EP3166994A1 - Procédé de revêtement de substrats en plastique - Google Patents

Procédé de revêtement de substrats en plastique

Info

Publication number
EP3166994A1
EP3166994A1 EP15725304.8A EP15725304A EP3166994A1 EP 3166994 A1 EP3166994 A1 EP 3166994A1 EP 15725304 A EP15725304 A EP 15725304A EP 3166994 A1 EP3166994 A1 EP 3166994A1
Authority
EP
European Patent Office
Prior art keywords
coating
compound
coating agent
carbene
application
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15725304.8A
Other languages
German (de)
English (en)
Inventor
Audree Andersen
Bjoern Heinz
Christina HAAF-KLEINHUBBERT
Bastian Marten Noller
Helen Brannon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Coatings GmbH
Original Assignee
BASF Coatings GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Coatings GmbH filed Critical BASF Coatings GmbH
Publication of EP3166994A1 publication Critical patent/EP3166994A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B05D3/101—Pretreatment of polymeric substrate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B05D7/26—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials synthetic lacquers or varnishes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/532—Base coat plus clear coat type the two layers being cured or baked together, i.e. wet on wet
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene

Definitions

  • the present invention relates to a process for coating plastic substrates with an aqueous coating agent.
  • the method can be used, for example, in the field of vehicle painting, for example in the painting of vehicle parts and accessories.
  • Plastics have prevailed in the context of vehicle painting as materials for vehicle parts as well as vehicle mounting and accessory parts both indoors and outdoors. Plastics as well as other materials for decorative reasons (for example, coloring) and / or due to technical expediency (for example, light and weather resistance) coated with appropriate coating or painted.
  • An important prerequisite for a high-quality coating is the adhesion to the substrate, that is to the substrate surface. It is generally known that especially in the coating or coating of plastics, in particular of non-polar plastics, such as polypropylene (PP) in pure form or in modified form (for example by adding ethylene-propylene-diene copolymers (EPDM)), sometimes serious adhesion problems to the plastic substrate may occur.
  • PP polypropylene
  • EPDM ethylene-propylene-diene copolymers
  • the adhesion problems are especially reinforced in the coating of non-polar plastic substrates due to the polarity differences of the two media, the plastic substrate and the coating agent again.
  • non-polar plastics are conventionally subjected to a surface-activating pretreatment.
  • the most commonly used methods are flaming, plasma treatment and corona discharge.
  • adhesion-promoting substances in particular chlorinated polyolefins, to improve adhesion.
  • the adhesion-promoting substances are used, for example, via adhesion primers which contain the adhesion-promoting substances and are applied to the plastic substrate in a separate coating process. Also possible is the direct addition of adhesion-promoting substances to the coating agent with which the decorative and / or technically expedient coating is to be produced.
  • chlorinated polyolefins to improve the adhesion properties may also lead to acceptable adhesion properties, but is unacceptable from an environmental point of view.
  • the patent application DE 199 61 983 A1 discloses a process for coating in particular non-polar plastics with water-based adhesion-promoting coating compositions, the coatings obtained by the process having good adhesion.
  • the plastic substrate must be cleaned with at least one specific organic solvent before application of the coating agent.
  • the coating agent additionally contains at least one adhesion promoter, in particular a chlorinated polyolefin.
  • WO 2013/064506 A1 describes a method for coating plastic substrates with an aqueous coating agent, by means of which a Excellent adhesion is achieved.
  • the process requires a very complex, combined pretreatment of annealing the plastic substrate and subsequent flame treatment.
  • such a method has certain disadvantages, especially in the field of industrial vehicle painting.
  • the additional complex pretreatment and / or the use of chlorinated polyolefins can offer, the possibility should be given in the context of the present invention to be able to do without it.
  • the object is achieved by a method for coating plastic substrates with an aqueous coating agent (A) containing at least one organic polymer as binder, wherein the coating agent is applied to at least one surface (O) of the plastic substrate and then cured, characterized in that
  • an aqueous coating agent (A) containing at least one organic polymer is used as binder.
  • the coating agent known to the person skilled in the art can be used.
  • the coating agent contains at least one organic polymer as binder.
  • These organic polymers are, for example, the polyurethane, polyester and / or epoxy resins known to those skilled in the art. Also possible is the use of polyacrylate and polymethacrylate resins known per se (hereinafter referred to as poly (meth) acrylate resins).
