EP3170635B1 - Osb (oriented strand board) - wood material board with improved properties and method for producing same - Google Patents

Osb (oriented strand board) - wood material board with improved properties and method for producing same Download PDF

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Publication number
EP3170635B1
EP3170635B1 EP15195141.5A EP15195141A EP3170635B1 EP 3170635 B1 EP3170635 B1 EP 3170635B1 EP 15195141 A EP15195141 A EP 15195141A EP 3170635 B1 EP3170635 B1 EP 3170635B1
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EP
European Patent Office
Prior art keywords
wood
strands
osb
torrefied
wood strands
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP15195141.5A
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German (de)
French (fr)
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EP3170635A1 (en
Inventor
Norbert Dr. Kalwa
Ingo Lehnhoff
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Swiss Krono Tec AG
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Swiss Krono Tec AG
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Publication date
Priority to PT151951415T priority Critical patent/PT3170635T/en
Application filed by Swiss Krono Tec AG filed Critical Swiss Krono Tec AG
Priority to ES15195141.5T priority patent/ES2660426T3/en
Priority to PL15195141T priority patent/PL3170635T3/en
Priority to EP15195141.5A priority patent/EP3170635B1/en
Priority to HUE15195141A priority patent/HUE036992T2/en
Priority to RU2018121541A priority patent/RU2684738C1/en
Priority to PCT/EP2016/076565 priority patent/WO2017084884A1/en
Priority to BR112018009286A priority patent/BR112018009286A8/en
Priority to CN201680067067.4A priority patent/CN108290311B/en
Priority to EP16794248.1A priority patent/EP3377283B1/en
Priority to US15/773,328 priority patent/US10730202B2/en
Priority to CA3005487A priority patent/CA3005487C/en
Priority to JP2018525776A priority patent/JP6518385B2/en
Priority to PL16794248T priority patent/PL3377283T3/en
Priority to ES16794248T priority patent/ES2812200T3/en
Priority to CN201910288929.1A priority patent/CN110142831B/en
Priority to UAA201806272A priority patent/UA124056C2/en
Priority to PT167942481T priority patent/PT3377283T/en
Priority to HUE16794248A priority patent/HUE050465T2/en
Publication of EP3170635A1 publication Critical patent/EP3170635A1/en
Application granted granted Critical
Publication of EP3170635B1 publication Critical patent/EP3170635B1/en
Priority to RU2019108980A priority patent/RU2766676C2/en
Priority to JP2019080211A priority patent/JP6752926B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/0085Thermal treatments, i.e. involving chemical modification of wood at temperatures well over 100°C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • B27D1/08Manufacture of shaped articles; Presses specially designed therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • B27N1/003Pretreatment of moulding material for reducing formaldehyde gas emission
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/04Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/10Moulding of mats
    • B27N3/12Moulding of mats from fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K1/00Damping wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2200/00Wooden materials to be treated
    • B27K2200/15Pretreated particles or fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/30Fireproofing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/60Improving the heat-storage capacity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/70Hydrophobation treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/001Heating

