EP3265047A1 - Composition de céramique cosmétique pulvérisable contenant un mélange, procédé pour recouvrir des restaurations dentaires en oxyde de zirconium et restauration dentaire en oxyde de zirconium - Google Patents

Composition de céramique cosmétique pulvérisable contenant un mélange, procédé pour recouvrir des restaurations dentaires en oxyde de zirconium et restauration dentaire en oxyde de zirconium

Info

Publication number
EP3265047A1
EP3265047A1 EP16708633.9A EP16708633A EP3265047A1 EP 3265047 A1 EP3265047 A1 EP 3265047A1 EP 16708633 A EP16708633 A EP 16708633A EP 3265047 A1 EP3265047 A1 EP 3265047A1
Authority
EP
European Patent Office
Prior art keywords
mass
restoration
dental
veneering
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16708633.9A
Other languages
German (de)
English (en)
Inventor
Michael Schmidt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gebrueder Brasseler GmbH and Co KG
Original Assignee
Gebrueder Brasseler GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102015204109.3A external-priority patent/DE102015204109A1/de
Priority claimed from DE102015204186.7A external-priority patent/DE102015204186A1/de
Application filed by Gebrueder Brasseler GmbH and Co KG filed Critical Gebrueder Brasseler GmbH and Co KG
Publication of EP3265047A1 publication Critical patent/EP3265047A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/15—Compositions characterised by their physical properties
    • A61K6/16—Refractive index
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/15—Compositions characterised by their physical properties
    • A61K6/17—Particle size
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/802—Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics
    • A61K6/818—Preparations for artificial teeth, for filling teeth or for capping teeth comprising ceramics comprising zirconium oxide
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/849—Preparations for artificial teeth, for filling teeth or for capping teeth comprising inorganic cements
    • A61K6/853—Silicates

