EP3123913A1 - Feuchttuch und verfahren zur herstellung des feuchttuchs - Google Patents

Feuchttuch und verfahren zur herstellung des feuchttuchs Download PDF

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Publication number
EP3123913A1
EP3123913A1 EP15768546.2A EP15768546A EP3123913A1 EP 3123913 A1 EP3123913 A1 EP 3123913A1 EP 15768546 A EP15768546 A EP 15768546A EP 3123913 A1 EP3123913 A1 EP 3123913A1
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EP
European Patent Office
Prior art keywords
containing layer
fiber
sheet
hydrophobic
fibers
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Granted
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EP15768546.2A
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English (en)
French (fr)
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EP3123913B1 (de
EP3123913A4 (de
Inventor
Takayoshi Konishi
Toshio HIRAOKA
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Unicharm Corp
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Unicharm Corp
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Publication of EP3123913A4 publication Critical patent/EP3123913A4/de
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
    • D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K7/00—Body washing or cleaning implements
    • A47K7/02—Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements
    • A47K7/03—Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements containing soap or other cleaning ingredients, e.g. impregnated
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/24—Towel dispensers, e.g. for piled-up or folded textile towels; Toilet-paper dispensers; Dispensers for piled-up or folded textile towels provided or not with devices for taking-up soiled towels as far as not mechanically driven
    • A47K10/32—Dispensers for paper towels or toilet-paper
    • A47K2010/3266—Wet wipes

Definitions

  • the present disclosure relates to a wet tissue and to a method of producing the wet tissue.
  • wet tissues of the type that can be flushed in toilets have been developed and are commercially available.
  • a wet tissue For flushing in a toilet, a wet tissue must have a prescribed level of wet strength, considering how it is to be used, and a prescribed level of water disintegratability, considering that it is to be flushed in a toilet.
  • wet strength considering how it is to be used
  • water disintegratability considering that it is to be flushed in a toilet.
  • PTL 1 describes a water disintegratable sheet containing a water-soluble polymer (methyl cellulose, hydroxypropyl methyl cellulose or the like) and at least one type of compound containing a benzene nucleus substituted with at least two hydroxyl groups (resorcin, pyrocatechol, pyrogallol, phloroglucinol or the like), and a water disintegratable wet tissue.
  • a water-soluble polymer methyl cellulose, hydroxypropyl methyl cellulose or the like
  • compound containing a benzene nucleus substituted with at least two hydroxyl groups resorcin, pyrocatechol, pyrogallol, phloroglucinol or the like
  • PTL 2 describes a layered nonwoven fabric having at least two different types of nonwoven fabrics, a water disintegratable nonwoven fabric composed of water disintegratable fibers including ionic fibers formed from a resin composition containing a cationic resin (for example, cationized cellulose, cationized starch, cationized guar gum, cationized dextrin or polydimethylmethylenepiperidinium chloride), and an anionic resin (for example, a polyacrylic acid salt, carboxymethyl cellulose, carboxymethyl starch, alginic acid, xanthan gum or a polymethacrylic acid salt), and a staple fiber nonwoven fabric formed from staple fibers, layered in a water disintegratable manner.
  • a cationic resin for example, cationized cellulose, cationized starch, cationized guar gum, cationized dextrin or polydimethylmethylenepiperidinium chloride
  • anionic resin for example, a polyacryl
  • PTL 3 describes a water disintegratable cleaning article comprising a water disintegratable sheet obtained by high-pressure water jet spray treatment of a wet web containing wood pulp, biodegradable synthetic fiber, a water-soluble binder with a carboxyl group and a cationic polymer, which is impregnated with an aqueous cleaning agent containing one or more different metal ions selected from among alkaline earth metals, manganese, zinc, cobalt and nickel, and an organic solvent, the water disintegratable sheet having a multi-ply structure obtained by stacking and embossing of two or more monolayer sheets, the monolayer sheet composing the outermost layer being subjected to high-pressure water jet spray treatment from each surface, and being stacked so that the treated surface is facing outward.
  • a water disintegratable cleaning article comprising a water disintegratable sheet obtained by high-pressure water jet spray treatment of a wet web containing wood pulp, biodegradable synthetic fiber, a water-soluble binder with a
  • PTL 4 describes a water disintegratable sheet employing an anionic adhesive (carboxymethyl cellulose sodium, carrageenan, sodium polyuronate and the like) and a cationic oligomer represented by formula (1) or (2).
  • anionic adhesive carboxymethyl cellulose sodium, carrageenan, sodium polyuronate and the like
  • cationic oligomer represented by formula (1) or (2).
  • PTL 5 describes a water disintegratable fiber sheet including unbeaten pulp (a) with a beating degree of 700 mL or greater, beaten pulp (b) with a beating degree of 400 to 650 mL, regenerated cellulose (c) with a beating degree of 700 mL or greater and refined fibrillated cellulose (d) with a beating degree of 0 to 400 mL.
  • the wet tissues with water disintegratability described in PTL 1 to 4 exhibit both wet strength and water disintegratability by the action of chemical agents. However, considering that a wet tissue is to contact human skin, it is desirable to develop a wet tissue that exhibits both wet strength and water disintegratability without including chemical agents.
  • water disintegratable fiber sheet described in PTL 5 achieves both wet strength and water disintegratability by addition of refined fibrillated cellulose, there is demand for a wet tissue that exhibits both wet strength and water disintegratability by different methods.
  • a wet tissue with water disintegratability including a multilayer sheet comprising a first sheet and a second sheet, wherein the first sheet includes a first hydrophilic fiber-containing layer including hydrophilic fibers at 95 to 100 mass% and a first hydrophobic fiber-containing layer including hydrophobic fibers at 5 to 30 mass%, and the second sheet includes a second hydrophilic fiber-containing layer including hydrophilic fiber at 95 to 100 mass% and a second hydrophobic fiber-containing layer including hydrophobic fiber at 5 to 30 mass%, the first hydrophobic fiber-containing layer being disposed adjacent to the second hydrophobic fiber-containing layer, the multilayer sheet having a plurality of connected sections, disposed across spacings, where the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer are connected, the spacings between the plurality of connected sections being 0.6 times or above the mean fiber length of the hydrophobic fibers of the first hydrophobic fiber-containing layer and 0.6 times or above the mean fiber length of the hydrophobic fiber
  • the wet tissue of the present disclosure exhibits both wet strength and water disintegratability.
  • the mean fiber length of the fibers including the hydrophilic fibers and hydrophobic fibers is the weight-weighted average fiber length, and it is the L(w) value measured using Kajaani fiber Lab fiber properties (off-line)] by Metso Automation.
  • melting point of hydrophobic fibers refers to the peak top temperature for the endothermic peak during conversion from solid to liquid, upon measurement with a differential scanning calorimetry analyzer at a temperature-elevating rate of 10°C/min.
  • the differential scanning calorimetry analyzer used may be, for example, a DSC-60-type DSC measuring apparatus by Shimadzu Corp.
  • the melting point is measured for each component.
  • the machine direction is the machine direction during production
  • the cross-machine direction is the direction perpendicular to the machine direction during production.
  • the spacing of the connected sections is the distance (inner distance) from one inner side to the other inner side between one connected section and the connected section located nearest to that connected section.
  • the spacing I is the inner distance between a connected section 5d and a connected section 5e located nearest to the connected section 5d.
  • the pitch between the connected sections is the center distance between one connected section and the connected section located nearest to that connected section.
  • the pitch P is the center distance between the connected section 5d and the connected section 5e located nearest to the connected section 5d.
  • the wet tissue of the present disclosure includes a multilayer sheet with water disintegratability, comprising a first sheet and a second sheet.
  • wet tissue and multilayer sheet differ in that a "wet tissue” includes a chemical solution while a “multilayer sheet” does not include a chemical solution.
  • the second sheet will sometimes appear to be stacked on the first sheet, but this appearance is not intended to restrict the use of the wet tissue. That is, the surface of the first sheet opposite the second sheet is capable of wiping off dirt, while the surface of the second sheet opposite the first sheet is also capable of wiping off dirt.
  • the first sheet includes a first hydrophilic fiber-containing layer including hydrophilic fibers at 95 to 100 mass% and a first hydrophobic fiber-containing layer including hydrophobic fibers at 5 to 30 mass%
  • the second sheet includes a second hydrophilic fiber-containing layer including hydrophilic fibers at 95 to 100 mass% and a second hydrophobic fiber-containing layer including hydrophobic fibers at 5 to 30 mass%
  • the first hydrophobic fiber-containing layer is disposed adjacent to the second hydrophobic fiber-containing layer
  • the multilayer sheet has a plurality of connected sections, disposed across spacings, that connect the first hydrophobic fiber-containing layer and second hydrophobic fiber-containing layer.
  • Fig. 1 shows a plan view of a wet tissue according to an embodiment of the present disclosure
  • Fig. 2 shows a cross-sectional view along plane II-II of Fig. 1 .
