EP3288524A1

EP3288524A1 - Skin care preparation

Info

Publication number: EP3288524A1
Application number: EP16715301.4A
Authority: EP
Inventors: Stefanie Hentrey; Kerstin Heike; Jane Djamil; Kathrin BORCHERS; Christiane Meyer
Original assignee: Beiersdorf AG
Current assignee: Beiersdorf AG
Priority date: 2015-04-27
Filing date: 2016-04-08
Publication date: 2018-03-07
Also published as: WO2016173824A1; DE102015207624A1

Abstract

The invention relates to cosmetic or dermatological preparations comprising an oil and a water phase, in which sodium polyacrylate is dispersed in the oil phase and the water phase comprises one or a maximum of two gel formers. No emulsifiers, no surfactants and no celluloses are contained in the preparation. Said cosmetic or dermatological preparations can be used on a wet or moist skin, in particular in the face, and impart a conditioned feeling.

Description

Skin care preparation

The invention is a cosmetic or dermatological preparation comprising an oil and a water phase. In the oil phase, sodium polyacrylate is dispersed and the

Water phase comprises one or at most two gelling agents. Emulsifiers, surfactants and

Celluloses are not included in the formulation, as are none

Acrylates / Alkyl Acrylates Crosspolymers.

A characteristic of cosmetic products, which is very important for consumers but difficult to quantify, is their texture and sensor technology. The term "texture" is understood to mean those properties of a cosmetic which can be traced back to the structure of the preparation, can be sensed by tactile and tactile sensations and, if appropriate, expressed in mechanical or rheological flow properties. The texture can be tested in particular by means of sensors. The texture of cosmetic products, which optionally can be influenced with the aid of additives, is of almost the same significance for the consumer as their objectively ascertainable effects.

The term "sensorics" refers to the scientific discipline that deals with the evaluation of cosmetic preparations based on sensory impressions. The sensory evaluation of a cosmetic is based on the visual, olfactory and haptic impressions.

• Visual impressions: all features perceptible with the eye (color, shape, structure).

• Olfactory impressions: all perceptible when inhaling air through the nose

Olfactory impressions, which can often be differentiated into initial odor (head note), main odor (middle note, body) and after-odor (ending). The volatiles released only after use also contribute to the olfactory impression.

• Haptic impressions: all sensations of the sense of touch, the predominantly structure and

Consistency of the product.

The sensory analysis makes use of the possibility, the sensory

Integral overall impression of a product. Disadvantages of the sensory analysis are the subjectivity of the impression, an easy influenceability of the test persons and the resulting strong dispersion of the results. These weaknesses are today countered by the use of groups of trained test persons, mutual screening of the examiners and statistical analysis of the most numerous analysis data.

An object of the present invention is therefore to provide preparations which, in addition to the customary for cosmetics criteria such as compatibility, storage stability and the like also provide the consumer so far unknown cosmetic, especially sensory, benefits. In particular, the preparations sought should be suitable for use in the personal care sector and should be sensory-attractive, in particular, for use in the face or neck.

A problem in the manufacture of care products has been the use of

Emulsifiers. So that both hydrating and oil-containing, caring components can be used, emulsifiers are often used. Without emulsifiers water and oil could not mix permanently. However, emulsifiers are known to "wash out" lipids from the skin, further enhancing their ability to deliver lipids

Dehydration of the skin.

In the prior art this is countered by describing a so-called. Bi-gel technology that is free of emulsifiers.

The elimination of emulsifiers in bi-gel technology is achieved by mixing two gels. One of the gels contains more water and the other more oils. The

Stability of the mixture is ensured by the fact that, on the one hand, gels already have internal stability due to their higher strength. In addition, long-chain polysaccharides are used to form the oily gel as tiny globules in the

embedded hydrous gel.

Generally, bi-gels are formed by a mixture of certain oleogels comprising a variety of oils and cellulosic polymers with certain carbomer-based aqueous gels. The weight ratios between oil and water phase are in the range between 5/95 to 40/60. In principle, these bi-gels, according to their appearance and the relatively firm consistency, are an O / W cream without the use of any surfactants or emulsifiers.