  • the said organic polymers as binders preferably additionally contain different functional groups for chemical crosslinking, hydroxy groups being preferred.
  • Polyurethane, polyester and / or poly (meth) acrylate resins which preferably contain hydroxyl groups, are preferably used as binders.
  • Such organic polymers or resins are described, for example, in the Rompp Lexikon Lacke and Druckmaschine, Georg Thieme Verlag, Stuttgart, New York, 1998, pages 73 to 74.
  • the dispersibility of the organic polymers or resins in water can be carried out by means of the measures familiar to the person skilled in the art. This may be the ionic modification of the organic polymers by introduction of monomers, for example Carboxylate or sulfonate groups act. Also possible is the nonionic modification by, for example, polyglycol ether chains or the use of certain additives described below, such as dispersants, for example emulsifiers.
  • fully etherified and / or partially etherified aminoplast resins for example, in addition to the abovementioned resin systems, additionally fully etherified and / or partially etherified aminoplast resins, monomeric and / or polymeric polyamines, and monomeric and / or polymeric blocked and / or free polyisocyanates are present in the aqueous coating composition as crosslinker.
  • fully etherified and / or partially etherified amino resins particularly preferably fully etherified and / or partially etherified melamine-formaldehyde resins, are preferably used.
  • suitable organic polymers and monomers for example of suitable polyurethane, polyester, poly (meth) acrylate and / or epoxy resins having suitable functional groups, preferably hydroxy groups, and optionally amino resins, polyamines and / or polyisocyanates is carried out as appropriate the desired and / or required properties of the coating system to be produced.
  • Another selection criterion are the desired and / or required curing conditions, in particular the curing temperatures. How to make such a selection is known to those skilled in the art and may be adapted accordingly.
  • Possible components are the per se known one-component as well as two-component coating systems (cf. also Rompp-Lexikon Lacke und Druckmaschine, Georg Thieme Verlag, Stuttgart, New York, 1998, pages 274-276, and pages 641-642).
  • one-component systems are used.
  • the proportion of a separately considered resin as a binder and a crosslinker is advantageously not less than 3 wt .-%, based on the total amount of the aqueous coating composition.
  • the aqueous coating agent (A) may contain at least one conventional and known coloring and / or effect pigment.
  • the coating composition contains at least one pigment.
  • pigments are inorganic-based pigments, such as, for example, titanium dioxide, iron oxide and carbon black, or else customary metal pigments (for example commercial aluminum bronzes, high-grade steel bronzes) and non-metallic effect pigments (for example pearlescent or interference pigments).
  • organic-based coloring pigments such as azo pigments and phthalocyanine pigments can be used.
  • the proportion of pigments in the coating composition is, for example, in the range from 0 to 20% by weight, preferably from 2 to 15% by weight, in each case based on the total amount of the aqueous coating composition.
  • the aqueous coating compositions (A) may also contain organic solvents in addition to water.
  • organic solvents May include, for example, aliphatic and / or aromatic hydrocarbons such as toluene, xylene, solvent naphtha, Solvesso 100, Shellsol A, ketones such as acetone, methyl ethyl ketone or methyl amyl ketone, esters, such as Ethyl acetate, butyl acetate, pentyl acetate or ethyl ethoxypropionate, ethers such as butyl glycol, dipropylene glycol methyl ether, alcohols such as ethylhexanol, butoxypropanol, isopropanol or butyldiglycol or mixtures of the abovementioned solvents. Water-miscible organic solvents are preferably used.
  • the coating agent (A) to be used is aqueous.
  • Aqueous is a familiar to the expert specification of coating compositions containing not only organic solvents as solvents, but also based on water as a solvent.
  • aqueous means, in particular, that the coating composition contains at least 10% by weight, preferably at least 20, very particularly preferably at least 25% by weight of water, in each case based on the total amount of the coating composition.
  • aqueous that, in addition to the stated requirement, "at least 10% by weight (or at least 20 or 25% by weight) of water, based on the total amount of the coating composition," is to be fulfilled as a further requirement that the proportion organic solvent in the coating composition is less than 25% by weight, in particular less than 20% by weight, in each case based on the total amount of the coating agent.
  • paint additives are, for example, but not exclusively,
  • Catalysts such as acid-containing catalysts based on, for example, substituted phosphonic diesters or substituted phosphoric acid esters,
  • paint additives are available, for example, commercially from different suppliers.