Definitions

  • the present invention relates to a process for the production of OSB wood-based panels according to the preamble of claim 1, OSB wood-based panels produced by the method according to claim 11 and the use of torrefected wooden strands according to claim 15.
  • Coated boards also known as OSB (Oriented Strand Boards) are wood-based panels made from long strands.
  • OSB Oriented Strand Boards
  • the OSB boards originally obtained as waste products of the veneer and plywood industry are increasingly being used in wood and prefabricated house construction, since OSB boards are lightweight and nevertheless fulfill the structural requirements set on construction boards.
  • OSB boards are used as building boards and as wall or roof planking or in the floor area.
  • the production of OSB boards is carried out in a multi-stage process, wherein initially the chips or strands of debarked roundwood, preferably coniferous wood, are peeled off in the longitudinal direction by rotating blades. In the subsequent drying process, the natural moisture of the beach is reduced at high temperatures.
  • the degree of moisture of the strands may vary depending on the adhesive used, and the humidity should be well below 10% in order to avoid breakers during later compression. Depending on the adhesive, wetting may be more favorable on rather wet beaches or on dry beaches.
  • as little moisture as possible should be present in the strands during the pressing process, in order to reduce the vapor pressure generated during the pressing process as far as possible, as this could otherwise cause the raw plate to burst.
  • gluing device in which the glue or adhesive is applied finely distributed to the chips.
  • PMDI polymeric diphenylmethane diisocyanate
  • MUPF glues melamine-urea-phenol-formaldehyde
  • the glues can also be mixed in the OSB boards. These glues are used because the OSB boards are often used for structural applications as mentioned above. There must be used moist or moisture-resistant glues.
  • the glued strands are scattered in scattering apparatuses alternately along and across the production direction, so that the strands are arranged crosswise in at least three layers (lower cover layer - middle layer - upper cover layer).
  • the scattering direction of the lower and upper cover layer is the same, but deviate from the scattering direction of the middle layer.
  • the strands used in the top and middle layers differ from each other.
  • the strands used in the outer layers are flat and the strands used in the middle layer are less flat up to span-shaped.
  • two strands of material are used in the manufacture of the OSB boards: one with flat strands for the later cover layers and one with "chips" for the middle layer. Accordingly, the strands in the middle layer may be qualitatively inferior because the flexural strength is generated substantially by the cover layers. Therefore, fines produced during machining can also be used in the middle layer of OSB boards.
  • OSB boards are enjoying increasing popularity and diverse applications, for example as a construction element in house construction or as formwork in concrete construction.
  • the inherent hygroscopic properties of wood-based materials have a detrimental effect in some applications.
  • Volatile organic compounds also called VOCs, include volatile organic compounds that readily evaporate or are already present as gas at lower temperatures, such as room temperature.
  • the volatile organic compounds VOC are either already present in the wood material and are released during workup from this or they are formed according to the current state of knowledge by the degradation of unsaturated fatty acids, which in turn are decomposition products of wood.
  • Typical conversion products that occur during processing for example, pentanal and hexanal, but also octanal, octenal or 1-heptenal.
  • softwoods from which OSB boards are predominantly produced contain large amounts of resin and fats which lead to the formation of volatile organic terpene compounds and aldehydes.
  • VOCs and aldehydes, such as formaldehyde can also be formed or released when certain adhesives are used for the production of wood-based materials.
  • OSB boards are critical mainly because this material is predominantly used uncoated. This allows the ingredients to exude unhindered.
  • OSB boards are often used for cladding / paneling of large areas, which usually results in a high space loading (m 2 OSB / m 3 room air). This leads in addition to a concentration of certain substances in the room air.
  • OSB boards Another problem in the production of OSB boards is the swelling tendency of the wood strands, which can lead to a reduction in the technological values such as strength values of the OSB wood-based boards.
  • One approach to reducing swelling is in eg US 6098679 described.
  • a method and apparatus is shown for pre-treating or post-treating OSB panels to reduce swelling.
  • the OSB plate is charged with superheated steam in a vacuum chamber.
  • the invention is now based on the technical object to improve the known per se method for the production of OSB material boards to produce OSB material plates with a significantly reduced emission of volatile organic compounds (VOCs) and with improved swelling values simply and safely. If possible, the manufacturing process should be changed as little as possible and the cost do not rise disproportionately. Furthermore, the solution should include the greatest possible flexibility. Finally, environmental aspects should also be considered, ie the solution should not cause additional energy consumption or generate additional waste.
  • the present method enables the production of OSB wood-based panels using torrefied wooden strands which are introduced into a known manufacturing process in addition to or as an alternative to untreated wood strands.
  • An OSB wood-based panel produced by the method according to the invention comprising torrefied wood has a reduced emission of volatile organic compounds, in particular of terpenes, organic acids such as acetic acid and aldehydes.
  • OSB wood-based panels By providing the present method, there are several advantages.
  • a simple production of OSB wood-based panels is possible without substantially influencing the usual process chain without the classical drying process with significantly reduced emission of volatile organic compounds from the OSB.
  • the produced OSB wood-based panels also have a significantly lower swelling and higher dimensional stability.
  • simple products are produced, which are produced by the addition of aqueous formulations, with an adjustment of the water balance is possible.
  • Torrefaction is a thermochemical treatment process in which the material to be torrefied is heated in an oxygen-reduced or oxygen-free gas atmosphere at atmospheric pressure. Due to the lack of oxygen, the material does not burn, instead there is a mass loss due to the decomposition of wood components, which are degraded to volatile compounds at Torrefiz istsstemperaturen. These are mainly hemicelluloses and lignins. In addition, low molecular weight compounds such as formic acid, terpenes, hydrocarbons, etc. driven out. Torrefied material is hydrophobic and therefore less susceptible to ambient humidity, so that the risk of rotting torrefected material is extremely low.
  • the tanning step of the wood strands may be provided in various ways in the present process.
  • At least a portion of the wood strands used to make the OSB boards are dried prior to torrefying, i. in this case dried or pre-dried wood strands, e.g. subjected to a degree of moisture of 5 to 15% moisture, preferably 5 to 10% moisture of Torrefizierung.
  • At least a portion of the wood strands are torrefied with a humidity of 20-50% by weight, i.
  • a humidity of 20-50% by weight i.
  • the present method enables torrefaction of wet or dry wood strands.
  • the torrefaction of wet wood strands is advantageous because the drying step is saved.
  • torrefined wood strands or a mixture of torrefied wood strands and untreated (ie non-torrefied) wood strands are used as the middle layer and / or top layer of the OSB material board.
  • the torrequel faced wood strands are used only in the middle layer, only in one or both cover layers or in all layers.
  • the use of a dryer is eliminated.
  • torrefied wood strands In another variant it is possible to form only the middle layer of torrefied wood strands and to use dried and non-tinted wood strands for one or both cover layers. Since torrefected strands have a brown color, it may be advantageous to use torrefied strands only in the middle layer.
  • only one or both cover layers are formed of torrefied wood strands, and for the middle layer, dried and untorn wood strands are used.
  • the middle and outer layers in each case a mixture with any ratio of torrefiz faced wooden strands and non-torrefected wooden strands.
  • the mixture may comprise between 10 and 50% by weight, preferably between 20 and 30% by weight of untreated or non-torrefied wood strands and between 50 and 90% by weight, preferably between 70 and 80% by weight of torrefied wood strands.
  • the step of Torrefizierens the wood strands can be performed separately from the manufacturing process of OSB wood-based panels.
  • the torrefaction step occurs outside the overall process or process line.
  • the wood strands are thereby discharged from the manufacturing process and introduced into the torrefying apparatus (e.g., torrefying reactor).
  • the Torrefiz convinced wood strands may, after an intermediate storage, for example. be returned to the conventional manufacturing process immediately before gluing. This allows a high flexibility in the manufacturing process.
  • the Torrefizianss intimid the wood strands can be integrated in yet another embodiment variant in the manufacturing process of the OSB wood-based panels, ie the Torrefiz michianss Republic is incorporated into the overall process or process line and takes place online.
  • the torrefaction can be carried out immediately after the cutting and provision of the wooden strands, or only after the sifting and separation of the wooden strands according to the use of the wooden strands for the middle or top layer. In the latter case, a separate torrefaction of the wooden strands can be made according to the torrefaction requirements for the wooden strands used in the middle and top layers.
  • the wood strands used herein may have a length of between 50 to 200 mm, preferably 70 to 180 mm, particularly preferably 90 to 150 mm; a width between 5 to 50 mm, preferably 10 to 30 mm, particularly preferably 15 to 20 mm; and a thickness between 0.1 and 2 mm, preferably between 0, 3 and 1.5 mm, particularly preferably between 0, 4 and 1 mm.
  • the wood strands for example, have a length between 150 and 200 mm, a width between 15 and 20 mm, a thickness between 0.5 and 1 mm and a moisture content of max. 50% up.
  • the torrefaction of the wood strands is carried out in at least one Torrefiz réellesreaktor, preferably in two Torrefiz réellesreaktoren.
  • the Torrefiz réellesreaktor used here can be present as a batch system or as a continuously operated system or work.
  • the torrefaction of wood strands used for the middle layer and topsheets of the OSB wood-based panel may each be performed separately in at least two torrefying reactors.
  • the two Torrefizianssreaktoren used are preferably connected in parallel or arranged in this case.
  • the wood strands are torrefied by heating in an oxygen-poor or oxygen-free atmosphere under atmospheric pressure at a temperature between 150 ° C and 300 ° C, preferably between 200 ° C and 280 ° C, particularly preferably between 220 ° C and 260 ° C. It can be torrefied under atmospheric pressure in the presence of an inert gas, preferably nitrogen as the reaction gas or gas stream. It is also possible to use saturated steam, in which case the Torrefiz michellessrea runs at temperatures between 160 ° C and 200 ° C and pressures of 6 bar to 16 bar.
  • Torrefizierens is preferably terminated at a loss of mass of the wood strands of 10 to 30%, preferably 15 to 20%.
  • the duration of the process varies depending on the amount and type of the starting material used and can be between 1 and 5 h, preferably between 2 and 3 h.
  • the pyrolysis gases released during the torrefaction process essentially from hemicelluloses and other low molecular weight compounds, are used to generate process energy.
  • the amount of gas mixture formed as gaseous fuel is sufficient to operate the process energetically self-sufficient.
  • the torrefied wooden strands are cooled in water before gluing with a suitable binder.
  • the torrefected wooden strands can be cooled in a water bath, which ensures complete wetting with water.
  • a wetting agent which facilitates the wetting of the hydrophobic strands can be added to the water.
  • the contacting of the wood strands with the at least one binder in step c) is preferably carried out by spraying or atomizing the binder onto the wood strands.
  • Many OSB systems work with rotating coils (drums with atomizer gluing). A mixer gluing would also be possible.
  • the strands are intimately mixed with the glue in a mixer by rotating blades.
  • a polymer adhesive is preferably used as a binder which is selected from the group consisting of formaldehyde adhesives, polyurethane adhesives, epoxy adhesives, polyester adhesives.
  • formaldehyde condensate adhesive in particular, a phenol-formaldehyde resin adhesive (PF), a cresol / resorcinol-formaldehyde resin adhesive, urea-formaldehyde resin adhesive (UF) and / or melamine-formaldehyde resin adhesive (MF) can be used.
  • polyurethane adhesive based on aromatic polyisocyanates, in particular Polydiphenylmethane diisocyanate (PMDI), tolylene diisocyanate (TDI) and / or diphenylmethane diisocyanate (MDI) is present, with PMDI being particularly preferred.
  • PMDI Polydiphenylmethane diisocyanate
  • TDI tolylene diisocyanate
  • MDI diphenylmethane diisocyanate
  • the torrefied and non-torrefied wood strands having a binder amount of 1.0 to 5.0% by weight, preferably 2 to 4% by weight, especially 3% by weight (based on the total amount of wood strands) glued.
  • the first polymer adhesive at least one polycondensation adhesive such as a polyamide, a polyester, a silicone and / or a formaldehyde condensate adhesive, in particular a phenol-formaldehyde resin adhesive (PF), a cresol / resorcinol formaldehyde resin adhesive , Urea-formaldehyde-resin adhesive (UF) and / or melamine-formaldehyde-resin adhesive (MF) are used, and as the second polymer adhesive at least one polyaddition adhesive such as an epoxy resin, polycyanurate and / or a polyurethane adhesive, in particular a polyurethane adhesive based on polydiphenylmethane diisocyanate (PMDI) can be used.
  • PF phenol-formaldehyde resin adhesive
  • UF cresol / resorcinol formaldehyde resin adhesive
  • UF Urea-formaldehyde-resin adhesive
  • binder variants are particularly preferred: phenol-formaldehyde adhesive (PF); Melamine-urea-formaldehyde-resin adhesive (MUF); Melamine-urea-phenol formaldehyde resin adhesive (MUPF); PMDI adhesives and a combination of MUF / MUPF and PMDI adhesives.
  • PF phenol-formaldehyde adhesive
  • MUF Melamine-urea-formaldehyde-resin adhesive
  • MUPF Melamine-urea-phenol formaldehyde resin adhesive
  • PMDI adhesives and a combination of MUF / MUPF and PMDI adhesives.
  • preference is given to using PMDI for the middle layer and as binder in the outer layers MUF or MUPF.
  • PMDI adhesives for all layers, i. for the cover layers and the middle layer.
  • the flame retardant may typically be added in an amount between 1 and 20% by weight, preferably between 5 and 15% by weight, particularly preferably ⁇ 10% by weight, based on the total amount of wood strands.
  • Typical flame retardants are selected from the group comprising phosphates, borates, in particular ammonium polyphosphate, tris (tri-bromneopentyl) phosphate, zinc borate or boric acid complexes of polyhydric alcohols.
  • the glued (torrefied and / or non-torrefied) wood strands are scattered onto a conveyor belt to form a first cover layer along the transport direction, then to form a middle layer transversely to the transport direction and finally to form a second cover layer along the transport direction.
  • the glued wooden strands are pressed at temperatures between 200 and 250 ° C., preferably 220 and 230 ° C., to form an OSB wood-based panel.
  • the present method enables the production of an OSB wood-based panel with reduced emission of volatile organic compounds (VOCs) comprising torrefied wood strands.
  • VOCs volatile organic compounds
  • the OSB wood-based panel produced by the present method has in particular a reduced emission of aldehydes released during wood pulping, in particular pentanal or hexanal, organic acids such as acetic acid and / or terpenes, in particular carene and pinene.
  • aldehydes released during wood pulping in particular pentanal or hexanal
  • organic acids such as acetic acid and / or terpenes, in particular carene and pinene.
  • the present OSB wood-based panel may consist entirely of torrefied wooden strands or of a mixture of torrefied and non-torrefied wooden strands.
  • the present OSB board has a reduced swelling value, in particular one of 20% to 50%, preferably 30% to 40%, compared to OSB boards made entirely of non-torrefied wood strips. reduced source value by 35%.
  • the swelling tendency of the present OSB wood-based panel is between 5 and 30%, preferably between 10 and 25%, particularly preferably between 15 and 20% (after 24 hours of water storage).
  • the present OSB wood-based panel may have a bulk density between 300 and 1000 kg / m 3 , preferably between 500 and 800 kg / m 3 , particularly preferably between 500 and 600 kg / m 3 .
  • the thickness of the present OSB wood-based panel may be between 5 and 50 mm, preferably between 10 and 40 mm, wherein in particular a thickness between 15 and 25 mm is preferred.
  • the object of the present invention is also achieved with the use of torrefied wood strands to reduce the emission of volatile organic compounds (VOCs) from OSB wood-based panels.
  • VOCs volatile organic compounds
  • the torrefected wood strands are used for reducing aldehydes, organic acids and / or terpenes released during the wood pulping, in particular the cutting of the woods in strands.
  • the torrefied wood strands are preferably used for reducing the emission of organic acids, in particular for reducing the emission of acetic acid from OSB wood-based panels.
  • Organic acids are produced in particular as cleavage products of the wood constituents cellulose, hemicelluloses and lignin, alkanoic acids such as acetic acid and propionic acid or aromatic acids preferably being formed.
  • aldehydes can be formed from the basic building blocks of cellulose or hemicellulose.
  • aldehyde furfural is formed from mono- and disaccharides of cellulose or hemicellulose, while aromatic aldehydes can be liberated during the partial hydrolytic exclusion of lignin.
  • the Torrequel being strands to reduce the emission of C1-C10 aldehydes, particularly preferably from formaldehyde, acetaldehyde, pentanal, hexanal or furfural used in OSB wood-based panels.
  • the torrefied wooden strands are used to reduce the emission of terpenes.
  • the torrefied wood strands can be used to reduce liberated terpenes, in particular C10 monoterpenes and C15 sesquiterpenes, particularly preferably acyclic or cyclic monoterpenes.
  • Typical acyclic terpenes are terpene hydrocarbons such as myrcene, terpene alcohols such as gerianol, linaool, ipsinol and terpene aldehydes such as citral.
  • Typical representatives of the monocyclic terpenes are p-menthane, terpeninol, limonene or carvone, and typical representatives of the bicyclic terpenes are caran, pinane, bornan, in particular 3-carene and ⁇ -pinene being of importance.
  • Terpenes are components of the tree resins and therefore especially in very resinous tree species such as pine or spruce.
  • first embodiment of the method according to the invention describes the individual process steps, starting with the provision of the wood output product to the finished OSB wood-based panel.
  • step 1 suitable wood starting material for the production of the wood strands is first provided.
  • wood source material all conifers, hardwoods or mixtures thereof are suitable.
  • the debarking (step 2) and the cutting (step 3) of the wood starting material takes place in suitable chippers, wherein the size of the wood strands can be controlled accordingly. After comminution and provision of the wood strands, they are optionally subjected to a predrying process, with a moisture content of 5-10% being set with respect to the initial moisture content of the woodchips (not shown).
  • the wooden strands are introduced into a torrefying reactor (step 4).
  • the torrefaction of the wooden strands takes place in a temperature range between 220 ° and 260 ° C.
  • the resulting pyrolysis gases or Torrgase be used to generate the necessary energy for the process plant.
  • the torrefected wooden strands are watered, sighted and separated (step 5).
  • step 6a There is a separation in wooden strands for use as a middle layer (step 6a) or as a cover layer (step 6b) with respective gluing.
  • the glued Torrefiz fortunate wood strands are scattered onto a conveyor belt in the order first lower cover layer, middle layer and second upper cover layer (step 7) and then pressed to form an OSB wood-based panel (step 8).
  • the wood starting material is analogous to FIG. 1 initially provided (step 1), debarked (step 2) and machined (step 3).
  • the strands of wood may be subjected to a predrying process, with a humidity of 5-10% being adjusted in relation to the initial moisture content of the strands of wood (step 3a).
  • a separation in wood strands is already carried out after the optional drying for use as a middle layer or as a cover layer (step 5).
  • the torrefaction of the wooden strands takes place in a temperature range between 220 ° and 260 ° C. Torrefaction can be set to the desired torrefaction level for the center and top layers.
  • the resulting pyrolysis gases or Torrgase be used to generate the necessary energy for the process plant.
  • the glued Torrefiz fortunate wood strands are scattered onto a conveyor belt in the order first lower cover layer, middle layer and second upper cover layer (step 7) and then pressed to form an OSB wood-based panel (step 8).
  • the obtained OSB wood-based panel is assembled in each case in a suitable manner.
  • Strands are produced from pine logs and torrefied in a continuous torrefaction apparatus at 180 ° C to a mass loss of about 20%. This takes place under saturated steam. In the process, the beaches turn from light yellow to light brown. The beaches are then cooled in water.
  • the binder (PMDI, about 3% by weight) in a gluing machine (Beleimtrommel, for example, the Fa. Coil) finely distributed on the torrefiz faced wooden strands applied.
  • the glued torrefied stands are sprinkled in an OSB plant as a middle layer.
  • the cover layer is formed from strands which have been dried in a tumble dryer. These have also been glued with PMDI as a glue (about 3% by weight). The beaches are not z. As a paraffin emulsion additionally hydrophobic, so as not to interfere with the subsequently performed tests by the hydrophobing agent. The scattered strands are pressed in a Contipresse to OSB plates.
  • the percentage distribution between middle and top layer is at least 70% to 30%.
  • the strands are pressed into slabs with a density of about 570 kg / m 3 .
  • test plate After a storage time of about one week, the test plate was tested together with a standard plate in the same strength in a micro-chamber on the VOC delivery.
  • Chamber parameters temperature 23 ° C; Humidity 0%; Air flow 150 ml / min; Air exchange 188 / h; Load 48.8 m 2 / m 3 ; Sample surface 0.003 m 2 , chamber volume: 48 ml
  • Table 1 parameter Test plate ⁇ g / m 2 xh Standard plate ⁇ g / m 2 xh hexanal 1093 3164 3-Carene 388 1962 ⁇ -Pinene 322 1174 pentanal 78 354 ⁇ -pinene 98 314
  • the source values are reduced by about 35% through the use of torrefied strands.

Description

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von OSB-Holzwerkstoffplatten gemäß dem Oberbegriff nach Anspruch 1, mit dem Verfahren hergestellte OSB-Holzwerkstoffplatten gemäß Anspruch 11 und die Verwendung von torrefizierten Holzstrands gemäß Anspruch 15.The present invention relates to a process for the production of OSB wood-based panels according to the preamble of claim 1, OSB wood-based panels produced by the method according to claim 11 and the use of torrefected wooden strands according to claim 15.

Beschreibungdescription

Grobspanplatten, auch OSB-Platten (oriented strand boards) genannt, sind Holzwerkstoffplatten, die aus langen Spänen (strands) hergestellt werden. Die ursprünglich als Abfallprodukte der Furnier- und Sperrholzindustrie anfallenden OSB-Platten werden jedoch zunehmend im Holz- und Fertighausbau eingesetzt, da OSB-Platten leicht sind und trotzdem die an Bauplatten gesetzten statischen Anforderungen erfüllen. So werden OSB-Platten als Bauplatten und als Wand- oder Dachbeplankung oder auch im Fußbodenbereich eingesetzt.Coated boards, also known as OSB (Oriented Strand Boards), are wood-based panels made from long strands. However, the OSB boards originally obtained as waste products of the veneer and plywood industry are increasingly being used in wood and prefabricated house construction, since OSB boards are lightweight and nevertheless fulfill the structural requirements set on construction boards. For example, OSB boards are used as building boards and as wall or roof planking or in the floor area.