Definitions

  • the present invention relates to a substance mixture for the refining of dental restorations made of zirconium dioxide, comprising a burn-on lithium silicate system and / or feldspar system. Moreover, the present invention relates to a substance mixture for use in a therapeutic method for the treatment of the human or animal body.
  • the present invention relates to a substance mixture for specific use in a method for dental reconstruction, which comprises the following steps: i) in vivo preparation of a tooth to be reconstructed for a zirconia restoration by means of abrasives, ii) impression of the tooth to be reconstructed, iii) dental design and preparation of the zirconia restoration as a white, according to substantially non-reduced dimensional data obtained during the impression, iv) performing a dental in vivo try-in of the white, v) spraying the white body with the mixture, vi) performing a method for Preparation of dental restorations according to any of claims 12 to 14 and vii) attaching the zirconia restoration to the tooth to be reconstructed.
  • the present invention relates to a method of making a dental restoration.
  • the present invention relates to a dental restoration.
  • the optical appearance of a lithium silicate veneer can be adapted particularly well to that of natural tooth material.
  • lithium silicate is less hard than zirconia, which is often preferred by patients.
  • the veneering ceramic is usually built up in layers in several fires, each subsequent layer is burned out at a lower temperature. The disadvantage of this is that this can cause stresses both between layers of the lithium silicate veneer system and between the veneering ceramic and the zirconium dioxide framework. In the worst case, this can lead to later flaking or the so-called "chipping".
  • the separate production of the dental framework made of zirconium dioxide and a veneering of lithium disilicate is described in the prior art, wherein after further processing steps, the separately manufactured veneer on the scaffold shell is taken care of and post-processed if necessary. Silk pieces are then glued together or bonded to a low melting glass solder.
  • WO 2012/062292 discloses a translucent veneering ceramic based on lithium disilicate on yttrium-stabilized zirconium dioxide. It is proposed to glaze the previously known veneering ceramic by local melting at temperatures of about 1000 ° C. or to produce a typical lithium disilicate glass-ceramic veneering layer at low temperatures below 900 ° C.
  • the veneering material is applied to the zirconium framework by brush application according to this prior art of slip dressings or powder emulsions of the previously known veneering ceramic material based on lithium disilicate. Due to the consistency of the slip dressings or powder emulsions, however, the safe repeatability of the veneering firing is disadvantageous because the layer thicknesses on application to the zirconium framework are difficult to control.
  • EP 1 546 052 B1 and WO 2004/009503 A1 make sprayable opaquers, ie ceramic primers and transparent glazes or gloss layers, as a substitute for ceramic materials previously applied manually by brush technique in the context of a traditional layering for metal ceramics.
  • they should first apply an opaque opaque ceramic layer ("coating"), which completely covers the metal framework in the visible range.
  • opaque firing then follows the previously described stratification of Veneering. Layer by layer, different colored dentin, incisal and enamel compounds and stains are applied and each separately fired. After the final polishing of the layering, the veneering is sealed with a sprayable transparent ceramic glaze.
  • the object of the present invention is to provide a substance mixture for the refining of dental restorations made of zirconium dioxide, comprising a burn-on lithium silicate system and / or feldspar system, as well as a method for the production of dental restorations, which determine the production and enable the installation of dental reconstructions with improved optical and mechanical properties quickly and inexpensively, bypassing the disadvantages of the prior art.
  • the invention is further based on the object of specifying optimum matching of the two ceramic components zirconium oxide and lithium silicate in order to achieve maximum usability of such dental restorations in terms of physical, chemical, biocompatible, dental-functional and aesthetic properties.
  • the object directed to a substance mixture is a mixture of substances of the type mentioned above, in which the lithium silicate system and / or feldspar system is present in a dispersion with a volatile, preferably organic, liquid, at least under normal conditions. Due to the admixture of a volatile liquid, the mixture of substances is advantageously sprayable. It is therefore advantageously possible to detect the substance mixture according to the invention on a zirconium dioxide white body, whereby a reproducible layer thickness, which is, for example, in the range of 1 .mu.m to 50 .mu.m, reproducibly adjusts itself.
  • the organic liquid contains a, preferably heavy, alcohol, in particular propanol, preferably isopropanol. It has been found that, in particular, isopropanol, owing to the comparatively low boiling point, has the required volatility in an advantageous manner. At the same time, in particular, isopropanol, but also other alcohols, have proved particularly suitable for the spray application of the lithium silicate glass ceramic mass.
  • the lithium silicate system and / or the feldspar system have a particle size is present between 0.3 pm and 50 pm, that is to say as powdered lithium silicate.
  • a lithium silicate glass fused at 1400 ° C is fritted in water, then annealed for nucleation at a temperature of 940 ° C to 950 ° C for a period of time to be mechanically pulverized after cooling to the desired grain size interval.
  • the pulverized lithium silicate system and / or feldspar system is based on the dispersion in one Mass ratio to the liquid in the range 1: 0.2 to 1: 8.0 before.