EP 1 083 880 B1 discloses the use of cellulosic polymers, e.g. Ethylcellulose, described in stable gel mixtures consisting of an oleogel and an aqueous gel.

Polysaccharides (also called multiple sugars, multiple sugars, glycans / glycans or polyoses) are carbohydrates in which a large number (at least ten)

Monosaccharides (simple sugars) are linked via a glycosidic bond. These are biopolymers from an unknown number of monosaccharide units or with statistical molecular size distribution. Examples of polysaccharides are glycogen, starch (amylose and amylopectin), pectins, chitin, callose and cellulose. Tapioca or tapioca starch is an almost tasteless starch, which is made from the processed and dried cassava root (cassava).

In DE 102012221227 A1 hydrodispersions are described, which include thickeners such as sodium polyacrylate. A disclosure of dispersing sodium polyacrylate in the oil phase is lacking as is the addition of another gelling agent to the water phase.

It is further desirable to provide a skin care preparation which

especially on moist skin and can be followed by rinsing leaves a particularly pleasant caregiver residue on the skin.

In particular, the object is to provide a corresponding care preparation for the application on the face.

In DE 102004017221 A1 and DE 102004017223 A1 O / W gel composition are described, wherein either the gelling agent, such as

Sodium polyacrylate, or a mixture of gelling agents dispersed in a liquid oil phase and then emulsified with the aqueous phase, or swelling of the gelling agent or a mixture of gelling agent in the aqueous phase and this mixed with the liquid oil phase or a swelling of the gelling agent or a Mixture of gel formers in a low molecular weight polyol or polyol mixture having a molecular weight <1000 daltons processed with the aqueous phase and with the liquid oil phase.

During development it turned out that O / W emulsions do not leave enough residue. Although W / O emulsions leave behind residue, but this residue is not perceived as sensory pleasant. The task was therefore one

Formulation to meet the sensory requirements and does not have the disadvantages of the prior art.

The object is achieved by the preparation according to the invention according to the claims.

The invention is a cosmetic or dermatological preparation comprising an oil phase and a water phase, wherein sodium polyacrylate is dispersed in the oil phase, the water phase comprises one or at most two gel formers and no emulsifiers, surfactants, celluloses and advantageously no acrylates / alkyl acrylate crosspolymers in the Preparation are included.

The preparations according to the invention are therefore not emulsions. In contrast to the known bi-gel formulation is omitted according to the invention on the addition of celluloses.

The proportion by weight of sodium polyacrylate according to the invention preferably in the range of 0.5 wt.% To 2 wt.%, In particular 0.8 to 1, 2 wt.%, Based on the total mass of the preparation selected.

The proportion of gelling agents, in particular xanthan gum, is in total in the range from 0.1% by weight to 1.5% by weight, in particular in the range from 0.15 to 0.3% by weight, based on the total mass of the preparation, selected.

A preferred gelling agent is xanthan gum, a microbial anionic heteropolysaccharide produced by Xanthomonas campestris and some other species under aerobic conditions and having a molecular weight of 2 to 15 million daltons. Xanthan is formed from a chain of β-1,4-linked glucose with side chains. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate, the number of pyruvate units determining the viscosity of the xanthan gum.

Xanthan gum is available, for example, under the trade name Xanthan gum food grade, type FF from Jungbunzlauer, or from Rahn under the trade name Keltrol CG-F.

In the formulation according to the invention, the gelling agent (xanthan gum) in the

Water phase and sodium polyacrylate dispersed in the oil phase.

On the other hand, stirring the sodium polyacrylate into the water phase does not guarantee the stability of the preparation structure.

Is dispersed both the xanthan gum and the sodium polyacrylate in the

Water phase and leaves the oil phase without further thickener, the preparation is also unstable after some time.

Therefore, according to the present invention, it has been found that there is a stabilizing effect when the sodium polyacrylate is dispersed in the oil phase.