  • the proportion of a particular additive is advantageously less than 10 wt .-%, in particular less than 5 wt .-%, particularly preferably less than 3 wt .-%, each based on the total amount of the aqueous coating composition.
  • the aqueous coating agent is substantially free of chlorinated polyolefins.
  • aqueous coating agent is not more than 5% by weight, in particular not more than 2.5% by weight, particularly preferably not more than 2.0% by weight, very particularly preferably not more than 1.0% by weight, of the respective substance (s), in each case based on the total amount of the coating agent
  • the aqueous coating composition is completely free of chlorinated polyolefins.
  • the coating agent may also contain at least one carbene-forming compound (C) described in more detail below.
  • the coating agent may contain the carbene-forming compound (C) in its original form (compare formula (I)).
  • a compound (C) is covalently linked to another component contained in the coating agent (A) while retaining its carbene-forming ability.
  • This embodiment is expressly included within the scope of the present invention, when it is stated that the coating agent (A) contains the carbene-forming compound (C). This is because the ability to form a carbene is retained and, moreover, the compound (C), although in a linked form, is still present in the coating composition.
  • the reaction of a polyisocyanate used in the coating composition (A) with a hydroxy-functional or amino-functional compound (C) may be mentioned.
  • the linkage is carried out in a manner known per se by forming a urethane or urea function.
  • the proportion is calculated accordingly taking into account the amount of compound (C) used in the reaction.
  • the aqueous coating agent is an aqueous basecoat.
  • a basecoat is known to be a pigment-containing coating agent referred to that can be used in particular in the automotive finishing but also in the general industrial coating for building a coloring coating, in particular a coloring intermediate coating in a multi-layer coating on, for example, a plastic substrate. On the intermediate coating thus constructed, a clear coat is then often built, whereby the classic multi-layer coating is produced.
  • the preparation of the aqueous coating composition, in particular of the aqueous basecoat material has no special features in terms of method, but is carried out by customary and known methods with the aid of customary and known mixing units, such as stirred kettles or dissolvers.
  • the plastic substrates to be coated or to be coated by the method according to the invention are those of conventional plastics such as, for example, polystyrene (PS), polyvinyl chloride (PVC), polyurethane (PUR), glass fiber-reinforced unsaturated polyesters, polymethyl methacrylate (PMMA), polyphenylene sulfide (PPS) , Polyoxymethylene (POM), polyphenylene ether (PPE), polyphenylene oxide (PPO), polyurea, polybutadiene terephthalate (PBT), polycarbonate (PC), acrylonitrile-butadiene-styrene copolymers (ABS), polyolefins such as polypropylene (PP) and polyethylene (PE) optionally modified with ethylene-propylene-diene copolymers (EPDM) and ethylene-propylene-rubber (EPR).
  • PS polystyrene
  • PVC polyvinyl chloride
  • PUR polyurethane
  • the process according to the invention can be used particularly advantageously for coating nonpolar plastics, in particular polyolefins such as PP and PP modified with EPDM components.
  • the modification of PP with EPDM essentially serves to elastify the plastic and determines, among other things, the paintability. At low EPDM levels, the paintability or adhesion is usually poor. Only with EPDM contents of about 20 to 25 wt .-% is no longer in the prior art of hard-to-paint plastics.
  • the process according to the invention can be used particularly advantageously for the coating of polypropylene / EPDM plastics with low EPDM contents of, for example, not higher than 25% by weight, in particular not higher than 10% by weight.
  • plastic substrates are therefore polyolefin plastic substrates.
  • the plastic substrates may be simple plastic sheets. Are possible as substrates but also vehicle bodies made of plastics or certain vehicle parts and vehicle attachment and accessories for both the vehicle interior and the vehicle exterior.
  • the carbene-forming compound (C) which is contained in the coating agent (A) as described above and / or which is applied directly to the surface of the plastic substrate as described below before application of the coating agent has the following formula (I):
  • the compounds (C) are accordingly diazo compounds, more precisely each have a Diazirinoli.
  • a diazirine group is a functional group which can form a carbene by thermolysis or photolysis and corresponding removal of a nitrogen molecule.
  • the compounds (I) in the context of the present invention by definition and for better clarity also referred to as carbene-forming compounds.
  • Activation to carbene formation is therefore By definition, it is understood that such a compound is exposed to conditions which may result in thermal and / or photolysis (ie, thermal energy and / or electromagnetic radiation, such as UV radiation is supplied), with compound (C) reacting to carbene ,
  • the photolytic activation that is the activation by exposure to electromagnetic radiation, in particular UV radiation
  • This form of activation results in a particularly well-adherent coating.
