EP3276021B1 - Hochfestes stahlblech und herstellungsverfahren dafür - Google Patents

Hochfestes stahlblech und herstellungsverfahren dafür Download PDF

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Publication number
EP3276021B1
EP3276021B1 EP15887414.9A EP15887414A EP3276021B1 EP 3276021 B1 EP3276021 B1 EP 3276021B1 EP 15887414 A EP15887414 A EP 15887414A EP 3276021 B1 EP3276021 B1 EP 3276021B1
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Prior art keywords
inclusive
steel sheet
annealing
temperature
area fraction
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EP15887414.9A
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English (en)
French (fr)
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EP3276021A1 (de
EP3276021A4 (de
Inventor
Kenji Kawamura
Noriaki Kohsaka
Yasuhiro Nishimura
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JFE Steel Corp
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JFE Steel Corp
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/001—Heat treatment of ferrous alloys containing Ni
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/002—Heat treatment of ferrous alloys containing Cr
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/20—Zinc
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the present invention relates to a high-strength steel sheet excellent in punchability, having a tensile strength (TS) of 780 MPa or more, and suitable for use as automobile body frame members.
  • the invention also relates to a method for producing the high-strength steel sheet.
  • Steel sheets used for structural members and reinforcing members of automobiles are mainly steel sheets having a tensile strength (TS) of 780 MPa or more.
  • TS tensile strength
  • To strengthen a steel sheet it is effective to utilize structural strengthening, and one method is to form a complex structure including soft ferrite and hard martensite.
  • a steel sheet having this complex structure has good ductility, an excellent strength-ductility balance (compatibility), and relatively good press formability.
  • TS tensile strength
  • the high-strength steel sheets used as materials of automobile components are subjected to punching and therefore required to have punchability.
  • the required punchability is that the amount of wear of the punch and die is small, i.e., continuous punchability is excellent, and that variations in press formability of punched edge faces and their vicinities when continuous punching is performed are small.
  • Patent Literature 2 discloses a hot-rolled steel sheet in which deterioration in punchability is prevented by reducing the contents of Ti-based nitrides in the steel sheet.
  • Patent Literature 3 (PTL 3) describes a high-strength galvanized steel sheet having excellent formability, weldability and fatigue properties and a tensile strength equal to or higher than 980 MPa as well as a method for manufacturing the steel sheet.
  • the steel sheet has a composition comprising C: 0.05 % to lower than 0.12 %, Si: 0.35 % to lower than 0.80 %, Mn: 2.0 to 3.5 %, P: 0.001 to 0.040 %, S: 0.0001 to 0.0050 %, Al: 0.005 to 0.1 %, N: 0.0001 to 0.0060 %, Cr: 0.01 to 0.41 %, Ti: 0.010 to 0.080 %, Nb: 0.010 to 0.080 %, B: 0.0001 to 0.0030 %, Ni: lower than 0,04 % and Mo: lower than 0.05 %, all in mass%, and Fe and unavoidable impurities as the balance; a microstructure comprising a recrystallized ferrite phase with a volume fraction of 20 to 70 % and an average grain diameter equal to or smaller than 5 ⁇ m; a tensile strength equal to or higher than 980 MPa; an endurance ratio of 0.42 or more; and a galvanized layer on
  • Patent Literature 1 With the technique described in Patent Literature 1, the variations in the material properties of the steel sheet can be reduced.
  • the punch and die damage as the number of times the punching is performed increases, and it is inevitable that the clearance between the punch and die fluctuates. Therefore, it is difficult to maintain the formability of punched edge faces and their vicinities constant, and a problem arises in that cracking occurs during press forming in some cases.
  • a high-strength steel sheet of 780 MPa or more is more susceptible to cracking than a steel sheet of 590 MPa or less.
  • the variations in formability of punched edge faces and their vicinities directly lead to cracking during press forming.
  • its steel structure contains hard martensite in order to strengthen the steel sheet. Therefore, when the high-strength steel sheet is subjected to punching, voids are formed at the interface between the martensite and ferrite, causing deterioration in press formability.
  • the clearance is constant each time punching is performed, the formability of the punched edge faces and their vicinities is stable.
  • the clearance fluctuates, damage to punched edge faces of the steel sheet varies, and it is unfortunately difficult to perform continuous pressing stably.
  • Patent Literature 2 In the hot-rolled steel sheet in Patent Literature 2, a ferrite-bainite structure composed mainly of ferrite is recommended. Therefore, the technique in Patent Literature 2 does not address the above problem at the martensite-ferrite interface that occurs in two-phase structure steel composed mainly of ferrite and martensite.
  • the evaluation described in Patent Literature 2 is performed only for punching at a constant clearance, and the formability of punched edge faces is not stabilized when the clearance fluctuates.
  • the present invention has been made in view of the above circumstances, and it is an object to provide a high-strength steel sheet excellent in punchability and having a TS of 780 MPa or more and to provide a method for producing the high-strength steel sheet.
  • the present inventors have conducted extensive studies on various factors causing variations in formability of punched edge faces and their vicinities when continuous punching is performed. As a result, the inventors have found that a high-strength hot-dip galvanized steel sheet having a TS of 780 MPa or more and excellent in punchability can be obtained by using, as its steel structure, a three-phase structure including a ferrite phase, a martensite phase, and a bainite phase and finely controlling average crystal grain diameters of crystal grains in the martensite phase.
  • the present invention is summarized as follows.
  • a high-strength steel sheet having a high-tensile strength of 780 MPa or more and excellent in punchability is obtained.
  • the application of the high-strength steel sheet of the present invention to frame members of automobile bodies can contribute to improvement in collision safety and weight reduction significantly.
  • excellent in punchability means that ⁇ derived using a method described in EXAMPLES is 10 or less and ⁇ /ave ⁇ 5-20 is from 0.90 to 1.20 inclusive. Preferably, ⁇ is 8 or less, and ⁇ /ave ⁇ 5-20 is from 1.00 to 1.15 inclusive.