Die Herstellung der OSB-Platten erfolgt in einem mehrstufigen Prozess, wobei zunächst die Späne oder Strands aus entrindetem Rundholz, bevorzugt Nadelhölzer, in Längsrichtung durch rotierende Messer abgeschält werden. Im sich anschließenden Trocknungsvorgang wird die natürliche Feuchtigkeit der Strands bei hohen Temperaturen reduziert. Der Feuchtigkeitsgrad der Strands kann je nach verwendeten Klebstoff variieren, wobei sich die Feuchtigkeit deutlich unter 10% bewegen sollte, um Spalter beim späteren Verpressen zu vermeiden. In Abhängigkeit vom Klebstoff kann eine Benetzung auf eher feuchten Strands oder auf trockenen Strands günstiger sein. Außerdem sollte während des Pressvorganges möglichst wenig Feuchtigkeit in den Strands vorhanden sein, um den während des Pressvorganges entstehenden Dampfdruck weitestgehend zu reduzieren, da dieser die Rohplatte ansonsten zum Platzen bringen könnte.The production of OSB boards is carried out in a multi-stage process, wherein initially the chips or strands of debarked roundwood, preferably coniferous wood, are peeled off in the longitudinal direction by rotating blades. In the subsequent drying process, the natural moisture of the beach is reduced at high temperatures. The degree of moisture of the strands may vary depending on the adhesive used, and the humidity should be well below 10% in order to avoid breakers during later compression. Depending on the adhesive, wetting may be more favorable on rather wet beaches or on dry beaches. In addition, as little moisture as possible should be present in the strands during the pressing process, in order to reduce the vapor pressure generated during the pressing process as far as possible, as this could otherwise cause the raw plate to burst.

Im Anschluss an die Trocknung der Strands werden diese in eine Beleimvorrichtung eingeführt, in welcher der Leim bzw. Klebstoff fein verteilt auf die Späne aufgebracht wird. Zur Verleimung werden überwiegend PMDI- (polymeres Diphenylmethandiisocyanat) oder MUPF-Leime (Melamin-Harnstoff-Phenol-Formaldehyd) eingesetzt. Die Leime können in den OSB-Platten auch gemischt eingesetzt werden. Diese Leime werden verwendet, da die OSB-Platten wie oben erwähnt häufig für konstruktive Anwendungen genutzt werden. Dort müssen feucht- bzw. nässebeständige Leime verwendet werden.Following the drying of the strands they are introduced into a gluing device in which the glue or adhesive is applied finely distributed to the chips. For gluing predominantly PMDI (polymeric diphenylmethane diisocyanate) or MUPF glues (melamine-urea-phenol-formaldehyde) are used. The glues can also be mixed in the OSB boards. These glues are used because the OSB boards are often used for structural applications as mentioned above. There must be used moist or moisture-resistant glues.

Nach der Beleimung werden die beleimten Strands in Streuapparaturen alternierend längs und quer zur Produktionsrichtung gestreut, so dass die Strands kreuzweise in mindestens drei Schichten angeordnet sind (untere Deckschicht - Mittelschicht - obere Deckschicht). Die Streurichtung von unterer und oberer Deckschicht ist dabei gleich, weichen jedoch von der Streurichtung der Mittelschicht ab. Auch unterscheiden sich die in der Deckschicht und Mittelschicht verwendeten Strands voneinander. So sind die in den Deckschichten verwendeten Strands flächig und die in der Mittelschicht verwendeten Strands weniger flächig bis hin zu spanförmig. Üblicherweise werden bei der Herstellung der OSB-Platten zwei Materialstränge gefahren: einer mit flächigen Strands für die späteren Deckschichten und einer mit "Spänen" für die Mittelschicht. Entsprechend können die Strands in der Mittelschicht qualitativ schlechter sein, da die Biegefestigkeit im Wesentlichen durch die Deckschichten erzeugt wird. Deshalb kann auch Feingut, das beim Zerspanen entsteht, in der Mittelschicht von OSB-Platten verwendet werden.After gluing, the glued strands are scattered in scattering apparatuses alternately along and across the production direction, so that the strands are arranged crosswise in at least three layers (lower cover layer - middle layer - upper cover layer). The scattering direction of the lower and upper cover layer is the same, but deviate from the scattering direction of the middle layer. Also, the strands used in the top and middle layers differ from each other. Thus, the strands used in the outer layers are flat and the strands used in the middle layer are less flat up to span-shaped. Usually, two strands of material are used in the manufacture of the OSB boards: one with flat strands for the later cover layers and one with "chips" for the middle layer. Accordingly, the strands in the middle layer may be qualitatively inferior because the flexural strength is generated substantially by the cover layers. Therefore, fines produced during machining can also be used in the middle layer of OSB boards.

Im Anschluss an die Streuung der Strands erfolgt ein kontinuierliches Verpressen der selbigen unter hohem Druck und hoher Temperatur von z.B. 200 bis 250°C.Following the scattering of the strands, continuous compression of the same under high pressure and temperature of e.g. 200 to 250 ° C.

OSB-Platten erfreuen sich nicht zuletzt auf Grund ihrer Nachhaltigkeit immer größerer Beliebtheit und vielfältiger Anwendung, beispielsweise als Konstruktionselement beim Hausbau oder als Schalung im Betonbau. Den Holzwerkstoffen innewohnende hygroskopische Eigenschaften wirken sich bei einigen Anwendungen jedoch nachteilig aus.Not least because of their sustainability, OSB boards are enjoying increasing popularity and diverse applications, for example as a construction element in house construction or as formwork in concrete construction. The inherent hygroscopic properties of wood-based materials, however, have a detrimental effect in some applications.

Besonders bei einer Verwendung von OSB im Innenbereich wird ein Entweichen von Holzinhaltsstoffen kritisch gesehen. Dies ist insbesondere bei OSB-Platten aus Kiefernholz problematisch, da diese besonders hohe Emission von flüchtigen organischen Verbindungen zeigen.Especially when using indoor OSB, the escape of wood constituents is viewed critically. This is particularly problematic in OSB pine panels, as they show very high emission of volatile organic compounds.

Im Verlaufe der Herstellung von Holzwerkstoffplatten und insbesondere bedingt durch den Herstellungsprozess der Holzstrands entstehen bzw. werden eine Vielzahl von flüchtigen organischen Verbindungen freigesetzt. Zu den flüchtigen organischen Verbindungen, auch VOCs genannt, gehören flüchtige organische Stoffe, die leicht verdampfen bzw. bereits bei niedrigeren Temperaturen, wie zum Beispiel Raumtemperatur als Gas vorliegen.In the course of the production of wood-based panels and in particular due to the production process of the wood strands arise or a variety of volatile organic compounds are released. Volatile organic compounds, also called VOCs, include volatile organic compounds that readily evaporate or are already present as gas at lower temperatures, such as room temperature.

Die flüchtigen organischen Verbindungen VOC sind entweder bereits im Holzmaterial vorhanden und werden während der Aufarbeitung aus diesem abgegeben oder sie werden nach derzeitigem Erkenntnisstand durch den Abbau von ungesättigten Fettsäuren gebildet, die wiederum Zersetzungsprodukte des Holzes sind. Typische Umwandlungsprodukte, die während der Bearbeitung auftreten, sind zum Beispiel Pentanal und Hexanal, aber auch Octanal, Octenal oder 1-Heptenal. Insbesondere Nadelhölzer, aus denen vorwiegend OSB-Platten hergestellt werden, enthalten große Mengen an Harz und Fetten, die zur Bildung von flüchtigen organischen Terpenverbindungen und Aldehyden führen. VOC und Aldehyde, wie Formaldehyd, können jedoch auch bei der Verwendung bestimmter Klebstoffe für die Herstellung der Holzwerkstoffe entstehen bzw. freigesetzt werden.The volatile organic compounds VOC are either already present in the wood material and are released during workup from this or they are formed according to the current state of knowledge by the degradation of unsaturated fatty acids, which in turn are decomposition products of wood. Typical conversion products that occur during processing, for example, pentanal and hexanal, but also octanal, octenal or 1-heptenal. In particular, softwoods from which OSB boards are predominantly produced contain large amounts of resin and fats which lead to the formation of volatile organic terpene compounds and aldehydes. However, VOCs and aldehydes, such as formaldehyde, can also be formed or released when certain adhesives are used for the production of wood-based materials.

Die Emission von Inhaltsstoffen bei OSB-Werkstoffplatten ist vor allem deshalb kritisch, weil dieser Werkstoff zum überwiegenden Teil unbeschichtet verwendet wird. Dadurch können die Inhaltsstoffe ungehindert ausdünsten. Außerdem werden die OSB-Platten häufig zur Verkleidung/Beplankung von großen Flächen verwendet, woraus sich meist eine hohe Raumbeladung (m2 OSB / m3 Raumluft) ergibt. Dies führt zusätzlich zu einer Aufkonzentration bestimmter Substanzen in der Raumluft.The emission of ingredients in OSB boards is critical mainly because this material is predominantly used uncoated. This allows the ingredients to exude unhindered. In addition, the OSB boards are often used for cladding / paneling of large areas, which usually results in a high space loading (m 2 OSB / m 3 room air). This leads in addition to a concentration of certain substances in the room air.

Um das Problem der VOC-Emission zu lösen, wurden in der Vergangenheit verschiedene Ansätze beschrieben. So geht aus der EP 2 615 126 B1 hervor, dass eine Reduzierung der VOC-Emission in OSB-Platten durch die Verwendung von mit Silanverbindungen modifizierten Nanopartikeln bewirkt werden kann. Die Verwendung derartiger Nanopartikel in OSB-Platten ist allerdings mit relativ hohen Kosten verbunden.To solve the problem of VOC emission, various approaches have been described in the past. So goes out of the EP 2 615 126 B1 show that a reduction in VOC emission in OSB plates can be achieved through the use of nanoparticles modified with silane compounds. However, the use of such nanoparticles in OSB boards is associated with relatively high costs.

Es ist demnach erstrebenswert, weitergehende Lösungen zu entwickeln, durch welche die Freisetzung von leichtflüchtigen organischen Verbindungen aus OSB-Holzwerkstoffplatten, reduziert wird.It is therefore desirable to develop further solutions which reduce the release of volatile organic compounds from OSB wood-based panels.

Ein weiteres Problem bei der Herstellung von OSB-Werkstoffplatten besteht in der Quellneigung der Holzstrands, die zu einer Verminderung der technologischen Werte wie Festigkeitswerte der OSB-Holzwerkstoffplatten führen können. Ein Ansatz zur Verringerung der Quellneigung ist z.B. in US 6098679 beschrieben. Hier wird ein Verfahren und eine Vorrichtung gezeigt, mit dem OSB-Platten vor- oder nachbehandelt werden, um die Quellneigung zu vermindern. Dazu wird die OSB-Platte in einer Vakuumkammer mit Heißdampf beaufschlagt.Another problem in the production of OSB boards is the swelling tendency of the wood strands, which can lead to a reduction in the technological values such as strength values of the OSB wood-based boards. One approach to reducing swelling is in eg US 6098679 described. Here, a method and apparatus is shown for pre-treating or post-treating OSB panels to reduce swelling. For this purpose, the OSB plate is charged with superheated steam in a vacuum chamber.

Der Erfindung liegt nunmehr die technische Aufgabe zu Grunde, das an sich bekannte Verfahren zur Herstellung von OSB-Werkstoffplatten dahingehend zu verbessern, um einfach und sicher OSB-Werkstoffplatten mit einer deutlich verringerten Emission von flüchtigen organischen Verbindungen (VOCs) sowie mit verbesserten Quellwerten herzustellen. Wenn möglich, sollte der Herstellprozess so wenig wie möglich verändert werden und die Kosten nicht unverhältnismäßig steigen. Weiterhin sollte die Lösung eine möglichst große Flexibilität beinhalten. Letztlich sollen auch ökologische Aspekte mit in Betracht gezogen werden, d. h. die Lösung sollte keine zusätzlichen Energieverbräuche hervorrufen oder zusätzliche Abfälle erzeugen.The invention is now based on the technical object to improve the known per se method for the production of OSB material boards to produce OSB material plates with a significantly reduced emission of volatile organic compounds (VOCs) and with improved swelling values simply and safely. If possible, the manufacturing process should be changed as little as possible and the cost do not rise disproportionately. Furthermore, the solution should include the greatest possible flexibility. Finally, environmental aspects should also be considered, ie the solution should not cause additional energy consumption or generate additional waste.

Diese Aufgabe wird erfindungsgemäß durch ein Verfahren zur Herstellung von OSB-Holzwerkstoffplatten mit den Merkmalen des Anspruchs 1 und eine daraus hergestellte OSB-Holzwerkstoffplatte gemäß Anspruch 11 gelöst.This object is achieved by a method for producing OSB wood-based panels with the features of claim 1 and an OSB wood-based panel made therefrom according to claim 11.