For preparation, the sodium polyacrylate is predispersed in an oil and then added to the batch. This ensures that the gelling agent does not clump when in contact with water, but is finely distributed and meanwhile forms the structure according to the invention.

Sodium polyacrylate is therefore preferably predispersed in the oil phase. The one or two gelling agents, in particular xanthan gum, are dispersed in the water phase and then the oil phase is added to the water phase. Due to the dispersion of the sodium polyacrylate, the oil phase has not formed into a gel but the oil phase is still liquid. The oil phase is thus more spreadable and can be better distributed on the skin. In contrast to many prior art formulations, no sticky or waxy residue on the skin that is adversely affected by the user is produced.

The oil phase is structured, similar to the lamellar structure

Phase components.

Unstructured, however, are classic liquids or liquid mixtures.

The task of providing a sensory acceptable preparation is thus fulfilled.

In contrast to the preparations of DE 102004017221 A1 and DE 102004017223 A1, in which three different production processes are described, according to the invention only the dispersion of sodium polyacrylate in the oil phase is selected. In addition, DE 102004017221 A1 describes emulsions, but preparations according to the invention without emulsifiers. Furthermore, no further gelling agents are present in the preparations of DE 102004017221 A1 and DE 102004017223 A1 in addition to acrylate gel formers.

In the oil phase of the invention, in addition to the sodium polyacrylate, also a fatty alcohol, e.g. Cetyl Stearyl Alcohol, so when cooling the preparation of the fatty alcohol again "solid" and thickens the oil phase, however, only slightly.

It has also been found that the sensory effects are further improved if one or more starch compounds, in particular tapioca starch, are added to the preparation.

This sensory enhancement was astonishing, as it was expected that the addition of a powder or powdery substance would result in a powdery, smooth but not richer sensor.

However, it was found that the addition of starch, in particular tapioca starch, to the preparations according to the invention led to a further improved dispersibility and above all an unexpected richness. The preparations according to the invention thus have a cream-like character and thus convey an even stronger

Nursing feeling for the user.

This is another sensory advantage over the prior art formulations. The proportion of starch compounds, in particular tapioca starch, in total is advantageously in the range of 0, 1 wt.% To 8 wt.%, In particular in the range of 1 to 3 wt.%, Based on the total mass of the preparation selected.

In an in-use study, more than 200 subjects tested two preparations according to the invention.

Both formulas according to Example 1 contained i.a. Tapioca. The two formulas differ only in the amount of starch (CLG 04 = about 0.85 to 1% by weight of tapioca, CLG 05 = about 2.5 to 3% by weight of tapioca). The evaluation of the subject assessment for skin care and sensory aspects, shown in the figure, shows that both formulations according to the invention achieved good values despite addition of starch. It is amazing that the formula performs better with a higher amount of tapioca (CLG 05), especially in the parameters that are very relevant for face care.

In addition to the gel formers and starch compounds, no celluloses and advantageously no further polysaccharides, in particular no further thickeners, are contained in the preparation according to the invention in the preparation.

Advantageously, therefore, no further thickener is present in the oil phase and in particular in the entire preparation.

In addition, the preparation in particular also does not comprise acrylates / alkyl acrylate crosspolymers.

No further substances means that the proportion of these substances below 0, 1 wt.%, In particular less than 0.01 wt.%, Preferably 0 wt.%, Based on the total mass of the preparation is, if immaterial by impurities or manufacturing processes Shares of these substances should be added but once.

According to the invention as thickeners or thickening substances are those substances to be considered, which increases the viscosity of the preparation or phase compared to preparations without this substance.

Likewise, the addition of surfactants and emulsifiers is dispensed with in order to solve the stated tasks of providing a sensory-acceptable preparation which simultaneously leaves a nourishing residue on the skin.

The proportion of surfactants or emulsifiers in the preparation is therefore at most 0.1% by weight, in particular less than 0.01% by weight, advantageously 0% by weight, based on the total mass of the preparation, in accordance with the invention as "free of "to apply. This means, as already stated, to include any impurities of these substances with.