  • the specified ratio refers only to the dispersion itself, wherein any further constituents of the mixture according to the invention are not included in the ratio. It has been found within the scope of the invention that in the specified interval of the mass ratios, the sprayability is maintained on the one hand and on the other hand, the suitable layer for coating processing by spraying on the zirconia body is controllable.
  • the dispersion is present in a volume fraction of between 0.3% by volume and 50.0% by volume. Outside the stated interval, the sprayability is not sufficient, so that the generation of uniform, thin layers of lithium silicate system and / or feldspar system on the zirconia body can fail.
  • a propellant in particular selected from: 1,1,1,2-tetrafluorethane, propane and / or butane, 2,3,3,3-tetrafluoropropene, 1,3,3,3- Tetrafluoropropene and C0 2 .
  • the propellant gas preferably comprises R134a and / or HF0-1234ze.
  • the name of said special propellant gases refers to DIN 8960, according to which in particular R134a refers to 1, 1, 1, 2-Tetrafiuorethan.
  • the mixture of substances can be stored in this embodiment in the context of the invention in a spray can and according to the invention well homogenized by the propellant within the spray can by appropriate shaking and carried out with high Austriebsrate from the spray as a fine spray.
  • HF0-1234ze ie 1, 3,3,3-tetrafluoropropene, represents a particularly environmentally friendly alternative, with which according to the invention also good spray results can be realized.
  • the propellant gas in a volume ratio to the dispersion and / or the lithium silicate system and / or feldspar system is present in the range from 50% to 97%.
  • n) fluoride 0.0-4.0 Ma.% wherein preferably the first mold to the second mold in a mass ratio in the range of 0.1: 1 to 10: 1 is present.
  • the first form and / or the second form as coloring or fluorescent additives pigments and / or dioxides or fluorides of the following Elements Fe, Sn, Ce, Mn, V, Cr, Pr, Tb, Nd, Sm, In, Eu, Dy contained singly or in combination.
  • coloring additives or pigments attention must be paid to the interaction with the base color of the zirconium framework. Because this may already have a pre-coloring, which is customized to a patient, so that the body can already have a custom color. Surprisingly, the abovementioned additives do not impair the spray behavior of the substance mixture according to the invention.
  • the finished fired surface coating of lithium silicate is not transparent in the sense of a glaze, but highly translucent and, in interaction with the pre-colored zirconium oxide, produces near-natural color effects which are controlled by non-opaque colorations of the lithium silicate.
  • the surface treatment alone does not form a tooth-colored layer.
  • optical effects not previously achieved also arise.
  • Specifically adjusted coloring additives in the lithium silicate system as described above, according to the invention make it possible to shift defined for a tooth color defining hue, chroma, value values of the pre-colored zirconia.
  • the object of the invention is based equally solved by a mixture for use in a therapeutic method for the treatment of the human or animal body, wherein the mixture of substances according to one of claims 1 to 9 is configured.
  • the object is achieved by a substance mixture for specific application in a method for dental reconstruction, which comprises the following steps: i) in vivo preparation of a tooth to be reconstructed for a zirconia restoration by means of abrasives, ii) impression of the tooth to be reconstructed, iii) dental technology Design and manufacture of the zirconia restoration as a body, in accordance with substantially non-reduced dimensional data obtained during the impression, iv) performing a dental in vivo try-in of the body, v) spraying the body with the composition, vi) performing an after one of claims 12 to 14 and vii) attaching the zirconia restoration on the tooth to be reconstructed, which is designed according to one of claims 1 to 9.
  • the impression of the tooth to be reconstructed in the context of the invention can be done digitally or by classical spoon impression.
  • the dental technical design can take place by CAD / CAM or in classical wax technique, whereby the anatomical tooth shape of the restoration experiences only minimal reductions for the consideration of the veneering strength and possibly bite increases in the final insertion in patients.
  • the preparation of the zirconia restoration can be carried out by CNC milling, additive processes or manual milling as a zirconia white body, preferably of zirconium oxide pre-dyed in tooth colors. Possibly. can be carried out according to the invention, a manual reworking on white and minimizing the milling tracks.
  • a tooth-colored design of the zirconium as well as reinforcement of translucent areas by infiltration of the white body can be made with suitable commercially available liquids.
  • a sintering of the white compact can be made according to the zirconia manufacturer's specifications for final hardness. It is preferably a model sample and possibly a grinding of crown margins and the occlusion.
  • a dental in vivo try-in of the sintered zirconia structure of the white body, corrections on the zirconia body, such as streaking of occlusion and contact points can be performed.
  • a cleaning of the zirconium restoration can be carried out by means of a steam jet.
  • any conventional surface preparation for the veneering can be dispensed with in the prior art.
  • spraying of the zirconium oxide restoration with the substance mixture according to the invention preferably takes place. Due to the above-highlighted advantageous properties of the composition according to the invention in terms of sprayability surprisingly, the preparation of the final dental restoration in an overall process on the spot at the dentist by the dentist or by its technician can be done with advantage. In doing so, the dentist can grind in the necessary adjustments to the zirconium body during the try-in of the zirconium framework. Subsequently, the zirconium framework can be sprayed with the substance mixture according to the invention by the dentist. No special experience or skills are required for this.