  • the high-strength steel sheet of the present invention has a chemical composition containing, in mass %, C: from 0.07% to 0.15% inclusive, Si: from 0.01% to 0.50% inclusive, Mn: from 2.0% to 3.0% inclusive, P: from 0.001% to 0.050% inclusive, S: from 0.0005% to 0.010% inclusive, sol. Al: from 0.005% to 0.100% inclusive, N: from 0.0001% to 0.0060% inclusive, Ti: from 0.01% to 0.10% inclusive, and Nb: from 0.01% to 0.10% inclusive, with the balance being Fe and unavoidable impurities.
  • C is an element effective in strengthening the steel sheet and contributes to the strengthening through the formation of martensite.
  • C forms fine carbides or carbonitrides with carbide-forming elements such as Nb and Ti to thereby contribute to the strengthening.
  • the content of C must be 0.07% or more. If the content of C exceeds 0.15%, spot-weldability deteriorates significantly. If the content of C exceeds 0.15%, the amount of the martensite phase increases, and this causes the steel sheet to be hardened, so that press formability may deteriorate. Therefore, the content of C is from 0.07% to 0.15% inclusive.
  • the content of C is preferably 0.08% or more.
  • the content of C is more preferably 0.12% or less.
  • Si from 0.01% to 0.50% inclusive
  • the content of Si is 0.50% or less.
  • the content of Si is preferably 0.20% or less.
  • Si is an element that improves ductility and contributes to improvement in strength. To obtain these effects, the content of Si must be 0.01% or more. Therefore, the content of Si is from 0.01% to 0.50% inclusive.
  • Mn from 2.0% to 3.0% inclusive
  • Mn is an element effective in increasing the strength of the steel sheet and is an element that functions effectively to obtain a complex structure. Mn is an element that lowers the Ac3 transformation point.
  • the content of Mn must be 2.0% or more. Also in terms of ensuring the strength by allowing low-temperature transformation phases to be stably formed during a cooling process from the austenite present at the time of heat annealing, the content of Mn is preferably 2.0% or more. If the content of Mn exceeds 3.0%, segregation of Mn in a portion positioned one-half the thickness of the sheet, i.e., a so-called Mn band, occurs significantly.
  • the content of Mn is from 2.0% to 3.0% inclusive.
  • the content of Mn is from 2.2% to 2.8% inclusive.
  • P is an element that dissolves in the steel and contributes to strengthening of the steel sheet.
  • P is also an element that segregates at grain boundaries and therefore causes a reduction in grain boundary binding force and deterioration in workability.
  • P is concentrated on the surface of the steel sheet, and this causes a reduction in chemical conversion treatability, corrosion resistance, etc. If the content of P exceeds 0.050%, the above influences become significant. However, an excessive reduction in the content of P causes an increase in production cost. Therefore, the content of P is from 0.001% to 0.050% inclusive.
  • S is an element that adversely affects workability.
  • S is present as MnS inclusions. This causes, in particular, deterioration in local ductility of the material and results in deterioration in workability. Moreover, the presence of sulfides causes deterioration in weldability.
  • These adverse effects can be avoided when the content of S is 0.010% or less. It is preferable that the content of S is 0.005% or less, because press workability can be improved significantly. However, an excessive reduction in the content of S causes an increase in production cost. Therefore, the content of S is from 0.0005% to 0.010% inclusive.
  • Al is an element effective as a deoxidizing agent. To obtain this effect, the content of sol. Al is 0.005% or more. If the content of sol. Al exceeds 0.100%, the cost of raw materials increases, and Al may cause surface defects in the steel sheet. Therefore, the content of Al in the form of sol. Al is from 0.005% to 0.100% inclusive.
  • N from 0.0001% to 0.0060% inclusive
  • the content of N is as small as possible.
  • the allowable content of N is up to 0.0060%.
  • An excessive reduction in the content of N causes an increase in production cost. Therefore, the content of N is from 0.0001% to 0.0060% inclusive.
  • Fine precipitates of Ti (mainly carbide, nitride, and carbonitride. These are hereinafter referred to as carbonitrides) contribute to an increase in strength and function advantageously to reduce the size of the ferrite and martensite.
  • the content of Ti must be 0.01% or more.
  • the content of Ti is preferably 0.02% or more.
  • Nb from 0.01% to 0.10% inclusive
  • Nb mainly carbonitrides
  • the Nb content must be 0.01% or more.
  • the Nb content is preferably 0.02% or more.
  • the content of Nb must be 0.10% or less. As described above, the content of Nb is from 0.01% to 0.10% inclusive.
  • the chemical composition of the high-strength steel sheet of the present invention may further contain, in mass %, at least one selected from Mo: from 0.05% to 1.00% inclusive, Cr: from 0.05% to 1.00% inclusive, V: from 0.02% to 0.50% inclusive, Zr: from 0.02% to 0.20% inclusive, B: from 0.0001% to 0.0030% inclusive, Cu: from 0.05% to 1.00% inclusive, and Ni: from 0.05% to 1.00% inclusive.
  • Mo is an element that improves hardenability and contributes to strengthening through the formation of martensite. Mo may be contained as needed. To obtain these effects, the content of Mo is preferably 0.05% or more. If the content of Mo exceeds 1.00%, not only the above effects are saturated, but also the raw material cost increases. Therefore, preferably, the content of Mo is from 0.05% to 1.00% inclusive.
  • Cr is an element that improves hardenability and contributes to strengthening through the formation of martensite. Cr may be contained as needed. To obtain these effects, the content of Cr is preferably 0.05% or more. If the content of Cr exceeds 1.00%, not only the above effects are saturated, but also the raw material cost increases. Therefore, preferably, the content of Cr is from 0.05% to 1.00% inclusive.
