EP3259235A1 - Dispositif électrochimique produisant une teneur en liquide de désinfection (ozone, chlore actif, peroxyde d'hydrogène) - Google Patents
Dispositif électrochimique produisant une teneur en liquide de désinfection (ozone, chlore actif, peroxyde d'hydrogène)Info
- Publication number
- EP3259235A1 EP3259235A1 EP13884589.6A EP13884589A EP3259235A1 EP 3259235 A1 EP3259235 A1 EP 3259235A1 EP 13884589 A EP13884589 A EP 13884589A EP 3259235 A1 EP3259235 A1 EP 3259235A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- solution
- cell
- tank
- disinfection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 42
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000000460 chlorine Substances 0.000 title claims abstract description 14
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 14
- 239000007788 liquid Substances 0.000 title claims abstract description 12
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 89
- 239000000243 solution Substances 0.000 claims abstract description 33
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 21
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims abstract description 8
- 244000005700 microbiome Species 0.000 claims abstract description 8
- 230000008029 eradication Effects 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 239000012266 salt solution Substances 0.000 claims abstract description 5
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- 238000003860 storage Methods 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 8
- 238000005259 measurement Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 238000013461 design Methods 0.000 claims description 4
- 241000894006 Bacteria Species 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 230000036541 health Effects 0.000 claims description 2
- 230000007246 mechanism Effects 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000004457 water analysis Methods 0.000 claims description 2
- 239000000047 product Substances 0.000 claims 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 2
- 239000012263 liquid product Substances 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000006193 liquid solution Substances 0.000 abstract description 3
- 238000012824 chemical production Methods 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 238000010586 diagram Methods 0.000 description 45
- 210000004027 cell Anatomy 0.000 description 27
- 230000008569 process Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 210000005056 cell body Anatomy 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910000457 iridium oxide Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011045 prefiltration Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4616—Power supply
- C02F2201/4617—DC only
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4618—Supplying or removing reactants or electrolyte
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Definitions
- Electrochemical device producing fully complex disinfection liquid solution content (ozone, active chlorine, hydrogen peroxide) in liquid form
- the solution can by generated by passing the original water through the electrolysis cell that content the suitable metal electrode after adding the salt solution (sodium chloride - NaCL) to raw water, a DC voltage is applied between the electrodes, leading to the electrolysis of the water.
- the complete solution production liquid of the device can be storage in collect tank to be ready to use, the generated disinfection solution can be used for many fields that they need sterilization instead of using any other chemical production.
- Electrochemical water disinfection is a rarely used but convenient and highly efficient way to produce germ-free water.
- the technique works without the addition of chemical compounds to the water to be treated, but is nevertheless based on the biotical action of various chemical Substances
- Electrochemical water disinfection can be defined as the eradication of microorganisms by using an electric current passed through the water under treatment by means of suitable electrodes. At the phase boundary between the electrodes and the water, the electric current leads to the electrochemical production of disinfecting species from the water itself, (For example, ozone), or from species dissolved in the water (for example, chloride is oxidized to free chlorine).
- Electrode materials for electrochemical water disinfection have been developed and optimized only in the last forty years. These are titanium electrodes with mixed oxide coatings based on iridium and/or ruthenium oxide, and doped diamond electrodes.
- the solution can by generated by passing the original water through the electrolysis cell that content suitable metal electrode after adding the salt (sodium chloride - NaCL) to water, a DC voltage is applied between the electrodes, leading to the electrolysis of the water.
- salt sodium chloride - NaCL
- This tank content the original water to be the main source for the water needed in the system, it's selected with suitable capacity according to the system capacity, this tank provide with mechanical level float to refill the tank with the original water when the level decreased, it is provide with low level sensor (diagram -PI-SY) part-Al, connected to control panel of the system
- This tank content the dilution water and salt to be the source of the chloride needed in the system, it's selected with suitable capacity, this tank provide with mechanical level float and electric valve to refill the tank with the original water when the level decreased. It is provide with low level sensor (diagram -PI-SY) part-A2 connected to control panel of the system, salt is added by manual when the salt concentration is low- Product tank(diagram -PI-SY) part-26
- the disinfection solution product is collects in this tank to be ready to dose in the water under treat or to be use for any other disinfection application; this tank should be made from anti corrosive material with suitable capacity, provided with level sensor (diagram -PI-SY) part-A3 to stop the system when the tank is full
- this tank should be made from anti corrosive material with suitable capacity
- the system provided with special pump that can give suitable flow and pressure according to the system capacity, this pump drag the original water from the water tank at the same time this pump is used for water and acid washing
- the dosing pump used to dose the salt solution with the original water to increase chloride ion in the water, a suitable adjustment dose is equipped according to the system capacity, and this pump is working with full automatic control via the control unit PLC
- the cell content the metal electrode that can issue the chemical equation to produce the disinfection solution the cell is provided with suitable voltage and current
- the electric board has all the electric components with all relay, contactor and other necessary protection device and the suitable power supply for all system parts
- the PLC program startup and the display screen (HMI) will show all the information about system parts as in the figure -1
- the cell's power has circuit breaker protection provided with limit set point to adjust the necessary current value, this alarm activated when the circuit breaker shut down the power if the limit ampere is over, new screen will display the responsible massage as figure -14
- the cell's power has voltage measurement instrument provided with limit set point to adjust the necessary voltage value, this alarm activated when the voltage value is out of limit set point for high and low, new screen will display the responsible massage as figure-
- the system is providing with current measurement unit with tow limit set point for low and high, when the passing current through the electrode arrived to the limit set point, the current measurement unit gives signal to the PLC, when the PLC get this signal, the PLC will know the product solution has good quality for disinfect, at this time start signal for the 2 way Electric valve for product (diagram -PI-SY) part-18 to open, and 2 way Electric valve for drain (diagram -PI-SY) part-19 to close.