Fatty alcohols, in particular cetylstearyl alcohol, according to the invention are not considered as emulsifiers. As stated, therefore, no emulsifiers, with the exception of fatty alcohols, being included in the preparation.

Cetylstearyl alcohol is known as an emollient in cosmetics.

Cetylstearyl alcohol, also referred to as stearolum, CTFA or cetearyl alcohol, is a common name for a mixture of the alcohols cetyl alcohol (hexadecanol) and stearyl alcohol (octadecanol). Since the two components are often prepared by reducing the corresponding fatty acids, these alcohols are also referred to as fatty alcohols. Cetylstearyl alcohol is used in a variety of pharmaceutical and cosmetic preparations, increases the stability of emulsions and improves the texture of

Preparations.

In the emulsifier-free preparation according to the invention, the fatty alcohols and in particular cetylstearyl alcohol serve to improve the stability of the preparation.

Although various references suggest that cetearyl alcohol is a co-emulsifier, these are not to be understood as emulsifiers which are excluded according to the invention.

In other words, in addition to fatty alcohols or cetearyl alcohol, the preparations according to the invention do not comprise emulsifiers.

The proportion of fatty alcohols, in particular cetylstearyl alcohol, is advantageously selected in the range of up to 5% by weight, in particular up to 2.5% by weight.

The preferred avoidance of the addition of substances such as emulsifiers, thickeners, surfactants or preservatives is important according to the invention, since on the one hand disadvantages such as incompatibilities are reduced and on the other hand an application-friendly and, above all, sensory-acceptable cosmetic can be provided.

The proportion of these substances to be avoided is therefore, as stated several times, below 0.1% by weight, in particular below 0.01% by weight or at exactly 0% by weight, based on the total mass of the preparation.

A further advantage according to the invention results when the weight ratio of the oil phase to the water phase is in the range from 2% by weight to 98% by weight to 25% by weight to 75% % By weight, in particular in the range from 18% by weight to 82% by weight, based on the total mass of the preparation.

On the one hand, this mixing ratio makes it possible to adjust the viscosity of the preparation in order to ensure topical application and friability and, on the other hand, to achieve a sensory, pleasant skin sensation.

Furthermore, these inventive mixing ratios have an advantageous effect on the storage stability of the formulation

The application of the preparation according to the invention takes place on the skin, in particular moist or wet skin, in particular on the face or neck.

The use of the preparation on moist or wet skin, in particular facial skin, is therefore preferred according to the invention.

A moist or wet skin is present during or after showering or bathing, so that the application of the preparation according to the invention takes place during or after showering or bathing.

When distributing the preparation according to the invention on the skin, a fine oil film forms on the skin, which maintains the skin even after drying of the skin and produces a sensory pleasant feeling.

Consumer studies have shown that the skin feel after application of the

product was very pleasant and the consumers have perceived a positive effect compared to before.

In the case of commercial O / W emulsions, the oil components are stably incorporated into the emulsion structure via emulsifiers. As a result, the oil components do not "adhere" or at least badly adhere to the skin surface and are washed away again during the subsequent rinsing off.

In the case of an emulsifier-based formula, slow-spreading oils or waxes are therefore used, so that sufficient residue can remain on the skin at all. However, these slow-spreading oils or waxes usually cause a dull or sticky skin sensation and are therefore perceived as sensory unpleasant.

In the case of the emulsifier-free formulation according to the invention, therefore, other oil components are preferably available.

Advantageous polar oil components can be selected for the purposes of the present invention from the group of esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 up to 30 carbon atoms. Such ester oils can then advantageously be selected from the group consisting of phenethyl benzoate, 2-phenylethyl benzoate, isopropyl lauroyl sarcosinate, phenyl trimethicone, cyclomethicone, dibutyl adipate,

Octyl palmitate, octyl cocoate, octyl isostearate, octyl dodecyl myristate, octyl dodecanol,

Cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate,

Isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, stearyl heptanoate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, tridecyl stearate, tridecyl trimellitate, as well as synthetic, semi-synthetic and natural mixtures of such esters, e.g. B. jojoba oil.