  • V from 0.02% to 0.50% inclusive
  • V forms fine carbonitrides and can thereby contribute to an increase in strength, as do Nb and Ti.
  • V may be contained as needed.
  • the content of V is preferably 0.02% or more. If the content of V exceeds 0.50%, not only the effect is saturated, but also the raw material cost increases. Therefore, preferably, the content of V is 0.50% or less.
  • Zr also forms fine carbonitrides and is effective in increasing strength. Zr may be contained as needed. To obtain the above effect, the content of Zr must be 0.02% or more. If the content of Zr exceeds 0.20%, not only the effect is saturated, but also the raw material cost increases. Therefore, preferably, the content of Zr is from 0.02% to 0.20% inclusive.
  • B has the function of suppressing the formation and growth of ferrite from austenite grain boundaries and may be contained as needed.
  • the effect of B is obtained when its content is 0.0001% or more. If the content of B exceeds 0.0030%, workability deteriorates. Therefore, when B is contained, its content is preferably within the range from 0.0001% to 0.0030% inclusive.
  • B it is preferable to prevent the formation of BN so that the above effect is obtained. Therefore, it is preferable that a combination of B and Ti is contained.
  • Cu is effective in increasing the hardenability of the steel to thereby strengthening a hot-rolled steel sheet.
  • the content of Cu must be 0.05% or more.
  • the content of Cu is 0.05% to 1.00%.
  • Ni from 0.05% to 1.00% inclusive
  • Ni is effective in increasing the hardenability of the steel to thereby strengthening a hot-rolled steel sheet.
  • the content of Ni must be 0.05% or more.
  • the content of Ni is 0.05% to 1.00%.
  • the chemical composition of the high-strength steel sheet of the present invention may further contain, in mass %, at least one element selected from Ca: from 0.001% to 0.005% inclusive, Sb: from 0.0030% to 0.0100% inclusive, and REM: from 0.001% to 0.005% inclusive.
  • Ca has the effect of improving ductility through control of the morphology of sulfides such as MnS.
  • the effect tends to be saturated. Therefore, when Ca is contained, its content is preferably from 0.0001% to 0.0050% inclusive.
  • Sb is an element that tends to segregate on the surface etc. and has the function of suppressing reactions in a surface layer during production steps such as nitrogen absorption and decarbonization.
  • the addition of Sb allows reactions of elements such as nitrogen and carbon whose contents are likely to vary to be suppressed even when the steel material is exposed to a high-temperature atmosphere during heating in a hot-rolling step or during annealing, and therefore Sb has the effect of preventing significant component variations.
  • the content of Sb when Sb is contained, it is preferable that the content of Sb is 0.0030% to 0.0100%. In the present invention, it is more preferable that the content of Sb is 0.0060% to 0.0100%.
  • the REM has the function of controlling the morphology of sulfide-based inclusions and thereby contributes to improvement in press formability. To obtain this effect, the content of REM must be 0.001% or more. However, the addition of a large amount of REM causes the sulfide-based inclusions to be coarsened, and punchability deteriorates. Therefore, the upper limit of the content of REM is preferably 0.005% or less.
  • the balance other than the above elements is Fe and unavoidable impurities.
  • the above-described basic composition is satisfied and also formula (1) is satisfied.
  • the symbols of elements represent the contents of the elements. 0.05 ⁇ C ⁇ 12 / 93 Nb ⁇ 12 / 48 Ti ⁇ 48 / 14 N ⁇ 48 / 32 S ⁇ 0.12
  • Formula (1) above defines the amount of C that is not fixed as carbides. If the amount of C present is large and exceeds 0.12%, the fraction of the martensite increases, and the ductility may decrease. Therefore, the amount of C not fixed as carbides that is calculated from formula (1) is preferably 0.12% or less.
  • the amount of C not fixed as carbides is less than 0.05%, the amount of C in austenite during annealing in a two-phase region after cold-rolling becomes small, and therefore the amount of the martensite phase formed after cooling becomes small, so that it may be difficult to obtain a high strength of 780 MPa or more. Therefore, preferably, the amount of C not fixed as carbides is 0.05% or more. The amount is preferably 0.07% or more.
  • the steel structure of the high-strength steel sheet of the present invention includes a ferrite phase, a martensite phase, and a bainite phase.
  • the rest of the structure includes a perlite phase, a retained austenite phase, carbides, etc.
  • the allowable content of these phases is such that their total area fraction is 5% or less.
  • at least 90% of the rest of the structure excluding the ferrite and martensite phases is the bainite phase.
  • the ferrite phase and the bainite phase are softer than the martensite phase, and their area fractions are not particularly specified.
  • the area fractions of the ferrite and bainite phases are each 20% or more.
  • the total area fraction of the ferrite and bainite phases is preferably 50% to 80% and more preferably 60% to 80%.
  • the martensite phase is a hard phase and is effective in increasing the strength of the steel sheet through transformation strengthening.
  • the area fraction of the martensite phase must be 20% or more. Since the martensite is hard, it may serve as origins of voids formed during punching because of the difference in formability between the martensite and the soft ferrite phase. To ensure stable punchability, at least a prescribed amount of martensite must be present. Also from this point of view, the area fraction of the martensite must be 20% or more. If the area fraction of the martensite exceeds 50%, the punchability may deteriorate. Therefore, the area fraction of the martensite is 50% or less. Preferably, the area fraction of the martensite is 40% or less.
  • the area fraction of crystal grains with an average crystal grain diameter of less than 1.0 ⁇ m is 5% to 30%.
  • the average crystal grain diameter of the martensite phase differs from the grain diameter of prior austenite during annealing but is equal to the grain diameter of the prior austenite after quenching.
