EP3157672A4 - Compositions de catalyseur à tamis moléculaire, composites de catalyseur, systèmes, et procédés - Google Patents

Compositions de catalyseur à tamis moléculaire, composites de catalyseur, systèmes, et procédés Download PDF

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Publication number
EP3157672A4
EP3157672A4 EP15809019.1A EP15809019A EP3157672A4 EP 3157672 A4 EP3157672 A4 EP 3157672A4 EP 15809019 A EP15809019 A EP 15809019A EP 3157672 A4 EP3157672 A4 EP 3157672A4
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EP
European Patent Office
Prior art keywords
systems
methods
molecular sieve
catalyst
composites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP15809019.1A
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German (de)
English (en)
Other versions
EP3157672A1 (fr
Inventor
Natalia Trukhan
Ulrich Mueller
Michael Breen
Barbara Slawski
Qi Fu
Jaya L. Mohanan
Martin W. Kraus
Ahmad Moini
Xiaofan Yang
John K. Hochmuth
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BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US14/687,097 external-priority patent/US9889437B2/en
Application filed by BASF Corp filed Critical BASF Corp
Priority claimed from PCT/US2015/036243 external-priority patent/WO2015195809A1/fr
Publication of EP3157672A1 publication Critical patent/EP3157672A1/fr
Publication of EP3157672A4 publication Critical patent/EP3157672A4/fr
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9436Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/104Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2063Lanthanum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2065Cerium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20715Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20723Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/2073Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20746Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20753Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/911NH3-storage component incorporated in the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Processes For Solid Components From Exhaust (AREA)
EP15809019.1A 2014-06-18 2015-06-17 Compositions de catalyseur à tamis moléculaire, composites de catalyseur, systèmes, et procédés Pending EP3157672A4 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201462013847P 2014-06-18 2014-06-18
US201462081243P 2014-11-18 2014-11-18
US14/687,097 US9889437B2 (en) 2015-04-15 2015-04-15 Isomorphously substituted catalyst
PCT/US2015/036243 WO2015195809A1 (fr) 2014-06-18 2015-06-17 Compositions de catalyseur à tamis moléculaire, composites de catalyseur, systèmes, et procédés

Publications (2)

Publication Number Publication Date
EP3157672A1 EP3157672A1 (fr) 2017-04-26
EP3157672A4 true EP3157672A4 (fr) 2018-04-04

Family

ID=54936079

Family Applications (2)

Application Number Title Priority Date Filing Date
EP15808974.8A Pending EP3157671A4 (fr) 2014-06-18 2015-06-17 Compositions catalytiques à tamis moléculaire, composites catalytiques, systèmes et procédés
EP15809019.1A Pending EP3157672A4 (fr) 2014-06-18 2015-06-17 Compositions de catalyseur à tamis moléculaire, composites de catalyseur, systèmes, et procédés

Family Applications Before (1)

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EP15808974.8A Pending EP3157671A4 (fr) 2014-06-18 2015-06-17 Compositions catalytiques à tamis moléculaire, composites catalytiques, systèmes et procédés

Country Status (9)

Country Link
EP (2) EP3157671A4 (fr)
JP (2) JP6615794B2 (fr)
KR (1) KR102436905B1 (fr)
CN (2) CN106660022B (fr)
BR (1) BR112016029733B8 (fr)
CA (1) CA2952437C (fr)
MX (2) MX2016016920A (fr)
RU (1) RU2727801C2 (fr)
WO (1) WO2015195819A1 (fr)