Entsprechend wird ein Verfahren zur Herstellung von OSB-Holzwerkstoffplatten, insbesondere von OSB-Holzwerkstoffplatten mit reduzierter Emission an flüchtigen organischen Verbindungen (VOCs) bereitgestellt, welches die folgenden Schritte umfasst:

  1. a) Herstellen von Holzstrands aus geeigneten Hölzern,
  2. b) Torrefizieren von zumindest einem Teil der Holzstrands;
  3. c) Beleimen der torrefizierten Holzstrands und nicht-torrefizierten Holzstrands mit mindestens einem Bindemittel;
  4. d) Aufstreuen der beleimten Holzstrands auf ein Transportband; und
  5. e) Verpressen der beleimten Holzstrands zu einer OSB-Holzwerkstoffplatte.
Accordingly, there is provided a process for producing OSB wood-based panels, in particular OSB wood-based panels having reduced emission of volatile organic compounds (VOCs), comprising the following steps:
  1. a) making wooden strips of suitable woods,
  2. b) Torrefying at least a portion of the wooden strands;
  3. c) gluing the torrefied wooden strands and non-torrefied wooden strands with at least one binder;
  4. d) sprinkling the glued wooden strands onto a conveyor belt; and
  5. e) pressing the glued wooden strands into an OSB wood-based panel.

Das vorliegende Verfahren ermöglicht die Herstellung von OSB-Holzwerkstoffplatten unter Verwendung von torrefizierten Holzstrands, die zusätzlich oder alternativ zu unbehandelten Holzstrands in einen bekannten Herstellungsprozess eingeführt werden. Eine mit dem erfindungsgemäßen Verfahren hergestellte OSB-Holzwerkstoffplatte umfassend torrefiziertes Holz weist eine verminderte Emission von flüchtigen organischen Verbindungen, insbesondere von Terpenen, organischen Säuren wie Essigsäure und Aldehyden auf.The present method enables the production of OSB wood-based panels using torrefied wooden strands which are introduced into a known manufacturing process in addition to or as an alternative to untreated wood strands. An OSB wood-based panel produced by the method according to the invention comprising torrefied wood has a reduced emission of volatile organic compounds, in particular of terpenes, organic acids such as acetic acid and aldehydes.

Durch die Bereitstellung des vorliegenden Verfahrens ergeben sich verschiedene Vorteile. So ist eine einfache Herstellung der OSB-Holzwerkstoffplatten ohne wesentliche Beeinflussung der üblichen Prozesskette bei Verzicht auf den klassischen Trocknungsprozess bei deutlich verminderter Emission flüchtiger organischer Verbindungen aus dem OSB möglich. Die hergestellten OSB-Holzwerkstoffplatten weisen zudem eine deutlich niedrigere Quellung und höhere Dimensionsstabilität auf. Auch können durch den Einsatz von torrefizierten Strands, die eine sehr niedrige Feuchte besitzen, einfacher Produkte hergestellt werden, die durch Zugabe von wässrigen Formulierungen produziert werden, wobei eine Anpassung des Wasserhaushaltes möglich ist.By providing the present method, there are several advantages. Thus, a simple production of OSB wood-based panels is possible without substantially influencing the usual process chain without the classical drying process with significantly reduced emission of volatile organic compounds from the OSB. The produced OSB wood-based panels also have a significantly lower swelling and higher dimensional stability. Also, through the use of torrefied beaches, which have a very low humidity, simple products are produced, which are produced by the addition of aqueous formulations, with an adjustment of the water balance is possible.

Torrefizierung ist ein thermochemisches Behandlungsverfahren, bei welchem das zu torrefizierende Material in einer sauerstoffreduzierten oder sauerstofffreien Gasatmosphäre bei Atmosphärendruck erhitzt wird. Aufgrund des Mangels an Sauerstoff verbrennt das Material nicht, stattdessen kommt es zu einem Masseverlust aufgrund der Zersetzung von Holzbestandteilen, die bei den Torrefizierungstemperaturen zu flüchtigen Verbindungen abgebaut werden. Dies sind vor allem Hemizellulosen und Lignine. Zusätzlich werden niedermolekulare Verbindungen wie Ameisensäure, Terpene, Kohlenwasserstoffe usw. ausgetrieben. Torrefiziertes Material ist hydrophob und daher weniger anfällig gegenüber der Umgebungsfeuchte, so dass die Verrottungsgefahr von torrefiziertem Material äußerst gering ist.Torrefaction is a thermochemical treatment process in which the material to be torrefied is heated in an oxygen-reduced or oxygen-free gas atmosphere at atmospheric pressure. Due to the lack of oxygen, the material does not burn, instead there is a mass loss due to the decomposition of wood components, which are degraded to volatile compounds at Torrefizierungsstemperaturen. These are mainly hemicelluloses and lignins. In addition, low molecular weight compounds such as formic acid, terpenes, hydrocarbons, etc. driven out. Torrefied material is hydrophobic and therefore less susceptible to ambient humidity, so that the risk of rotting torrefected material is extremely low.

Der Torrifizierungsschritt der Holzstrands kann in dem vorliegenden Verfahren in verschiedener Weise vorgesehen sein.The tanning step of the wood strands may be provided in various ways in the present process.

In einer Ausführungsform des vorliegenden Verfahrens wird zumindest ein Teil der für die Herstellung der OSB-Werkstoffplatten verwendeten Holzstrands vor dem Torrefizieren getrocknet, d.h. es werden in diesem Falle bereits getrocknete bzw. vorgetrocknete Holzstrands z.B. mit einem Feuchtigkeitsgrad von 5 bis 15% Feuchte, bevorzugt 5 bis 10% Feuchte der Torrefizierung unterworfen.In one embodiment of the present method, at least a portion of the wood strands used to make the OSB boards are dried prior to torrefying, i. in this case dried or pre-dried wood strands, e.g. subjected to a degree of moisture of 5 to 15% moisture, preferably 5 to 10% moisture of Torrefizierung.

In einer weiteren zweiten Ausführungsform des vorliegenden Verfahrens wird zumindest ein Teil der Holzstrands mit einer Feuchte von 20-50 Gew% torrefiziert, d.h. hier erfolgt keine vorherige Trocknung der Holzstrands, sondern die Holzstrands werden ohne weitere Vorbehandlung nach dem Zerspanen der Torrefizierungsvorrichtung zugeführt.In a further second embodiment of the present method at least a portion of the wood strands are torrefied with a humidity of 20-50% by weight, i. Here no previous drying of the wooden strands, but the wood strands are fed without further pretreatment after chipping the Torrefizierungsvorrichtung.

Entsprechend ermöglicht das vorliegende Verfahren die Torrefizierung von feuchten oder trockenen Holzstrands. Insbesondere die Torrefizierung von feuchten Holzstrands ist vorteilhaft, da der Trocknungsschritt eingespart wird.Accordingly, the present method enables torrefaction of wet or dry wood strands. In particular, the torrefaction of wet wood strands is advantageous because the drying step is saved.

In einer weiteren Ausführungsform des vorliegenden Verfahrens werden torrefizierte Holzstrands oder eine Mischung aus torrefizierten Holzstrands und unbehandelten (d.h. nicht-torrefizierten) Holzstrands als Mittelschicht und/oder Deckschicht der OSB-Werkstoffplatte verwendet.In another embodiment of the present method, torrefined wood strands or a mixture of torrefied wood strands and untreated (ie non-torrefied) wood strands are used as the middle layer and / or top layer of the OSB material board.

Demnach ist in einer Variante eine vollständige Substitution der Holzstrands möglich, wobei die torrefizierten Holzstrands nur in der Mittelschicht, nur in einer oder beiden Deckschichten oder auch in sämtlichen Schichten verwendet werden. In dieser Variante entfällt die Verwendung eines Trockners.Accordingly, in one variant, a complete substitution of the wood strands is possible, the torrefizierten wood strands are used only in the middle layer, only in one or both cover layers or in all layers. In this variant, the use of a dryer is eliminated.

In einer anderen Variante ist es möglich, lediglich die Mittelschicht aus torrefizierten Holzstrands zu bilden und für eine oder beide Deckschichten getrocknete und nichttorrefizierte Holzstrands zu verwenden. Da torrefizierte Strands eine braune Farbe haben, kann es entsprechend vorteilhaft sein, nur in der Mittelschicht torrefizierte Strands einzusetzen.In another variant it is possible to form only the middle layer of torrefied wood strands and to use dried and non-tinted wood strands for one or both cover layers. Since torrefected strands have a brown color, it may be advantageous to use torrefied strands only in the middle layer.

In einer noch weiteren Variante werden lediglich eine oder beide Deckschichten aus torrefizierten Holzstrands gebildet und für die Mittelschicht werden getrocknete und nichttorrefizierte Holzstrands verwendet.In yet another variant, only one or both cover layers are formed of torrefied wood strands, and for the middle layer, dried and untorn wood strands are used.

In einer noch weiteren Variante ist es denkbar und möglich, für die Mittel- und Deckschichten jeweils ein Gemisch mit beliebigen Verhältnis von torrefizierten Holzstrands und nicht-torrefizierten Holzstrands zu verwenden. In solche einem Fall kann das Gemisch zwischen 10 und 50 Gew%, bevorzugt zwischen 20 und 30 Gew% an unbehandelten bzw. nicht-torrefizierten Holzstrands und zwischen 50 und 90 Gew%, bevorzugt zwischen 70 und 80 Gew% an torrefizierten Holzstrands umfassen.In yet another variant, it is conceivable and possible to use for the middle and outer layers in each case a mixture with any ratio of torrefizierten wooden strands and non-torrefected wooden strands. In such a case, the mixture may comprise between 10 and 50% by weight, preferably between 20 and 30% by weight of untreated or non-torrefied wood strands and between 50 and 90% by weight, preferably between 70 and 80% by weight of torrefied wood strands.

In einer weiteren Ausführungsvariante kann der Schritt des Torrefizierens der Holzstrands separat von dem Herstellungsprozess der OSB-Holzwerkstoffplatten durchgeführt werden. Demnach erfolgt der Torrefizierungsschritt in dieser Ausführungsvariante des vorliegenden Verfahrens außerhalb des Gesamtprozesses bzw. der Prozesslinie. Die Holzstrands werden hierbei aus dem Herstellungsprozess ausgeschleust und in die Torrefizierungsvorrichtung (z.B. Torrefizierungsreaktor) eingeführt. Anschließend können die torrefizierten Holzstrands ggf. nach einer Zwischenlagerung z.B. unmittelbar vor der Beleimung wieder in den herkömmlichen Herstellungsprozess eingeschleust werden. Dies ermöglicht eine hohe Flexibilität im Herstellungsverfahren.In a further embodiment, the step of Torrefizierens the wood strands can be performed separately from the manufacturing process of OSB wood-based panels. Thus, in this embodiment of the present method, the torrefaction step occurs outside the overall process or process line. The wood strands are thereby discharged from the manufacturing process and introduced into the torrefying apparatus (e.g., torrefying reactor). Subsequently, the Torrefizierten wood strands may, after an intermediate storage, for example. be returned to the conventional manufacturing process immediately before gluing. This allows a high flexibility in the manufacturing process.

Der Torrefizierungsschritt der Holzstrands kann in einer noch weiteren Ausführungsvariante in den Herstellungsprozess der OSB-Holzwerkstoffplatten integriert sein, d.h. der Torrefizierungsschritt ist in den Gesamtprozess bzw. Prozesslinie eingegliedert und erfolgt online.The Torrefizierungsschritt the wood strands can be integrated in yet another embodiment variant in the manufacturing process of the OSB wood-based panels, ie the Torrefizierungsschritt is incorporated into the overall process or process line and takes place online.