  • the zirconium oxide restoration can then be sprayed directly with the substance mixture according to the invention. No special experience or skills are required for this.
  • the subsequent short sintering of the thin lithium silicate layer can be carried out within a patient appointment directly on site at the dentist with a conventional ceramic oven. After a few minutes, the burning process is complete.
  • the dentist can advantageously save more natural tooth mass substance-saving.
  • the mechanical strength is determined by the Zirkonbasis, the lithium silicate surface finishing does not require mechanically relevant strength, since the veneering layer has a thickness of, for example, 1 pm to 50pm. This is usually negligible even in dental practice.
  • the object directed to a method is achieved by a method for producing a dental restoration, wherein a raw veneer layer of a composition according to one of claims 1 to 11 is sprayed onto a dental restoration made of zirconium dioxide, wherein the restoration substantially the outer dimensions and / or the Form of the tooth to be restored is allowed to vent the restoration, the restoration is subjected to a temperature treatment to produce a mutually diffused composite layer between the dental restoration and the Rohverblendtik by the Rohverblend harsh is crystallized into a veneer.
  • the restoration can be subjected to a temperature treatment of 850-950 ° C., and the raw veneering layer, which will generally be a powder layer, is melted to form a veneering layer and partially or completely vitrified. there This results in a mutually diffused composite zone between the zirconium oxide and the lithium silicate.
  • the surfaces are advantageously pore-free and smooth and the surface hardness of the zirconium oxide is reduced by more than 50% due to the lithium coating. This significantly reduces the risk of abrasion for antagonists.
  • the resulting by mutual diffusion and tuned coefficients of thermal expansion bond provides the invention advantageously with a low-stress surface without tendency to chipping, cracking or chipping.
  • the inventive method can be carried out quickly and easily with advantage after a short learning phase and not specially trained people circles. Due to the small layer thickness of the applied lithium silicate, the zirconia may advantageously have substantially the outer dimensions of the tooth to be restored. This eliminates advantageously a common cause of the need for reworking onsolidling.
  • the temperature treatment is carried out at a temperature in the interval 850 ° C to 950 ° C.
  • the mentioned temperature interval there is an optimum with regard to the sintering of the raw veneer layer from the mixture of substances according to the invention and with regard to the heating of the zirconium base.
  • the zirconium base is not yet deformed in the said temperature interval, but it heats up in such a way that a mutually diffused composite layer is obtained between the dental restorations and the raw veneer layer by crystallizing the raw veneer layer into a veneering layer.
  • the Rohverblend Mrs is removed to correct errors before the temperature treatment and then sprayed again, the removal is preferably carried out by washing with water, evaporation and / or by means of compressed air.
  • the thin spray layer can advantageously be removed by the methods mentioned for the purpose of correction without any problem.
  • a dental restoration by a dental restoration, which by a method can be produced according to one of claims 12 to 14, wherein the veneering layer has a thickness in the range of 1, 0 pm to 50 pm.
  • a dental restoration according to the invention combines the advantageous properties of a full ceramic construction of zirconium dioxide in terms of biocompatibility and hardness with the advantageous properties of lithium silicate system and / or feldspar system in terms of optical appearance and lower hardness and is at the same time simpler and less expensive to produce than conventional Zirconia dentures with conventional veneers.
  • a sprayable veneering of zirconium dioxide dental restorations with lithium silicate is generally proposed, wherein advantageously the self-adjusting coating can be overburned with identical or different dental ceramic systems at the same or higher or lower temperature, without loss of dimensional stability or of the adhesive bond to suffer.
  • a sprayable veneering of zirconium dioxide dental restorations with a lithium silicate system is generally proposed, wherein the resulting coating advantageously effects a specific controllable change in the perceived tooth color, without the applied and fired layer itself reflecting the perceived coloration or color change.
  • the dentist To reconstruct a tooth to be reconstructed, the dentist first prepares the tooth to be reconstructed by means of abrasives for a zirconium dioxide restoration. In this case, more tooth substance can be retained, since no additional mass for the veneering ceramic must be removed. Subsequently, the dental design data are recorded and the zirconia restoration up to is done in a known manner. The resulting white compact essentially has the dimensions of the finished implant, since the thickness of the veneer layer is virtually negligible.
  • the mixture of substances in said composition is, after vigorous shaking of the spray bottle in which the mixture is stored, preferably at least 3 minutes, at room temperature, ie 15 to 25 ° C, sprayed onto the zirconia surface to be veneered.
  • the spraying should take place in well-ventilated rooms, which are equipped with a suitable extraction system.
  • the finished sintered and fitted zirconia restoration must be dry, clean, free of dust and grease.
  • no special surface preparations, adhesion promoters, solvents or preparatory fires are required.
  • the spraying should be done at a distance of about 5 to 10 cm with short small sprays for an optimal application.
  • the optimal spray distance of 5 cm to 10 cm results in a spray cone of about 1 cm, which ensures that the dental restoration is uniformly thin coated with the powdered lithium silicate.