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EP3157671A4 (fr) * 2014-06-18 2018-02-14 BASF Corporation Compositions catalytiques à tamis moléculaire, composites catalytiques, systèmes et procédés
JP6702759B2 (ja) * 2015-03-05 2020-06-03 国立大学法人広島大学 チタンを含有するaei型ゼオライト及びその製造方法
WO2017210812A1 (fr) * 2016-06-06 2017-12-14 Rhodia Operations Zéolite de terre rare et son procédé de préparation
CA3026838A1 (fr) 2016-06-08 2017-12-14 Stefan Maurer Gmelinite a promoteur de cuivre et son utilisation dans la reduction catalytique selective de no x
CA3074818A1 (fr) * 2017-09-07 2019-03-14 Basf Corporation Zeolite a teneur reduite en aluminium extra-charpente
EP3700863B1 (fr) * 2017-10-27 2021-09-29 Chevron U.S.A. Inc. Tamis moléculaire ssz-112, sa synthèse et son utilisation
FR3081340B1 (fr) * 2018-05-24 2020-06-26 IFP Energies Nouvelles Catalyseur comprenant un melange d'une zeolithe de type structural afx et d'une zeolithe de type structural bea et au moins un metal de transition pour la reduction selective de nox
US11219886B2 (en) 2018-05-25 2022-01-11 Basf Se Rare earth element containing aluminum-rich zeolitic material
CN108722477B (zh) * 2018-06-06 2021-01-15 中国科学院过程工程研究所 一种抗碱中毒高效脱硝催化剂及其制备方法和应用
WO2020092111A1 (fr) * 2018-10-31 2020-05-07 Basf Corporation Couche lavis catalytique à alumine ajoutée pour réduction de no x
US11786887B2 (en) 2018-12-06 2023-10-17 Basf Se Aqueous suspension comprising a zeolitic material and a zirconium chelate complex
CN114025877A (zh) * 2019-04-27 2022-02-08 萨德化学制品印度私人有限公司 金属交换沸石的制备方法
US20220331787A1 (en) * 2019-09-25 2022-10-20 Basf Corporation Cu-cha scr catalysts having specific lattice strain and domain size characteristics
CA3163748A1 (fr) * 2019-12-04 2021-06-10 Haldor Topsoe A/S Reaction endothermique d'un gaz d'alimentation chauffe par chauffage par resistance
CN110947415A (zh) * 2019-12-10 2020-04-03 惠州市瑞合环保科技有限公司 选择性还原催化剂及其制备方法
CN110961144A (zh) * 2019-12-14 2020-04-07 中触媒新材料股份有限公司 一种具有cha/lev拓扑结构共生复合分子筛及其制备方法和scr应用
CN115304077B (zh) * 2022-08-10 2024-06-14 浙江浙能技术研究院有限公司 用于选择性催化还原氮氧化物的分子筛及其制法与应用
CN115301281B (zh) * 2022-08-17 2023-05-26 四川大学 抗硫抗水的催化剂及其制备方法和应用

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WO2009141324A1 (fr) * 2008-05-21 2009-11-26 Basf Se Procédé de synthèse directe de zéolithes contenant du cu et dotées d'une structure cha
WO2011084218A2 (fr) * 2009-12-17 2011-07-14 Pq Corporation Chabazite à haute teneur en silice pour la réduction catalytique sélective, ses procédés de préparation et d'utilisation
DE102010055680A1 (de) * 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Umsetzung stickstoffhaltiger Verbindungen
US20130052125A1 (en) * 2011-08-25 2013-02-28 Basf Corporation Molecular Sieve Precursors And Synthesis Of Molecular Sieves

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EP2161070B1 (fr) * 2008-09-04 2013-11-27 Haldor Topsoe A/S Procédé et système de catalyseur pour la réduction de NOx
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WO2014062949A1 (fr) * 2012-10-19 2014-04-24 Basf Corporation Tamis moléculaire à petits pores à cycle à 8 en tant que catalyseur scr à température élevée
EP3157671A4 (fr) * 2014-06-18 2018-02-14 BASF Corporation Compositions catalytiques à tamis moléculaire, composites catalytiques, systèmes et procédés

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Publication number Priority date Publication date Assignee Title
WO2009141324A1 (fr) * 2008-05-21 2009-11-26 Basf Se Procédé de synthèse directe de zéolithes contenant du cu et dotées d'une structure cha
WO2011084218A2 (fr) * 2009-12-17 2011-07-14 Pq Corporation Chabazite à haute teneur en silice pour la réduction catalytique sélective, ses procédés de préparation et d'utilisation
DE102010055680A1 (de) * 2010-12-22 2012-06-28 Süd-Chemie AG Verfahren zur Umsetzung stickstoffhaltiger Verbindungen
US20130052125A1 (en) * 2011-08-25 2013-02-28 Basf Corporation Molecular Sieve Precursors And Synthesis Of Molecular Sieves

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KR20170021835A (ko) 2017-02-28
CN106660022B (zh) 2020-09-22
RU2727801C2 (ru) 2020-07-24
JP6882427B2 (ja) 2021-06-02
JP6615794B2 (ja) 2019-12-04
JP2020037108A (ja) 2020-03-12
BR112016029733B8 (pt) 2022-09-27
JP2017521241A (ja) 2017-08-03
CN106660022A (zh) 2017-05-10
RU2017101429A (ru) 2018-07-18
CA2952437A1 (fr) 2015-12-23
EP3157671A4 (fr) 2018-02-14
EP3157671A1 (fr) 2017-04-26
RU2017101429A3 (fr) 2018-11-09
BR112016029733A2 (pt) 2017-08-22
CA2952437C (fr) 2023-08-29
BR112016029733B1 (pt) 2022-09-06
EP3157672A1 (fr) 2017-04-26
BR112016029733A8 (pt) 2020-10-20
WO2015195819A1 (fr) 2015-12-23
MX2023001935A (es) 2023-03-16
CN106660021A (zh) 2017-05-10
MX2016016920A (es) 2017-10-31
CN106660021B (zh) 2020-09-11
KR102436905B1 (ko) 2022-08-29

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