EP3356478A1 - Composition d'encre destinée à être utilisée sur des surfaces non absorbantes - Google Patents

Composition d'encre destinée à être utilisée sur des surfaces non absorbantes

Info

Publication number
EP3356478A1
EP3356478A1 EP15779148.4A EP15779148A EP3356478A1 EP 3356478 A1 EP3356478 A1 EP 3356478A1 EP 15779148 A EP15779148 A EP 15779148A EP 3356478 A1 EP3356478 A1 EP 3356478A1
Authority
EP
European Patent Office
Prior art keywords
ink
weight
aqueous ink
aqueous
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15779148.4A
Other languages
German (de)
English (en)
Inventor
Stanley Litman
Pamela Geddes
Morgan EDWARDS
Michael Carson
Kevin J. Hook
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RR Donnelley and Sons Co
Original Assignee
RR Donnelley and Sons Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RR Donnelley and Sons Co filed Critical RR Donnelley and Sons Co
Publication of EP3356478A1 publication Critical patent/EP3356478A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat

Definitions

  • the present subject matter relates generally to ink compositions, and more particularly, to ink compositions used in a printing system that enables high-speed printing on non-absorbent surfaces.
  • Aqueous inks have been used in the printing industry for limited commercial print applications.
  • An increase in the use of aqueous inks is due in part to environmental concerns about volatile organic compounds (VOC's) that solvent based inks emit when dried.
  • VOC's volatile organic compounds
  • the water is partially absorbed by the surface and this makes drying the ink after printing quicker.
  • the use of aqueous based inks sometimes can create performance issues and also, it is more difficult to quickly dry these inks when the ink sits on top of the surface.
  • Non-absorbent surfaces that keep the water based vehicle on the surface include plastic films, metal films, and similar surfaces. In these surfaces, the printed material is heat treated to remove the vehicle or exposed to ultraviolet light after printing, but if the physical properties of the ink composition do not assist in the adherence of the ink to the surface, there will be poor performance of the ink during and after printing. Under such circumstances, it is desirable for the images on the non-absorbent surface to have long term durability.
  • Long term durability refers to the ability of the ink to remain on the final product and resist water exposure, highlighting, rubbing, scratching, and other abrasions.
  • Long term durability refers to the ability of the ink to remain on the final product and resist water exposure, highlighting, rubbing, scratching, and other abrasions.
  • the ink During printing, there is a tendency for the ink to be disturbed by shear stresses as the printed product moves through subsequent cylinders and/or other elements of the high speed printing press.
  • an aqueous ink comprising: from about 3 to about 15% by weight of one or more polymers; from about 0.5 to about 12% by weight of one or more colorants; from about 5 to about 35% by weight of a solvent; from about 0.03 to about 1.0% by weight of a pH modifier; and from about 50 to about 80% by weight of water, wherein the aqueous ink has a viscosity from about 1 to about 20 mPa-s such that the aqueous ink can be applied to a non-absorbent surface in a layer.
  • Aspect 2 the aqueous ink of aspect 1, wherein the viscosity is from about 4 to about 14 mPa-s.
  • Aspect 3 the aqueous ink of any of aspects 1 and 2, wherein one of the one or more polymers is a urethane silanol.
  • Aspect 4 the aqueous ink of any of aspects 1 through 3, further comprising from about 0.1 to about 5% by weight of a surfactant.
  • Aspect 5 the aqueous ink of any of aspects 1 through 4, further comprising from about 1 to about 20% by weight of a crosslinker.
  • Aspect 6 the aqueous ink of any of aspects 1 through 5, wherein the crosslinker is an iso-cyanate crosslinker.
  • Aspect 7 the aqueous ink of any of aspects 1 through 6, wherein one of the one or more polymers is a self-crosslinking urethane silanol.
  • Aspect 8 the aqueous ink of any of aspects 1 through 7, wherein the solvent is chosen from the group consisting of l-(2-hydroxyethyl)-2-pyrrolidone, alcohols, polyols, glycerols, and glycols.
  • Aspect 9 the aqueous ink of aspect 5, wherein the surfactant is an ethoxylated molecule.
  • Aspect 10 the aqueous ink of any of aspects 1 through 9, wherein the pH modifier is dimethylethanolamine.
  • Aspect 1 1 the aqueous ink of any of aspects 1 through 10, wherein the ink has a dynamic surface tension at 25 degrees Celsius from about 20 to about 45 dynes/cm.