  • the sprayed mixture of substances according to the invention should still be moist when hitting the zirconium dioxide restoration, but should not run. It should always be like this be sprayed strongly that shimmers through the raw veneer layer nor the zirconium surface.
  • the carrier liquid releases completely after a few seconds and leaves a thin white powder layer, which adheres well to the zirconia surface.
  • the ceramic fire is carried out as follows. The exact values for the heating and cooling rate as well as for the upper holding time depend on the mass of the zirconium dioxide structure which is to be blended. For larger restorations, the hold time must be extended and the cooling process slowed down.
  • Drying time 1 minute
  • standby temperature 400 ° C to 500 ° C
  • heating rate 20 Kelvin per minute to 100 Kelvin per minute, preferably 90 ° C per minute
  • holding temperature: 720 ° C to 840 ° C preferably 820 ° C
  • further heating rate 100 Kelvin per minute to 80 Kelvin per minute, preferably 20 degrees per minute
  • final temperature 850 ° C to 950 ° C, depending on the desired structure
  • Holding time 0 to 15 minutes, preferably 5 minutes, then long-term cooling at a suitable cooling rate.
  • the surface With proper preparation of the zirconium base, that is, with a carefully finished white body with individual color design and subsequent sintering, the surface will be dense and sufficiently sizing after the above firing to seal even with only one thin layer all remaining traces of processing.
  • Previously finished with the sintered zirconia finishes remain sharp, fine bumps in the zirconium are cured according to the invention by the lithium silicate veneer.
  • the glossy surface does not require polish with advantage.
  • the veneering layer can be corrected with advantage in exceptional cases with fine diamonds, if this should be exceptionally necessary.
  • the invention further relates to a sprayable veneering ceramic composition for dental restorations made of zirconium dioxide (ZrO 2 ), which, after a ceramic firing, enables improved adhesion to the ZrO 2 substrate compared to known dental veneering ceramics. Furthermore, the present invention relates to a method for the spray-coating of dental restorations of Zr0 2 and to a dental restoration produced by the method.
  • the veneering ceramic composition according to the invention comprises a mixture of substances as described above.
  • the veneering ceramic composition is preferably in the form of a dispersion and comprises a disperse phase and a dispersion medium.
  • the disperse phase contains a ceramic material which is in the form of a powdered glass ceramic, and after application to a ZrO 2 restoration and thermal treatment forms a vitreous coating which is modeled on the natural tooth enamel.
  • the pulverized glass ceramic according to the invention comprises Si0 2 , Nb 2 0 5 , Al 2 0 3 , Li 2 0, Na 2 0 and Zr0 2 and may additionally contain other ceramic materials.
  • the ceramic compounds of the disperse phase are thus converted into a glass and are in powder form and substantially insoluble in the surrounding dispersion medium.
  • Isopropanol, ethanol or ethylene glycol is used as the dispersion medium, these alcohols can be used individually or in any mixture.
  • the alcohols according to the invention, and in particular isopropanol have proved to be optimum dispersants, since these alcohols have a high evaporation rate and a good dispersibility for ceramic powders, which suppresses agglomeration of the ceramic powders.
  • the veneering ceramic composition according to the invention also contains at least one propellant. It has been found that the very good powder-like fine distribution of the ceramic material in the dispersion medium facilitates the spraying of the veneering ceramic composition, whereby a uniform ceramic film can be applied to the surface of a ZrO 2 restoration.
  • the high evaporation rate of the alcohols used according to the invention isopropanol and / or ethanol and / or ethylene glycol
  • the Ceramic powder is thus evenly on the Zr0 2 surface, without it can lead to slipping or dripping of the veneering ceramic composition.
  • the spray application according to the invention requires far less skilled craftsmanship of the dental technician than a liquid application or paste application.
  • the sprayable veneering ceramic composition according to the invention is thus easily applicable and allows the formation of a glass layer with increased adhesion between the ceramic glass layer in the boundary region to the zirconium dioxide base body.
  • the zirconia body for the dental restoration conventional zirconia materials and yttrium-stabilized zirconia materials are used.
  • the disperse phase has a grain size of a maximum of 63 mesh, in particular of at most 75 mesh on.
  • the powdered glass-ceramic phase is characterized by a very small grain size, which improves the adhesion of the powder on the zirconia surface of the dental restoration.
  • a uniform application with the desired layer thickness is promoted, since the grain size promotes the fine distribution of the ceramic powder both in the dispersion medium and in the spray output.
  • the veneering ceramic composition according to the invention is advantageously characterized in that a mass ratio of disperse phase to the alcohol used in the dispersion medium, namely isopropanol and / or ethanol and / or ethylene glycol, 1: 0.2 to 1: 8.0 and in particular 1: 0 , 3 to 1: 6.0.
  • the stated mass ratio makes it even easier to form spray nozzles and thus drip off the veneering ceramic composition from the applied surface be prevented.
  • the proportion of volatile alcohol based on the ceramic powder is thus just so high that a very good dispersion is achieved and just so low that the evaporation is particularly fast.
  • the blowing agent is selected from: 1,1,1,2-tetrafluoroethane, propane / butane, 2,3,3,3-tetrafluoropropene and CO 2 .
  • An environmentally preferred propellant is 1,3,3,3-tetrafluoropropene.