Other preferred oils are selected from the group Caprylic / Capric triglycerides, tri-isostearin, octyl stearates, dicaprylyl carbonates and / or shea butter.

Exceptionally preferred oil components according to the invention are selected from

Fatty acid and fatty alcohol esters. Particularly preferred in this case is isopropyl palmitate.

It is further preferred that one or more vegetable oils be selected as the lipid component of the oil phase. Preferred vegetable oils are to be selected from almond oil, grapeseed oil, and / or sunflower oil.

These oil components are particularly good on the skin and convey

pleasant, smooth, soft skin feeling.

The cosmetic or dermatological preparations according to the invention may further contain cosmetic adjuvants and other active ingredients, such as are commonly used in such preparations, for. As substances for preventing foaming, dyes and color pigments, moisturizing and / or moisturizing substances, fats, oils, waxes or other common ingredients of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives, self-tanner , Buffers, pH Regulators, Herbal Extracts, Sebum Absorbing Substances, UV Filters, Active Ingredients such as Anti Age, Anti-Cellulite, Anti Acne, Anti-Rosacea, Anti-Neurodermatitis, Antioxidants, Moisturizers, Chelating Agents, Antiperspirants, Bleaches and Dyes etc. if the additive does not hinder or preclude the required properties in terms of stability, structure formation and sensory properties. Preservatives or auxiliaries may also be present in the preparation, advantageously to a proportion of 0.02 to 2% by weight, in particular 0.02 to 1% by weight, based on the total mass of the preparation. If necessary, the preparation can also

Preservative-free formulated.

Surprisingly, it has been shown that the choice of preservative can influence the preparation structure. Thus, the addition of methylparaben showed that the oil pots have a smaller diameter than

Preparations with another preservative.

Preferred preservatives or preservative auxiliaries are to be selected from the group Piroctone Olamine, phenoxyethanol, benzethonium chlorides, diazolidinyl urea, sodium benzoates, methylparaben, DMDM hydantoin + iodopropynyl butylcarbamates, propylparaben, hexamidines diisethionates, ethylparaben, DMDM hydantoin, butylenes glycol + iodopropynyl butylcarbamates and caprylyl Glycol, ethylhexylglycerol, methylpropanediol; Benzyl alcohol, hydroxyacetophenones, diols (1,2-alkanediols), 1,2-hexanediol, pentylenes glycol, 1,2-octanediol, decylene glycol.

Phenoxyethanol is advantageous in a proportion of 0.6 to 1 wt.% And / or Methylparaben advantageous to a proportion of 0.3 to 0.4 wt.%, In each case based on the total mass of the preparation contained in the preparation.

Due to the special structure and by the easy breaking up of the formulation according to the invention, a further advantage over preparations of the prior art showed - an improved availability of active ingredient. In addition, both water-soluble and fat-soluble active ingredients can be used well in accordance with the invention. One achieves on the one hand a higher flexibility in the question of the usability of possible active ingredients as well as in the amount of active ingredients that can be provided due to the better availability in smaller proportions.

Preferred active ingredients may include: tocopherol / tocopheryl acetates,

Panthenol, Fucus Vesiculosus Extract, Prunus Amygdalus Dulcis Oil, Butyrospermum Parkii Butter, Calendula Officinalis Flower Extract, Nelumbium Speciosum Flower Extract,

Glycyrrhiza Inflata Root Extract, Vitis Vinifera Seed Oil, Chamomilla Recutita Flower Extract, Centaurea Cyanus Flower Extract, Argania Spinosa Kernel Oil, Aloe Barbadensis, Kaolin, Cucumis Sativus, Ubiquinone, Creatine, Sodium Hyaluronate, Magnolia Officinalis Bark Extract, 4-Butylresorcinol, Calcium Pantothenate, Hydrolyzed Pearl, Glycine Soy Germ Extract, Arctium Lappa Fruit Extract, Glycosylrutin, Isoquercitrin, Eucerit and / or Glyceryl Glucoside. The cosmetic preparations according to the invention can be prepared as described below.