  • Aspect 12 an ink comprising: from about 0.5 to about 10% by weight of an epoxy resin; from about 4 to about 30% by weight of a solvent; and one or more metallic colorants, wherein the ink has a viscosity from about 1 to about 20 mPa-s such that the ink can be applied to a non-absorbent surface in a layer.
  • Aspect 13 the ink of aspect 12, wherein the viscosity is from about 4 to about 14 mPa-s.
  • Aspect 14 the ink of any of aspects 1277 and 13, wherein the solvent is dimethyl sulfoxide.
  • Aspect 15 the ink of any of aspects 12 through 14, wherein the epoxy resin is a bisphenol A epoxy resin.
  • Aspect 16 the ink of any of aspects 12 through 15, wherein the ink has a dynamic surface tension at 25 degrees Celsius from about 20 to about 35 dynes/cm.
  • Aspect 17 a method for high speed variable printing comprising the steps of: providing an aqueous ink, the aqueous ink comprising: from about 3 to about 15% by weight of one or more polymers; from about 0.5 to about 12% by weight of a pigment; from about 5 to about 35% by weight of a solvent; from about 0.03 to about 1.0% by weight of a pH modifier; and from about 50 to about 80% by weight of water, wherein the aqueous ink has a viscosity from about 1 to about 20 mPa-s; and applying the aqueous ink onto a non-absorbent substrate in a first layer.
  • Aspect 18 the method of aspect 17, the method further comprising the step of applying the aqueous ink in a plurality of further layers.
  • Aspect 19 the method of any of aspects 17 and 18, wherein the aqueous ink further comprises from about 0.1 to about 5.0% by weight of a surfactant.
  • Aspect 20 the method of any of aspects 17 through 19, the method further comprising the step of applying heat to crosslink the one or more polymers of the aqueous ink.
  • an ink composition includes a colorant, one or more polymers comprising polyurethane siloxane, water, and a solvent.
  • the ink composition has a total solids content of less than about 20 percent by weight. Further, the ink has an initial surface tension of less than about 50 dynes per centimeter on application and the surface tension on drying should not increase by more than 20 percent.
  • an ink composition adapted to be applied to a non-absorbent surface includes from about 0.5 percent to about 12 percent by weight of a colorant, from about 3 percent to about 15 percent by weight of a polyurethane siloxane, and an aqueous based solvent. Further the ink has an initial surface tension of less than about 50 dynes per centimeter on application and the surface tension on drying should not increase by more than 20 percent.
  • an ink composition includes a colorant, an epoxy resin, and an aprotic solvent.
  • the ink may additionally include a metallic pigment and have an initial surface tension of less than about 40 dynes per centimeter on application and the surface tension on drying should not increase by more than 20 percent.
  • An ink composition of the present application includes a colorant, a polyurethane siloxane, a solvent, water, and optionally a crosslinker.
  • the ink composition has a total solids content of less than about 20% by weight, and a ratio of colorant to polyurethane between about 2: 1 and 1 :2 by weight. Further the ink has an initial surface tension of less than about 50 dynes per centimeter on application and the surface tension on drying should not increase by more than 20%.
  • Such ink composition is suitable for use in a variety of high-speed printing systems.
  • a non-absorbent print medium such as metal foils, ceramics, plastics, highly coated papers or other similar substrates, receives ink using a variety of printing methods.
  • the ink composition has a viscosity such that the ink composition can be applied to a substrate using a variety of printing methods.
  • the viscosity may range from about 1.0 to 20.0 cP, preferably from about 4.0 cP to about 6.0 cP, although the preferred viscosity may depend in part on the requirements of the print system to be used.
  • the initial surface tension of the ink be less than 50 dynes/cm. At this surface tension the ink will properly spread on the non-absorbent surface. It is preferred that the surface tension be less than 40 dynes/cm.
  • Another important aspect is that on drying the surface tension of the ink not increase dramatically. It has been found that if the surface tension changes too greatly upon drying, the physical properties of the ink on the non-absorbent surface are degraded. In particular, the solvent resistance, the rub resistance and leveling of the ink on the non-absorbent surface are not satisfactory if the surface tension changes too much, more than 20%, on drying.