  • a particularly fine droplet size of the spray aerosol and thus an even better distribution of the ceramic powder while increasing the adhesion to the Zr0 2 basic body is achieved by the advantageous development in which a volume ratio of a total volume of the disperse phase and of the alcohol (isopropanol and / or ethanol and or ethylene glycol) to the volume of propellant is 3:97 to 30:70.
  • the sprayable veneering ceramic composition according to the invention also advantageously contains the following composition: 1 part by weight of disperse phase, 0.2 to 5 parts by weight of isopropanol and / or ethanol and / or ethylene glycol and 1 to 12 parts by weight of blowing agent.
  • the pulverized glass ceramic in the disperse phase of the sprayable veneering ceramic composition may further comprise from 0.1 to 9.0 mass% of polymeric lacquer formers.
  • B 2 0 3 may be added.
  • An advantageous veneering ceramic composition is characterized in that the pulverized glass ceramic in the disperse phase based on the total mass of the disperse phase 55.0-72.5 mass% Si0 2 , 6.0-19.8 mass% Nb 2 0th 5 , 1, 2-6.0 mass% Al 2 O 3 , 5.0-16.5 mass% Li 2 0, 1, 4-11, 0 mass% Na 2 O and 0.5-4 , 0 mass% Zr0 2 contains.
  • the pulverized glass ceramic of the disperse phase based on the total mass of the disperse phase contains 58.0-68.0 mass% Si0 2 , 10.0-19.8 mass% Nb 2 O s , 1, 2 -6.0 mass% Al 2 O 3 , 8.0-16.5 mass% Li 2 0, 1, 4-8.0 mass% Na 2 O and 0.5-4.0 mass% Zr0 2 .
  • the powdered glass ceramic contains the disperse phase of the sprayable ceramic veneering composition according to the invention preferably further at least one compound selected from: Ti0 2 , La 2 0 3 , MgO, CaO, ZnO, BaO, P 2 0 5 and a fluoride, wherein a total concentration of these compounds not more than 4 mass -% based on the total mass of the powder constituents of the disperse phase.
  • the pulverized glass ceramic may contain, as coloring or fluorescent additives, pigments and oxides or fluorides of the following elements: Fe, Sn, Ce, Mn, V, Cr, Pr, Tb, Nd, Sm, In, Eu, Dy, individually or in combination, which exclude both the color-neutral transparent character of a typical dental ceramic glaze and the opaque character of dental opaquers, liners and the like, for the veneering layer.
  • a method for coating dental restorations made of zirconium dioxide comprises the steps of i) spraying the above-described sprayable veneering ceramic composition onto a dental restoration of zirconia having a layer thickness of 0.1 to 100 ⁇ m, in particular of 1 to 10 ⁇ m and ii) heating the veneering ceramic composition coated restoration a temperature between 840 ° C and 950 ° C for a period of 0.1 to 2 hours.
  • a minimum layer thickness of 0.1 to 100 pm, and preferably from 1 to 30 pm is sufficient to produce mechanically highly durable surface coatings with high security against chipping and chipping. Thin layers of conventional layered or brushed dental ceramics do not provide this.
  • the spray application according to the invention shows particularly good application results.
  • a stable veneering ceramic coating can be applied, which is distinguished by a good and durable adhesive bond between the Zr0 2 material of the dental restoration and the ceramic coating.
  • the process also requires a low level of craftsmanship, so it is easy to apply with good results.
  • a dental restoration made of zirconium dioxide is also described according to the invention. It is characterized by a permanently stable veneer, which meets the high aesthetic requirements of a denture material.
  • the dental restoration according to the invention can be obtained by the method described above and in particular has a layer thickness of the veneering ceramic of 0.1-100 ⁇ m. Further details, advantages and features of the present invention will become apparent from the following description of an embodiment with reference to the drawing. 1 shows a schematic sectional representation of a dental restoration
  • FIG. 1 shows a dental restoration 1 according to an embodiment of the invention.
  • the dental restoration 1 comprises a base body 2 made of zirconium dioxide. In this case, yttrium-stabilized zirconium dioxide can also be used.
  • a veneering ceramic 3 is arranged in the form of a glassy coating.
  • the veneering ceramic 3 was obtained by spray application of a veneering ceramic composition.
  • the veneering ceramic composition comprised a disperse phase and a dispersion medium.
  • the disperse phase contained a pulverized glass which, based on the total mass of the disperse phase, was 55.0-72.5 mass% Si0 2 , 6.0-19.8 mass% Nb 2 O 5 , 1, 2-6, 0% by mass of Al 2 O 3> 5.0-16.5% by mass of Li 2 O, 1, 4-11, 0% by mass of Na 2 O and 0.5-4.0% by mass of ZrO 2 ,
  • the pulverized glass was exemplified by the fact that from the ceramics Si0 2 , Nb 2 0 5 , Al 2 0 3 , Li 2 0, Na 2 0 and Zr0 2 and optionally other ceramic materials (eg: B 2 0 3 ) Melting at temperatures around 1400X a glass was prepared which was then fritted and further annealed for nucleation at a temperature of 480 ° C to 590 ° C for a period of two to six hours, and then pulverized.
  • the sprayable veneering ceramic composition contained isopropanol.
  • the sprayable veneering ceramic composition contained at least one propellant, preferably 1, 1, 1, 2-tetrafluoroethane.
  • Another possible particularly environmentally friendly blowing agent is preferably 1, 3,3,3-tetrafluoropropene.
  • a grain size of the disperse phase was a maximum of 75 mesh.
  • a mass ratio of disperse phase to isopropanol was 1: 0.2 to 1: 8.0.
  • the sprayable veneering ceramic composition was applied from a pressure vessel with a volume ratio of a total volume of disperse phase and isopropanol to the volume of the propellant being 3:97 to 30:70.
  • the uniform particle distribution of ceramic powder already present in the spray composition was also uniformly transferred to the surface of the base body 2, so that a fine layer thickness D of 0.1 to 100 ⁇ m was formed, which was sufficient for a good veneer and also low that a peeling of the ceramic coating was prevented after appropriate thermal treatment to form a vitreous Keramikverblendung. Due to the low layer thickness application in combination with the sprayable veneering ceramic composition according to the invention, a very good bond between the Zr0 2 base body 2 and the veneering ceramic 3 was achieved.