In diesem Falle kann die Torrefizierung unmittelbar nach der Zerspanung und Bereitstellung der Holzstrands erfolgen oder erst nach dem Sichten und Separieren der Holzstrands entsprechend der Verwendung der Holzstrands für Mittel- oder Deckschicht. Im letzteren Fall kann eine separate Torrefizierung der Holzstrands entsprechend den Torrefizierungserfordernissen für die in Mittel- und Deckschicht verwendeten Holzstrands erfolgen.
Die vorliegend verwendeten Holzstrands können eine Länge zwischen 50 bis 200 mm, bevorzugt 70 bis 180 mm, insbesondere bevorzugt 90 bis 150 mm; eine Breite zwischen 5 bis 50 mm, bevorzugt 10 bis 30 mm, insbesondere bevorzugt 15 bis 20 mm; und eine Dicke zwischen 0,1 und 2 mm, bevorzugt zwischen 0, 3 und 1,5 mm, insbesondere bevorzugt zwischen 0, 4 und 1 mm aufweisen.
In einer Ausführungsform weisen die Holzstrands z.B. eine Länge zwischen 150 und 200 mm, eine Breite zwischen 15 und 20 mm, eine Dicke zwischen 0,5 und 1 mm und eine Feuchte von max. 50% auf.
In einer weitergehenden Variante des vorliegenden Verfahrens wird die Torrefizierung der Holzstrands in mindestens einem Torrefizierungsreaktor, bevorzugt in zwei Torrefizierungsreaktoren durchgeführt. Der vorliegend zum Einsatz kommende Torrefizierungsreaktor kann als Batch-Anlage oder als kontinuierlich betriebene Anlage vorliegen bzw. funktionieren.
Wie bereits oben angemerkt, kann die Torrefizierung von für die Mittelschicht und die Deckschichten der OSB-Holzwerkstoffplatte verwendeten Holzstrands jeweils separat in mindestens zwei Torrefizierungsreaktoren durchgeführt wird. Dies ermöglicht eine Anpassung des Torrefizierungsgrades der in der Mittel- und/oder Deckschicht verwendeten torrefizierten Holzstrands an die jeweiligen Erfordernisse und Kundenwünsche.
Die zwei verwendeten Torrefizierungsreaktoren sind in diesem Fall bevorzugt parallel geschaltet bzw. angeordnet. Erfindungsgemäß werden die Holzstrands durch Erhitzen in sauerstoffarmer oder sauerstofffreier Atmosphäre unter Atmosphärendruck bei einer Temperatur zwischen 150°C und 300°C, bevorzugt zwischen 200°C und 280°C, insbesondere bevorzugt zwischen 220°C und 260°C torrefiziert. Es kann unter Atmosphärendruck in Gegenwart eines Inertgases, bevorzugt Stickstoff als Reaktionsgas oder Gasstrom torrefiziert werden. Es ist auch möglich Sattdampf zu verwenden, wobei in diesem Fall der Torrefizierungsprozess bei Temperaturen zwischen 160°C und 200°C und Drücken von 6 bar bis 16 bar abläuft.
In this case, the torrefaction can be carried out immediately after the cutting and provision of the wooden strands, or only after the sifting and separation of the wooden strands according to the use of the wooden strands for the middle or top layer. In the latter case, a separate torrefaction of the wooden strands can be made according to the torrefaction requirements for the wooden strands used in the middle and top layers.
The wood strands used herein may have a length of between 50 to 200 mm, preferably 70 to 180 mm, particularly preferably 90 to 150 mm; a width between 5 to 50 mm, preferably 10 to 30 mm, particularly preferably 15 to 20 mm; and a thickness between 0.1 and 2 mm, preferably between 0, 3 and 1.5 mm, particularly preferably between 0, 4 and 1 mm.
In one embodiment, the wood strands, for example, have a length between 150 and 200 mm, a width between 15 and 20 mm, a thickness between 0.5 and 1 mm and a moisture content of max. 50% up.
In a further variant of the present method, the torrefaction of the wood strands is carried out in at least one Torrefizierungsreaktor, preferably in two Torrefizierungsreaktoren. The Torrefizierungsreaktor used here can be present as a batch system or as a continuously operated system or work.
As noted above, the torrefaction of wood strands used for the middle layer and topsheets of the OSB wood-based panel may each be performed separately in at least two torrefying reactors. This makes it possible to adapt the Torrefizierungsgrades the torrefizierten wooden strands used in the middle and / or top layer to the respective requirements and customer requirements.
The two Torrefizierungsreaktoren used are preferably connected in parallel or arranged in this case. According to the invention, the wood strands are torrefied by heating in an oxygen-poor or oxygen-free atmosphere under atmospheric pressure at a temperature between 150 ° C and 300 ° C, preferably between 200 ° C and 280 ° C, particularly preferably between 220 ° C and 260 ° C. It can be torrefied under atmospheric pressure in the presence of an inert gas, preferably nitrogen as the reaction gas or gas stream. It is also possible to use saturated steam, in which case the Torrefizierungsprozess runs at temperatures between 160 ° C and 200 ° C and pressures of 6 bar to 16 bar.

Der Prozess des Torrefizierens wird bevorzugt bei einem Masseverlust der Holzstrands von 10 bis 30%, bevorzugt 15 bis 20% beendet. Die Dauer des Prozesses variiert in Abhängigkeit der Menge und Art des eingesetzten Ausgangsmaterials und kann zwischen 1 und 5 h, bevorzugt zwischen 2 und 3 h betragen.The process of Torrefizierens is preferably terminated at a loss of mass of the wood strands of 10 to 30%, preferably 15 to 20%. The duration of the process varies depending on the amount and type of the starting material used and can be between 1 and 5 h, preferably between 2 and 3 h.

Die während des Torrefizierungsprozesses im Wesentlichen aus Hemizellulosen und anderen niedermolekularen Verbindungen freigesetzten Pyrolysegase werden zur Erzeugung von Prozessenergie benutzt. Dabei ist die Menge an gebildeten Gasgemisch als gasförmiger Brennstoff ausreichend, um den Prozess energetisch autark zu betreiben.The pyrolysis gases released during the torrefaction process, essentially from hemicelluloses and other low molecular weight compounds, are used to generate process energy. The amount of gas mixture formed as gaseous fuel is sufficient to operate the process energetically self-sufficient.

Es ist ebenfalls bevorzugt, wenn die torrefizierten Holzstrands vor der Beleimung mit einem geeigneten Bindemittel in Wasser abgekühlt werden. So können die torrefizierten Holzstrands in einem Wasserbad abgekühlt werden, das eine vollständige Benetzung mit Wasser sicherstellt. Dem Wasser kann ein Netzmittel, das die Benetzung der hydrophoben Strands erleichtert zugegeben werden.It is also preferred if the torrefied wooden strands are cooled in water before gluing with a suitable binder. Thus, the torrefected wooden strands can be cooled in a water bath, which ensures complete wetting with water. A wetting agent which facilitates the wetting of the hydrophobic strands can be added to the water.

Das In-Kontaktbringen der Holzstrands mit dem mindestens einen Bindemittel in Schritt c) erfolgt bevorzugt durch Aufsprühen bzw. Verdüsen des Bindemittels auf die Holzstrands. So arbeiten viele OSB-Anlagen mit rotierenden Coils (Trommeln mit Atomizer-Beleimung). Eine Mischerbeleimung wäre auch möglich. Dabei werden die Strands in einem Mischer durch sich drehende Schaufeln innig mit dem Leim vermischt.The contacting of the wood strands with the at least one binder in step c) is preferably carried out by spraying or atomizing the binder onto the wood strands. Many OSB systems work with rotating coils (drums with atomizer gluing). A mixer gluing would also be possible. The strands are intimately mixed with the glue in a mixer by rotating blades.

In einer Ausführungsform des vorliegenden Verfahrens wird bevorzugt ein Polymerklebstoff als Bindemittel verwendet, der ausgewählt ist aus der Gruppe enthaltend Formaldehyd-Klebstoffe, Polyurethan-Klebstoffe, Epoxidharz-Klebstoffe, Polyester-Klebstoffe. Als Formaldehydkondensat-Klebstoff kann insbesondere ein Phenol-Formaldehydharz-Klebstoff (PF), ein Kresol-/ Resorcin-Formaldehydharz-Klebstoff, Harnstoff-Formaldehyd Harz-Klebstoff (UF) und/oder Melamin-Formaldehyd Harz Klebstoff (MF) verwendet werden.In one embodiment of the present method, a polymer adhesive is preferably used as a binder which is selected from the group consisting of formaldehyde adhesives, polyurethane adhesives, epoxy adhesives, polyester adhesives. As the formaldehyde condensate adhesive, in particular, a phenol-formaldehyde resin adhesive (PF), a cresol / resorcinol-formaldehyde resin adhesive, urea-formaldehyde resin adhesive (UF) and / or melamine-formaldehyde resin adhesive (MF) can be used.

Vorliegend ist die Verwendung eines Polyurethan-Klebstoffes bevorzugt, wobei der Polyurethan-Klebstoff auf der Basis von aromatischen Polyisocyanaten, insbesondere Polydiphenylmethandiisocyanat (PMDI), Toluylendiisocyanat (TDI) und/oder Diphenylmethandiisocyanat (MDI) vorliegt, wobei PMDI besonders bevorzugt ist.In the present case, the use of a polyurethane adhesive is preferred, wherein the polyurethane adhesive based on aromatic polyisocyanates, in particular Polydiphenylmethane diisocyanate (PMDI), tolylene diisocyanate (TDI) and / or diphenylmethane diisocyanate (MDI) is present, with PMDI being particularly preferred.

Im Falle der Verwendung von PMDI-Klebstoffen werden die die torrefizierten und nicht-torrefizierten Holzstrands mit einer Bindemittelmenge von 1,0 bis 5,0 Gew%, bevorzugt 2 bis 4 Gew%, insbesondere 3 Gew% (bezogen auf die Gesamtmenge der Holzstrands) beleimt.In the case of using PMDI adhesives, the torrefied and non-torrefied wood strands having a binder amount of 1.0 to 5.0% by weight, preferably 2 to 4% by weight, especially 3% by weight (based on the total amount of wood strands) glued.

In einer weiteren Ausführungsform des vorliegenden Verfahrens ist es ebenfalls möglich mehr als einen Polymerklebstoff zu verwenden. So können als erster Polymerklebstoff mindestens ein Polykondensationsklebstoff wie ein Polyamid-, ein Polyester-, ein Silikon- und/oder ein Formaldehydkondensat-Klebstoff, insbesondere ein Phenol-Formaldehyd-Harz-Klebstoff (PF), ein Kresol-/ Resorcin-Formaldehydharz-Klebstoff, Harnstoff-Formaldehyd-Harz-Klebstoff (UF) und/oder Melamin-Formaldehyd-Harz-Klebstoff (MF) verwendet werden, und als zweiter Polymerklebstoff mindestens ein Polyadditionsklebstoff wie ein Epoxidharz-, Polycyanurat- und/oder ein Polyurethan-Klebstoff, insbesondere ein Polyurethan-Klebstoff auf der Basis von Polydiphenylmethandiisocyanat (PMDI), verwendet werden. Derartige Hybridklebstoffsysteme sind aus der EP 2 447 332 B1 bekannt.In a further embodiment of the present method, it is also possible to use more than one polymer adhesive. Thus, as the first polymer adhesive at least one polycondensation adhesive such as a polyamide, a polyester, a silicone and / or a formaldehyde condensate adhesive, in particular a phenol-formaldehyde resin adhesive (PF), a cresol / resorcinol formaldehyde resin adhesive , Urea-formaldehyde-resin adhesive (UF) and / or melamine-formaldehyde-resin adhesive (MF) are used, and as the second polymer adhesive at least one polyaddition adhesive such as an epoxy resin, polycyanurate and / or a polyurethane adhesive, in particular a polyurethane adhesive based on polydiphenylmethane diisocyanate (PMDI) can be used. Such hybrid adhesive systems are known from EP 2 447 332 B1 known.

Die folgenden Bindemittelvarianten sind besonders bevorzugt: Phenol-Formaldehyd-Klebstoff (PF); Melamin-Harnstoff-Formaldehyd-Harz-Klebstoff (MUF); Melamin-Harnstoff-Phenol Formaldehyd-Harz-Klebstoff (MUPF); PMDI-Klebstoffe und eine Kombination von MUF/MUPF und PMDI-Klebstoffen. In letzterem Fall wird für die Mittelschicht bevorzugt PMDI und in den Deckschichten MUF oder MUPF als Bindemittel verwendet. Besonders bevorzugt ist die Verwendung von PMDI-Klebstoffen für alle Schichten, d.h. für die Deckschichten und die Mittelschicht.The following binder variants are particularly preferred: phenol-formaldehyde adhesive (PF); Melamine-urea-formaldehyde-resin adhesive (MUF); Melamine-urea-phenol formaldehyde resin adhesive (MUPF); PMDI adhesives and a combination of MUF / MUPF and PMDI adhesives. In the latter case, preference is given to using PMDI for the middle layer and as binder in the outer layers MUF or MUPF. Particularly preferred is the use of PMDI adhesives for all layers, i. for the cover layers and the middle layer.

Es ist ebenfalls möglich, zusammen oder separat mit dem Bindemittel den Holzstrands mindestens ein Flammschutzmittel zuzuführen.It is also possible to supply at least one flame retardant to the wood strands together or separately with the binder.

Das Flammschutzmittel kann typischerweise in einer Menge zwischen 1 und 20 Gew%, bevorzugt zwischen 5 und 15 Gew%, insbesondere bevorzugt ≥10 Gew% bezogen auf die Gesamtmenge der Holzstrands zugegeben werden.The flame retardant may typically be added in an amount between 1 and 20% by weight, preferably between 5 and 15% by weight, particularly preferably ≥ 10% by weight, based on the total amount of wood strands.

Typische Flammschutzmittel sind ausgewählt aus der Gruppe umfassend Phosphate, Borate, insbesondere Ammoniumpolyphosphat, Tris(tri-bromneopentyl)phosphat, Zinkborat oder Borsäurekomplexe von mehrwertigen Alkoholen.Typical flame retardants are selected from the group comprising phosphates, borates, in particular ammonium polyphosphate, tris (tri-bromneopentyl) phosphate, zinc borate or boric acid complexes of polyhydric alcohols.