  • the average crystal grain diameters and morphology of the martensite phase after secondary annealing greatly affect the formation of voids during punching. The smaller the crystal grains of the martensite phase, the smaller the voids formed during punching. Therefore, smaller crystal grains are particularly preferable when punching is performed with an appropriate clearance.
  • the area fraction of the crystal grains with an average crystal grain diameter of less than 1.0 ⁇ m in the martensite phase must be within the range of 5% and 30%.
  • the average crystal grain diameter of a crystal grain means the diameter of a perfect circle having the same area as the crystal grain and can be measured by a method described in EXAMPLES.
  • the area fraction of crystal grains with an average crystal grain diameter of 1.0 to 4.0 ⁇ m is 70 to 95%.
  • the crystal grains with an average crystal grain diameter of 1.0 to 4.0 ⁇ m are important in terms of ensuring the formability of punched edge faces stably even when the punching clearance fluctuates. This effect can be obtained when the area fraction is within the range of 70% and 95%.
  • the area fraction is 80% or more.
  • the crystal grains with an average crystal grain diameter of 1.0 ⁇ m to 4.0 ⁇ m include crystal grains with a major axis of 1.0 ⁇ m to 3.0 ⁇ m at an area fraction of less than 20%, because the formability of punched edge faces can be ensured stably even when the punching clearance fluctuates. It is preferable that, in the martensite phase, the crystal grains with an average crystal grain diameter of 1.0 ⁇ m to 4.0 ⁇ m further include crystal grains with a major axis of more than 3.0 ⁇ m at an area fraction of 80% or more, because the formability of punched edge faces can be ensured stably even when the punching clearance fluctuates.
  • the major axis of a crystal grain in the martensite phase means the length of the longest straight line in the crystal grain obtained by structure observation described in the EXAMPLES.
  • the area fraction of the crystal grains with a major axis of 1.0 ⁇ m to 3.0 ⁇ m is less than 20%, because the formability of punched edge faces can be ensured stably even when the punching clearance fluctuates. If the area fraction of the crystal grains with a major axis of 1.0 ⁇ m to 3.0 ⁇ m is 20% or more, the formability of punched edge faces varies when the punching clearance fluctuates. In this case, cracking may occur during press forming in some cases, causing a problem.
  • the area fraction of the crystal grains with a major axis of more than 3.0 ⁇ m is 80% or more, because the formability of punched edge faces can be ensured even when the punching clearance fluctuates. If the area fraction of the crystal grains with a major axis of more than 3.0 ⁇ m is less than 80%, the formability of punched edge faces varies when the punching clearance fluctuates. In this case, cracking may occur during press forming in some cases, causing a problem.
  • the area fraction of crystal grains with an average crystal grain diameter of more than 4.0 ⁇ m is less than 5%.
  • the martensite phase contains coarse crystal grains, voids are likely to be formed during punching. It is therefore preferable that the crystal grains are small.
  • crystal grains of more than 4.0 ⁇ m tend to cause significant deterioration in punchability.
  • the area fraction of such crystal grains is less than 5%, the deterioration is allowable.
  • the high-strength steel sheet of the present invention is produced by subjecting a steel slab having the chemical composition described above to hot rolling, cold rolling, primary annealing, optional light reduction rolling, optional pickling, and then secondary annealing. The production method and conditions will next be described.
  • the temperature at which the steel slab is reheated is lower than 1,200°C, precipitates containing Ti and Nb do not re-dissolve but are coarsened. In this case, not only the precipitation strengthening ability of the precipitates is lost, but also their pinning effect of preventing recrystallization is lost, so that it may be difficult to ensure stable punchability. Therefore, the temperature at which the steel slab is reheated is 1,200°C or higher. No particular limitation is imposed on the upper limit of the reheating temperature. In terms of energy efficiency and yield, the reheating temperature is preferably lower than 1,400°C and more preferably 1,300°C or lower.
  • the finishing temperature of the hot rolling is equal to or lower than the Ar3 point, coarse grains are formed in a surface layer, and therefore it is difficult to form a uniform steel structure, so that stable punchability may not be obtained. It is preferable that the finishing temperature is equal to or higher than the Ar3 point. No particular limitation is imposed on the upper limit of the finishing temperature. Preferably, the finishing temperature is 1,000°C or lower.
  • the coiling temperature is 500°C to 700°C.
  • the coiling temperature is more preferably 550°C to 650°C.
  • the hot-rolled steel sheet is then pickled according to a routine procedure to remove scales. Then the resulting hot-rolled steel sheet is cold-rolled to produce a cold-rolled steel sheet with a final thickness.
  • the rolling reduction in the cold rolling is preferably 40% or more. A rolling reduction of less than 40% is not preferable because the steel sheet structure after finish annealing is coarse-grained and the strength-ductility balance may deteriorate.
  • the rolling reduction is more preferably 50% or more. If the rolling reduction exceeds 90%, a load on the rolling rolls increases, and rolling troubles such as chattering and breakage of the sheet occur. Therefore, preferably, the rolling reduction in the cold rolling is 90% or less.
  • the rolling reduction is more preferably 80% or less.
  • the cold-rolled steel sheet is then subjected to primary annealing. It is preferable in terms of improving productivity that the primary annealing and secondary annealing described later are performed as continuous annealing.
  • the primary annealing temperature in the primary annealing is from the Ac3 point to the Ac3 point + 60°C inclusive.
  • the primary annealing temperature is equal to or higher than the Ac3 point, the steel structure after the secondary annealing is made uniform, and the desired properties can be obtained. If the primary annealing temperature is lower than the Ac3 point, the structure tends to be non-uniform even after the secondary annealing, and the desired properties cannot be obtained. If the primary annealing temperature is higher than the Ac3 point + 60°C, the structure becomes coarse.
  • the ratio of the crystal grains with an average crystal grain diameter of more than 4.0 ⁇ m in the martensite phase after the secondary annealing increases, and the properties after the secondary annealing deteriorate.