Landscapes

  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Public Health (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Dental Preparations (AREA)

Abstract

Pour donner un mélange permettant d'améliorer les restaurations dentaires en oxyde de zirconium, comprenant un système de silicate de lithium et/ou un système de feldspath surcalcinable, ainsi qu'un procédé pour fabriquer une restauration dentaire permettant la fabrication et la pose de reconstructions dentaires ayant de meilleures propriétés optiques et mécaniques de manière rapide et économique tout en évitant les inconvénients de l'état de la technique, on propose que le système de silicate de lithium et/ou le système de feldspath se trouve(nt) dans une dispersion avec au moins un liquide, de préférence organique et volatil en conditions normales ou qu'une couche cosmétique brute en mélange de matériaux de ce type soit pulvérisée sur une restauration dentaire en oxyde de zirconium. La restauration présente essentiellement les dimensions globales de la dent à restaurer, qu'on laisse la restauration sécher et que l'on soumette la restauration à un traitement thermique afin de produire une couche composite diffusée de manière réciproque entre la restauration dentaire et la couche cosmétique brute en laissant cristalliser la couche cosmétique brute en une couche cosmétique finale.
EP16708633.9A 2015-03-06 2016-03-02 Composition de céramique cosmétique pulvérisable contenant un mélange, procédé pour recouvrir des restaurations dentaires en oxyde de zirconium et restauration dentaire en oxyde de zirconium Withdrawn EP3265047A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102015204109.3A DE102015204109A1 (de) 2015-03-06 2015-03-06 Sprühbare Verblendkeramik-Zusammensetzung, Verfahren zur Beschichtung von dentalen Restaurationen aus Zirkoniumdioxid und dentale Restauration aus Zirkoniumdioxid
DE102015204186.7A DE102015204186A1 (de) 2015-03-09 2015-03-09 Stoffgemisch, Verfahren zur Herstellung einer dentalen Restauration und Dentalrestauration
PCT/EP2016/054421 WO2016142234A1 (fr) 2015-03-06 2016-03-02 Composition de céramique cosmétique pulvérisable contenant un mélange, procédé pour recouvrir des restaurations dentaires en oxyde de zirconium et restauration dentaire en oxyde de zirconium

Publications (1)

Publication Number Publication Date
EP3265047A1 true EP3265047A1 (fr) 2018-01-10

Family

ID=55486642

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16708633.9A Withdrawn EP3265047A1 (fr) 2015-03-06 2016-03-02 Composition de céramique cosmétique pulvérisable contenant un mélange, procédé pour recouvrir des restaurations dentaires en oxyde de zirconium et restauration dentaire en oxyde de zirconium

Country Status (2)