Die beleimten (torrefizierten und/oder nicht-torrefizierten) Holzstrands werden auf ein Transportband unter Ausbildung einer ersten Deckschicht längs zur Transportrichtung, anschließend unter Ausbildung einer Mittelschicht quer zur Transportrichtung und abschließend unter Ausbildung einer zweiten Deckschicht längs zur Transportrichtung aufgestreut.The glued (torrefied and / or non-torrefied) wood strands are scattered onto a conveyor belt to form a first cover layer along the transport direction, then to form a middle layer transversely to the transport direction and finally to form a second cover layer along the transport direction.

Nach dem Aufstreuen erfolgt das Verpressen der beleimten Holzstrands bei Temperaturen zwischen 200 und 250°C, bevorzugt 220 und 230°C zu einer OSB-Holzwerkstoffplatte.After sprinkling, the glued wooden strands are pressed at temperatures between 200 and 250 ° C., preferably 220 and 230 ° C., to form an OSB wood-based panel.

In einer ersten bevorzugten Ausführungsform umfasst das vorliegende Verfahren zur Herstellung einer OSB-Holzwerkstoffplatte mit reduzierter VOC-Emission die folgenden Schritte:

  • Herstellen von Holzstrands aus geeigneten Hölzern, insbesondere mittels Zerspanen von geeigneten Hölzern,
  • Torrefizieren der Holzstrands ohne vorherige Trocknung der Holzstrands;
  • Sichten und Separieren der torrefizierten Holzstrands in Holzstrands geeignet zur Verwendung als Mittelschicht und Deckschicht;
  • Beleimen der separierten torrefizierten Holzstrands;
  • Aufstreuen der beleimten torrefizierten Holzstrands auf ein Transportband in der Reihenfolge erste untere Deckschicht, Mittelschicht und zweite obere Deckschicht; und
  • Verpressen der beleimten Holzstrands zu einer OSB-Holzwerkstoffplatte.
In a first preferred embodiment, the present process for producing an OSB wood-based panel with reduced VOC emission comprises the following steps:
  • Making wooden strips of suitable woods, in particular by means of cutting suitable woods,
  • Torrefying the wooden strands without first drying the wooden strands;
  • Sifting and separating the torrefied wooden strands in wooden strands suitable for use as a middle layer and topcoat;
  • Gluing the separated torrefected wooden strips;
  • Sprinkling the glued torrefied wooden strands on a conveyor belt in the order of first lower cover layer, middle layer and second upper cover layer; and
  • Pressing the glued wooden strands into an OSB wood-based panel.

In einer zweiten bevorzugten Ausführungsform umfasst das vorliegende Verfahren zur Herstellung einer OSB-Holzwerkstoffplatte mit reduzierter VOC-Emission die folgenden Schritte:

  • Herstellen von Holzstrands aus geeigneten Hölzern, insbesondere mittels Zerspanen von geeigneten Hölzern;
  • ggfs. Trocknen der Holzstrands;
  • Sichten und Separieren der Holzstrands in Holzstrands geeignet zur Verwendung als Mittelschicht und Deckschicht;
  • Torrefizieren der für die Mittelschicht vorgesehenen Holzstrands und/oder Torrefizieren der für die Deckschicht(en) vorgesehenen Holzstrands;
  • Beleimen der separierten torrefizierten Holzstrands;
  • Aufstreuen der beleimten torrefizierten Holzstrands auf ein Transportband in der Reihenfolge erste untere Deckschicht, Mittelschicht und zweite obere Deckschicht; und
  • Verpressen der beleimten Holzstrands zu einer OSB-Holzwerkstoffplatte.
In a second preferred embodiment, the present process for producing an OSB wood-based panel with reduced VOC emission comprises the following steps:
  • Manufacture of wooden strips of suitable woods, in particular by means of cutting of suitable woods;
  • if necessary, drying the wooden strips;
  • Sifting and separating the wooden strands in wooden strands suitable for use as a middle layer and topcoat;
  • Torrefying the wooden strands provided for the middle layer and / or torrefying the wood strands provided for the cover layer (s);
  • Gluing the separated torrefected wooden strips;
  • Sprinkling the glued torrefied wooden strands on a conveyor belt in the order of first lower cover layer, middle layer and second upper cover layer; and
  • Pressing the glued wooden strands into an OSB wood-based panel.

Entsprechend ermöglicht das vorliegende Verfahren die Herstellung einer OSB-Holzwerkstoffplatte mit reduzierter Emission an flüchtigen organischen Verbindungen (VOCs), welche torrefizierte Holzstrands umfasst.Accordingly, the present method enables the production of an OSB wood-based panel with reduced emission of volatile organic compounds (VOCs) comprising torrefied wood strands.

Die mit dem vorliegenden Verfahren hergestellte OSB-Holzwerkstoffplatte weist insbesondere eine reduzierte Emission von während des Holzaufschlusses freigesetzten Aldehyden, insbesondere Pentanal oder Hexanal, organischen Säuren wie Essigsäure und/oder Terpenen, insbesondere Caren und Pinen auf. Diesbezüglich wird auch auf die Ausführungen weiter unten verwiesen.The OSB wood-based panel produced by the present method has in particular a reduced emission of aldehydes released during wood pulping, in particular pentanal or hexanal, organic acids such as acetic acid and / or terpenes, in particular carene and pinene. In this regard, reference is also made to the comments below.

Die vorliegende OSB-Holzwerkstoffplatte kann dabei vollständig aus torrefizierten Holzstrands oder aus einem Gemisch von torrefizierten und nicht-torrefizierten Holzstrands bestehen.The present OSB wood-based panel may consist entirely of torrefied wooden strands or of a mixture of torrefied and non-torrefied wooden strands.

Die vorliegende OSB-Werkstoffplatte weist einen gegenüber einer vollständig aus nicht-torrefizierten Holzstrands hergestellten OSB-Werkstoffplatten reduzierten Quellwert, insbesondere einen um 20% bis 50%, bevorzugt 30% bis 40% z.B. um 35 % reduzierten Quellwert auf. Die Quellneigung der vorliegenden OSB-Holzwerkstoffplatte liegt zwischen 5 und 30%, bevorzugt zwischen 10 und 25 %, insbesondere bevorzugt zwischen 15 und 20% (nach 24 h Wasserlagerung).The present OSB board has a reduced swelling value, in particular one of 20% to 50%, preferably 30% to 40%, compared to OSB boards made entirely of non-torrefied wood strips. reduced source value by 35%. The swelling tendency of the present OSB wood-based panel is between 5 and 30%, preferably between 10 and 25%, particularly preferably between 15 and 20% (after 24 hours of water storage).

Die vorliegende OSB-Holzwerkstoffplatte kann eine Rohdichte zwischen 300 und 1000 kg/m3, bevorzugt zwischen 500 und 800 kg/m3, insbesondere bevorzugt zwischen 500 und 600 kg/m3 aufweisen.The present OSB wood-based panel may have a bulk density between 300 and 1000 kg / m 3 , preferably between 500 and 800 kg / m 3 , particularly preferably between 500 and 600 kg / m 3 .

Die Dicke der vorliegenden OSB-Holzwerkstoffplatte kann zwischen 5 und 50 mm, bevorzugt zwischen 10 und 40 mm betragen, wobei insbesondere eine Dicke zwischen 15 und 25 mm bevorzugt ist.The thickness of the present OSB wood-based panel may be between 5 and 50 mm, preferably between 10 and 40 mm, wherein in particular a thickness between 15 and 25 mm is preferred.

Die Aufgabe der vorliegenden Erfindung wird ebenfalls mit der Verwendung von torrefizierten Holzstrands zur Reduzierung der Emission von flüchtigen organischen Verbindungen (VOCs) aus OSB-Holzwerkstoffplatten gelöst.The object of the present invention is also achieved with the use of torrefied wood strands to reduce the emission of volatile organic compounds (VOCs) from OSB wood-based panels.

In einer bevorzugten Variante werden die torrefizierten Holzstrands zur Reduzierung von während des Holzaufschlusses, insbesondere der Zerspanung der Hölzer in Strands, freigesetzten Aldehyden, organischen Säuren und/oder Terpenen verwendet.In a preferred variant, the torrefected wood strands are used for reducing aldehydes, organic acids and / or terpenes released during the wood pulping, in particular the cutting of the woods in strands.

Entsprechend werden die torrefizierten Holzstrands vorliegend bevorzugt zur Reduzierung der Emission von organischen Säuren, insbesondere zur Reduzierung der Emission von Essigsäure aus OSB-Holzwerkstoffplatten verwendet. Organische Säuren fallen insbesondere als Spaltprodukte der Holzbestandteile Zellulose, Hemizellulosen und Lignin an, wobei bevorzugt Alkansäuren, wie Essigsäure und Propionsäure oder aromatische Säuren gebildet werden.Accordingly, in the present case, the torrefied wood strands are preferably used for reducing the emission of organic acids, in particular for reducing the emission of acetic acid from OSB wood-based panels. Organic acids are produced in particular as cleavage products of the wood constituents cellulose, hemicelluloses and lignin, alkanoic acids such as acetic acid and propionic acid or aromatic acids preferably being formed.

Es ist ebenfalls wünschenswert, die torrefizierten Holzstrands zur Reduzierung der Emission von Aldehyden aus OSB-Holzwerkstoffplatten einzusetzen. Wie oben bereits erläutert, erfolgt eine Freisetzung von Aldehyden während der hydrolytischen Aufarbeitung von Holz bzw. Lignozellulose. Dabei können spezifische Aldehyde aus den Grundbausteinen der Zellulose oder Hemizellulose gebildet werden. So wird z.B. der Aldehyd Furfural aus Mono-und Disacchariden der Zellulose bzw. Hemizellulose gebildet, während aromatische Aldehyde während des partiell stattfindenden hydrolytischen Ausschlusses von Lignin freigesetzt werden können. Entsprechend werden die torrefizierten Holzstrands zur Reduzierung der Emission von C1-C10 Aldehyden, insbesondere bevorzugt vom Formaldehyd, Acetaldehyd, Pentanal, Hexanal oder auch Furfural in OSB-Holzwerkstoffplatten eingesetzt.It is also desirable to use the torrefied wood strands to reduce the emission of aldehydes from OSB wood-based panels. As already explained above, there is a release of aldehydes during the hydrolytic workup of wood or lignocellulose. In this case, specific aldehydes can be formed from the basic building blocks of cellulose or hemicellulose. For example, the aldehyde furfural is formed from mono- and disaccharides of cellulose or hemicellulose, while aromatic aldehydes can be liberated during the partial hydrolytic exclusion of lignin. Accordingly, the Torrefizierten wood strands to reduce the emission of C1-C10 aldehydes, particularly preferably from formaldehyde, acetaldehyde, pentanal, hexanal or furfural used in OSB wood-based panels.

In einer weiteren Ausführungsform der vorliegenden Erfindung werden die torrefizierten Holzstrands zur Reduzierung der Emission von Terpenen verwendet. So können die torrefizierten Holzstrands zur Reduzierung von freigesetzten Terpenen, insbesondere C10-Monoterpene und C15-Sesquiterpene, insbesondere bevorzugt acyclische oder cyclische Monoterpene eingesetzt werden.In another embodiment of the present invention, the torrefied wooden strands are used to reduce the emission of terpenes. For example, the torrefied wood strands can be used to reduce liberated terpenes, in particular C10 monoterpenes and C15 sesquiterpenes, particularly preferably acyclic or cyclic monoterpenes.

Typische acyclische Terpene sind Terpenkohlenwasserstoffe wie Myrcen, Terpenalkohole wie Gerianol, Linaool, Ipsinol und Terpenaldehyde wie Citral. Typische Vertreter der monocyclischen Terpene sind p-Menthan, Terpeninol, Limonen oder Carvon, und typische Vertreter der bicyclischen Terpene sind Caran, Pinan, Bornan, wobei insbesondere 3-Caren und α-Pinen von Bedeutung sind. Terpene sind Bestandteile der Baumharze und von daher besonders in sehr harzhaltigen Baumarten wie Kiefer oder Fichte vorhanden.Typical acyclic terpenes are terpene hydrocarbons such as myrcene, terpene alcohols such as gerianol, linaool, ipsinol and terpene aldehydes such as citral. Typical representatives of the monocyclic terpenes are p-menthane, terpeninol, limonene or carvone, and typical representatives of the bicyclic terpenes are caran, pinane, bornan, in particular 3-carene and α-pinene being of importance. Terpenes are components of the tree resins and therefore especially in very resinous tree species such as pine or spruce.

Die Erfindung wird nachfolgend unter Bezugnahme auf die Figur der Zeichnung an einem Ausführungsbeispiel näher erläutert. Es zeigen:

Figur 1
eine schematische Darstellung einer ersten Ausführungsform des erfindungsgemäßen Verfahrens, und
Figur 2
eine schematische Darstellung einer zweiten Ausführungsform des erfindungsgemäßen Verfahrens.
The invention will be explained in more detail with reference to the figure of the drawing of an embodiment. Show it:
FIG. 1
a schematic representation of a first embodiment of the method according to the invention, and
FIG. 2
a schematic representation of a second embodiment of the method according to the invention.