  • the first sheet includes a first hydrophilic fiber-containing layer 2a including hydrophilic fibers (not shown) at 95 to 100 mass% and a first hydrophobic fiber-containing layer 2b including hydrophobic fibers (not shown) at 5 to 30 mass%
  • the second sheet 3 includes a second hydrophilic fiber-containing layer 3a including hydrophilic fibers (not shown) at 95 to 100 mass% and a second hydrophobic fiber-containing layer 3b including hydrophobic fibers (not shown) at 5 to 30 mass%.
  • the first hydrophobic fiber-containing layer 2b is disposed adjacent to the second hydrophobic fiber-containing layer 3b
  • the multilayer sheet 4 has a plurality of connected sections 5 formed by connecting the first hydrophobic fiber-containing layer 2b and second hydrophobic fiber-containing layer 3b.
  • the multilayer sheet 4 has a plurality of embossed sections 5' formed by embossing the first hydrophobic fiber-containing layer 2b and the second hydrophobic fiber-containing layer 3b.
  • the plurality of embossed sections 5' are configured in a zigzag fashion.
  • the connected sections are embossed sections, but the connected sections in the wet tissue of the present disclosure are not limited to being embossed sections.
  • the connected sections are, for example, adhesive sections formed by an adhesive, or pressure-sensitive adhesive sections formed by a pressure-sensitive adhesive.
  • the connected sections may be formed by connecting the surface of the first sheet, and specifically the surface of the first hydrophobic fiber-containing layer that is opposite the first hydrophilic fiber-containing layer, and the surface of the second sheet, and specifically the surface of the second hydrophobic fiber-containing layer that is opposite the second hydrophilic fiber-containing layer, but preferably the connected sections are formed by further connecting the fibers inside either the first hydrophobic fiber-containing layer or the second hydrophobic fiber-containing layer, and more preferably they are formed by further connecting the fibers inside both the first sheet and the second sheet. This is from the viewpoint of the wet strength of the wet tissue.
  • the connected sections are preferably embossed sections.
  • the hydrophobic fibers of the first hydrophobic fiber-containing layer and second hydrophobic fiber-containing layer preferably include heat-fusible fibers, and more preferably they include heat-fusible fibers comprising composite fibers that include a low-melting-point component and a high-melting-point component having a higher melting point than the low-melting-point component (hereunder also referred to as "heat-fusible fibers comprising composite fibers that include a low-melting-point component and a high-melting-point component").
  • the hydrophobic fibers of the first hydrophobic fiber-containing layer are fused with the hydrophobic fibers of the second hydrophobic fiber-containing layer
  • the second hydrophobic fiber-containing layer includes the hydrophilic fibers described below
  • at least some of the (low-melting-point component of the) heat-fusible fibers of the first hydrophobic fiber-containing layer are fused with the hydrophilic fibers of the second hydrophobic fiber-containing layer.
  • the hydrophobic fibers of the second hydrophobic fiber-containing layer are fused with the hydrophobic fibers of the first hydrophobic fiber-containing layer
  • the first hydrophobic fiber-containing layer includes the hydrophilic fibers described below
  • at least some of the (low-melting-point component of the) heat-fusible fibers of the second hydrophobic fiber-containing layer are fused with the hydrophilic fibers of the first hydrophobic fiber-containing layer.
  • the connected sections are adhesive sections
  • the viscosity of the adhesive is reduced so that it seeps into either or both the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer, and preferably the adhesive bonds with the fibers contained in either or both the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer.
  • the connected sections are pressure-sensitive adhesive sections.
  • the connected sections may have connecting of the fibers, such as the hydrophilic fibers, included in the first hydrophilic fiber-containing layer and/or the second hydrophilic fiber-containing layer, but preferably the connected sections are not present on the outermost surface (the use-surface) of the multilayer sheet. This is because the connected sections, or embossed sections, for example, tend to be harder than the nonwoven fabric sections, and when the connected sections are present on the outermost surface (use-surface) of the multilayer sheet, the user will tend to sense a feeling of hardness.
  • wet tissue when wet, will tend to exhibit wet strength that is a combination of the wet strength of the first sheet and the wet strength of the second sheet, and when disintegrated by water, it will tend to exhibit the individual water disintegratability of the first sheet and second sheet.
  • the wet tissue of the present disclosure will tend to exhibit twice the wet strength of the first sheet, and to exhibit the same water disintegratability as the first sheet.
  • the spacing between the plurality of connected sections is 0.6 times or above, preferably 0.7 times or above, more preferably 0.8 times or above, even more preferably 1.0 times or above, yet more preferably 1.5 times or above, and even yet more preferably 2.0 times or above the mean fiber length of the hydrophobic fibers of the first hydrophobic fiber-containing layer.
  • the spacing between the plurality of connected sections is 0.6 times or above, preferably 0.7 times or above, more preferably 0.8 times or above, even more preferably 1.0 times or above, yet more preferably 1.5 times or above, and even yet more preferably 2.0 times or above the mean fiber length of the hydrophobic fibers of the second hydrophobic fiber-containing layer.
  • Fig. 3 is a schematic diagram for illustration of the relationship between the connected section spacings and the fiber length.
  • Fig. 3 is a plan view of region III of Fig. 1 , the second sheet 3 being omitted for ease of explanation.
  • the only hydrophobic fibers of the first hydrophobic fiber-containing layer 2b shown are the hydrophobic fibers 6a, 6b and 6c connected to the connected sections 5a, 5b and 5c.
  • the hydrophobic fibers 6a connected to the connected section 5a will not connect with the adjacent connected section 5b (or 5c) even if they are tangled with the hydrophobic fibers 6b (or 6c) connected to the adjacent connected section 5b (or 5c) at a tangled point 7ab (or 7ac).
  • the adjacent connected sections 5a to 5c are not connected by the hydrophobic fibers 6a to 6c. Therefore, when the wet tissue has been discarded in a flush toilet, the connected sections 5a to 5c easily separate into separate fragments so that the water disintegratability of the wet tissue is less likely to be reduced.
  • the relationship between the spacing between the connected sections and the fiber lengths is the same as for the second hydrophobic fiber-containing layer.
  • the fibers composing the nonwoven fabric In a nonwoven fabric, such as a wet tissue, the fibers composing the nonwoven fabric generally do not exist in a straight linear form, but are tangled with other fibers and meandering. Thus, even when the spacing I between the connected sections 5 is shorter than the mean fiber length of the hydrophobic fibers 6, the connected sections 5a to 5c will often be separable into different fragments when discarded in a flush toilet or the like.
  • the plurality of connected sections must have a spacing of 0.6 times or above the mean fiber length of the hydrophobic fibers in both the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer.
  • the spacing between the plurality of connected sections is preferably 0.6 times or above, more preferably 0.7 times or above, even more preferably 0.8 times or above, yet more preferably 1.0 times or above, even yet more preferably 1.5 times or above, and most preferably 2.0 times or above the mean fiber length of each of the fibers types in the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer.
  • the hydrophilic fibers are connected by hydrogen bonding with the other fibers, and particularly the hydrophilic fibers, the connecting points by hydrogen bonding with the other fibers readily disappear upon disposal in a flush toilet or the like.
  • the mean fiber length of the hydrophilic fibers has less of an effect on the water disintegratability of the wet tissue than the mean fiber length of synthetic fibers, especially when the connected sections are embossed sections.
  • the lower limit for the area ratio of the connected sections with respect to the multilayer sheet will differ depending on the area of the individual connected sections, but it is generally 0.5% or greater, preferably 1.0% or greater, more preferably 1.2% or greater and even more preferably 1.5% or greater. If the area ratio is less than 0.5%, connection between the first sheet and the second sheet will be insufficient, resulting in reduced wet strength of the wet tissue and possible tearing of the wet tissue during use.
  • the upper limit for the area ratio will also differ depending on the area of the individual connected sections and the number density of the connected sections, but it is generally 12% or less, preferably 10.0% or less, more preferably 8.0% or less, and even more preferably 5.0% or less. If the area ratio is greater than 12.0%, connection between the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer will be strong and the wet strength of the wet tissue will be increased, but when the wet tissue has been discarded in a flush toilet, the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer will have difficulty separating, the water disintegratability of the wet tissue may be reduced, and the bending resistance of the wet tissue will tend to increase (the wet tissue will become hard).
  • This upper limit is preferred when the number density of the connected sections is low, such as when the connected sections have a number density of preferably 10 to 1,000/m 2 and more preferably 50 to 500/m 2 .
  • the connected sections are linear connected sections.
  • the upper limit for the area ratio is preferably 5.0% or less, more preferably 4.5% or less, even more preferably 4.0% or less, and yet more preferably 3.8% or less.
  • the connected sections are punctiform connected sections.
  • the area ratio of the connected sections is calculated by the following formula.
  • Area ratio connected sections % 100 ⁇ total area of connected sections , mm 2 / area of multilayer sheet , mm 2
  • the number density of the connected sections is the number of connected sections per 1 m 2 of the multilayer sheet.