  • Suitable surface active agents to provide the above surface tension properties include nonionic compounds comprised of silicone, ethylene oxide (EO), and propylene oxide (PO) such as Silwet Hydrostable 212, available from Momentive Performance Products (Albany, New York), fluorinated nonionics such as Multiwet VE- LQ-(AP), available from Croda Industrial Chemicals (East Yorkshire, England) and the like. These surface active agents can be present in amounts ranging from about 0.1 to 3.0% by weight, more preferably less than 1.0% by weight.
  • the surfactant or surface modifying agent may include, for example, nonionic surfactants, such as poloxamer, ethoxylated acetylenediol, ethoxylated alcohols, or other ethoxylated surfactants. Any type of surfactant may be useful to include in the ink composition to impart the desired properties including anionic, nonionic, cationic, or other types of surfactants.
  • leveling agents also can act as surface modifying agents in an amount of up to about 2.5% by weight.
  • ethoxylated acetylenediol based surfactants suitable for use include
  • Air Products' Surfynol® 400 series surfactants Surfynol® 420, 440, 465, and 485, respectively.
  • the Surfynol® 400 series surfactants by Air Products (Allentown, PA) are produced by reacting various amounts of ethylene oxide with 2,4,7,9-tetra-methyl-5- decyne-4,7-diol (Air Products' Surfynol® 104), a nonionic molecule with a hydrophilic section in the middle of two symmetric hydrophobic groups.
  • ethoxylated alcohols based surfactants suitable for use include
  • Tomadol® series surfactants by Air Products (Allentown, PA). Tomadol® ethoxylated alcohols are produced by a base-catalyzed condensation reaction of ethylene oxide with an alcohols of varying chain lengths ranging from C9 to Ci 5 .
  • the ink composition may be printed in a heated environment of about 120 degrees Fahrenheit (-50 degrees Celsius).
  • the ink composition may be printed onto a substrate and heated by a platen.
  • the platen may be heated to a temperature of about 100 degrees Fahrenheit (-40 degrees Celsius) or to a temperature of about 120 degrees Fahrenheit (-50 degrees Celsius).
  • the substrate is then heated to a temperature greater than 220 degrees Fahrenheit (-100 degrees Celsius) for about ten minutes to unblock and enable crosslinking.
  • the ink is then cured at about 300 degrees Fahrenheit (-150 degrees Celsius) for ten minutes.
  • Appropriate thickness is achieved by printing multiple layers prior to curing.
  • the ink composition may be disposed in a layer having a thickness in the range from about 5 microns to about 15 microns.
  • the desired ink thickness may be obtained by printing a number of layers of ink onto the substrate.
  • the thickness may be obtained by printing up to about 50 layers, preferably up to about 30 layers, and more preferably up to about 15 layers of ink over the substrate, although the number of layers depends on various factors such as, for example, selection of the means for applying the ink, fluid solids content of the ink composition, and mass flow rate.
  • the polymer acts as a binder to stabilize the colorant on the print medium and provides increased long term durability of a final product. Immediate durability refers to the ability of the ink composition to bond to the print medium quickly and move through a high speed printing press without transferring to elements of the press.
  • Suitable polymers for the ink composition of the present application include urethane resin emulsions having a silanol group or a group capable of preparing a silanol group by hydrolysis, such urethane resins include Takelac® WS-5000, Takelac® WS-5100, Takelac® WS-4000, and Takelac® WS-6021, manufactured by Mitsui Chemicals, Inc. (Tokyo, Japan). These are self-crosslinking polyurethane dispersions that form siloxane bonds with the evaporation of water. Polymers may be self- crosslinking through heat and/or hydrolysis. Polymers may also be crosslinked via one or more crosslinkers or catalysts.
  • suitable crosslinkers include blocked isocyanates wherein the application of heat enables crosslinking.
  • a suitable crosslinker is Trixene® Aqua BI 201 by Baxenden Chemicals Limited (Lancashire, England). This crosslinker becomes unblocked between 110 and 120 degrees Celsius.
  • Certain embodiments comprise an epoxy binder.
  • Suitable epoxy resins include DER 684-EK40 by Dow Chemical Company (Midland, Michigan). This resin is formed by reacting epichlorohydrin with bisphenol A to form diglycidyl ethers of bisphenol A.
  • the colorant may be any conventional pigment or dye commercially available.
  • suitable colorants include but, are not limited to, carbon black colorant such as Pro- Jet® Black APD1000 by FujiFilm (New Castle, DE), magenta colorant such as Cab-O-Jet® 465 by Cabot Corp. (Boston, MA), cyan colorant such as Cab-O-Jet® 450 or 452 by Cabot Corp. (Boston, MA), or yellow colorant such as Cab-O- Jet® 470 by Cabot Corp. (Boston, MA) visibly opaque infra-red transmitting dyes such as Epolight 7527A by Epolin, Inc.