- a pulse counter (diagram -PI-SY) part-6 is providing to give pulse signal to the PLC to calculate on line flow rate and total production.
- the system has automatic or manual washing and cleaning procedure, first washing is done using original raw water with downstream flow direction to discharge all the solid that can be generate into the electrolysis cell during operation, when the first washing begin, the feed pump start working to push original water into the system via 3way inlet valve that will turn on to let original water go into the electrolysis cell from the upper inlet side (diagram -PI- CELL) part-22, and 2 way Electric valve for discharge (diagram -PI-SY) part-14 will open, after 1 minutes, second washing will start, this washing is done with upstream flow direction by Acid to remove scaling formation, the acidic solution is provided to the system by the Acid tank (diagram -PI-SY) part-2 when the second washing begin the feed pump will start working and 2 way Electric valve for Acid drag (diagram -PI-SY) part-4 will open to allow the acid solution goes into the system, 3way inlet valve that will turn to let the acid solution go into the electrolysis cell from the bottom inlet side (diagram -PI-CELL) part-21, during all the time
- the product solution has very strong activity to eradication of microorganisms without any other chemical needed to add and maybe able to be dangerous for the human healthy or for ambience environment
- the dose can be started from lmL/L to 3mL/L
- For wastewater can be started from 5 to 15mL/L or can be calculate according to water analysis
- the disinfection product has full safety for human health Activated and efficient biocide
- Electrolysis cell (PI-CELL)
Abstract
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SY2013/000001 WO2014185868A1 (fr) | 2013-05-15 | 2013-05-15 | Dispositif électrochimique produisant une teneur en liquide de désinfection (ozone, chlore actif, peroxyde d'hydrogène) |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3259235A1 true EP3259235A1 (fr) | 2017-12-27 |
EP3259235A4 EP3259235A4 (fr) | 2018-11-07 |
Family
ID=51898705
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13884589.6A Withdrawn EP3259235A4 (fr) | 2013-05-15 | 2013-05-15 | Dispositif électrochimique produisant une teneur en liquide de désinfection (ozone, chlore actif, peroxyde d'hydrogène) |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3259235A4 (fr) |
WO (1) | WO2014185868A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108658184A (zh) * | 2018-05-15 | 2018-10-16 | 廊坊市凯翔工贸有限公司 | 除硫杀菌装置 |
EP3771693A1 (fr) | 2019-07-30 | 2021-02-03 | Lift Holding GmbH | Désinfection de l'eau |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3819329A (en) * | 1971-05-11 | 1974-06-25 | Morton Norwich Products Inc | Spray sanitizing system with electrolytic generator |
CA1114329A (fr) * | 1977-02-18 | 1981-12-15 | Nobutaka Goto | Procede d'obtention d'hypochlorite de sodium |
JP3768160B2 (ja) * | 2001-12-25 | 2006-04-19 | 三洋電機株式会社 | 水処理装置 |
TW201012973A (en) * | 2008-09-30 | 2010-04-01 | Industrie De Nora Spa | Cathode member and bipolar plate for hypochlorite cells |
EP2537812B1 (fr) * | 2009-07-16 | 2015-07-01 | pro aqua Diamantelektroden Produktion GmbH & Co KG | Chlorateur intégrable pour spas portables |
EP2697730A4 (fr) * | 2011-04-15 | 2015-04-15 | Advanced Diamond Technologies Inc | Système et procédé électrochimiques destinés à une génération sur site d'oxydants sous une densité de courant élevée |
-
2013
- 2013-05-15 EP EP13884589.6A patent/EP3259235A4/fr not_active Withdrawn
- 2013-05-15 WO PCT/SY2013/000001 patent/WO2014185868A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
EP3259235A4 (fr) | 2018-11-07 |
WO2014185868A1 (fr) | 2014-11-20 |
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A4 | Supplementary search report drawn up and despatched |
Effective date: 20181010 |
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RIC1 | Information provided on ipc code assigned before grant |
Ipc: C02F 1/467 20060101AFI20181004BHEP |
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