  • connected sections are not particularly restricted, and examples of connected sections include punctiform connected sections, for example, connected sections with circular, elliptical, rectangular or triangular shapes, star shapes, heart shapes or any desired character shapes or symbol shapes.
  • the punctiform connected sections may be disposed on the multilayer sheet without any particular restrictions so long as the spacing is within the prescribed relationship with the mean fiber length of the hydrophobic fibers of both the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer, and the punctiform connected sections may be disposed, for example, in an arrangement that is zigzag, such as a square zigzag or 60° zigzag.
  • the connected sections may be linear connected sections, such as straight linear connected sections or non-linear connected sections, such as curved connected sections.
  • Linear connected sections may be arranged, for example, in parallel or non-parallel.
  • each connected section also varies depending on the area ratio of the connected sections, the shapes of the connected sections, and other factors, but when the connected sections are punctiform connected sections, each of the connected sections has an area of preferably 0.4 to 9.0 mm 2 , more preferably 0.4 to 7.0 mm 2 and even more preferably 1.0 to 5.0 mm 2 . If the area is less than 0.4 mm 2 , connection between the first sheet and the second sheet may be insufficient, and if the area is greater than 9.0 mm 2 , the wet strength of the wet tissue will tend to be reduced.
  • the connected sections are embossed sections, and the area is less than 0.4 mm 2 , the protrusions on the embossing roll for formation of the embossed sections will be more acute angles which may open holes in the wet tissue, and when the number of embossed sections is increased to increase the wet strength it will become difficult to ensure the spacing between the embossed sections, while if the area is greater than 9.0 mm 2 , the skin of the user will tend to sense the hardness of the embossed sections.
  • the connected sections When the connected sections are linear connected sections, the connected sections have widths of preferably 0.3 to 3.0 mm, more preferably 0.5 to 2.5 mm and even more preferably 1.0 to 2.0 mm. If the widths are less than 0.3 mm, connection between the first sheet and the second sheet may be insufficient, and the wet strength of the wet tissue may be insufficient. If it exceeds 3.0 mm, the wet strength of the wet tissue will increase but the water disintegratability of the wet tissue will tend to be reduced.
  • the connected sections are embossed sections, and the widths are less than 0.3 mm, the protrusions of the embossing rolls for formation of the embossed sections will be more acute angles, which may potentially open holes in the wet tissue.
  • each of the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer includes a prescribed amount of hydrophilic fibers
  • each of the first hydrophobic fiber-containing layer and second hydrophobic fiber-containing layer includes a prescribed amount of hydrophobic fibers
  • the simple term "fiber” refers to all of the types of fibers in the first sheet, the second sheet, the first hydrophilic fiber-containing layer or second hydrophilic fiber-containing layer, or in the first hydrophobic fiber-containing layer or second hydrophobic fiber-containing layer.
  • Each of the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer includes hydrophilic fibers at 95 to 100 mass%, preferably include hydrophilic fibers at 97 to 100 mass% and more preferably include hydrophilic fibers at 100 mass%. If the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer include hydrophilic fibers in such amounts, the layer will have excellent feel on the skin. Also, when the hydrophobic fibers are heat-fusible fibers and the connected sections are embossed sections, the embossing roll used to form the embossed sections will be less likely to be fouled, while the user will not directly contact the embossed sections so that the user will be less likely to feel the hardness of the embossed sections.
  • Each of the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer includes hydrophobic fibers at 5 to 30 mass%, preferably include hydrophobic fibers at 6 to 25 mass%, and more preferably include hydrophobic fibers at 7 to 20 mass%. If the proportion of hydrophobic fibers is less than 5 mass%, the wet strength of the wet tissue will tend to be reduced, and if the proportion of hydrophobic fibers exceeds 30 mass%, the water disintegratability will tend to be reduced.
  • the hydrophobic fibers are heat-fusible fibers and the connected sections are embossed sections, and the proportion of hydrophobic fibers is less than 5 mass%, the connecting force between the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer by the embossed sections will be reduced and the water disintegratability of the wet tissue will increase, but the wet strength will also be reduced, tending to result in tearing during use, and also tending to reduce the bending resistance (resulting in softness).
  • the hydrophobic fibers are heat-fusible fibers and the connected sections are embossed sections, and the proportion of hydrophobic fibers is greater than 30 mass%, the connecting force between the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer by the embossed sections will be increased and the wet strength of the wet tissue will increase, but the water disintegratability will also tend to be inferior and the bending resistance will tend to increase (result in hardness).
  • Each of the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer preferably further include hydrophilic fibers. This is from the viewpoint of retentivity of chemical solutions.
  • the first hydrophobic fiber-containing layer includes hydrophilic fibers
  • the first hydrophobic fiber-containing layer includes hydrophobic fibers and hydrophilic fibers, respectively, at 5 to 30 mass% and 70 to 95 mass%, preferably 6 to 25 mass% and 75 to 94 mass% and more preferably 7 to 20 mass% and 80 to 93 mass%.
  • the preferred proportion of hydrophobic fibers and hydrophilic fibers in the second hydrophobic fiber-containing layer is as explained above for the first hydrophobic fiber-containing layer.
  • the hydrophilic fibers are not particularly restricted so long as they are fibers with hydrophilicity and capable of retaining water on the surface or in the interiors.
  • the hydrophilic fibers may be cellulosic fibers, examples of cellulosic fibers including pulp and regenerated cellulose fibers.
  • pulp examples include wood pulp and nonwood pulp.
  • wood pulp examples include conifer pulp and broadleaf tree pulp.
  • nonwood pulp examples include straw pulp, bagasse pulp, reed pulp, kenaf pulp, mulberry pulp, bamboo pulp, hemp pulp and cotton pulp (such as cotton linter).
  • the pulp may be non-beaten pulp that has not been subjected to beating treatment, beaten pulp that has been subjected to beating treatment, or a combination thereof.
  • Non-beaten pulp preferably has a Canadian Standard Freeness of 700 mL or greater.
  • CSF Canadian Standard Freeness
  • the mean fiber length of the non-beaten pulp is not particularly restricted but is generally preferred to be 2 to 4 mm from the viewpoint of economy and productivity.
  • Beaten pulp is pulp obtained by beating non-beaten pulp by a method, such as free beating or wet beating, and it has main body sections and microfiber sections extending from the main body sections. If the wet tissue includes beaten pulp, the wet strength and dry strength of the wet tissue will be increased.
  • the beaten pulp preferably has a Canadian Standard Freeness of 400 to 650 mL, and more preferably it has a Canadian Standard Freeness of 400 to 600 mL.
  • the regenerated cellulose fibers may be a rayon, such as viscose rayon obtained from viscose, polynosic and modal, or cuprammonium rayon obtained from cuprammonium salt solutions of cellulose, (also known as "cupra”); or lyocell, such as Tencel R , which are not via cellulose derivatives, obtained by organic solvent spinning methods using organic solvents that are mixed solutions of organic compounds and water.
  • rayon such as viscose rayon obtained from viscose, polynosic and modal, or cuprammonium rayon obtained from cuprammonium salt solutions of cellulose, (also known as "cupra"); or lyocell, such as Tencel R , which are not via cellulose derivatives, obtained by organic solvent spinning methods using organic solvents that are mixed solutions of organic compounds and water.
  • the regenerated cellulose fibers are preferably rayon and especially viscose rayon, from the viewpoint of water absorption, ease of forming the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer, and economy.
  • the cellulosic fibers may be, for example, semi-synthetic cellulose fibers, such as acetate fibers, among which triacetate fibers and diacetate fibers may be mentioned.
  • the hydrophobic fibers may be ones commonly used in the technical field, and are preferably synthetic fibers.
  • the synthetic fibers may be ones containing only a single component, such as simple fibers, or ones containing multiple components, such as composite fibers.
  • the components include polyolefin-based polymers, such as polyethylene and polypropylene; polyester-based polymers, for example, terephthalate-based polymers, such as polyethylene terephthalate (PET), polybutylene terephthalate and polypentylene terephthalate; polyamide-based polymers, such as nylon 6 and nylon 6,6; acrylic polymers; polyacrylonitrile-based polymers; and their modified forms.
  • PET polyethylene terephthalate
  • polybutylene terephthalate and polypentylene terephthalate polyamide-based polymers, such as nylon 6 and nylon 6,6
  • acrylic polymers polyacrylonitrile-based polymers
  • polyacrylonitrile-based polymers and their modified forms.
  • the hydrophobic fibers preferably include heat-fusible fibers, and more preferably they include heat-fusible fibers comprising composite fibers that include a low-melting-point component and a high-melting-point component having a higher melting point than the low-melting-point component.
  • the low-melting-point component has a melting point of preferably 120 to 180°C, more preferably 130 to 170°C and even more preferably 140 to 160°C. If the melting point is lower than 120°C, the drying temperature of the first sheet and/or second sheet will need to be lowered to below the melting point of the low-melting-point component in order to prevent fusion of the low-melting-point component, and the productivity of the wet tissue will tend to be reduced.