  • This primary annealing temperature is not preferable also in terms of energy efficiency. Therefore, the primary annealing temperature is from the Ac3 point to the Ac3 point + 60°C inclusive.
  • the primary annealing time in the primary annealing is from 10 seconds to 200 seconds inclusive. If the primary annealing time is shorter than 10 seconds, recrystallization does not proceed sufficiently, and a steel sheet with the desired properties cannot be obtained. If the primary annealing time exceeds 200 seconds, the ratio of the crystal grains with an average crystal grain diameter of more than 4.0 ⁇ m in the martensite phase after the secondary annealing increases. In this case, not only the properties after the secondary annealing deteriorate, but also a large amount of energy is consumed, so that the production cost increases. Therefore, the primary annealing time is from 10 seconds to 200 seconds inclusive.
  • the cooling rate (average cooling rate) during cooling in the primary annealing is 10°C/s or more at least in the temperature range from the primary annealing temperature to 550°C. If the average cooling rate is less than 10°C/s, a large amount of perlite is formed, and a complex structure including ferrite, martensite, and bainite may not be obtained.
  • the upper limit of the cooling rate is not particularly specified. However, to prevent deterioration of the shape of the steel sheet, the cooling rate is preferably 200°C/s or less. The cooling rate is preferably 20°C/s to 50°C/s.
  • the resulting steel sheet is subjected to light reduction rolling and then pickling.
  • the pickling and the light reduction rolling are not essential and are performed for the purpose of correcting the shape of the steel sheet.
  • the rolling reduction is 0.3% to 3.0%.
  • the pickling is performed to remove scales, and general conditions may be appropriately used.
  • the steel sheet subjected to the light reduction rolling and the pickling after the primary annealing is then subjected to secondary annealing.
  • the secondary annealing temperature in the secondary annealing is equal to or lower than the Ac3 point and is from (the primary annealing temperature - 80°C) to (the primary annealing temperature - 30°C).
  • To control the fractions of phases in the final structure it is necessary to control the secondary annealing temperature within the specific range with respect to the primary annealing temperature.
  • the secondary annealing temperature is lower than (the primary annealing temperature - 80°C), it is difficult to ensure a tensile strength of 780 MPa stably.
  • the structure becomes excessively coarse.
  • the area fraction of the crystal grains with an average crystal grain diameter of 1.0 ⁇ m to 4.0 ⁇ m in the martensite phase tends to be less than 70%, and the area fraction of the crystal grains with an average crystal grain diameter of more than 4.0 ⁇ m becomes 5% or more, so that voids are likely to be formed excessively during punching. Therefore, the secondary annealing temperature is equal to or lower than the Ac3 point and is within the range of (the primary annealing temperature - 80°C) and (the primary annealing temperature - 30°C) .
  • the secondary annealing time in the secondary annealing is from 10 seconds to 100 seconds inclusive. If the secondary annealing time is shorter than 10 seconds, recrystallization does not proceed sufficiently, and a steel sheet with the desired properties cannot be obtained. If the secondary annealing time exceeds 100 seconds, the area fraction of the crystal grains with an average crystal grain diameter of 1.0 ⁇ m to 4.0 ⁇ m in the martensite phase tends to be less than 70%, and the area fraction of the crystal grains with an average crystal grain diameter of more than 4.0 ⁇ m tends to be 5% or more.
  • the area fraction of the crystal grains with a major axis of 1.0 ⁇ m to 3.0 ⁇ m tends to be 20% or more, and the area fraction of the crystal grains with a major axis of more than 3.0 ⁇ m tends to be less than 80%.
  • the secondary annealing time is from 10 seconds to 100 seconds inclusive.
  • the cooling rate (average cooling rate) during cooling in the secondary annealing is 10°C/s or more at least in the temperature range from the secondary annealing temperature to 550°C. If the average cooling rate is less than 10°C/s, a large amount of perlite is formed, and a complex structure including ferrite, martensite, and bainite may not be obtained.
  • the upper limit of the cooling rate is not particularly specified. However, to prevent deterioration of the shape of the steel sheet, the cooling rate is preferably 200°C/s or less. The cooling rate is preferably 20°C/s to 50°C/s.
  • the cooling stop temperature during cooling in the secondary annealing is 400°C to 550°C.
  • the cooling stop temperature is important in terms of the formation of the bainite phase. If the cooling stop temperature is lower than 400°C, a large proportion of the low-temperature transformation phases is the martensite phase, and the formability of punched edge faces is poor. If the cooling stop temperature exceeds 550°C, pearlite and cementite are formed, and the formability of punched edge faces is poor. Therefore, preferably, the cooling stop temperature is 400°C to 550°C.
  • the period of time during which the steel sheet is at 400°C to 550°C is 20 seconds to 100 seconds.
  • the residence time is important in terms of the formation of a certain amount of bainite phase. If the residence time is shorter than 20 seconds, the formation of the bainite phase is insufficient, and the formability of punched edge faces is poor. If the residence time exceeds 100 seconds, the amount of the bainite phase formed is excessively large. In this case, the prescribed amount of martensite cannot be formed, and the formability of punched edge faces is poor. Therefore, the residence time is 20 seconds to 100 seconds.
  • the cooling in the secondary annealing is continued until room temperature is reached under the condition of an average cooling rate of 10°C/s or more. If the average cooling rate is less than 10°C/s, the martensite phase is not easily formed, and the formability of punched edge faces may be poor.
  • the upper limit of the average cooling rate during the cooling is not particularly specified. However, to prevent deterioration of the shape of the steel sheet, the average cooling rate is preferably 100°C/s or less. The average cooling rate is more preferably 20°C/s to 50°C/s.
  • the high-strength steel sheet of the present invention can be produced in the manner described above.
  • the high-strength steel sheet obtained as described above may be used as a product without any other treatment or may be cooled and subjected to coating treatment such as hot-dip coating or electroplating to obtain a product.