Die in Figur 1 gezeigte erste Ausführungsform des erfindungsgemäßen Verfahrens beschreibt die einzelnen Verfahrensschritte beginnend mit dem Bereitstellen des Holzausgangsproduktes bis zur fertigen OSB-Holzwerkstoffplatte.In the FIG. 1 shown first embodiment of the method according to the invention describes the individual process steps, starting with the provision of the wood output product to the finished OSB wood-based panel.

Entsprechend wird zunächst in Schritt 1 geeignetes Holzausgangsmaterial zur Herstellung der Holzstrands bereitgestellt. Als Holzausgangsmaterial sind sämtliche Nadelhölzer, Laubhölzer oder auch Mischungen davon geeignet.Accordingly, in step 1 suitable wood starting material for the production of the wood strands is first provided. As wood source material all conifers, hardwoods or mixtures thereof are suitable.

Das Entrinden (Schritt 2) und das Zerspanen (Schritt 3) des Holzausgangsmaterials erfolgt in hierfür geeigneten Zerspanern, wobei die Größe der Holzstrands entsprechend gesteuert werden kann. Nach Zerkleinerung und Bereitstellung der Holzstrands werden diese ggf. einem Vortrocknungsprozess unterzogen, wobei eine Feuchte von 5-10 % in Bezug auf die Ausgangsfeuchte der Holzhackschnitzel eingestellt wird (nicht gezeigt).The debarking (step 2) and the cutting (step 3) of the wood starting material takes place in suitable chippers, wherein the size of the wood strands can be controlled accordingly. After comminution and provision of the wood strands, they are optionally subjected to a predrying process, with a moisture content of 5-10% being set with respect to the initial moisture content of the woodchips (not shown).

Im Falle der in Figur 1 gezeigten Ausführungsform werden die Holzstrands in einen Torrefizierungsreaktor eingeführt (Schritt 4). Die Torrefizierung der Holzstrands erfolgt in einem Temperaturbereich zwischen 220° und 260°C. Die dabei entstehenden Pyrolysegase bzw. Torrgase werden zur Erzeugung der für die Prozessanlage notwendigen Energie genutzt.In the case of in FIG. 1 In the embodiment shown, the wooden strands are introduced into a torrefying reactor (step 4). The torrefaction of the wooden strands takes place in a temperature range between 220 ° and 260 ° C. The resulting pyrolysis gases or Torrgase be used to generate the necessary energy for the process plant.

Nach Abschluss der Torrefizierung, die im vorliegenden Fall ca. 2 Stunden dauert, werden die torrefizierten Holzstrands gewässert, gesichtet und separiert (Schritt 5).After completion of the torrefaction, which in the present case takes about 2 hours, the torrefected wooden strands are watered, sighted and separated (step 5).

Es erfolgt eine Separierung in Holzstrands zur Verwendung als Mittelschicht (Schritt 6a) oder als Deckschicht (Schritt 6b) mit jeweiliger Beleimung.There is a separation in wooden strands for use as a middle layer (step 6a) or as a cover layer (step 6b) with respective gluing.

Die beleimten torrefizierten Holzstrands werden auf ein Transportband in der Reihenfolge erste untere Deckschicht, Mittelschicht und zweite obere Deckschicht aufgestreut (Schritt 7) und anschließend zu einer OSB-Holzwerkstoffplatte verpresst (Schritt 8).The glued Torrefizierten wood strands are scattered onto a conveyor belt in the order first lower cover layer, middle layer and second upper cover layer (step 7) and then pressed to form an OSB wood-based panel (step 8).

In der in Figur 2 gezeigten zweiten Ausführungsform wird das Holzausgangsmaterial in Analogie zu Figur 1 zunächst bereitgestellt (Schritt 1), entrindet (Schritt 2) und zerspant (Schritt 3). Die Holzstrands werden ggf. einem Vortrocknungsprozess unterzogen, wobei eine Feuchte von 5-10 % in Bezug auf die Ausgangsfeuchte der Holzstrands eingestellt wird (Schritt 3a). Im Unterschied zu der Ausführungsvariante der Figur 1 erfolgt bereits nach der optionalen Trocknung eine Separierung in Holzstrands zur Verwendung als Mittelschicht oder als Deckschicht (Schritt 5).In the in FIG. 2 As shown in the second embodiment, the wood starting material is analogous to FIG. 1 initially provided (step 1), debarked (step 2) and machined (step 3). The strands of wood may be subjected to a predrying process, with a humidity of 5-10% being adjusted in relation to the initial moisture content of the strands of wood (step 3a). In contrast to the variant of the FIG. 1 a separation in wood strands is already carried out after the optional drying for use as a middle layer or as a cover layer (step 5).

Daran schließt sich die Torrefizierung der für die Mittelschicht vorgesehenen Holzstrands (Schritt 4a) und/oder Torrefizierung der für die Deckschicht(en) vorgesehene Holzstrands (Schritt 4b) in einem jeweils geeigneten Torrefizierungsreaktor an. Die Torrefizierung der Holzstrands erfolgt in einem Temperaturbereich zwischen 220° und 260°C. Die Torrefizierung kann auf den gewünschten Torrefizierungsgrad für die Mittel- und Deckschichten eingestellt werden.This is followed by torrefaction of the wood strands provided for the middle layer (step 4a) and / or torrefaction of the wood strands (step 4b) provided for the cover layer (s) in a suitable torrefaction reactor. The torrefaction of the wooden strands takes place in a temperature range between 220 ° and 260 ° C. Torrefaction can be set to the desired torrefaction level for the center and top layers.

Die dabei entstehenden Pyrolysegase bzw. Torrgase werden zur Erzeugung der für die Prozessanlage notwendigen Energie genutzt.The resulting pyrolysis gases or Torrgase be used to generate the necessary energy for the process plant.

Nach Abschluss der Torrefizierung, die im vorliegenden Fall ca. 2 Stunden dauert, werden die torrefizierten Holzstrands beleimt (Schritte 6 a,b).After completion of the torrefaction, which takes in the present case about 2 hours, the Torrefizierten wooden strands are glued (steps 6 a, b).

Die beleimten torrefizierten Holzstrands werden auf ein Transportband in der Reihenfolge erste untere Deckschicht, Mittelschicht und zweite obere Deckschicht aufgestreut (Schritt 7) und anschließend zu einer OSB-Holzwerkstoffplatte verpresst (Schritt 8).The glued Torrefizierten wood strands are scattered onto a conveyor belt in the order first lower cover layer, middle layer and second upper cover layer (step 7) and then pressed to form an OSB wood-based panel (step 8).

In der Endbearbeitung wird die erhaltene OSB-Holzwerkstoffplatte jeweils in geeigneter Weise konfektioniert.In the finishing, the obtained OSB wood-based panel is assembled in each case in a suitable manner.

Ausführungsbeispiel:Embodiment:

Aus Kiefernstämmen werden Strands erzeugt und in einer kontinuierlich arbeitenden Torrefizierungsapparatur bei 180°C bis zu einem Masseverlust von ca. 20% torrefiziert. Dies erfolgt unter Sattdampf. Bei dem Prozess verfärben sich die Strands von hellgelb nach hellbraun. Anschließend werden die Strands in Wasser abgekühlt.Strands are produced from pine logs and torrefied in a continuous torrefaction apparatus at 180 ° C to a mass loss of about 20%. This takes place under saturated steam. In the process, the beaches turn from light yellow to light brown. The beaches are then cooled in water.

Anschließend wird das Bindemittel (PMDI, ca. 3 Gew%) in einer Beleimmaschine (Beleimtrommel, beispielsweise der Fa. Coil) fein verteilt auf die torrefizierten Holzstrands aufgebracht. Die beleimten torrefizierten Stands werden in einer OSB-Anlage als Mittelschicht gestreut.Subsequently, the binder (PMDI, about 3% by weight) in a gluing machine (Beleimtrommel, for example, the Fa. Coil) finely distributed on the torrefizierten wooden strands applied. The glued torrefied stands are sprinkled in an OSB plant as a middle layer.

Die Deckschicht wird aus Strands gebildet, die in einem Trommeltrockner getrocknet worden sind. Diese sind ebenfalls mit PMDI als Leim (ca. 3 Gew%) beleimt worden. Die Strands werden nicht durch z. B. eine Paraffinemulsion zusätzlich hydrophobiert, um die anschließend durchzuführenden Prüfungen nicht durch das Hydrophobierungsmittel zu stören. Die gestreuten Strands werden in einer Contipresse zu OSB-Platten verpresst.The cover layer is formed from strands which have been dried in a tumble dryer. These have also been glued with PMDI as a glue (about 3% by weight). The beaches are not z. As a paraffin emulsion additionally hydrophobic, so as not to interfere with the subsequently performed tests by the hydrophobing agent. The scattered strands are pressed in a Contipresse to OSB plates.

Die prozentuale Verteilung zwischen Mittel- und Deckschicht ist mindestens 70% zu 30%. Die Strands werden zu Platten verpresst, die eine Rohdichte von ca. 570 kg/m3 haben.The percentage distribution between middle and top layer is at least 70% to 30%. The strands are pressed into slabs with a density of about 570 kg / m 3 .

Nach einer Lagerzeit von ca. einer Woche wurde die Versuchsplatte zusammen mit einer Standardplatte in gleicher Stärke in einer Mikrokammer auf die VOC-Abgabe geprüft.After a storage time of about one week, the test plate was tested together with a standard plate in the same strength in a micro-chamber on the VOC delivery.

Kammerparameter: Temperatur 23°C; Feuchte 0%; Luftdurchfluss 150 ml/min; Luftwechsel 188 / h; Beladung 48,8 m2/m3; Probenoberfläche 0,003 m2, Kammervolumen: 48 mlChamber parameters: temperature 23 ° C; Humidity 0%; Air flow 150 ml / min; Air exchange 188 / h; Load 48.8 m 2 / m 3 ; Sample surface 0.003 m 2 , chamber volume: 48 ml

Die Werte der mengenmäßig wichtigsten Parameter sind in der Tabelle 1 dargestellt. Tabelle 1 Parameter Versuchsplatte µg/m2 x h Standardplatte µg/m2 x h Hexanal 1093 3164 3-Carene 388 1962 α-Pinene 322 1174 Pentanal 78 354 β-Pinen 98 314 The values of the quantitatively most important parameters are shown in Table 1. Table 1 parameter Test plate μg / m 2 xh Standard plate μg / m 2 xh hexanal 1093 3164 3-Carene 388 1962 α-Pinene 322 1174 pentanal 78 354 β-pinene 98 314

Wie aus den Ergebnissen zu entnehmen ist, werden die Emissionen der mengenmäßig wichtigsten Parameter um den Faktor 3 bis 5 reduziert.As can be seen from the results, the emissions of the quantitatively most important parameters are reduced by a factor of 3 to 5.

Zusätzlich wurde auch die Dickenquellung bestimmt. Tabelle 2 Versuchsplatte Standardplatte Quellung (24 h ) in % 18,3 27,44 In addition, the thickness swelling was determined. Table 2 test drive standard plate Swelling (24 h) in% 18.3 27.44

Wie aus der Tabelle zu entnehmen ist, werden die Quellwerte durch die Verwendung von torrefizierten Strands um ca. 35% reduziert.As can be seen from the table, the source values are reduced by about 35% through the use of torrefied strands.