  • the high-melting-point component has a melting point of preferably 170 to 300°C, more preferably 180 to 290°C, even more preferably 200 to 270°C and yet more preferably 220 to 260°C. If the melting point is lower than 170°C, not only the low-melting-point component but also the high-melting-point component will undergo melting during the embossing step, and the embossed sections will become hard, sometimes lowering the feel of the wet tissue on the skin.
  • the melting point is preferably not higher than 300°C from the viewpoint of economy.
  • the low-melting-point component and high-melting-point component have a difference in melting point of preferably 50 to 110°C, more preferably 60 to 100°C and even more preferably 70 to 90°C. If the difference in melting point is less than 50°C, it will tend to be difficult to melt only the low-melting-point component in the embossing step, while if the difference in melting point is greater than 110°C, the melting point of the low-melting-point component will be lower, often resulting in melting of the low-melting-point component during drying of the first sheet and/or second sheet, or the melting point of the high-melting-point component will be high, which is undesirable in terms of economy.
  • the low-melting-point component and high-melting-point component are not particularly restricted, and may be selected from among the polymers listed for the hydrophobic synthetic fibers.
  • the low-melting-point component is preferably a terephthalate-based polymer with a lower melting point than PET, and the high-melting-point component is preferably PET.
  • the composite fibers may be, for example, core-sheath type, core-sheath eccentric type or side-by-side type fibers.
  • each of the first sheet and second sheet separated from the multilayer sheet exhibits, in a disintegration test as an indicator of water disintegratability, a disintegratability of 100 seconds or less, and preferably exhibits a disintegratability of 90 seconds or less, more preferably 80 seconds or less, and even more preferably 70 seconds or less. If the disintegratability exceeds 100 seconds, toilet pipes etc. may become clogged, depending on their thickness. There is no particular lower limit on the disintegratability.
  • toilet paper should satisfy the standard of a disintegratability of no more than 100 seconds, and considering that the wet tissue of the present disclosure is to be discarded in a flush toilet, it preferably has disintegratability equivalent to that of toilet paper.
  • the water disintegratability of the first sheet and second sheet separated from the multilayer sheet is used because when the wet tissue is discarded in a flush toilet, usually the water stream strips off the first sheet and second sheet at a relatively early stage, followed by the fragments.
  • the multilayer sheet is obtained by drying of the wet tissue for 24 hours under conditions of 20 ⁇ 5°C, 65 ⁇ 5% RH, and vaporizing off the chemical solution from the wet tissue.
  • the wet tissue of the present disclosure preferably also has a disintegratability of 100 seconds or less in a disintegration test for the wet tissue itself, assuming that the first sheet and second sheet will not separate when discarded in a flush toilet, such as when the water stream is weak.
  • the disintegration test is conducted according to "4.5 Disintegratability" for toilet paper of JIS P 4501:1993. Specifically, it is as follows.
  • a 300 mL beaker containing 300 mL of water (water temperature: 20°C ⁇ 5°C) is placed in a magnetic stirrer, and the rotational speed of the rotor (discoid rotor with diameter: 35 mm, thickness: 12 mm) is adjusted to 600 ⁇ 10 rpm.
  • a test strip with 114 ⁇ 2 mm sides is loaded into a beaker, and a stopwatch is activated.
  • the rotational speed of the rotor first falls to about 500 rpm due to the resistance of the test strip, the rotational speed increasing as the test strip becomes loose, and upon recovering to 540 rpm, the stopwatch is stopped and the time is measured in second units.
  • the results of disintegratability are expressed as a mean value for 5 tests.
  • the wet tissue of the present disclosure before impregnation of the chemical solution, i.e. the multilayer sheet, has a bending resistance of 150 mm or less, preferably a bending resistance of 145 mm or less, and more preferably 140 mm or less, and more preferably it has a bending resistance of preferably 135 mm or less. If the bending resistance is greater than 150 mm, the user will tend to feel hardness in the wet tissue. There is no particular lower limit for the bending resistance, but it will generally be 20 mm or above.
  • the bending resistance is measured according to "6.7.3 41.5 Cantilever method" of the general test methods for nonwoven fabrics of JIS L 1913:2010, except that the length of the test strip was changed from “(25 ⁇ 1) mm x (250 ⁇ 1) mm” to "(25 ⁇ 1) mm x (200 ⁇ 1) mm”.
  • the bending resistance is preferably within the range specified above in any direction of the multilayer sheet, for example, in both the longitudinal and widthwise directions according to the aforementioned JIS standard, such as in both the machine direction and the cross-machine direction during production of the first sheet and the second sheet.
  • the wet tissue of the present disclosure has a tensile strength of 1.0N or greater and preferably 1.1 N or greater per 25 mm width. If the tensile strength is lower than 1.0N per 25 mm width, the wet tissue can potentially tear when the wet tissue is removed.
  • the tensile strength of the wet tissue may be referred to as the "wet strength" of the wet tissue, and the units of the tensile strength per 25 mm width of the wet tissue may be expressed as "N/25 mm”.
  • the tensile strength is preferably within the range specified above in any direction of the wet tissue, such as in both the machine direction and the cross-machine direction during production of the first sheet and second sheet.
  • the tensile strength is measured according to "7.1 General method" of the Wet Tensile Strength Test Methods for Paper or Boards" of JIS P 8135:1998, except for the difference specified below.
  • a multilayer sheet is cut to 25 mm width x 150 mm length to prepare a sample, which is immersed in distilled water with a mass ratio of 250 mass%, after which the sample is set on a wire mesh for 1 minute.
  • the sample is set in a Tensilon tensile tester with a chuck spacing of 100 mm, and the sample is subjected to a tensile test at a pull rate of 100 mm/min, measuring the tensile strength (N) when the sample is torn.
  • the multilayer sheet is obtained by drying of the wet tissue for 24 hours under conditions of 20 ⁇ 5°C, 65 ⁇ 5% RH, and vaporizing off the chemical solution from the wet tissue.
  • the fiber density of the first hydrophobic fiber-containing layer is preferably higher than the fiber density of the first hydrophilic fiber-containing layer
  • the fiber density of the second hydrophobic fiber-containing layer is preferably higher than the fiber density of the second hydrophilic fiber-containing layer.
  • the fiber density is calculated by dividing the basis weight of each layer (the first hydrophobic fiber-containing layer, second hydrophobic fiber-containing layer, first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer) by the thickness of each layer, and is compared.
  • the basis weight is calculated by dividing the mass of each layer that has been separated, by the area.
  • the thickness is measured by immersing the first sheet (or second sheet) in liquid nitrogen and folding it in two, and observing the cross-section with a microscope.
  • the mean fiber length of the fibers in the first sheet and second sheet is not particularly restricted so long as it satisfies the aforementioned conditions with the spacing of the connected sections formed in the multilayer sheet, but the mean fiber length of the hydrophobic fibers and the mean fiber length of the hydrophilic fibers are preferably 6.5 mm or less, more preferably 6.0 mm or less, and even more preferably 5.5 mm or less. If the mean fiber length is greater than 6.5 mm, the absolute number of tangled points between the fibers in the first sheet and second sheet will increase, tending to lower the water disintegratability.
  • the absolute number of tangled points between the fibers will increase, thereby tending to lower the water disintegratability and increase the wet strength.
  • each of the fibers in the first sheet and second sheet for example, the hydrophobic fibers and hydrophilic fibers, and preferably the hydrophilic fibers other than pulp, has a mean fiber length of preferably 2.0 mm or greater, more preferably 2.5 mm or greater and even more preferably 3.0 mm or greater. If the mean fiber length is smaller than 2.0 mm, the wet strength of the first sheet and second sheet will be reduced, and the wet tissue may tear during use.
  • the multilayer sheet of the present disclosure when containing no chemical solution, has a basis weight of preferably 30 to 90 g/m 2 , more preferably 40 to 80 g/m 2 , even more preferably 50 to 70 g/m 2 and yet more preferably 55 to 65 g/m 2 . If the basis weight is lower than 30 g/m 2 , the wet tissue may tear when the wet tissue is removed, and when the basis weight is greater than 90 g/m 2 , the user may feel hardness when using the wet tissue.
  • each of the first sheet and the second sheet when containing no chemical solution, has a basis weight of preferably 15 to 45 g/m 2 , more preferably 20 to 40 g/m 2 , even more preferably 25 to 35 g/m 2 and yet more preferably 27 to 33 g/m 2 . If the basis weight is lower than 15 g/m 2 , the water disintegratability will improve but the wet strength will tend to be reduced, and the bending resistance will tend to be lower. If the basis weight is higher than 45 g/m 2 , the wet strength will increase but the water disintegratability will tend to be reduced and the bending resistance will tend to be higher.