Country Link
EP (1) EP3265047A1 (fr)
WO (1) WO2016142234A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019166920A1 (fr) 2018-02-28 2019-09-06 3M Innovative Properties Company Kit de pièces et procédé de cuisson rapide d'un article en zircone poreuse en combinaison avec un agent de traitement de surface contenant une poudre de verre
WO2020049432A1 (fr) 2018-09-04 2020-03-12 3M Innovative Properties Company Composition de vernissage fluorescent pour article de zircone dentaire, procédé de frittage et kit de pièces
CN112638349A (zh) 2018-09-04 2021-04-09 3M创新有限公司 用于牙科氧化锆制品的上釉组合物、烧结方法以及套件盒
CN110040963A (zh) * 2019-03-29 2019-07-23 合肥卓越义齿制作有限公司 一种贵金属烤瓷牙用象牙白釉料及其使用方法
CN111470882B (zh) * 2020-03-02 2022-11-15 北京大学口腔医学院 一种用于牙科的氧化锆表面处理方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6059949A (en) 1997-04-23 2000-05-09 Cerel (Ceramic Technologies) Ltd. Method of electrophoretic deposition of ceramic bodies for use in manufacturing dental appliances
US7018465B2 (en) 2002-07-22 2006-03-28 Enamelite, Llc Aerosolized ceramic porcelains and glaze composition
WO2011098115A1 (fr) * 2010-02-09 2011-08-18 Vita Zahnfabrik H. Rauter Gmbh & Co. Kg Procédé pour l'amélioration de la stabilité de zircone stabilisée par de l'yttrium pour des restaurations dentaires
DE102010035545A1 (de) 2010-08-24 2012-03-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verblendkeramik für dentale Restaurationen aus yttriumstabilisiertem Zirkoniumdioxid sowie Verfahren zu deren Auftrag

Also Published As

Publication number Publication date
WO2016142234A1 (fr) 2016-09-15

Similar Documents

Publication Publication Date Title
EP3558671B1 (fr) L'utilisation de corps multicouche en céramique oxydée présentant un comportement au frittage adapté
US9668838B2 (en) Dental block
WO2016142234A1 (fr) Composition de céramique cosmétique pulvérisable contenant un mélange, procédé pour recouvrir des restaurations dentaires en oxyde de zirconium et restauration dentaire en oxyde de zirconium
DE19904522C5 (de) Einfärbung von keramischem Zahnersatz mittels ionischer oder komplexhaltiger Lösungen
US6626986B2 (en) Low-temperature-sintering potassium-zinc-silicate glass
DE10031431B4 (de) Tiefsinterndes Kalium-Zink-Silicat-Glas und dessen Verwendung
EP3829482B1 (fr) Ébauche multicolore à des fins dentaires
EP3013278B1 (fr) Coloration de céramique poreuse
EP2287122B1 (fr) Vitrocéramique de phosphosilicate
DE102015122861A1 (de) Verfahren zur Herstellung eines Rohlings, Rohling sowie eine dentale Restauration
EP3601199B1 (fr) Procédé de fabrication d'un corps en céramique émaillée
DE102015204109A1 (de) Sprühbare Verblendkeramik-Zusammensetzung, Verfahren zur Beschichtung von dentalen Restaurationen aus Zirkoniumdioxid und dentale Restauration aus Zirkoniumdioxid
EP3366260B1 (fr) Procédé de fabrication d'une prothèse dentaire
EP1167311B1 (fr) Vitrocéramique en apatite à basse température de frittage
DE10045663A1 (de) Dentales pastenähnliches Prozellan
EP0847375B1 (fr) Composition de verre de silicate et procede de modification de materiaux ceramiques
EP2045218B1 (fr) Glaçure destinée au revêtement de surfaces
EP1905412B1 (fr) Verre pour utilisation dentaire
DE102015204186A1 (de) Stoffgemisch, Verfahren zur Herstellung einer dentalen Restauration und Dentalrestauration
WO2013090860A1 (fr) Bloc dentaire
EP3733618A1 (fr) Vitrocéramique à faible point de fusion
DE19834106C2 (de) Strahlmittel auf Basis silikatischer Dentalkeramik
DE202019100979U1 (de) System und Kit zur Färbung von Dentalkeramik
DE102004041687A1 (de) Verfahren zur Herstellung eines Verbundes zwischen Titan und Keramik ohne Bonder für Zahnersatz sowie ein daraus hergestellter Verbund zwischen Titan und Keramik ohne Bonder für Zahnersatz
EP3189826B1 (fr) Conditionnement de la surface de composants dentaires

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20170704

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20181002

RIC1 Information provided on ipc code assigned before grant

Ipc: A61K 6/00 20200101AFI20200313BHEP

Ipc: A61K 6/849 20200101ALI20200313BHEP

Ipc: A61K 6/80 20200101ALI20200313BHEP

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20200514

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20200925