  • the compound (C) has as residue Ri an apparently electron-withdrawing group, for example a CF 3 group (groups with correspondingly negative inductive effect (-I effect)).
  • Suitable radicals Ri are the halogen-containing radicals -CF 3 and -CCI 3 or the halide radicals -F and -Cl.
  • the respective radical Ri is then attached to the carbon atom of the three-membered ring containing the diazirine group.
  • Preferred is wherein Ri to CF 3 or Cl, most preferably CF 3.
  • the compound (C) further has a substituted phenyl radical R 2 , which is also attached to the carbon atom of the three-membered ring containing the diazirine group.
  • the phenyl radical is substituted in the ortho- and / or para-position when viewed from the carbon atom of the phenyl ring to which the diaziridine ring is attached.
  • Substituted means, in accordance with the wording commonly used in this context, which is present in ortho and / or para position on the corresponding carbon atom of the phenyl ring is a non-hydrogen radical (ortho position R 4 , para position R 3 ).
  • Y OH, C0 2 H.
  • They are thus groups that are more polar, in particular by the OH, C0 2 H, NH 2 or Br, than is the case for example with pure alkyl radicals or hydrogen.
  • Y is preferably OH or CO 2 H. For m, preference is given to 0 or 1.
  • the phenyl ring of compound (C) is thus preferably a phenyl ring substituted in para position to the diazirine ring.
  • the method according to the invention for coating comprises firstly applying a carbene-forming compound (C) directly to a surface (O) of the plastic substrate and then activating the compound (C) for carbene formation. Only then is the aqueous coating agent applied to the surface (O) of the plastic substrate and then cured.
  • a component for example a compound (C) or an aqueous coating agent directly to a surface of a substrate is understood as follows.
  • the respective component is applied so that the component after application is disposed on the surface of the substrate and is in direct contact with the surface.
  • no other layer is arranged between the layer formed by the applied component and the surface of the substrate.
  • a component for example a compound (C) or an aqueous coating composition to a substrate (without the specification "direct") is therefore understood as follows:
  • the respective component is applied so that the component after application to the surface of the substrate there is not necessarily direct contact with the surface, for example, others may be interposed between the layer and the surface of the substrate Layers can be arranged.
  • An unspecified application comprises as generic term the direct and the non-direct application.
  • the compound (C) is applied directly to a surface (O) of the plastic substrate and then activated for carbene formation. Assuming that this forms a continuous layer directly on the substrate, this has the immediate result that the coating agent (A), which is applied after the application and activation of the compound (C), no longer directly on the Surface (O) is applied, since a layer is already arranged therebetween.
  • a component to a surface (O) of a substrate is equivalent to the formation of a layer or coating on the surface of the substrate.
  • a coating will usually be continuous, that is cover the entire surface.
  • a coating is not completely continuous, so that not the entire surface of the substrate is covered.
  • Such coatings often result when only comparatively little material is applied. If a layer thickness of a layer is specified in the context of the present invention, the average layer thickness is to be understood hereunder.
  • a compound (C) can be carried out by customary and known methods.
  • a compound (C) in an organic solvent preferably acetone, methyl ethyl ketone, cyclohexane and / or tetrahydrofuran, preferably methyl ethyl ketone, are dissolved and then applied by conventional application methods such as spraying, pouring, dipping, impregnation or trickling.
  • the spray application is preferred.
  • a compound (C) is applied in the form of a solution in an organic solvent.
  • the concentration of the solution may vary Application vary widely and, for example, in the range of 0.001 to 1 mol / l.
  • the solution may, of course, also contain more than one compound (C), in which case the specified concentration range stands for the total concentration of all compounds (C) present.
  • the applied solution of the compound (C) in an organic solvent is then preferably flashed for a period of 1 to 60 minutes at room temperature (ie, 10 to 40 ° C). In this case, at least the majority of the organic solvent evaporates, the compound (C) then being present in finely divided form on the substrate.
  • the carbene-forming compound (C) is activated for carbene formation.
  • activation includes the supply of thermal energy and / or the exposure to electromagnetic radiation, preferably UV radiation.