Water and glycerin are heated to 75 ° C. At 75 ° C with stirring (1 10 - 160 rpm), the addition of the gelling agent. The resulting solution is hereinafter referred to as the aqueous phase. Separately from the aqueous phase oils of the invention, fatty alcohols, preservatives, stabilizers are heated to 80 ° C and the

Polyacrylate thickener dispersed in the solution (60 - 90rpm). This obtained solution will hereinafter be referred to as oily phase. Subsequently, the oily phase is added with stirring (160-190 rpm) of the aqueous phase and mixed. Mix at 65 ° C with an Ultraturrax® (7000-8000 rpm) over a period of 3-8 minutes. After cooling, the addition of the other substances and perfume is carried out at 25 ° C. with stirring (160-190 rpm).

The following examples illustrate preparations according to the invention. The numbers are, unless otherwise stated, parts by weight based on the total mass of the preparation.

Examples

INCI 1 2 3 4 5

Caprylic / Capric Triglycerides 15.00 0.00 0.00 0.00 0.00

Isopropyl Palmitate 0.00 10.00 8.00 10.00 3.00

Prunus Amygdalus Dulcis Oil 0.00 0.00 5.00 0.00 0.00

Octyl dodecanol 0.00 0.00 5.00 0.00 8.00

Tapioca Starch 3.00 2.60 1.00 2.60 2.00

Perfumes 0.35 0.50 0.45 0.40 0.30

Glycerin 12,00 9,00 7,00 9,00 10,00

Xanthan gum 0.30 0.20 0.00 0.20 0.25

Chondrus Crispus 0.00 0.00 0.30 0.00 0.00

Phenoxyethanol q.s. q.s. q.s. q.s. q.s.

Ethanol qsqsqsqsqs Ethylparaben qsqsqsqsqs

Trisodium EDTA q.s. q.s. q.s. q.s. q.s.

Benzethonium Chloride q.s. q.s. q.s. q.s. q.s.

Methylparaben q.s. q.s. q.s. q.s. q.s.

Piroctone Olamine q.s. q.s. q.s. q.s. q.s.

Cetearyl Alcohol 1, 80 2,00 2,20 2,00 2,20

Sodium polyacrylates 1, 30 1, 00 1, 20 1, 00 0.75

Tocopheryl Acetate q.s. q.s. q.s. q.s. q.s.

Panthenol q.s. q.s. q.s. q.s. q.s.

Aqua q.s. q.s. q.s. q.s. q.s.

INCI 6 7 8 9 10

Caprylic / Capric Triglycerides 0,00 7,00 0,00 5,00 0,00

Isopropyl Palmitate 10.00 0.00 10.00 5.00 8.00

Prunus Amygdalus Dulcis Oil 0,00 0,50 0,00 1, 00 3,00

Octyl Dodecanol 0.00 3.00 2.00 0.00 0.00

Tapioca Starch 0.90 2.50 0.90 2.00 3.00

Perfume 0.40 0.50 0.40 0.35 0.50

Glycerine 9.00 5.00 9.00 10.00 7.00

Xanthan gum 0.20 0.00 0.30 0.25 0.00

Chondrus Crispus 0.00 0.25 0.00 0.00 0.20

Phenoxyethanol q.s. q.s. q.s. q.s. q.s.

Ethanol q.s. q.s. q.s. q.s. q.s.

Ethylparaben q.s. q.s. q.s. q.s. q.s.

Trisodium EDTA q.s. q.s. q.s. q.s. q.s.

Benzethonium Chloride qsqsqsqsqs Methylparaben qsqsqsqsqs

Piroctone Olamine q.s. q.s. q.s. q.s. q.s.

Cetearyl Alcohol 2,00 2,50 1, 50 1, 80 2,00

Sodium polyacrylate 1, 00 1, 20 0.80 0.75 1, 00

Tocopheryl Acetate q.s. q.s. q.s. q.s. q.s.