  • the multilayer sheet has a thickness of preferably 0.10 to 0.70 mm, more preferably 0.12 to 0.60 mm, even more preferably 0.14 to 0.50 mm and yet more preferably 0.16 to 0.40 mm. If the thickness is less than 0.10 mm, the water disintegratability of the wet tissue will improve but the wet strength will tend to be reduced, and the bending resistance will tend to be lower. If the thickness is greater than 0.70 mm, the wet strength of the wet tissue will increase but the water disintegratability will tend to be reduced, and the bending resistance will tend to be higher.
  • the thickness of the multilayer sheet is the thickness in the region of the multilayer sheet where the connected sections are not present.
  • each of the first sheet and second sheet has, in the dry state, a thickness of preferably 0.05 to 0.35 mm, more preferably 0.06 to 0.30 mm, even more preferably 0.07 to 0.25 mm and yet more preferably 0.08 to 0.20 mm. If the thickness is less than 0.05 mm, the water disintegratability of the wet tissue will increase but the wet strength will tend to be reduced, and the bending resistance will tend to be lower. If the thickness is greater than 0.35 mm, the wet strength of the wet tissue will increase but the water disintegratability will tend to be reduced, and the bending resistance will tend to be higher.
  • the thickness of the first sheet and the second sheet is their thickness in the region where the connected sections are not present.
  • the multilayer sheet is obtained by drying of the wet tissue for 24 hours under conditions of 20 ⁇ 5°C, 65 ⁇ 5% RH, and vaporizing off the chemical solution. Also, the first sheet and second sheet are obtained by detaching the first sheet and second sheet from the multilayer sheet.
  • the thicknesses of the first sheet and second sheet, and of the multilayer sheet are measured using an FS-60DS by Daiei Kagaku Seiki Mfg. Co., Ltd., under the conditions, probe: 15 cm 2 , measuring load: 3 gf/cm 2 .
  • the first hydrophilic fiber-containing layer and the second hydrophilic fiber-containing layer are disposed on the surface layer of a multilayer sheet, the multilayer sheet having a ridge-furrow structure formed by spraying a high-pressure water jet onto one or both surfaces of the multilayer sheet.
  • Fig. 4 is a diagram illustrating such an embodiment, corresponding to a cross-sectional view along plane II-II of Fig. 1 .
  • the first hydrophilic fiber-containing layer 2a and second hydrophilic fiber-containing layer 3a are disposed on the surface layer of the multilayer sheet 4, and the multilayer sheet 4 has a ridge-furrow structure including a plurality of ridges 8 and a plurality of furrows 9 formed by spraying a high-pressure water jet on both surfaces of the multilayer sheet 4, and specifically the surface 10' and surface 10".
  • the wet tissue has a ridge-furrow structure as shown in Fig. 4 , the dirt removal property will be improved on both surfaces of the wet tissue.
  • a wet tissue according to yet another embodiment of the present disclosure has a fold structure formed by crepe treatment of the first sheet and/or second sheet.
  • chemical solutions with which the multilayer sheet may be impregnated include those used as chemical solutions for wet tissues in the technical field, and are not particularly restricted, with examples including aqueous solutions containing antimicrobial agents, detergents, antiseptic agents and the like, and the chemical solution may even be distilled water.
  • the method of producing the wet tissue of the present disclosure includes the following steps.
  • step (1) to step (3) The steps of (1) to (3) above will also be referred to as step (1) to step (3), respectively.
  • Step (1) can be further divided into the following steps.
  • step (1 a) to (1e) above will also be referred to as step (1 a) to step (1e), respectively.
  • Step (2) can be further divided into the following steps.
  • step (2a) to (2e) above will also be referred to as step (2a) to step (2e), respectively.
  • step (1a) and step (2a) following a method known in the technical field, the aqueous dispersion of starting material for each of the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer is supplied onto the support, forming the respective webs of the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer on the support.
  • step (1 b) and step (2b) the web of each of the first hydrophilic fiber-containing layer and the web of the second hydrophilic fiber-containing layer is sprayed with a high-pressure water jet discharged from a high-pressure water jet nozzle, to form the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer.
  • the web of the first hydrophilic fiber-containing layer and the web of the second hydrophilic fiber-containing layer are subjected to energy of preferably 0.03 to 0.25 kW/m 2 , more preferably 0.04 to 0.20 kW/m 2 , even more preferably 0.05 to 0.15 kW/m 2 , yet more preferably 0.06 to 0.12 kW/m 2 , and even yet more preferably 0.07 to 0.10 kW/m 2 .
  • the degree of intertangling of the fibers will be insufficient, tending to result in lower wet strength. Moreover if the energy is higher than 0.25 kW/m 2 , tangling of the fibers will progress, increasing the wet strength, but the water disintegratability will tend to be lower, and the bending resistance will tend to be higher.
  • the high-pressure water jet energy is calculated by the following formula.
  • High ⁇ pressure water jet energy kW / m 2 1.63 ⁇ spray pressure kg / cm 2 ⁇ spray flow rate m 3 / min / transport speed M / min / 60
  • Spray flow rate m 3 /min 750 ⁇ orifice total opean area m 2 ⁇ spray pressure kg / cm 2 0.495
  • the spray pressure is the pressure inside the nozzle at the point of spraying from the high-pressure water jet nozzles
  • the spray flow rate is the total flow per minute of the high-pressure water jet sprayed from the high-pressure water jet nozzles
  • the orifice total open area is the total nozzle area of the high-pressure water jet nozzles.
  • the high-pressure water jet nozzle preferably has hole diameters of 70 to 130 ⁇ m. If the hole diameters are smaller than 70 ⁇ m the nozzle may tend to become clogged, and if the hole diameters are larger than 130 ⁇ m the efficiency of fiber tangling will tend to be reduced.
  • the high-pressure water jet nozzle pitch will generally be in the range of 0.3 to 1.0 mm.
  • the high-pressure water jet nozzle sprays the high-pressure water jet onto the web from a distance of preferably 0.5 to 3.0 cm, more preferably 0.5 to 2.0 cm and even more preferably 0.5 to 1.0 cm. If the spacing is less than 0.5 cm the web may tear, and if the spacing is greater than 3.0 cm the tangling of fibers in the web will tend to be insufficient.
  • step (1c) and step (2c) following a method known in the technical field, the aqueous dispersion of the starting material for the first hydrophobic fiber-containing layer and the aqueous dispersion of the second hydrophobic fiber-containing layer are supplied onto the support, respectively forming a web of the first hydrophobic fiber-containing layer and a web of the second hydrophobic fiber-containing layer on the support.
  • step (1d) the web of the first hydrophobic fiber-containing layer is stacked onto the surface of the first hydrophilic fiber-containing layer that has not been sprayed with the high-pressure water jet, and a water-including first sheet is formed.
  • the fibers contained therein become entangled, thereby connecting the first hydrophobic fiber-containing layer and the first hydrophilic fiber-containing layer.
  • the first hydrophobic fiber-containing layer preferably further includes hydrophilic fibers. This is because in the subsequent step (1e), the hydrophilic fibers of the first hydrophobic fiber-containing layer and the hydrophilic fibers of the first hydrophilic fiber-containing layer form hydrogen bonds, and the first hydrophobic fiber-containing layer and first hydrophilic fiber-containing layer are become connected by them.
  • Step (2d) is similar to step (1d), and from the viewpoint of the connecting strength between the second hydrophobic fiber-containing layer and the second hydrophilic fiber-containing layer, the second hydrophobic fiber-containing layer preferably further includes hydrophilic fibers.
  • the sheet is dried by a method known in the technical field.
  • the first sheet and second sheet are each preferably dried at a temperature that is lower, more preferably a temperature of at least 10°C lower, even more preferably a temperature of at least 20°C lower and yet more preferably a temperature of at least 30°C lower than the melting point of the hydrophobic fibers. If the drying temperature is close to the melting point of the hydrophobic fibers, the hydrophobic fibers may melt during drying, and the hydrophobic fibers may fuse with the other fibers, lowering the water disintegratability of the wet tissue.
  • the melting point is the lowest among the melting points of the multiple components.
  • the first sheet includes heat-fusible fibers comprising composite fibers that include a low-melting-point component and a high-melting-point component, as the hydrophobic fibers
  • the first sheet is dried in step (1e) at a temperature that is preferably lower, more preferably a temperature of at least 10°C lower, even more preferably a temperature of at least 20°C lower and yet more preferably a temperature that is at least 30°C lower, than the melting point of the low-melting-point component in the first sheet.
  • the low-melting-point component may melt during drying, and the heat-fusible fibers may fuse with the other fibers, lowering the water disintegratability of the wet tissue.
  • the second sheet includes heat-fusible fibers comprising composite fibers that include a low-melting-point component and a high-melting-point component as the hydrophobic fibers.
  • step (1e) and step (2e) can be carried out using a dryer known in the technical field, for example, a roll-type dryer, such as a yankee dryer.
  • a roll-type dryer is used to dry the first sheet
  • the first sheet is dried in such a manner that the first hydrophobic fiber-containing layer does not contact with the roll of the roll-type dryer, or in other words, the first sheet is dried with the first hydrophilic fiber-containing layer contacting the roll of the roll-type dryer. This is in order to prevent fouling of the roll due to fusion of the hydrophobic fibers.