  • the carbenes formed which are known to be very unstable, for example, react with the surface of the plastic substrate and thereby form a strong link
  • the activation can take place thermally (thermolysis), preference being given to using the compound (C) applied to the surface for a period of from 5 to 120 minutes, preferably from 20 to 60 minutes, at from 60 to 140 ° C.
  • thermolysis 80 to 120 ° C, this can be done in conventional Ovens, such as a convection oven, take place.
  • Ovens such as a convection oven
  • the temperature is chosen in any case so that the selected plastic substrate in the described thermolysis maintains its original shape and does not deform or decompose.
  • the skilled person is in any case, at what temperature which plastic substrate is deformed or from which temperature the softening of the respective material occurs. The corresponding conditions can therefore be easily adapted to the respective individual case.
  • UV radiation is typically in the spectral range of about 100 to 380 nanometers.
  • UV radiation for activation can be known to be generated by the use of typical and commercially available mercury vapor lamps.
  • the emission spectrum of such lamps is known to be a line spectrum with spectral lines in the UV region at about 184, 254, 297, 313, 334 and 365 nanometers.
  • mercury vapor lamps are included in typical UV curing equipment.
  • Corresponding apparatuses are available, for example, from the company IST Strahlentechnik Metz GmbH (Germany), for example the model type M-40-2 * 1 -R-Ir-SLC-So-inert, UV lamp type (mercury-vapor lamp type) M 400 U 2 H.
  • energy emitted during irradiation is in the range of 500 to 3000 mJ per cm 2 of the substrate surface to which the compound (C) has been applied. This is achieved by UV irradiation of the substrates using appropriate equipment for periods of, for example, 0.1 to 10 seconds, especially 1 to 5 seconds.
  • the application of the compound (C) is carried out so that after activation and the associated evaporation of organic solvents on the substrate, a layer with a dry film thickness of for example 0.2 to 5 microns, preferably 0.3 to 3 microns remains.
  • the determination of the dry film thicknesses was carried out in the context of the present invention by magnetic-inductive measurement according to DIN EN ISO 2178.
  • the application of this designed for ferromagnetic substrates measurement method was made possible as follows. In addition to the respective plastic substrate, a metallic substrate was coated simultaneously or in parallel in the same way. The measured layer thicknesses on the metallic substrate were then equated with the layer thicknesses on the plastic substrate.
  • the application of the coating composition (A) as described above takes place on the already coated surface (O) of the substrate.
  • the coating agent (A) is applied directly to the layer obtained after application and activation of the compound (C).
  • the application of the aqueous coating composition can be carried out by all customary application methods, such as, for example, spraying, knife coating, brushing, pouring, dipping, impregnating, trickling or rolling, preferably by spray application.
  • the plastic substrate to be coated can rest as such, wherein the application device or -anläge is moved.
  • the substrate to be coated can also be moved, with the application system resting relative to the substrate or being moved in a suitable manner.
  • spray application methods are used, such as compressed air spraying (pneumatic application), airless spraying, high rotation, electrostatic spray application (ESTA), optionally combined with hot spray application such as hot air hot spraying.
  • the aqueous coating agent applied to the surface (O) of the plastic substrate (or the layer directly obtained by application and activation of a compound (C)) is cured, whereby a cured coating is prepared.
  • the curing of the applied aqueous coating composition has no special features, but is carried out by the usual and known methods such as heating in a convection oven or by irradiation with IR lamps. Also possible is the actinic curing by, for example, UV radiation in radiation-curing systems.
  • the curing conditions depend, for example, on the temperature sensitivity of the plastic substrates used and on the aqueous coating compositions used, for example according to whether the aqueous coating composition used contains self-crosslinking or externally crosslinking binders and optionally crosslinkers.
  • the cure can be in the range of room temperature or even at elevated temperatures in the range of, for example 40 ° C to 120 ° C, preferably from 60 ° C to 100 ° C take place.
  • the duration of the curing phase is chosen individually and is inter alia dependent on the factors already mentioned (for example, choice of the binder and / or the curing temperatures).
  • the curing can take place over a period of 5 minutes to 120 minutes, preferably 10 minutes to 40 minutes.
  • the curing may optionally also precede a venting or predrying phase, for example at room temperature for a period of 1 to 60 minutes.
  • Which curing conditions are to be applied to which substrates and / or coating materials belongs to the general knowledge in the field, so that the conditions can be adapted and selected by the person skilled in the art.
  • the application of the aqueous coating agent is carried out in the usual and known layer thicknesses, for example in wet film layer thicknesses of 10 to 200 micrometers, preferably from 50 to 150 micrometers.
