EP3135751B1 - Waschmittelzusammensetzung, die einen sichtbaren indikator für die desinfektion enthält - Google Patents

Waschmittelzusammensetzung, die einen sichtbaren indikator für die desinfektion enthält Download PDF

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Publication number
EP3135751B1
EP3135751B1 EP16185176.1A EP16185176A EP3135751B1 EP 3135751 B1 EP3135751 B1 EP 3135751B1 EP 16185176 A EP16185176 A EP 16185176A EP 3135751 B1 EP3135751 B1 EP 3135751B1
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EP
European Patent Office
Prior art keywords
detergent composition
composition according
detergent
disinfecting
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP16185176.1A
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English (en)
French (fr)
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EP3135751A1 (de
Inventor
Cécile PONSARD
Hervé DOHOLLOU
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IPC
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments

Definitions

  • One solution is to include a flow indicator, also called an indicator of application, in the composition to find out where the detergent was applied when washing a soil, for example.
  • a flow indicator also called an indicator of application
  • This type of compositions contains, for example, a visual color indicator which shows where the solution has already been applied, which avoids having to pass several times on the same zone to avoid omitting to treat zones. The amount of detergent consumed is thereby reduced.
  • Such detergent solutions are described in the patent application FR 2 948 536 .
  • the solutions described in the application FR 2 948 536 require a control reagent to turn a colored indicator.
  • Such a solution is complicated to implement and also requires the use of a volatile control reagent releasing vapors of ammonia, which can cause nuisance for users.
  • the detergent according to the invention has shown a particularly pronounced disinfecting efficiency in a relatively short time of less than ten minutes, and even in a time less than or equal to 5 minutes, which corresponds to the color change time of the halochromic compound. in the detergent composition when applied to a surface to be treated.
  • the halochromic compound therefore, is not only a passage indicator, it is also a real visual indicator of the action of the detergent which qualifies it as a safety indicator.
  • the composition advantageously comprises a solvent, preferably water.
  • Such a disinfecting mixture has a time of action corresponding substantially to the color change time of the halochromic compound in the detergent composition when applied to a surface to be treated, or it has finished acting before the color of the solution turns.
  • the ammonium chloride is particularly preferably didecyldimethylammonium chloride.
  • the alcohol used is preferably ethanol which imparts a complementary microbial effect to the disinfecting composition according to the invention.
  • the sequestering agent is a complexing agent such as ((2- (biscarboxymethylamino) ethyl) carboxymethylamino) acetic acid, or its tetrasodium salt, also known under the name EDTA (CAS number: 64-02-8).
  • the sequestering agent is methyl glycine diacetate (MGDA) or a chelating agent such as N, N-diacetic acid glutamic acid (GLDA) - CAS No. 51981-21-6 - or a salt thereof .
  • the present invention also relates in another aspect to a use of the detergent composition as described above in the context of the invention, after dilution in water, for the cleaning and disinfection of floors and surfaces and visual inspection of said cleaning and said disinfection.
  • the pH of the solution is 12.7 Last name Quantity in% CAS No. didecyldimethylammonium chloride 0.8 7173-51-5 2-amethanol 3 141-43-5 Ethanol 8 64-17-5 Welded 0.5 1310-73-2 N, N-diacetic glutamic acid 2 51981-21-6 thymolphthalein 0.06 125-20-2 Water qs - -

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Claims (11)