  • the second sheet as well.
  • step (3) using a method known in the technical field, the second sheet is stacked on the first sheet with the first hydrophobic fiber-containing layer and second hydrophobic fiber-containing layer facing each other, to form a stacked sheet, and the stacked sheet is connected to form a multilayer sheet having a plurality of connected sections.
  • the stacked sheet is embossed at a temperature of at least the melting point of the low-melting-point component and below the melting point of the high-melting-point component, more preferably the stacked sheet is embossed at a temperature of at least 10°C higher than the melting point of the low-melting-point component and more than 10°C below the melting point of the high-melting-point component, even more preferably the stacked sheet is embossed at a temperature of at least 20°C higher than the melting point of the low-melting-point component and more than 20°C below the melting point of the high-melting-point component, and even yet more preferably the stacked sheet is embossed at a temperature of at least 30°C higher than the melting point of the low-melting-point component and more than 30
  • the embossing temperature is close to the melting point of the low-melting-point component, melting of the low-melting-point component will be insufficient, and connection between the first sheet and second sheet will also be sufficient, or the time for the embossing step will tend to be longer. If the embossing temperature is close to the melting point of the high-melting-point component, the high-melting-point component will melt and the embossed sections may become hard.
  • the adhesive or pressure-sensitive adhesive may be coated on the first hydrophobic fiber-containing layer and/or second hydrophobic fiber-containing layer, and the first sheet may be stacked on the second sheet with the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer facing each other, connecting the first sheet and second sheet to form a multilayer sheet.
  • the method of producing the wet tissue of the present disclosure may include, after step (3), the following step:
  • step (4) The step of (4) above will also be referred to as step (4).
  • step (4) the multilayer sheet is impregnated with a chemical solution by a method known in the technical field.
  • Fig. 5 is a schematic diagram for illustration of a method of producing a wet tissue according to one embodiment of the present disclosure, and specifically of step (1) and step (2).
  • an aqueous dispersion of the starting material for the first hydrophilic fiber-containing layer is supplied onto a support 103 from a starting material supply head 102, and a web 104 of the first hydrophilic fiber-containing layer is formed on the support 103.
  • the web 104 is dewatered with a suction box 107, and the web 104 is passed between two high-pressure water jet nozzles 105 disposed over the support 103, and two suction boxes 107 that collect water sprayed from the high-pressure water jet nozzles 105, disposed at locations facing the high-pressure water jet nozzles 105 in a manner sandwiching the support 103.
  • the web 104 receives a high-pressure water jet from the high-pressure water jet nozzle 105, tangling the fibers together and forming a first hydrophilic fiber-containing layer 106 that contains water.
  • the energy received from the high-pressure water jets, etc., ridges and furrows will sometimes be formed on the surface of the first hydrophilic fiber-containing layer 106 facing the high-pressure water jet nozzles 105.
  • an aqueous dispersion of the starting material for the first hydrophobic fiber-containing layer is supplied onto the support 113 from a starting material supply head 112, and a web 114 of the first hydrophobic fiber-containing layer is formed on the support 113.
  • the web 114 is dewatered by a suction box 117 and the dewatered web 114 is transferred onto a transport conveyor 121.
  • the web 114 of the first hydrophobic fiber-containing layer transported by the transport conveyor 121 is then stacked on the first hydrophilic fiber-containing layer 106 to form a first sheet 122.
  • the first sheet 122 is transferred to the transport conveyor 123, after which it is transferred to a dryer 124.
  • the dryer 124 may be a yankee dryer, for example.
  • the dried first sheet 122 is then wound onto a wind-up roll 125.
  • the second sheet can be produced using the production apparatus 101 shown in Fig. 5 , similar to the first sheet, and therefore it will not be explained here.
  • Fig. 6 is a schematic diagram for illustration of a method of producing a wet tissue according to one embodiment of the present disclosure, and specifically of step (3) and step (4).
  • the second sheet 127 wound out from the wind-up roll 126 is stacked onto the first sheet 122 wound out from the wind-up roll 125, with the first hydrophobic fiber-containing layer (not shown) and the second hydrophobic fiber-containing layer (not shown) facing each other, to form the stacked sheet 128.
  • the stacked sheet 128 is then passed between a pair of embossing rolls 129 that are heated, to form a multilayer sheet 130 having a plurality of embossed sections (not shown).
  • a plurality of embossed sections are formed connecting the first hydrophobic fiber-containing layer (not shown) and second hydrophobic fiber-containing layer (not shown).
  • the multilayer sheet 130 is then cut to a prescribed size and the cut sheet is folded and impregnated with a chemical solution to complete the wet tissue.
  • the method of producing a wet tissue according to yet another embodiment of the present disclosure further includes a step of crepe treatment of the first sheet and/or second sheet.
  • the wet tissue will have a fold structure, providing effects, such as improved dirt removability and improved feel on the skin.
  • the step of crepe treatment of the first sheet is preferably carried out after step (1 e).
  • the step of crepe treatment of the second sheet is also preferably carried out after step (2e).
  • the crepe treatment is carried out, for example, at the dryer 124 shown in Fig. 5 , by pulling the first sheet 122, which is adhered to the surface of the dryer 124, off from the surface using a doctor blade.
  • the wet tissue of the present disclosure can also be produced by steps known in the prior art, such as a combination of the steps described in Japanese Unexamined Patent Publication No. 2012-202004 , Japanese Unexamined Patent Publication No. 2012-20211 and Japanese Unexamined Patent Publication No. 2013-76196 , for example.
  • NNKP Northern bleached Kraft pulp
  • the Northern bleached Kraft pulp was mixed with a mixer to obtain beaten pulp having a CSF of 600 mL.
  • Corona (mean fiber length: 5 mm, 0.7 dtex) by Daiwabo Rayon Co., Ltd. was prepared.
  • Core-sheath composite fibers (trade name: Tepilus, type: TJ04BN, cut length: 5 mm, 2.2 dtex) by Teijin, Ltd. were prepared.
  • the core was PET with a melting point of 265°C
  • the sheath was terephthalate-based fiber with a melting point of 150°C.
  • Aqueous dispersion No. 1 as the starting material for the first hydrophilic fiber-containing layer containing 70 parts by mass of beaten pulp and 30 parts by mass of rayon (A), was prepared.
  • aqueous dispersion No. 1 as the starting material for the first hydrophilic fiber-containing layer was supplied onto the support (OS80 by Nippon Filcon Co., Ltd.) from the starting material supply head, and dewatering was carried out from a suction box to form web No. 1 of the first hydrophilic fiber-containing layer.
  • a high-pressure water jet was sprayed onto web No. 1 of the first hydrophilic fiber-containing layer from a high-pressure water jet nozzle, while suctioning the water by suction from below the support, to obtain first hydrophilic fiber-containing layer No. 1.
  • the high-pressure water jet nozzles were situated at a distance of about 2 cm from above web No. 1 for the first sheet, and they had hole diameters of 92 ⁇ m and hole pitches of 0.5 mm.
  • the energy received by the high-pressure water jet was 0.088 (KW/m 2 ).
  • aqueous dispersion No. 1 was prepared as the starting material for the first hydrophobic fiber-containing layer, containing 60 parts by mass of beaten pulp, 32 parts by mass of non-beaten pulp and 8 parts by mass of heat-fusible fiber.
  • aqueous dispersion No. 1 as the starting material for the first hydrophobic fiber-containing layer was supplied onto the support (OS80 by Nippon Filcon Co., Ltd.) from the starting material supply head, and dewatering was carried out from a suction box to form web No. 1 of the first hydrophobic fiber-containing layer.
  • Web No. 1 for the hydrophobic fiber-containing layer was stacked over hydrophilic fiber-containing layer No. 1, to form first sheet No. 1 containing water, and first sheet No. 1 was dried for about 4 seconds with a yankee dryer kept at 120°C.
  • the dried first sheet No. 1 had hydrophobic fiber-containing layer No. 1 and hydrophilic fiber-containing layer No. 1 connected by hydrogen bonding, for example.
  • Second sheet No. 1 was obtained by the same production method as for first sheet No. 1.
  • Second sheet No. 1 was stacked onto first sheet No. 1 with the first hydrophobic fiber-containing layer No. 1 and second hydrophobic fiber-containing layer No. 1 facing each other, to form stacked sheet No. 1, and then the stacked sheet No. 1 was passed through a pair of embossing rolls that had been heated to 160°C, to form multilayer sheet No. 1 having a plurality of embossed sections.
  • the pair of embossing rolls had rotational axis lines in the direction perpendicular to the machine direction, and had protrusions with diameters of 2.2 mm disposed on the outer peripheral surface of the upper roll in a square zigzag fashion at a pitch of 20 mm in the machine direction and 20 mm in the cross-machine direction, while the surface of the lower roll was flat.