Panthenol q.s. q.s. q.s. q.s. q.s.

Aqua q.s. q.s. q.s. q.s. q.s.

Claims

claims

1. Cosmetic or dermatological preparation comprising an oil and a

Water phase, wherein sodium polyacrylate dispersed in the oil phase, the

Water phase comprises one or a maximum of two gelling agents and no surfactants, no celluloses and no emulsifiers, with fatty alcohols are excluded, are included in the preparation.

2. Preparation according to claim 1, characterized in that in addition to cetearyl alcohol no further emulsifiers are included.

3. Preparation according to claim 1 or 2, characterized in that no

Acrylates / alkyl acrylate cross polymers are included.

4. Preparation according to one of the preceding claims, characterized in that as gelling agent xanthan gum is selected.

5. Preparation according to one of the preceding claims, characterized in that in addition one or more starch compounds are contained in the preparation.

6. Preparation according to one of the preceding claims, characterized in that in addition to the gelling agents and starch compounds no further polysaccharides, in particular no further thickeners, are included in the preparation.

7. Preparation according to one of the preceding claims, characterized in that the weight ratio of the oil phase to the water phase in the range of 2 wt.% To 98 wt.% To 25 wt.% To 75 wt.%, In particular in the range of 18 wt.% To 82 wt.%, Based on the total mass of the preparation is selected.

8. Preparation according to one of the preceding claims, characterized in that the proportion by weight of sodium polyacrylate in the range of 0.5 wt.% To 2 wt.%, In particular 0.8 to 1, 2 wt.%, Based on the total mass of the preparation, is selected.

9. Preparation according to one of the preceding claims, characterized in that the proportion of gelling agents, in particular xanthan gum, in total in the range of 0, 1 wt.% To 1, 5 wt.%, In particular in the range of 0.15 to 0.3 % By weight, based on the total mass of the preparation.

10. Preparation according to one of the preceding claims 5 to 9, characterized in that the proportion of starch compounds, in particular tapioca starch, total in the range of 0, 1 wt.% To 8 wt.%, In particular in the range of 1 to 3 wt.%, based on the total mass of the preparation is selected.

1 1. A preparation according to any one of the preceding claims, characterized in that one or more fatty alcohols, in particular cetylstearyl alcohol, to a proportion of up to 5 wt.%, In particular up to 2.5 wt.%, Based on the total mass of the preparation are included ,

12. Preparation according to one of the preceding claims obtainable in that

Sodium polyacrylate is dispersed in the oil phase, the one or two gelling agent, in particular xanthan gum, is dispersed in the water phase and then the oil phase is added to the water phase.

13. Preparation according to one of the preceding claims, characterized in that as part of the oil phase one or more lipids are selected from the group of esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols having a

Chain length of 3 to 30 carbon atoms, from the group of esters of aromatic

Carboxylic acids and saturated and / or unsaturated, branched and / or

unbranched alcohols having a chain length of 3 to 30 carbon atoms.

14. A preparation according to claim 13, characterized in that as ester oils one or more compounds from the group phenethyl benzoate, 2-phenylethyl benzoate, isopropyl lauroyl sarcosinate, phenyl trimethicone, cyclomethicone, dibutyl adipate,

Octyl palmitate, octyl cocoate, octyl isostearate, octyl dodecyl myristate, octyl dodecanol, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate,

Isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate,

Isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, stearyl heptanoate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, tridecyl stearate, tridecyl trimellitate, and synthetic, semi-synthetic and natural mixtures of such esters, especially jojoba oil.

15. Preparation according to one of the preceding claims 13 or 14 characterized

in that isopropyl palmitate is selected as the oil component.

16. Preparation according to one of the preceding claims, characterized in that one or more vegetable oils are selected as part of the oil phase.

17. Use of a preparation according to one of the preceding claims on moist skin, in particular moist facial skin.

18. Use of a preparation according to one of the preceding claims during or after showering or bathing.