  • the resulting dry film layer thicknesses after curing are then, for example, in the range of 2 to 40 micrometers, in particular 5 to 20 micrometers.
  • the coating agent (A) comprises at least one carbene-forming compound (C).
  • the carbene-forming compound (C) as described above is in any case activated after the application of the coating agent (A) for carbene formation.
  • the curing conditions can be chosen so that also takes place during curing activation. From the above it follows that in this case the curing preferably takes place at temperatures of preferably 60 to 100 ° C over a period of 5 to 120 minutes, since then a thermolytic activation of the carbene-forming compound (C) can result simultaneously.
  • the activation can also be carried out photolytically before, during or after the curing or a combined activation by thermolysis and photolysis take place.
  • the applied coating agent also electromagnetic Radiation, in particular UV radiation, exposes.
  • photolytic activation the preferred conditions already mentioned above for embodiment (i) apply.
  • the coating composition (A) is preferably applied directly to the surface (O) of the plastic substrate.
  • Another object of the present invention is a coated plastic substrate, which is characterized in that it has been coated by the method according to the invention. Further coatings can be produced on the coated plastic substrate as described above.
  • a further coating agent is applied and cured on the coated plastic substrate as described above, or a further cured coating is produced.
  • a clearcoat or a clearcoat is a coating material which, after application and curing, forms a transparent coating (the clearcoat layer) with protective and / or decorative properties.
  • Protective properties are, for example, scratch resistance and weather resistance, in particular UV resistance.
  • As a decorative property for example, to understand a good gloss.
  • the clearcoats to be used it is the clearcoat materials commonly used in the field of plastic coating, the selection and use of which is known in the art (see also Rompp-Lexikon Lacke and printing inks, Georg Thieme Verlag, Stuttgart, New York, 1998, page 325).
  • the general application and curing methods of the further coating composition, in particular of the clearcoat correspond to those described above for the aqueous coating composition.
  • Such a coating which is then to be referred to as a classic multilayer coating, is preferably produced by wet-on-wet coating. This means that the further coating agent, in particular the clearcoat, is applied to the applied aqueous coating agent (A), without the latter being previously cured separately.
  • the clearcoat is preferably applied directly to the layer produced by the coating agent (A).
  • the compound (C) can therefore be activated before, during or after the application of the clearcoat for carbene formation.
  • the application of the further coating agent, in particular of the clearcoat takes place in the customary and known layer thicknesses, for example in wet film layer thicknesses of 50 to 250 micrometers, preferably of 100 to 180 micrometers.
  • the resulting dry film layer thicknesses after curing are then, for example, in the range of 15 to 80 micrometers, in particular 25 to 50 micrometers.
  • coated plastic substrates which have been coated by the process according to the invention are therefore suitable for the aesthetically and technically demanding field of vehicle painting, in particular automobile finishing.
  • coated plastic substrates in particular those with a
  • Multilayer coated plastic substrates may be used as vehicle parts and vehicle mounting and accessory parts for both the interior and exterior of vehicles.
  • the coatings or coating layers produced by the process according to the invention for coating plastic substrates also have excellent adhesion. It also follows from the above that the use of compounds of the formula (I) for improving the adhesion of coatings prepared on plastic substrates and produced by means of aqueous coating compositions is the subject of the present invention. The invention will be explained in more detail with reference to the following examples.
  • plastic substrates each in the form of test plates having a size of 10 ⁇ 10 ⁇ 0.3 cm or 100 ⁇ 100 ⁇ 3 cm, were coated with different aqueous coating compositions.
  • plastic materials PP plates (Daplen TM EE103AE (Borealis)) were used.
  • the aqueous coating agent (A) used for the coating was the aqueous basecoat composed according to Table 1.
  • the basecoat was prepared by combining and intimately mixing the components listed in Table 1 in a dissolver.
  • Table 1 Composition of the aqueous basecoat used
  • Foamstar MF324 (commercial 0.5
  • Viscalex HV 30 (commercial 0.4
  • Tinting paste 1 (10% dispersion of the 10.1
  • Clay paste 2 (50% dispersion of the 0.1
  • Component quantity (in% by weight)
  • Tinuvin 1 130 (commercial UV absorber) 0.9
  • the solution containing the diazirine-containing compound (C) was applied directly to a plastic substrate.