  • Multilayer sheet No. 1 had embossed sections with diameters of 2.2 mm (area: approximately 3.8 mm 2 ) arranged in a square zigzag fashion at a pitch of 20 mm in the machine direction and 20 mm in the cross-machine direction, the spacing of the embossed sections was approximately 12 mm, and the embossed sections had an area ratio of 1.7% with respect to the multilayer sheet.
  • Multilayer sheet No. 1 was cut to approximately 20 cm x 13 cm and impregnated with a chemical solution to produce wet tissue No. 1.
  • a wet tissue was produced according to the method described in PTL 5. Specifically, 26 parts by mass of beaten pulp (CSF: 600 mL), 50 parts by mass of non-beaten pulp (CSF: 740 mL), 21 parts by mass of rayon (B) and 3 parts by mass of fibrillated cellulose fiber were mixed together with water, and a square sheet machine was used to produce a fiber web by a wet paper forming method.
  • the fiber web was placed on a 100 mesh plastic net, and the fiber web was sprayed with a high-pressure water jet from high-pressure water jet nozzles (nozzle diameter: 92 ⁇ , 0.5 mm pitch) while suctioning off the water by suction from below, after which it was dried with a rotary dryer to obtain sheet No. 2.
  • Sheet No. 2 was impregnated with a chemical solution to obtain wet tissue No. 2.
  • the energy received by the high-pressure water jet was 0.285 (KW/m 2 ).
  • the fibrillated cellulose fiber was prepared by wet beating Tencel (trade name of Lenzing (Austria), mean fiber length: 3 mm, 1.7 dtex) with a batch macerator (pulper by Aikawa Iron Works Co.) and a continuous macerator (B-type Top Finer by Aikawa Iron Works Co.), and the fiber length in the peak of the weight-weighted average fiber length distribution of the fibrillated cellulose was 3 mm, the mass of the microfiber portion was 1.54 mass%, and the Canadian Standard Freeness was 200 mL.
  • the "thickness” was measured using an FS-60DS by Daiei Kagaku Seiki Mfg. Co., Ltd. (probe: 15 cm 2 , measuring load: 3 gf/cm 2 ), and the mean value of the thickness at 3 locations was used.
  • the "wet strength" for the wet tissue was measured by the method described in the present specification, and for the first sheet and second sheet it was measured in the same manner as for the wet tissue, after allowing the sheet to absorb 250 mass% of distilled water.
  • the tensile strength was measured using an AGS-1kNG autograph by Shimadzu Corp.
  • the "disintegratability" was measured by the method described in the present specification.
  • the first sheet and second sheet were separated after embossing was formed in the multilayer sheet, and were supplied to a disintegration test.
  • the wet tissue it was supplied directly to the disintegration test.
  • the disintegratability was measured using a TTP stirrer for paper disintegration testing, by As One Corp.
  • the "bending resistance” was measured by the method described in the present specification.
  • Example No. Example 1 Comp. Example 1 First sheet and second sheet Sheet No. No.1 No.2 Sheet type First Second - Fiber-containing layer Hydrophilic Hydrophobic Hydrophilic Hydrophobic - Beaten pulp (parts) 70 60 70 60 26 Non-beaten pulp (parts) - 32 - 32 50 Rayon (A) (parts) 30 - 30 - - Rayon (B) (parts) - - - - 21 Heat-fusible fiber (parts) - 8 - 8 - Fibrillated cellulose fiber (parts) - - - - 3 High-pressure water jet energy (kW/m 2 ) 0.088 - 0.088 - 0.285 Dry basis weight (g/m 2 ) 14.2 15.0 14.2 15.0 - Dry thickness (mm) 0.12 0.12 - Wet strength (N/25 ).
  • Table 1 shows that in Example 1, the tensile strength of the wet tissue in the machine direction and cross-machine direction was greater than 1.0 N/25 mm, while the disintegratability of the first sheet and second sheet was less than 100 seconds, indicating that both wet strength and water disintegratability had been obtained.
  • Starting material No. 1 for a first sheet was prepared containing 45 parts by mass of beaten pulp, 32 parts by mass of non-beaten pulp, 15 parts by mass of rayon (A) and 8 parts by mass of heat-fusible fibers.
  • starting material No. 1 for the first sheet was supplied onto the support (OS80 by Nippon Filcon Co., Ltd.) from the starting material supply head, and dewatering was carried out from the suction boxes to form web No. 11 for the first sheet.
  • a high-pressure water jet was sprayed onto web No. 11 for the first sheet from the high-pressure water jet nozzles, while suctioning the water with a suction from below the support, to obtain first sheet No. 11.
  • the high-pressure water jet nozzles were situated at a distance of about 2 cm from above web No. 11 for the first sheet, and they had hole diameters of 92 ⁇ m and hole pitches of 0.5 mm.
  • the energy received by the high-pressure water jets was 0.088 (KW/m 2 ).
  • first sheet No. 11 was dried for approximately 4 seconds with a yankee dryer kept at 120°C.
  • Second sheet No. 11 was obtained by the same production method as for first sheet No. 11.
  • Second sheet No. 11 was stacked onto first sheet No. 11 to form stacked sheet No. 11, and then stacked sheet No. 11 was passed through a pair of embossing rolls that had been heated to 160°C, to form multilayer sheet No. 11 having a plurality of embossed sections.
  • the pair of embossing rolls were identical to those used in Production Example 1.
  • Multilayer sheet No. 1 was cut to approximately 20 cm x approximately 13 cm and impregnated with a chemical solution to produce wet tissue No. 1.
  • First sheet No. 12, second sheet No. 12, multilayer sheet No. 12 and wet tissue No. 12 were produced in the same manner as Reference Production Example 1, except that the upper roll of the pair of embossing rolls was changed to one having protrusions with diameters of 0.88 mm arranged in a 60° zigzag pattern with a pitch of 4.5 mm in the cross-machine direction.
  • Multilayer sheet No. 12 had embossed sections with diameters of 0.88 mm (area: approximately 0.6 mm 2 ) arranged in a 60° zigzag fashion at a pitch of 4.5 mm in the cross-machine direction, the spacing of the embossed sections being approximately 3.6 mm, and the embossed sections having an area ratio of 3.4% with respect to the multilayer sheet.
  • First sheet No. 13, second sheet No. 13, multilayer sheet No. 13 and wet tissue No. 13 were produced in the same manner as Reference Production Example 1, except that the upper roll of the pair of embossing rolls was changed to one having on the outer peripheral surface protrusions with widths of 1.5 mm protruding in the direction perpendicular to the rotational axis line, arranged continuously at a pitch of 10 mm.
  • Multilayer sheet No. 13 had embossed sections with widths of 1.5 mm, extending in the machine direction, arranged in a striped fashion at a pitch of 10 mm in the cross-machine direction, the spacing between the embossed sections being 8.5 mm, and the embossed sections having an area ratio of 15% with respect to the multilayer sheet.
  • Table 2 suggests that the water disintegratability is excellent even when the embossing spacing is shorter than the rayon mean fiber length. Furthermore, Table 2 suggests that the water disintegratability is excellent even when the area ratio of the adhesive sections is high.
  • the present disclosure relates to the following aspects J1 to J16.
  • a wet tissue with water disintegratability including a multilayer sheet comprising a first sheet and a second sheet, wherein the first sheet includes a first hydrophilic fiber-containing layer including hydrophilic fibers at 95 to 100 mass% and a first hydrophobic fiber-containing layer including hydrophobic fibers at 5 to 30 mass%, and the second sheet includes a second hydrophilic fiber-containing layer including hydrophilic fiber at 95 to 100 mass% and a second hydrophobic fiber-containing layer including hydrophobic fiber at 5 to 30 mass%, the first hydrophobic fiber-containing layer being disposed adjacent to the second hydrophobic fiber-containing layer, the multilayer sheet having a plurality of connected sections, disposed across spacings, where the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer are connected, the spacings between the plurality of connected sections being 0.6 times or above the mean fiber length of the hydrophobic fibers of the first hydrophobic fiber-containing layer and 0.6 times or above the mean fiber length of the hydrophobic fibers of the second hydropho
  • a fiber density of the first hydrophobic fiber-containing layer is higher than a fiber density of the first hydrophilic fiber-containing layer
  • a fiber density of the second hydrophobic fiber-containing layer is higher than a fiber density of the second hydrophilic fiber-containing layer
  • each of the first hydrophobic fiber-containing layer and second hydrophobic fiber-containing layer includes, as the hydrophobic fibers, heat-fusible fibers consisting of composite fibers that include a low-melting-point component and a high-melting-point component having a higher melting point than the low-melting-point component.
  • each of the plurality of the connected sections is an embossed section, and in the embossed section, at least some of the low-melting-point component of the hydrophobic fibers of the first hydrophobic fiber-containing layer are fused with the fibers in the second hydrophobic fiber-containing layer, and/or at least some of the low-melting-point component of the hydrophobic fibers of the second hydrophobic fiber-containing layer are fused with the fibers in the first hydrophobic fiber-containing layer.