  • Visibly opaque infra-red transmitting dyes such as Epolight 7527A, should transmit greater than 80% of light having a wavelength greater than 850 nm and should transmit between 5 and 15% of light having a wavelengths less than 550 nm.
  • the total solids content of the ink composition is less than about 20% by weight.
  • the ink composition may include about 0.5 to about 12 percent by weight of a colorant and about 3 to about 15 percent by weight of a polymer (polyurethane siloxane) and crosslinker.
  • the ratio of colorant to polymer and crosslinker may range from about 2: 1 to about 1 :2.
  • the ink composition of the present application may include water as a solvent.
  • the composition may also include a water-soluble organic compound as a co- solvent.
  • Suitable water-soluble or miscible organic components include: glycerin; alcohols, such as methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n- butyl alcohol, sec-butyl alcohol, or tert-butyl alcohol; amides, such as dimethylformamide or dimethylacetamide; carboxylic acids; esters, such as ethyl acetate, methyl lactate, ethyl lactate, propyl lactate and ethylene carbonate; ethers, such as 2- butoxyethanol, tetrahydrofuran or dioxane; glycols, such as propylene glycol, and diethylene glycol; glycol esters; glycol ethers, such as propylene glycol methyl ether, dipropylene glycol methyl ether; ketones
  • Additional contemplated components in the ink composition include a solvent, a preservative such as Proxel® GXL by Arch Biocides (Smyrna, GA), a humectant (e.g. propylene glycol), a biocide, a colorant, a polymer, a leveling agent, a salt, an inorganic compound, an organic compound, water, a viscosity adjuster such as Walocel® CRT 30 by Dow Chemical Company (Midland, MI), a pH modifier such as diethanolamine or triethanolamine, and/or any combination thereof.
  • a solvent such as Proxel® GXL by Arch Biocides (Smyrna, GA), a humectant (e.g. propylene glycol), a biocide, a colorant, a polymer, a leveling agent, a salt, an inorganic compound, an organic compound, water, a viscosity adjuster such as Walocel® CRT 30 by
  • Example 1 A black ink composition useful in the present disclosure was prepared having the following formulation:
  • pH modifier dimethylethanolamine
  • HEP hydroxyethyl pyrrolidone
  • Viscosity of the ink at 32 degrees Celsius was 5.13 cP and the pH was 5.
  • Example 2 A black infrared transmitting ink composition useful in the present disclosure was prepared having the following formulation:
  • humectant (2 -hydroxyethyl pyrrolidone)
  • colloidal silica dispersion (Ludox® AS-40) (40% solids)
  • visibly opaque IR transmitting dye solution (20% Epolight 7527A in hydroxyethyl pyrrolidone solution)
  • pH modifier dimethylethanolamine
  • the dye solution and HEP were vigorously mixed and the polymer was added very slowly. After a period of vigorous mixing, the deionized water was added. Subsequently, the pH modifier was added and later the crosslinker was added. After a period of mixing, the silica dispersion was added and after an additional period of vigorous mixing, the ink was filtered.
  • Viscosity of the ink at 32 degrees Celsius was 4.50 cP and the pH was
  • Example 3 A first white ink composition useful in the present disclosure was prepared having the following formulation: 33.7 % by weight deionized water,
  • the titanium oxide dispersion and the silica dispersion were mildly mixed and the polymer and crosslinker were added very slowly. After mild mixing, the deionized water, HEP, and preservative were added, after another period of mild mixing, the pH modifier was added. Then, the surfactant was added, and after mixing, the ink was filtered.
  • the ink composition was 16.4% solids. Viscosity of the liquid ink at 32 degrees Celsius was 4.92 cP and the pH was 9.2. Surface tension at 25 degrees Celsius was 43.68 dynes/cm.
  • Example 4 A second white ink composition useful in the present disclosure was prepared having the following formulation:
  • humectant ethylene glycol
  • the ink composition was 14.7% solids. Viscosity of the liquid ink at 32 degrees Celsius was 6.03 cP and the pH was 8.6. Surface tension at 25 degrees Celsius was 31.44 dynes/cm.
  • Example 5 A metallic ink composition useful in the present disclosure was prepared having the following formulation:
  • the aluminum dispersion, the polymer, and the aprotic solvent were mildly mixed. After a period of mild mixing, the ink was filtered.
  • the ink composition was 4% solids. Viscosity of the ink at 32 degrees