  • the clearcoat (Table 2) was then applied pneumatically and dried for 10 .mu.m The mixture was then cured for a period of 30 minutes at a temperature of 80 ° C.
  • the dry layer thicknesses of the individual layers in the multilayer coating (E1) produced according to the invention were 2 micrometers (layer based on the diazirine-containing compound). 15 microns (basecoat) and 42 microns (clearcoat).
  • the adhesion properties of the coatings produced were investigated by a well-known steam jet test (DIN 55662: 2009-12, 1 min steam irradiation at 60 ° C., pressure 67 bar, vertical distance from the test specimen 10 cm).
  • Table 4 shows the adhesion properties of the coatings produced as a function of the plastic substrates used and their pretreatment.
  • the comparison with the results for the multi-layer coating (V3) also shows the surprising advantage of the method according to the invention, in particular in the coating of non-polar plastic substrates (here PP).
  • the adhesion of the multi-layer coating (V3) is significantly worse than is the case for the very well-adherent multi-layer coatings (E1) and (E2).

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un procédé de revêtement de substrats en plastique avec un agent de revêtement aqueux (A) contenant au moins un polymère organique comme liant, l'agent de revêtement étant appliqué sur au moins une surface (O) du substrat en plastique et étant ensuite durci. Ledit procédé est caractérisé en ce que (i), avant l'application de l'agent de revêtement (A), un composé (C) formant du carbène de la formule (I) avec R1= −(CX2)nX, où X = F ou Cl et n = 0 ou 1, R2= (a) avec R3, R4 indépendamment l'un de l'autre = −H, −(CH2)mY, où Y = OH, CO2H, NH2 ou Br et m = 0 à 4, où R3 = R4 = −H est exclu, est appliqué directement sur la surface (O) et est activé pour la formation du carbène et/ou (ii) l'agent de revêtement (A) contient le composé formant du carbène (C) et celui-ci est activé après l'application de l'agent de revêtement (A) pour la formation du carbène (C). L'invention concerne en outre des revêtements produits grâce à ce procédé ainsi que des substrats en plastique revêtus au moyen de celui-ci.
EP15725304.8A 2014-07-09 2015-05-22 Procédé de revêtement de substrats en plastique Withdrawn EP3166994A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14176258.3A EP2966118A1 (fr) 2014-07-09 2014-07-09 Procédé de revêtement de substrats en plastique
PCT/EP2015/061360 WO2016005094A1 (fr) 2014-07-09 2015-05-22 Procédé de revêtement de substrats en plastique

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EP3166994A1 true EP3166994A1 (fr) 2017-05-17

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US (1) US20170204236A1 (fr)
EP (2) EP2966118A1 (fr)
JP (1) JP2017528306A (fr)
CN (1) CN106471048A (fr)
WO (1) WO2016005094A1 (fr)

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US9899212B2 (en) 2015-04-17 2018-02-20 The University Of Rochester Methods for depositing a monolayer on a substrate
EP3727256B1 (fr) 2017-12-21 2024-02-14 Essity Hygiene and Health Aktiebolag Article absorbant à affaissement réduit et méthode de fabrication dudit article absorbant
CN108795003A (zh) * 2018-06-18 2018-11-13 北京点域科技有限公司 一种可生物降解医用材料的制备方法
CN109162110B (zh) * 2018-09-25 2020-12-08 四川大学 一种基于光敏反应型增塑剂同步内增塑制造聚氯乙烯人造革的方法

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DE19961983A1 (de) 1999-12-22 2001-07-05 Dupont Performance Coatings Verfahren zur Lackierung von Kunststoffsubstraten
CA2420723A1 (fr) * 2000-10-16 2002-04-25 Novartis Ag Procede de revetement de la surface d'un materiau
AU2010339654B2 (en) * 2009-12-21 2014-07-17 Innovative Surface Technologies, Inc. Coating agents and coated articles
CN103906798B (zh) 2011-10-31 2016-08-24 巴斯夫涂料有限公司 涂覆塑料基材的方法
WO2013113117A1 (fr) * 2012-01-30 2013-08-08 The University Of Western Ontario Sels ioniques de phosphonium fluoré liés à des précurseurs de carbène

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JP2017528306A (ja) 2017-09-28
US20170204236A1 (en) 2017-07-20
WO2016005094A1 (fr) 2016-01-14
EP2966118A1 (fr) 2016-01-13
CN106471048A (zh) 2017-03-01

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