  1. Detergenzzusammensetzung zur Desinfektion und Entfettung von Böden und Oberflächen von Gebäuden, umfassend:
    - ein Ammoniumhalogenid, wobei das Ammonium zwei Alkylketten, die jeweils 1 bis 3 Kohlenstoffatome enthalten, und zwei Alkylketten, die jeweils 7 bis 14 Kohlenstoffatome enthalten, trägt;
    - einen Aminoalkohol;
    - einen Alkohol;
    - eine aus einem Metallhydroxid bestehende Basis;
    - ein Sequestrierungsmittel und
    - eine halochrome Verbindung mit einem Umschlagbereich unterhalb des pH-Werts der Zusammensetzung.
  2. Detergenzzusammensetzung nach Anspruch 1, wobei das Ammoniumhalogenid ein Chlorid ist.
  3. Detergenzzusammensetzung nach Anspruch 2, wobei das Ammoniumchlorid Didecyldimethylammoniumchlorid ist.
  4. Detergenzzusammensetzung nach einem der Ansprüche 1 bis 3, wobei das Metallhydroxid aus den Basen Natronlauge und Kalilauge ausgewählt ist.
  5. Detergenzzusammensetzung nach einem der Ansprüche 1 bis 4, wobei die halochrome Verbindung ein Phthalein ist.
  6. Detergenzzusammensetzung nach Anspruch 5, wobei das Phthalein Thymolphthalein ist.
  7. Detergenzzusammensetzung nach einem der Ansprüche 1 bis 6, wobei der Aminoalkohol 2-Aminoethanol ist.
  8. Detergenzzusammensetzung nach einem der Ansprüche 1 bis 7, wobei der Alkohol Ethanol ist.
  9. Detergenzzusammensetzung nach einem der Ansprüche 1 bis 8, wobei das Sequestrierungsmittel Glutaminsäure-N,N-diessigsäure ist.
  10. Detergenzzusammensetzung nach einem der Ansprüche 1 bis 9, umfassend:
    0,5 bis 1,5% Didecyldimethylammoniumchlorid;
    0,5 bis 5% 2-Aminoethanol;
    5 bis 15% Ethanol;
    0,1 bis 1% Natronlauge;
    0,5 bis 3% Glutaminsäure-N,N-diessigsäure und
    0,01 bis 0,08% Thymolphthalein.
  11. Verwendung der Detergenzzusammensetzung nach einem der Ansprüche 1 bis 10 nach Verdünnen in Wasser zur Reinigung und Desinfektion von Böden und Oberflächen und zur visuellen Kontrolle der Sicherheit der Reinigung und der vorstehend genannten Desinfektion.
EP16185176.1A 2015-08-24 2016-08-22 Waschmittelzusammensetzung, die einen sichtbaren indikator für die desinfektion enthält Active EP3135751B1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1557865A FR3040394B1 (fr) 2015-08-24 2015-08-24 Composition detergente contenant un temoin visuel de desinfection

Publications (2)

Publication Number Publication Date
EP3135751A1 EP3135751A1 (de) 2017-03-01
EP3135751B1 true EP3135751B1 (de) 2017-11-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP16185176.1A Active EP3135751B1 (de) 2015-08-24 2016-08-22 Waschmittelzusammensetzung, die einen sichtbaren indikator für die desinfektion enthält

Country Status (2)

Country Link
EP (1) EP3135751B1 (de)
FR (1) FR3040394B1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3141072A1 (fr) 2022-10-21 2024-04-26 Ipc Produits d’entretien parfumés de rémanence prolongée

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5064635A (en) 1985-05-24 1991-11-12 Irene Casey Cleaner and disinfectant with dye
FR2673640B1 (fr) * 1991-03-07 1994-08-19 Reckitt Colman Nouvelles compositions a usage menager, leur procede de preparation et leurs applications notamment dans le domaine de l'entretien menager.
US5435935A (en) * 1993-11-22 1995-07-25 The Procter & Gamble Company Alkaline liquid hard-surface cleaning composition containing a quarternary ammonium disinfectant and selected dicarboxylate sequestrants
FR2948536B1 (fr) * 2009-07-30 2016-09-23 Bernard Joaniquet Composition desinfectante

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3141072A1 (fr) 2022-10-21 2024-04-26 Ipc Produits d’entretien parfumés de rémanence prolongée

Also Published As

Publication number Publication date
EP3135751A1 (de) 2017-03-01
FR3040394A1 (fr) 2017-03-03
FR3040394B1 (fr) 2018-02-09

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