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

Selon un aspect de l'invention, une composition d'encre comprend un colorant, un ou plusieurs polymères tels qu'un siloxane de polyuréthane, un tensioactif, de l'eau et un solvant. La composition d'encre présente une teneur totale en matières solides inférieure à environ 20 % en poids. En outre, l'encre présente une tension de surface initiale inférieure à environ 50 dynes par centimètre lors de l'application et la tension de surface lors du séchage ne doit pas augmenter de plus de 20 %.
EP15779148.4A 2015-10-01 2015-10-01 Composition d'encre destinée à être utilisée sur des surfaces non absorbantes Withdrawn EP3356478A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2015/053544 WO2017058233A1 (fr) 2015-10-01 2015-10-01 Composition d'encre destinée à être utilisée sur des surfaces non absorbantes

Publications (1)

Publication Number Publication Date
EP3356478A1 true EP3356478A1 (fr) 2018-08-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP15779148.4A Withdrawn EP3356478A1 (fr) 2015-10-01 2015-10-01 Composition d'encre destinée à être utilisée sur des surfaces non absorbantes

Country Status (3)

Country Link
EP (1) EP3356478A1 (fr)
CN (1) CN108137966A (fr)
WO (1) WO2017058233A1 (fr)

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US20030055135A1 (en) * 2001-09-17 2003-03-20 Westvaco Corporation Pigmented ink jet inks
KR100808250B1 (ko) * 2006-06-14 2008-02-29 삼성전자주식회사 잉크조성물, 이를 포함한 잉크조성물 카트리지
KR101156889B1 (ko) * 2006-09-15 2012-06-21 가부시키가이샤 리코 기록용 잉크, 잉크젯 기록 방법 및 잉크젯 기록 장치
US7927416B2 (en) * 2006-10-31 2011-04-19 Sensient Colors Inc. Modified pigments and methods for making and using the same
ATE520536T1 (de) * 2007-08-20 2011-09-15 Moore Wallace North America Verfahren und vorrichtung für tintenstrahldruck
JP5459460B2 (ja) * 2007-12-05 2014-04-02 セイコーエプソン株式会社 インクジェット用水性白色インク組成物およびこれを用いた記録物
US20090306285A1 (en) * 2008-05-08 2009-12-10 E.I.Du Pont De Nemours And Company Inkjet inks containing crosslinked polyurethanes
JP2011153180A (ja) * 2010-01-26 2011-08-11 Seiko Epson Corp 白色インク組成物
JP5837765B2 (ja) * 2011-06-02 2015-12-24 株式会社松井色素化学工業所 インクジェット捺染用インク
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JP2014019842A (ja) * 2012-07-23 2014-02-03 Seiko Epson Corp インクジェット組成物、インクジェット記録装置、および記録物
JP6472947B2 (ja) * 2013-10-25 2019-02-20 セイコーエプソン株式会社 インクジェットインク組成物、記録方法、及び記録物
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Also Published As

Publication number Publication date
WO2017058233A1 (fr) 2017-04-06
CN108137966A (zh) 2018-06-08

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