Claims (15)

  1. Process for the production of OSB-wood-composite boards, in particular of OSB-wood-composite boards with reduced emission of volatile organic compounds (VOCs), comprising the following steps:
    a) production of wood strands made of suitable woods,
    b) torrefaction of at least a portion of the wood strands via heating in a low-oxygen-content or oxygen-free atmosphere under atmospheric pressure or elevated pressure at a temperature of from 150°C to 300°C;
    c) gluing of the torrefied wood strands and non-torrefied wood strands with at least one binder;
    d) application, by scattering, of the glued wood strands to a conveyor belt; and
    e) pressing of the glued wood strands to give an OSB-wood-composite board.
  2. Process according to Claim 1, characterized in that at least a portion of the wood strands is dried before torrefaction.
  3. Process according to Claim 1, characterized in that at least a portion of the wood strands is torrefied with moisture content of from 20 to 50% by weight.
  4. Process according to any of the preceding claims, characterized in that torrefied wood strands, or a mixture of torrefied wood strands and non-torrefied wood strands, are/is used as middle layer and/or outer layer of the OSB-wood-composite board.
  5. Process according to any of the preceding claims, characterized in that the wood strands are torrefied in at least one torrefaction reactor, preferably in two torrefaction reactors.
  6. Process according to any of the preceding claims, characterized in that wood strands used for the middle layer and the outer layers of the OSB-wood-composite board are respectively torrefied separately in at least two torrefaction reactors.
  7. Process according to any of the preceding claims, characterized in that the wood strands are torrefied via heating in a low-oxygen-content or oxygen-free atmosphere under atmospheric pressure or elevated pressure at a temperature of from 200°C to 280°C, with particular preference from 220°C to 260°C.
  8. Process according to any of the preceding claims, characterized in that, before gluing with a suitable binder, the torrefied wood strands are cooled in water.
  9. Process according to any of the preceding claims, characterized in that the quantity of binder used to glue the torrefied and non-torrefied wood strands is from 1.0 to 5.0% by weight, preferably from 2 to 4% by weight, in particular 3% by weight (based on the total quantity of the wood strands).
  10. Process according to any of the preceding claims, characterized in that the glued wood strands are pressed at temperatures of from 200 to 250°C, preferably from 220 to 230°C, to give an OSB-wood-composite board.
  11. OSB-wood-composite board with reduced emission of volatile organic compounds (VOCs) which can be produced in a process according to any of the preceding claims comprising torrefied wood strands.
  12. OSB-wood-composite board according to Claim 11, characterized by reduced emission of terpenes and/or organic acids and/or aldehydes liberated during wood digestion.
  13. OSB-wood-composite board according to Claim 11 or 12, characterized by a swelling value reduced in comparison with that of an OSB-wood-composite board produced entirely from non-torrefied wood strands, in particular a swelling value reduced by from 20% to 50%, preferably from 30% to 40%.
  14. OSB-wood-composite board according to any of Claims 11 to 13, characterized in that this is composed entirely of torrefied wood strands or of a mixture of torrefied and non-torrefied wood strands.
  15. Use of torrefied wood strands for reducing emission of volatile organic compounds (VOCs) from OSB-wood-composite boards.
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ES15195141.5T ES2660426T3 (en) 2015-11-18 2015-11-18 OSB wood-oriented material board (oriented strand board) with improved properties and production process
PL15195141T PL3170635T3 (en) 2015-11-18 2015-11-18 Osb (oriented strand board) - wood material board with improved properties and method for producing same
EP15195141.5A EP3170635B1 (en) 2015-11-18 2015-11-18 Osb (oriented strand board) - wood material board with improved properties and method for producing same
HUE15195141A HUE036992T2 (en) 2015-11-18 2015-11-18 Osb (oriented strand board) - wood material board with improved properties and method for producing same
PT151951415T PT3170635T (en) 2015-11-18 2015-11-18 Osb (oriented strand board) - wood material board with improved properties and method for producing same
CA3005487A CA3005487C (en) 2015-11-18 2016-11-03 Osb (oriented strand board) wood material panel having improved properties and method for producing same
BR112018009286A BR112018009286A8 (en) 2015-11-18 2016-11-03 osb (oriented strand board) material board with improved properties and processes for producing it
CN201680067067.4A CN108290311B (en) 2015-11-18 2016-11-03 The application of OSB wood-based plate and its manufacturing method and baked wooden shavings
EP16794248.1A EP3377283B1 (en) 2015-11-18 2016-11-03 Osb (oriented strand board) - wood material board with improved properties and method for producing same
US15/773,328 US10730202B2 (en) 2015-11-18 2016-11-03 OSB (oriented strand board) wood material panel having improved properties and method for producing same
RU2018121541A RU2684738C1 (en) 2015-11-18 2016-11-03 Osb (oriented strand board) based on wood material with improved characteristics and method of its manufacture
PCT/EP2016/076565 WO2017084884A1 (en) 2015-11-18 2016-11-03 Osb (oriented strand board) wood material panel having improved properties and method for producing same
PL16794248T PL3377283T3 (en) 2015-11-18 2016-11-03 Osb (oriented strand board) - wood material board with improved properties and method for producing same
ES16794248T ES2812200T3 (en) 2015-11-18 2016-11-03 Board made of material derived from OSB wood (oriented strand board) with improved properties and a procedure for its manufacture
CN201910288929.1A CN110142831B (en) 2015-11-18 2016-11-03 OSB (oriented strand Board) artificial board having improved characteristics and method for manufacturing the same
UAA201806272A UA124056C2 (en) 2015-11-18 2016-11-03 Osb (oriented strand board) wood material panel having improved properties and method for producing same
PT167942481T PT3377283T (en) 2015-11-18 2016-11-03 Osb (oriented strand board) wood material panel having improved properties and method for producing same
HUE16794248A HUE050465T2 (en) 2015-11-18 2016-11-03 Osb (oriented strand board) - wood material board with improved properties and method for producing same
JP2018525776A JP6518385B2 (en) 2015-11-18 2016-11-03 OSB (oriented strand board) wood material panel with improved properties and method of making the same
RU2019108980A RU2766676C2 (en) 2015-11-18 2019-03-27 Osb board (oriented strand board) based on a wood material with improved characteristics and method for manufacture thereof
JP2019080211A JP6752926B2 (en) 2015-11-18 2019-04-19 OSB (Oriented Strand Board) wood-based panel with improved properties and its manufacturing method

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10730202B2 (en) * 2015-11-18 2020-08-04 SWISS KRONO Tec AG OSB (oriented strand board) wood material panel having improved properties and method for producing same
WO2022043470A1 (en) 2020-08-26 2022-03-03 Suncoal Industries Gmbh Modified fine particulate carbon materials and method for producing same

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT3178622T (en) * 2015-12-07 2018-10-30 SWISS KRONO Tec AG Method of manufacturing of wood material board with reduced emission of volatile organic compounds (vocs)
PL3395520T3 (en) * 2017-04-25 2020-05-18 SWISS KRONO Tec AG Method for the preparation of osb wood-base panels with reduced emission of volatile organic compounds (vocs)
CN109342489B (en) * 2018-12-07 2023-05-23 黑龙江省能源环境研究院 A local temperature control structure for detecting building materials volatility
DE102019122059A1 (en) * 2019-08-16 2021-02-18 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for the production of a wood molding
CN112428379B (en) * 2020-11-13 2022-04-08 山东唐唐家居有限公司 Multi-layer molded door panel molding device and process thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06155420A (en) * 1992-11-17 1994-06-03 Yamaha Corp Wooden fiber material and production thereof
US5506026A (en) * 1993-05-31 1996-04-09 Yamaha Corporation Wood board and a flooring material made therefrom
US5641819A (en) * 1992-03-06 1997-06-24 Campbell; Craig C. Method and novel composition board products
US20080263890A1 (en) * 2005-04-04 2008-10-30 Edmond-Pierre Picard Wood Heat Treating Method, a Plant for Carrying Out Said Method and Heat Treated Wood
EP2889112A1 (en) * 2013-12-27 2015-07-01 "Latvian State Institute of Wood Chemistry" Derived public person Method for hydrothermal treatment of wood

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60133281U (en) * 1984-02-17 1985-09-05 株式会社 小金井製作所 solenoid valve
DK0695408T3 (en) 1993-05-12 2001-06-18 Valtion Teknillinen Method of improving the resistance of cellulose-containing products to mold and advice
RU2041827C1 (en) * 1993-06-30 1995-08-20 Решетов Вячеслав Александрович Method of making the molding material of wood particles
CN1043019C (en) * 1995-09-14 1999-04-21 南京林业大学 Method for mfg. oriented structure shaving board
US6075076A (en) 1995-12-27 2000-06-13 North American Paper Corporation Composite wood products prepared from solvent extracted wood particulates
US6098679A (en) 1998-03-17 2000-08-08 Noranda Forest Inc. Dimensionally stable oriented strand board (OSB) and method for making the same
NO324222B1 (en) * 2003-03-11 2007-09-10 Aibel Gas Technology As System and method for checking gas emissions from an oil storage tank
DE102004011931B4 (en) * 2004-03-11 2006-09-14 Kronotec Ag Insulation board made of a wood-material-binder fiber mixture
DE102004062649C5 (en) 2004-12-21 2013-06-06 Kronotec Ag Process for the production of a wood fiber insulation board or mats and wood fiber insulation boards or mats produced by this process
CN2777916Y (en) * 2004-12-30 2006-05-03 深圳富泰宏精密工业有限公司 Cover spacing structure
KR100970112B1 (en) 2006-09-26 2010-07-15 (주)엘지하우시스 Wood flooring with carbonized solid wood using symmetric structure and process for preparing the same
BE1017821A5 (en) * 2007-10-19 2009-08-04 Flooring Ind Ltd Sarl PLATE, METHODS FOR MANUFACTURING PLATES AND PANEL THAT CONTAINS SUCH PLATE MATERIAL.
CN101181789B (en) * 2007-12-07 2012-09-05 上海星嘉诺华材料科技有限公司 Wood-plastic profiles and manufacturing method therefor
SE532746C2 (en) * 2008-06-11 2010-03-30 Bio Energy Dev North Ab Process and apparatus for the production of dry-refined lignocellulosic material
CN101307240A (en) * 2008-06-16 2008-11-19 南京林业大学 Decatizing and charring process of cotton wood
DE102009023643B4 (en) * 2009-05-28 2016-08-18 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Wood-based product and process for its preparation
CN101637928A (en) * 2009-08-13 2010-02-03 嘉汉林业(广州)有限公司 Single-veneer composite decoration board
SG183181A1 (en) * 2010-02-04 2012-09-27 Titan Wood Ltd Process for the acetylation of wood elements
CN102398288B (en) * 2010-09-17 2014-04-23 李和麟 Method for manufacturing laminated veneer lumber by using wood
CN102407553A (en) * 2010-09-21 2012-04-11 大亚科技股份有限公司 Manufacturing method of high density fiberboard for whitened type E1 grade floor substrate
EP2447332B1 (en) 2010-10-27 2014-01-22 Kronotec AG Hybrid adhesive and use of same in wooden boards
JP5165044B2 (en) * 2010-10-29 2013-03-21 ニチハ株式会社 Wood fiber board and manufacturing method thereof
HUE026093T2 (en) 2011-04-20 2016-05-30 John Griem Method of manufacturing a fireproof board from strands of wood
FI20115570L (en) * 2011-06-09 2012-12-10 Ekolite Oy Process for the manufacture of natural fiber composite materials, products obtained and processes for application thereof
PL2615126T3 (en) 2012-01-16 2014-01-31 SWISS KRONO Tec AG Use of modified nanoparticles in wood materials for reducing the emission of volatile organic compounds (VOCs)
JP5965670B2 (en) * 2012-03-01 2016-08-10 国立研究開発法人森林総合研究所 Process for producing heat-treated wood
FR2989016A1 (en) * 2012-04-06 2013-10-11 Dumoulin Bois Method for printing relief pattern on face of wood plate or wooden derivate panel to manufacture e.g. terrace floor, involves compressing die on solid wood or wood derivative panel at cold by using press, and printing pattern on panel face
CN102837347B (en) * 2012-09-24 2015-05-27 中南林业科技大学 Poplar structural engineering material and manufacture method thereof
CN202866235U (en) * 2012-10-10 2013-04-10 徐州加林木业有限公司 Carbonized woodiness artificial board composite floor
CN102873720A (en) 2012-10-10 2013-01-16 徐州加林木业有限公司 Carbonized wood board and production method and application thereof
EP2765178A1 (en) 2013-02-07 2014-08-13 Arbaflame Technology AS Method of producing carbon-enriched biomass material
CN104511955A (en) * 2013-09-27 2015-04-15 青岛市首胜实业有限公司 Processing method of solid wood floor
CN104626292B (en) * 2015-02-06 2016-04-06 寿光市鲁丽木业股份有限公司 One can facing oriented wood chipboard and preparation technology thereof
ES2660426T3 (en) * 2015-11-18 2018-03-22 SWISS KRONO Tec AG OSB wood-oriented material board (oriented strand board) with improved properties and production process
PT3178622T (en) * 2015-12-07 2018-10-30 SWISS KRONO Tec AG Method of manufacturing of wood material board with reduced emission of volatile organic compounds (vocs)

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5641819A (en) * 1992-03-06 1997-06-24 Campbell; Craig C. Method and novel composition board products
JPH06155420A (en) * 1992-11-17 1994-06-03 Yamaha Corp Wooden fiber material and production thereof
US5506026A (en) * 1993-05-31 1996-04-09 Yamaha Corporation Wood board and a flooring material made therefrom
US20080263890A1 (en) * 2005-04-04 2008-10-30 Edmond-Pierre Picard Wood Heat Treating Method, a Plant for Carrying Out Said Method and Heat Treated Wood
EP2889112A1 (en) * 2013-12-27 2015-07-01 "Latvian State Institute of Wood Chemistry" Derived public person Method for hydrothermal treatment of wood

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10730202B2 (en) * 2015-11-18 2020-08-04 SWISS KRONO Tec AG OSB (oriented strand board) wood material panel having improved properties and method for producing same
WO2022043470A1 (en) 2020-08-26 2022-03-03 Suncoal Industries Gmbh Modified fine particulate carbon materials and method for producing same

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