  • each of the plurality of connected sections has an area of 0.4 to 9 mm 2 .
  • each of the first hydrophilic fiber-containing layer and second hydrophilic fiber-containing layer includes hydrophilic fibers at 100 mass%, and each of the first hydrophobic fiber-containing layer and second hydrophobic fiber-containing layer includes hydrophobic fibers at 5 to 30 mass% and hydrophilic fibers at 70 to 95 mass%.
  • hydrophilic fibers of the first hydrophilic fiber-containing layer and/or the hydrophilic fibers of the second hydrophilic fiber-containing layer include pulp and regenerated cellulose.
  • a method of producing the wet tissue according to any one of J1 to J10 including the steps of:
  • step (1) further includes the steps of:
  • step (2) further includes the steps of:
  • each of the first hydrophobic fiber-containing layer and the second hydrophobic fiber-containing layer include, as hydrophobic fibers, heat-fusible fibers consisting of composite fibers including a low-melting-point component and a high-melting-point component having a higher melting point than the low-melting-point component, in step (1), the water-including first sheet is dried at a temperature lower than the melting point of the low-melting-point component of the hydrophobic fibers in the first hydrophobic fiber-containing layer, and in step (2), the water-including second sheet is dried at a temperature lower than the melting point of the low-melting-point component of the hydrophobic fibers in the second hydrophobic fiber-containing layer.
  • step (3) the stacked sheet is embossed at a temperature at or above the melting point of the low-melting-point component of the hydrophobic fibers in the first hydrophobic fiber-containing layer and the low-melting-point component of the hydrophobic fibers in the second hydrophobic fiber-containing layer, and below the melting point of the high-melting-point component of the hydrophobic fibers in the first hydrophobic fiber-containing layer and the high-melting-point component of the hydrophobic fibers in the second hydrophobic fiber-containing layer, to form a multilayer sheet having a plurality of connected sections.
  • step (1e) the water-including first sheet is dried while contacting the first hydrophilic fiber-containing layer with a roll of a roll-type dryer.
  • step (2e) the water-including second sheet is dried while contacting the second hydrophilic fiber-containing layer with a roll of a roll-type dryer.
  • step (1) further includes a step of crepe treatment of the first sheet
  • step (2) further includes a step of crepe treatment of the second sheet.

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  • Sanitary Thin Papers (AREA)
EP15768546.2A 2014-03-28 2015-01-22 Feuchttuch und verfahren zur herstellung des feuchttuchs Not-in-force EP3123913B1 (de)

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JP2014070528A JP5805251B2 (ja) 2014-03-28 2014-03-28 ウェットティッシュ、及びウェットティッシュの製造方法
PCT/JP2015/051693 WO2015146256A1 (ja) 2014-03-28 2015-01-22 ウェットティッシュ、及びウェットティッシュの製造方法

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Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT512460B1 (de) * 2011-11-09 2013-11-15 Chemiefaser Lenzing Ag Dispergierbare nicht-gewebte Textilien
WO2017106422A1 (en) 2015-12-15 2017-06-22 The Procter & Gamble Company Compressible pre-moistened fibrous structures
WO2017106417A1 (en) 2015-12-15 2017-06-22 The Procter & Gamble Company Pre-moistened fibrous structures exhibiting increased capacity
US11479919B2 (en) 2018-08-23 2022-10-25 Eastman Chemical Company Molded articles from a fiber slurry
US11339537B2 (en) 2018-08-23 2022-05-24 Eastman Chemical Company Paper bag
US11421385B2 (en) 2018-08-23 2022-08-23 Eastman Chemical Company Soft wipe comprising cellulose acetate
US11530516B2 (en) 2018-08-23 2022-12-20 Eastman Chemical Company Composition of matter in a pre-refiner blend zone
US11390996B2 (en) 2018-08-23 2022-07-19 Eastman Chemical Company Elongated tubular articles from wet-laid webs
US11332885B2 (en) 2018-08-23 2022-05-17 Eastman Chemical Company Water removal between wire and wet press of a paper mill process
US11230811B2 (en) 2018-08-23 2022-01-25 Eastman Chemical Company Recycle bale comprising cellulose ester
US11421387B2 (en) 2018-08-23 2022-08-23 Eastman Chemical Company Tissue product comprising cellulose acetate
US11414818B2 (en) 2018-08-23 2022-08-16 Eastman Chemical Company Dewatering in paper making process
US11492755B2 (en) 2018-08-23 2022-11-08 Eastman Chemical Company Waste recycle composition
US11396726B2 (en) 2018-08-23 2022-07-26 Eastman Chemical Company Air filtration articles
US11390991B2 (en) 2018-08-23 2022-07-19 Eastman Chemical Company Addition of cellulose esters to a paper mill without substantial modifications
US11519132B2 (en) 2018-08-23 2022-12-06 Eastman Chemical Company Composition of matter in stock preparation zone of wet laid process
US11332888B2 (en) 2018-08-23 2022-05-17 Eastman Chemical Company Paper composition cellulose and cellulose ester for improved texturing
US11492756B2 (en) 2018-08-23 2022-11-08 Eastman Chemical Company Paper press process with high hydrolic pressure
US11299854B2 (en) 2018-08-23 2022-04-12 Eastman Chemical Company Paper product articles
US11492757B2 (en) 2018-08-23 2022-11-08 Eastman Chemical Company Composition of matter in a post-refiner blend zone
US11639579B2 (en) * 2018-08-23 2023-05-02 Eastman Chemical Company Recycle pulp comprising cellulose acetate
US11408128B2 (en) 2018-08-23 2022-08-09 Eastman Chemical Company Sheet with high sizing acceptance
US11286619B2 (en) 2018-08-23 2022-03-29 Eastman Chemical Company Bale of virgin cellulose and cellulose ester
US11401659B2 (en) 2018-08-23 2022-08-02 Eastman Chemical Company Process to produce a paper article comprising cellulose fibers and a staple fiber
US11512433B2 (en) 2018-08-23 2022-11-29 Eastman Chemical Company Composition of matter feed to a head box
US11525215B2 (en) 2018-08-23 2022-12-13 Eastman Chemical Company Cellulose and cellulose ester film
US11441267B2 (en) * 2018-08-23 2022-09-13 Eastman Chemical Company Refining to a desirable freeness
US11401660B2 (en) 2018-08-23 2022-08-02 Eastman Chemical Company Broke composition of matter
US11306433B2 (en) 2018-08-23 2022-04-19 Eastman Chemical Company Composition of matter effluent from refiner of a wet laid process
US11414791B2 (en) 2018-08-23 2022-08-16 Eastman Chemical Company Recycled deinked sheet articles
US11466408B2 (en) 2018-08-23 2022-10-11 Eastman Chemical Company Highly absorbent articles
US11313081B2 (en) 2018-08-23 2022-04-26 Eastman Chemical Company Beverage filtration article
CN114908602B (zh) * 2022-04-19 2023-09-22 苏州大学 可冲散湿巾的制备方法及可冲散湿巾

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3566044B2 (ja) * 1997-09-24 2004-09-15 ユニ・チャーム株式会社 水解性の繊維シート及びそれが重ねられた拭き取り用シート
JP3148735B2 (ja) * 1999-04-02 2001-03-26 花王株式会社 ウェットシート用基材
JP3748022B2 (ja) * 1999-11-19 2006-02-22 ユニ・チャーム株式会社 水解性の吸収性物品およびその製造方法
US6361784B1 (en) * 2000-09-29 2002-03-26 The Procter & Gamble Company Soft, flexible disposable wipe with embossing
JP3938290B2 (ja) * 2001-05-16 2007-06-27 ユニ・チャーム株式会社 水解性シートおよびその製造方法
JP3993452B2 (ja) * 2002-03-29 2007-10-17 ユニ・チャーム株式会社 薄型の吸収性物品およびその製造方法
JP4454289B2 (ja) * 2003-11-13 2010-04-21 明星産商株式会社 柄模様現出ウェットティッシュ
JP4619110B2 (ja) * 2004-12-27 2011-01-26 花王株式会社 水解紙の製造方法及び水解性清拭物品の製造方法
JP4456610B2 (ja) * 2007-01-31 2010-04-28 大王製紙株式会社 衛生薄葉紙
JP4585530B2 (ja) * 2007-02-02 2010-11-24 大王製紙株式会社 薄葉紙
JP5237623B2 (ja) * 2007-12-25 2013-07-17 花王株式会社 ウエットシート用シート基材
WO2010021572A1 (en) * 2008-08-19 2010-02-25 Sca Hygiene Products Ab A tissue paper/nonwoven laminate product
JP5317995B2 (ja) * 2010-01-26 2013-10-16 日本製紙クレシア株式会社 洗浄機能付きトイレ用トイレットペーパー
WO2012078860A1 (en) * 2010-12-08 2012-06-14 Buckeye Technologies Inc. Dispersible nonwoven wipe material

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JP2015188711A (ja) 2015-11-02
EP3123913A4 (de) 2017-03-15

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