |
EP3764372A1 (de) | Kabel, das eine feuerbeständige schicht umfasst | |
EP2015316A2 (de) | Elektrischer Signalübertragungsdraht für die Luft- und Raumfahrtindustrie | |
EP2783372B1 (de) | Hochspannungsstromkabel für extreme bedingungen | |
EP4092689A1 (de) | Elektrisches kabel, das teilentladungen begrenzt | |
EP3965123A1 (de) | Elektrisches kabel für die luftfahrtindustrie | |
EP3965124A1 (de) | Elektrisches kabel, das teilentladungen begrenzt | |
FR3086791A1 (fr) | Ame conductrice multibrin carbonee-metallique pour cable electrique |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20190208 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: H01B 3/30 20060101ALI20190429BHEP Ipc: H01B 7/28 20060101AFI20190429BHEP Ipc: H01B 7/29 20060101ALI20190429BHEP Ipc: H01B 3/44 20060101ALI20190429BHEP |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20190612 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP Ref country code: AT Ref legal event code: REF Ref document number: 1199921 Country of ref document: AT Kind code of ref document: T Effective date: 20191115 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602018001054 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20191106 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200206 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200306 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200206 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200207 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200306 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602018001054 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1199921 Country of ref document: AT Kind code of ref document: T Effective date: 20191106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20200807 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20200131 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200131 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200131 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200131 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210131 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210131 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191106 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230124 Year of fee payment: 6 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240119 Year of fee payment: 7 Ref country code: GB Payment date: 20240119 Year of fee payment: 7 |