  • the treatment when the coating treatment used is hot-dip galvanization widely used for automobile steel sheets etc., the treatment may be performed as follows. After the above-described soaking and cooling treatment or further the overaging treatment (the above treatment in which the steel sheet is held at 400°C to 550°C for a prescribed time during cooling in the secondary annealing) performed in an upstream continuous annealing furnace in a hot-dip galvanization line, the steel sheet is immersed in a hot-dip galvanization bath to form a hot-dip galvanized layer on the surface of the steel sheet. Then the resulting steel sheet may be subjected to an alloying treatment to form a galvannealed steel sheet.
  • the continuous annealing including the soaking and cooling treatment or including the soaking and cooling treatment and the overaging treatment may be separated from the coating treatment, and they may be performed in different lines.
  • the galvanized layer is a layer containing mainly Zn.
  • the galvannealed layer is a layer containing mainly an Fe-Zn alloy that is formed by diffusion of Fe in the steel into the galvanized coating through a galvannealing reaction.
  • the galvanized layer and the galvannealed layer may contain Fe, Al, Sb, Pb, Bi, Mg, Ca, Be, Ti, Cu, Ni, Co, Cr, Mn, P, B, Sn, Zr, Hf, Sr, V, Se, and REM in addition to Zn so long as the effects of the present invention are not impaired.
  • the annealed steel sheet or the steel sheet subjected to the coating treatment may be subjected to temper rolling or levelling for the purpose of shape correction, surface roughness adjustment, improvement in mechanical properties, etc.
  • the total percentage elongation in the temper rolling and the levelling is preferably within the range of 0.2% to 3%. This is because, if the total percentage elongation is less than 0.2%, the prescribed purposes such as shape correction are not achieved. If the total percentage elongation exceeds 3%, a significant reduction in ductility occurs.
  • Molten steel having a chemical composition shown in Table 1 was produced in a converter. Then hot rolling was performed at a slab reheating temperature of 1,200°C, a hot-rolling finishing temperature of 880°C, and a coiling temperature of 600°C, followed by pickling and cold rolling at a rolling reduction of 60%. Then only primary annealing or the primary annealing, light reduction rolling at 0.5%, pickling, and secondary annealing were performed under conditions shown in Table 2 to produce a cold-rolled steel sheet with a thickness of 1.2 mm, a hot-dip galvanized steel sheet (GI steel sheet), and a galvannealed steel sheet (GA steel sheet).
  • GI steel sheet hot-dip galvanized steel sheet
  • GA steel sheet galvannealed steel sheet
  • the hot-dip galvanization treatment was performed such that the coating weight per side was adjusted to 50 g/m 2 (double-sided coating).
  • the content of Fe in the coating layer was adjusted to 9% to 12% by mass.
  • the cooling in the primary annealing and the cooling in the secondary annealing were performed at an average cooling rate of 20°C/s, respectively. [Table 1] % by mass Steel No C Si Mn P S sol.
  • a specimen for structure observation was taken from a steel sheet.
  • An L cross section (a vertical cross section parallel to the rolling direction) was mechanically polished and etched with nital, and an image of the cross section was taken at a magnification of 3,000X using a scanning electron microscope (SEM).
  • SEM photograph taken at a depth of 3/8 the thickness of the sheet from its surface
  • steel structure identification was performed, and the area fraction of the martensite phase, the area fraction of the ferrite phase, and the area fraction of the second phase other than the martensite were measured.
  • the structure photograph was transferred onto a transparency. Then the transferred image was colored, captured, and binarized, and each of the area fractions was determined using image analysis software.
  • the circle equivalent diameter of the crystal grain was calculated using its area and used as the average grain diameter.
  • the major axis of each of the martensite crystal grains was determined using an SEM photograph taken at a magnification of 5,000X using the SEM. Specifically, a maximum length of each crystal grain was measured for at least 100 crystal grains, and the average length was defined as the major axis of the crystal grain.
  • the "Second phase other than M” in Table 2 means a phase other than ferrite and martensite and was found to include bainite.
  • the area fraction of the bainite phase included in the "second phase other than M" was 90% or more.
  • the area fraction of the bainite phase was determined using the colored portions obtained by the method described above.
  • the bainite phase included in colored portions excluding the ferrite and martensite phases was identified, and the area fraction of the identified bainite phase was measured.
  • JIS No. 5 tensile test specimen JIS Z 2201 in which a direction 90° with respect to the rolling direction (C direction) was used as a tensile direction was taken from a steel sheet, and a tensile test was performed according to the specifications of JIS Z 2241 to measure the YS, TS, and El.
  • the criterion (pass/fail criterion) of the tensile test was TS ⁇ 780 MPa.
  • ⁇ ⁇ represents the difference between the maximum and minimum of the ⁇ values evaluated when punching was performed with the punching clearance falling within the range of 5 to 20%.
  • the difference between the maximum and minimum among three values including ⁇ measured according to The Japan Iron and Steel Federation Standard JFS T 1001 and ⁇ values ( ⁇ 5 and ⁇ 20 ) measured with target clearances set to 5% and 20% may be used as a substitute for the above difference.
  • a value obtained with the clearance deviating by up to ⁇ 1% from a target clearance may be used for the evaluation.
  • ⁇ / ave ⁇ 5 ⁇ 20 ⁇ /ave ⁇ 5-20 represents a value obtained by dividing the ⁇ measured according to The Japan Iron and Steel Federation Standard JFS T 1001 by the average of ⁇ values evaluated when punching was performed with the punching clearance falling within the range of 5% to 20%.
  • a value obtained by division by the average of three values including the ⁇ measured according to The Japan Iron and Steel Federation Standard JFS T 1001 and the ⁇ values ( ⁇ 5 and ⁇ 20 ) measured with target clearances set to 5% and 20% may be used as a substitute for the above value.
  • a value obtained with the clearance deviating by up to ⁇ 1% from a target clearance may be used for the evaluation.
  • steel sheets Nos. 1, 3, 4, 9, 10, 16, 17, 19, 20, and 22 to 24 are Inventive Examples in which their chemical composition and production method conform to the present invention. These steel sheets satisfy TS ⁇ 780 MPa or more. In these steel sheets, ⁇ , which is an indicator of the punchability, is 10 or less, and ⁇ /ave ⁇ 5-20 is 0.90 to 1.20. Therefore, in these steel sheets, the formability of punched edge faces is good.
  • a high-strength steel sheet having a tensile strength of 780 MPa or more and excellent in punchability can be obtained.
  • the high-strength steel sheet is applicable to difficult-to-form members such as automobile structural members to which conventional high-strength steel sheets are not easily applied.
  • the steel sheet of the invention When used for automobile structural members, the steel sheet contributes to a reduction in weight of the automobiles, an improvement in safety, etc. and is therefore very useful from the industrial point of view.

Claims (7)

  1. Hochfestes Stahlblech mit einer Zugfestigkeit von 780 MPa oder mehr und ausgezeichneter Stanzbarkeit, wobei das hochfeste Stahlblech eine chemische Zusammensetzung aufweist, in Massen-% umfassend C: von 0,07% bis einschließlich 0,15%, Si: von 0,01% bis einschließlich 0,50%, Mn: von 2,0% bis einschließlich 3,0%, P: von 0,001% bis einschließlich 0,050%, S: von 0,0005% bis einschließlich 0,010%, Sol-Al: von 0,005% bis einschließlich 0,100%, N: von 0,0001% bis einschließlich 0,0060%, Ti: von 0,01% bis einschließlich 0,10%, Nb: von 0,01% bis einschließlich 0,10%, gegebenenfalls mindestens eines, ausgewählt aus Mo: von 0,05% bis einschließlich 1,00%, Cr: von 0,05% bis einschließlich 1,00%, V: von 0,02% bis einschließlich 0,50%, Zr: von 0,02% bis einschließlich 0,20%, B: von 0,0001% bis einschließlich 0,0030%, Cu: von 0,05% bis einschließlich 1,00% und Ni: von 0,05% bis einschließlich 1,00%, und gegebenenfalls mindestens ein Element, ausgewählt aus Ca: von 0,001% bis einschließlich 0,005%, Sb: von 0,0030% bis einschließlich 0,0100% und SEM: von 0,001% bis einschließlich 0,005%, wobei der Rest Eisen und unvermeidbare Verunreinigungen sind,
    worin das hochfeste Stahlblech eine Stahlstruktur aufweist, die eine Ferritphase, eine Martensitphase und eine Bainitphase enthält,
    ein Flächenanteil der Martensitphase von 20% bis einschließlich 50% beträgt,
    ein Gesamtflächenanteil der Phasen, die nicht Ferrit, Martensit oder Bainit sind, 5% oder weniger beträgt,
    mindestens 90% des Rests der Stahlstruktur außer der Ferrit- und Martensitphasen die Bainitphase ist,
    die Martensitphase Kristallkörner mit einem durchschnittlichen Kristallkorndurchmesser von weniger als 1,0 µm zu einem Flächenanteil von 5% bis 30%, Kristallkörner mit einem durchschnittlichen Kristallkorndurchmesser von 1,0 µm bis 4,0 µm zu einem Flächenanteil von 70% bis 95% und Kristallkörner mit einem durchschnittlichen Kristallkorndurchmesser von mehr als 4,0 µm zu einem Flächenanteil von weniger als 5% umfasst,
    die Stahlstruktur bei einer Tiefe von 3/8 der Dicke des Stahlblechs von deren Oberfläche aus bestimmt wird und
    die Zugfestigkeit unter Verwendung eines JIS Nr. 5-Zugtestprüflings gemäß JIS Z 2201 gemessen wird, worin eine Richtung von 90° bezogen auf die Walzrichtung als Zugrichtung verwendet wird und ein Zugtest gemäß den Angaben von JIS Z 2241 durchgeführt wird.
  2. Hochfestes Stahlblech gemäß Anspruch 1, worin, in der Martensitphase, die Kristallkörner mit einem durchschnittliche Kristallkorndurchmesser von 1,0 µm bis 4,0 µm Kristallkörner mit einer Hauptachse von 1,0 µm bis 3,0 µm zu einem Flächenanteil von weniger als 20% und Kristallkörner mit einer Hauptachse von mehr als 3,0 µm zu einem Flächenanteil von 80% oder mehr umfassen.
  3. Hochfestes Stahlblech gemäß Anspruch 1 oder 2, worin die chemische Zusammensetzung in Massen-% mindestens eines umfasst, ausgewählt aus Mo: von 0,05% bis einschließlich 1,00%, Cr: von 0,05% bis einschließlich 1,00%, V: von 0,02% bis einschließlich 0,50%, Zr: von 0,02% bis einschließlich 0,20%, B: von 0,0001% bis einschließlich 0,0030%, Cu: von 0,05% bis einschließlich 1,00% und Ni: von 0,05% bis einschließlich 1,00%.
  4. Hochfestes Stahlblech gemäß mindestens einem der Ansprüche 1 bis 3, worin die chemische Zusammensetzung in Massen-% mindestens ein Element umfasst, ausgewählt aus Ca: von 0,001% bis einschließlich 0,005%, Sb: von 0,0030% bis einschließlich 0,0100% und SEM: von 0,001% bis einschließlich 0,005%.
  5. Verfahren zur Herstellung des hochfesten Stahlblechs gemäß mindestens einem der Ansprüche 1 bis 4, das Verfahren umfassend das Nacherwärmen, Warmwalzen, Aufrollen, Kaltwalzen, primäres Glühen und sekundäres Glühen einer Stahlbramme mit der chemischen Zusammensetzung gemäß Anspruch 1, 3 oder 4,
    worin die Nacherwärmungstemperatur 1.200°C oder höher beträgt,
    worin die Aufrolltemperatur 500 bis 700°C beträgt, worin das primäre Glühen bei einer Primärglühtemperatur von einem Ac3-Punkt bis einschließlich zum Ac3-Punkt + 60°C für eine Primärglühzeit von 10 Sekunden bis einschließlich 200 Sekunden durchgeführt wird, wobei die Primärglühzeit eine Haltezeit bei der Primärglühtemperatur ist,
    worin eine Abkühlgeschwindigkeit während des Abkühlens beim primären Glühen mindestens in dem Temperaturbereich von der Primärglühtemperatur runter auf 550°C 10°C/s oder mehr beträgt,
    worin das sekundäre Glühen bei einer Glühtemperatur gleich oder niedriger als dem Ac3-Punkt für eine Sekundärglühzeit von 10 Sekunden bis einschließlich 100 Sekunden durchgeführt wird, wobei die Glühtemperatur (Primärglühtemperatur - 80°C) bis (Primärglühtemperatur - 30°C) ist, wobei die Sekundärglühzeit eine Haltezeit bei der Sekundärglühtemperatur ist und
    worin beim sekundären Glühen Abkühlen auf eine Abkühlstopptemperatur von 400°C bis 550°C so durchgeführt wird, dass eine Verweilzeit, in der das Stahlblech bei 400°C bis 550°C gehalten wird, 20 Sekunden bis einschließlich 100 Sekunden beträgt.
  6. Verfahren zur Herstellung des hochfesten Stahlblechs gemäß Anspruch 5, das Verfahren nach dem sekundären Glühen ferner umfassend das Durchführen von Abkühlen und das anschließende Durchführen von Galvanisieren.
  7. Verfahren zur Herstellung des hochfesten Stahlblechs gemäß Anspruch 6, das Verfahren ferner umfassend das Durchführen einer Legierungsbehandlung nach dem Galvanisieren.
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JP6384703B1 (ja) * 2017-03-13 2018-09-05 Ｊｆｅスチール株式会社 高強度冷延鋼板とその製造方法
WO2021070639A1 (ja) * 2019-10-11 2021-04-15 Ｊｆｅスチール株式会社 高強度鋼板および衝撃吸収部材ならびに高強度鋼板の製造方法
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Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4816090A (en) * 1986-09-10 1989-03-28 The Broken Hill Proprietary Co., Ltd. Heat treated cold rolled steel strapping
JPH06179922A (ja) 1992-12-12 1994-06-28 Sumitomo Metal Ind Ltd 深絞り用高張力薄鋼板の製造法
JP3304191B2 (ja) 1994-03-29 2002-07-22 川崎製鉄株式会社 耐二次加工脆性に優れる高強度合金化溶融亜鉛めっき鋼板の製造方法
JP3424619B2 (ja) * 1999-09-16 2003-07-07 住友金属工業株式会社 高張力冷延鋼板及びその製造方法
TWI290177B (en) * 2001-08-24 2007-11-21 Nippon Steel Corp A steel sheet excellent in workability and method for producing the same
CN1169991C (zh) * 2001-10-19 2004-10-06 住友金属工业株式会社 具有优异的可加工性和成型精度的薄钢板及其制造方法
AU2003211764A1 (en) 2002-03-18 2003-09-29 Kawasaki Steel Corporation Process for producing high tensile hot-dip zinc-coated steel sheet of excellent ductility and antifatigue properties
JP4205892B2 (ja) 2002-05-23 2009-01-07 新日本製鐵株式会社 プレス成形性と打抜き加工性に優れた高強度熱延鋼板及びその製造方法
JP4640130B2 (ja) 2005-11-21 2011-03-02 Ｊｆｅスチール株式会社 機械特性ばらつきの小さい高強度冷延鋼板およびその製造方法
JP5082432B2 (ja) * 2006-12-26 2012-11-28 Ｊｆｅスチール株式会社 高強度溶融亜鉛めっき鋼板の製造方法
JP5315954B2 (ja) * 2008-11-26 2013-10-16 Ｊｆｅスチール株式会社 高強度溶融亜鉛めっき鋼板およびその製造方法
JP4924730B2 (ja) 2009-04-28 2012-04-25 Ｊｆｅスチール株式会社 加工性、溶接性および疲労特性に優れる高強度溶融亜鉛めっき鋼板およびその製造方法
JP5703608B2 (ja) * 2009-07-30 2015-04-22 Ｊｆｅスチール株式会社 高強度鋼板およびその製造方法
JP5487916B2 (ja) 2009-11-30 2014-05-14 新日鐵住金株式会社 衝突吸収エネルギーに優れた引張最大強度９００ＭＰａ以上の高強度亜鉛めっき鋼板及びその製造方法
CA2850091C (en) * 2011-09-30 2016-06-28 Nippon Steel & Sumitomo Metal Corporation High-strength hot-dip galvanized steel sheet and high-strength alloyed hot-dip galvanized steel sheet having excellent formability and small material anisotropy with ultimate tensile strength of 980 mpa or more and manufacturing method therefor
CN103930585B (zh) * 2011-11-15 2015-07-22 杰富意钢铁株式会社 薄钢板及其制造方法
US10144996B2 (en) 2012-12-18 2018-12-04 Jfe Steel Corporation High strength cold rolled steel sheet with low yield ratio and method of manufacturing the same
JP5821912B2 (ja) * 2013-08-09 2015-11-24 Ｊｆｅスチール株式会社 高強度冷延鋼板およびその製造方法
CN107109572B (zh) * 2015-01-16 2019-09-10 杰富意钢铁株式会社 高强度钢板及其制造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

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